#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/19/4311990.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4311990
loop_
_publ_author_name
'Yan-Dan Chen'
'Li-Yi Zhang'
'Lin-Xi Shi'
'Zhong-Ning Chen'
_publ_section_title
;
 Syntheses, Characterization, and Luminescence of PtII-MI (M = Cu, Ag, Au)
 Heterometallic Complexes by Incorporating Pt(diimine)(dithiolate) with
 [M2(dppm)2]2+ (dppm = Bis(diphenylphosphino)methane)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7493
_journal_page_last               7501
_journal_paper_doi               10.1021/ic049104r
_journal_volume                  43
_journal_year                    2004
_chemical_formula_sum            'C31 H37 Ag Cl0 F6 O1.5 P2 Pt S2 Sb'
_chemical_formula_weight         1098.38
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.2270(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.7116(5)
_cell_length_b                   18.9579(7)
_cell_length_c                   16.2170(7)
_cell_measurement_reflns_used    5237
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.01
_cell_measurement_theta_min      1.66
_cell_volume                     3897.4(3)
_computing_cell_refinement       'Siemens SMART & SAINT'
_computing_data_collection       'Siemens SMART'
_computing_data_reduction        'Siemens XPREP'
_computing_structure_refinement  'Siemens SHELXTL'
_computing_structure_solution    'Siemens SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.983
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Siemens SMART CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0370
_diffrn_reflns_av_sigmaI/netI    0.0502
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            11144
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.66
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  .
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.009
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  .5770
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.872
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2108
_exptl_crystal_size_max          .41
_exptl_crystal_size_mid          .30
_exptl_crystal_size_min          .27
_refine_diff_density_max         2.049
_refine_diff_density_min         -1.638
_refine_diff_density_rms         0.201
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.207
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     385
_refine_ls_number_reflns         6759
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.207
_refine_ls_R_factor_all          0.1040
_refine_ls_R_factor_gt           0.0721
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0570P)²+54.2445P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1585
_refine_ls_wR_factor_ref         0.1844
_reflns_number_gt                5112
_reflns_number_total             6759
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic049104rsi20040708_085850_2.cif
_cod_data_source_block           2(Compound17)
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_formula_sum        'C31 H37 Ag Cl0 F6 O1.50 P2 Pt S2 Sb'
_cod_database_code               4311990
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt 0.41478(4) 0.06817(3) 0.62013(3) 0.04255(18) Uani 1 1 d . . .
Ag Ag 0.50426(11) 0.07194(6) 0.44469(8) 0.0630(3) Uani 1 1 d . . .
Sb Sb 0.49698(10) 0.39571(7) 0.19903(9) 0.0800(4) Uani 1 1 d . . .
S1 S 0.3311(3) -0.0419(2) 0.6134(3) 0.0620(10) Uani 1 1 d . . .
S2 S 0.3313(3) 0.0959(2) 0.4907(2) 0.0623(10) Uani 1 1 d . . .
P1 P 0.5065(3) 0.16946(18) 0.6448(2) 0.0460(8) Uani 1 1 d . . .
P2 P 0.5059(3) 0.05533(19) 0.7446(2) 0.0484(9) Uani 1 1 d . . .
F1 F 0.3622(14) 0.3780(18) 0.2187(17) 0.289(17) Uani 1 1 d . . .
F2 F 0.462(3) 0.4848(12) 0.184(2) 0.36(2) Uani 1 1 d . . .
F3 F 0.524(2) 0.4187(19) 0.3047(14) 0.281(16) Uani 1 1 d . . .
F4 F 0.6314(14) 0.4110(17) 0.1717(15) 0.262(15) Uani 1 1 d . . .
F5 F 0.535(3) 0.3117(12) 0.221(3) 0.36(2) Uani 1 1 d . . .
F6 F 0.4681(19) 0.377(2) 0.0954(14) 0.33(2) Uani 1 1 d . . .
O01 O 0.679(3) 0.224(2) 0.923(2) 0.287(17) Uiso 1 1 d D . .
O02 O 1.045(4) 0.038(3) 1.032(3) 0.20(2) Uiso 0.50 1 d P . .
C1 C 0.5887(13) 0.1351(8) 0.7361(10) 0.063(4) Uani 1 1 d . . .
H1A H 0.6605 0.1243 0.7238 0.076 Uiso 1 1 calc R . .
H1B H 0.5884 0.1657 0.7840 0.076 Uiso 1 1 calc R . .
C01 C 0.738(3) 0.181(2) 0.977(3) 0.209(17) Uiso 1 1 d D . .
H01A H 0.6882 0.1591 1.0125 0.251 Uiso 1 1 calc R . .
H01B H 0.7823 0.2116 1.0125 0.251 Uiso 1 1 calc R . .
C2 C 0.2301(16) -0.0293(12) 0.5289(16) 0.106(8) Uani 1 1 d . . .
H2A H 0.2091 -0.0752 0.5072 0.127 Uiso 1 1 calc R . .
H2B H 0.1689 -0.0081 0.5513 0.127 Uiso 1 1 calc R . .
C02 C 0.808(5) 0.122(3) 0.949(4) 0.34(3) Uiso 1 1 d D . .
H02A H 0.8406 0.0979 0.9971 0.509 Uiso 1 1 calc R . .
H02B H 0.8623 0.1413 0.9178 0.509 Uiso 1 1 calc R . .
H02C H 0.7669 0.0887 0.9160 0.509 Uiso 1 1 calc R . .
C3 C 0.2598(18) 0.0130(15) 0.4628(13) 0.114(9) Uani 1 1 d . . .
H3A H 0.1965 0.0250 0.4286 0.137 Uiso 1 1 calc R . .
H3B H 0.3038 -0.0152 0.4292 0.137 Uiso 1 1 calc R . .
C03 C 0.608(3) 0.257(2) 0.974(2) 0.25(2) Uiso 1 1 d D . .
H03A H 0.6435 0.2886 1.0145 0.296 Uiso 1 1 calc R . .
H03B H 0.5653 0.2236 1.0019 0.296 Uiso 1 1 calc R . .
C04 C 0.543(2) 0.2981(16) 0.9071(18) 0.144(10) Uiso 1 1 d D . .
H04A H 0.4889 0.3247 0.9317 0.217 Uiso 1 1 calc R . .
H04B H 0.5104 0.2655 0.8676 0.217 Uiso 1 1 calc R . .
H04C H 0.5879 0.3296 0.8798 0.217 Uiso 1 1 calc R . .
C11 C 0.4296(13) 0.2446(8) 0.6801(10) 0.063(4) Uani 1 1 d . . .
C12 C 0.4747(16) 0.3105(9) 0.6851(15) 0.101(8) Uani 1 1 d . . .
H12A H 0.5444 0.3172 0.6729 0.121 Uiso 1 1 calc R . .
C13 C 0.414(3) 0.3667(12) 0.7086(18) 0.134(10) Uani 1 1 d . . .
H13A H 0.4428 0.4118 0.7091 0.160 Uiso 1 1 calc R . .
C14 C 0.317(2) 0.3582(12) 0.7304(16) 0.121(10) Uani 1 1 d . . .
H14A H 0.2802 0.3959 0.7510 0.145 Uiso 1 1 calc R . .
C15 C 0.2720(18) 0.2936(12) 0.7223(15) 0.108(8) Uani 1 1 d . . .
H15A H 0.2020 0.2879 0.7340 0.130 Uiso 1 1 calc R . .
C16 C 0.3281(15) 0.2361(9) 0.6968(11) 0.075(5) Uani 1 1 d . . .
H16A H 0.2962 0.1921 0.6913 0.090 Uiso 1 1 calc R . .
C21 C 0.5885(13) 0.2048(7) 0.5684(9) 0.053(4) Uani 1 1 d . . .
C22 C 0.5376(16) 0.2320(9) 0.4969(11) 0.074(5) Uani 1 1 d . . .
H22A H 0.4644 0.2346 0.4913 0.088 Uiso 1 1 calc R . .
C23 C 0.598(2) 0.2559(11) 0.4327(14) 0.107(8) Uani 1 1 d . . .
H23A H 0.5641 0.2723 0.3836 0.128 Uiso 1 1 calc R . .
C24 C 0.708(2) 0.2550(12) 0.4430(15) 0.104(8) Uani 1 1 d . . .
H24A H 0.7484 0.2736 0.4027 0.125 Uiso 1 1 calc R . .
C25 C 0.7552(18) 0.2256(12) 0.5146(16) 0.100(7) Uani 1 1 d . . .
H25A H 0.8284 0.2224 0.5209 0.120 Uiso 1 1 calc R . .
C26 C 0.6986(13) 0.2017(9) 0.5747(12) 0.071(5) Uani 1 1 d . . .
H26A H 0.7332 0.1825 0.6220 0.085 Uiso 1 1 calc R . .
C31 C 0.4355(13) 0.0640(8) 0.8372(9) 0.058(4) Uani 1 1 d . . .
C32 C 0.4891(19) 0.0774(11) 0.9125(10) 0.091(6) Uani 1 1 d . . .
H32A H 0.5620 0.0825 0.9172 0.110 Uiso 1 1 calc R . .
C33 C 0.430(3) 0.0831(14) 0.9818(14) 0.117(9) Uani 1 1 d . . .
H33A H 0.4651 0.0941 1.0324 0.141 Uiso 1 1 calc R . .
C34 C 0.325(3) 0.0733(14) 0.9787(15) 0.111(8) Uani 1 1 d . . .
H34A H 0.2884 0.0750 1.0264 0.134 Uiso 1 1 calc R . .
C35 C 0.273(2) 0.0609(13) 0.9038(15) 0.108(8) Uani 1 1 d . . .
H35A H 0.2000 0.0551 0.9006 0.130 Uiso 1 1 calc R . .
C36 C 0.3276(17) 0.0565(10) 0.8292(14) 0.089(6) Uani 1 1 d . . .
H36A H 0.2916 0.0490 0.7779 0.106 Uiso 1 1 calc R . .
C41 C 0.5857(14) -0.0232(8) 0.7622(10) 0.062(4) Uani 1 1 d . . .
C42 C 0.6939(16) -0.0230(11) 0.7573(13) 0.090(6) Uani 1 1 d . . .
H42A H 0.7300 0.0190 0.7504 0.108 Uiso 1 1 calc R . .
C43 C 0.747(2) -0.0868(12) 0.7628(18) 0.117(9) Uani 1 1 d . . .
H43A H 0.8201 -0.0871 0.7598 0.140 Uiso 1 1 calc R . .
C44 C 0.697(3) -0.1481(13) 0.7725(17) 0.125(10) Uani 1 1 d . . .
H44A H 0.7357 -0.1898 0.7753 0.150 Uiso 1 1 calc R . .
C45 C 0.591(2) -0.1506(10) 0.7783(15) 0.109(8) Uani 1 1 d . . .
H45A H 0.5565 -0.1932 0.7859 0.131 Uiso 1 1 calc R . .
C46 C 0.5346(17) -0.0869(9) 0.7724(12) 0.078(5) Uani 1 1 d . . .
H46A H 0.4618 -0.0873 0.7753 0.094 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Pt P1 73.21(13) . . ?
P2 Pt S1 98.44(15) . . ?
P1 Pt S1 171.64(15) . . ?
P2 Pt S2 172.51(15) . . ?
P1 Pt S2 99.30(15) . . ?
S1 Pt S2 89.05(16) . . ?
P2 Pt Ag 92.86(10) . 3_656 ?
P1 Pt Ag 127.87(10) . 3_656 ?
S1 Pt Ag 51.21(11) . 3_656 ?
S2 Pt Ag 91.62(11) . 3_656 ?
P2 Pt Ag 127.87(11) . . ?
P1 Pt Ag 85.69(10) . . ?
S1 Pt Ag 99.86(11) . . ?
S2 Pt Ag 49.71(11) . . ?
Ag Pt Ag 63.61(4) 3_656 . ?
S2 Ag S1 174.21(15) . 3_656 ?
S2 Ag Pt 127.24(12) . 3_656 ?
S1 Ag Pt 48.83(9) 3_656 3_656 ?
S2 Ag Pt 47.66(10) . . ?
S1 Ag Pt 136.61(12) 3_656 . ?
Pt Ag Pt 116.39(4) 3_656 . ?
S2 Ag Ag 85.39(12) . 3_656 ?
S1 Ag Ag 94.69(12) 3_656 3_656 ?
Pt Ag Ag 59.38(4) 3_656 3_656 ?
Pt Ag Ag 57.01(4) . 3_656 ?
F5 Sb F6 93(2) . . ?
F5 Sb F2 175(2) . . ?
F6 Sb F2 91.9(19) . . ?
F5 Sb F3 89.5(18) . . ?
F6 Sb F3 177.6(19) . . ?
F2 Sb F3 85.9(17) . . ?
F5 Sb F1 92.8(17) . . ?
F6 Sb F1 89.8(11) . . ?
F2 Sb F1 88.3(17) . . ?
F3 Sb F1 89.5(12) . . ?
F5 Sb F4 86.7(15) . . ?
F6 Sb F4 86.2(12) . . ?
F2 Sb F4 92.5(16) . . ?
F3 Sb F4 94.6(12) . . ?
F1 Sb F4 175.9(12) . . ?
C2 S1 Pt 102.1(7) . . ?
C2 S1 Ag 108.6(8) . 3_656 ?
Pt S1 Ag 79.95(12) . 3_656 ?
C3 S2 Pt 102.1(8) . . ?
C3 S2 Ag 101.9(9) . . ?
Pt S2 Ag 82.64(13) . . ?
C21 P1 C11 105.9(7) . . ?
C21 P1 C1 110.8(7) . . ?
C11 P1 C1 107.6(8) . . ?
C21 P1 Pt 120.6(5) . . ?
C11 P1 Pt 115.6(5) . . ?
C1 P1 Pt 95.4(5) . . ?
C31 P2 C41 104.4(7) . . ?
C31 P2 C1 107.8(8) . . ?
C41 P2 C1 111.6(8) . . ?
C31 P2 Pt 118.5(6) . . ?
C41 P2 Pt 118.2(5) . . ?
C1 P2 Pt 95.9(5) . . ?
C01 O01 C03 103(3) . . ?
P2 C1 P1 93.2(7) . . ?
P2 C1 H1A 113.1 . . ?
P1 C1 H1A 113.1 . . ?
P2 C1 H1B 113.1 . . ?
P1 C1 H1B 113.1 . . ?
H1A C1 H1B 110.5 . . ?
O01 C01 C02 123(4) . . ?
O01 C01 H01A 106.5 . . ?
C02 C01 H01A 106.5 . . ?
O01 C01 H01B 106.5 . . ?
C02 C01 H01B 106.5 . . ?
H01A C01 H01B 106.5 . . ?
C3 C2 S1 115.7(15) . . ?
C3 C2 H2A 108.4 . . ?
S1 C2 H2A 108.4 . . ?
C3 C2 H2B 108.4 . . ?
S1 C2 H2B 108.4 . . ?
H2A C2 H2B 107.4 . . ?
C01 C02 H02A 109.5 . . ?
C01 C02 H02B 109.5 . . ?
H02A C02 H02B 109.5 . . ?
C01 C02 H02C 109.5 . . ?
H02A C02 H02C 109.5 . . ?
H02B C02 H02C 109.5 . . ?
C2 C3 S2 116.7(15) . . ?
C2 C3 H3A 108.1 . . ?
S2 C3 H3A 108.1 . . ?
C2 C3 H3B 108.1 . . ?
S2 C3 H3B 108.1 . . ?
H3A C3 H3B 107.3 . . ?
O01 C03 C04 98(3) . . ?
O01 C03 H03A 112.2 . . ?
C04 C03 H03A 112.2 . . ?
O01 C03 H03B 112.2 . . ?
C04 C03 H03B 112.2 . . ?
H03A C03 H03B 109.8 . . ?
C03 C04 H04A 109.5 . . ?
C03 C04 H04B 109.5 . . ?
H04A C04 H04B 109.5 . . ?
C03 C04 H04C 109.5 . . ?
H04A C04 H04C 109.5 . . ?
H04B C04 H04C 109.5 . . ?
C16 C11 C12 119.9(16) . . ?
C16 C11 P1 120.5(12) . . ?
C12 C11 P1 119.5(13) . . ?
C11 C12 C13 119(2) . . ?
C11 C12 H12A 120.7 . . ?
C13 C12 H12A 120.7 . . ?
C14 C13 C12 122(2) . . ?
C14 C13 H13A 119.0 . . ?
C12 C13 H13A 119.0 . . ?
C13 C14 C15 118.8(18) . . ?
C13 C14 H14A 120.6 . . ?
C15 C14 H14A 120.6 . . ?
C14 C15 C16 121(2) . . ?
C14 C15 H15A 119.4 . . ?
C16 C15 H15A 119.4 . . ?
C11 C16 C15 119.3(18) . . ?
C11 C16 H16A 120.4 . . ?
C15 C16 H16A 120.4 . . ?
C22 C21 C26 118.7(15) . . ?
C22 C21 P1 117.0(13) . . ?
C26 C21 P1 124.1(12) . . ?
C21 C22 C23 119(2) . . ?
C21 C22 H22A 120.3 . . ?
C23 C22 H22A 120.3 . . ?
C24 C23 C22 120(2) . . ?
C24 C23 H23A 120.0 . . ?
C22 C23 H23A 120.0 . . ?
C25 C24 C23 118(2) . . ?
C25 C24 H24A 120.8 . . ?
C23 C24 H24A 120.8 . . ?
C26 C25 C24 122(2) . . ?
C26 C25 H25A 119.2 . . ?
C24 C25 H25A 119.2 . . ?
C25 C26 C21 122(2) . . ?
C25 C26 H26A 119.1 . . ?
C21 C26 H26A 119.1 . . ?
C36 C31 C32 121.9(17) . . ?
C36 C31 P2 117.5(14) . . ?
C32 C31 P2 120.6(15) . . ?
C31 C32 C33 118(2) . . ?
C31 C32 H32A 121.1 . . ?
C33 C32 H32A 121.1 . . ?
C34 C33 C32 123(2) . . ?
C34 C33 H33A 118.3 . . ?
C32 C33 H33A 118.3 . . ?
C33 C34 C35 118(2) . . ?
C33 C34 H34A 120.9 . . ?
C35 C34 H34A 120.9 . . ?
C34 C35 C36 122(2) . . ?
C34 C35 H35A 119.1 . . ?
C36 C35 H35A 119.1 . . ?
C31 C36 C35 117(2) . . ?
C31 C36 H36A 121.5 . . ?
C35 C36 H36A 121.5 . . ?
C42 C41 C46 119.1(17) . . ?
C42 C41 P2 122.4(14) . . ?
C46 C41 P2 118.2(14) . . ?
C41 C42 C43 119(2) . . ?
C41 C42 H42A 120.7 . . ?
C43 C42 H42A 120.7 . . ?
C44 C43 C42 122(2) . . ?
C44 C43 H43A 119.1 . . ?
C42 C43 H43A 119.1 . . ?
C43 C44 C45 121(2) . . ?
C43 C44 H44A 119.3 . . ?
C45 C44 H44A 119.3 . . ?
C44 C45 C46 118(2) . . ?
C44 C45 H45A 121.1 . . ?
C46 C45 H45A 121.1 . . ?
C41 C46 C45 121(2) . . ?
C41 C46 H46A 119.4 . . ?
C45 C46 H46A 119.4 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt P2 2.264(4) . ?
Pt P1 2.267(3) . ?
Pt S1 2.341(4) . ?
Pt S2 2.342(4) . ?
Pt Ag 3.0624(13) 3_656 ?
Pt Ag 3.1418(13) . ?
Ag S2 2.416(4) . ?
Ag S1 2.424(4) 3_656 ?
Ag Pt 3.0624(13) 3_656 ?
Ag Ag 3.271(2) 3_656 ?
Sb F5 1.70(2) . ?
Sb F6 1.73(2) . ?
Sb F2 1.76(2) . ?
Sb F3 1.78(2) . ?
Sb F1 1.797(16) . ?
Sb F4 1.820(18) . ?
S1 C2 1.82(2) . ?
S1 Ag 2.424(4) 3_656 ?
S2 C3 1.85(2) . ?
P1 C21 1.806(15) . ?
P1 C11 1.842(16) . ?
P1 C1 1.865(16) . ?
P2 C31 1.812(14) . ?
P2 C41 1.813(16) . ?
P2 C1 1.853(15) . ?
O01 C01 1.392(19) . ?
O01 C03 1.421(19) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C01 C02 1.526(5) . ?
C01 H01A 0.9700 . ?
C01 H01B 0.9700 . ?
C2 C3 1.41(3) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C02 H02A 0.9600 . ?
C02 H02B 0.9600 . ?
C02 H02C 0.9600 . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C03 C04 1.524(5) . ?
C03 H03A 0.9700 . ?
C03 H03B 0.9700 . ?
C04 H04A 0.9600 . ?
C04 H04B 0.9600 . ?
C04 H04C 0.9600 . ?
C11 C16 1.35(2) . ?
C11 C12 1.37(2) . ?
C12 C13 1.38(3) . ?
C12 H12A 0.9300 . ?
C13 C14 1.32(3) . ?
C13 H13A 0.9300 . ?
C14 C15 1.35(3) . ?
C14 H14A 0.9300 . ?
C15 C16 1.38(2) . ?
C15 H15A 0.9300 . ?
C16 H16A 0.9300 . ?
C21 C22 1.39(2) . ?
C21 C26 1.40(2) . ?
C22 C23 1.41(3) . ?
C22 H22A 0.9300 . ?
C23 C24 1.40(3) . ?
C23 H23A 0.9300 . ?
C24 C25 1.39(3) . ?
C24 H24A 0.9300 . ?
C25 C26 1.33(3) . ?
C25 H25A 0.9300 . ?
C26 H26A 0.9300 . ?
C31 C36 1.37(3) . ?
C31 C32 1.38(2) . ?
C32 C33 1.40(3) . ?
C32 H32A 0.9300 . ?
C33 C34 1.35(4) . ?
C33 H33A 0.9300 . ?
C34 C35 1.36(3) . ?
C34 H34A 0.9300 . ?
C35 C36 1.44(3) . ?
C35 H35A 0.9300 . ?
C36 H36A 0.9300 . ?
C41 C42 1.38(2) . ?
C41 C46 1.39(2) . ?
C42 C43 1.39(3) . ?
C42 H42A 0.9300 . ?
C43 C44 1.34(3) . ?
C43 H43A 0.9300 . ?
C44 C45 1.36(3) . ?
C44 H44A 0.9300 . ?
C45 C46 1.40(3) . ?
C45 H45A 0.9300 . ?
C46 H46A 0.9300 . ?
