#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:55:03 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179161 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/22/4312288.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4312288
loop_
_publ_author_name
'Cheuk-Fai Chow'
'Michael H. W. Lam'
'Wai-Yeung Wong'
_publ_section_title
;
 A Heterobimetallic Ruthenium(II)-Copper(II) Donor-Acceptor Complex as a
 Chemodosimetric Ensemble for Selective Cyanide Detection
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8387
_journal_page_last               8393
_journal_paper_doi               10.1021/ic0492587
_journal_volume                  43
_journal_year                    2004
_chemical_formula_sum            'C30 H56 Cl2 Cu2 N12 O11 Ru'
_chemical_formula_weight         1059.92
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.792(3)
_cell_angle_beta                 94.251(4)
_cell_angle_gamma                112.956(4)
_cell_formula_units_Z            2
_cell_length_a                   11.006(2)
_cell_length_b                   13.471(3)
_cell_length_c                   16.514(3)
_cell_measurement_temperature    273(2)
_cell_volume                     2236.2(8)
_computing_data_reduction        SAINT
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.953
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  'Smart CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0407
_diffrn_reflns_av_sigmaI/netI    0.0977
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            10303
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.96
_exptl_absorpt_coefficient_mu    1.460
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6849
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            dark-green
_exptl_crystal_density_diffrn    1.574
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1088
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.548
_refine_diff_density_min         -1.240
_refine_diff_density_rms         0.149
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.896
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     508
_refine_ls_number_reflns         7508
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.896
_refine_ls_R_factor_all          0.1060
_refine_ls_R_factor_gt           0.0723
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1041P)²+18.2214P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1750
_refine_ls_wR_factor_ref         0.1959
_reflns_number_gt                5218
_reflns_number_total             7508
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0492587si20040607_103822.cif
_cod_data_source_block           wy0937wm
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4312288
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.3163(8) 0.4775(6) 0.2019(5) 0.0299(18) Uani 1 1 d . . .
H1A H 0.3240 0.5066 0.1521 0.036 Uiso 1 1 calc R . .
C2 C 0.3288(10) 0.5436(7) 0.2705(6) 0.043(2) Uani 1 1 d . . .
H2A H 0.3454 0.6161 0.2664 0.051 Uiso 1 1 calc R . .
C3 C 0.3172(10) 0.5045(8) 0.3471(6) 0.042(2) Uani 1 1 d . . .
C4 C 0.2943(11) 0.3963(7) 0.3478(6) 0.045(2) Uani 1 1 d . . .
H4A H 0.2850 0.3660 0.3971 0.054 Uiso 1 1 calc R . .
C5 C 0.2847(9) 0.3318(6) 0.2771(5) 0.0306(19) Uani 1 1 d . . .
C6 C 0.2650(9) 0.2157(6) 0.2746(5) 0.0307(19) Uani 1 1 d . . .
C7 C 0.2498(10) 0.1603(7) 0.3435(5) 0.040(2) Uani 1 1 d . . .
H7A H 0.2509 0.1959 0.3939 0.048 Uiso 1 1 calc R . .
C8 C 0.2329(9) 0.0514(7) 0.3384(5) 0.037(2) Uani 1 1 d . . .
C9 C 0.2266(9) 0.0032(7) 0.2604(5) 0.037(2) Uani 1 1 d . . .
H9A H 0.2124 -0.0697 0.2529 0.045 Uiso 1 1 calc R . .
C10 C 0.2411(8) 0.0619(6) 0.1939(5) 0.0308(19) Uani 1 1 d . . .
H10A H 0.2361 0.0269 0.1426 0.037 Uiso 1 1 calc R . .
C11 C 0.3197(12) 0.5768(8) 0.4240(6) 0.054(3) Uani 1 1 d . . .
C12 C 0.2133(14) 0.6212(10) 0.4119(7) 0.074(4) Uani 1 1 d . . .
H12A H 0.2236 0.6573 0.3631 0.112 Uiso 1 1 calc R . .
H12B H 0.2215 0.6716 0.4580 0.112 Uiso 1 1 calc R . .
H12C H 0.1273 0.5626 0.4070 0.112 Uiso 1 1 calc R . .
C13 C 0.4560(15) 0.6733(11) 0.4339(9) 0.090(5) Uani 1 1 d . . .
H13A H 0.4670 0.7101 0.3855 0.135 Uiso 1 1 calc R . .
H13B H 0.5251 0.6471 0.4425 0.135 Uiso 1 1 calc R . .
H13C H 0.4609 0.7226 0.4800 0.135 Uiso 1 1 calc R . .
C14 C 0.3010(18) 0.5201(10) 0.5008(7) 0.095(5) Uani 1 1 d . . .
H14A H 0.3028 0.5695 0.5460 0.142 Uiso 1 1 calc R . .
H14B H 0.3713 0.4957 0.5113 0.142 Uiso 1 1 calc R . .
H14C H 0.2172 0.4589 0.4940 0.142 Uiso 1 1 calc R . .
C15 C 0.2215(12) -0.0126(8) 0.4114(6) 0.052(3) Uani 1 1 d . . .
C16 C 0.211(2) 0.0486(11) 0.4889(7) 0.118(7) Uani 1 1 d . . .
H16A H 0.2865 0.1162 0.4995 0.176 Uiso 1 1 calc R . .
H16B H 0.2073 0.0061 0.5338 0.176 Uiso 1 1 calc R . .
H16C H 0.1313 0.0622 0.4827 0.176 Uiso 1 1 calc R . .
C17 C 0.3419(15) -0.0407(14) 0.4209(10) 0.105(6) Uani 1 1 d . . .
H17A H 0.4208 0.0247 0.4309 0.158 Uiso 1 1 calc R . .
H17B H 0.3453 -0.0815 0.3718 0.158 Uiso 1 1 calc R . .
H17C H 0.3359 -0.0833 0.4660 0.158 Uiso 1 1 calc R . .
C18 C 0.0985(13) -0.1227(10) 0.3958(8) 0.081(4) Uani 1 1 d . . .
H18A H 0.0189 -0.1094 0.3902 0.121 Uiso 1 1 calc R . .
H18B H 0.0967 -0.1645 0.4409 0.121 Uiso 1 1 calc R . .
H18C H 0.1042 -0.1621 0.3466 0.121 Uiso 1 1 calc R . .
C19 C 0.2692(8) 0.3587(6) 0.0171(5) 0.0291(18) Uani 1 1 d . . .
C20 C 0.0392(11) 0.5767(9) -0.1354(7) 0.056(3) Uani 1 1 d . . .
H20A H 0.0935 0.6530 -0.1369 0.067 Uiso 1 1 calc R . .
H20B H -0.0466 0.5700 -0.1197 0.067 Uiso 1 1 calc R . .
C21 C 0.0221(10) 0.5171(9) -0.2176(6) 0.050(3) Uani 1 1 d . . .
H21A H -0.0447 0.4439 -0.2194 0.060 Uiso 1 1 calc R . .
H21B H -0.0058 0.5537 -0.2592 0.060 Uiso 1 1 calc R . .
C22 C 0.1466(13) 0.4306(11) -0.2970(7) 0.068(3) Uani 1 1 d . . .
H22A H 0.1365 0.4545 -0.3503 0.081 Uiso 1 1 calc R . .
H22B H 0.0710 0.3636 -0.2932 0.081 Uiso 1 1 calc R . .
C23 C 0.2719(16) 0.4121(13) -0.2868(7) 0.087(4) Uani 1 1 d . . .
H23A H 0.2642 0.3498 -0.3231 0.104 Uiso 1 1 calc R . .
H23B H 0.3458 0.4749 -0.3002 0.104 Uiso 1 1 calc R . .
C24 C 0.5283(8) 0.6797(6) -0.1079(5) 0.0261(18) Uani 1 1 d . . .
C25 C 0.0678(9) 0.1972(6) 0.0976(5) 0.0303(19) Uani 1 1 d . . .
C26 C -0.4604(10) 0.0684(10) 0.1110(9) 0.070(4) Uani 1 1 d . . .
H26A H -0.5112 0.1133 0.1107 0.084 Uiso 1 1 calc R . .
H26B H -0.5017 0.0089 0.0682 0.084 Uiso 1 1 calc R . .
C27 C -0.4590(11) 0.0264(9) 0.1899(8) 0.061(3) Uani 1 1 d . . .
H27A H -0.5482 -0.0210 0.1992 0.073 Uiso 1 1 calc R . .
H27B H -0.4249 0.0855 0.2333 0.073 Uiso 1 1 calc R . .
C28 C -0.3327(15) -0.0565(14) 0.2710(9) 0.091(5) Uani 1 1 d . . .
H28A H -0.3199 0.0042 0.3105 0.109 Uiso 1 1 calc R . .
H28B H -0.4027 -0.1203 0.2866 0.109 Uiso 1 1 calc R . .
C29 C -0.2173(14) -0.0732(12) 0.2715(9) 0.084(4) Uani 1 1 d . . .
H29A H -0.2373 -0.1455 0.2457 0.100 Uiso 1 1 calc R . .
H29B H -0.1816 -0.0696 0.3276 0.100 Uiso 1 1 calc R . .
C30 C -0.2573(9) -0.1471(6) -0.0135(5) 0.0307(19) Uani 1 1 d . . .
Cl1 Cl 0.8634(5) 0.2497(3) 0.3613(2) 0.0964(13) Uani 1 1 d . . .
Cl2 Cl 0.7762(3) 0.25698(19) 0.87678(18) 0.0534(7) Uani 1 1 d . . .
Cu1 Cu 0.23780(10) 0.48809(8) -0.12626(6) 0.0306(3) Uani 1 1 d . . .
Cu2 Cu -0.21022(10) 0.05082(9) 0.13411(7) 0.0347(3) Uani 1 1 d . . .
N1 N 0.2929(6) 0.3703(5) 0.2027(4) 0.0259(15) Uani 1 1 d . . .
N2 N 0.2620(6) 0.1677(5) 0.1998(4) 0.0218(14) Uani 1 1 d . . .
N3 N 0.2672(8) 0.4198(6) -0.0303(5) 0.0396(18) Uani 1 1 d . . .
N4 N 0.1036(8) 0.5309(7) -0.0753(5) 0.046(2) Uani 1 1 d . . .
H4B H 0.0418 0.4725 -0.0575 0.055 Uiso 1 1 calc R . .
H4C H 0.1437 0.5804 -0.0321 0.055 Uiso 1 1 calc R . .
N5 N 0.1520(8) 0.5148(6) -0.2318(5) 0.0422(19) Uani 1 1 d . . .
H5A H 0.2052 0.5809 -0.2457 0.051 Uiso 1 1 calc R . .
N6 N 0.2948(11) 0.3932(9) -0.2020(6) 0.066(3) Uani 1 1 d . . .
H6A H 0.3815 0.4083 -0.1892 0.079 Uiso 1 1 calc R . .
H6B H 0.2484 0.3230 -0.1957 0.079 Uiso 1 1 calc R . .
N7 N 0.4112(7) 0.6393(6) -0.1145(5) 0.0436(19) Uani 1 1 d . . .
N8 N -0.0427(7) 0.1535(6) 0.1033(5) 0.0353(17) Uani 1 1 d . . .
N9 N -0.3224(8) 0.1332(6) 0.0961(6) 0.053(2) Uani 1 1 d . . .
H9B H -0.2927 0.1992 0.1243 0.063 Uiso 1 1 calc R . .
H9C H -0.3178 0.1416 0.0427 0.063 Uiso 1 1 calc R . .
N10 N -0.3731(8) -0.0339(7) 0.1885(5) 0.047(2) Uani 1 1 d . . .
H10B H -0.4183 -0.0984 0.1576 0.056 Uiso 1 1 calc R . .
N11 N -0.1143(9) 0.0074(7) 0.2284(5) 0.051(2) Uani 1 1 d . . .
H11A H -0.0603 -0.0220 0.2087 0.062 Uiso 1 1 calc R . .
H11B H -0.0649 0.0661 0.2632 0.062 Uiso 1 1 calc R . .
N12 N -0.2496(7) -0.0784(6) 0.0368(5) 0.0381(18) Uani 1 1 d . . .
O1 O 0.9354(16) 0.3576(9) 0.3983(7) 0.148(6) Uani 1 1 d . . .
O2 O 0.8305(18) 0.2406(10) 0.2772(7) 0.167(7) Uani 1 1 d . . .
O3 O 0.7630(16) 0.1934(10) 0.4017(7) 0.143(6) Uani 1 1 d . . .
O4 O 0.9521(19) 0.2050(19) 0.3795(12) 0.211(9) Uani 1 1 d . . .
O5 O 0.7329(15) 0.2352(8) 0.7940(6) 0.129(5) Uani 1 1 d . . .
O6 O 0.7567(10) 0.3482(8) 0.9083(6) 0.090(3) Uani 1 1 d . . .
O7 O 0.9129(11) 0.2876(10) 0.8891(13) 0.189(9) Uani 1 1 d . . .
O8 O 0.7158(13) 0.1632(9) 0.9116(6) 0.126(5) Uani 1 1 d . . .
O9 O 0.617(5) 0.301(4) 0.313(3) 0.54(3) Uiso 1 1 d . . .
O10 O 0.0724(9) 0.1755(8) 0.8569(6) 0.083(3) Uiso 1 1 d . . .
O11 O 0.4658(11) 0.2881(9) 0.8865(6) 0.099(3) Uiso 1 1 d . . .
Ru1 Ru 0.27127(6) 0.26097(5) 0.10054(4) 0.02059(19) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 N1 123.1(8) . . ?
C1 C2 C3 121.2(8) . . ?
C4 C3 C2 115.6(8) . . ?
C4 C3 C11 123.0(9) . . ?
C2 C3 C11 121.3(8) . . ?
C5 C4 C3 121.7(9) . . ?
N1 C5 C4 122.0(7) . . ?
N1 C5 C6 114.1(7) . . ?
C4 C5 C6 124.0(7) . . ?
N2 C6 C7 122.1(7) . . ?
N2 C6 C5 114.9(7) . . ?
C7 C6 C5 123.1(7) . . ?
C6 C7 C8 121.1(8) . . ?
C9 C8 C7 115.6(8) . . ?
C9 C8 C15 120.5(8) . . ?
C7 C8 C15 123.8(8) . . ?
C10 C9 C8 120.9(8) . . ?
N2 C10 C9 123.1(8) . . ?
C14 C11 C12 108.5(11) . . ?
C14 C11 C3 114.0(8) . . ?
C12 C11 C3 110.3(9) . . ?
C14 C11 C13 109.6(11) . . ?
C12 C11 C13 108.0(10) . . ?
C3 C11 C13 106.4(10) . . ?
C8 C15 C17 107.8(10) . . ?
C8 C15 C16 112.5(8) . . ?
C17 C15 C16 110.8(12) . . ?
C8 C15 C18 110.6(9) . . ?
C17 C15 C18 106.1(11) . . ?
C16 C15 C18 108.8(11) . . ?
N3 C19 Ru1 177.3(7) . . ?
N4 C20 C21 109.3(8) . . ?
N5 C21 C20 107.0(8) . . ?
N5 C22 C23 109.1(10) . . ?
N6 C23 C22 108.4(10) . . ?
N7 C24 Ru1 176.0(7) . 2_665 ?
N8 C25 Ru1 171.2(7) . . ?
C27 C26 N9 108.8(10) . . ?
C26 C27 N10 107.3(8) . . ?
C29 C28 N10 110.8(11) . . ?
C28 C29 N11 113.1(11) . . ?
N12 C30 Ru1 178.6(7) . 2 ?
O3 Cl1 O4 102.0(12) . . ?
O3 Cl1 O2 114.0(10) . . ?
O4 Cl1 O2 111.1(12) . . ?
O3 Cl1 O1 112.8(8) . . ?
O4 Cl1 O1 100.5(12) . . ?
O2 Cl1 O1 114.8(8) . . ?
O8 Cl2 O5 107.2(7) . . ?
O8 Cl2 O7 108.7(9) . . ?
O5 Cl2 O7 110.2(11) . . ?
O8 Cl2 O6 116.9(8) . . ?
O5 Cl2 O6 109.5(6) . . ?
O7 Cl2 O6 104.3(8) . . ?
N3 Cu1 N4 92.0(3) . . ?
N3 Cu1 N6 92.9(3) . . ?
N4 Cu1 N6 153.9(4) . . ?
N3 Cu1 N5 161.4(3) . . ?
N4 Cu1 N5 83.4(3) . . ?
N6 Cu1 N5 83.8(3) . . ?
N3 Cu1 N7 103.0(3) . . ?
N4 Cu1 N7 102.7(3) . . ?
N6 Cu1 N7 101.0(4) . . ?
N5 Cu1 N7 95.6(3) . . ?
N8 Cu2 N10 167.7(3) . . ?
N8 Cu2 N9 96.0(3) . . ?
N10 Cu2 N9 83.1(3) . . ?
N8 Cu2 N11 92.0(3) . . ?
N10 Cu2 N11 82.8(3) . . ?
N9 Cu2 N11 149.0(4) . . ?
N8 Cu2 N12 98.3(3) . . ?
N10 Cu2 N12 93.8(3) . . ?
N9 Cu2 N12 105.1(3) . . ?
N11 Cu2 N12 103.3(3) . . ?
C5 N1 C1 116.4(7) . . ?
C5 N1 Ru1 117.4(5) . . ?
C1 N1 Ru1 126.2(5) . . ?
C10 N2 C6 117.2(7) . . ?
C10 N2 Ru1 125.6(5) . . ?
C6 N2 Ru1 116.9(5) . . ?
C19 N3 Cu1 165.8(7) . . ?
C20 N4 Cu1 110.2(6) . . ?
C21 N5 C22 114.8(8) . . ?
C21 N5 Cu1 109.3(6) . . ?
C22 N5 Cu1 107.7(6) . . ?
C23 N6 Cu1 110.2(7) . . ?
C24 N7 Cu1 145.4(7) . . ?
C25 N8 Cu2 161.5(7) . . ?
C26 N9 Cu2 107.1(6) . . ?
C27 N10 C28 113.4(10) . . ?
C27 N10 Cu2 108.8(6) . . ?
C28 N10 Cu2 110.0(7) . . ?
C29 N11 Cu2 108.0(7) . . ?
C30 N12 Cu2 172.9(7) . . ?
C19 Ru1 C30 90.0(3) . 2 ?
C19 Ru1 C24 90.0(3) . 2_665 ?
C30 Ru1 C24 90.7(3) 2 2_665 ?
C19 Ru1 C25 92.5(3) . . ?
C30 Ru1 C25 89.8(3) 2 . ?
C24 Ru1 C25 177.4(3) 2_665 . ?
C19 Ru1 N1 96.8(3) . . ?
C30 Ru1 N1 173.0(3) 2 . ?
C24 Ru1 N1 87.5(3) 2_665 . ?
C25 Ru1 N1 91.7(3) . . ?
C19 Ru1 N2 172.3(3) . . ?
C30 Ru1 N2 96.8(3) 2 . ?
C24 Ru1 N2 93.5(3) 2_665 . ?
C25 Ru1 N2 83.9(3) . . ?
N1 Ru1 N2 76.6(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.357(12) . ?
C1 N1 1.366(10) . ?
C2 C3 1.398(13) . ?
C3 C4 1.380(13) . ?
C3 C11 1.540(13) . ?
C4 C5 1.380(12) . ?
C5 N1 1.360(10) . ?
C5 C6 1.490(10) . ?
C6 N2 1.348(10) . ?
C6 C7 1.386(12) . ?
C7 C8 1.400(12) . ?
C8 C9 1.388(12) . ?
C8 C15 1.513(12) . ?
C9 C10 1.377(12) . ?
C10 N2 1.348(10) . ?
C11 C14 1.510(16) . ?
C11 C12 1.515(16) . ?
C11 C13 1.544(17) . ?
C15 C17 1.514(18) . ?
C15 C16 1.514(16) . ?
C15 C18 1.559(15) . ?
C19 N3 1.179(11) . ?
C19 Ru1 1.973(9) . ?
C20 N4 1.479(13) . ?
C20 C21 1.491(15) . ?
C21 N5 1.478(12) . ?
C22 N5 1.492(13) . ?
C22 C23 1.494(18) . ?
C23 N6 1.460(15) . ?
C24 N7 1.180(10) . ?
C24 Ru1 2.023(8) 2_665 ?
C25 N8 1.140(11) . ?
C25 Ru1 2.058(9) . ?
C26 C27 1.456(17) . ?
C26 N9 1.476(13) . ?
C27 N10 1.468(13) . ?
C28 C29 1.374(18) . ?
C28 N10 1.489(15) . ?
C29 N11 1.494(15) . ?
C30 N12 1.175(11) . ?
C30 Ru1 1.983(9) 2 ?
Cl1 O3 1.328(12) . ?
Cl1 O4 1.358(15) . ?
Cl1 O2 1.394(12) . ?
Cl1 O1 1.424(11) . ?
Cl2 O8 1.367(10) . ?
Cl2 O5 1.387(10) . ?
Cl2 O7 1.390(11) . ?
Cl2 O6 1.401(8) . ?
Cu1 N3 1.951(7) . ?
Cu1 N4 2.002(8) . ?
Cu1 N6 2.030(9) . ?
Cu1 N5 2.040(7) . ?
Cu1 N7 2.166(7) . ?
Cu2 N8 1.953(7) . ?
Cu2 N10 2.025(8) . ?
Cu2 N9 2.048(8) . ?
Cu2 N11 2.059(8) . ?
Cu2 N12 2.177(7) . ?
N1 Ru1 2.100(6) . ?
N2 Ru1 2.115(6) . ?
Ru1 C30 1.983(9) 2 ?
Ru1 C24 2.023(8) 2_665 ?
