#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:56:35 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179162 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/23/4312396.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4312396
loop_
_publ_author_name
'Andrew D. Burrows'
'Mary F. Mahon'
'Steven P. Nolan'
'Maurizio Varrone'
_publ_section_title
;
 Diphosphines Possessing Electronically Different Donor Groups: Synthesis
 and Coordination Chemistry of the Unsymmetrical
 Di(N-pyrrolyl)phosphino-Functionalized dppm Analogue Ph2PCH2P(NC4H4)2
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7227
_journal_page_last               7238
_journal_paper_doi               10.1021/ic034487z
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C42 H36 Cl2 N4 P4 Pd'
_chemical_formula_weight         897.93
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.1460(10)
_cell_angle_beta                 99.3950(10)
_cell_angle_gamma                109.7990(10)
_cell_formula_units_Z            2
_cell_length_a                   9.3820(2)
_cell_length_b                   10.5300(2)
_cell_length_c                   22.6890(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      18
_cell_measurement_theta_min      12
_cell_volume                     2073.85(7)
_computing_data_reduction
'Denzo and Scalepack (otwinowski & Minor, 1997'
_computing_molecular_graphics    'ORTEX (P.McArdle, 1995)'
_computing_publication_material  'SHELXL-97/2 (Sheldrick,1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       KappaCCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0608
_diffrn_reflns_av_sigmaI/netI    0.0615
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            25293
_diffrn_reflns_theta_full        24.71
_diffrn_reflns_theta_max         24.71
_diffrn_reflns_theta_min         3.59
_exptl_absorpt_coefficient_mu    0.766
_exptl_absorpt_correction_T_max  1.03
_exptl_absorpt_correction_T_min  0.97
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
multi-scan from symmetry-related measurements (Blessing 1995)
;
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.438
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             912
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.855
_refine_diff_density_min         -0.586
_refine_diff_density_rms         0.087
_refine_ls_extinction_coef       0.0029(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     482
_refine_ls_number_reflns         7043
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0649
_refine_ls_R_factor_gt           0.0432
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
; calc
 [1.00000+0.00000exp(0.00(sinθ/λ)²)]/
   [σ²(Fo²)+0.0000+2.8130*P+(0.0452P)²+0.0000sinθ/λ]
 where P = 0.00000Fo² + 1.00000Fc²
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1004
_refine_ls_wR_factor_ref         0.1114
_reflns_number_gt                5413
_reflns_number_total             7043
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034487zsi20030806_093646_3.cif
_cod_data_source_block           compound_4_(k01adb9)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'multiscan'
changed to 'multi-scan' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4312396
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 1.0000 1.0000 0.0000 0.02535(14) Uani 1 2 d S . .
Cl1 Cl 1.21963(12) 1.15426(11) 0.05676(5) 0.0375(3) Uani 1 1 d . . .
P1 P 0.91025(12) 0.93867(11) 0.08915(5) 0.0267(2) Uani 1 1 d . . .
P2 P 1.07099(14) 0.78840(12) 0.17935(5) 0.0366(3) Uani 1 1 d . . .
N1 N 1.2435(5) 0.8511(4) 0.22954(18) 0.0498(11) Uani 1 1 d . . .
N2 N 1.1230(4) 0.7297(4) 0.11828(16) 0.0372(9) Uani 1 1 d . . .
C1 C 1.3834(6) 0.9473(6) 0.2245(3) 0.0699(18) Uani 1 1 d . . .
H1 H 1.4057 0.9976 0.1908 0.084 Uiso 1 1 calc R . .
C2 C 1.4834(8) 0.9567(7) 0.2765(4) 0.091(2) Uani 1 1 d . . .
H2 H 1.5880 1.0149 0.2852 0.109 Uiso 1 1 calc R . .
C3 C 1.4072(9) 0.8670(8) 0.3148(3) 0.099(3) Uani 1 1 d . . .
H3 H 1.4507 0.8535 0.3539 0.119 Uiso 1 1 calc R . .
C4 C 1.2594(8) 0.8019(6) 0.2863(2) 0.076(2) Uani 1 1 d . . .
H4 H 1.1814 0.7354 0.3021 0.092 Uiso 1 1 calc R . .
C5 C 1.2074(6) 0.7969(6) 0.0761(2) 0.0499(13) Uani 1 1 d . . .
H5 H 1.2464 0.8921 0.0737 0.060 Uiso 1 1 calc R . .
C6 C 1.2238(8) 0.7033(7) 0.0395(3) 0.0714(19) Uani 1 1 d . . .
H6 H 1.2774 0.7210 0.0068 0.086 Uiso 1 1 calc R . .
C7 C 1.1480(7) 0.5742(7) 0.0577(3) 0.0674(17) Uani 1 1 d . . .
H7 H 1.1412 0.4898 0.0394 0.081 Uiso 1 1 calc R . .
C8 C 1.0871(6) 0.5921(5) 0.1056(2) 0.0461(12) Uani 1 1 d . . .
H8 H 1.0293 0.5222 0.1270 0.055 Uiso 1 1 calc R . .
C9 C 1.0578(5) 0.9517(4) 0.15564(18) 0.0337(10) Uani 1 1 d . . .
C10 C 0.7623(5) 0.7755(4) 0.09210(17) 0.0300(9) Uani 1 1 d . . .
C11 C 0.7579(5) 0.6625(4) 0.05824(19) 0.0352(10) Uani 1 1 d . . .
H11 H 0.8317 0.6708 0.0331 0.042 Uiso 1 1 calc R . .
C12 C 0.6464(6) 0.5379(5) 0.0610(2) 0.0432(11) Uani 1 1 d . . .
H12 H 0.6441 0.4608 0.0378 0.052 Uiso 1 1 calc R . .
C13 C 0.5383(6) 0.5254(5) 0.0974(2) 0.0483(13) Uani 1 1 d . . .
H13 H 0.4604 0.4401 0.0984 0.058 Uiso 1 1 calc R . .
C14 C 0.5430(6) 0.6361(5) 0.1322(2) 0.0471(12) Uani 1 1 d . . .
H14 H 0.4691 0.6269 0.1574 0.057 Uiso 1 1 calc R . .
C15 C 0.6560(5) 0.7612(5) 0.1304(2) 0.0382(10) Uani 1 1 d . . .
H15 H 0.6610 0.8370 0.1551 0.046 Uiso 1 1 calc R . .
C16 C 0.8230(5) 1.0612(4) 0.10736(19) 0.0320(10) Uani 1 1 d . . .
C17 C 0.9007(6) 1.1724(5) 0.1473(2) 0.0487(12) Uani 1 1 d . . .
H17 H 1.0037 1.1866 0.1661 0.058 Uiso 1 1 calc R . .
C18 C 0.8325(7) 1.2632(6) 0.1608(3) 0.0605(15) Uani 1 1 d . . .
H18 H 0.8890 1.3405 0.1878 0.073 Uiso 1 1 calc R . .
C19 C 0.6811(7) 1.2420(6) 0.1348(3) 0.0626(16) Uani 1 1 d . . .
H19 H 0.6302 1.2999 0.1465 0.075 Uiso 1 1 calc R . .
C20 C 0.6056(6) 1.1358(6) 0.0919(3) 0.0560(14) Uani 1 1 d . . .
H20 H 0.5044 1.1240 0.0717 0.067 Uiso 1 1 calc R . .
C21 C 0.6767(5) 1.0462(5) 0.0782(2) 0.0433(11) Uani 1 1 d . . .
H21 H 0.6240 0.9735 0.0483 0.052 Uiso 1 1 calc R . .
Pd2 Pd 0.5000 0.5000 0.5000 0.03029(14) Uani 1 2 d S . .
Cl2 Cl 0.34608(19) 0.30550(12) 0.53382(6) 0.0663(5) Uani 1 1 d . . .
P3 P 0.55952(13) 0.35706(11) 0.43676(4) 0.0278(2) Uani 1 1 d . . .
P4 P 0.22544(14) 0.27687(13) 0.37697(6) 0.0419(3) Uani 1 1 d . . .
N3 N 0.2596(5) 0.3305(5) 0.3087(2) 0.0565(12) Uani 1 1 d . . .
N4 N 0.0799(4) 0.1216(5) 0.35806(18) 0.0484(11) Uani 1 1 d . . .
C22 C 0.3049(7) 0.2758(7) 0.2636(2) 0.079(2) Uani 1 1 d . . .
H22 H 0.3334 0.1974 0.2645 0.095 Uiso 1 1 calc R . .
C23 C 0.3015(10) 0.3582(11) 0.2148(3) 0.116(4) Uani 1 1 d . . .
H23 H 0.3224 0.3445 0.1760 0.140 Uiso 1 1 calc R . .
C24 C 0.2604(10) 0.4641(14) 0.2366(5) 0.148(6) Uani 1 1 d . . .
H24 H 0.2546 0.5387 0.2147 0.178 Uiso 1 1 calc R . .
C25 C 0.2313(7) 0.4474(8) 0.2905(5) 0.110(3) Uani 1 1 d . . .
H25 H 0.1971 0.5041 0.3134 0.132 Uiso 1 1 calc R . .
C26 C 0.0729(8) 0.0132(7) 0.3227(2) 0.079(2) Uani 1 1 d . . .
H26 H 0.1521 0.0066 0.3029 0.094 Uiso 1 1 calc R . .
C27 C -0.0684(10) -0.0849(8) 0.3206(3) 0.102(3) Uani 1 1 d . . .
H27 H -0.1061 -0.1704 0.2981 0.122 Uiso 1 1 calc R . .
C28 C -0.1445(7) -0.0375(9) 0.3565(5) 0.107(4) Uani 1 1 d . . .
H28 H -0.2441 -0.0857 0.3646 0.129 Uiso 1 1 calc R . .
C29 C -0.0560(7) 0.0888(7) 0.3788(4) 0.083(2) Uani 1 1 d . . .
H29 H -0.0831 0.1457 0.4045 0.100 Uiso 1 1 calc R . .
C30 C 0.3874(5) 0.2172(4) 0.40056(17) 0.0298(9) Uani 1 1 d . . .
C31 C 0.6822(5) 0.2758(5) 0.47847(18) 0.0359(10) Uani 1 1 d . . .
C32 C 0.8109(6) 0.3590(6) 0.5188(2) 0.0584(15) Uani 1 1 d . . .
H32 H 0.8294 0.4531 0.5250 0.070 Uiso 1 1 calc R . .
C33 C 0.9122(7) 0.3012(9) 0.5497(3) 0.079(2) Uani 1 1 d . . .
H33 H 0.9999 0.3564 0.5775 0.095 Uiso 1 1 calc R . .
C34 C 0.8857(7) 0.1647(8) 0.5404(3) 0.079(2) Uani 1 1 d . . .
H34 H 0.9559 0.1270 0.5614 0.095 Uiso 1 1 calc R . .
C35 C 0.7602(7) 0.0836(6) 0.5013(3) 0.0616(16) Uani 1 1 d . . .
H35 H 0.7434 -0.0102 0.4948 0.074 Uiso 1 1 calc R . .
C36 C 0.6556(6) 0.1388(5) 0.4704(2) 0.0438(12) Uani 1 1 d . . .
H36 H 0.5664 0.0819 0.4439 0.053 Uiso 1 1 calc R . .
C37 C 0.6558(5) 0.4235(4) 0.37470(18) 0.0336(10) Uani 1 1 d . . .
C38 C 0.6137(5) 0.5188(4) 0.34120(19) 0.0390(11) Uani 1 1 d . . .
H38 H 0.5411 0.5545 0.3528 0.047 Uiso 1 1 calc R . .
C39 C 0.6777(6) 0.5614(5) 0.2910(2) 0.0536(15) Uani 1 1 d . . .
H39 H 0.6488 0.6262 0.2681 0.064 Uiso 1 1 calc R . .
C40 C 0.7828(8) 0.5101(6) 0.2744(2) 0.0669(18) Uani 1 1 d . . .
H40 H 0.8268 0.5399 0.2401 0.080 Uiso 1 1 calc R . .
C41 C 0.8248(7) 0.4169(8) 0.3066(3) 0.0732(19) Uani 1 1 d . . .
H41 H 0.8978 0.3822 0.2947 0.088 Uiso 1 1 calc R . .
C42 C 0.7609(7) 0.3722(6) 0.3569(2) 0.0563(14) Uani 1 1 d . . .
H42 H 0.7896 0.3063 0.3790 0.068 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Pd1 Cl1 180.0 . 2_775 ?
Cl1 Pd1 P1 91.94(4) . 2_775 ?
Cl1 Pd1 P1 88.06(4) 2_775 2_775 ?
Cl1 Pd1 P1 88.06(4) . . ?
Cl1 Pd1 P1 91.94(4) 2_775 . ?
P1 Pd1 P1 180.0 2_775 . ?
C16 P1 C10 104.13(19) . . ?
C16 P1 C9 104.4(2) . . ?
C10 P1 C9 103.97(19) . . ?
C16 P1 Pd1 105.86(14) . . ?
C10 P1 Pd1 120.56(13) . . ?
C9 P1 Pd1 116.25(15) . . ?
N2 P2 N1 102.8(2) . . ?
N2 P2 C9 101.51(19) . . ?
N1 P2 C9 98.2(2) . . ?
C1 N1 C4 107.9(5) . . ?
C1 N1 P2 131.2(4) . . ?
C4 N1 P2 120.8(4) . . ?
C8 N2 C5 107.7(4) . . ?
C8 N2 P2 120.5(3) . . ?
C5 N2 P2 131.8(3) . . ?
C2 C1 N1 107.7(6) . . ?
C1 C2 C3 108.8(6) . . ?
C4 C3 C2 108.1(6) . . ?
C3 C4 N1 107.5(6) . . ?
C6 C5 N2 107.9(5) . . ?
C5 C6 C7 108.5(5) . . ?
C8 C7 C6 107.6(5) . . ?
C7 C8 N2 108.4(5) . . ?
P1 C9 P2 115.1(2) . . ?
C11 C10 C15 119.3(4) . . ?
C11 C10 P1 120.2(3) . . ?
C15 C10 P1 120.4(3) . . ?
C10 C11 C12 120.3(4) . . ?
C11 C12 C13 120.1(5) . . ?
C14 C13 C12 120.4(5) . . ?
C13 C14 C15 119.9(5) . . ?
C14 C15 C10 120.0(4) . . ?
C17 C16 C21 118.4(4) . . ?
C17 C16 P1 122.2(3) . . ?
C21 C16 P1 119.3(3) . . ?
C18 C17 C16 121.3(5) . . ?
C17 C18 C19 120.0(5) . . ?
C20 C19 C18 119.1(5) . . ?
C19 C20 C21 120.1(5) . . ?
C16 C21 C20 120.8(5) . . ?
Cl2 Pd2 Cl2 180.0 2_666 . ?
Cl2 Pd2 P3 85.89(4) 2_666 2_666 ?
Cl2 Pd2 P3 94.11(4) . 2_666 ?
Cl2 Pd2 P3 94.11(4) 2_666 . ?
Cl2 Pd2 P3 85.89(4) . . ?
P3 Pd2 P3 180.00(4) 2_666 . ?
C31 P3 C37 104.3(2) . . ?
C31 P3 C30 104.8(2) . . ?
C37 P3 C30 103.51(19) . . ?
C31 P3 Pd2 110.99(14) . . ?
C37 P3 Pd2 120.08(14) . . ?
C30 P3 Pd2 111.79(13) . . ?
N3 P4 N4 102.3(2) . . ?
N3 P4 C30 100.9(2) . . ?
N4 P4 C30 98.8(2) . . ?
C22 N3 C25 109.2(6) . . ?
C22 N3 P4 131.5(4) . . ?
C25 N3 P4 119.3(6) . . ?
C26 N4 C29 107.4(5) . . ?
C26 N4 P4 130.2(4) . . ?
C29 N4 P4 122.4(5) . . ?
N3 C22 C23 107.0(8) . . ?
C24 C23 C22 104.6(8) . . ?
C25 C24 C23 111.5(9) . . ?
C24 C25 N3 107.6(10) . . ?
N4 C26 C27 108.1(7) . . ?
C28 C27 C26 107.3(7) . . ?
C29 C28 C27 108.8(6) . . ?
C28 C29 N4 108.3(7) . . ?
P3 C30 P4 110.9(2) . . ?
C36 C31 C32 120.0(4) . . ?
C36 C31 P3 122.9(3) . . ?
C32 C31 P3 117.1(4) . . ?
C31 C32 C33 118.8(6) . . ?
C34 C33 C32 120.5(6) . . ?
C35 C34 C33 120.7(6) . . ?
C34 C35 C36 119.8(6) . . ?
C31 C36 C35 120.1(5) . . ?
C42 C37 C38 119.1(4) . . ?
C42 C37 P3 120.8(4) . . ?
C38 C37 P3 119.9(3) . . ?
C39 C38 C37 120.0(5) . . ?
C40 C39 C38 119.9(5) . . ?
C41 C40 C39 120.7(5) . . ?
C40 C41 C42 120.1(5) . . ?
C37 C42 C41 120.1(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 Cl1 2.3077(10) . ?
Pd1 Cl1 2.3077(10) 2_775 ?
Pd1 P1 2.3361(10) 2_775 ?
Pd1 P1 2.3361(10) . ?
P1 C16 1.819(4) . ?
P1 C10 1.817(4) . ?
P1 C9 1.842(4) . ?
P2 N2 1.712(4) . ?
P2 N1 1.731(4) . ?
P2 C9 1.850(4) . ?
N1 C1 1.384(7) . ?
N1 C4 1.402(7) . ?
N2 C8 1.385(6) . ?
N2 C5 1.392(6) . ?
C1 C2 1.361(8) . ?
C2 C3 1.391(11) . ?
C3 C4 1.362(9) . ?
C5 C6 1.340(8) . ?
C6 C7 1.410(9) . ?
C7 C8 1.346(7) . ?
C10 C11 1.388(6) . ?
C10 C15 1.400(6) . ?
C11 C12 1.383(6) . ?
C12 C13 1.385(7) . ?
C13 C14 1.380(7) . ?
C14 C15 1.389(7) . ?
C16 C17 1.374(6) . ?
C16 C21 1.378(6) . ?
C17 C18 1.373(7) . ?
C18 C19 1.385(8) . ?
C19 C20 1.376(8) . ?
C20 C21 1.384(7) . ?
Pd2 Cl2 2.3000(12) 2_666 ?
Pd2 Cl2 2.3000(12) . ?
Pd2 P3 2.3196(10) 2_666 ?
Pd2 P3 2.3196(10) . ?
P3 C31 1.815(4) . ?
P3 C37 1.821(4) . ?
P3 C30 1.833(4) . ?
P4 N3 1.702(5) . ?
P4 N4 1.729(4) . ?
P4 C30 1.839(4) . ?
N3 C22 1.356(8) . ?
N3 C25 1.401(8) . ?
N4 C26 1.359(8) . ?
N4 C29 1.368(7) . ?
C22 C23 1.424(10) . ?
C23 C24 1.403(14) . ?
C24 C25 1.299(13) . ?
C26 C27 1.370(9) . ?
C27 C28 1.357(12) . ?
C28 C29 1.342(11) . ?
C31 C36 1.381(7) . ?
C31 C32 1.397(7) . ?
C32 C33 1.400(8) . ?
C33 C34 1.378(10) . ?
C34 C35 1.360(9) . ?
C35 C36 1.404(7) . ?
C37 C42 1.382(7) . ?
C37 C38 1.393(6) . ?
C38 C39 1.385(6) . ?
C39 C40 1.372(8) . ?
C40 C41 1.359(9) . ?
C41 C42 1.392(7) . ?
