#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:57:32 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179163 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/24/4312424.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4312424
loop_
_publ_author_name
'Zuzanna T. Cygan'
'Jeff W. Kampf'
'Mark M. Banaszak Holl'
_publ_section_title
;
 Reactions of Palladium Germylene Complexes: Formation of Sulfide Bridges
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7219
_journal_page_last               7226
_journal_paper_doi               10.1021/ic034613z
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C54 H72 Ge N2 P2 Pd S2 Si4'
_chemical_formula_weight         1166.55
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.0526(14)
_cell_length_b                   20.666(2)
_cell_length_c                   22.719(2)
_cell_measurement_reflns_used    6734
_cell_measurement_temperature    158(2)
_cell_measurement_theta_max      26.18
_cell_measurement_theta_min      3.26
_cell_volume                     6128.3(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      158(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0477
_diffrn_reflns_av_sigmaI/netI    0.0396
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            53009
_diffrn_reflns_theta_full        26.41
_diffrn_reflns_theta_max         26.41
_diffrn_reflns_theta_min         3.26
_exptl_absorpt_coefficient_mu    1.016
_exptl_absorpt_correction_T_max  0.898
_exptl_absorpt_correction_T_min  0.781
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, Acta Cryst. (1995) A51 33-38.'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.264
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2424
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.26
_refine_diff_density_max         0.654
_refine_diff_density_min         -0.521
_refine_diff_density_rms         0.060
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.099(8)
_refine_ls_extinction_coef       0.00059(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     608
_refine_ls_number_reflns         12528
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0432
_refine_ls_R_factor_gt           0.0352
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0296P)²+4.7149P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0770
_refine_ls_wR_factor_ref         0.0799
_reflns_number_gt                11204
_reflns_number_total             12528
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034613zsi20030603_125230_2.cif
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        6128.5(11)
_cod_database_code               4312424
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge -0.28203(3) 0.473784(18) 0.133520(16) 0.02927(9) Uani 1 1 d . . .
Pd1 Pd -0.08621(2) 0.383691(11) 0.145700(11) 0.02693(7) Uani 1 1 d . . .
P1 P 0.08360(8) 0.41435(4) 0.15765(4) 0.03057(19) Uani 1 1 d . . .
P2 P -0.06630(7) 0.27357(4) 0.15226(4) 0.0319(2) Uani 1 1 d . . .
S1 S -0.26184(7) 0.36859(4) 0.12879(4) 0.0353(2) Uani 1 1 d . . .
S2 S -0.11745(6) 0.49593(4) 0.13879(4) 0.03197(19) Uani 1 1 d . . .
Si1 Si -0.26102(12) 0.52791(11) 0.00793(6) 0.0786(5) Uani 1 1 d . . .
Si2 Si -0.47554(9) 0.51030(6) 0.05709(6) 0.0449(3) Uani 1 1 d . . .
Si3 Si -0.33468(9) 0.58057(6) 0.22149(5) 0.0450(3) Uani 1 1 d . . .
Si4 Si -0.37668(9) 0.44137(6) 0.25609(5) 0.0420(3) Uani 1 1 d . . .
N1 N -0.3488(2) 0.49908(15) 0.20220(13) 0.0334(7) Uani 1 1 d . . .
N2 N -0.3431(3) 0.50910(19) 0.06730(15) 0.0483(9) Uani 1 1 d . . .
C1 C -0.3371(7) 0.5482(8) -0.0596(4) 0.128(7) Uani 1 1 d . . .
H1A H -0.3792 0.5110 -0.0708 0.191 Uiso 1 1 calc R . .
H1B H -0.2903 0.5590 -0.0918 0.191 Uiso 1 1 calc R . .
H1C H -0.3815 0.5854 -0.0513 0.191 Uiso 1 1 calc R . .
C2 C -0.1780(5) 0.4576(3) -0.0130(3) 0.095(2) Uani 1 1 d . . .
H2A H -0.1155 0.4580 0.0109 0.143 Uiso 1 1 calc R . .
H2B H -0.1596 0.4609 -0.0548 0.143 Uiso 1 1 calc R . .
H2C H -0.2153 0.4172 -0.0063 0.143 Uiso 1 1 calc R . .
C3 C -0.1750(5) 0.5988(2) 0.0202(3) 0.083(2) Uani 1 1 d . . .
H3A H -0.2162 0.6368 0.0303 0.125 Uiso 1 1 calc R . .
H3B H -0.1358 0.6075 -0.0157 0.125 Uiso 1 1 calc R . .
H3C H -0.1276 0.5893 0.0526 0.125 Uiso 1 1 calc R . .
C4 C -0.5186(4) 0.4542(3) -0.0020(2) 0.0727(16) Uani 1 1 d . . .
H4A H -0.4880 0.4672 -0.0396 0.109 Uiso 1 1 calc R . .
H4B H -0.5935 0.4557 -0.0052 0.109 Uiso 1 1 calc R . .
H4C H -0.4970 0.4100 0.0076 0.109 Uiso 1 1 calc R . .
C5 C -0.5215(5) 0.5942(3) 0.0415(3) 0.093(2) Uani 1 1 d . . .
H5A H -0.5107 0.6214 0.0763 0.140 Uiso 1 1 calc R . .
H5B H -0.5947 0.5932 0.0319 0.140 Uiso 1 1 calc R . .
H5C H -0.4832 0.6122 0.0082 0.140 Uiso 1 1 calc R . .
C6 C -0.5482(3) 0.4829(3) 0.1227(2) 0.0667(15) Uani 1 1 d . . .
H6A H -0.5296 0.4381 0.1319 0.100 Uiso 1 1 calc R . .
H6B H -0.6218 0.4854 0.1145 0.100 Uiso 1 1 calc R . .
H6C H -0.5316 0.5107 0.1563 0.100 Uiso 1 1 calc R . .
C7 C -0.2851(4) 0.63082(19) 0.1607(2) 0.0538(11) Uani 1 1 d . . .
H7A H -0.2159 0.6164 0.1503 0.081 Uiso 1 1 calc R . .
H7B H -0.2830 0.6762 0.1731 0.081 Uiso 1 1 calc R . .
H7C H -0.3302 0.6265 0.1264 0.081 Uiso 1 1 calc R . .
C8 C -0.2433(4) 0.5903(2) 0.2846(2) 0.0642(14) Uani 1 1 d . . .
H8A H -0.2662 0.5637 0.3178 0.096 Uiso 1 1 calc R . .
H8B H -0.2411 0.6358 0.2965 0.096 Uiso 1 1 calc R . .
H8C H -0.1747 0.5764 0.2723 0.096 Uiso 1 1 calc R . .
C9 C -0.4603(4) 0.6183(3) 0.2419(3) 0.0781(17) Uani 1 1 d . . .
H9A H -0.5087 0.6133 0.2092 0.117 Uiso 1 1 calc R . .
H9B H -0.4502 0.6644 0.2501 0.117 Uiso 1 1 calc R . .
H9C H -0.4877 0.5969 0.2770 0.117 Uiso 1 1 calc R . .
C10 C -0.4504(4) 0.4780(3) 0.3191(2) 0.0667(15) Uani 1 1 d . . .
H10A H -0.4123 0.5149 0.3350 0.100 Uiso 1 1 calc R . .
H10B H -0.4596 0.4455 0.3501 0.100 Uiso 1 1 calc R . .
H10C H -0.5175 0.4926 0.3051 0.100 Uiso 1 1 calc R . .
C11 C -0.4606(3) 0.3737(2) 0.23116(19) 0.0506(11) Uani 1 1 d . . .
H11A H -0.5311 0.3894 0.2270 0.076 Uiso 1 1 calc R . .
H11B H -0.4587 0.3387 0.2603 0.076 Uiso 1 1 calc R . .
H11C H -0.4361 0.3575 0.1932 0.076 Uiso 1 1 calc R . .
C12 C -0.2581(4) 0.4053(2) 0.28814(18) 0.0570(13) Uani 1 1 d . . .
H12A H -0.2187 0.3839 0.2570 0.085 Uiso 1 1 calc R . .
H12B H -0.2768 0.3736 0.3183 0.085 Uiso 1 1 calc R . .
H12C H -0.2164 0.4396 0.3059 0.085 Uiso 1 1 calc R . .
C13 C 0.1077(3) 0.45544(17) 0.22762(17) 0.0348(9) Uani 1 1 d . . .
C14 C 0.0273(3) 0.46996(19) 0.26453(17) 0.0386(9) Uani 1 1 d . . .
H14 H -0.0406 0.4591 0.2533 0.046 Uiso 1 1 calc R . .
C15 C 0.0447(4) 0.5002(2) 0.31789(19) 0.0493(11) Uani 1 1 d . . .
H15 H -0.0113 0.5097 0.3432 0.059 Uiso 1 1 calc R . .
C16 C 0.1432(4) 0.5166(2) 0.3346(2) 0.0618(13) Uani 1 1 d . . .
H16 H 0.1550 0.5372 0.3714 0.074 Uiso 1 1 calc R . .
C17 C 0.2237(4) 0.5029(2) 0.2979(2) 0.0657(14) Uani 1 1 d . . .
H17 H 0.2914 0.5144 0.3091 0.079 Uiso 1 1 calc R . .
C18 C 0.2066(3) 0.4724(2) 0.2444(2) 0.0483(10) Uani 1 1 d . . .
H18 H 0.2627 0.4630 0.2191 0.058 Uiso 1 1 calc R . .
C19 C 0.1914(3) 0.35716(16) 0.15464(17) 0.0341(8) Uani 1 1 d . . .
C20 C 0.2164(3) 0.32071(18) 0.20463(17) 0.0396(9) Uani 1 1 d . . .
H20 H 0.1764 0.3250 0.2394 0.048 Uiso 1 1 calc R . .
C21 C 0.2980(3) 0.27901(19) 0.20392(19) 0.0448(10) Uani 1 1 d . . .
H21 H 0.3147 0.2550 0.2383 0.054 Uiso 1 1 calc R . .
C22 C 0.3561(3) 0.27160(19) 0.1536(2) 0.0490(11) Uani 1 1 d . . .
H22 H 0.4122 0.2423 0.1533 0.059 Uiso 1 1 calc R . .
C23 C 0.3329(3) 0.3066(2) 0.1042(2) 0.0487(11) Uani 1 1 d . . .
H23 H 0.3734 0.3019 0.0698 0.058 Uiso 1 1 calc R . .
C24 C 0.2501(3) 0.34901(18) 0.10430(18) 0.0393(9) Uani 1 1 d . . .
H24 H 0.2337 0.3725 0.0696 0.047 Uiso 1 1 calc R . .
C25 C 0.1145(3) 0.47249(17) 0.10000(18) 0.0376(9) Uani 1 1 d . . .
C26 C 0.1549(3) 0.53433(19) 0.1116(2) 0.0513(11) Uani 1 1 d . . .
H26 H 0.1707 0.5469 0.1508 0.062 Uiso 1 1 calc R . .
C27 C 0.1715(4) 0.5766(2) 0.0654(3) 0.0697(16) Uani 1 1 d . . .
H27 H 0.1993 0.6182 0.0731 0.084 Uiso 1 1 calc R . .
C28 C 0.1480(4) 0.5591(2) 0.0085(3) 0.0664(16) Uani 1 1 d . . .
H28 H 0.1602 0.5888 -0.0227 0.080 Uiso 1 1 calc R . .
C29 C 0.1077(4) 0.4998(2) -0.0039(2) 0.0561(13) Uani 1 1 d . . .
H29 H 0.0916 0.4880 -0.0432 0.067 Uiso 1 1 calc R . .
C30 C 0.0904(4) 0.45668(18) 0.04279(17) 0.0458(10) Uani 1 1 d . . .
H30 H 0.0614 0.4155 0.0347 0.055 Uiso 1 1 calc R . .
C31 C -0.0316(3) 0.24436(17) 0.22529(17) 0.0346(8) Uani 1 1 d . . .
C32 C -0.0238(3) 0.2882(2) 0.27172(17) 0.0434(10) Uani 1 1 d . . .
H32 H -0.0315 0.3332 0.2646 0.052 Uiso 1 1 calc R . .
C33 C -0.0044(4) 0.2660(3) 0.3288(2) 0.0571(12) Uani 1 1 d . . .
H33 H 0.0015 0.2960 0.3603 0.069 Uiso 1 1 calc R . .
C34 C 0.0059(4) 0.2012(3) 0.3392(2) 0.0623(14) Uani 1 1 d . . .
H34 H 0.0198 0.1863 0.3779 0.075 Uiso 1 1 calc R . .
C35 C -0.0039(4) 0.1574(2) 0.2938(2) 0.0573(13) Uani 1 1 d . . .
H35 H 0.0028 0.1124 0.3014 0.069 Uiso 1 1 calc R . .
C36 C -0.0234(3) 0.17860(19) 0.2377(2) 0.0459(10) Uani 1 1 d . . .
H36 H -0.0314 0.1480 0.2069 0.055 Uiso 1 1 calc R . .
C37 C 0.0274(3) 0.24488(16) 0.09966(16) 0.0339(8) Uani 1 1 d . . .
C38 C 0.1069(3) 0.20313(18) 0.11431(18) 0.0423(10) Uani 1 1 d . . .
H38 H 0.1154 0.1889 0.1538 0.051 Uiso 1 1 calc R . .
C39 C 0.1740(4) 0.1824(2) 0.0705(2) 0.0498(11) Uani 1 1 d . . .
H39 H 0.2290 0.1543 0.0805 0.060 Uiso 1 1 calc R . .
C40 C 0.1620(4) 0.2014(2) 0.0140(2) 0.0564(13) Uani 1 1 d . . .
H40 H 0.2077 0.1860 -0.0153 0.068 Uiso 1 1 calc R . .
C41 C 0.0836(4) 0.2435(2) -0.00143(18) 0.0512(11) Uani 1 1 d . . .
H41 H 0.0763 0.2573 -0.0411 0.061 Uiso 1 1 calc R . .
C42 C 0.0160(3) 0.26526(19) 0.04123(17) 0.0412(9) Uani 1 1 d . . .
H42 H -0.0379 0.2940 0.0309 0.049 Uiso 1 1 calc R . .
C43 C -0.1776(3) 0.22275(16) 0.13693(19) 0.0381(9) Uani 1 1 d . . .
C44 C -0.1845(3) 0.18146(18) 0.08906(18) 0.0391(9) Uani 1 1 d . . .
H44 H -0.1301 0.1797 0.0613 0.047 Uiso 1 1 calc R . .
C45 C -0.2700(3) 0.1426(2) 0.0813(2) 0.0476(11) Uani 1 1 d . . .
H45 H -0.2739 0.1143 0.0485 0.057 Uiso 1 1 calc R . .
C46 C -0.3495(4) 0.1452(2) 0.1212(2) 0.0529(12) Uani 1 1 d . . .
H46 H -0.4082 0.1187 0.1157 0.063 Uiso 1 1 calc R . .
C47 C -0.3441(4) 0.1858(2) 0.1691(2) 0.0578(13) Uani 1 1 d . . .
H47 H -0.3990 0.1873 0.1965 0.069 Uiso 1 1 calc R . .
C48 C -0.2580(4) 0.2247(2) 0.1774(2) 0.0514(11) Uani 1 1 d . . .
H48 H -0.2541 0.2525 0.2106 0.062 Uiso 1 1 calc R . .
C49 C 0.4019(14) 0.2745(4) 0.4442(5) 0.174(6) Uani 1 1 d . . .
H49 H 0.4567 0.2536 0.4641 0.209 Uiso 1 1 calc R . .
C50 C 0.3031(14) 0.2717(4) 0.4673(5) 0.165(7) Uani 1 1 d . . .
H50 H 0.2895 0.2513 0.5039 0.198 Uiso 1 1 calc R . .
C51 C 0.2267(10) 0.2996(6) 0.4351(4) 0.151(5) Uani 1 1 d . . .
H51 H 0.1577 0.2968 0.4482 0.182 Uiso 1 1 calc R . .
C52 C 0.2489(7) 0.3309(4) 0.3847(4) 0.124(3) Uani 1 1 d . . .
H52 H 0.1944 0.3506 0.3636 0.149 Uiso 1 1 calc R . .
C53 C 0.3428(8) 0.3357(4) 0.3631(4) 0.109(3) Uani 1 1 d . . .
H53 H 0.3554 0.3586 0.3276 0.131 Uiso 1 1 calc R . .
C54 C 0.4200(10) 0.3074(4) 0.3928(5) 0.133(3) Uani 1 1 d . . .
H54 H 0.4879 0.3102 0.3780 0.160 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ge1 N1 111.64(15) . . ?
N2 Ge1 S1 113.74(13) . . ?
N1 Ge1 S1 112.07(10) . . ?
N2 Ge1 S2 112.48(11) . . ?
N1 Ge1 S2 110.66(10) . . ?
S1 Ge1 S2 95.26(4) . . ?
P2 Pd1 P1 98.91(3) . . ?
P2 Pd1 S1 89.39(3) . . ?
P1 Pd1 S1 171.44(3) . . ?
P2 Pd1 S2 176.55(3) . . ?
P1 Pd1 S2 84.52(3) . . ?
S1 Pd1 S2 87.19(3) . . ?
C25 P1 C13 106.29(18) . . ?
C25 P1 C19 103.17(17) . . ?
C13 P1 C19 101.50(17) . . ?
C25 P1 Pd1 107.88(13) . . ?
C13 P1 Pd1 113.10(13) . . ?
C19 P1 Pd1 123.42(12) . . ?
C37 P2 C31 108.96(18) . . ?
C37 P2 C43 102.89(18) . . ?
C31 P2 C43 100.42(18) . . ?
C37 P2 Pd1 111.01(11) . . ?
C31 P2 Pd1 114.55(12) . . ?
C43 P2 Pd1 117.88(12) . . ?
Ge1 S1 Pd1 88.71(3) . . ?
Ge1 S2 Pd1 88.16(3) . . ?
N2 Si1 C3 115.0(2) . . ?
N2 Si1 C2 112.0(2) . . ?
C3 Si1 C2 107.3(2) . . ?
N2 Si1 C1 110.7(3) . . ?
C3 Si1 C1 105.4(5) . . ?
C2 Si1 C1 105.8(5) . . ?
N2 Si2 C6 113.3(2) . . ?
N2 Si2 C4 112.7(2) . . ?
C6 Si2 C4 103.6(3) . . ?
N2 Si2 C5 110.9(3) . . ?
C6 Si2 C5 105.7(3) . . ?
C4 Si2 C5 110.2(3) . . ?
N1 Si3 C7 113.01(17) . . ?
N1 Si3 C9 111.7(2) . . ?
C7 Si3 C9 104.9(3) . . ?
N1 Si3 C8 111.2(2) . . ?
C7 Si3 C8 106.8(2) . . ?
C9 Si3 C8 108.9(3) . . ?
N1 Si4 C11 114.93(18) . . ?
N1 Si4 C12 111.89(18) . . ?
C11 Si4 C12 107.9(2) . . ?
N1 Si4 C10 111.4(2) . . ?
C11 Si4 C10 103.4(2) . . ?
C12 Si4 C10 106.7(2) . . ?
Si4 N1 Si3 120.21(18) . . ?
Si4 N1 Ge1 119.54(17) . . ?
Si3 N1 Ge1 115.53(17) . . ?
Si2 N2 Si1 119.8(2) . . ?
Si2 N2 Ge1 122.7(2) . . ?
Si1 N2 Ge1 116.51(19) . . ?
C14 C13 C18 119.1(4) . . ?
C14 C13 P1 120.0(3) . . ?
C18 C13 P1 120.9(3) . . ?
C13 C14 C15 120.5(4) . . ?
C14 C15 C16 120.3(4) . . ?
C17 C16 C15 119.6(4) . . ?
C16 C17 C18 120.3(4) . . ?
C17 C18 C13 120.2(4) . . ?
C24 C19 C20 118.3(3) . . ?
C24 C19 P1 122.1(3) . . ?
C20 C19 P1 119.6(3) . . ?
C21 C20 C19 120.6(4) . . ?
C20 C21 C22 120.5(4) . . ?
C23 C22 C21 119.9(4) . . ?
C22 C23 C24 120.3(4) . . ?
C19 C24 C23 120.4(4) . . ?
C30 C25 C26 118.6(4) . . ?
C30 C25 P1 118.1(3) . . ?
C26 C25 P1 123.1(3) . . ?
C27 C26 C25 119.3(5) . . ?
C28 C27 C26 120.8(5) . . ?
C29 C28 C27 121.0(5) . . ?
C28 C29 C30 118.6(5) . . ?
C25 C30 C29 121.7(4) . . ?
C36 C31 C32 118.3(4) . . ?
C36 C31 P2 121.8(3) . . ?
C32 C31 P2 119.5(3) . . ?
C31 C32 C33 120.1(4) . . ?
C34 C33 C32 120.0(5) . . ?
C33 C34 C35 120.3(4) . . ?
C36 C35 C34 120.2(4) . . ?
C35 C36 C31 121.0(4) . . ?
C38 C37 C42 119.5(4) . . ?
C38 C37 P2 123.3(3) . . ?
C42 C37 P2 117.1(3) . . ?
C37 C38 C39 119.3(4) . . ?
C40 C39 C38 121.0(4) . . ?
C39 C40 C41 120.5(4) . . ?
C42 C41 C40 119.7(4) . . ?
C41 C42 C37 119.9(4) . . ?
C44 C43 C48 119.1(4) . . ?
C44 C43 P2 123.7(3) . . ?
C48 C43 P2 117.1(3) . . ?
C43 C44 C45 120.5(4) . . ?
C46 C45 C44 120.0(4) . . ?
C47 C46 C45 120.3(4) . . ?
C46 C47 C48 120.0(4) . . ?
C47 C48 C43 120.0(4) . . ?
C54 C49 C50 120.1(13) . . ?
C51 C50 C49 117.2(11) . . ?
C52 C51 C50 120.1(12) . . ?
C53 C52 C51 123.4(11) . . ?
C52 C53 C54 118.3(10) . . ?
C53 C54 C49 120.8(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 N2 1.852(3) . ?
Ge1 N1 1.862(3) . ?
Ge1 S1 2.1925(10) . ?
Ge1 S2 2.1996(10) . ?
Pd1 P2 2.2955(9) . ?
Pd1 P1 2.3213(10) . ?
Pd1 S1 2.3453(10) . ?
Pd1 S2 2.3603(9) . ?
P1 C25 1.823(4) . ?
P1 C13 1.829(4) . ?
P1 C19 1.839(4) . ?
P2 C37 1.809(4) . ?
P2 C31 1.823(4) . ?
P2 C43 1.826(4) . ?
Si1 N2 1.766(4) . ?
Si1 C3 1.867(6) . ?
Si1 C2 1.874(7) . ?
Si1 C1 1.874(8) . ?
Si2 N2 1.745(4) . ?
Si2 C6 1.855(5) . ?
Si2 C4 1.861(5) . ?
Si2 C5 1.869(5) . ?
Si3 N1 1.750(3) . ?
Si3 C7 1.845(5) . ?
Si3 C9 1.873(5) . ?
Si3 C8 1.875(5) . ?
Si4 N1 1.748(3) . ?
Si4 C11 1.864(4) . ?
Si4 C12 1.866(5) . ?
Si4 C10 1.884(5) . ?
C13 C14 1.376(5) . ?
C13 C18 1.392(6) . ?
C14 C15 1.382(6) . ?
C15 C16 1.383(6) . ?
C16 C17 1.372(7) . ?
C17 C18 1.387(6) . ?
C19 C24 1.387(5) . ?
C19 C20 1.402(5) . ?
C20 C21 1.370(6) . ?
C21 C22 1.380(6) . ?
C22 C23 1.369(6) . ?
C23 C24 1.392(5) . ?
C25 C30 1.376(6) . ?
C25 C26 1.408(6) . ?
C26 C27 1.382(7) . ?
C27 C28 1.378(8) . ?
C28 C29 1.362(7) . ?
C29 C30 1.403(5) . ?
C31 C36 1.392(5) . ?
C31 C32 1.394(5) . ?
C32 C33 1.397(6) . ?
C33 C34 1.367(7) . ?
C34 C35 1.378(7) . ?
C35 C36 1.371(6) . ?
C37 C38 1.390(6) . ?
C37 C42 1.400(5) . ?
C38 C39 1.394(6) . ?
C39 C40 1.351(7) . ?
C40 C41 1.388(7) . ?
C41 C42 1.385(6) . ?
C43 C44 1.385(5) . ?
C43 C48 1.395(6) . ?
C44 C45 1.386(5) . ?
C45 C46 1.379(6) . ?
C46 C47 1.375(7) . ?
C47 C48 1.394(6) . ?
C49 C54 1.371(13) . ?
C49 C50 1.394(17) . ?
C50 C51 1.364(16) . ?
C51 C52 1.347(12) . ?
C52 C53 1.323(11) . ?
C53 C54 1.347(12) . ?
