#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:59:37 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179165 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/26/4312688.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4312688
loop_
_publ_author_name
'William J. Evans'
'Dimitrios G. Giarikos'
'Daniel Josell'
'Joseph W. Ziller'
_publ_section_title
;
 Synthesis and Structure of Polymeric Networks of Silver
 Hexafluoroacetylacetonate Complexes of THF, Toluene, and
 Vinyltrimethylsilane
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8255
_journal_page_last               8261
_journal_paper_doi               10.1021/ic034649r
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C20 H15 Ag3 F18 O6 Si'
_chemical_formula_weight         1045.02
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXTL
_cell_angle_alpha                93.6360(10)
_cell_angle_beta                 103.6640(10)
_cell_angle_gamma                114.4510(10)
_cell_formula_units_Z            2
_cell_length_a                   11.3415(5)
_cell_length_b                   11.7534(5)
_cell_length_c                   13.3836(5)
_cell_measurement_temperature    165(2)
_cell_volume                     1551.66(11)
_computing_cell_refinement       'Bruker SMART/SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      165(2)
_diffrn_measured_fraction_theta_full 0.942
_diffrn_measured_fraction_theta_max 0.942
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0174
_diffrn_reflns_av_sigmaI/netI    0.0195
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            16519
_diffrn_reflns_theta_full        28.29
_diffrn_reflns_theta_max         28.29
_diffrn_reflns_theta_min         2.06
_diffrn_standards_decay_%        '< 1.0'
_diffrn_standards_interval_count 'initial 50 frames recollected'
_diffrn_standards_number         '50 frames'
_exptl_absorpt_coefficient_mu    2.056
_exptl_absorpt_correction_T_max  0.6605
_exptl_absorpt_correction_T_min  0.5775
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.237
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             1000
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.22
_refine_diff_density_max         2.074
_refine_diff_density_min         -1.004
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     425
_refine_ls_number_reflns         7252
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0365
_refine_ls_R_factor_gt           0.0333
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0376P)²+5.2974P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0838
_refine_ls_wR_factor_ref         0.0865
_reflns_number_gt                6654
_reflns_number_total             7252
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034649rsi20030909_043531.cif
_cod_data_source_block           dg60
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_database_code               4312688
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.27760(3) 0.61291(2) 0.19984(2) 0.02574(7) Uani 1 1 d . . .
Ag2 Ag -0.05684(3) 0.44583(3) 0.09729(2) 0.02590(7) Uani 1 1 d . . .
Ag3 Ag 0.02778(3) 0.47342(3) 0.36959(2) 0.02958(8) Uani 1 1 d . . .
Si1 Si 0.60282(12) 0.86127(13) 0.30711(11) 0.0440(3) Uani 1 1 d . . .
O1 O 0.1417(2) 0.4521(2) 0.03170(19) 0.0249(5) Uani 1 1 d . . .
O2 O 0.1056(3) 0.3951(2) 0.2252(2) 0.0272(5) Uani 1 1 d . A .
O3 O 0.1700(3) 0.7063(2) 0.0754(2) 0.0292(5) Uani 1 1 d . . .
O4 O 0.1189(3) 0.6480(2) 0.2675(2) 0.0292(5) Uani 1 1 d . A .
O5 O -0.1720(3) 0.3781(3) 0.2265(2) 0.0333(6) Uani 1 1 d . A .
O6 O -0.1486(3) 0.4567(3) 0.4502(2) 0.0361(6) Uani 1 1 d . . .
C1 C 0.4762(5) 0.5970(5) 0.2105(5) 0.0564(14) Uani 1 1 d . A .
C2 C 0.5093(7) 0.6820(6) 0.2873(5) 0.0387(14) Uiso 0.65 1 d P A 1
C3 C 0.5184(11) 0.9305(11) 0.3707(9) 0.067(3) Uiso 0.65 1 d P A 1
H3A H 0.5238 0.9097 0.4409 0.100 Uiso 0.65 1 calc PR A 1
H3B H 0.4233 0.8965 0.3297 0.100 Uiso 0.65 1 calc PR A 1
H3C H 0.5622 1.0231 0.3761 0.100 Uiso 0.65 1 calc PR A 1
C4 C 0.5942(10) 0.9012(9) 0.1684(7) 0.062(2) Uiso 0.65 1 d P A 1
H4A H 0.6404 0.8629 0.1348 0.092 Uiso 0.65 1 calc PR A 1
H4B H 0.6384 0.9937 0.1734 0.092 Uiso 0.65 1 calc PR A 1
H4C H 0.4993 0.8673 0.1268 0.092 Uiso 0.65 1 calc PR A 1
C5 C 0.7801(9) 0.9066(9) 0.3746(7) 0.062(2) Uiso 0.65 1 d P A 1
H5A H 0.8076 0.8458 0.3461 0.094 Uiso 0.65 1 calc PR A 1
H5B H 0.7913 0.9063 0.4495 0.094 Uiso 0.65 1 calc PR A 1
H5C H 0.8364 0.9919 0.3645 0.094 Uiso 0.65 1 calc PR A 1
C2B C 0.5083(12) 0.7123(11) 0.2135(9) 0.034(2) Uiso 0.35 1 d P A 2
C3B C 0.5047(19) 0.9515(17) 0.3389(15) 0.057(4) Uiso 0.35 1 d P A 2
H3BA H 0.4541 0.9641 0.2738 0.085 Uiso 0.35 1 calc PR A 2
H3BB H 0.5683 1.0343 0.3830 0.085 Uiso 0.35 1 calc PR A 2
H3BC H 0.4415 0.9022 0.3762 0.085 Uiso 0.35 1 calc PR A 2
C4B C 0.734(2) 0.984(2) 0.2643(18) 0.088(6) Uiso 0.35 1 d P A 2
H4BA H 0.7939 0.9502 0.2461 0.132 Uiso 0.35 1 calc PR A 2
H4BB H 0.7876 1.0580 0.3209 0.132 Uiso 0.35 1 calc PR A 2
H4BC H 0.6920 1.0096 0.2029 0.132 Uiso 0.35 1 calc PR A 2
C5B C 0.698(2) 0.830(2) 0.4321(17) 0.086(6) Uiso 0.35 1 d P A 2
H5BA H 0.7467 0.7832 0.4144 0.130 Uiso 0.35 1 calc PR A 2
H5BB H 0.6332 0.7792 0.4679 0.130 Uiso 0.35 1 calc PR A 2
H5BC H 0.7624 0.9110 0.4783 0.130 Uiso 0.35 1 calc PR A 2
C6 C 0.2202(4) 0.3310(4) -0.0593(3) 0.0317(8) Uani 1 1 d . A .
F1 F 0.1874(3) 0.2086(2) -0.0865(2) 0.0495(7) Uani 1 1 d . . .
F2 F 0.3562(2) 0.3944(3) -0.0308(2) 0.0451(6) Uani 1 1 d . . .
F3 F 0.1754(2) 0.3711(2) -0.14456(17) 0.0371(5) Uani 1 1 d . . .
C7 C 0.1680(3) 0.3577(3) 0.0311(3) 0.0251(7) Uani 1 1 d . . .
C8 C 0.1625(4) 0.2813(3) 0.1064(3) 0.0286(7) Uani 1 1 d . A .
H8A H 0.1828 0.2114 0.0964 0.034 Uiso 1 1 calc R . .
C9 C 0.1277(4) 0.3046(3) 0.1967(3) 0.0270(7) Uani 1 1 d . . .
C10 C 0.1181(5) 0.2072(4) 0.2704(3) 0.0385(9) Uani 1 1 d . A .
C11 C 0.1919(4) 0.9056(4) 0.0365(3) 0.0352(8) Uani 1 1 d . A .
C12 C 0.1630(4) 0.8046(3) 0.1069(3) 0.0272(7) Uani 1 1 d . . .
C13 C 0.1379(4) 0.8354(3) 0.1998(3) 0.0322(8) Uani 1 1 d . A .
H13A H 0.1346 0.9141 0.2140 0.039 Uiso 1 1 calc R . .
C14 C 0.1176(4) 0.7548(3) 0.2721(3) 0.0304(7) Uani 1 1 d . . .
C15 C 0.0902(5) 0.7984(4) 0.3711(4) 0.0445(10) Uani 1 1 d . A .
C16 C -0.3941(4) 0.2816(4) 0.1145(3) 0.0302(7) Uani 1 1 d . A .
C17 C -0.2923(4) 0.3477(3) 0.2230(3) 0.0271(7) Uani 1 1 d . . .
C18 C -0.3469(4) 0.3622(4) 0.3028(3) 0.0350(9) Uani 1 1 d . A .
H18A H -0.4420 0.3335 0.2852 0.042 Uiso 1 1 calc R . .
C19 C -0.2720(4) 0.4158(5) 0.4065(3) 0.0381(9) Uani 1 1 d . . .
F4 F 0.2396(4) 0.2151(4) 0.3150(3) 0.0791(11) Uani 1 1 d . . .
F5 F 0.0656(4) 0.2237(3) 0.3442(3) 0.0706(10) Uani 1 1 d . . .
F6 F 0.0433(3) 0.0883(2) 0.2188(2) 0.0571(8) Uani 1 1 d . . .
F7 F 0.3229(3) 0.9865(3) 0.0671(3) 0.0627(9) Uani 1 1 d . . .
F8 F 0.1220(3) 0.9734(2) 0.0394(2) 0.0515(7) Uani 1 1 d . . .
F9 F 0.1623(3) 0.8546(2) -0.06289(19) 0.0394(5) Uani 1 1 d . . .
F10 F 0.1861(4) 0.8095(4) 0.4555(2) 0.0796(11) Uani 1 1 d . . .
F11 F 0.0831(5) 0.9076(3) 0.3738(3) 0.0782(12) Uani 1 1 d . . .
F12 F -0.0244(4) 0.7125(3) 0.3821(3) 0.0697(10) Uani 1 1 d . . .
F13 F -0.4029(3) 0.1680(3) 0.0876(2) 0.0517(7) Uani 1 1 d . . .
F14 F -0.5193(2) 0.2663(3) 0.10784(19) 0.0438(6) Uani 1 1 d . . .
F15 F -0.3548(3) 0.3492(3) 0.04147(18) 0.0510(7) Uani 1 1 d . . .
C20 C -0.3609(8) 0.4027(8) 0.4806(6) 0.0314(15) Uiso 0.50 1 d P A 1
F16 F -0.3500(10) 0.3397(9) 0.5495(7) 0.094(3) Uiso 0.50 1 d P A 1
F17 F -0.2989(8) 0.5211(8) 0.5515(6) 0.0740(19) Uiso 0.50 1 d P A 1
F18 F -0.4854(6) 0.3714(6) 0.4414(4) 0.0462(12) Uiso 0.50 1 d P A 1
C20B C -0.3447(11) 0.4627(11) 0.4747(8) 0.047(2) Uiso 0.50 1 d P A 2
F16B F -0.3034(12) 0.5883(11) 0.4883(9) 0.116(3) Uiso 0.50 1 d P A 2
F17B F -0.3069(6) 0.4554(6) 0.5699(5) 0.0535(14) Uiso 0.50 1 d P A 2
F18B F -0.4701(5) 0.4298(5) 0.4327(4) 0.0400(11) Uiso 0.50 1 d P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag1 C2B 31.1(3) . . ?
C1 Ag1 O4 155.12(17) . . ?
C2B Ag1 O4 139.5(3) . . ?
C1 Ag1 C2 31.1(2) . . ?
C2B Ag1 C2 26.3(3) . . ?
O4 Ag1 C2 126.52(17) . . ?
C1 Ag1 O3 127.67(18) . . ?
C2B Ag1 O3 106.7(3) . . ?
O4 Ag1 O3 72.64(9) . . ?
C2 Ag1 O3 129.96(18) . . ?
C1 Ag1 O1 95.45(15) . . ?
C2B Ag1 O1 111.9(3) . . ?
O4 Ag1 O1 105.99(9) . . ?
C2 Ag1 O1 126.50(17) . . ?
O3 Ag1 O1 70.94(8) . . ?
C1 Ag1 Ag2 140.78(13) . . ?
C2B Ag1 Ag2 160.8(3) . . ?
O4 Ag1 Ag2 56.62(6) . . ?
C2 Ag1 Ag2 165.23(16) . . ?
O3 Ag1 Ag2 64.39(6) . . ?
O1 Ag1 Ag2 49.79(5) . . ?
O5 Ag2 O1 118.15(9) . 2_565 ?
O5 Ag2 O2 77.98(9) . . ?
O1 Ag2 O2 160.37(8) 2_565 . ?
O5 Ag2 O3 113.44(9) . 2_565 ?
O1 Ag2 O3 71.36(8) 2_565 2_565 ?
O2 Ag2 O3 114.18(8) . 2_565 ?
O5 Ag2 O1 143.88(9) . . ?
O1 Ag2 O1 97.96(7) 2_565 . ?
O2 Ag2 O1 66.85(8) . . ?
O3 Ag2 O1 75.87(8) 2_565 . ?
O5 Ag2 Ag2 169.42(7) . 2_565 ?
O1 Ag2 Ag2 51.29(6) 2_565 2_565 ?
O2 Ag2 Ag2 112.46(6) . 2_565 ?
O3 Ag2 Ag2 64.72(6) 2_565 2_565 ?
O1 Ag2 Ag2 46.67(5) . 2_565 ?
O5 Ag2 Ag1 112.88(6) . . ?
O1 Ag2 Ag1 110.37(6) 2_565 . ?
O2 Ag2 Ag1 50.42(6) . . ?
O3 Ag2 Ag1 124.48(6) 2_565 . ?
O1 Ag2 Ag1 48.63(5) . . ?
Ag2 Ag2 Ag1 74.628(11) 2_565 . ?
O6 Ag3 O5 153.92(9) 2_566 . ?
O6 Ag3 O6 77.44(10) 2_566 . ?
O5 Ag3 O6 76.99(9) . . ?
O6 Ag3 O4 110.45(10) 2_566 . ?
O5 Ag3 O4 87.44(9) . . ?
O6 Ag3 O4 121.59(9) . . ?
O6 Ag3 O2 126.43(9) 2_566 . ?
O5 Ag3 O2 76.80(9) . . ?
O6 Ag3 O2 150.69(9) . . ?
O4 Ag3 O2 69.92(8) . . ?
C3 Si1 C2B 121.3(5) . . ?
C3 Si1 C5 116.4(5) . . ?
C2B Si1 C5 118.0(5) . . ?
C3 Si1 C4B 110.4(8) . . ?
C2B Si1 C4B 113.6(8) . . ?
C5 Si1 C4B 61.3(8) . . ?
C3 Si1 C2 109.2(4) . . ?
C2B Si1 C2 33.4(4) . . ?
C5 Si1 C2 107.3(4) . . ?
C4B Si1 C2 139.5(8) . . ?
C3 Si1 C5B 95.4(8) . . ?
C2B Si1 C5B 108.2(8) . . ?
C5 Si1 C5B 44.5(7) . . ?
C4B Si1 C5B 105.0(10) . . ?
C2 Si1 C5B 79.3(7) . . ?
C3 Si1 C3B 15.9(6) . . ?
C2B Si1 C3B 117.6(7) . . ?
C5 Si1 C3B 124.1(6) . . ?
C4B Si1 C3B 100.9(9) . . ?
C2 Si1 C3B 115.4(6) . . ?
C5B Si1 C3B 110.6(9) . . ?
C3 Si1 C4 110.4(5) . . ?
C2B Si1 C4 72.2(5) . . ?
C5 Si1 C4 107.4(4) . . ?
C4B Si1 C4 51.8(8) . . ?
C2 Si1 C4 105.6(3) . . ?
C5B Si1 C4 149.7(8) . . ?
C3B Si1 C4 94.5(7) . . ?
C7 O1 Ag2 136.3(2) . 2_565 ?
C7 O1 Ag1 111.6(2) . . ?
Ag2 O1 Ag1 108.54(9) 2_565 . ?
C7 O1 Ag2 120.0(2) . . ?
Ag2 O1 Ag2 82.04(7) 2_565 . ?
Ag1 O1 Ag2 81.58(7) . . ?
C9 O2 Ag2 118.4(2) . . ?
C9 O2 Ag3 140.2(2) . . ?
Ag2 O2 Ag3 87.36(8) . . ?
C12 O3 Ag1 119.2(2) . . ?
C12 O3 Ag2 131.5(2) . 2_565 ?
Ag1 O3 Ag2 108.50(9) . 2_565 ?
C14 O4 Ag1 120.2(2) . . ?
C14 O4 Ag3 129.6(2) . . ?
Ag1 O4 Ag3 107.35(10) . . ?
C17 O5 Ag3 130.6(2) . . ?
C17 O5 Ag2 130.1(2) . . ?
Ag3 O5 Ag2 94.57(9) . . ?
C19 O6 Ag3 129.6(2) . 2_566 ?
C19 O6 Ag3 127.7(2) . . ?
Ag3 O6 Ag3 102.56(10) 2_566 . ?
C2B C1 C2 50.7(6) . . ?
C2B C1 Ag1 75.7(6) . . ?
C2 C1 Ag1 76.9(4) . . ?
C1 C2 Si1 131.6(6) . . ?
C1 C2 Ag1 72.0(4) . . ?
Si1 C2 Ag1 110.0(3) . . ?
C1 C2B Si1 139.3(9) . . ?
C1 C2B Ag1 73.2(6) . . ?
Si1 C2B Ag1 114.0(5) . . ?
F1 C6 F3 107.8(3) . . ?
F1 C6 F2 107.3(3) . . ?
F3 C6 F2 106.4(3) . . ?
F1 C6 C7 113.2(3) . . ?
F3 C6 C7 112.4(3) . . ?
F2 C6 C7 109.4(3) . . ?
O1 C7 C8 126.9(3) . . ?
O1 C7 C6 115.9(3) . . ?
C8 C7 C6 117.1(3) . . ?
C7 C8 C9 121.6(3) . . ?
O2 C9 C8 127.9(3) . . ?
O2 C9 C10 116.4(3) . . ?
C8 C9 C10 115.7(3) . . ?
F5 C10 F4 108.4(4) . . ?
F5 C10 F6 107.6(4) . . ?
F4 C10 F6 105.8(4) . . ?
F5 C10 C9 112.3(3) . . ?
F4 C10 C9 110.6(4) . . ?
F6 C10 C9 111.9(3) . . ?
F9 C11 F7 107.1(3) . . ?
F9 C11 F8 107.2(3) . . ?
F7 C11 F8 107.7(3) . . ?
F9 C11 C12 112.1(3) . . ?
F7 C11 C12 109.8(3) . . ?
F8 C11 C12 112.7(3) . . ?
O3 C12 C13 127.7(3) . . ?
O3 C12 C11 115.3(3) . . ?
C13 C12 C11 116.9(3) . . ?
C14 C13 C12 122.1(3) . . ?
O4 C14 C13 128.1(3) . . ?
O4 C14 C15 114.4(3) . . ?
C13 C14 C15 117.5(3) . . ?
F11 C15 F12 107.5(4) . . ?
F11 C15 F10 107.7(4) . . ?
F12 C15 F10 105.6(4) . . ?
F11 C15 C14 114.4(4) . . ?
F12 C15 C14 110.9(4) . . ?
F10 C15 C14 110.3(4) . . ?
F13 C16 F14 106.9(3) . . ?
F13 C16 F15 107.2(3) . . ?
F14 C16 F15 106.6(3) . . ?
F13 C16 C17 111.2(3) . . ?
F14 C16 C17 113.9(3) . . ?
F15 C16 C17 110.5(3) . . ?
O5 C17 C18 129.4(3) . . ?
O5 C17 C16 114.5(3) . . ?
C18 C17 C16 116.1(3) . . ?
C17 C18 C19 124.6(3) . . ?
O6 C19 C18 130.6(4) . . ?
O6 C19 C20 115.5(4) . . ?
C18 C19 C20 113.2(4) . . ?
O6 C19 C20B 112.3(5) . . ?
C18 C19 C20B 115.3(5) . . ?
C20 C19 C20B 24.7(4) . . ?
F16 C20 F18 108.0(8) . . ?
F16 C20 F17 94.6(8) . . ?
F18 C20 F17 109.8(7) . . ?
F16 C20 C19 116.4(8) . . ?
F18 C20 C19 118.7(6) . . ?
F17 C20 C19 106.5(6) . . ?
F17B C20B F18B 118.1(9) . . ?
F17B C20B F16B 97.3(9) . . ?
F18B C20B F16B 97.3(9) . . ?
F17B C20B C19 112.1(8) . . ?
F18B C20B C19 115.9(8) . . ?
F16B C20B C19 113.3(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C1 2.308(4) . ?
Ag1 C2B 2.337(12) . ?
Ag1 O4 2.359(3) . ?
Ag1 C2 2.365(7) . ?
Ag1 O3 2.418(3) . ?
Ag1 O1 2.534(2) . ?
Ag1 Ag2 3.3406(4) . ?
Ag2 O5 2.390(3) . ?
Ag2 O1 2.404(2) 2_565 ?
Ag2 O2 2.496(3) . ?
Ag2 O3 2.522(3) 2_565 ?
Ag2 O1 2.579(2) . ?
Ag2 Ag2 3.2731(5) 2_565 ?
Ag3 O6 2.372(3) 2_566 ?
Ag3 O5 2.373(3) . ?
Ag3 O6 2.434(3) . ?
Ag3 O4 2.533(3) . ?
Ag3 O2 2.571(2) . ?
Si1 C3 1.802(11) . ?
Si1 C2B 1.821(11) . ?
Si1 C5 1.826(9) . ?
Si1 C4B 1.83(2) . ?
Si1 C2 1.892(7) . ?
Si1 C5B 1.91(2) . ?
Si1 C3B 1.921(18) . ?
Si1 C4 1.933(9) . ?
O1 C7 1.262(4) . ?
O1 Ag2 2.404(2) 2_565 ?
O2 C9 1.247(4) . ?
O3 C12 1.244(4) . ?
O3 Ag2 2.522(3) 2_565 ?
O4 C14 1.258(4) . ?
O5 C17 1.247(4) . ?
O6 C19 1.246(5) . ?
O6 Ag3 2.372(3) 2_566 ?
C1 C2B 1.245(12) . ?
C1 C2 1.254(8) . ?
C6 F1 1.329(4) . ?
C6 F3 1.332(5) . ?
C6 F2 1.347(5) . ?
C6 C7 1.535(5) . ?
C7 C8 1.387(5) . ?
C8 C9 1.403(5) . ?
C9 C10 1.544(5) . ?
C10 F5 1.311(5) . ?
C10 F4 1.328(6) . ?
C10 F6 1.330(5) . ?
C11 F9 1.327(5) . ?
C11 F7 1.331(5) . ?
C11 F8 1.341(5) . ?
C11 C12 1.540(5) . ?
C12 C13 1.399(5) . ?
C13 C14 1.388(5) . ?
C14 C15 1.535(6) . ?
C15 F11 1.317(5) . ?
C15 F12 1.325(6) . ?
C15 F10 1.328(6) . ?
C16 F13 1.317(5) . ?
C16 F14 1.336(4) . ?
C16 F15 1.340(4) . ?
C16 C17 1.538(5) . ?
C17 C18 1.389(5) . ?
C18 C19 1.391(5) . ?
C19 C20 1.546(9) . ?
C19 C20B 1.576(11) . ?
C20 F16 1.233(12) . ?
C20 F18 1.265(10) . ?
C20 F17 1.428(11) . ?
C20B F17B 1.266(12) . ?
C20B F18B 1.276(11) . ?
C20B F16B 1.335(15) . ?
