#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/30/4313036.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4313036
loop_
_publ_author_name
'Karl M. Kadish'
'Li-Lun Wang'
'Antoine Thuriere'
'Eric Van Caemelbecke'
'John L. Bear'
_publ_section_title
;
 Factors Affecting the Electrochemical and Spectroelectrochemical
 Properties of Diruthenium(III,II) Complexes Containing Four Identical
 Unsymmetrical Bridging Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              834
_journal_page_last               843
_journal_paper_doi               10.1021/ic020590x
_journal_volume                  42
_journal_year                    2003
_chemical_formula_moiety         'C48 H44 N8 Cl Ru2, 2 C H2 Cl2'
_chemical_formula_sum            'C50 H48 Cl5 N8 Ru2'
_chemical_formula_weight         1140.35
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.855(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.2054(11)
_cell_length_b                   15.3926(9)
_cell_length_c                   17.6305(10)
_cell_measurement_reflns_used    4966
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      23.52
_cell_measurement_theta_min      1.73
_cell_volume                     4932.3(5)
_computing_cell_refinement       'Bruker SAINT software (Bruker, 1999)'
_computing_data_collection       'Siemens SMART software (Siemens, 1996)'
_computing_data_reduction        'Bruker SAINT software (Bruker, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      223(2)
_diffrn_detector_area_resol_mean 1K
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Siemens SMART CCD'
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0342
_diffrn_reflns_av_sigmaI/netI    0.0315
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            11457
_diffrn_reflns_theta_full        23.52
_diffrn_reflns_theta_max         23.52
_diffrn_reflns_theta_min         1.73
_diffrn_standards_decay_%        0.0
_exptl_absorpt_coefficient_mu    0.927
_exptl_absorpt_correction_T_max  0.9429
_exptl_absorpt_correction_T_min  0.7764
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            Yellow-green
_exptl_crystal_density_diffrn    1.536
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'Flat column'
_exptl_crystal_F_000             2308
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.831
_refine_diff_density_min         -0.590
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     307
_refine_ls_number_reflns         3645
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0498
_refine_ls_R_factor_gt           0.0302
_refine_ls_shift/su_max          0.301
_refine_ls_shift/su_mean         0.013
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0442P)²+17.4431P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0813
_refine_ls_wR_factor_ref         0.0911
_reflns_number_gt                2540
_reflns_number_total             3813
_reflns_threshold_expression     >4sigma(I)
_cod_data_source_file            ic020590x_5.cif
_cod_data_source_block           k742
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Empirical'
changed to 'empirical' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_formula_sum        'C50 H48 N8 Cl5 Ru2'
_cod_database_code               4313036
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.5000 0.41506(3) 0.2500 0.02664(15) Uani 1 2 d S . .
Ru2 Ru 0.5000 0.26698(3) 0.2500 0.02432(15) Uani 1 2 d S . .
Cl1 Cl 0.5000 0.57666(10) 0.2500 0.0466(4) Uani 1 2 d S . .
N1 N 0.40220(18) 0.4100(2) 0.1526(2) 0.0289(8) Uani 1 1 d . . .
N2 N 0.43292(18) 0.2682(2) 0.1333(2) 0.0285(8) Uani 1 1 d . . .
N3 N 0.55984(18) 0.4096(2) 0.1691(2) 0.0293(8) Uani 1 1 d . . .
N4 N 0.59050(18) 0.2683(2) 0.2113(2) 0.0283(8) Uani 1 1 d . . .
C1 C 0.3525(2) 0.4765(3) 0.1341(3) 0.0343(11) Uani 1 1 d . . .
H1 H 0.3616 0.5256 0.1676 0.041 Uiso 1 1 calc R . .
C2 C 0.2901(2) 0.4748(3) 0.0691(3) 0.0394(12) Uani 1 1 d . . .
H2 H 0.2567 0.5215 0.0588 0.047 Uiso 1 1 calc R . .
C3 C 0.2765(2) 0.4031(3) 0.0182(3) 0.0410(12) Uani 1 1 d . . .
H3 H 0.2350 0.4018 -0.0281 0.049 Uiso 1 1 calc R . .
C4 C 0.3244(2) 0.3344(3) 0.0364(3) 0.0370(11) Uani 1 1 d . . .
H4 H 0.3156 0.2857 0.0024 0.044 Uiso 1 1 calc R . .
C5 C 0.3872(2) 0.3362(3) 0.1061(2) 0.0290(9) Uani 1 1 d . . .
C6 C 0.4273(2) 0.1927(3) 0.0843(3) 0.0323(11) Uani 1 1 d . . .
C7 C 0.4401(3) 0.1952(3) 0.0103(3) 0.0398(12) Uani 1 1 d . . .
C8 C 0.4352(3) 0.1169(4) -0.0313(3) 0.0490(13) Uani 1 1 d . . .
H8 H 0.4429 0.1173 -0.0813 0.059 Uiso 1 1 calc R . .
C9 C 0.4195(3) 0.0395(4) -0.0015(3) 0.0535(15) Uani 1 1 d . . .
H9 H 0.4160 -0.0118 -0.0315 0.064 Uiso 1 1 calc R . .
C10 C 0.4090(3) 0.0369(3) 0.0721(3) 0.0475(13) Uani 1 1 d . . .
H10 H 0.3994 -0.0163 0.0931 0.057 Uiso 1 1 calc R . .
C11 C 0.4125(2) 0.1128(3) 0.1148(3) 0.0373(11) Uani 1 1 d . . .
H11 H 0.4050 0.1112 0.1648 0.045 Uiso 1 1 calc R . .
C12 C 0.4608(3) 0.2775(4) -0.0232(3) 0.0523(14) Uani 1 1 d . . .
H12A H 0.4883 0.3149 0.0205 0.078 Uiso 1 1 calc R . .
H12B H 0.4166 0.3072 -0.0554 0.078 Uiso 1 1 calc R . .
H12C H 0.4910 0.2634 -0.0563 0.078 Uiso 1 1 calc R . .
C13 C 0.5610(2) 0.4769(3) 0.1186(3) 0.0383(11) Uani 1 1 d . . .
H13 H 0.5319 0.5261 0.1182 0.046 Uiso 1 1 calc R . .
C14 C 0.6024(3) 0.4757(3) 0.0694(3) 0.0452(12) Uani 1 1 d . . .
H14 H 0.6012 0.5226 0.0348 0.054 Uiso 1 1 calc R . .
C15 C 0.6467(3) 0.4038(3) 0.0708(3) 0.0463(13) Uani 1 1 d . . .
H15 H 0.6771 0.4026 0.0384 0.056 Uiso 1 1 calc R . .
C16 C 0.6458(2) 0.3352(3) 0.1193(3) 0.0404(11) Uani 1 1 d . . .
H16 H 0.6760 0.2868 0.1206 0.049 Uiso 1 1 calc R . .
C17 C 0.6000(2) 0.3363(3) 0.1675(2) 0.0299(10) Uani 1 1 d . . .
C18 C 0.6404(2) 0.1968(3) 0.2244(3) 0.0312(10) Uani 1 1 d . . .
C19 C 0.7152(2) 0.2057(3) 0.2720(3) 0.0339(11) Uani 1 1 d . . .
C20 C 0.7594(3) 0.1311(3) 0.2877(3) 0.0458(13) Uani 1 1 d . . .
H20 H 0.8090 0.1359 0.3195 0.055 Uiso 1 1 calc R . .
C21 C 0.7320(3) 0.0513(3) 0.2578(3) 0.0516(14) Uani 1 1 d . . .
H21 H 0.7628 0.0023 0.2693 0.062 Uiso 1 1 calc R . .
C22 C 0.6591(3) 0.0432(3) 0.2107(3) 0.0482(13) Uani 1 1 d . . .
H22 H 0.6403 -0.0114 0.1901 0.058 Uiso 1 1 calc R . .
C23 C 0.6139(3) 0.1155(3) 0.1938(3) 0.0387(11) Uani 1 1 d . . .
H23 H 0.5646 0.1097 0.1612 0.046 Uiso 1 1 calc R . .
C24 C 0.7488(3) 0.2919(3) 0.3053(3) 0.0444(13) Uani 1 1 d . . .
H24A H 0.7126 0.3268 0.3192 0.067 Uiso 1 1 calc R . .
H24B H 0.7644 0.3221 0.2654 0.067 Uiso 1 1 calc R . .
H24C H 0.7909 0.2822 0.3528 0.067 Uiso 1 1 calc R . .
C25 C 0.364(2) 0.7620(14) 0.1635(8) 0.076(11) Uiso 0.20 1 d PG A -1
Cl2 Cl 0.4144(8) 0.8423(9) 0.2288(7) 0.1071(16) Uiso 0.20 1 d PG A -1
Cl3 Cl 0.3409(9) 0.7925(11) 0.0628(7) 0.1071(16) Uiso 0.20 1 d PG A -1
C26 C 0.3922(5) 0.7494(9) 0.1791(17) 0.048(8) Uiso 0.20 1 d PG B -2
Cl4 Cl 0.3822(7) 0.8571(7) 0.2057(7) 0.1071(16) Uiso 0.20 1 d PG B -2
Cl5 Cl 0.3083(6) 0.7016(6) 0.1244(7) 0.1071(16) Uiso 0.20 1 d PG B -2
C27 C 0.3426(15) 0.7282(14) 0.1734(10) 0.039(7) Uiso 0.15 1 d PG C -3
Cl6 Cl 0.4063(10) 0.8047(11) 0.2288(8) 0.1071(16) Uiso 0.15 1 d PG C -3
Cl7 Cl 0.3135(10) 0.7496(13) 0.0704(9) 0.1071(16) Uiso 0.15 1 d PG C -3
C28 C 0.389(3) 0.769(2) 0.1434(11) 0.11(2) Uiso 0.15 1 d PG D -4
Cl8 Cl 0.3654(9) 0.8106(12) 0.0461(8) 0.1071(16) Uiso 0.15 1 d PG D -4
Cl9 Cl 0.4486(9) 0.8371(12) 0.2147(8) 0.1071(16) Uiso 0.15 1 d PG D -4
Cl10 Cl 0.3319(11) 0.7788(13) 0.0844(11) 0.090(5) Uiso 0.15 1 d P E 5
Cl11 Cl 0.3673(17) 0.7381(18) 0.1066(16) 0.110(7) Uiso 0.10 1 d P E 5
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ru1 N1 175.73(18) . 2_655 ?
N1 Ru1 N3 90.75(13) . 2_655 ?
N1 Ru1 N3 89.08(13) 2_655 2_655 ?
N1 Ru1 N3 89.08(13) . . ?
N1 Ru1 N3 90.75(13) 2_655 . ?
N3 Ru1 N3 175.44(18) 2_655 . ?
N1 Ru1 Ru2 87.87(9) . . ?
N1 Ru1 Ru2 87.87(9) 2_655 . ?
N3 Ru1 Ru2 87.72(9) 2_655 . ?
N3 Ru1 Ru2 87.72(9) . . ?
N1 Ru1 Cl1 92.13(9) . . ?
N1 Ru1 Cl1 92.13(9) 2_655 . ?
N3 Ru1 Cl1 92.28(9) 2_655 . ?
N3 Ru1 Cl1 92.28(9) . . ?
Ru2 Ru1 Cl1 180.0 . . ?
N2 Ru2 N2 178.93(19) . 2_655 ?
N2 Ru2 N4 90.49(14) . 2_655 ?
N2 Ru2 N4 89.50(14) 2_655 2_655 ?
N2 Ru2 N4 89.50(14) . . ?
N2 Ru2 N4 90.49(14) 2_655 . ?
N4 Ru2 N4 178.89(19) 2_655 . ?
N2 Ru2 Ru1 89.46(10) . . ?
N2 Ru2 Ru1 89.46(10) 2_655 . ?
N4 Ru2 Ru1 89.45(9) 2_655 . ?
N4 Ru2 Ru1 89.45(9) . . ?
C1 N1 C5 118.7(4) . . ?
C1 N1 Ru1 122.6(3) . . ?
C5 N1 Ru1 118.6(3) . . ?
C5 N2 C6 120.1(3) . . ?
C5 N2 Ru2 119.4(3) . . ?
C6 N2 Ru2 120.0(3) . . ?
C13 N3 C17 118.8(4) . . ?
C13 N3 Ru1 122.5(3) . . ?
C17 N3 Ru1 118.7(3) . . ?
C17 N4 C18 118.9(4) . . ?
C17 N4 Ru2 118.8(3) . . ?
C18 N4 Ru2 122.2(3) . . ?
N1 C1 C2 122.9(4) . . ?
C1 C2 C3 119.1(4) . . ?
C4 C3 C2 119.3(4) . . ?
C3 C4 C5 120.4(4) . . ?
N2 C5 N1 116.2(3) . . ?
N2 C5 C4 124.5(4) . . ?
N1 C5 C4 119.3(4) . . ?
C7 C6 C11 119.7(4) . . ?
C7 C6 N2 122.5(4) . . ?
C11 C6 N2 117.7(4) . . ?
C8 C7 C6 117.5(5) . . ?
C8 C7 C12 120.1(5) . . ?
C6 C7 C12 122.4(4) . . ?
C9 C8 C7 122.2(5) . . ?
C8 C9 C10 120.2(5) . . ?
C9 C10 C11 119.5(5) . . ?
C10 C11 C6 120.9(5) . . ?
C14 C13 N3 122.9(4) . . ?
C13 C14 C15 118.8(5) . . ?
C16 C15 C14 119.7(5) . . ?
C15 C16 C17 120.5(4) . . ?
N4 C17 N3 116.6(4) . . ?
N4 C17 C16 124.3(4) . . ?
N3 C17 C16 119.1(4) . . ?
C23 C18 C19 119.4(4) . . ?
C23 C18 N4 119.1(4) . . ?
C19 C18 N4 121.4(4) . . ?
C20 C19 C18 118.1(4) . . ?
C20 C19 C24 119.2(4) . . ?
C18 C19 C24 122.7(4) . . ?
C21 C20 C19 121.7(4) . . ?
C20 C21 C22 119.9(5) . . ?
C21 C22 C23 120.0(5) . . ?
C22 C23 C18 120.9(4) . . ?
Cl3 C25 Cl2 112.6 . . ?
Cl4 C26 Cl5 112.6 . . ?
Cl6 C27 Cl7 112.6 . . ?
Cl9 C28 Cl8 112.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N1 2.098(3) . ?
Ru1 N1 2.098(3) 2_655 ?
Ru1 N3 2.103(4) 2_655 ?
Ru1 N3 2.103(4) . ?
Ru1 Ru2 2.2795(7) . ?
Ru1 Cl1 2.4873(17) . ?
Ru2 N2 2.044(3) . ?
Ru2 N2 2.044(3) 2_655 ?
Ru2 N4 2.062(3) 2_655 ?
Ru2 N4 2.062(3) . ?
N1 C1 1.366(5) . ?
N1 C5 1.375(5) . ?
N2 C5 1.351(5) . ?
N2 C6 1.431(5) . ?
N3 C13 1.370(5) . ?
N3 C17 1.372(5) . ?
N4 C17 1.347(5) . ?
N4 C18 1.428(5) . ?
C1 C2 1.364(6) . ?
C2 C3 1.394(7) . ?
C3 C4 1.370(6) . ?
C4 C5 1.416(6) . ?
C6 C7 1.404(7) . ?
C6 C11 1.407(6) . ?
C7 C8 1.398(7) . ?
C7 C12 1.504(7) . ?
C8 C9 1.375(8) . ?
C9 C10 1.377(7) . ?
C10 C11 1.380(7) . ?
C13 C14 1.354(7) . ?
C14 C15 1.391(7) . ?
C15 C16 1.363(6) . ?
C16 C17 1.407(6) . ?
C18 C23 1.393(6) . ?
C18 C19 1.416(6) . ?
C19 C20 1.401(6) . ?
C19 C24 1.508(6) . ?
C20 C21 1.373(7) . ?
C21 C22 1.384(7) . ?
C22 C23 1.384(6) . ?
C25 Cl3 1.7499 . ?
C25 Cl2 1.7499 . ?
C26 Cl4 1.7499 . ?
C26 Cl5 1.7500 . ?
C27 Cl6 1.7499 . ?
C27 Cl7 1.7500 . ?
C28 Cl9 1.7499 . ?
C28 Cl8 1.7500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ru1 Ru2 N2 21.39(13) . . . . ?
N1 Ru1 Ru2 N2 -158.61(13) 2_655 . . . ?
N3 Ru1 Ru2 N2 112.22(13) 2_655 . . . ?
N3 Ru1 Ru2 N2 -67.78(13) . . . . ?
Cl1 Ru1 Ru2 N2 72(100) . . . . ?
N1 Ru1 Ru2 N2 -158.61(13) . . . 2_655 ?
N1 Ru1 Ru2 N2 21.39(13) 2_655 . . 2_655 ?
N3 Ru1 Ru2 N2 -67.78(13) 2_655 . . 2_655 ?
N3 Ru1 Ru2 N2 112.22(13) . . . 2_655 ?
Cl1 Ru1 Ru2 N2 -108(100) . . . 2_655 ?
N1 Ru1 Ru2 N4 -69.11(13) . . . 2_655 ?
N1 Ru1 Ru2 N4 110.89(13) 2_655 . . 2_655 ?
N3 Ru1 Ru2 N4 21.73(13) 2_655 . . 2_655 ?
N3 Ru1 Ru2 N4 -158.27(13) . . . 2_655 ?
Cl1 Ru1 Ru2 N4 -18(100) . . . 2_655 ?
N1 Ru1 Ru2 N4 110.89(13) . . . . ?
N1 Ru1 Ru2 N4 -69.11(13) 2_655 . . . ?
N3 Ru1 Ru2 N4 -158.27(13) 2_655 . . . ?
N3 Ru1 Ru2 N4 21.73(13) . . . . ?
Cl1 Ru1 Ru2 N4 162(100) . . . . ?
N1 Ru1 N1 C1 156.2(3) 2_655 . . . ?
N3 Ru1 N1 C1 68.5(3) 2_655 . . . ?
N3 Ru1 N1 C1 -116.1(3) . . . . ?
Ru2 Ru1 N1 C1 156.2(3) . . . . ?
Cl1 Ru1 N1 C1 -23.8(3) . . . . ?
N1 Ru1 N1 C5 -22.9(3) 2_655 . . . ?
N3 Ru1 N1 C5 -110.6(3) 2_655 . . . ?
N3 Ru1 N1 C5 64.8(3) . . . . ?
Ru2 Ru1 N1 C5 -22.9(3) . . . . ?
Cl1 Ru1 N1 C5 157.1(3) . . . . ?
N2 Ru2 N2 C5 -27.9(3) 2_655 . . . ?
N4 Ru2 N2 C5 61.5(3) 2_655 . . . ?
N4 Ru2 N2 C5 -117.4(3) . . . . ?
Ru1 Ru2 N2 C5 -27.9(3) . . . . ?
N2 Ru2 N2 C6 160.6(3) 2_655 . . . ?
N4 Ru2 N2 C6 -110.0(3) 2_655 . . . ?
N4 Ru2 N2 C6 71.1(3) . . . . ?
Ru1 Ru2 N2 C6 160.6(3) . . . . ?
N1 Ru1 N3 C13 69.4(3) . . . . ?
N1 Ru1 N3 C13 -114.9(3) 2_655 . . . ?
N3 Ru1 N3 C13 157.3(3) 2_655 . . . ?
Ru2 Ru1 N3 C13 157.3(3) . . . . ?
Cl1 Ru1 N3 C13 -22.7(3) . . . . ?
N1 Ru1 N3 C17 -111.4(3) . . . . ?
N1 Ru1 N3 C17 64.3(3) 2_655 . . . ?
N3 Ru1 N3 C17 -23.5(3) 2_655 . . . ?
Ru2 Ru1 N3 C17 -23.5(3) . . . . ?
Cl1 Ru1 N3 C17 156.5(3) . . . . ?
N2 Ru2 N4 C17 61.2(3) . . . . ?
N2 Ru2 N4 C17 -117.7(3) 2_655 . . . ?
N4 Ru2 N4 C17 -28.2(3) 2_655 . . . ?
Ru1 Ru2 N4 C17 -28.2(3) . . . . ?
N2 Ru2 N4 C18 -114.2(3) . . . . ?
N2 Ru2 N4 C18 66.9(3) 2_655 . . . ?
N4 Ru2 N4 C18 156.3(3) 2_655 . . . ?
Ru1 Ru2 N4 C18 156.3(3) . . . . ?
C5 N1 C1 C2 -3.4(6) . . . . ?
Ru1 N1 C1 C2 177.5(3) . . . . ?
N1 C1 C2 C3 -1.0(7) . . . . ?
C1 C2 C3 C4 2.7(7) . . . . ?
C2 C3 C4 C5 -0.1(7) . . . . ?
C6 N2 C5 N1 -172.2(4) . . . . ?
Ru2 N2 C5 N1 16.3(5) . . . . ?
C6 N2 C5 C4 10.8(6) . . . . ?
Ru2 N2 C5 C4 -160.7(3) . . . . ?
C1 N1 C5 N2 -171.3(4) . . . . ?
Ru1 N1 C5 N2 7.9(5) . . . . ?
C1 N1 C5 C4 5.9(6) . . . . ?
Ru1 N1 C5 C4 -175.0(3) . . . . ?
C3 C4 C5 N2 172.6(4) . . . . ?
C3 C4 C5 N1 -4.3(6) . . . . ?
C5 N2 C6 C7 63.0(6) . . . . ?
Ru2 N2 C6 C7 -125.5(4) . . . . ?
C5 N2 C6 C11 -120.7(4) . . . . ?
Ru2 N2 C6 C11 50.7(5) . . . . ?
C11 C6 C7 C8 1.9(6) . . . . ?
N2 C6 C7 C8 178.1(4) . . . . ?
C11 C6 C7 C12 -176.1(4) . . . . ?
N2 C6 C7 C12 0.1(7) . . . . ?
C6 C7 C8 C9 -0.9(7) . . . . ?
C12 C7 C8 C9 177.2(5) . . . . ?
C7 C8 C9 C10 -0.9(8) . . . . ?
C8 C9 C10 C11 1.6(7) . . . . ?
C9 C10 C11 C6 -0.5(7) . . . . ?
C7 C6 C11 C10 -1.3(6) . . . . ?
N2 C6 C11 C10 -177.7(4) . . . . ?
C17 N3 C13 C14 -2.7(6) . . . . ?
Ru1 N3 C13 C14 176.5(4) . . . . ?
N3 C13 C14 C15 -1.1(7) . . . . ?
C13 C14 C15 C16 2.2(7) . . . . ?
C14 C15 C16 C17 0.5(7) . . . . ?
C18 N4 C17 N3 -168.1(4) . . . . ?
Ru2 N4 C17 N3 16.3(5) . . . . ?
C18 N4 C17 C16 14.1(6) . . . . ?
Ru2 N4 C17 C16 -161.5(3) . . . . ?
C13 N3 C17 N4 -172.6(4) . . . . ?
Ru1 N3 C17 N4 8.2(5) . . . . ?
C13 N3 C17 C16 5.3(6) . . . . ?
Ru1 N3 C17 C16 -173.9(3) . . . . ?
C15 C16 C17 N4 173.5(4) . . . . ?
C15 C16 C17 N3 -4.3(7) . . . . ?
C17 N4 C18 C23 -116.5(5) . . . . ?
Ru2 N4 C18 C23 59.0(5) . . . . ?
C17 N4 C18 C19 67.5(5) . . . . ?
Ru2 N4 C18 C19 -117.1(4) . . . . ?
C23 C18 C19 C20 -1.3(7) . . . . ?
N4 C18 C19 C20 174.8(4) . . . . ?
C23 C18 C19 C24 178.1(4) . . . . ?
N4 C18 C19 C24 -5.8(7) . . . . ?
C18 C19 C20 C21 0.5(8) . . . . ?
C24 C19 C20 C21 -178.9(5) . . . . ?
C19 C20 C21 C22 0.1(9) . . . . ?
C20 C21 C22 C23 0.0(8) . . . . ?
C21 C22 C23 C18 -0.8(8) . . . . ?
C19 C18 C23 C22 1.4(7) . . . . ?
N4 C18 C23 C22 -174.7(4) . . . . ?
