#------------------------------------------------------------------------------
#$Date: 2016-03-23 02:33:46 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179188 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/32/4313284.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4313284
loop_
_publ_author_name
'Quan-Ming Wang'
'Thomas C. W. Mak'
_publ_section_title
;
 Assembly of Discrete, One-, Two-, and Three-Dimensional Silver(I)
 Supramolecular Complexes Containing Encapsulated Acetylide Dianion with
 Nitrogen-Donor Spacers
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1637
_journal_page_last               1643
_journal_paper_doi               10.1021/ic026019f
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C24 H13 Ag6 F15 N2 O10'
_chemical_formula_weight         1421.58
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.2760(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.4014(5)
_cell_length_b                   28.4257(11)
_cell_length_c                   8.5790(3)
_cell_measurement_temperature    293(2)
_cell_volume                     3455.7(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_av_sigmaI/netI    0.0469
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       37
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            23113
_diffrn_reflns_theta_full        28.04
_diffrn_reflns_theta_max         28.04
_diffrn_reflns_theta_min         1.44
_exptl_absorpt_coefficient_mu    3.470
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5273
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.732
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2672
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.905
_refine_diff_density_min         -1.668
_refine_diff_density_rms         0.112
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.931
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     541
_refine_ls_number_reflns         8324
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.931
_refine_ls_R_factor_all          0.0596
_refine_ls_R_factor_gt           0.0340
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0358P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0703
_refine_ls_wR_factor_ref         0.0773
_reflns_number_gt                5636
_reflns_number_total             8324
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic026019fsi20021222_111119_3.cif
_cod_data_source_block           complex3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4313284
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.14330(3) 0.230864(13) -0.62271(4) 0.04653(11) Uani 1 1 d . . .
Ag2 Ag 0.17899(3) 0.171300(13) -0.28701(4) 0.04540(10) Uani 1 1 d . . .
Ag3 Ag 0.33365(3) 0.214897(14) -0.03806(5) 0.05229(12) Uani 1 1 d . . .
Ag4 Ag 0.35395(3) 0.189351(13) -0.39671(5) 0.04645(11) Uani 1 1 d . . .
Ag5 Ag 0.08512(3) 0.313463(13) -0.45938(4) 0.04600(10) Uani 1 1 d . . .
Ag6 Ag 0.26151(3) 0.343479(12) -0.25745(5) 0.04895(11) Uani 1 1 d . . .
C1 C 0.2370(3) 0.23553(15) -0.3685(5) 0.0354(10) Uani 1 1 d . . .
C2 C 0.2247(3) 0.27807(15) -0.3622(5) 0.0354(10) Uani 1 1 d . . .
O11 O 0.0214(2) 0.26615(15) -0.8038(4) 0.0655(11) Uani 1 1 d . . .
O12 O -0.0489(2) 0.30927(13) -0.6449(4) 0.0605(10) Uani 1 1 d . . .
O21 O -0.0251(2) 0.34807(14) -0.2959(4) 0.0606(10) Uani 1 1 d . . .
O22 O 0.0811(2) 0.34365(12) -0.0746(4) 0.0526(9) Uani 1 1 d . . .
O31 O 0.3696(3) 0.13594(12) -0.0218(4) 0.0577(10) Uani 1 1 d . . .
O32 O 0.4126(3) 0.12461(12) -0.2567(4) 0.0560(9) Uani 1 1 d . . .
O41 O 0.4635(3) 0.18397(13) -0.5578(5) 0.0621(10) Uani 1 1 d . . .
O42 O 0.4568(2) 0.25752(13) -0.6468(4) 0.0585(10) Uani 1 1 d . . .
O51 O 0.1656(3) 0.09848(12) -0.2245(5) 0.0653(11) Uani 1 1 d . . .
O52 O 0.1087(4) 0.10585(15) -0.0014(6) 0.1091(19) Uani 1 1 d . . .
C11 C -0.0461(3) 0.28603(17) -0.7635(6) 0.0394(11) Uani 1 1 d . . .
C12 C -0.1396(4) 0.2823(2) -0.8823(6) 0.0538(14) Uani 1 1 d . . .
C21 C 0.0087(3) 0.35887(17) -0.1594(6) 0.0436(11) Uani 1 1 d . . .
C22 C -0.0437(4) 0.3973(2) -0.0845(8) 0.0681(17) Uani 1 1 d . . .
C31 C 0.4018(3) 0.11341(17) -0.1214(6) 0.0442(12) Uani 1 1 d . . .
C32 C 0.4342(5) 0.0636(2) -0.0737(7) 0.0705(18) Uani 1 1 d . . .
C41 C 0.4894(3) 0.21720(18) -0.6294(6) 0.0425(11) Uani 1 1 d . . .
C42 C 0.5751(4) 0.2080(2) -0.7080(7) 0.0578(15) Uani 1 1 d . . .
C51 C 0.1360(4) 0.08446(18) -0.1089(7) 0.0536(14) Uani 1 1 d . . .
C52 C 0.1286(6) 0.0314(2) -0.0928(9) 0.082(2) Uani 1 1 d . . .
F11 F -0.1285(3) 0.28939(17) -1.0299(4) 0.0987(13) Uani 1 1 d . . .
F12 F -0.2042(2) 0.30994(17) -0.8532(5) 0.125(2) Uani 1 1 d . . .
F13 F -0.1738(3) 0.23939(15) -0.8840(5) 0.1094(15) Uani 1 1 d . . .
F21 F -0.1320(3) 0.40244(18) -0.1522(5) 0.1234(18) Uani 1 1 d . . .
F22 F -0.0018(4) 0.43815(15) -0.0877(7) 0.1336(19) Uani 1 1 d . . .
F23 F -0.0443(3) 0.38979(16) 0.0686(5) 0.1026(14) Uani 1 1 d . . .
F31 F 0.3728(4) 0.04067(13) -0.0057(5) 0.1125(15) Uani 1 1 d . . .
F32 F 0.4508(4) 0.03730(14) -0.1874(5) 0.144(2) Uani 1 1 d . . .
F33 F 0.5096(3) 0.06437(15) 0.0369(6) 0.1269(18) Uani 1 1 d . . .
F41 F 0.6457(6) 0.1961(8) -0.6079(13) 0.123(5) Uani 0.65 1 d P . .
F42 F 0.5982(10) 0.2433(4) -0.789(2) 0.112(4) Uani 0.65 1 d P . .
F43 F 0.5589(10) 0.1723(7) -0.805(3) 0.155(5) Uani 0.65 1 d P . .
F41' F 0.6459(11) 0.2413(10) -0.651(4) 0.112(5) Uani 0.35 1 d P . .
F42' F 0.5601(14) 0.2142(12) -0.8536(16) 0.091(6) Uani 0.35 1 d P . .
F43' F 0.6171(18) 0.1691(8) -0.678(3) 0.090(6) Uani 0.35 1 d P . .
F51 F 0.0412(4) 0.01811(18) -0.1488(8) 0.160(2) Uani 1 1 d . . .
F52 F 0.1457(5) 0.01646(15) 0.0490(6) 0.167(3) Uani 1 1 d . . .
F53 F 0.1800(4) 0.00708(13) -0.1711(7) 0.143(2) Uani 1 1 d . . .
N1 N 0.2967(3) 0.40866(13) -0.1375(5) 0.0429(9) Uani 1 1 d . . .
N2 N 0.1868(3) 0.63099(18) -0.4916(6) 0.0651(14) Uani 1 1 d . . .
H2A H 0.1473 0.6414 -0.5712 0.078 Uiso 1 1 calc R . .
C011 C 0.3737(4) 0.43193(18) -0.1617(6) 0.0512(13) Uani 1 1 d . . .
H01A H 0.4170 0.4166 -0.2123 0.061 Uiso 1 1 calc R . .
C012 C 0.3906(3) 0.47779(16) -0.1140(6) 0.0464(12) Uani 1 1 d . . .
H01B H 0.4444 0.4929 -0.1350 0.056 Uiso 1 1 calc R . .
C013 C 0.3303(4) 0.50174(16) -0.0365(5) 0.0419(11) Uani 1 1 d . . .
C014 C 0.2532(4) 0.47691(18) -0.0079(7) 0.0614(15) Uani 1 1 d . . .
H01C H 0.2103 0.4911 0.0464 0.074 Uiso 1 1 calc R . .
C015 C 0.2389(4) 0.43076(19) -0.0596(7) 0.0629(16) Uani 1 1 d . . .
H01D H 0.1862 0.4148 -0.0383 0.076 Uiso 1 1 calc R . .
C016 C 0.3479(4) 0.55200(16) 0.0206(6) 0.0500(13) Uani 1 1 d . . .
H01E H 0.2896 0.5644 0.0458 0.060 Uiso 1 1 calc R . .
H01F H 0.3939 0.5515 0.1180 0.060 Uiso 1 1 calc R . .
C021 C 0.2744(4) 0.6483(3) -0.4659(8) 0.086(2) Uani 1 1 d . . .
H02A H 0.2925 0.6705 -0.5343 0.104 Uiso 1 1 calc R . .
C022 C 0.3368(4) 0.6329(2) -0.3373(8) 0.0679(17) Uani 1 1 d . . .
H02B H 0.3977 0.6451 -0.3177 0.081 Uiso 1 1 calc R . .
C023 C 0.3114(3) 0.59943(16) -0.2355(6) 0.0462(12) Uani 1 1 d . . .
C024 C 0.2204(4) 0.58222(18) -0.2703(7) 0.0544(14) Uani 1 1 d . . .
H02C H 0.2009 0.5594 -0.2054 0.065 Uiso 1 1 calc R . .
C025 C 0.1578(4) 0.5985(2) -0.4007(7) 0.0601(15) Uani 1 1 d . . .
H02D H 0.0966 0.5868 -0.4239 0.072 Uiso 1 1 calc R . .
C026 C 0.3823(4) 0.58540(16) -0.0930(6) 0.0517(14) Uani 1 1 d . . .
H02E H 0.4050 0.6137 -0.0354 0.062 Uiso 1 1 calc R . .
H02F H 0.4357 0.5710 -0.1293 0.062 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O11 Ag1 C1 145.56(14) . . ?
O11 Ag1 O22 103.65(13) . 4_565 ?
C1 Ag1 O22 93.49(13) . 4_565 ?
O11 Ag1 C2 84.66(13) . 4_565 ?
C1 Ag1 C2 118.78(14) . 4_565 ?
O22 Ag1 C2 107.11(13) 4_565 4_565 ?
O11 Ag1 C2 119.98(13) . . ?
C1 Ag1 C2 27.06(13) . . ?
O22 Ag1 C2 115.10(12) 4_565 . ?
C2 Ag1 C2 121.55(15) 4_565 . ?
O11 Ag1 Ag5 74.38(9) . . ?
C1 Ag1 Ag5 71.19(11) . . ?
O22 Ag1 Ag5 118.97(9) 4_565 . ?
C2 Ag1 Ag5 132.50(9) 4_565 . ?
C2 Ag1 Ag5 47.38(9) . . ?
O11 Ag1 Ag6 116.38(9) . 4_565 ?
C1 Ag1 Ag6 97.07(11) . 4_565 ?
O22 Ag1 Ag6 72.64(9) 4_565 4_565 ?
C2 Ag1 Ag6 42.49(10) 4_565 4_565 ?
C2 Ag1 Ag6 117.89(9) . 4_565 ?
Ag5 Ag1 Ag6 163.182(18) . 4_565 ?
O11 Ag1 Ag3 117.72(11) . 4_565 ?
C1 Ag1 Ag3 54.65(11) . 4_565 ?
O22 Ag1 Ag3 138.37(8) 4_565 4_565 ?
C2 Ag1 Ag3 74.07(10) 4_565 4_565 ?
C2 Ag1 Ag3 47.50(9) . 4_565 ?
Ag5 Ag1 Ag3 78.866(14) . 4_565 ?
Ag6 Ag1 Ag3 84.511(15) 4_565 4_565 ?
O11 Ag1 Ag5 61.05(9) . 4_565 ?
C1 Ag1 Ag5 153.32(11) . 4_565 ?
O22 Ag1 Ag5 75.69(8) 4_565 4_565 ?
C2 Ag1 Ag5 45.76(10) 4_565 4_565 ?
C2 Ag1 Ag5 166.95(9) . 4_565 ?
Ag5 Ag1 Ag5 135.408(17) . 4_565 ?
Ag6 Ag1 Ag5 56.574(12) 4_565 4_565 ?
Ag3 Ag1 Ag5 119.641(17) 4_565 4_565 ?
O11 Ag1 Ag2 59.88(10) . 4_565 ?
C1 Ag1 Ag2 104.39(11) . 4_565 ?
O22 Ag1 Ag2 161.97(8) 4_565 4_565 ?
C2 Ag1 Ag2 66.37(9) 4_565 4_565 ?
C2 Ag1 Ag2 81.49(9) . 4_565 ?
Ag5 Ag1 Ag2 66.214(13) . 4_565 ?
Ag6 Ag1 Ag2 106.813(15) 4_565 4_565 ?
Ag3 Ag1 Ag2 57.926(12) 4_565 4_565 ?
Ag5 Ag1 Ag2 88.910(13) 4_565 4_565 ?
O11 Ag1 Ag2 140.97(10) . . ?
C1 Ag1 Ag2 41.10(11) . . ?
O22 Ag1 Ag2 52.63(8) 4_565 . ?
C2 Ag1 Ag2 128.94(10) 4_565 . ?
C2 Ag1 Ag2 63.52(9) . . ?
Ag5 Ag1 Ag2 90.404(14) . . ?
Ag6 Ag1 Ag2 87.989(14) 4_565 . ?
Ag3 Ag1 Ag2 93.259(13) 4_565 . ?
Ag5 Ag1 Ag2 125.016(15) 4_565 . ?
Ag2 Ag1 Ag2 144.850(16) 4_565 . ?
O51 Ag2 C1 160.56(16) . . ?
O51 Ag2 Ag4 111.95(12) . . ?
C1 Ag2 Ag4 48.61(12) . . ?
O51 Ag2 Ag3 107.56(11) . . ?
C1 Ag2 Ag3 67.09(11) . . ?
Ag4 Ag2 Ag3 65.592(14) . . ?
O51 Ag2 Ag1 134.12(11) . 4_566 ?
C1 Ag2 Ag1 60.85(12) . 4_566 ?
Ag4 Ag2 Ag1 101.950(15) . 4_566 ?
Ag3 Ag2 Ag1 59.650(12) . 4_566 ?
O51 Ag2 Ag1 134.65(11) . . ?
C1 Ag2 Ag1 45.40(11) . . ?
Ag4 Ag2 Ag1 68.516(13) . . ?
Ag3 Ag2 Ag1 112.453(15) . . ?
Ag1 Ag2 Ag1 85.773(10) 4_566 . ?
O51 Ag2 Ag5 81.27(11) . 4_566 ?
C1 Ag2 Ag5 113.32(12) . 4_566 ?
Ag4 Ag2 Ag5 139.005(16) . 4_566 ?
Ag3 Ag2 Ag5 73.442(13) . 4_566 ?
Ag1 Ag2 Ag5 53.052(11) 4_566 4_566 ?
Ag1 Ag2 Ag5 129.865(16) . 4_566 ?
O42 Ag3 O31 100.16(13) 4_566 . ?
O42 Ag3 C2 151.73(13) 4_566 4_566 ?
O31 Ag3 C2 102.18(14) . 4_566 ?
O42 Ag3 C1 125.07(13) 4_566 4_566 ?
O31 Ag3 C1 129.17(13) . 4_566 ?
C2 Ag3 C1 28.03(13) 4_566 4_566 ?
O42 Ag3 Ag4 79.94(9) 4_566 4_566 ?
O31 Ag3 Ag4 149.68(9) . 4_566 ?
C2 Ag3 Ag4 72.02(10) 4_566 4_566 ?
C1 Ag3 Ag4 45.51(10) 4_566 4_566 ?
O42 Ag3 Ag2 112.05(9) 4_566 . ?
O31 Ag3 Ag2 77.02(10) . . ?
C2 Ag3 Ag2 89.80(10) 4_566 . ?
C1 Ag3 Ag2 102.37(9) 4_566 . ?
Ag4 Ag3 Ag2 131.451(17) 4_566 . ?
O42 Ag3 Ag1 116.73(10) 4_566 4_566 ?
O31 Ag3 Ag1 132.51(10) . 4_566 ?
C2 Ag3 Ag1 56.78(11) 4_566 4_566 ?
C1 Ag3 Ag1 47.61(9) 4_566 4_566 ?
Ag4 Ag3 Ag1 70.152(13) 4_566 4_566 ?
Ag2 Ag3 Ag1 62.425(13) . 4_566 ?
O42 Ag3 Ag4 58.58(9) 4_566 . ?
O31 Ag3 Ag4 77.32(9) . . ?
C2 Ag3 Ag4 144.00(11) 4_566 . ?
C1 Ag3 Ag4 143.56(9) 4_566 . ?
Ag4 Ag3 Ag4 125.187(17) 4_566 . ?
Ag2 Ag3 Ag4 54.650(12) . . ?
Ag1 Ag3 Ag4 96.590(15) 4_566 . ?
O42 Ag3 Ag6 148.56(10) 4_566 4_566 ?
O31 Ag3 Ag6 63.56(9) . 4_566 ?
C2 Ag3 Ag6 40.09(10) 4_566 4_566 ?
C1 Ag3 Ag6 65.65(10) 4_566 4_566 ?
Ag4 Ag3 Ag6 100.771(15) 4_566 4_566 ?
Ag2 Ag3 Ag6 91.216(14) . 4_566 ?
Ag1 Ag3 Ag6 92.362(14) 4_566 4_566 ?
Ag4 Ag3 Ag6 133.509(16) . 4_566 ?
C1 Ag4 O32 130.45(15) . . ?
C1 Ag4 O41 137.62(15) . . ?
O32 Ag4 O41 91.92(13) . . ?
C1 Ag4 Ag2 48.34(12) . . ?
O32 Ag4 Ag2 87.01(9) . . ?
O41 Ag4 Ag2 157.45(10) . . ?
C1 Ag4 Ag3 58.20(12) . 4_565 ?
O32 Ag4 Ag3 162.88(10) . 4_565 ?
O41 Ag4 Ag3 80.95(9) . 4_565 ?
Ag2 Ag4 Ag3 105.514(15) . 4_565 ?
C1 Ag4 Ag3 63.61(11) . . ?
O32 Ag4 Ag3 76.53(9) . . ?
O41 Ag4 Ag3 141.59(11) . . ?
Ag2 Ag4 Ag3 59.758(12) . . ?
Ag3 Ag4 Ag3 99.436(13) 4_565 . ?
C1 Ag4 Ag6 94.85(11) . 4_565 ?
O32 Ag4 Ag6 108.53(9) . 4_565 ?
O41 Ag4 Ag6 67.49(10) . 4_565 ?
Ag2 Ag4 Ag6 91.494(15) . 4_565 ?
Ag3 Ag4 Ag6 83.208(14) 4_565 4_565 ?
Ag3 Ag4 Ag6 150.919(17) . 4_565 ?
C2 Ag5 O12 144.99(14) . . ?
C2 Ag5 O52 110.21(19) . 4_565 ?
O12 Ag5 O52 94.09(18) . 4_565 ?
C2 Ag5 O21 125.30(14) . . ?
O12 Ag5 O21 82.46(12) . . ?
O52 Ag5 O21 79.97(16) 4_565 . ?
C2 Ag5 Ag1 60.70(11) . . ?
O12 Ag5 Ag1 84.43(9) . . ?
O52 Ag5 Ag1 130.19(13) 4_565 . ?
O21 Ag5 Ag1 147.94(10) . . ?
C2 Ag5 Ag6 45.19(11) . . ?
O12 Ag5 Ag6 164.83(10) . . ?
O52 Ag5 Ag6 70.98(15) 4_565 . ?
O21 Ag5 Ag6 97.11(9) . . ?
Ag1 Ag5 Ag6 102.936(15) . . ?
C2 Ag5 Ag1 53.70(11) . 4_566 ?
O12 Ag5 Ag1 132.80(11) . 4_566 ?
O52 Ag5 Ag1 120.78(14) 4_565 4_566 ?
O21 Ag5 Ag1 74.49(8) . 4_566 ?
Ag1 Ag5 Ag1 93.811(12) . 4_566 ?
Ag6 Ag5 Ag1 60.698(12) . 4_566 ?
C2 Ag5 Ag2 84.38(11) . 4_565 ?
O12 Ag5 Ag2 80.74(10) . 4_565 ?
O52 Ag5 Ag2 69.87(12) 4_565 4_565 ?
O21 Ag5 Ag2 144.07(9) . 4_565 ?
Ag1 Ag5 Ag2 60.733(12) . 4_565 ?
Ag6 Ag5 Ag2 91.218(15) . 4_565 ?
Ag1 Ag5 Ag2 138.082(16) 4_566 4_565 ?
C2 Ag6 N1 176.51(16) . . ?
C2 Ag6 Ag5 50.34(12) . . ?
N1 Ag6 Ag5 129.98(11) . . ?
C2 Ag6 Ag1 55.55(12) . 4_566 ?
N1 Ag6 Ag1 121.08(11) . 4_566 ?
Ag5 Ag6 Ag1 62.728(13) . 4_566 ?
C2 Ag6 Ag3 46.88(12) . 4_565 ?
N1 Ag6 Ag3 136.17(11) . 4_565 ?
Ag5 Ag6 Ag3 76.777(13) . 4_565 ?
Ag1 Ag6 Ag3 101.541(14) 4_566 4_565 ?
C2 Ag6 Ag4 100.46(12) . 4_566 ?
N1 Ag6 Ag4 76.75(10) . 4_566 ?
Ag5 Ag6 Ag4 129.595(16) . 4_566 ?
Ag1 Ag6 Ag4 66.876(12) 4_566 4_566 ?
Ag3 Ag6 Ag4 115.155(15) 4_565 4_566 ?
C2 C1 Ag2 138.5(4) . . ?
C2 C1 Ag4 135.9(4) . . ?
Ag2 C1 Ag4 83.05(15) . . ?
C2 C1 Ag1 91.9(3) . . ?
Ag2 C1 Ag1 93.50(15) . . ?
Ag4 C1 Ag1 100.91(17) . . ?
C2 C1 Ag3 65.5(3) . 4_565 ?
Ag2 C1 Ag3 155.4(2) . 4_565 ?
Ag4 C1 Ag3 76.29(13) . 4_565 ?
Ag1 C1 Ag3 77.74(13) . 4_565 ?
C1 C2 Ag6 150.4(4) . . ?
C1 C2 Ag5 123.1(4) . . ?
Ag6 C2 Ag5 84.47(15) . . ?
C1 C2 Ag3 86.5(3) . 4_565 ?
Ag6 C2 Ag3 93.03(16) . 4_565 ?
Ag5 C2 Ag3 111.85(18) . 4_565 ?
C1 C2 Ag1 91.6(3) . 4_566 ?
Ag6 C2 Ag1 81.96(15) . 4_566 ?
Ag5 C2 Ag1 80.54(14) . 4_566 ?
Ag3 C2 Ag1 166.3(2) 4_565 4_566 ?
C1 C2 Ag1 61.0(3) . . ?
Ag6 C2 Ag1 147.1(2) . . ?
Ag5 C2 Ag1 71.91(12) . . ?
Ag3 C2 Ag1 75.71(12) 4_565 . ?
Ag1 C2 Ag1 115.09(16) 4_566 . ?
C11 O11 Ag1 123.1(3) . . ?
C11 O12 Ag5 117.5(3) . . ?
C21 O21 Ag5 116.9(3) . . ?
C21 O22 Ag1 121.0(3) . 4_566 ?
C31 O31 Ag3 125.3(3) . . ?
C31 O32 Ag4 127.2(3) . . ?
C41 O41 Ag4 124.0(3) . . ?
C41 O42 Ag3 125.0(3) . 4_565 ?
C51 O51 Ag2 125.4(4) . . ?
C51 O52 Ag5 132.2(4) . 4_566 ?
O12 C11 O11 129.1(4) . . ?
O12 C11 C12 115.7(4) . . ?
O11 C11 C12 115.1(4) . . ?
F12 C12 F13 106.8(5) . . ?
F12 C12 F11 108.1(5) . . ?
F13 C12 F11 104.0(5) . . ?
F12 C12 C11 114.2(4) . . ?
F13 C12 C11 110.7(5) . . ?
F11 C12 C11 112.5(5) . . ?
O21 C21 O22 128.6(5) . . ?
O21 C21 C22 116.0(5) . . ?
O22 C21 C22 115.4(5) . . ?
F21 C22 F22 107.9(6) . . ?
F21 C22 F23 106.2(5) . . ?
F22 C22 F23 104.3(6) . . ?
F21 C22 C21 113.9(5) . . ?
F22 C22 C21 111.1(5) . . ?
F23 C22 C21 112.9(5) . . ?
O31 C31 O32 130.2(5) . . ?
O31 C31 C32 115.8(5) . . ?
O32 C31 C32 114.0(5) . . ?
F32 C32 F33 108.5(6) . . ?
F32 C32 F31 106.2(6) . . ?
F33 C32 F31 102.9(5) . . ?
F32 C32 C31 115.3(5) . . ?
F33 C32 C31 110.8(5) . . ?
F31 C32 C31 112.4(6) . . ?
O41 C41 O42 129.4(5) . . ?
O41 C41 C42 115.5(5) . . ?
O42 C41 C42 115.1(5) . . ?
F42' C42 F41 134.5(10) . . ?
F42' C42 F43' 108.7(12) . . ?
F41 C42 F43' 47.6(10) . . ?
F42' C42 F42 50.7(11) . . ?
F41 C42 F42 108.6(9) . . ?
F43' C42 F42 128.9(10) . . ?
F42' C42 F43 59.2(10) . . ?
F41 C42 F43 105.1(10) . . ?
F43' C42 F43 58.6(10) . . ?
F42 C42 F43 107.0(9) . . ?
F42' C42 F41' 103.9(13) . . ?
F41 C42 F41' 59.7(9) . . ?
F43' C42 F41' 103.0(12) . . ?
F42 C42 F41' 55.2(9) . . ?
F43 C42 F41' 141.0(8) . . ?
F42' C42 C41 114.2(8) . . ?
F41 C42 C41 111.3(7) . . ?
F43' C42 C41 117.0(9) . . ?
F42 C42 C41 113.9(6) . . ?
F43 C42 C41 110.4(6) . . ?
F41' C42 C41 108.6(8) . . ?
O51 C51 O52 131.1(5) . . ?
O51 C51 C52 116.1(5) . . ?
O52 C51 C52 112.7(5) . . ?
F52 C52 F53 106.8(7) . . ?
F52 C52 F51 105.2(6) . . ?
F53 C52 F51 104.8(7) . . ?
F52 C52 C51 114.5(6) . . ?
F53 C52 C51 115.5(6) . . ?
F51 C52 C51 109.3(7) . . ?
F43' F41 C42 66.7(11) . . ?
F43' F41 F41' 125.8(18) . . ?
C42 F41 F41' 66.1(9) . . ?
F42' F42 F41' 125.7(16) . . ?
F42' F42 C42 61.9(9) . . ?
F41' F42 C42 67.0(10) . . ?
F43' F43 F42' 107.9(13) . . ?
F43' F43 C42 58.9(8) . . ?
F42' F43 C42 57.8(8) . . ?
F42 F41' F41 106.0(14) . . ?
F42 F41' C42 57.7(8) . . ?
F41 F41' C42 54.2(8) . . ?
F42 F42' C42 67.4(11) . . ?
F42 F42' F43 125.9(16) . . ?
C42 F42' F43 63.0(9) . . ?
F41 F43' F43 126.7(18) . . ?
F41 F43' C42 65.8(12) . . ?
F43 F43' C42 62.5(9) . . ?
C015 N1 C011 117.3(4) . . ?
C015 N1 Ag6 122.8(3) . . ?
C011 N1 Ag6 119.1(3) . . ?
C025 N2 C021 123.2(5) . . ?
N1 C011 C012 122.0(5) . . ?
C013 C012 C011 121.5(5) . . ?
C012 C013 C014 115.8(4) . . ?
C012 C013 C016 122.9(5) . . ?
C014 C013 C016 121.3(5) . . ?
C013 C014 C015 120.4(5) . . ?
N1 C015 C014 122.8(5) . . ?
C026 C016 C013 116.1(4) . . ?
N2 C021 C022 118.8(6) . . ?
C021 C022 C023 121.3(5) . . ?
C024 C023 C022 117.1(5) . . ?
C024 C023 C026 124.3(5) . . ?
C022 C023 C026 118.6(5) . . ?
C023 C024 C025 120.8(5) . . ?
N2 C025 C024 118.7(5) . . ?
C023 C026 C016 116.1(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O11 2.352(3) . ?
Ag1 C1 2.355(4) . ?
Ag1 O22 2.364(3) 4_565 ?
Ag1 C2 2.554(4) 4_565 ?
Ag1 C2 2.690(4) . ?
Ag1 Ag5 2.9321(5) . ?
Ag1 Ag6 3.0663(6) 4_565 ?
Ag1 Ag3 3.1159(5) 4_565 ?
Ag1 Ag5 3.1254(5) 4_565 ?
Ag1 Ag2 3.2006(5) 4_565 ?
Ag1 Ag2 3.3011(5) . ?
Ag2 O51 2.156(3) . ?
Ag2 C1 2.174(4) . ?
Ag2 Ag4 2.8886(5) . ?
Ag2 Ag3 3.0596(5) . ?
Ag2 Ag1 3.2006(5) 4_566 ?
Ag2 Ag5 3.3573(6) 4_566 ?
Ag3 O42 2.286(4) 4_566 ?
Ag3 O31 2.302(3) . ?
Ag3 C2 2.371(4) 4_566 ?
Ag3 C1 2.601(4) 4_566 ?
Ag3 Ag4 2.9728(5) 4_566 ?
Ag3 Ag1 3.1159(5) 4_566 ?
Ag3 Ag4 3.2250(6) . ?
Ag3 Ag6 3.2434(6) 4_566 ?
Ag4 C1 2.183(4) . ?
Ag4 O32 2.276(3) . ?
Ag4 O41 2.281(4) . ?
Ag4 Ag3 2.9728(5) 4_565 ?
Ag4 Ag6 3.2789(6) 4_565 ?
Ag5 C2 2.270(4) . ?
Ag5 O12 2.275(3) . ?
Ag5 O52 2.356(4) 4_565 ?
Ag5 O21 2.499(4) . ?
Ag5 Ag6 2.9346(5) . ?
Ag5 Ag1 3.1254(5) 4_566 ?
Ag5 Ag2 3.3573(6) 4_565 ?
Ag6 C2 2.092(4) . ?
Ag6 N1 2.136(4) . ?
Ag6 Ag1 3.0663(6) 4_566 ?
Ag6 Ag3 3.2434(6) 4_565 ?
Ag6 Ag4 3.2789(6) 4_566 ?
C1 C2 1.225(6) . ?
C1 Ag3 2.601(4) 4_565 ?
C2 Ag3 2.371(4) 4_565 ?
C2 Ag1 2.554(4) 4_566 ?
O11 C11 1.225(6) . ?
O12 C11 1.220(6) . ?
O21 C21 1.224(6) . ?
O22 C21 1.238(5) . ?
O22 Ag1 2.364(3) 4_566 ?
O31 C31 1.223(6) . ?
O32 C31 1.241(6) . ?
O41 C41 1.221(6) . ?
O42 C41 1.237(6) . ?
O42 Ag3 2.286(4) 4_565 ?
O51 C51 1.214(6) . ?
O52 C51 1.227(7) . ?
O52 Ag5 2.356(4) 4_566 ?
C11 C12 1.541(6) . ?
C12 F12 1.277(6) . ?
C12 F13 1.314(7) . ?
C12 F11 1.320(6) . ?
C21 C22 1.533(8) . ?
C22 F21 1.308(7) . ?
C22 F22 1.311(8) . ?
C22 F23 1.332(7) . ?
C31 C32 1.523(7) . ?
C32 F32 1.285(7) . ?
C32 F33 1.309(7) . ?
C32 F31 1.316(7) . ?
C41 C42 1.531(7) . ?
C42 F42' 1.242(13) . ?
C42 F41 1.254(9) . ?
C42 F43' 1.263(15) . ?
C42 F42 1.299(10) . ?
C42 F43 1.308(10) . ?
C42 F41' 1.414(16) . ?
C51 C52 1.519(8) . ?
C52 F52 1.271(8) . ?
C52 F53 1.287(8) . ?
C52 F51 1.320(9) . ?
F41 F43' 1.02(2) . ?
F41 F41' 1.33(2) . ?
F42 F42' 1.09(2) . ?
F42 F41' 1.262(19) . ?
F43 F43' 1.258(19) . ?
F43 F42' 1.261(19) . ?
N1 C015 1.317(6) . ?
N1 C011 1.338(6) . ?
N2 C025 1.324(7) . ?
N2 C021 1.335(8) . ?
C011 C012 1.375(6) . ?
C012 C013 1.366(6) . ?
C013 C014 1.374(7) . ?
C013 C016 1.517(6) . ?
C014 C015 1.389(7) . ?
C016 C026 1.506(7) . ?
C021 C022 1.365(8) . ?
C022 C023 1.384(7) . ?
C023 C024 1.380(7) . ?
C023 C026 1.500(7) . ?
C024 C025 1.385(7) . ?
