#------------------------------------------------------------------------------
#$Date: 2016-03-23 02:46:51 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179204 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/38/4313860.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4313860
loop_
_publ_author_name
'Louis S. Hegedus'
'Michael J. Sundermann'
'Peter K. Dorhout'
_publ_section_title
;
 Synthesis, Complexation, and Coordination Oligomerization of
 1,8-Pyrazine-Capped 5,12-Dioxocyclams
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4346
_journal_page_last               4354
_journal_paper_doi               10.1021/ic030090j
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C32 H50 Cu N6 O10 Rh'
_chemical_formula_weight         845.23
_chemical_name_common            'Bis Copper Bis Rhodium'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.406(6)
_cell_angle_beta                 93.866(6)
_cell_angle_gamma                104.369(6)
_cell_formula_units_Z            2
_cell_length_a                   9.533(3)
_cell_length_b                   14.048(5)
_cell_length_c                   14.153(5)
_cell_measurement_reflns_used    5223
_cell_measurement_temperature    183(2)
_cell_measurement_theta_max      23.27
_cell_measurement_theta_min      3.10
_cell_volume                     1815.7(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      183(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0547
_diffrn_reflns_av_sigmaI/netI    0.0754
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            11570
_diffrn_reflns_theta_full        23.27
_diffrn_reflns_theta_max         23.27
_diffrn_reflns_theta_min         3.10
_exptl_absorpt_coefficient_mu    1.103
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            green/brown
_exptl_crystal_density_diffrn    1.546
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plates
_exptl_crystal_F_000             876
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.38
_refine_diff_density_max         0.607
_refine_diff_density_min         -0.890
_refine_diff_density_rms         0.097
_refine_ls_extinction_coef       0.0042(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.967
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     452
_refine_ls_number_reflns         5223
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.967
_refine_ls_R_factor_all          0.0744
_refine_ls_R_factor_gt           0.0467
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0701P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1132
_refine_ls_wR_factor_ref         0.1238
_reflns_number_gt                3754
_reflns_number_total             5223
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic030090j_1.cif
_cod_data_source_block           complex8
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        1815.7(10)
_cod_database_code               4313860
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C -0.0011(8) 0.7636(5) 0.3101(4) 0.0513(18) Uani 1 1 d . . .
H1A H 0.0048 0.8320 0.2987 0.077 Uiso 1 1 calc R . .
H1B H -0.0845 0.7186 0.2703 0.077 Uiso 1 1 calc R . .
H1C H 0.0885 0.7461 0.2938 0.077 Uiso 1 1 calc R . .
C2 C -0.1705(6) 0.5879(5) 0.3841(5) 0.0456(16) Uani 1 1 d . . .
H2A H -0.1703 0.5835 0.3145 0.068 Uiso 1 1 calc R . .
H2B H -0.2524 0.6134 0.4037 0.068 Uiso 1 1 calc R . .
H2C H -0.1802 0.5219 0.4035 0.068 Uiso 1 1 calc R . .
C3 C -0.0288(6) 0.6575(4) 0.4314(4) 0.0350(14) Uani 1 1 d . . .
C4 C 0.1019(6) 0.6201(4) 0.3994(4) 0.0335(14) Uani 1 1 d . . .
C5 C 0.3605(6) 0.6542(4) 0.3926(4) 0.0391(15) Uani 1 1 d . . .
C6 C 0.3537(8) 0.6546(5) 0.2831(4) 0.058(2) Uani 1 1 d . . .
H6A H 0.2716 0.6011 0.2519 0.088 Uiso 1 1 calc R . .
H6B H 0.4445 0.6447 0.2602 0.088 Uiso 1 1 calc R . .
H6C H 0.3407 0.7184 0.2678 0.088 Uiso 1 1 calc R . .
C7 C 0.3765(7) 0.5529(4) 0.4142(5) 0.0499(18) Uani 1 1 d . . .
H7A H 0.2884 0.5016 0.3878 0.075 Uiso 1 1 calc R . .
H7B H 0.3904 0.5534 0.4835 0.075 Uiso 1 1 calc R . .
H7C H 0.4608 0.5388 0.3851 0.075 Uiso 1 1 calc R . .
C8 C 0.4913(6) 0.7409(4) 0.4305(4) 0.0334(14) Uani 1 1 d . . .
H8A H 0.5815 0.7205 0.4185 0.040 Uiso 1 1 calc R . .
H8B H 0.4891 0.7968 0.3942 0.040 Uiso 1 1 calc R . .
C9 C 0.5891(6) 0.8794(4) 0.5551(4) 0.0352(14) Uani 1 1 d . . .
H9A H 0.6550 0.9074 0.5121 0.042 Uiso 1 1 calc R . .
C10 C 0.5737(6) 0.9379(4) 0.6474(4) 0.0403(15) Uani 1 1 d . . .
C11 C 0.7023(7) 1.0307(5) 0.6614(6) 0.064(2) Uani 1 1 d . . .
H11A H 0.7936 1.0109 0.6577 0.096 Uiso 1 1 calc R . .
H11B H 0.7035 1.0686 0.7241 0.096 Uiso 1 1 calc R . .
H11C H 0.6920 1.0720 0.6112 0.096 Uiso 1 1 calc R . .
C12 C 0.4277(6) 0.9687(4) 0.6539(4) 0.0357(14) Uani 1 1 d . . .
C13 C 0.1661(6) 0.9230(4) 0.6539(4) 0.0354(14) Uani 1 1 d . . .
C14 C 0.1721(7) 0.9470(5) 0.7609(4) 0.0520(18) Uani 1 1 d . . .
H14A H 0.2547 1.0041 0.7835 0.078 Uiso 1 1 calc R . .
H14B H 0.1839 0.8897 0.7912 0.078 Uiso 1 1 calc R . .
H14C H 0.0816 0.9629 0.7776 0.078 Uiso 1 1 calc R . .
C15 C 0.1367(7) 1.0092(4) 0.6064(5) 0.0486(17) Uani 1 1 d . . .
H15A H 0.2147 1.0693 0.6285 0.073 Uiso 1 1 calc R . .
H15B H 0.0433 1.0202 0.6232 0.073 Uiso 1 1 calc R . .
H15C H 0.1331 0.9937 0.5369 0.073 Uiso 1 1 calc R . .
C16 C 0.0387(6) 0.8323(4) 0.6148(4) 0.0343(14) Uani 1 1 d . . .
H16A H -0.0397 0.8293 0.6576 0.041 Uiso 1 1 calc R . .
H16B H -0.0003 0.8428 0.5513 0.041 Uiso 1 1 calc R . .
C17 C -0.0395(6) 0.6599(4) 0.5396(4) 0.0375(15) Uani 1 1 d . . .
H17A H -0.1162 0.6152 0.5640 0.045 Uiso 1 1 calc R . .
C18 C 0.0852(6) 0.6961(4) 0.6987(4) 0.0349(14) Uani 1 1 d . . .
H18A H 0.0022 0.6375 0.6989 0.042 Uiso 1 1 calc R . .
H18B H 0.0772 0.7474 0.7505 0.042 Uiso 1 1 calc R . .
C19 C 0.5525(6) 0.7085(4) 0.5936(4) 0.0346(14) Uani 1 1 d . . .
H19A H 0.6504 0.7437 0.6251 0.042 Uiso 1 1 calc R . .
H19B H 0.5620 0.6496 0.5516 0.042 Uiso 1 1 calc R . .
C20 C 0.2265(6) 0.6667(4) 0.7194(4) 0.0269(13) Uani 1 1 d . . .
C21 C 0.2638(6) 0.6255(4) 0.7980(4) 0.0328(14) Uani 1 1 d . . .
H21A H 0.1960 0.6094 0.8436 0.039 Uiso 1 1 calc R . .
C22 C 0.4532(6) 0.6748(4) 0.6691(4) 0.0315(14) Uani 1 1 d . . .
C23 C 0.4892(6) 0.6325(4) 0.7475(4) 0.0334(14) Uani 1 1 d . . .
H23A H 0.5828 0.6207 0.7566 0.040 Uiso 1 1 calc R . .
C24 C 0.6034(6) 0.6756(4) 1.0980(4) 0.0384(15) Uani 1 1 d . . .
C25 C 0.6620(7) 0.7761(5) 1.1532(5) 0.0552(19) Uani 1 1 d . . .
H25A H 0.7061 0.7702 1.2161 0.083 Uiso 1 1 calc R . .
H25B H 0.5827 0.8084 1.1612 0.083 Uiso 1 1 calc R . .
H25C H 0.7357 0.8160 1.1185 0.083 Uiso 1 1 calc R . .
C26 C 0.2459(6) 0.4839(4) 1.0658(4) 0.0316(14) Uani 1 1 d . . .
C27 C 0.0998(6) 0.4711(5) 1.1022(4) 0.0452(16) Uani 1 1 d . . .
H27A H 0.0987 0.4396 1.1607 0.068 Uiso 1 1 calc R . .
H27B H 0.0252 0.4292 1.0537 0.068 Uiso 1 1 calc R . .
H27C H 0.0798 0.5361 1.1162 0.068 Uiso 1 1 calc R . .
C28 C 0.5749(10) 0.9154(6) 0.8164(5) 0.081(3) Uani 1 1 d . . .
H28A H 0.5847 0.8667 0.8592 0.122 Uiso 1 1 calc R . .
H28B H 0.4796 0.9295 0.8200 0.122 Uiso 1 1 calc R . .
H28C H 0.6517 0.9767 0.8356 0.122 Uiso 1 1 calc R . .
C29 C 1.001(2) 0.159(2) -0.0009(15) 0.219(11) Uani 1 1 d . . .
C30 C 0.676(2) 0.1577(15) -0.0091(12) 0.217(10) Uani 1 1 d . . .
H30A H 0.5808 0.1474 -0.0452 0.326 Uiso 1 1 calc R . .
H30B H 0.6736 0.1890 0.0560 0.326 Uiso 1 1 calc R . .
H30C H 0.6985 0.0936 -0.0066 0.326 Uiso 1 1 calc R . .
C31 C 0.782(2) 0.2188(12) -0.0539(15) 0.186(9) Uani 1 1 d . . .
H31A H 0.7682 0.2860 -0.0561 0.223 Uiso 1 1 calc R . .
H31B H 0.7964 0.1886 -0.1180 0.223 Uiso 1 1 calc R . .
C32 C 1.1243(14) 0.1816(12) 0.0700(12) 0.175(7) Uani 1 1 d . . .
H32A H 1.1162 0.2345 0.1191 0.263 Uiso 1 1 calc R . .
H32B H 1.2141 0.2034 0.0396 0.263 Uiso 1 1 calc R . .
H32C H 1.1266 0.1221 0.0996 0.263 Uiso 1 1 calc R . .
Cu2 Cu 0.27695(7) 0.77222(5) 0.54845(5) 0.0287(2) Uani 1 1 d . . .
N1 N 0.2336(5) 0.6790(3) 0.4314(3) 0.0334(11) Uani 1 1 d . . .
N2 N 0.4971(5) 0.7758(3) 0.5336(3) 0.0309(11) Uani 1 1 d . . .
N3 N 0.3036(5) 0.8993(3) 0.6256(3) 0.0323(11) Uani 1 1 d . . .
N4 N 0.0750(5) 0.7350(3) 0.6051(3) 0.0299(11) Uani 1 1 d . . .
N5 N 0.3224(5) 0.6881(3) 0.6568(3) 0.0267(10) Uani 1 1 d . . .
N6 N 0.3930(5) 0.6082(3) 0.8104(3) 0.0319(11) Uani 1 1 d . . .
O1 O -0.0184(4) 0.7551(3) 0.4074(3) 0.0395(10) Uani 1 1 d . . .
O2 O 0.0753(4) 0.5410(3) 0.3445(3) 0.0440(11) Uani 1 1 d . . .
O3 O 0.5876(5) 0.8765(3) 0.7203(3) 0.0526(12) Uani 1 1 d . . .
O4 O 0.4377(4) 1.0549(3) 0.6902(3) 0.0467(11) Uani 1 1 d . . .
O5 O 0.3824(4) 0.3986(3) 0.8623(3) 0.0375(10) Uani 1 1 d . . .
O6 O 0.2668(4) 0.5250(3) 0.9911(2) 0.0323(9) Uani 1 1 d . . .
O7 O 0.5426(4) 0.6718(3) 1.0158(3) 0.0379(10) Uani 1 1 d . . .
O8 O 0.6604(4) 0.5477(3) 0.8882(2) 0.0338(9) Uani 1 1 d . . .
O9 O 0.957(2) 0.1181(18) -0.0784(11) 0.315(11) Uani 1 1 d . . .
O10 O 0.9100(13) 0.2146(6) 0.0311(8) 0.150(3) Uani 1 1 d . . .
Rh1 Rh 0.46082(5) 0.53762(3) 0.93495(3) 0.02773(18) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 C3 C2 109.5(5) . . ?
O1 C3 C17 108.4(4) . . ?
C2 C3 C17 105.6(5) . . ?
O1 C3 C4 110.5(5) . . ?
C2 C3 C4 110.3(5) . . ?
C17 C3 C4 112.3(5) . . ?
O2 C4 N1 126.6(6) . . ?
O2 C4 C3 117.6(5) . . ?
N1 C4 C3 115.8(5) . . ?
N1 C5 C8 106.3(4) . . ?
N1 C5 C7 112.6(5) . . ?
C8 C5 C7 114.6(5) . . ?
N1 C5 C6 111.4(5) . . ?
C8 C5 C6 103.3(5) . . ?
C7 C5 C6 108.3(5) . . ?
N2 C8 C5 114.2(4) . . ?
N2 C9 C10 117.4(4) . . ?
O3 C10 C9 105.9(5) . . ?
O3 C10 C11 110.1(5) . . ?
C9 C10 C11 106.0(5) . . ?
O3 C10 C12 108.7(5) . . ?
C9 C10 C12 116.1(5) . . ?
C11 C10 C12 109.9(5) . . ?
O4 C12 N3 125.7(6) . . ?
O4 C12 C10 116.3(5) . . ?
N3 C12 C10 117.9(5) . . ?
N3 C13 C14 111.0(5) . . ?
N3 C13 C15 111.5(5) . . ?
C14 C13 C15 109.5(5) . . ?
N3 C13 C16 107.4(4) . . ?
C14 C13 C16 111.5(5) . . ?
C15 C13 C16 105.8(5) . . ?
N4 C16 C13 115.6(4) . . ?
N4 C17 C3 117.7(4) . . ?
N4 C18 C20 113.1(4) . . ?
N2 C19 C22 112.4(4) . . ?
N5 C20 C21 118.7(5) . . ?
N5 C20 C18 115.1(5) . . ?
C21 C20 C18 126.1(5) . . ?
N6 C21 C20 120.4(5) . . ?
N5 C22 C23 118.9(5) . . ?
N5 C22 C19 115.4(5) . . ?
C23 C22 C19 125.7(5) . . ?
N6 C23 C22 120.1(5) . . ?
O7 C24 O5 125.5(5) . 2_667 ?
O7 C24 C25 116.5(6) . . ?
O5 C24 C25 118.0(6) 2_667 . ?
O6 C26 O8 124.8(5) . 2_667 ?
O6 C26 C27 117.7(5) . . ?
O8 C26 C27 117.5(5) 2_667 . ?
O9 C29 O10 110(2) . . ?
O9 C29 C32 143(3) . . ?
O10 C29 C32 107(2) . . ?
C30 C31 O10 90.7(16) . . ?
N3 Cu2 N1 155.92(19) . . ?
N3 Cu2 N4 84.75(18) . . ?
N1 Cu2 N4 99.85(18) . . ?
N3 Cu2 N2 99.21(18) . . ?
N1 Cu2 N2 85.70(18) . . ?
N4 Cu2 N2 157.23(17) . . ?
N3 Cu2 N5 99.27(18) . . ?
N1 Cu2 N5 104.81(18) . . ?
N4 Cu2 N5 78.71(16) . . ?
N2 Cu2 N5 78.52(16) . . ?
C4 N1 C5 118.0(5) . . ?
C4 N1 Cu2 124.9(4) . . ?
C5 N1 Cu2 114.9(4) . . ?
C8 N2 C9 109.6(4) . . ?
C8 N2 C19 111.2(4) . . ?
C9 N2 C19 111.1(4) . . ?
C8 N2 Cu2 101.5(3) . . ?
C9 N2 Cu2 110.2(3) . . ?
C19 N2 Cu2 112.8(3) . . ?
C12 N3 C13 116.7(5) . . ?
C12 N3 Cu2 128.2(4) . . ?
C13 N3 Cu2 115.1(3) . . ?
C16 N4 C18 112.3(4) . . ?
C16 N4 C17 110.2(4) . . ?
C18 N4 C17 107.6(4) . . ?
C16 N4 Cu2 100.9(3) . . ?
C18 N4 Cu2 112.5(3) . . ?
C17 N4 Cu2 113.3(3) . . ?
C22 N5 C20 122.0(5) . . ?
C22 N5 Cu2 118.8(3) . . ?
C20 N5 Cu2 118.1(3) . . ?
C21 N6 C23 119.8(5) . . ?
C21 N6 Rh1 122.7(4) . . ?
C23 N6 Rh1 117.5(4) . . ?
C1 O1 C3 113.8(4) . . ?
C28 O3 C10 117.0(5) . . ?
C24 O5 Rh1 119.4(4) 2_667 . ?
C26 O6 Rh1 119.1(3) . . ?
C24 O7 Rh1 119.2(4) . . ?
C26 O8 Rh1 120.3(3) 2_667 . ?
C29 O10 C31 112.5(14) . . ?
O8 Rh1 O7 88.82(16) . . ?
O8 Rh1 O6 175.74(14) . . ?
O7 Rh1 O6 90.17(15) . . ?
O8 Rh1 O5 91.37(15) . . ?
O7 Rh1 O5 175.88(15) . . ?
O6 Rh1 O5 89.34(15) . . ?
O8 Rh1 N6 90.88(15) . . ?
O7 Rh1 N6 91.94(16) . . ?
O6 Rh1 N6 93.29(15) . . ?
O5 Rh1 N6 92.17(16) . . ?
O8 Rh1 Rh1 87.44(10) . 2_667 ?
O7 Rh1 Rh1 88.29(11) . 2_667 ?
O6 Rh1 Rh1 88.39(10) . 2_667 ?
O5 Rh1 Rh1 87.61(12) . 2_667 ?
N6 Rh1 Rh1 178.31(12) . 2_667 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 O1 1.413(7) . ?
C2 C3 1.518(8) . ?
C3 O1 1.431(7) . ?
C3 C17 1.539(8) . ?
C3 C4 1.543(8) . ?
C4 O2 1.243(6) . ?
C4 N1 1.338(7) . ?
C5 N1 1.464(7) . ?
C5 C8 1.528(8) . ?
C5 C7 1.529(8) . ?
C5 C6 1.548(8) . ?
C8 N2 1.480(7) . ?
C9 N2 1.487(7) . ?
C9 C10 1.500(8) . ?
C10 O3 1.436(7) . ?
C10 C11 1.536(8) . ?
C10 C12 1.562(8) . ?
C12 O4 1.239(7) . ?
C12 N3 1.338(7) . ?
C13 N3 1.499(7) . ?
C13 C14 1.509(8) . ?
C13 C15 1.525(8) . ?
C13 C16 1.545(8) . ?
C16 N4 1.485(7) . ?
C17 N4 1.496(7) . ?
C18 N4 1.496(7) . ?
C18 C20 1.524(7) . ?
C19 N2 1.504(7) . ?
C19 C22 1.513(7) . ?
C20 N5 1.321(6) . ?
C20 C21 1.376(7) . ?
C21 N6 1.318(7) . ?
C22 N5 1.309(7) . ?
C22 C23 1.377(8) . ?
C23 N6 1.332(7) . ?
C24 O7 1.254(7) . ?
C24 O5 1.269(7) 2_667 ?
C24 C25 1.490(8) . ?
C26 O6 1.264(6) . ?
C26 O8 1.265(6) 2_667 ?
C26 C27 1.494(7) . ?
C28 O3 1.433(8) . ?
C29 O9 1.18(2) . ?
C29 O10 1.37(2) . ?
C29 C32 1.44(2) . ?
C30 C31 1.39(2) . ?
C31 O10 1.67(2) . ?
Cu2 N3 1.935(5) . ?
Cu2 N1 1.945(5) . ?
Cu2 N4 2.103(4) . ?
Cu2 N2 2.112(4) . ?
Cu2 N5 2.122(4) . ?
N6 Rh1 2.249(4) . ?
O5 C24 1.269(7) 2_667 ?
O5 Rh1 2.039(4) . ?
O6 Rh1 2.038(4) . ?
O7 Rh1 2.035(4) . ?
O8 C26 1.265(6) 2_667 ?
O8 Rh1 2.033(4) . ?
Rh1 Rh1 2.3889(10) 2_667 ?
