#------------------------------------------------------------------------------
#$Date: 2016-03-23 02:48:26 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179207 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/39/4313962.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4313962
loop_
_publ_author_name
'Yonghong Wan'
'Liping Zhang'
'Linpei Jin'
'Song Gao'
'Shaozhe Lu'
_publ_section_title
;
 High-Dimensional Architectures from the Self-Assembly of Lanthanide Ions
 with Benzenedicarboxylates and 1,10-Phenanthroline
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4985
_journal_page_last               4994
_journal_paper_doi               10.1021/ic034258c
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C48 H40 Eu2 N4 O18'
_chemical_formula_weight         1264.76
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.391(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.979(4)
_cell_length_b                   11.5989(19)
_cell_length_c                   20.810(3)
_cell_measurement_temperature    293(2)
_cell_volume                     4746.5(14)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0473
_diffrn_reflns_av_sigmaI/netI    0.0567
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            19249
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.98
_exptl_absorpt_coefficient_mu    2.700
_exptl_absorpt_correction_T_max  0.8768
_exptl_absorpt_correction_T_min  0.2942
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.771
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2504
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.964
_refine_diff_density_min         -0.785
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.977
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     649
_refine_ls_number_reflns         8347
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.977
_refine_ls_R_factor_all          0.0482
_refine_ls_R_factor_gt           0.0298
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0256P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0586
_refine_ls_wR_factor_ref         0.0640
_reflns_number_gt                6456
_reflns_number_total             8347
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034258csi20030310_091045_2.cif
_cod_data_source_block           complex2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4313962
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.053766(11) 0.421736(18) 0.445831(10) 0.01642(6) Uani 1 1 d . . .
Eu2 Eu 0.400915(11) 0.820743(18) 0.463992(11) 0.02061(7) Uani 1 1 d . . .
O1 O 0.40354(15) 1.0069(2) 0.51050(15) 0.0267(7) Uani 1 1 d . . .
O2 O 0.49778(15) 1.1134(2) 0.54650(15) 0.0283(7) Uani 1 1 d . . .
O3 O 0.46577(18) 1.5416(3) 0.56201(17) 0.0455(10) Uani 1 1 d . . .
O4 O 0.39073(18) 1.6187(3) 0.46924(16) 0.0383(9) Uani 1 1 d . . .
O5 O 0.12096(15) 0.4274(3) 0.37054(14) 0.0316(8) Uani 1 1 d . . .
O6 O 0.01892(15) 0.3512(3) 0.32456(14) 0.0292(7) Uani 1 1 d . . .
O7 O -0.00944(17) 0.0853(3) 0.12598(15) 0.0332(8) Uani 1 1 d . . .
O8 O 0.04450(16) 0.1212(3) 0.05392(15) 0.0339(8) Uani 1 1 d . . .
O9 O 0.33508(15) 0.7910(3) 0.53822(15) 0.0287(7) Uani 1 1 d . . .
O10 O 0.40252(16) 0.8180(3) 0.64663(15) 0.0377(9) Uani 1 1 d . . .
O11 O 0.11353(15) 0.5817(2) 0.51130(14) 0.0262(7) Uani 1 1 d . . .
O13 O 0.40576(18) 0.7267(3) 0.35989(17) 0.0455(9) Uani 1 1 d . . .
O14 O 0.48481(15) 0.7718(3) 0.57639(14) 0.0290(7) Uani 1 1 d . . .
N1 N 0.17499(19) 0.3413(3) 0.51605(18) 0.0258(9) Uani 1 1 d . . .
N2 N 0.0700(2) 0.2022(3) 0.44310(19) 0.0317(10) Uani 1 1 d . . .
N3 N 0.27426(19) 0.8060(3) 0.38939(18) 0.0262(9) Uani 1 1 d . . .
N4 N 0.35792(18) 0.9648(3) 0.36182(18) 0.0280(9) Uani 1 1 d . . .
C1 C 0.4344(2) 1.1028(4) 0.5178(2) 0.0218(10) Uani 1 1 d . . .
C2 C 0.3931(2) 1.2095(3) 0.4905(2) 0.0220(10) Uani 1 1 d . . .
C3 C 0.3273(2) 1.2020(4) 0.4435(2) 0.0298(11) Uani 1 1 d . . .
H3A H 0.3076 1.1300 0.4300 0.036 Uiso 1 1 calc R . .
C4 C 0.2909(2) 1.3007(4) 0.4165(3) 0.0355(12) Uani 1 1 d . . .
H4A H 0.2469 1.2951 0.3850 0.043 Uiso 1 1 calc R . .
C5 C 0.3199(3) 1.4075(4) 0.4365(2) 0.0339(12) Uani 1 1 d . . .
H5A H 0.2954 1.4737 0.4177 0.041 Uiso 1 1 calc R . .
C6 C 0.3852(2) 1.4174(4) 0.4843(2) 0.0267(10) Uani 1 1 d . . .
C7 C 0.4215(2) 1.3178(4) 0.5108(2) 0.0254(10) Uani 1 1 d . . .
H7A H 0.4654 1.3235 0.5425 0.030 Uiso 1 1 calc R . .
C8 C 0.4165(3) 1.5337(4) 0.5075(2) 0.0314(12) Uani 1 1 d . . .
C9 C 0.0755(2) 0.3789(4) 0.3212(2) 0.0232(10) Uani 1 1 d . . .
C10 C 0.0898(2) 0.3535(4) 0.2564(2) 0.0227(10) Uani 1 1 d . . .
C11 C 0.1388(3) 0.4153(4) 0.2405(2) 0.0341(12) Uani 1 1 d . . .
H11A H 0.1637 0.4720 0.2703 0.041 Uiso 1 1 calc R . .
C12 C 0.1512(3) 0.3930(4) 0.1804(2) 0.0415(14) Uani 1 1 d . . .
H12A H 0.1841 0.4347 0.1698 0.050 Uiso 1 1 calc R . .
C13 C 0.1141(2) 0.3083(4) 0.1363(2) 0.0323(12) Uani 1 1 d . . .
H13A H 0.1215 0.2946 0.0954 0.039 Uiso 1 1 calc R . .
C14 C 0.0666(2) 0.2442(3) 0.15225(19) 0.0196(10) Uani 1 1 d . . .
C15 C 0.0535(2) 0.2679(4) 0.21171(19) 0.0206(10) Uani 1 1 d . . .
H15A H 0.0202 0.2264 0.2218 0.025 Uiso 1 1 calc R . .
C16 C 0.0312(2) 0.1444(4) 0.1068(2) 0.0252(11) Uani 1 1 d . . .
C17 C 0.3462(2) 0.7965(4) 0.6021(2) 0.0260(11) Uani 1 1 d . . .
C18 C 0.2857(2) 0.7762(4) 0.6247(2) 0.0239(10) Uani 1 1 d . . .
C19 C 0.2873(2) 0.8196(4) 0.6879(2) 0.0341(12) Uani 1 1 d . . .
H19A H 0.3263 0.8560 0.7168 0.041 Uiso 1 1 calc R . .
C20 C 0.2318(2) 0.8088(4) 0.7076(2) 0.0320(12) Uani 1 1 d . . .
H20A H 0.2331 0.8395 0.7494 0.038 Uiso 1 1 calc R . .
C21 C 0.1738(2) 0.7529(4) 0.6662(2) 0.0299(11) Uani 1 1 d . . .
H21A H 0.1362 0.7472 0.6799 0.036 Uiso 1 1 calc R . .
C22 C 0.1715(2) 0.7051(3) 0.6043(2) 0.0205(10) Uani 1 1 d . . .
C23 C 0.2280(2) 0.7190(4) 0.5839(2) 0.0218(10) Uani 1 1 d . . .
H23A H 0.2266 0.6891 0.5420 0.026 Uiso 1 1 calc R . .
C24 C 0.1102(2) 0.6374(3) 0.5624(2) 0.0212(10) Uani 1 1 d . . .
C25 C 0.2261(2) 0.4064(4) 0.5534(2) 0.0365(12) Uani 1 1 d . . .
H25A H 0.2191 0.4855 0.5542 0.044 Uiso 1 1 calc R . .
C26 C 0.2903(3) 0.3627(5) 0.5918(3) 0.0452(14) Uani 1 1 d . . .
H26A H 0.3247 0.4121 0.6174 0.054 Uiso 1 1 calc R . .
C27 C 0.3019(3) 0.2481(5) 0.5913(3) 0.0434(14) Uani 1 1 d . . .
H27A H 0.3440 0.2178 0.6174 0.052 Uiso 1 1 calc R . .
C28 C 0.2503(3) 0.1761(4) 0.5515(2) 0.0374(13) Uani 1 1 d . . .
C29 C 0.2593(3) 0.0539(5) 0.5454(3) 0.0480(15) Uani 1 1 d . . .
H29A H 0.3015 0.0208 0.5688 0.058 Uiso 1 1 calc R . .
C30 C 0.2085(3) -0.0125(5) 0.5070(3) 0.0524(16) Uani 1 1 d . . .
H30A H 0.2164 -0.0906 0.5027 0.063 Uiso 1 1 calc R . .
C31 C 0.1422(3) 0.0332(4) 0.4722(3) 0.0396(13) Uani 1 1 d . . .
C32 C 0.0869(3) -0.0343(5) 0.4349(3) 0.0557(17) Uani 1 1 d . . .
H32A H 0.0921 -0.1134 0.4315 0.067 Uiso 1 1 calc R . .
C33 C 0.0250(3) 0.0156(5) 0.4035(3) 0.0636(19) Uani 1 1 d . . .
H33A H -0.0124 -0.0291 0.3791 0.076 Uiso 1 1 calc R . .
C34 C 0.0187(3) 0.1345(4) 0.4084(3) 0.0503(16) Uani 1 1 d . . .
H34A H -0.0236 0.1680 0.3864 0.060 Uiso 1 1 calc R . .
C35 C 0.1320(2) 0.1531(4) 0.4754(2) 0.0293(11) Uani 1 1 d . . .
C36 C 0.1866(2) 0.2260(4) 0.5142(2) 0.0255(10) Uani 1 1 d . . .
C37 C 0.3971(3) 1.0398(4) 0.3468(2) 0.0400(13) Uani 1 1 d . . .
H37A H 0.4437 1.0344 0.3702 0.048 Uiso 1 1 calc R . .
C38 C 0.3743(3) 1.1267(5) 0.2986(3) 0.0494(15) Uani 1 1 d . . .
H38A H 0.4047 1.1777 0.2903 0.059 Uiso 1 1 calc R . .
C39 C 0.3065(3) 1.1358(5) 0.2637(3) 0.0486(15) Uani 1 1 d . . .
H39A H 0.2897 1.1949 0.2320 0.058 Uiso 1 1 calc R . .
C40 C 0.2617(3) 1.0556(4) 0.2757(2) 0.0376(13) Uani 1 1 d . . .
C41 C 0.1898(3) 1.0583(5) 0.2408(3) 0.0518(16) Uani 1 1 d . . .
H41A H 0.1711 1.1151 0.2081 0.062 Uiso 1 1 calc R . .
C42 C 0.1488(3) 0.9809(5) 0.2541(3) 0.0516(16) Uani 1 1 d . . .
H42A H 0.1022 0.9850 0.2306 0.062 Uiso 1 1 calc R . .
C43 C 0.1753(3) 0.8920(4) 0.3039(2) 0.0379(13) Uani 1 1 d . . .
C44 C 0.1352(3) 0.8047(5) 0.3167(3) 0.0440(14) Uani 1 1 d . . .
H44A H 0.0886 0.8037 0.2927 0.053 Uiso 1 1 calc R . .
C45 C 0.1638(3) 0.7215(5) 0.3637(3) 0.0406(13) Uani 1 1 d . . .
H45A H 0.1375 0.6629 0.3720 0.049 Uiso 1 1 calc R . .
C46 C 0.2336(2) 0.7261(4) 0.3993(2) 0.0335(12) Uani 1 1 d . . .
H46A H 0.2528 0.6695 0.4319 0.040 Uiso 1 1 calc R . .
C47 C 0.2459(2) 0.8877(4) 0.3409(2) 0.0289(11) Uani 1 1 d . . .
C48 C 0.2900(2) 0.9701(4) 0.3263(2) 0.0286(11) Uani 1 1 d . . .
O15 O 0.4705(4) 0.7847(7) 0.2727(3) 0.181(4) Uani 1 1 d . . .
O16 O 0.4309(3) 0.0513(4) 0.7051(3) 0.118(2) Uani 1 1 d . . .
O17 O 0.3968(4) 0.4901(4) 0.3248(3) 0.123(2) Uani 1 1 d . . .
O18 O 0.4514(4) 0.4439(8) 0.6793(4) 0.186(3) Uani 1 1 d . . .
O12 O 0.05966(15) 0.6392(3) 0.58137(14) 0.0270(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O12 Eu1 O8 75.85(10) 3_566 4_566 ?
O12 Eu1 O11 131.11(10) 3_566 . ?
O8 Eu1 O11 79.77(10) 4_566 . ?
O12 Eu1 O7 87.01(11) 3_566 2 ?
O8 Eu1 O7 127.94(11) 4_566 2 ?
O11 Eu1 O7 75.66(10) . 2 ?
O12 Eu1 O5 127.86(10) 3_566 . ?
O8 Eu1 O5 150.11(11) 4_566 . ?
O11 Eu1 O5 92.25(10) . . ?
O7 Eu1 O5 76.35(11) 2 . ?
O12 Eu1 O6 75.18(10) 3_566 . ?
O8 Eu1 O6 142.44(10) 4_566 . ?
O11 Eu1 O6 137.75(10) . . ?
O7 Eu1 O6 73.54(10) 2 . ?
O5 Eu1 O6 52.79(10) . . ?
O12 Eu1 N2 80.08(11) 3_566 . ?
O8 Eu1 N2 82.44(12) 4_566 . ?
O11 Eu1 N2 137.39(11) . . ?
O7 Eu1 N2 142.80(11) 2 . ?
O5 Eu1 N2 84.40(12) . . ?
O6 Eu1 N2 69.47(11) . . ?
O12 Eu1 N1 136.83(11) 3_566 . ?
O8 Eu1 N1 77.37(11) 4_566 . ?
O11 Eu1 N1 75.14(11) . . ?
O7 Eu1 N1 136.04(12) 2 . ?
O5 Eu1 N1 72.74(10) . . ?
O6 Eu1 N1 109.31(10) . . ?
N2 Eu1 N1 63.28(11) . . ?
O12 Eu1 C9 101.47(12) 3_566 . ?
O8 Eu1 C9 157.37(12) 4_566 . ?
O11 Eu1 C9 116.12(12) . . ?
O7 Eu1 C9 73.65(12) 2 . ?
O5 Eu1 C9 26.49(11) . . ?
O6 Eu1 C9 26.31(11) . . ?
N2 Eu1 C9 74.99(12) . . ?
N1 Eu1 C9 90.79(12) . . ?
O12 Eu1 O8 66.90(9) 3_566 2 ?
O8 Eu1 O8 83.17(10) 4_566 2 ?
O11 Eu1 O8 68.64(9) . 2 ?
O7 Eu1 O8 45.21(9) 2 2 ?
O5 Eu1 O8 120.85(9) . 2 ?
O6 Eu1 O8 106.52(9) . 2 ?
N2 Eu1 O8 146.30(11) . 2 ?
N1 Eu1 O8 141.31(10) . 2 ?
C9 Eu1 O8 116.88(10) . 2 ?
O12 Eu1 C16 76.00(11) 3_566 2 ?
O8 Eu1 C16 106.35(12) 4_566 2 ?
O11 Eu1 C16 71.21(10) . 2 ?
O7 Eu1 C16 21.89(11) 2 2 ?
O5 Eu1 C16 97.99(12) . 2 ?
O6 Eu1 C16 89.20(11) . 2 ?
N2 Eu1 C16 151.37(11) . 2 ?
N1 Eu1 C16 144.69(11) . 2 ?
C9 Eu1 C16 94.49(12) . 2 ?
O8 Eu1 C16 23.33(10) 2 2 ?
O12 Eu1 Eu1 64.17(7) 3_566 3_566 ?
O8 Eu1 Eu1 48.27(8) 4_566 3_566 ?
O11 Eu1 Eu1 67.90(7) . 3_566 ?
O7 Eu1 Eu1 79.91(8) 2 3_566 ?
O5 Eu1 Eu1 152.26(7) . 3_566 ?
O6 Eu1 Eu1 132.11(7) . 3_566 ?
N2 Eu1 Eu1 123.34(9) . 3_566 ?
N1 Eu1 Eu1 117.43(8) . 3_566 ?
C9 Eu1 Eu1 150.67(9) . 3_566 ?
O8 Eu1 Eu1 34.90(5) 2 3_566 ?
C16 Eu1 Eu1 58.14(9) 2 3_566 ?
O2 Eu2 O1 81.21(10) 3_676 . ?
O2 Eu2 O4 115.39(11) 3_676 1_545 ?
O1 Eu2 O4 151.61(11) . 1_545 ?
O2 Eu2 O9 147.37(10) 3_676 . ?
O1 Eu2 O9 78.81(10) . . ?
O4 Eu2 O9 75.46(11) 1_545 . ?
O2 Eu2 O14 77.95(10) 3_676 . ?
O1 Eu2 O14 85.07(10) . . ?
O4 Eu2 O14 76.86(10) 1_545 . ?
O9 Eu2 O14 74.87(10) . . ?
O2 Eu2 O13 75.23(11) 3_676 . ?
O1 Eu2 O13 139.95(11) . . ?
O4 Eu2 O13 68.42(11) 1_545 . ?
O9 Eu2 O13 134.79(11) . . ?
O14 Eu2 O13 120.07(11) . . ?
O2 Eu2 N3 138.24(11) 3_676 . ?
O1 Eu2 N3 100.36(11) . . ?
O4 Eu2 N3 82.58(11) 1_545 . ?
O9 Eu2 N3 71.21(11) . . ?
O14 Eu2 N3 143.75(11) . . ?
O13 Eu2 N3 77.88(12) . . ?
O2 Eu2 N4 77.39(11) 3_676 . ?
O1 Eu2 N4 72.53(11) . . ?
O4 Eu2 N4 131.57(11) 1_545 . ?
O9 Eu2 N4 119.87(11) . . ?
O14 Eu2 N4 148.80(11) . . ?
O13 Eu2 N4 71.01(12) . . ?
N3 Eu2 N4 63.85(11) . . ?
C1 O1 Eu2 142.1(3) . . ?
C1 O2 Eu2 146.2(3) . 3_676 ?
C8 O4 Eu2 141.1(3) . 1_565 ?
C9 O5 Eu1 93.8(3) . . ?
C9 O6 Eu1 91.3(2) . . ?
C16 O7 Eu1 113.1(3) . 2_545 ?
C16 O8 Eu1 172.3(3) . 4_565 ?
C16 O8 Eu1 78.9(3) . 2_545 ?
Eu1 O8 Eu1 96.83(10) 4_565 2_545 ?
C17 O9 Eu2 136.2(3) . . ?
C24 O11 Eu1 134.9(3) . . ?
C25 N1 C36 117.5(4) . . ?
C25 N1 Eu1 123.8(3) . . ?
C36 N1 Eu1 118.8(3) . . ?
C34 N2 C35 118.4(4) . . ?
C34 N2 Eu1 120.7(3) . . ?
C35 N2 Eu1 120.9(3) . . ?
C46 N3 C47 117.7(4) . . ?
C46 N3 Eu2 122.6(3) . . ?
C47 N3 Eu2 119.6(3) . . ?
C37 N4 C48 117.9(4) . . ?
C37 N4 Eu2 123.6(3) . . ?
C48 N4 Eu2 118.2(3) . . ?
O2 C1 O1 123.5(4) . . ?
O2 C1 C2 118.2(4) . . ?
O1 C1 C2 118.2(4) . . ?
C3 C2 C7 119.1(4) . . ?
C3 C2 C1 121.0(4) . . ?
C7 C2 C1 119.9(4) . . ?
C4 C3 C2 120.4(4) . . ?
C5 C4 C3 120.0(4) . . ?
C4 C5 C6 120.7(4) . . ?
C7 C6 C5 118.9(4) . . ?
C7 C6 C8 120.1(4) . . ?
C5 C6 C8 121.0(4) . . ?
C2 C7 C6 120.9(4) . . ?
O3 C8 O4 123.7(4) . . ?
O3 C8 C6 119.3(4) . . ?
O4 C8 C6 117.0(4) . . ?
O6 C9 O5 122.0(4) . . ?
O6 C9 C10 119.1(4) . . ?
O5 C9 C10 118.9(4) . . ?
O6 C9 Eu1 62.4(2) . . ?
O5 C9 Eu1 59.7(2) . . ?
C10 C9 Eu1 177.6(3) . . ?
C11 C10 C15 119.2(4) . . ?
C11 C10 C9 120.6(4) . . ?
C15 C10 C9 120.2(4) . . ?
C10 C11 C12 120.4(4) . . ?
C13 C12 C11 119.5(4) . . ?
C14 C13 C12 120.7(4) . . ?
C13 C14 C15 119.7(4) . . ?
C13 C14 C16 120.1(4) . . ?
C15 C14 C16 120.1(4) . . ?
C14 C15 C10 120.3(4) . . ?
O8 C16 O7 122.8(4) . . ?
O8 C16 C14 120.0(4) . . ?
O7 C16 C14 117.2(4) . . ?
O8 C16 Eu1 77.8(3) . 2_545 ?
O7 C16 Eu1 45.1(2) . 2_545 ?
C14 C16 Eu1 161.8(3) . 2_545 ?
O10 C17 O9 124.8(4) . . ?
O10 C17 C18 118.6(4) . . ?
O9 C17 C18 116.6(4) . . ?
C23 C18 C19 118.6(4) . . ?
C23 C18 C17 122.1(4) . . ?
C19 C18 C17 119.2(4) . . ?
C20 C19 C18 120.3(4) . . ?
C19 C20 C21 120.8(4) . . ?
C20 C21 C22 120.3(4) . . ?
C21 C22 C23 118.5(4) . . ?
C21 C22 C24 119.6(4) . . ?
C23 C22 C24 121.9(4) . . ?
C18 C23 C22 121.4(4) . . ?
O12 C24 O11 124.9(4) . . ?
O12 C24 C22 117.1(4) . . ?
O11 C24 C22 117.9(4) . . ?
N1 C25 C26 123.5(5) . . ?
C27 C26 C25 119.4(5) . . ?
C26 C27 C28 119.4(5) . . ?
C27 C28 C36 118.1(5) . . ?
C27 C28 C29 123.0(5) . . ?
C36 C28 C29 118.9(5) . . ?
C30 C29 C28 121.2(5) . . ?
C29 C30 C31 121.6(5) . . ?
C32 C31 C35 118.0(5) . . ?
C32 C31 C30 123.4(5) . . ?
C35 C31 C30 118.6(5) . . ?
C33 C32 C31 119.9(5) . . ?
C32 C33 C34 119.0(6) . . ?
N2 C34 C33 123.2(5) . . ?
N2 C35 C31 121.5(5) . . ?
N2 C35 C36 118.1(4) . . ?
C31 C35 C36 120.4(4) . . ?
N1 C36 C28 122.0(4) . . ?
N1 C36 C35 118.9(4) . . ?
C28 C36 C35 119.1(4) . . ?
N4 C37 C38 124.7(5) . . ?
C39 C38 C37 118.5(5) . . ?
C38 C39 C40 119.6(5) . . ?
C39 C40 C48 117.6(5) . . ?
C39 C40 C41 123.2(5) . . ?
C48 C40 C41 119.2(5) . . ?
C42 C41 C40 121.4(5) . . ?
C41 C42 C43 121.3(5) . . ?
C44 C43 C47 117.2(5) . . ?
C44 C43 C42 123.5(5) . . ?
C47 C43 C42 119.2(5) . . ?
C45 C44 C43 120.5(5) . . ?
C44 C45 C46 118.4(5) . . ?
N3 C46 C45 124.0(5) . . ?
N3 C47 C43 122.2(4) . . ?
N3 C47 C48 118.2(4) . . ?
C43 C47 C48 119.6(4) . . ?
N4 C48 C40 121.6(4) . . ?
N4 C48 C47 119.1(4) . . ?
C40 C48 C47 119.3(4) . . ?
C24 O12 Eu1 144.5(3) . 3_566 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O12 2.355(3) 3_566 ?
Eu1 O8 2.377(3) 4_566 ?
Eu1 O11 2.383(3) . ?
Eu1 O7 2.394(3) 2 ?
Eu1 O5 2.447(3) . ?
Eu1 O6 2.507(3) . ?
Eu1 N2 2.572(4) . ?
Eu1 N1 2.624(4) . ?
Eu1 C9 2.828(4) . ?
Eu1 O8 3.100(3) 2 ?
Eu1 C16 3.112(5) 2 ?
Eu1 Eu1 4.1246(6) 3_566 ?
Eu2 O2 2.339(3) 3_676 ?
Eu2 O1 2.359(3) . ?
Eu2 O4 2.359(3) 1_545 ?
Eu2 O9 2.429(3) . ?
Eu2 O14 2.454(3) . ?
Eu2 O13 2.459(3) . ?
Eu2 N3 2.574(4) . ?
Eu2 N4 2.606(4) . ?
O1 C1 1.270(5) . ?
O2 C1 1.259(5) . ?
O2 Eu2 2.339(3) 3_676 ?
O3 C8 1.243(5) . ?
O4 C8 1.264(5) . ?
O4 Eu2 2.359(3) 1_565 ?
O5 C9 1.264(5) . ?
O6 C9 1.254(5) . ?
O7 C16 1.261(5) . ?
O7 Eu1 2.394(3) 2_545 ?
O8 C16 1.256(5) . ?
O8 Eu1 2.377(3) 4_565 ?
O8 Eu1 3.100(3) 2_545 ?
O9 C17 1.268(5) . ?
O10 C17 1.246(5) . ?
O11 C24 1.267(5) . ?
N1 C25 1.321(6) . ?
N1 C36 1.362(5) . ?
N2 C34 1.325(6) . ?
N2 C35 1.364(6) . ?
N3 C46 1.323(6) . ?
N3 C47 1.362(5) . ?
N4 C37 1.308(6) . ?
N4 C48 1.359(6) . ?
C1 C2 1.504(6) . ?
C2 C3 1.389(6) . ?
C2 C7 1.390(6) . ?
C3 C4 1.382(6) . ?
C4 C5 1.379(6) . ?
C5 C6 1.390(6) . ?
C6 C7 1.388(6) . ?
C6 C8 1.505(6) . ?
C9 C10 1.510(6) . ?
C10 C11 1.385(6) . ?
C10 C15 1.393(5) . ?
C11 C12 1.387(6) . ?
C12 C13 1.384(6) . ?
C13 C14 1.374(6) . ?
C14 C15 1.386(6) . ?
C14 C16 1.515(6) . ?
C16 Eu1 3.112(5) 2_545 ?
C17 C18 1.519(6) . ?
C18 C23 1.383(6) . ?
C18 C19 1.398(6) . ?
C19 C20 1.368(6) . ?
C20 C21 1.384(6) . ?
C21 C22 1.388(6) . ?
C22 C23 1.400(6) . ?
C22 C24 1.500(6) . ?
C24 O12 1.254(5) . ?
C25 C26 1.399(7) . ?
C26 C27 1.352(7) . ?
C27 C28 1.390(7) . ?
C28 C36 1.415(6) . ?
C28 C29 1.441(7) . ?
C29 C30 1.333(7) . ?
C30 C31 1.428(7) . ?
C31 C32 1.390(7) . ?
C31 C35 1.412(6) . ?
C32 C33 1.362(8) . ?
C33 C34 1.393(7) . ?
C35 C36 1.426(6) . ?
C37 C38 1.385(6) . ?
C38 C39 1.357(8) . ?
C39 C40 1.405(7) . ?
C40 C48 1.417(6) . ?
C40 C41 1.429(7) . ?
C41 C42 1.338(7) . ?
C42 C43 1.430(7) . ?
C43 C44 1.398(7) . ?
C43 C47 1.413(6) . ?
C44 C45 1.356(7) . ?
C45 C46 1.393(7) . ?
C47 C48 1.433(6) . ?
O12 Eu1 2.355(3) 3_566 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 Eu2 O1 C1 10.5(4) 3_676 . . . ?
O4 Eu2 O1 C1 139.3(4) 1_545 . . . ?
O9 Eu2 O1 C1 164.6(4) . . . . ?
O14 Eu2 O1 C1 89.0(4) . . . . ?
O13 Eu2 O1 C1 -43.7(5) . . . . ?
N3 Eu2 O1 C1 -127.2(4) . . . . ?
N4 Eu2 O1 C1 -69.0(4) . . . . ?
O12 Eu1 O5 C9 -5.6(3) 3_566 . . . ?
O8 Eu1 O5 C9 131.4(3) 4_566 . . . ?
O11 Eu1 O5 C9 -155.3(3) . . . . ?
O7 Eu1 O5 C9 -80.7(3) 2 . . . ?
O6 Eu1 O5 C9 -1.1(2) . . . . ?
N2 Eu1 O5 C9 67.3(3) . . . . ?
N1 Eu1 O5 C9 131.0(3) . . . . ?
O8 Eu1 O5 C9 -89.0(3) 2 . . . ?
C16 Eu1 O5 C9 -84.0(3) 2 . . . ?
Eu1 Eu1 O5 C9 -112.6(2) 3_566 . . . ?
O12 Eu1 O6 C9 177.5(3) 3_566 . . . ?
O8 Eu1 O6 C9 -141.8(3) 4_566 . . . ?
O11 Eu1 O6 C9 41.5(3) . . . . ?
O7 Eu1 O6 C9 86.3(3) 2 . . . ?
O5 Eu1 O6 C9 1.2(2) . . . . ?
N2 Eu1 O6 C9 -97.7(3) . . . . ?
N1 Eu1 O6 C9 -47.5(3) . . . . ?
O8 Eu1 O6 C9 117.7(3) 2 . . . ?
C16 Eu1 O6 C9 101.8(3) 2 . . . ?
Eu1 Eu1 O6 C9 145.4(2) 3_566 . . . ?
O2 Eu2 O9 C17 -10.1(5) 3_676 . . . ?
O1 Eu2 O9 C17 -63.3(4) . . . . ?
O4 Eu2 O9 C17 104.5(4) 1_545 . . . ?
O14 Eu2 O9 C17 24.5(4) . . . . ?
O13 Eu2 O9 C17 142.1(4) . . . . ?
N3 Eu2 O9 C17 -168.5(4) . . . . ?
N4 Eu2 O9 C17 -125.5(4) . . . . ?
O12 Eu1 O11 C24 31.6(4) 3_566 . . . ?
O8 Eu1 O11 C24 -29.3(4) 4_566 . . . ?
O7 Eu1 O11 C24 104.4(4) 2 . . . ?
O5 Eu1 O11 C24 179.7(4) . . . . ?
O6 Eu1 O11 C24 148.7(3) . . . . ?
N2 Eu1 O11 C24 -96.1(4) . . . . ?
N1 Eu1 O11 C24 -108.8(4) . . . . ?
C9 Eu1 O11 C24 167.8(4) . . . . ?
O8 Eu1 O11 C24 57.3(4) 2 . . . ?
C16 Eu1 O11 C24 82.1(4) 2 . . . ?
Eu1 Eu1 O11 C24 19.7(4) 3_566 . . . ?
O12 Eu1 N1 C25 -142.9(3) 3_566 . . . ?
O8 Eu1 N1 C25 -90.1(4) 4_566 . . . ?
O11 Eu1 N1 C25 -7.5(3) . . . . ?
O7 Eu1 N1 C25 42.4(4) 2 . . . ?
O5 Eu1 N1 C25 89.6(4) . . . . ?
O6 Eu1 N1 C25 128.4(4) . . . . ?
N2 Eu1 N1 C25 -177.9(4) . . . . ?
C9 Eu1 N1 C25 109.3(4) . . . . ?
O8 Eu1 N1 C25 -28.5(4) 2 . . . ?
C16 Eu1 N1 C25 10.4(5) 2 . . . ?
Eu1 Eu1 N1 C25 -62.4(4) 3_566 . . . ?
O12 Eu1 N1 C36 37.3(4) 3_566 . . . ?
O8 Eu1 N1 C36 90.1(3) 4_566 . . . ?
O11 Eu1 N1 C36 172.7(3) . . . . ?
O7 Eu1 N1 C36 -137.5(3) 2 . . . ?
O5 Eu1 N1 C36 -90.2(3) . . . . ?
O6 Eu1 N1 C36 -51.4(3) . . . . ?
N2 Eu1 N1 C36 2.2(3) . . . . ?
C9 Eu1 N1 C36 -70.5(3) . . . . ?
O8 Eu1 N1 C36 151.7(3) 2 . . . ?
C16 Eu1 N1 C36 -169.4(3) 2 . . . ?
Eu1 Eu1 N1 C36 117.8(3) 3_566 . . . ?
O12 Eu1 N2 C34 22.5(4) 3_566 . . . ?
O8 Eu1 N2 C34 99.4(4) 4_566 . . . ?
O11 Eu1 N2 C34 165.3(4) . . . . ?
O7 Eu1 N2 C34 -48.9(5) 2 . . . ?
O5 Eu1 N2 C34 -107.5(4) . . . . ?
O6 Eu1 N2 C34 -55.2(4) . . . . ?
N1 Eu1 N2 C34 179.0(4) . . . . ?
C9 Eu1 N2 C34 -82.3(4) . . . . ?
O8 Eu1 N2 C34 33.9(5) 2 . . . ?
C16 Eu1 N2 C34 -11.1(5) 2 . . . ?
Eu1 Eu1 N2 C34 72.4(4) 3_566 . . . ?
O12 Eu1 N2 C35 -159.6(4) 3_566 . . . ?
O8 Eu1 N2 C35 -82.7(3) 4_566 . . . ?
O11 Eu1 N2 C35 -16.8(4) . . . . ?
O7 Eu1 N2 C35 129.0(3) 2 . . . ?
O5 Eu1 N2 C35 70.4(3) . . . . ?
O6 Eu1 N2 C35 122.7(4) . . . . ?
N1 Eu1 N2 C35 -3.1(3) . . . . ?
C9 Eu1 N2 C35 95.6(4) . . . . ?
O8 Eu1 N2 C35 -148.2(3) 2 . . . ?
C16 Eu1 N2 C35 166.8(3) 2 . . . ?
Eu1 Eu1 N2 C35 -109.7(3) 3_566 . . . ?
O2 Eu2 N3 C46 152.4(3) 3_676 . . . ?
O1 Eu2 N3 C46 -119.3(4) . . . . ?
O4 Eu2 N3 C46 32.2(4) 1_545 . . . ?
O9 Eu2 N3 C46 -45.0(3) . . . . ?
O14 Eu2 N3 C46 -23.4(4) . . . . ?
O13 Eu2 N3 C46 101.6(4) . . . . ?
N4 Eu2 N3 C46 176.2(4) . . . . ?
O2 Eu2 N3 C47 -32.5(4) 3_676 . . . ?
O1 Eu2 N3 C47 55.9(3) . . . . ?
O4 Eu2 N3 C47 -152.7(3) 1_545 . . . ?
O9 Eu2 N3 C47 130.2(3) . . . . ?
O14 Eu2 N3 C47 151.7(3) . . . . ?
O13 Eu2 N3 C47 -83.3(3) . . . . ?
N4 Eu2 N3 C47 -8.7(3) . . . . ?
O2 Eu2 N4 C37 -14.6(4) 3_676 . . . ?
O1 Eu2 N4 C37 70.0(4) . . . . ?
O4 Eu2 N4 C37 -127.5(4) 1_545 . . . ?
O9 Eu2 N4 C37 135.5(4) . . . . ?
O14 Eu2 N4 C37 24.0(5) . . . . ?
O13 Eu2 N4 C37 -93.1(4) . . . . ?
N3 Eu2 N4 C37 -178.6(4) . . . . ?
O2 Eu2 N4 C48 172.1(3) 3_676 . . . ?
O1 Eu2 N4 C48 -103.3(3) . . . . ?
O4 Eu2 N4 C48 59.2(4) 1_545 . . . ?
O9 Eu2 N4 C48 -37.8(4) . . . . ?
O14 Eu2 N4 C48 -149.4(3) . . . . ?
O13 Eu2 N4 C48 93.6(3) . . . . ?
N3 Eu2 N4 C48 8.1(3) . . . . ?
Eu2 O2 C1 O1 123.9(5) 3_676 . . . ?
Eu2 O2 C1 C2 -55.9(7) 3_676 . . . ?
Eu2 O1 C1 O2 -56.5(7) . . . . ?
Eu2 O1 C1 C2 123.3(4) . . . . ?
O2 C1 C2 C3 163.0(4) . . . . ?
O1 C1 C2 C3 -16.8(6) . . . . ?
O2 C1 C2 C7 -15.0(6) . . . . ?
O1 C1 C2 C7 165.2(4) . . . . ?
C7 C2 C3 C4 0.8(7) . . . . ?
C1 C2 C3 C4 -177.2(4) . . . . ?
C2 C3 C4 C5 -0.1(7) . . . . ?
C3 C4 C5 C6 -0.9(7) . . . . ?
C4 C5 C6 C7 1.2(7) . . . . ?
C4 C5 C6 C8 -178.6(4) . . . . ?
C3 C2 C7 C6 -0.5(6) . . . . ?
C1 C2 C7 C6 177.6(4) . . . . ?
C5 C6 C7 C2 -0.5(7) . . . . ?
C8 C6 C7 C2 179.3(4) . . . . ?
Eu2 O4 C8 O3 -3.4(8) 1_565 . . . ?
Eu2 O4 C8 C6 177.2(3) 1_565 . . . ?
C7 C6 C8 O3 -19.0(7) . . . . ?
C5 C6 C8 O3 160.8(5) . . . . ?
C7 C6 C8 O4 160.5(4) . . . . ?
C5 C6 C8 O4 -19.7(7) . . . . ?
Eu1 O6 C9 O5 -2.1(4) . . . . ?
Eu1 O6 C9 C10 177.9(3) . . . . ?
Eu1 O5 C9 O6 2.1(5) . . . . ?
Eu1 O5 C9 C10 -177.8(3) . . . . ?
O12 Eu1 C9 O6 -2.4(3) 3_566 . . . ?
O8 Eu1 C9 O6 78.3(4) 4_566 . . . ?
O11 Eu1 C9 O6 -150.3(2) . . . . ?
O7 Eu1 C9 O6 -85.8(3) 2 . . . ?
O5 Eu1 C9 O6 -177.9(4) . . . . ?
N2 Eu1 C9 O6 73.9(3) . . . . ?
N1 Eu1 C9 O6 135.9(3) . . . . ?
O8 Eu1 C9 O6 -72.2(3) 2 . . . ?
C16 Eu1 C9 O6 -79.0(3) 2 . . . ?
Eu1 Eu1 C9 O6 -59.3(3) 3_566 . . . ?
O12 Eu1 C9 O5 175.5(2) 3_566 . . . ?
O8 Eu1 C9 O5 -103.8(4) 4_566 . . . ?
O11 Eu1 C9 O5 27.7(3) . . . . ?
O7 Eu1 C9 O5 92.1(3) 2 . . . ?
O6 Eu1 C9 O5 177.9(4) . . . . ?
N2 Eu1 C9 O5 -108.1(3) . . . . ?
N1 Eu1 C9 O5 -46.1(3) . . . . ?
O8 Eu1 C9 O5 105.8(3) 2 . . . ?
C16 Eu1 C9 O5 98.9(3) 2 . . . ?
Eu1 Eu1 C9 O5 118.7(2) 3_566 . . . ?
O12 Eu1 C9 C10 -132(8) 3_566 . . . ?
O8 Eu1 C9 C10 -51(8) 4_566 . . . ?
O11 Eu1 C9 C10 80(8) . . . . ?
O7 Eu1 C9 C10 145(8) 2 . . . ?
O5 Eu1 C9 C10 53(8) . . . . ?
O6 Eu1 C9 C10 -129(8) . . . . ?
N2 Eu1 C9 C10 -55(8) . . . . ?
N1 Eu1 C9 C10 7(8) . . . . ?
O8 Eu1 C9 C10 158(8) 2 . . . ?
C16 Eu1 C9 C10 152(8) 2 . . . ?
Eu1 Eu1 C9 C10 171(8) 3_566 . . . ?
O6 C9 C10 C11 157.3(4) . . . . ?
O5 C9 C10 C11 -22.7(6) . . . . ?
Eu1 C9 C10 C11 -74(8) . . . . ?
O6 C9 C10 C15 -22.3(6) . . . . ?
O5 C9 C10 C15 157.6(4) . . . . ?
Eu1 C9 C10 C15 106(8) . . . . ?
C15 C10 C11 C12 0.7(7) . . . . ?
C9 C10 C11 C12 -179.0(4) . . . . ?
C10 C11 C12 C13 -0.1(8) . . . . ?
C11 C12 C13 C14 -1.7(8) . . . . ?
C12 C13 C14 C15 2.9(7) . . . . ?
C12 C13 C14 C16 -174.3(4) . . . . ?
C13 C14 C15 C10 -2.3(6) . . . . ?
C16 C14 C15 C10 174.9(4) . . . . ?
C11 C10 C15 C14 0.5(6) . . . . ?
C9 C10 C15 C14 -179.8(4) . . . . ?
Eu1 O8 C16 O7 55(2) 4_565 . . . ?
Eu1 O8 C16 O7 -1.8(4) 2_545 . . . ?
Eu1 O8 C16 C14 -128(2) 4_565 . . . ?
Eu1 O8 C16 C14 175.6(4) 2_545 . . . ?
Eu1 O8 C16 Eu1 56(2) 4_565 . . 2_545 ?
Eu1 O7 C16 O8 2.5(5) 2_545 . . . ?
Eu1 O7 C16 C14 -175.0(3) 2_545 . . . ?
C13 C14 C16 O8 -1.0(6) . . . . ?
C15 C14 C16 O8 -178.1(4) . . . . ?
C13 C14 C16 O7 176.6(4) . . . . ?
C15 C14 C16 O7 -0.6(6) . . . . ?
C13 C14 C16 Eu1 165.2(7) . . . 2_545 ?
C15 C14 C16 Eu1 -12.0(11) . . . 2_545 ?
Eu2 O9 C17 O10 -2.8(7) . . . . ?
Eu2 O9 C17 C18 176.5(3) . . . . ?
O10 C17 C18 C23 -160.0(4) . . . . ?
O9 C17 C18 C23 20.6(6) . . . . ?
O10 C17 C18 C19 21.9(6) . . . . ?
O9 C17 C18 C19 -157.4(4) . . . . ?
C23 C18 C19 C20 -2.2(7) . . . . ?
C17 C18 C19 C20 175.9(4) . . . . ?
C18 C19 C20 C21 1.4(7) . . . . ?
C19 C20 C21 C22 1.0(7) . . . . ?
C20 C21 C22 C23 -2.5(6) . . . . ?
C20 C21 C22 C24 175.6(4) . . . . ?
C19 C18 C23 C22 0.7(6) . . . . ?
C17 C18 C23 C22 -177.4(4) . . . . ?
C21 C22 C23 C18 1.6(6) . . . . ?
C24 C22 C23 C18 -176.4(4) . . . . ?
Eu1 O11 C24 O12 -20.4(7) . . . . ?
Eu1 O11 C24 C22 158.7(3) . . . . ?
C21 C22 C24 O12 8.8(6) . . . . ?
C23 C22 C24 O12 -173.2(4) . . . . ?
C21 C22 C24 O11 -170.3(4) . . . . ?
C23 C22 C24 O11 7.7(6) . . . . ?
C36 N1 C25 C26 -1.5(7) . . . . ?
Eu1 N1 C25 C26 178.7(4) . . . . ?
N1 C25 C26 C27 0.2(8) . . . . ?
C25 C26 C27 C28 1.5(8) . . . . ?
C26 C27 C28 C36 -1.7(7) . . . . ?
C26 C27 C28 C29 176.9(5) . . . . ?
C27 C28 C29 C30 179.6(5) . . . . ?
C36 C28 C29 C30 -1.8(8) . . . . ?
C28 C29 C30 C31 -2.4(9) . . . . ?
C29 C30 C31 C32 -176.1(6) . . . . ?
C29 C30 C31 C35 4.1(8) . . . . ?
C35 C31 C32 C33 -0.7(9) . . . . ?
C30 C31 C32 C33 179.6(6) . . . . ?
C31 C32 C33 C34 1.1(10) . . . . ?
C35 N2 C34 C33 0.1(8) . . . . ?
Eu1 N2 C34 C33 178.0(5) . . . . ?
C32 C33 C34 N2 -0.8(10) . . . . ?
C34 N2 C35 C31 0.3(7) . . . . ?
Eu1 N2 C35 C31 -177.6(3) . . . . ?
C34 N2 C35 C36 -178.3(4) . . . . ?
Eu1 N2 C35 C36 3.7(5) . . . . ?
C32 C31 C35 N2 0.0(7) . . . . ?
C30 C31 C35 N2 179.7(5) . . . . ?
C32 C31 C35 C36 178.6(5) . . . . ?
C30 C31 C35 C36 -1.6(7) . . . . ?
C25 N1 C36 C28 1.1(6) . . . . ?
Eu1 N1 C36 C28 -179.1(3) . . . . ?
C25 N1 C36 C35 178.7(4) . . . . ?
Eu1 N1 C36 C35 -1.4(5) . . . . ?
C27 C28 C36 N1 0.5(7) . . . . ?
C29 C28 C36 N1 -178.3(4) . . . . ?
C27 C28 C36 C35 -177.2(4) . . . . ?
C29 C28 C36 C35 4.1(7) . . . . ?
N2 C35 C36 N1 -1.4(6) . . . . ?
C31 C35 C36 N1 179.9(4) . . . . ?
N2 C35 C36 C28 176.3(4) . . . . ?
C31 C35 C36 C28 -2.4(7) . . . . ?
C48 N4 C37 C38 2.0(8) . . . . ?
Eu2 N4 C37 C38 -171.4(4) . . . . ?
N4 C37 C38 C39 -0.2(9) . . . . ?
C37 C38 C39 C40 -1.9(9) . . . . ?
C38 C39 C40 C48 2.2(8) . . . . ?
C38 C39 C40 C41 -179.4(5) . . . . ?
C39 C40 C41 C42 -179.4(6) . . . . ?
C48 C40 C41 C42 -1.0(9) . . . . ?
C40 C41 C42 C43 0.0(9) . . . . ?
C41 C42 C43 C44 -175.8(6) . . . . ?
C41 C42 C43 C47 1.5(9) . . . . ?
C47 C43 C44 C45 1.3(8) . . . . ?
C42 C43 C44 C45 178.6(5) . . . . ?
C43 C44 C45 C46 0.7(8) . . . . ?
C47 N3 C46 C45 -0.8(7) . . . . ?
Eu2 N3 C46 C45 174.4(4) . . . . ?
C44 C45 C46 N3 -1.0(8) . . . . ?
C46 N3 C47 C43 2.9(7) . . . . ?
Eu2 N3 C47 C43 -172.4(3) . . . . ?
C46 N3 C47 C48 -175.8(4) . . . . ?
Eu2 N3 C47 C48 8.8(5) . . . . ?
C44 C43 C47 N3 -3.2(7) . . . . ?
C42 C43 C47 N3 179.4(5) . . . . ?
C44 C43 C47 C48 175.5(5) . . . . ?
C42 C43 C47 C48 -1.9(7) . . . . ?
C37 N4 C48 C40 -1.5(7) . . . . ?
Eu2 N4 C48 C40 172.2(3) . . . . ?
C37 N4 C48 C47 178.9(4) . . . . ?
Eu2 N4 C48 C47 -7.4(6) . . . . ?
C39 C40 C48 N4 -0.5(7) . . . . ?
C41 C40 C48 N4 -179.0(5) . . . . ?
C39 C40 C48 C47 179.1(5) . . . . ?
C41 C40 C48 C47 0.6(7) . . . . ?
N3 C47 C48 N4 -0.8(7) . . . . ?
C43 C47 C48 N4 -179.6(4) . . . . ?
N3 C47 C48 C40 179.6(4) . . . . ?
C43 C47 C48 C40 0.9(7) . . . . ?
O11 C24 O12 Eu1 -4.9(8) . . . 3_566 ?
C22 C24 O12 Eu1 176.1(3) . . . 3_566 ?
