#------------------------------------------------------------------------------
#$Date: 2016-03-23 02:48:26 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179207 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/39/4313963.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4313963
loop_
_publ_author_name
'Yonghong Wan'
'Liping Zhang'
'Linpei Jin'
'Song Gao'
'Shaozhe Lu'
_publ_section_title
;
 High-Dimensional Architectures from the Self-Assembly of Lanthanide Ions
 with Benzenedicarboxylates and 1,10-Phenanthroline
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4985
_journal_page_last               4994
_journal_paper_doi               10.1021/ic034258c
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C24 H16 Eu N2 O7'
_chemical_formula_weight         596.35
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.660(7)
_cell_angle_beta                 91.787(7)
_cell_angle_gamma                112.946(6)
_cell_formula_units_Z            2
_cell_length_a                   10.331(5)
_cell_length_b                   10.887(5)
_cell_length_c                   11.404(5)
_cell_measurement_reflns_used    940
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.26
_cell_measurement_theta_min      3.12
_cell_volume                     1109.0(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0220
_diffrn_reflns_av_sigmaI/netI    0.0475
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            4514
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.90
_exptl_absorpt_coefficient_mu    2.877
_exptl_absorpt_correction_T_max  0.7618
_exptl_absorpt_correction_T_min  0.5969
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.786
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             586
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.858
_refine_diff_density_min         -0.843
_refine_diff_density_rms         0.193
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     315
_refine_ls_number_reflns         3826
_refine_ls_number_restraints     5
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.0420
_refine_ls_R_factor_gt           0.0353
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1001P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1296
_refine_ls_wR_factor_ref         0.1345
_reflns_number_gt                3397
_reflns_number_total             3826
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034258csi20030310_091045_3.cif
_cod_data_source_block           complex3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        1109.1(9)
_cod_database_code               4313963
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.58719(3) 0.99659(3) 0.82930(3) 0.01868(16) Uani 1 1 d D . .
O1 O 0.3458(6) 0.8202(6) 0.7708(5) 0.0352(13) Uani 1 1 d . . .
O2 O 0.2965(7) 0.8628(6) 0.9616(5) 0.0460(16) Uani 1 1 d . . .
O3 O -0.2619(6) 0.1929(6) 0.7767(5) 0.0360(13) Uani 1 1 d . . .
O4 O -0.3024(7) 0.2039(7) 0.5891(6) 0.0531(18) Uani 1 1 d . . .
O5 O 0.5865(7) 0.8094(6) 0.8986(5) 0.0375(14) Uani 1 1 d . . .
O6 O 0.5304(7) 0.8617(6) 1.0908(6) 0.0411(15) Uani 1 1 d . . .
O7 O 0.4615(6) 1.0091(6) 0.6436(5) 0.0325(12) Uani 1 1 d D . .
N1 N 0.6131(8) 0.8137(7) 0.6340(6) 0.0367(16) Uani 1 1 d . . .
N2 N 0.8442(7) 1.0028(7) 0.8142(8) 0.0410(18) Uani 1 1 d . . .
C1 C 0.2696(8) 0.7885(7) 0.8506(7) 0.0269(16) Uani 1 1 d . . .
C2 C 0.1405(7) 0.6497(7) 0.8072(6) 0.0229(15) Uani 1 1 d . . .
C3 C 0.1155(9) 0.5624(9) 0.8789(8) 0.040(2) Uani 1 1 d . . .
H3 H 0.1785 0.5907 0.9518 0.049 Uiso 1 1 calc R . .
C4 C -0.0039(8) 0.4324(8) 0.8415(7) 0.0342(19) Uani 1 1 d . . .
H4 H -0.0198 0.3738 0.8893 0.041 Uiso 1 1 calc R . .
C5 C -0.1010(8) 0.3894(7) 0.7314(7) 0.0240(15) Uani 1 1 d . . .
C6 C -0.2304(8) 0.2519(7) 0.6965(7) 0.0245(15) Uani 1 1 d . . .
C7 C -0.0727(8) 0.4762(9) 0.6610(7) 0.0350(19) Uani 1 1 d . . .
H7 H -0.1361 0.4491 0.5886 0.042 Uiso 1 1 calc R . .
C8 C 0.0479(9) 0.6031(8) 0.6951(8) 0.036(2) Uani 1 1 d . . .
H8 H 0.0675 0.6577 0.6436 0.044 Uiso 1 1 calc R . .
C9 C 0.5021(12) 0.7179(11) 0.5454(10) 0.058(3) Uani 1 1 d . . .
H9 H 0.4111 0.7086 0.5592 0.070 Uiso 1 1 calc R . .
C10 C 0.5162(17) 0.6332(15) 0.4355(11) 0.077(4) Uani 1 1 d . . .
H10 H 0.4348 0.5637 0.3794 0.093 Uiso 1 1 calc R . .
C11 C 0.646(2) 0.6480(18) 0.4061(10) 0.094(5) Uani 1 1 d . . .
H11 H 0.6545 0.5923 0.3294 0.113 Uiso 1 1 calc R . .
C12 C 0.7661(15) 0.7478(15) 0.4928(11) 0.070(4) Uani 1 1 d . . .
C13 C 0.914(2) 0.775(2) 0.4735(17) 0.107(6) Uani 1 1 d . . .
H13 H 0.9304 0.7254 0.3977 0.128 Uiso 1 1 calc R . .
C14 C 1.0230(18) 0.868(2) 0.5612(17) 0.092(5) Uani 1 1 d . . .
H14 H 1.1144 0.8831 0.5445 0.111 Uiso 1 1 calc R . .
C15 C 1.0082(12) 0.9479(14) 0.6816(13) 0.064(3) Uani 1 1 d . . .
C16 C 1.1219(12) 1.0435(17) 0.7810(15) 0.079(4) Uani 1 1 d . . .
H16 H 1.2155 1.0601 0.7705 0.095 Uiso 1 1 calc R . .
C17 C 1.0950(12) 1.1088(16) 0.8878(19) 0.095(5) Uani 1 1 d . . .
H17 H 1.1698 1.1683 0.9542 0.114 Uiso 1 1 calc R . .
C18 C 0.9537(10) 1.0902(12) 0.9038(13) 0.065(3) Uani 1 1 d . . .
H18 H 0.9383 1.1410 0.9795 0.078 Uiso 1 1 calc R . .
C19 C 0.8681(9) 0.9279(10) 0.7056(9) 0.040(2) Uani 1 1 d . . .
C20 C 0.7455(11) 0.8298(11) 0.6103(8) 0.044(2) Uani 1 1 d . . .
C61 C 0.5499(7) 0.7802(7) 0.9954(8) 0.0274(17) Uani 1 1 d . . .
C62 C 0.5244(8) 0.6339(7) 0.9984(6) 0.0222(14) Uani 1 1 d . . .
C63 C 0.5672(10) 0.5459(8) 0.9058(8) 0.0339(18) Uani 1 1 d . . .
H63 H 0.6118 0.5766 0.8439 0.041 Uiso 1 1 calc R . .
C64 C 0.5410(9) 0.4111(8) 0.9091(8) 0.0353(19) Uani 1 1 d . . .
H64 H 0.5678 0.3509 0.8483 0.042 Uiso 1 1 calc R . .
H1 H 0.436(9) 0.922(4) 0.581(3) 0.08(4) Uiso 1 1 d D . .
H2 H 0.534(3) 1.071(8) 0.616(6) 0.10(5) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Eu1 O3 84.2(2) 2_677 1_665 ?
O6 Eu1 O2 73.2(2) 2_677 2_677 ?
O3 Eu1 O2 85.7(2) 1_665 2_677 ?
O6 Eu1 O1 80.3(2) 2_677 . ?
O3 Eu1 O1 139.0(2) 1_665 . ?
O2 Eu1 O1 124.6(2) 2_677 . ?
O6 Eu1 O5 124.6(2) 2_677 . ?
O3 Eu1 O5 142.8(2) 1_665 . ?
O2 Eu1 O5 82.0(2) 2_677 . ?
O1 Eu1 O5 74.6(2) . . ?
O6 Eu1 O7 73.9(2) 2_677 . ?
O3 Eu1 O7 70.26(19) 1_665 . ?
O2 Eu1 O7 140.7(2) 2_677 . ?
O1 Eu1 O7 69.06(19) . . ?
O5 Eu1 O7 135.3(2) . . ?
O6 Eu1 N1 146.7(2) 2_677 . ?
O3 Eu1 N1 93.0(2) 1_665 . ?
O2 Eu1 N1 139.9(2) 2_677 . ?
O1 Eu1 N1 80.4(2) . . ?
O5 Eu1 N1 75.1(2) . . ?
O7 Eu1 N1 73.9(2) . . ?
O6 Eu1 N2 142.6(2) 2_677 . ?
O3 Eu1 N2 68.2(2) 1_665 . ?
O2 Eu1 N2 79.8(3) 2_677 . ?
O1 Eu1 N2 137.0(2) . . ?
O5 Eu1 N2 75.1(2) . . ?
O7 Eu1 N2 116.5(2) . . ?
N1 Eu1 N2 62.8(2) . . ?
O6 Eu1 C1 72.8(2) 2_677 . ?
O3 Eu1 C1 149.75(19) 1_665 . ?
O2 Eu1 C1 105.4(2) 2_677 . ?
O1 Eu1 C1 19.19(19) . . ?
O5 Eu1 C1 67.4(2) . . ?
O7 Eu1 C1 84.41(18) . . ?
N1 Eu1 C1 95.7(2) . . ?
N2 Eu1 C1 140.7(2) . . ?
O6 Eu1 Eu1 57.97(16) 2_677 2_677 ?
O3 Eu1 Eu1 127.66(15) 1_665 2_677 ?
O2 Eu1 Eu1 51.58(16) 2_677 2_677 ?
O1 Eu1 Eu1 73.06(14) . 2_677 ?
O5 Eu1 Eu1 67.70(15) . 2_677 ?
O7 Eu1 Eu1 122.35(13) . 2_677 ?
N1 Eu1 Eu1 138.70(17) . 2_677 ?
N2 Eu1 Eu1 120.95(18) . 2_677 ?
C1 Eu1 Eu1 53.99(14) . 2_677 ?
C1 O1 Eu1 122.2(5) . . ?
C1 O2 Eu1 163.5(6) . 2_677 ?
C6 O3 Eu1 148.6(5) . 1_445 ?
C61 O5 Eu1 130.9(5) . . ?
C61 O6 Eu1 146.9(6) . 2_677 ?
Eu1 O7 H1 105.9(16) . . ?
Eu1 O7 H2 103.9(16) . . ?
H1 O7 H2 102.6(15) . . ?
C9 N1 C20 117.7(8) . . ?
C9 N1 Eu1 122.3(6) . . ?
C20 N1 Eu1 119.1(6) . . ?
C18 N2 C19 118.5(8) . . ?
C18 N2 Eu1 121.8(7) . . ?
C19 N2 Eu1 119.2(6) . . ?
O2 C1 O1 124.2(7) . . ?
O2 C1 C2 118.3(7) . . ?
O1 C1 C2 117.4(7) . . ?
O2 C1 Eu1 86.9(5) . . ?
O1 C1 Eu1 38.7(4) . . ?
C2 C1 Eu1 152.2(5) . . ?
C3 C2 C8 119.3(7) . . ?
C3 C2 C1 118.5(7) . . ?
C8 C2 C1 122.2(6) . . ?
C2 C3 C4 120.1(7) . . ?
C2 C3 H3 120.0 . . ?
C4 C3 H3 120.0 . . ?
C3 C4 C5 120.3(7) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
C7 C5 C4 118.6(7) . . ?
C7 C5 C6 122.6(7) . . ?
C4 C5 C6 118.9(6) . . ?
O3 C6 O4 124.1(7) . . ?
O3 C6 C5 118.1(6) . . ?
O4 C6 C5 117.9(6) . . ?
C5 C7 C8 121.5(7) . . ?
C5 C7 H7 119.2 . . ?
C8 C7 H7 119.2 . . ?
C7 C8 C2 120.1(7) . . ?
C7 C8 H8 119.9 . . ?
C2 C8 H8 119.9 . . ?
N1 C9 C10 123.0(11) . . ?
N1 C9 H9 118.5 . . ?
C10 C9 H9 118.5 . . ?
C11 C10 C9 121.4(13) . . ?
C11 C10 H10 119.3 . . ?
C9 C10 H10 119.3 . . ?
C10 C11 C12 118.6(10) . . ?
C10 C11 H11 120.7 . . ?
C12 C11 H11 120.7 . . ?
C11 C12 C20 117.9(11) . . ?
C11 C12 C13 124.4(13) . . ?
C20 C12 C13 117.7(14) . . ?
C14 C13 C12 121.3(13) . . ?
C14 C13 H13 119.4 . . ?
C12 C13 H13 119.4 . . ?
C13 C14 C15 123.3(12) . . ?
C13 C14 H14 118.4 . . ?
C15 C14 H14 118.4 . . ?
C16 C15 C19 116.6(11) . . ?
C16 C15 C14 125.2(12) . . ?
C19 C15 C14 118.2(13) . . ?
C17 C16 C15 119.7(11) . . ?
C17 C16 H16 120.2 . . ?
C15 C16 H16 120.2 . . ?
C16 C17 C18 121.1(14) . . ?
C16 C17 H17 119.5 . . ?
C18 C17 H17 119.5 . . ?
N2 C18 C17 121.5(13) . . ?
N2 C18 H18 119.2 . . ?
C17 C18 H18 119.2 . . ?
N2 C19 C15 122.3(10) . . ?
N2 C19 C20 117.3(7) . . ?
C15 C19 C20 120.3(9) . . ?
N1 C20 C12 121.3(10) . . ?
N1 C20 C19 119.5(8) . . ?
C12 C20 C19 119.2(9) . . ?
O6 C61 O5 125.6(7) . . ?
O6 C61 C62 115.8(7) . . ?
O5 C61 C62 118.6(6) . . ?
C64 C62 C63 121.0(7) 2_667 . ?
C64 C62 C61 119.9(6) 2_667 . ?
C63 C62 C61 119.1(6) . . ?
C64 C63 C62 118.3(7) . . ?
C64 C63 H63 120.9 . . ?
C62 C63 H63 120.9 . . ?
C62 C64 C63 120.7(7) 2_667 . ?
C62 C64 H64 119.6 2_667 . ?
C63 C64 H64 119.6 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O6 2.317(6) 2_677 ?
Eu1 O3 2.366(5) 1_665 ?
Eu1 O2 2.376(6) 2_677 ?
Eu1 O1 2.396(5) . ?
Eu1 O5 2.397(5) . ?
Eu1 O7 2.516(5) . ?
Eu1 N1 2.600(6) . ?
Eu1 N2 2.642(7) . ?
Eu1 C1 3.247(7) . ?
Eu1 Eu1 4.3331(18) 2_677 ?
O1 C1 1.261(9) . ?
O2 C1 1.232(10) . ?
O2 Eu1 2.376(6) 2_677 ?
O3 C6 1.252(9) . ?
O3 Eu1 2.366(5) 1_445 ?
O4 C6 1.257(10) . ?
O5 C61 1.269(10) . ?
O6 C61 1.256(10) . ?
O6 Eu1 2.317(6) 2_677 ?
O7 H1 0.928(10) . ?
O7 H2 0.930(11) . ?
N1 C9 1.334(12) . ?
N1 C20 1.356(11) . ?
N2 C18 1.315(14) . ?
N2 C19 1.350(12) . ?
C1 C2 1.497(10) . ?
C2 C3 1.389(11) . ?
C2 C8 1.399(10) . ?
C3 C4 1.395(11) . ?
C3 H3 0.9300 . ?
C4 C5 1.414(10) . ?
C4 H4 0.9300 . ?
C5 C7 1.372(10) . ?
C5 C6 1.494(10) . ?
C7 C8 1.384(10) . ?
C7 H7 0.9300 . ?
C8 H8 0.9300 . ?
C9 C10 1.363(15) . ?
C9 H9 0.9300 . ?
C10 C11 1.35(2) . ?
C10 H10 0.9300 . ?
C11 C12 1.38(2) . ?
C11 H11 0.9300 . ?
C12 C20 1.442(13) . ?
C12 C13 1.48(2) . ?
C13 C14 1.31(2) . ?
C13 H13 0.9300 . ?
C14 C15 1.43(2) . ?
C14 H14 0.9300 . ?
C15 C16 1.41(2) . ?
C15 C19 1.425(13) . ?
C16 C17 1.31(2) . ?
C16 H16 0.9300 . ?
C17 C18 1.419(16) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C20 1.443(14) . ?
C61 C62 1.521(9) . ?
C62 C64 1.382(11) 2_667 ?
C62 C63 1.405(10) . ?
C63 C64 1.398(10) . ?
C63 H63 0.9300 . ?
C64 C62 1.382(11) 2_667 ?
C64 H64 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O6 Eu1 O1 C1 -65.1(6) 2_677 . . . ?
O3 Eu1 O1 C1 -134.3(6) 1_665 . . . ?
O2 Eu1 O1 C1 -3.5(7) 2_677 . . . ?
O5 Eu1 O1 C1 65.1(6) . . . . ?
O7 Eu1 O1 C1 -141.5(6) . . . . ?
N1 Eu1 O1 C1 142.2(6) . . . . ?
N2 Eu1 O1 C1 111.7(6) . . . . ?
Eu1 Eu1 O1 C1 -5.8(5) 2_677 . . . ?
O6 Eu1 O5 C61 -14.6(8) 2_677 . . . ?
O3 Eu1 O5 C61 120.4(7) 1_665 . . . ?
O2 Eu1 O5 C61 48.5(7) 2_677 . . . ?
O1 Eu1 O5 C61 -80.8(7) . . . . ?
O7 Eu1 O5 C61 -117.2(7) . . . . ?
N1 Eu1 O5 C61 -164.7(7) . . . . ?
N2 Eu1 O5 C61 130.1(7) . . . . ?
C1 Eu1 O5 C61 -62.0(7) . . . . ?
Eu1 Eu1 O5 C61 -3.1(6) 2_677 . . . ?
O6 Eu1 N1 C9 -33.8(10) 2_677 . . . ?
O3 Eu1 N1 C9 -117.7(8) 1_665 . . . ?
O2 Eu1 N1 C9 155.5(7) 2_677 . . . ?
O1 Eu1 N1 C9 21.6(8) . . . . ?
O5 Eu1 N1 C9 98.0(8) . . . . ?
O7 Eu1 N1 C9 -49.3(8) . . . . ?
N2 Eu1 N1 C9 178.7(9) . . . . ?
C1 Eu1 N1 C9 33.3(8) . . . . ?
Eu1 Eu1 N1 C9 71.8(8) 2_677 . . . ?
O6 Eu1 N1 C20 135.2(6) 2_677 . . . ?
O3 Eu1 N1 C20 51.2(6) 1_665 . . . ?
O2 Eu1 N1 C20 -35.6(8) 2_677 . . . ?
O1 Eu1 N1 C20 -169.5(7) . . . . ?
O5 Eu1 N1 C20 -93.0(6) . . . . ?
O7 Eu1 N1 C20 119.7(7) . . . . ?
N2 Eu1 N1 C20 -12.4(6) . . . . ?
C1 Eu1 N1 C20 -157.8(6) . . . . ?
Eu1 Eu1 N1 C20 -119.3(6) 2_677 . . . ?
O6 Eu1 N2 C18 32.0(10) 2_677 . . . ?
O3 Eu1 N2 C18 77.3(8) 1_665 . . . ?
O2 Eu1 N2 C18 -12.0(8) 2_677 . . . ?
O1 Eu1 N2 C18 -142.8(8) . . . . ?
O5 Eu1 N2 C18 -96.4(8) . . . . ?
O7 Eu1 N2 C18 130.1(8) . . . . ?
N1 Eu1 N2 C18 -177.1(9) . . . . ?
C1 Eu1 N2 C18 -114.0(8) . . . . ?
Eu1 Eu1 N2 C18 -44.5(8) 2_677 . . . ?
O6 Eu1 N2 C19 -139.4(6) 2_677 . . . ?
O3 Eu1 N2 C19 -94.1(6) 1_665 . . . ?
O2 Eu1 N2 C19 176.6(6) 2_677 . . . ?
O1 Eu1 N2 C19 45.7(7) . . . . ?
O5 Eu1 N2 C19 92.2(6) . . . . ?
O7 Eu1 N2 C19 -41.3(6) . . . . ?
N1 Eu1 N2 C19 11.5(6) . . . . ?
C1 Eu1 N2 C19 74.6(7) . . . . ?
Eu1 Eu1 N2 C19 144.1(6) 2_677 . . . ?
Eu1 O2 C1 O1 -52(2) 2_677 . . . ?
Eu1 O2 C1 C2 126.7(17) 2_677 . . . ?
Eu1 O2 C1 Eu1 -41.0(19) 2_677 . . . ?
Eu1 O1 C1 O2 17.1(11) . . . . ?
Eu1 O1 C1 C2 -161.2(5) . . . . ?
O6 Eu1 C1 O2 -55.3(5) 2_677 . . . ?
O3 Eu1 C1 O2 -97.4(6) 1_665 . . . ?
O2 Eu1 C1 O2 11.1(6) 2_677 . . . ?
O1 Eu1 C1 O2 -165.9(9) . . . . ?
O5 Eu1 C1 O2 85.4(5) . . . . ?
O7 Eu1 C1 O2 -130.1(5) . . . . ?
N1 Eu1 C1 O2 156.7(5) . . . . ?
N2 Eu1 C1 O2 103.9(6) . . . . ?
Eu1 Eu1 C1 O2 7.2(4) 2_677 . . . ?
O6 Eu1 C1 O1 110.6(6) 2_677 . . . ?
O3 Eu1 C1 O1 68.5(7) 1_665 . . . ?
O2 Eu1 C1 O1 177.1(6) 2_677 . . . ?
O5 Eu1 C1 O1 -108.7(6) . . . . ?
O7 Eu1 C1 O1 35.8(6) . . . . ?
N1 Eu1 C1 O1 -37.4(6) . . . . ?
N2 Eu1 C1 O1 -90.2(7) . . . . ?
Eu1 Eu1 C1 O1 173.2(6) 2_677 . . . ?
O6 Eu1 C1 C2 148.4(11) 2_677 . . . ?
O3 Eu1 C1 C2 106.3(11) 1_665 . . . ?
O2 Eu1 C1 C2 -145.2(10) 2_677 . . . ?
O1 Eu1 C1 C2 37.7(10) . . . . ?
O5 Eu1 C1 C2 -70.9(10) . . . . ?
O7 Eu1 C1 C2 73.5(11) . . . . ?
N1 Eu1 C1 C2 0.4(11) . . . . ?
N2 Eu1 C1 C2 -52.4(12) . . . . ?
Eu1 Eu1 C1 C2 -149.1(11) 2_677 . . . ?
O2 C1 C2 C3 -45.1(11) . . . . ?
O1 C1 C2 C3 133.4(8) . . . . ?
Eu1 C1 C2 C3 107.8(11) . . . . ?
O2 C1 C2 C8 137.4(9) . . . . ?
O1 C1 C2 C8 -44.2(11) . . . . ?
Eu1 C1 C2 C8 -69.7(14) . . . . ?
C8 C2 C3 C4 -2.6(13) . . . . ?
C1 C2 C3 C4 179.8(8) . . . . ?
C2 C3 C4 C5 -0.7(14) . . . . ?
C3 C4 C5 C7 1.8(13) . . . . ?
C3 C4 C5 C6 -177.9(8) . . . . ?
Eu1 O3 C6 O4 4.7(16) 1_445 . . . ?
Eu1 O3 C6 C5 -176.8(7) 1_445 . . . ?
C7 C5 C6 O3 -166.8(8) . . . . ?
C4 C5 C6 O3 13.0(11) . . . . ?
C7 C5 C6 O4 11.9(12) . . . . ?
C4 C5 C6 O4 -168.4(8) . . . . ?
C4 C5 C7 C8 0.3(13) . . . . ?
C6 C5 C7 C8 -180.0(8) . . . . ?
C5 C7 C8 C2 -3.5(14) . . . . ?
C3 C2 C8 C7 4.6(13) . . . . ?
C1 C2 C8 C7 -177.8(8) . . . . ?
C20 N1 C9 C10 2.6(16) . . . . ?
Eu1 N1 C9 C10 171.7(9) . . . . ?
N1 C9 C10 C11 -4(2) . . . . ?
C9 C10 C11 C12 3(2) . . . . ?
C10 C11 C12 C20 1(2) . . . . ?
C10 C11 C12 C13 179.9(14) . . . . ?
C11 C12 C13 C14 -177.7(16) . . . . ?
C20 C12 C13 C14 2(2) . . . . ?
C12 C13 C14 C15 1(3) . . . . ?
C13 C14 C15 C16 176.6(15) . . . . ?
C13 C14 C15 C19 -2(2) . . . . ?
C19 C15 C16 C17 -0.4(19) . . . . ?
C14 C15 C16 C17 -178.9(13) . . . . ?
C15 C16 C17 C18 -3(2) . . . . ?
C19 N2 C18 C17 1.2(16) . . . . ?
Eu1 N2 C18 C17 -170.3(10) . . . . ?
C16 C17 C18 N2 3(2) . . . . ?
C18 N2 C19 C15 -4.7(13) . . . . ?
Eu1 N2 C19 C15 167.0(7) . . . . ?
C18 N2 C19 C20 178.3(9) . . . . ?
Eu1 N2 C19 C20 -10.0(10) . . . . ?
C16 C15 C19 N2 4.4(14) . . . . ?
C14 C15 C19 N2 -177.0(10) . . . . ?
C16 C15 C19 C20 -178.7(10) . . . . ?
C14 C15 C19 C20 -0.1(14) . . . . ?
C9 N1 C20 C12 0.8(14) . . . . ?
Eu1 N1 C20 C12 -168.7(8) . . . . ?
C9 N1 C20 C19 -177.4(9) . . . . ?
Eu1 N1 C20 C19 13.2(11) . . . . ?
C11 C12 C20 N1 -2.3(17) . . . . ?
C13 C12 C20 N1 178.3(11) . . . . ?
C11 C12 C20 C19 175.9(11) . . . . ?
C13 C12 C20 C19 -3.5(16) . . . . ?
N2 C19 C20 N1 -2.0(12) . . . . ?
C15 C19 C20 N1 -179.0(8) . . . . ?
N2 C19 C20 C12 179.9(9) . . . . ?
C15 C19 C20 C12 2.8(14) . . . . ?
Eu1 O6 C61 O5 54.4(13) 2_677 . . . ?
Eu1 O6 C61 C62 -124.7(8) 2_677 . . . ?
Eu1 O5 C61 O6 -14.8(12) . . . . ?
Eu1 O5 C61 C62 164.2(5) . . . . ?
O6 C61 C62 C64 11.3(10) . . . 2_667 ?
O5 C61 C62 C64 -167.8(8) . . . 2_667 ?
O6 C61 C62 C63 -169.1(7) . . . . ?
O5 C61 C62 C63 11.8(10) . . . . ?
C64 C62 C63 C64 0.5(14) 2_667 . . . ?
C61 C62 C63 C64 -179.1(8) . . . . ?
C62 C63 C64 C62 -0.5(14) . . . 2_667 ?
