#------------------------------------------------------------------------------
#$Date: 2016-03-23 02:51:16 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179211 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/41/4314195.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4314195
loop_
_publ_author_name
'Vincent J. Catalano'
'Mark A. Malwitz'
_publ_contact_author_address
;
Department of Chemistry
University of Nevada
Reno, NV  89557
;
_publ_contact_author_email       vjc@unr.edu
_publ_contact_author_name        'Professor Vincent J. Catalano'
_publ_contact_author_phone       '775 784 1329'
_publ_section_title
;
 Short Metal-Metal Separations in a Highly Luminescent Trimetallic Ag(I)
 Complex Stabilized by Bridging NHC Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5483
_journal_page_last               5485
_journal_paper_doi               10.1021/ic034483u
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C30 H28 Ag Cl N8 O'
_chemical_formula_weight         659.92
_chemical_name_common            1.Cl
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.800(12)
_cell_angle_beta                 101.364(12)
_cell_angle_gamma                99.519(10)
_cell_formula_units_Z            2
_cell_length_a                   10.9525(13)
_cell_length_b                   11.3411(17)
_cell_length_c                   13.2381(15)
_cell_measurement_reflns_used    27
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      12.52
_cell_measurement_theta_min      4.79
_cell_volume                     1479.0(4)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.952
_diffrn_measured_fraction_theta_max 0.952
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0402
_diffrn_reflns_av_sigmaI/netI    0.0925
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            5763
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.21
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.810
_exptl_absorpt_correction_T_max  0.5619
_exptl_absorpt_correction_T_min  0.5409
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            pale_yellow
_exptl_crystal_density_diffrn    1.482
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             672
_exptl_crystal_size_max          .10
_exptl_crystal_size_mid          .42
_exptl_crystal_size_min          .08
_refine_diff_density_max         0.344
_refine_diff_density_min         -0.354
_refine_diff_density_rms         0.073
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.012
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         4958
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.012
_refine_ls_R_factor_all          0.1107
_refine_ls_R_factor_gt           0.0575
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0500P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1100
_refine_ls_wR_factor_ref         0.1299
_reflns_number_gt                3124
_reflns_number_total             4958
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034483usi20030508_045038_2.cif
_cod_data_source_block           p1bar
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        1479.0(3)
_cod_database_code               4314195
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.59714(5) 0.90167(5) 0.54655(4) 0.05372(19) Uani 1 1 d . . .
Cl1 Cl 0.77736(18) 0.55691(18) 0.99612(16) 0.0771(5) Uani 1 1 d . . .
N1 N 0.4776(5) 0.7164(4) 0.3036(4) 0.0457(12) Uani 1 1 d . . .
N2 N 0.6751(5) 0.7985(4) 0.3261(4) 0.0453(12) Uani 1 1 d . . .
N3 N 0.5412(5) 1.0216(4) 0.7739(4) 0.0470(12) Uani 1 1 d . . .
N4 N 0.7334(5) 1.1013(5) 0.7827(4) 0.0548(14) Uani 1 1 d . . .
N5 N 0.3814(5) 0.6457(4) 0.4934(4) 0.0531(13) Uani 1 1 d . . .
N6 N 0.9458(6) 0.8474(6) 0.5292(5) 0.0768(17) Uani 1 1 d . . .
N7 N 0.2959(6) 0.7715(5) 0.7826(4) 0.0667(15) Uani 1 1 d . . .
N8 N 0.8885(7) 0.9311(5) 0.8038(5) 0.0810(19) Uani 1 1 d . . .
C1 C 0.5819(6) 0.8017(5) 0.3803(5) 0.0408(14) Uani 1 1 d . . .
C2 C 0.5044(7) 0.6601(6) 0.2045(5) 0.0553(17) Uani 1 1 d . . .
H2A H 0.4474 0.5984 0.1402 0.066 Uiso 1 1 calc R . .
C3 C 0.6290(7) 0.7117(6) 0.2188(5) 0.0571(17) Uani 1 1 d . . .
H3A H 0.6753 0.6925 0.1663 0.069 Uiso 1 1 calc R . .
C4 C 0.3516(6) 0.6869(6) 0.3235(5) 0.0545(16) Uani 1 1 d . . .
H4A H 0.2866 0.6501 0.2530 0.065 Uiso 1 1 calc R . .
H4B H 0.3341 0.7662 0.3667 0.065 Uiso 1 1 calc R . .
C5 C 0.3410(5) 0.5942(5) 0.3842(5) 0.0449(14) Uani 1 1 d . . .
C6 C 0.2920(6) 0.4649(6) 0.3265(5) 0.0634(18) Uani 1 1 d . . .
H6B H 0.2662 0.4326 0.2495 0.076 Uiso 1 1 calc R . .
C7 C 0.2813(7) 0.3827(6) 0.3845(7) 0.071(2) Uani 1 1 d . . .
H7B H 0.2471 0.2947 0.3474 0.086 Uiso 1 1 calc R . .
C8 C 0.3224(7) 0.4344(6) 0.4968(6) 0.0650(19) Uani 1 1 d . . .
H8B H 0.3165 0.3822 0.5383 0.078 Uiso 1 1 calc R . .
C9 C 0.3722(6) 0.5635(6) 0.5479(5) 0.0603(17) Uani 1 1 d . . .
H9A H 0.4015 0.5973 0.6248 0.072 Uiso 1 1 calc R . .
C10 C 0.8072(6) 0.8733(5) 0.3761(5) 0.0540(16) Uani 1 1 d . . .
H10A H 0.8092 0.9502 0.4367 0.065 Uiso 1 1 calc R . .
H10B H 0.8390 0.8999 0.3215 0.065 Uiso 1 1 calc R . .
C11 C 0.8954(6) 0.8018(6) 0.4194(5) 0.0525(16) Uani 1 1 d . . .
C12 C 0.9226(7) 0.6973(7) 0.3488(6) 0.0681(19) Uani 1 1 d . . .
H12A H 0.8864 0.6686 0.2728 0.082 Uiso 1 1 calc R . .
C13 C 1.0045(8) 0.6358(8) 0.3925(8) 0.094(3) Uani 1 1 d . . .
H13A H 1.0250 0.5650 0.3464 0.112 Uiso 1 1 calc R . .
C14 C 1.0556(8) 0.6801(10) 0.5048(10) 0.097(3) Uani 1 1 d . . .
H14A H 1.1096 0.6388 0.5364 0.117 Uiso 1 1 calc R . .
C15 C 1.0261(9) 0.7844(9) 0.5685(7) 0.095(3) Uani 1 1 d . . .
H15A H 1.0634 0.8151 0.6445 0.114 Uiso 1 1 calc R . .
C16 C 0.6263(6) 1.0127(5) 0.7128(5) 0.0458(15) Uani 1 1 d . . .
C17 C 0.7133(8) 1.1632(6) 0.8844(5) 0.0641(19) Uani 1 1 d . . .
H17A H 0.7722 1.2287 0.9451 0.077 Uiso 1 1 calc R . .
C18 C 0.5947(8) 1.1111(6) 0.8783(5) 0.0591(18) Uani 1 1 d . . .
H18A H 0.5542 1.1314 0.9349 0.071 Uiso 1 1 calc R . .
C19 C 0.4168(6) 0.9342(6) 0.7399(5) 0.0578(17) Uani 1 1 d . . .
H19A H 0.3910 0.8936 0.6598 0.069 Uiso 1 1 calc R . .
H19B H 0.3549 0.9824 0.7617 0.069 Uiso 1 1 calc R . .
C20 C 0.4140(6) 0.8314(5) 0.7891(5) 0.0510(15) Uani 1 1 d . . .
C21 C 0.5222(7) 0.7992(6) 0.8325(5) 0.0579(17) Uani 1 1 d . . .
H21A H 0.6034 0.8427 0.8352 0.069 Uiso 1 1 calc R . .
C22 C 0.5073(9) 0.6999(6) 0.8722(5) 0.074(2) Uani 1 1 d . . .
H22A H 0.5787 0.6752 0.9015 0.088 Uiso 1 1 calc R . .
C23 C 0.3875(9) 0.6392(6) 0.8678(6) 0.073(2) Uani 1 1 d . . .
H23A H 0.3757 0.5741 0.8960 0.088 Uiso 1 1 calc R . .
C24 C 0.2843(8) 0.6758(7) 0.8210(6) 0.078(2) Uani 1 1 d . . .
H24A H 0.2023 0.6320 0.8158 0.094 Uiso 1 1 calc R . .
C25 C 0.8585(7) 1.1149(6) 0.7598(7) 0.078(2) Uani 1 1 d . . .
H25A H 0.9005 1.2055 0.7853 0.093 Uiso 1 1 calc R . .
H25B H 0.8466 1.0785 0.6804 0.093 Uiso 1 1 calc R . .
C26 C 0.9426(7) 1.0502(6) 0.8144(5) 0.0584(17) Uani 1 1 d . . .
C27 C 1.0687(8) 1.1101(9) 0.8707(6) 0.090(3) Uani 1 1 d . . .
H27A H 1.1026 1.1948 0.8797 0.108 Uiso 1 1 calc R . .
C28 C 1.1445(11) 1.0423(14) 0.9140(10) 0.131(5) Uani 1 1 d . . .
H28A H 1.2309 1.0801 0.9505 0.157 Uiso 1 1 calc R . .
C29 C 1.0934(13) 0.9242(14) 0.9029(8) 0.125(5) Uani 1 1 d . . .
H29A H 1.1429 0.8771 0.9312 0.150 Uiso 1 1 calc R . .
C30 C 0.9686(13) 0.8727(9) 0.8503(7) 0.111(3) Uani 1 1 d . . .
H30A H 0.9340 0.7897 0.8452 0.133 Uiso 1 1 calc R . .
O1S O 0.0383(16) 0.5987(13) 0.9173(16) 0.082(5) Uani 0.50 1 d P . .
O2S O -0.008(2) 0.529(2) 0.8738(18) 0.150(9) Uani 0.50 1 d P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C16 Ag1 C1 175.0(2) . . ?
C1 N1 C2 111.8(5) . . ?
C1 N1 C4 124.1(5) . . ?
C2 N1 C4 124.1(5) . . ?
C1 N2 C3 111.2(5) . . ?
C1 N2 C10 124.3(5) . . ?
C3 N2 C10 124.5(5) . . ?
C16 N3 C18 111.5(6) . . ?
C16 N3 C19 124.1(5) . . ?
C18 N3 C19 123.7(6) . . ?
C16 N4 C17 111.3(6) . . ?
C16 N4 C25 123.9(6) . . ?
C17 N4 C25 124.2(6) . . ?
C5 N5 C9 116.5(5) . . ?
C11 N6 C15 116.3(7) . . ?
C20 N7 C24 117.4(6) . . ?
C26 N8 C30 114.7(8) . . ?
N1 C1 N2 103.8(5) . . ?
N1 C1 Ag1 127.2(4) . . ?
N2 C1 Ag1 128.8(4) . . ?
C3 C2 N1 106.4(6) . . ?
C2 C3 N2 106.8(6) . . ?
N1 C4 C5 113.3(5) . . ?
N5 C5 C6 123.3(5) . . ?
N5 C5 C4 116.2(5) . . ?
C6 C5 C4 120.5(5) . . ?
C5 C6 C7 119.2(6) . . ?
C8 C7 C6 118.2(6) . . ?
C7 C8 C9 119.1(6) . . ?
N5 C9 C8 123.8(6) . . ?
N2 C10 C11 113.7(4) . . ?
N6 C11 C12 123.0(6) . . ?
N6 C11 C10 116.0(6) . . ?
C12 C11 C10 121.0(6) . . ?
C11 C12 C13 118.7(7) . . ?
C14 C13 C12 119.2(8) . . ?
C15 C14 C13 118.7(8) . . ?
C14 C15 N6 124.1(8) . . ?
N3 C16 N4 103.3(5) . . ?
N3 C16 Ag1 128.7(5) . . ?
N4 C16 Ag1 127.8(4) . . ?
C18 C17 N4 106.2(6) . . ?
C17 C18 N3 107.7(6) . . ?
N3 C19 C20 113.1(5) . . ?
N7 C20 C21 123.1(5) . . ?
N7 C20 C19 113.5(6) . . ?
C21 C20 C19 123.3(6) . . ?
C20 C21 C22 118.1(7) . . ?
C23 C22 C21 119.5(7) . . ?
C22 C23 C24 118.6(7) . . ?
N7 C24 C23 123.2(7) . . ?
N4 C25 C26 112.4(5) . . ?
N8 C26 C27 122.6(8) . . ?
N8 C26 C25 116.0(6) . . ?
C27 C26 C25 121.4(7) . . ?
C26 C27 C28 118.8(9) . . ?
C29 C28 C27 119.4(12) . . ?
C28 C29 C30 118.8(12) . . ?
C29 C30 N8 125.5(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C16 2.082(6) . ?
Ag1 C1 2.083(6) . ?
N1 C1 1.348(7) . ?
N1 C2 1.374(7) . ?
N1 C4 1.461(7) . ?
N2 C1 1.358(7) . ?
N2 C3 1.375(7) . ?
N2 C10 1.452(7) . ?
N3 C16 1.345(7) . ?
N3 C18 1.365(7) . ?
N3 C19 1.437(7) . ?
N4 C16 1.352(7) . ?
N4 C17 1.383(8) . ?
N4 C25 1.455(8) . ?
N5 C5 1.321(7) . ?
N5 C9 1.353(7) . ?
N6 C11 1.338(8) . ?
N6 C15 1.350(10) . ?
N7 C20 1.331(8) . ?
N7 C24 1.338(8) . ?
N8 C26 1.333(8) . ?
N8 C30 1.352(11) . ?
C2 C3 1.344(9) . ?
C4 C5 1.518(7) . ?
C5 C6 1.370(8) . ?
C6 C7 1.391(8) . ?
C7 C8 1.358(9) . ?
C8 C9 1.361(8) . ?
C10 C11 1.503(8) . ?
C11 C12 1.371(9) . ?
C12 C13 1.375(10) . ?
C13 C14 1.368(11) . ?
C14 C15 1.344(12) . ?
C17 C18 1.311(9) . ?
C19 C20 1.506(7) . ?
C20 C21 1.370(9) . ?
C21 C22 1.387(8) . ?
C22 C23 1.358(10) . ?
C23 C24 1.370(10) . ?
C25 C26 1.487(9) . ?
C26 C27 1.372(10) . ?
C27 C28 1.384(14) . ?
C28 C29 1.313(14) . ?
C29 C30 1.339(14) . ?
O1S O2S 0.82(2) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 N1 C1 N2 0.7(6) . . . . ?
C4 N1 C1 N2 -179.7(4) . . . . ?
C2 N1 C1 Ag1 -174.6(4) . . . . ?
C4 N1 C1 Ag1 5.1(7) . . . . ?
C3 N2 C1 N1 -0.8(6) . . . . ?
C10 N2 C1 N1 -178.6(4) . . . . ?
C3 N2 C1 Ag1 174.4(4) . . . . ?
C10 N2 C1 Ag1 -3.4(7) . . . . ?
C16 Ag1 C1 N1 -161(2) . . . . ?
C16 Ag1 C1 N2 25(3) . . . . ?
C1 N1 C2 C3 -0.3(6) . . . . ?
C4 N1 C2 C3 -180.0(5) . . . . ?
N1 C2 C3 N2 -0.2(6) . . . . ?
C1 N2 C3 C2 0.6(6) . . . . ?
C10 N2 C3 C2 178.4(5) . . . . ?
C1 N1 C4 C5 -79.9(7) . . . . ?
C2 N1 C4 C5 99.8(6) . . . . ?
C9 N5 C5 C6 -0.1(9) . . . . ?
C9 N5 C5 C4 179.9(5) . . . . ?
N1 C4 C5 N5 85.4(7) . . . . ?
N1 C4 C5 C6 -94.6(7) . . . . ?
N5 C5 C6 C7 1.2(10) . . . . ?
C4 C5 C6 C7 -178.8(6) . . . . ?
C5 C6 C7 C8 -1.1(10) . . . . ?
C6 C7 C8 C9 -0.1(11) . . . . ?
C5 N5 C9 C8 -1.2(9) . . . . ?
C7 C8 C9 N5 1.3(11) . . . . ?
C1 N2 C10 C11 94.6(6) . . . . ?
C3 N2 C10 C11 -82.8(7) . . . . ?
C15 N6 C11 C12 -0.2(10) . . . . ?
C15 N6 C11 C10 -179.4(6) . . . . ?
N2 C10 C11 N6 -114.5(6) . . . . ?
N2 C10 C11 C12 66.4(7) . . . . ?
N6 C11 C12 C13 0.5(10) . . . . ?
C10 C11 C12 C13 179.6(6) . . . . ?
C11 C12 C13 C14 0.4(11) . . . . ?
C12 C13 C14 C15 -1.5(13) . . . . ?
C13 C14 C15 N6 1.9(14) . . . . ?
C11 N6 C15 C14 -1.0(12) . . . . ?
C18 N3 C16 N4 -1.0(6) . . . . ?
C19 N3 C16 N4 -171.6(5) . . . . ?
C18 N3 C16 Ag1 -176.1(4) . . . . ?
C19 N3 C16 Ag1 13.3(7) . . . . ?
C17 N4 C16 N3 -0.2(6) . . . . ?
C25 N4 C16 N3 170.7(5) . . . . ?
C17 N4 C16 Ag1 175.0(4) . . . . ?
C25 N4 C16 Ag1 -14.2(8) . . . . ?
C1 Ag1 C16 N3 157(2) . . . . ?
C1 Ag1 C16 N4 -16(3) . . . . ?
C16 N4 C17 C18 1.3(7) . . . . ?
C25 N4 C17 C18 -169.5(6) . . . . ?
N4 C17 C18 N3 -1.8(7) . . . . ?
C16 N3 C18 C17 1.8(7) . . . . ?
C19 N3 C18 C17 172.5(5) . . . . ?
C16 N3 C19 C20 98.2(6) . . . . ?
C18 N3 C19 C20 -71.3(7) . . . . ?
C24 N7 C20 C21 0.2(9) . . . . ?
C24 N7 C20 C19 177.9(5) . . . . ?
N3 C19 C20 N7 163.5(5) . . . . ?
N3 C19 C20 C21 -18.9(8) . . . . ?
N7 C20 C21 C22 -0.5(9) . . . . ?
C19 C20 C21 C22 -177.9(5) . . . . ?
C20 C21 C22 C23 -0.6(9) . . . . ?
C21 C22 C23 C24 1.9(10) . . . . ?
C20 N7 C24 C23 1.2(10) . . . . ?
C22 C23 C24 N7 -2.2(11) . . . . ?
C16 N4 C25 C26 -98.4(7) . . . . ?
C17 N4 C25 C26 71.3(8) . . . . ?
C30 N8 C26 C27 -1.7(10) . . . . ?
C30 N8 C26 C25 177.3(7) . . . . ?
N4 C25 C26 N8 46.8(9) . . . . ?
N4 C25 C26 C27 -134.1(7) . . . . ?
N8 C26 C27 C28 3.0(12) . . . . ?
C25 C26 C27 C28 -176.0(8) . . . . ?
C26 C27 C28 C29 -2.0(15) . . . . ?
C27 C28 C29 C30 -0.2(17) . . . . ?
C28 C29 C30 N8 1.6(16) . . . . ?
C26 N8 C30 C29 -0.6(12) . . . . ?
