#------------------------------------------------------------------------------
#$Date: 2016-03-23 02:53:44 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179216 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/43/4314372.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4314372
loop_
_publ_author_name
'Jean-Pierre Costes'
'Françoise Dahan'
'Franck Nicodème'
_publ_contact_author
;
       Dr Jean-Pierre Costes
       Laboratoire de Chimie de Coordination du CNRS
       205 Route de Narbonne
       31077 Toulouse Cedex 4
       France
;
_publ_contact_author_email       costes@lcctoul.lcc-toulouse.fr
_publ_contact_author_fax         '(33) 0561553003'
_publ_contact_author_phone       '(33) 0561333152'
_publ_section_title
;
 Structure-Based Description of a Step-by-Step Synthesis of Homo- and
 Heterodinuclear (4f, 4f') Lanthanide Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6556
_journal_page_last               6563
_journal_paper_doi               10.1021/ic034564q
_journal_volume                  42
_journal_year                    2003
_chemical_formula_sum            'C30 H35 Cl Eu N4 Na O11'
_chemical_formula_weight         838.02
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.283(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.6333(13)
_cell_length_b                   15.3799(12)
_cell_length_c                   17.1473(16)
_cell_measurement_temperature    180(2)
_cell_volume                     3350.2(6)
_computing_cell_refinement       'STOE-IPDS software (Stoe, 2.93, 1997)'
_computing_data_collection       'STOE-IPDS software (Stoe, 2.93, 1997)'
_computing_data_reduction        'XRED (Stoe, 1.08, 1996)'
_computing_molecular_graphics    'ZORTEP (Zsolnai, 1996)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  STOE-IPDS
_diffrn_measurement_method       'Imaging Plate Detector System'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0397
_diffrn_reflns_av_sigmaI/netI    0.0284
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            32575
_diffrn_reflns_theta_full        26.15
_diffrn_reflns_theta_max         26.15
_diffrn_reflns_theta_min         2.11
_exptl_absorpt_coefficient_mu    2.029
_exptl_absorpt_correction_T_max  0.7528
_exptl_absorpt_correction_T_min  0.4949
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'X-SHAPE (Stoe & Cie, 1996)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.661
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             1688
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.114
_refine_diff_density_min         -1.107
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.076
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     484
_refine_ls_number_reflns         6538
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.076
_refine_ls_R_factor_all          0.0419
_refine_ls_R_factor_gt           0.0358
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0817P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0858
_refine_ls_wR_factor_ref         0.0876
_reflns_number_gt                4818
_reflns_number_total             6538
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034564qsi20030526_041035_2.cif
_cod_data_source_block           (2)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Numerical'
changed to 'numerical' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0817P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0817P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3350.2(5)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4314372
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x+1/2, -y+1/2, z+1/2'
'-x, -y, -z'
'-x-1/2, y-1/2, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu 0.323659(13) 0.379921(10) 0.459275(10) 0.02661(9) Uani 1 d . . .
Na Na 0.27163(12) 0.48673(10) 0.26790(10) 0.0398(3) Uani 1 d . . .
O1 O 0.4034(3) 0.3909(2) 0.3641(2) 0.0491(8) Uani 1 d . . .
O2 O 0.4337(2) 0.4672(2) 0.23896(19) 0.0513(8) Uani 1 d . . .
O3 O 0.18641(19) 0.39848(16) 0.33510(15) 0.0302(5) Uani 1 d . . .
O4 O 0.0802(2) 0.51936(18) 0.22977(18) 0.0444(7) Uani 1 d . . .
O5 O 0.3198(2) 0.52994(16) 0.42954(18) 0.0380(6) Uani 1 d . . .
O6 O 0.2930(3) 0.6461(2) 0.3108(2) 0.0583(9) Uani 1 d . . .
O7 O 0.4807(2) 0.44094(19) 0.56713(18) 0.0420(7) Uani 1 d . . .
H7A H 0.492(3) 0.4960(19) 0.597(3) 0.046 Uiso 1 d . . .
H7B H 0.534(2) 0.440(3) 0.540(2) 0.046 Uiso 1 d . . .
N1 N 0.4689(3) 0.2616(2) 0.4944(2) 0.0405(8) Uani 1 d . . .
N2 N 0.1828(3) 0.2657(2) 0.44094(19) 0.0401(8) Uani 1 d . . .
N3 N 0.2350(3) 0.4554(2) 0.5454(2) 0.0454(8) Uani 1 d . . .
N4 N 0.3420(3) 0.2895(2) 0.59711(19) 0.0343(7) Uani 1 d . . .
C1 C 0.4836(3) 0.3623(3) 0.3460(3) 0.0373(8) Uani 1 d . . .
C2 C 0.5018(3) 0.3997(3) 0.2769(2) 0.0373(8) Uani 1 d . . .
C3 C 0.5821(3) 0.3686(3) 0.2535(3) 0.0440(10) Uani 1 d . . .
H3 H 0.5939 0.3940 0.2071 0.048 Uiso 1 calc R . .
C4 C 0.6453(4) 0.3013(3) 0.2963(3) 0.0497(11) Uani 1 d . . .
H4 H 0.6986 0.2791 0.2783 0.055 Uiso 1 calc R . .
C5 C 0.6310(3) 0.2665(3) 0.3649(3) 0.0401(9) Uani 1 d . . .
H5 H 0.6769 0.2217 0.3955 0.044 Uiso 1 calc R . .
C6 C 0.5496(3) 0.2956(2) 0.3913(2) 0.0369(8) Uani 1 d . . .
C7 C 0.5400(3) 0.2526(2) 0.4633(2) 0.0372(8) Uani 1 d . . .
H7 H 0.5942 0.2122 0.4911 0.041 Uiso 1 calc R . .
C8 C 0.4819(4) 0.2083(3) 0.5682(3) 0.0522(11) Uani 1 d . . .
H8A H 0.5562 0.1892 0.5935 0.057 Uiso 1 calc R . .
H8B H 0.4373 0.1558 0.5510 0.057 Uiso 1 calc R . .
C9 C 0.4521(3) 0.2580(3) 0.6333(2) 0.0385(8) Uani 1 d . . .
H9A H 0.4602 0.2195 0.6815 0.042 Uiso 1 calc R . .
H9B H 0.5002 0.3081 0.6538 0.042 Uiso 1 calc R . .
C10 C 0.4518(4) 0.5098(4) 0.1706(3) 0.0537(11) Uani 1 d . . .
H10A H 0.3998 0.5561 0.1484 0.059 Uiso 1 calc R . .
H10B H 0.4453 0.4674 0.1263 0.059 Uiso 1 calc R . .
H10C H 0.5228 0.5348 0.1906 0.059 Uiso 1 calc R . .
C11 C 0.0840(3) 0.4008(2) 0.3168(2) 0.0299(7) Uani 1 d . . .
C12 C 0.0237(3) 0.4653(2) 0.2603(2) 0.0347(8) Uani 1 d . . .
C13 C -0.0848(3) 0.4704(3) 0.2400(3) 0.0441(9) Uani 1 d . . .
H13 H -0.1229 0.5154 0.2037 0.048 Uiso 1 calc R . .
C14 C -0.1380(3) 0.4131(3) 0.2702(2) 0.0426(9) Uani 1 d . . .
H14 H -0.2122 0.4170 0.2546 0.047 Uiso 1 calc R . .
C15 C -0.0808(3) 0.3488(3) 0.3247(3) 0.0438(10) Uani 1 d . . .
H15 H -0.1169 0.3078 0.3459 0.048 Uiso 1 calc R . .
C16 C 0.0304(3) 0.3426(2) 0.3494(2) 0.0339(8) Uani 1 d . . .
C17 C 0.0841(3) 0.2714(3) 0.4035(2) 0.0427(9) Uani 1 d . . .
H17 H 0.0420 0.2256 0.4115 0.047 Uiso 1 calc R . .
C18 C 0.2201(4) 0.1888(3) 0.4931(3) 0.0532(12) Uani 1 d . . .
H18A H 0.2731 0.1581 0.4762 0.058 Uiso 1 calc R . .
H18B H 0.1605 0.1486 0.4852 0.058 Uiso 1 calc R . .
C19 C 0.2691(3) 0.2151(3) 0.5851(2) 0.0438(9) Uani 1 d . . .
H19A H 0.2125 0.2309 0.6058 0.048 Uiso 1 calc R . .
H19B H 0.3079 0.1649 0.6184 0.048 Uiso 1 calc R . .
C20 C 0.0251(4) 0.5915(3) 0.1804(4) 0.0669(16) Uani 1 d . . .
H20A H 0.0733 0.6250 0.1614 0.074 Uiso 1 calc R . .
H20B H -0.0021 0.6287 0.2143 0.074 Uiso 1 calc R . .
H20C H -0.0336 0.5700 0.1318 0.074 Uiso 1 calc R . .
C21 C 0.2476(3) 0.5910(2) 0.4230(3) 0.0448(10) Uani 1 d . . .
C22 C 0.2362(4) 0.6570(3) 0.3603(3) 0.0485(11) Uani 1 d . . .
C23 C 0.1651(4) 0.7241(3) 0.3544(3) 0.0633(15) Uani 1 d . . .
H23 H 0.1562 0.7684 0.3137 0.070 Uiso 1 calc R . .
C24 C 0.1062(5) 0.7286(4) 0.4064(3) 0.0722(18) Uani 1 d . . .
H24 H 0.0596 0.7758 0.4024 0.079 Uiso 1 calc R . .
C25 C 0.1174(4) 0.6635(3) 0.4629(3) 0.0595(14) Uani 1 d . . .
H25 H 0.0770 0.6657 0.4978 0.065 Uiso 1 calc R . .
C26 C 0.1848(4) 0.5948(3) 0.4713(2) 0.0455(10) Uani 1 d . . .
C27 C 0.1914(4) 0.5310(3) 0.5340(3) 0.0541(12) Uani 1 d . . .
H27 H 0.1591 0.5468 0.5725 0.060 Uiso 1 calc R . .
C28 C 0.2282(4) 0.4050(3) 0.6180(3) 0.0552(11) Uani 1 d . . .
H28A H 0.2204 0.4456 0.6602 0.061 Uiso 1 calc R . .
H28B H 0.1657 0.3666 0.5987 0.061 Uiso 1 calc R . .
C29 C 0.3249(4) 0.3519(3) 0.6562(2) 0.0440(9) Uani 1 d . . .
H29A H 0.3865 0.3912 0.6775 0.048 Uiso 1 calc R . .
H29B H 0.3199 0.3196 0.7046 0.048 Uiso 1 calc R . .
C30 C 0.2868(4) 0.7123(4) 0.2518(4) 0.0686(16) Uani 1 d . . .
H30A H 0.3315 0.6968 0.2202 0.076 Uiso 1 calc R . .
H30B H 0.3109 0.7674 0.2811 0.076 Uiso 1 calc R . .
H30C H 0.2138 0.7183 0.2132 0.076 Uiso 1 calc R . .
Cl1 Cl 0.16127(18) 0.48569(13) 0.07018(14) 0.0460(5) Uani 0.50 d P A 1
O8 O 0.1982(5) 0.4195(5) 0.1239(4) 0.0601(17) Uani 0.50 d P A 1
O9 O 0.1964(5) 0.5603(5) 0.1179(4) 0.0594(17) Uani 0.50 d P A 1
O10 O 0.0482(6) 0.4860(5) 0.0320(4) 0.0626(19) Uani 0.50 d P . 1
O11 O 0.1996(7) 0.4825(6) 0.0020(5) 0.077(2) Uani 0.50 d P A 1
Cl2 Cl 0.35249(15) 0.43929(13) -0.06870(12) 0.0394(4) Uani 0.50 d P B 2
O12 O 0.2800(5) 0.4292(5) -0.0253(4) 0.0554(16) Uani 0.50 d P B 2
O13 O 0.3566(6) 0.5252(4) -0.0865(5) 0.0588(17) Uani 0.50 d P B 2
O14 O 0.3157(7) 0.3902(5) -0.1434(5) 0.067(2) Uani 0.50 d P B 2
O15 O 0.4501(6) 0.4072(6) -0.0191(4) 0.0648(19) Uani 0.50 d P B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu O3 76.41(11) . . ?
O1 Eu O5 75.56(11) . . ?
O3 Eu O5 74.35(9) . . ?
O1 Eu O7 89.91(12) . . ?
O3 Eu O7 148.26(9) . . ?
O5 Eu O7 74.54(9) . . ?
O1 Eu N3 147.92(11) . . ?
O3 Eu N3 94.84(10) . . ?
O5 Eu N3 72.36(11) . . ?
O7 Eu N3 81.62(12) . . ?
O1 Eu N2 120.05(12) . . ?
O3 Eu N2 69.15(9) . . ?
O5 Eu N2 133.96(10) . . ?
O7 Eu N2 140.65(9) . . ?
N3 Eu N2 83.60(12) . . ?
O1 Eu N1 72.27(11) . . ?
O3 Eu N1 127.00(10) . . ?
O5 Eu N1 133.74(11) . . ?
O7 Eu N1 73.09(11) . . ?
N3 Eu N1 132.71(11) . . ?
N2 Eu N1 91.29(13) . . ?
O1 Eu N4 139.28(10) . . ?
O3 Eu N4 132.12(9) . . ?
O5 Eu N4 133.39(10) . . ?
O7 Eu N4 75.90(9) . . ?
N3 Eu N4 68.31(11) . . ?
N2 Eu N4 64.75(10) . . ?
N1 Eu N4 67.12(10) . . ?
O1 Eu Na 43.89(8) . . ?
O3 Eu Na 41.42(7) . . ?
O5 Eu Na 50.07(8) . . ?
O7 Eu Na 110.57(7) . . ?
N3 Eu Na 110.96(8) . . ?
N2 Eu Na 108.77(7) . . ?
N1 Eu Na 115.12(8) . . ?
N4 Eu Na 173.45(7) . . ?
O3 Na O1 72.12(10) . . ?
O3 Na O2 132.25(12) . . ?
O1 Na O2 64.35(10) . . ?
O3 Na O4 65.68(9) . . ?
O1 Na O4 137.69(11) . . ?
O2 Na O4 154.58(12) . . ?
O3 Na O8 98.8(2) . . ?
O1 Na O8 110.3(2) . . ?
O2 Na O8 79.54(17) . . ?
O4 Na O8 79.67(17) . . ?
O3 Na O6 116.16(12) . . ?
O1 Na O6 113.98(13) . . ?
O2 Na O6 99.18(13) . . ?
O4 Na O6 83.19(11) . . ?
O8 Na O6 129.8(2) . . ?
O3 Na O9 129.61(17) . . ?
O1 Na O9 147.48(18) . . ?
O2 Na O9 85.18(17) . . ?
O4 Na O9 70.18(17) . . ?
O8 Na O9 49.4(2) . . ?
O6 Na O9 80.38(18) . . ?
O3 Na O5 67.40(9) . . ?
O1 Na O5 66.94(10) . . ?
O2 Na O5 109.74(11) . . ?
O4 Na O5 93.51(10) . . ?
O8 Na O5 166.16(19) . . ?
O6 Na O5 60.31(10) . . ?
O9 Na O5 139.28(18) . . ?
O3 Na Cl1 113.28(9) . . ?
O1 Na Cl1 131.79(11) . . ?
O2 Na Cl1 84.02(10) . . ?
O4 Na Cl1 71.11(9) . . ?
O8 Na Cl1 23.99(19) . . ?
O6 Na Cl1 105.90(9) . . ?
O9 Na Cl1 25.68(16) . . ?
O5 Na Cl1 161.20(9) . . ?
O3 Na Eu 40.18(6) . . ?
O1 Na Eu 40.14(7) . . ?
O2 Na Eu 103.94(8) . . ?
O4 Na Eu 100.16(8) . . ?
O8 Na Eu 126.7(2) . . ?
O6 Na Eu 102.58(9) . . ?
O9 Na Eu 169.66(15) . . ?
O5 Na Eu 42.28(6) . . ?
Cl1 Na Eu 148.76(6) . . ?
C1 O1 Eu 143.1(3) . . ?
C1 O1 Na 120.8(3) . . ?
Eu O1 Na 95.96(11) . . ?
C2 O2 C10 116.1(3) . . ?
C2 O2 Na 119.7(2) . . ?
C10 O2 Na 122.8(3) . . ?
C11 O3 Eu 131.7(2) . . ?
C11 O3 Na 122.7(2) . . ?
Eu O3 Na 98.40(10) . . ?
C12 O4 C20 116.8(4) . . ?
C12 O4 Na 117.4(2) . . ?
C20 O4 Na 125.8(3) . . ?
C21 O5 Eu 131.6(3) . . ?
C21 O5 Na 101.0(2) . . ?
Eu O5 Na 87.65(9) . . ?
C22 O6 C30 117.5(4) . . ?
C22 O6 Na 105.6(2) . . ?
C30 O6 Na 121.0(4) . . ?
Eu O7 H7A 131(2) . . ?
Eu O7 H7B 103(2) . . ?
H7A O7 H7B 105(4) . . ?
C7 N1 C8 115.4(3) . . ?
C7 N1 Eu 127.8(3) . . ?
C8 N1 Eu 115.9(3) . . ?
C17 N2 C18 115.9(4) . . ?
C17 N2 Eu 129.2(3) . . ?
C18 N2 Eu 114.0(3) . . ?
C27 N3 C28 115.4(4) . . ?
C27 N3 Eu 128.5(3) . . ?
C28 N3 Eu 116.1(3) . . ?
C29 N4 C19 109.4(3) . . ?
C29 N4 C9 108.3(3) . . ?
C19 N4 C9 109.4(3) . . ?
C29 N4 Eu 106.4(2) . . ?
C19 N4 Eu 115.9(2) . . ?
C9 N4 Eu 107.2(2) . . ?
O1 C1 C6 122.4(4) . . ?
O1 C1 C2 118.3(4) . . ?
C6 C1 C2 119.3(4) . . ?
O2 C2 C3 126.1(4) . . ?
O2 C2 C1 113.9(3) . . ?
C3 C2 C1 120.0(4) . . ?
C4 C3 C2 121.0(4) . . ?
C4 C3 H3 119.5 . . ?
C2 C3 H3 119.5 . . ?
C5 C4 C3 119.7(4) . . ?
C5 C4 H4 120.1 . . ?
C3 C4 H4 120.1 . . ?
C4 C5 C6 121.5(4) . . ?
C4 C5 H5 119.2 . . ?
C6 C5 H5 119.2 . . ?
C1 C6 C5 118.4(4) . . ?
C1 C6 C7 124.8(4) . . ?
C5 C6 C7 116.8(4) . . ?
N1 C7 C6 128.7(3) . . ?
N1 C7 H7 115.6 . . ?
C6 C7 H7 115.6 . . ?
N1 C8 C9 111.8(3) . . ?
N1 C8 H8A 109.3 . . ?
C9 C8 H8A 109.3 . . ?
N1 C8 H8B 109.3 . . ?
C9 C8 H8B 109.3 . . ?
H8A C8 H8B 107.9 . . ?
N4 C9 C8 110.9(3) . . ?
N4 C9 H9A 109.5 . . ?
C8 C9 H9A 109.5 . . ?
N4 C9 H9B 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 108.0 . . ?
O2 C10 H10A 109.5 . . ?
O2 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
O2 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
O3 C11 C16 123.5(3) . . ?
O3 C11 C12 118.9(3) . . ?
C16 C11 C12 117.6(3) . . ?
O4 C12 C13 124.6(4) . . ?
O4 C12 C11 114.9(3) . . ?
C13 C12 C11 120.6(4) . . ?
C14 C13 C12 122.3(4) . . ?
C14 C13 H13 118.9 . . ?
C12 C13 H13 118.9 . . ?
C13 C14 C15 118.2(4) . . ?
C13 C14 H14 120.9 . . ?
C15 C14 H14 120.9 . . ?
C14 C15 C16 121.7(4) . . ?
C14 C15 H15 119.2 . . ?
C16 C15 H15 119.2 . . ?
C11 C16 C15 119.7(4) . . ?
C11 C16 C17 121.6(3) . . ?
C15 C16 C17 118.5(4) . . ?
N2 C17 C16 125.0(4) . . ?
N2 C17 H17 117.5 . . ?
C16 C17 H17 117.5 . . ?
N2 C18 C19 110.1(3) . . ?
N2 C18 H18A 109.6 . . ?
C19 C18 H18A 109.6 . . ?
N2 C18 H18B 109.6 . . ?
C19 C18 H18B 109.6 . . ?
H18A C18 H18B 108.2 . . ?
N4 C19 C18 111.6(3) . . ?
N4 C19 H19A 109.3 . . ?
C18 C19 H19A 109.3 . . ?
N4 C19 H19B 109.3 . . ?
C18 C19 H19B 109.3 . . ?
H19A C19 H19B 108.0 . . ?
O4 C20 H20A 109.5 . . ?
O4 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
O4 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
O5 C21 C26 125.0(4) . . ?
O5 C21 C22 115.7(4) . . ?
C26 C21 C22 119.3(4) . . ?
O6 C22 C23 126.0(4) . . ?
O6 C22 C21 116.7(4) . . ?
C23 C22 C21 117.3(5) . . ?
C24 C23 C22 122.3(5) . . ?
C24 C23 H23 118.9 . . ?
C22 C23 H23 118.9 . . ?
C25 C24 C23 118.3(5) . . ?
C25 C24 H24 120.9 . . ?
C23 C24 H24 120.9 . . ?
C24 C25 C26 122.6(5) . . ?
C24 C25 H25 118.7 . . ?
C26 C25 H25 118.7 . . ?
C25 C26 C21 120.2(5) . . ?
C25 C26 C27 117.5(4) . . ?
C21 C26 C27 122.2(4) . . ?
N3 C27 C26 129.1(4) . . ?
N3 C27 H27 115.4 . . ?
C26 C27 H27 115.4 . . ?
C29 C28 N3 109.8(4) . . ?
C29 C28 H28A 109.7 . . ?
N3 C28 H28A 109.7 . . ?
C29 C28 H28B 109.7 . . ?
N3 C28 H28B 109.7 . . ?
H28A C28 H28B 108.2 . . ?
N4 C29 C28 113.0(4) . . ?
N4 C29 H29A 109.0 . . ?
C28 C29 H29A 109.0 . . ?
N4 C29 H29B 109.0 . . ?
C28 C29 H29B 109.0 . . ?
H29A C29 H29B 107.8 . . ?
O6 C30 H30A 109.5 . . ?
O6 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
O6 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
O8 Cl1 O9 105.0(4) . . ?
O8 Cl1 O10 112.8(4) . . ?
O9 Cl1 O10 110.4(5) . . ?
O8 Cl1 O11 112.0(5) . . ?
O9 Cl1 O11 110.9(4) . . ?
O10 Cl1 O11 105.9(5) . . ?
O8 Cl1 Na 49.9(3) . . ?
O9 Cl1 Na 55.8(3) . . ?
O10 Cl1 Na 120.1(3) . . ?
O11 Cl1 Na 134.0(4) . . ?
Cl1 O8 Na 106.1(4) . . ?
Cl1 O9 Na 98.5(4) . . ?
Cl1 O10 O10 151.5(9) . 3_565 ?
O13 Cl2 O15 112.1(5) . . ?
O13 Cl2 O14 110.2(5) . . ?
O15 Cl2 O14 108.2(5) . . ?
O13 Cl2 O12 108.1(4) . . ?
O15 Cl2 O12 109.3(4) . . ?
O14 Cl2 O12 109.0(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu O1 2.272(3) . ?
Eu O3 2.286(2) . ?
Eu O5 2.359(2) . ?
Eu O7 2.452(3) . ?
Eu N3 2.506(3) . ?
Eu N2 2.536(3) . ?
Eu N1 2.593(3) . ?
Eu N4 2.674(3) . ?
Eu Na 3.5043(17) . ?
Na O3 2.343(3) . ?
Na O1 2.443(3) . ?
Na O2 2.453(3) . ?
Na O4 2.500(3) . ?
Na O8 2.525(7) . ?
Na O6 2.546(4) . ?
Na O9 2.652(7) . ?
Na O5 2.690(3) . ?
Na Cl1 3.171(3) . ?
O1 C1 1.317(5) . ?
O2 C2 1.386(5) . ?
O2 C10 1.440(5) . ?
O3 C11 1.315(4) . ?
O4 C12 1.361(5) . ?
O4 C20 1.432(5) . ?
O5 C21 1.335(5) . ?
O6 C22 1.351(6) . ?
O6 C30 1.416(5) . ?
O7 H7A 0.98(3) . ?
O7 H7B 0.99(4) . ?
N1 C7 1.273(5) . ?
N1 C8 1.463(5) . ?
N2 C17 1.266(6) . ?
N2 C18 1.459(5) . ?
N3 C27 1.289(6) . ?
N3 C28 1.497(6) . ?
N4 C29 1.475(5) . ?
N4 C19 1.481(5) . ?
N4 C9 1.482(5) . ?
C1 C6 1.399(5) . ?
C1 C2 1.418(6) . ?
C2 C3 1.382(6) . ?
C3 C4 1.375(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.370(6) . ?
C4 H4 0.9500 . ?
C5 C6 1.416(5) . ?
C5 H5 0.9500 . ?
C6 C7 1.448(6) . ?
C7 H7 0.9500 . ?
C8 C9 1.524(6) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 C16 1.394(5) . ?
C11 C12 1.422(5) . ?
C12 C13 1.394(5) . ?
C13 C14 1.357(6) . ?
C13 H13 0.9500 . ?
C14 C15 1.390(7) . ?
C14 H14 0.9500 . ?
C15 C16 1.421(5) . ?
C15 H15 0.9500 . ?
C16 C17 1.450(6) . ?
C17 H17 0.9500 . ?
C18 C19 1.528(6) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 C26 1.391(7) . ?
C21 C22 1.445(6) . ?
C22 C23 1.395(7) . ?
C23 C24 1.402(9) . ?
C23 H23 0.9500 . ?
C24 C25 1.362(8) . ?
C24 H24 0.9500 . ?
C25 C26 1.374(6) . ?
C25 H25 0.9500 . ?
C26 C27 1.434(7) . ?
C27 H27 0.9500 . ?
C28 C29 1.486(6) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
Cl1 O8 1.342(8) . ?
Cl1 O9 1.389(7) . ?
Cl1 O10 1.439(7) . ?
Cl1 O11 1.445(8) . ?
O10 O10 1.439(13) 3_565 ?
Cl2 O13 1.361(7) . ?
Cl2 O15 1.384(7) . ?
Cl2 O14 1.413(7) . ?
Cl2 O12 1.445(6) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O7 H7A O1 0.98(3) 2.19(3) 3.036(4) 144(4) 3_666
O7 H7B O5 0.99(4) 1.93(3) 2.736(4) 137(3) 3_666
