#------------------------------------------------------------------------------
#$Date: 2017-10-13 14:42:48 +0300 (Fri, 13 Oct 2017) $
#$Revision: 201982 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/31/47/4314766.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4314766
loop_
_publ_author_name
'Antonio R. Tapia-Benavides'
'Luis H. Mendoza-Huizar'
'Francisco Pérez-García'
'Hugo Tlahuext'
'Alejandro Alvarez'
'Margarita Tlahuextl'
_publ_contact_author_email       tromero@uaeh.edu.mx
_publ_contact_author_name        'Margarita Tlahuextl'
_publ_section_title
;
 Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1496
_journal_page_last               1502
_journal_paper_doi               10.1021/ic901740d
_journal_volume                  49
_journal_year                    2010
_chemical_absolute_configuration rm
_chemical_formula_moiety         'C24 H27 As N2 O2'
_chemical_formula_sum            'C24 H27 As N2 O2'
_chemical_formula_weight         450.40
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2009-08-29 # Formatted by publCIF
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.79(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.499(2)
_cell_length_b                   5.9685(12)
_cell_length_c                   17.833(4)
_cell_measurement_reflns_used    3838
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.05
_cell_measurement_theta_min      3.61
_cell_volume                     1117.4(4)
_computing_cell_refinement       'SAINT-Plus NT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT-Plus NT'
_computing_molecular_graphics    SHELXTL-NT
_computing_structure_refinement  SHELXTL-NT
_computing_structure_solution    'SHELXTL-NT (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0730
_diffrn_reflns_av_sigmaI/netI    0.0636
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            6883
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.14
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.542
_exptl_absorpt_correction_T_max  0.8365
_exptl_absorpt_correction_T_min  0.4953
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.339
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             468
_exptl_crystal_size_max          0.53
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.497
_refine_diff_density_min         -0.720
_refine_diff_density_rms         0.113
_refine_ls_abs_structure_details
; 
The absolute configuration was assigned to agree with the known
chirality at C4 and C5 arising from its precursor (+)-Norephedrine
;
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.124
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     272
_refine_ls_number_reflns         3838
_refine_ls_number_restraints     5
_refine_ls_restrained_S_all      1.124
_refine_ls_R_factor_all          0.0538
_refine_ls_R_factor_gt           0.0486
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1004P)²+0.3138P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1305
_refine_ls_wR_factor_ref         0.1527
_reflns_number_gt                2183
_reflns_number_total             3838
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic901740d_si_002.cif
_cod_data_source_block           pefpacom
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        1117.3(4)
_cod_database_code               4314766
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
As2 As 0.67770(4) 0.6809(3) 0.22761(2) 0.03380(19) Uani 1 1 d . . .
C4 C 0.4584(6) 0.8924(11) 0.2737(3) 0.0433(14) Uani 1 1 d D . .
H4 H 0.4345 1.0422 0.2910 0.052 Uiso 1 1 calc R . .
C5 C 0.5214(5) 0.7630(10) 0.3407(3) 0.0340(11) Uani 1 1 d . . .
H5 H 0.5850 0.8607 0.3646 0.041 Uiso 1 1 calc R . .
C6 C 0.8266(5) 0.7592(11) 0.2864(3) 0.0375(13) Uani 1 1 d . . .
C7 C 0.8859(6) 0.9632(11) 0.2803(4) 0.0459(14) Uani 1 1 d . . .
H7 H 0.8543 1.0683 0.2463 0.055 Uiso 1 1 calc R . .
C8 C 0.9927(7) 1.0154(14) 0.3241(4) 0.0570(18) Uani 1 1 d . . .
H8 H 1.0319 1.1545 0.3199 0.068 Uiso 1 1 calc R . .
C9 C 1.0395(7) 0.8572(16) 0.3738(5) 0.063(2) Uani 1 1 d . . .
H9 H 1.1122 0.8887 0.4023 0.075 Uiso 1 1 calc R . .
C10 C 0.9804(7) 0.655(2) 0.3817(4) 0.067(2) Uani 1 1 d . . .
H10 H 1.0119 0.5525 0.4165 0.081 Uiso 1 1 calc R . .
C11 C 0.8733(7) 0.6015(13) 0.3384(4) 0.0527(17) Uani 1 1 d . . .
H11 H 0.8335 0.4635 0.3438 0.063 Uiso 1 1 calc R . .
C12 C 0.3423(7) 0.7820(17) 0.2401(4) 0.066(2) Uani 1 1 d . . .
H12A H 0.3627 0.6312 0.2259 0.098 Uiso 1 1 calc R . .
H12B H 0.3144 0.8643 0.1966 0.098 Uiso 1 1 calc R . .
H12C H 0.2755 0.7799 0.2764 0.098 Uiso 1 1 calc R . .
C13 C 0.4269(5) 0.6894(16) 0.3997(3) 0.0363(10) Uani 1 1 d . . .
C14 C 0.4043(6) 0.8323(12) 0.4590(3) 0.0449(14) Uani 1 1 d . . .
H14 H 0.4445 0.9710 0.4612 0.054 Uiso 1 1 calc R . .
C15 C 0.3219(8) 0.7695(15) 0.5154(4) 0.059(2) Uani 1 1 d . . .
H15 H 0.3077 0.8662 0.5554 0.070 Uiso 1 1 calc R . .
C16 C 0.2623(7) 0.5694(17) 0.5129(4) 0.059(2) Uani 1 1 d . . .
H16 H 0.2079 0.5289 0.5512 0.070 Uiso 1 1 calc R . .
C17 C 0.2812(7) 0.4252(14) 0.4544(4) 0.0561(18) Uani 1 1 d . . .
H17 H 0.2384 0.2888 0.4524 0.067 Uiso 1 1 calc R . .
C18 C 0.3653(7) 0.4848(12) 0.3977(4) 0.0498(15) Uani 1 1 d . . .
H18 H 0.3798 0.3861 0.3584 0.060 Uiso 1 1 calc R . .
C4' C 0.7138(6) 0.3812(10) 0.1127(3) 0.0395(13) Uani 1 1 d D . .
H4' H 0.7641 0.2455 0.1042 0.047 Uiso 1 1 calc R . .
C5' C 0.7995(6) 0.5889(10) 0.0996(3) 0.0369(12) Uani 1 1 d . . .
H5' H 0.8825 0.5627 0.1238 0.044 Uiso 1 1 calc R . .
C12' C 0.5955(8) 0.3736(14) 0.0631(4) 0.0610(18) Uani 1 1 d . . .
H12D H 0.5522 0.5150 0.0654 0.092 Uiso 1 1 calc R . .
H12E H 0.5400 0.2570 0.0801 0.092 Uiso 1 1 calc R . .
H12F H 0.6195 0.3440 0.0123 0.092 Uiso 1 1 calc R . .
C13' C 0.8201(5) 0.6417(10) 0.0174(3) 0.0346(14) Uani 1 1 d . . .
C14' C 0.8965(7) 0.4961(12) -0.0254(4) 0.0496(15) Uani 1 1 d . . .
H14' H 0.9314 0.3682 -0.0035 0.060 Uiso 1 1 calc R . .
C15' C 0.9197(8) 0.5441(16) -0.1002(5) 0.065(2) Uani 1 1 d . . .
H15' H 0.9682 0.4455 -0.1284 0.078 Uiso 1 1 calc R . .
C16' C 0.8727(9) 0.7321(15) -0.1328(4) 0.069(3) Uani 1 1 d . . .
H16' H 0.8898 0.7633 -0.1827 0.082 Uiso 1 1 calc R . .
C17' C 0.7987(10) 0.8782(16) -0.0912(4) 0.074(2) Uani 1 1 d . . .
H17' H 0.7674 1.0085 -0.1132 0.088 Uiso 1 1 calc R . .
C18' C 0.7710(8) 0.8309(13) -0.0163(4) 0.0545(17) Uani 1 1 d . . .
H18' H 0.7195 0.9275 0.0107 0.065 Uiso 1 1 calc R . .
H3 H 0.533(4) 0.943(14) 0.1772(13) 0.05(2) Uiso 1 1 d D . .
H3' H 0.637(4) 0.299(7) 0.211(2) 0.041(17) Uiso 1 1 d D . .
N3 N 0.5629(5) 0.9151(9) 0.2213(3) 0.0392(11) Uani 1 1 d D . .
N3' N 0.6862(6) 0.3979(6) 0.1922(3) 0.0445(12) Uani 1 1 d D . .
O1 O 0.5854(4) 0.5764(7) 0.3084(2) 0.0376(9) Uani 1 1 d . . .
O1' O 0.7389(4) 0.7737(8) 0.1362(2) 0.0402(9) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3' As2 O1' 87.3(2) . . ?
N3' As2 N3 136.2(2) . . ?
O1' As2 N3 87.4(2) . . ?
N3' As2 O1 89.2(2) . . ?
O1' As2 O1 168.17(19) . . ?
N3 As2 O1 87.4(2) . . ?
N3' As2 C6 111.9(3) . . ?
O1' As2 C6 96.8(2) . . ?
N3 As2 C6 111.9(2) . . ?
O1 As2 C6 95.0(2) . . ?
N3 C4 C12 113.6(5) . . ?
N3 C4 C5 102.8(5) . . ?
C12 C4 C5 114.8(6) . . ?
N3 C4 H4 108.4 . . ?
C12 C4 H4 108.4 . . ?
C5 C4 H4 108.4 . . ?
O1 C5 C13 111.6(5) . . ?
O1 C5 C4 105.9(4) . . ?
C13 C5 C4 113.5(5) . . ?
O1 C5 H5 108.5 . . ?
C13 C5 H5 108.5 . . ?
C4 C5 H5 108.5 . . ?
C7 C6 C11 119.4(6) . . ?
C7 C6 As2 122.5(5) . . ?
C11 C6 As2 118.0(5) . . ?
C6 C7 C8 121.1(6) . . ?
C6 C7 H7 119.5 . . ?
C8 C7 H7 119.5 . . ?
C9 C8 C7 118.9(7) . . ?
C9 C8 H8 120.5 . . ?
C7 C8 H8 120.5 . . ?
C10 C9 C8 120.8(7) . . ?
C10 C9 H9 119.6 . . ?
C8 C9 H9 119.6 . . ?
C9 C10 C11 120.8(8) . . ?
C9 C10 H10 119.6 . . ?
C11 C10 H10 119.6 . . ?
C10 C11 C6 118.9(7) . . ?
C10 C11 H11 120.5 . . ?
C6 C11 H11 120.5 . . ?
C4 C12 H12A 109.5 . . ?
C4 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C4 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
C18 C13 C14 118.6(5) . . ?
C18 C13 C5 123.2(6) . . ?
C14 C13 C5 118.2(7) . . ?
C13 C14 C15 120.3(7) . . ?
C13 C14 H14 119.9 . . ?
C15 C14 H14 119.9 . . ?
C16 C15 C14 120.5(7) . . ?
C16 C15 H15 119.7 . . ?
C14 C15 H15 119.7 . . ?
C15 C16 C17 120.7(7) . . ?
C15 C16 H16 119.6 . . ?
C17 C16 H16 119.6 . . ?
C16 C17 C18 119.4(7) . . ?
C16 C17 H17 120.3 . . ?
C18 C17 H17 120.3 . . ?
C13 C18 C17 120.4(6) . . ?
C13 C18 H18 119.8 . . ?
C17 C18 H18 119.8 . . ?
N3' C4' C12' 113.5(6) . . ?
N3' C4' C5' 102.5(5) . . ?
C12' C4' C5' 114.1(5) . . ?
N3' C4' H4' 108.8 . . ?
C12' C4' H4' 108.8 . . ?
C5' C4' H4' 108.8 . . ?
O1' C5' C13' 110.5(5) . . ?
O1' C5' C4' 106.6(5) . . ?
C13' C5' C4' 113.7(5) . . ?
O1' C5' H5' 108.7 . . ?
C13' C5' H5' 108.7 . . ?
C4' C5' H5' 108.7 . . ?
C4' C12' H12D 109.5 . . ?
C4' C12' H12E 109.5 . . ?
H12D C12' H12E 109.5 . . ?
C4' C12' H12F 109.5 . . ?
H12D C12' H12F 109.5 . . ?
H12E C12' H12F 109.5 . . ?
C18' C13' C14' 118.7(6) . . ?
C18' C13' C5' 122.3(5) . . ?
C14' C13' C5' 118.9(5) . . ?
C15' C14' C13' 120.0(7) . . ?
C15' C14' H14' 120.0 . . ?
C13' C14' H14' 120.0 . . ?
C16' C15' C14' 121.0(7) . . ?
C16' C15' H15' 119.5 . . ?
C14' C15' H15' 119.5 . . ?
C15' C16' C17' 119.6(7) . . ?
C15' C16' H16' 120.2 . . ?
C17' C16' H16' 120.2 . . ?
C16' C17' C18' 120.5(8) . . ?
C16' C17' H17' 119.7 . . ?
C18' C17' H17' 119.7 . . ?
C13' C18' C17' 120.1(7) . . ?
C13' C18' H18' 120.0 . . ?
C17' C18' H18' 120.0 . . ?
C4 N3 As2 112.8(4) . . ?
C4 N3 H3 110(3) . . ?
As2 N3 H3 116(5) . . ?
C4' N3' As2 114.6(4) . . ?
C4' N3' H3' 118(3) . . ?
As2 N3' H3' 118(4) . . ?
C5 O1 As2 107.8(3) . . ?
C5' O1' As2 109.4(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
As2 N3' 1.806(5) . ?
As2 O1' 1.846(4) . ?
As2 N3 1.848(5) . ?
As2 O1 1.855(4) . ?
As2 C6 1.927(6) . ?
C4 N3 1.457(8) . ?
C4 C12 1.503(11) . ?
C4 C5 1.562(8) . ?
C4 H4 0.9800 . ?
C5 O1 1.427(7) . ?
C5 C13 1.520(8) . ?
C5 H5 0.9800 . ?
C6 C7 1.372(9) . ?
C6 C11 1.405(9) . ?
C7 C8 1.393(10) . ?
C7 H7 0.9300 . ?
C8 C9 1.381(12) . ?
C8 H8 0.9300 . ?
C9 C10 1.363(14) . ?
C9 H9 0.9300 . ?
C10 C11 1.392(11) . ?
C10 H10 0.9300 . ?
C11 H11 0.9300 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 C18 1.382(11) . ?
C13 C14 1.383(9) . ?
C14 C15 1.387(10) . ?
C14 H14 0.9300 . ?
C15 C16 1.349(12) . ?
C15 H15 0.9300 . ?
C16 C17 1.369(12) . ?
C16 H16 0.9300 . ?
C17 C18 1.397(10) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C4' N3' 1.455(8) . ?
C4' C12' 1.516(10) . ?
C4' C5' 1.551(9) . ?
C4' H4' 0.9800 . ?
C5' O1' 1.434(7) . ?
C5' C13' 1.519(8) . ?
C5' H5' 0.9800 . ?
C12' H12D 0.9600 . ?
C12' H12E 0.9600 . ?
C12' H12F 0.9600 . ?
C13' C18' 1.376(9) . ?
C13' C14' 1.414(9) . ?
C14' C15' 1.389(11) . ?
C14' H14' 0.9300 . ?
C15' C16' 1.353(13) . ?
C15' H15' 0.9300 . ?
C16' C17' 1.390(12) . ?
C16' H16' 0.9300 . ?
C17' C18' 1.398(10) . ?
C17' H17' 0.9300 . ?
C18' H18' 0.9300 . ?
N3 H3 0.86(3) . ?
N3' H3' 0.86(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N3 C4 C5 O1 -49.4(6) . . . . ?
C12 C4 C5 O1 74.4(6) . . . . ?
N3 C4 C5 C13 -172.3(5) . . . . ?
C12 C4 C5 C13 -48.4(8) . . . . ?
N3' As2 C6 C7 137.5(5) . . . . ?
O1' As2 C6 C7 47.7(5) . . . . ?
N3 As2 C6 C7 -42.2(6) . . . . ?
O1 As2 C6 C7 -131.4(5) . . . . ?
N3' As2 C6 C11 -43.9(6) . . . . ?
O1' As2 C6 C11 -133.7(5) . . . . ?
N3 As2 C6 C11 136.4(5) . . . . ?
O1 As2 C6 C11 47.2(5) . . . . ?
C11 C6 C7 C8 0.9(10) . . . . ?
As2 C6 C7 C8 179.4(5) . . . . ?
C6 C7 C8 C9 0.6(11) . . . . ?
C7 C8 C9 C10 -1.9(12) . . . . ?
C8 C9 C10 C11 1.7(13) . . . . ?
C9 C10 C11 C6 -0.3(13) . . . . ?
C7 C6 C11 C10 -1.0(11) . . . . ?
As2 C6 C11 C10 -179.6(6) . . . . ?
O1 C5 C13 C18 -29.2(8) . . . . ?
C4 C5 C13 C18 90.4(8) . . . . ?
O1 C5 C13 C14 149.1(5) . . . . ?
C4 C5 C13 C14 -91.2(6) . . . . ?
C18 C13 C14 C15 0.4(9) . . . . ?
C5 C13 C14 C15 -178.0(6) . . . . ?
C13 C14 C15 C16 -0.4(10) . . . . ?
C14 C15 C16 C17 -0.5(11) . . . . ?
C15 C16 C17 C18 1.4(11) . . . . ?
C14 C13 C18 C17 0.5(10) . . . . ?
C5 C13 C18 C17 178.8(6) . . . . ?
C16 C17 C18 C13 -1.4(11) . . . . ?
N3' C4' C5' O1' -45.8(6) . . . . ?
C12' C4' C5' O1' 77.3(6) . . . . ?
N3' C4' C5' C13' -167.7(5) . . . . ?
C12' C4' C5' C13' -44.6(7) . . . . ?
O1' C5' C13' C18' -7.4(8) . . . . ?
C4' C5' C13' C18' 112.3(7) . . . . ?
O1' C5' C13' C14' 169.9(5) . . . . ?
C4' C5' C13' C14' -70.4(7) . . . . ?
C18' C13' C14' C15' -0.8(10) . . . . ?
C5' C13' C14' C15' -178.2(6) . . . . ?
C13' C14' C15' C16' 1.7(12) . . . . ?
C14' C15' C16' C17' -0.9(13) . . . . ?
C15' C16' C17' C18' -0.9(15) . . . . ?
C14' C13' C18' C17' -1.0(11) . . . . ?
C5' C13' C18' C17' 176.4(7) . . . . ?
C16' C17' C18' C13' 1.8(14) . . . . ?
C12 C4 N3 As2 -94.2(6) . . . . ?
C5 C4 N3 As2 30.4(5) . . . . ?
N3' As2 N3 C4 80.9(5) . . . . ?
O1' As2 N3 C4 164.2(4) . . . . ?
O1 As2 N3 C4 -5.2(4) . . . . ?
C6 As2 N3 C4 -99.6(4) . . . . ?
C12' C4' N3' As2 -91.5(6) . . . . ?
C5' C4' N3' As2 32.0(6) . . . . ?
O1' As2 N3' C4' -8.9(4) . . . . ?
N3 As2 N3' C4' 74.4(6) . . . . ?
O1 As2 N3' C4' 159.8(5) . . . . ?
C6 As2 N3' C4' -105.1(5) . . . . ?
C13 C5 O1 As2 171.1(3) . . . . ?
C4 C5 O1 As2 47.1(5) . . . . ?
N3' As2 O1 C5 -161.2(4) . . . . ?
O1' As2 O1 C5 -88.7(10) . . . . ?
N3 As2 O1 C5 -24.9(3) . . . . ?
C6 As2 O1 C5 86.8(4) . . . . ?
C13' C5' O1' As2 165.4(4) . . . . ?
C4' C5' O1' As2 41.5(5) . . . . ?
N3' As2 O1' C5' -19.7(4) . . . . ?
N3 As2 O1' C5' -156.2(4) . . . . ?
O1 As2 O1' C5' -92.4(10) . . . . ?
C6 As2 O1' C5' 92.0(4) . . . . ?
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 ChemSpider 30660960
