#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:05:22 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179230 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/50/4315020.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4315020
loop_
_publ_author_name
'Mrituanjay D. Pandey'
'Ashutosh Kumar Mishra'
'Vadapalli Chandrasekhar'
'Sandeep Verma'
_publ_contact_author_address
;Department of Chemistry,
Indian Institute of Technology Kanpur,
Kanpur 208016, India
;
_publ_contact_author_email       sverma@iitk.ac.in
_publ_contact_author_fax         '91-512-259 7436'
_publ_contact_author_name        'Verma, Sandeep'
_publ_contact_author_phone       '91-512-259 7643'
_publ_section_title
;
 Silver-Guided Excimer Emission in an Adenine-Pyrene Conjugate:
 Fluorescence Lifetime and Crystal Studies
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2020
_journal_page_last               2022
_journal_paper_doi               10.1021/ic9022008
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety         'C24 H20 Ag N6, N O3, O'
_chemical_formula_sum            'C24 H21 Ag N7 O4'
_chemical_formula_weight         579.35
_chemical_name_common            'Adenine-pyrene silver complex'
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.473(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   19.543(2)
_cell_length_b                   14.719(2)
_cell_length_c                   17.692(2)
_cell_measurement_reflns_used    2040
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      22.72
_cell_measurement_theta_min      2.39
_cell_volume                     4904.7(10)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0643
_diffrn_reflns_av_sigmaI/netI    0.0726
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            12453
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         4.24
_exptl_absorpt_coefficient_mu    0.867
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.569
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2344
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.790
_refine_diff_density_min         -0.802
_refine_diff_density_rms         0.193
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     309
_refine_ls_number_reflns         4313
_refine_ls_number_restraints     124
_refine_ls_restrained_S_all      1.058
_refine_ls_R_factor_all          0.1221
_refine_ls_R_factor_gt           0.0873
_refine_ls_shift/su_max          0.047
_refine_ls_shift/su_mean         0.004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1654P)²+29.3871P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2405
_refine_ls_wR_factor_ref         0.2705
_reflns_number_gt                2901
_reflns_number_total             4313
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic9022008_si_002_3.cif
_cod_data_source_block           SV_VC_2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        4904.6(12)
_cod_database_code               4315020
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.9083(6) 0.5449(11) 0.6281(9) 0.086(4) Uani 1 1 d DU . .
C2 C 0.9051(5) 0.6034(12) 0.5670(11) 0.123(5) Uani 1 1 d DU . .
H2 H 0.9036 0.5810 0.5174 0.147 Uiso 1 1 calc R . .
C3 C 0.9042(7) 0.7001(13) 0.5801(15) 0.145(7) Uani 1 1 d DU . .
H3 H 0.9010 0.7383 0.5374 0.174 Uiso 1 1 calc R . .
C4 C 0.9078(10) 0.7402(14) 0.6522(14) 0.154(8) Uani 1 1 d GDU . .
C5 C 0.9124(9) 0.6768(12) 0.7116(12) 0.134(6) Uani 1 1 d GDU . .
C6 C 0.9099(6) 0.5863(11) 0.7061(9) 0.089(4) Uani 1 1 d DU . .
C7 C 0.9135(7) 0.5177(11) 0.7683(11) 0.106(7) Uani 1 1 d D . .
H7 H 0.9143 0.4555 0.7592 0.127 Uiso 1 1 calc R . .
C8 C 0.9159(8) 0.5560(11) 0.8448(10) 0.096(5) Uani 1 1 d D . .
H8 H 0.9197 0.5205 0.8892 0.115 Uiso 1 1 calc R . .
C9 C 0.9116(7) 0.7116(13) 0.7836(11) 0.112(5) Uani 1 1 d GDU . .
C10 C 0.9118(6) 0.6521(10) 0.8457(9) 0.085(4) Uani 1 1 d DU . .
C11 C 0.9173(8) 0.6964(12) 0.9182(10) 0.114(5) Uani 1 1 d DU . .
H11 H 0.9224 0.6622 0.9635 0.137 Uiso 1 1 calc R . .
C12 C 0.9152(10) 0.7883(13) 0.9220(15) 0.140(7) Uani 1 1 d DU . .
H12 H 0.9170 0.8140 0.9705 0.168 Uiso 1 1 calc R . .
C13 C 0.9108(9) 0.8448(16) 0.8619(12) 0.130(6) Uani 1 1 d DU . .
H13 H 0.9080 0.9074 0.8677 0.157 Uiso 1 1 calc R . .
C14 C 0.9105(10) 0.8081(13) 0.7945(10) 0.116(6) Uiso 1 1 d GDU . .
C15 C 0.9082(12) 0.8684(9) 0.7334(11) 0.178(10) Uiso 1 1 d GD . .
H15 H 0.9077 0.9307 0.7421 0.213 Uiso 1 1 calc R . .
C16 C 0.9065(11) 0.8357(14) 0.6592(10) 0.147(8) Uiso 1 1 d GD . .
H16 H 0.9047 0.8742 0.6171 0.177 Uiso 1 1 calc R . .
C17 C 0.9056(7) 0.4455(10) 0.6280(12) 0.101(6) Uani 1 1 d . . .
H17A H 0.9220 0.4231 0.5843 0.121 Uiso 1 1 calc R . .
H17B H 0.9383 0.4233 0.6758 0.121 Uiso 1 1 calc R . .
C18 C 0.7282(5) 0.6285(6) 0.7958(5) 0.036(2) Uani 1 1 d . . .
H18 H 0.7285 0.5864 0.8351 0.043 Uiso 1 1 calc R . .
C19 C 0.7274(4) 0.6870(5) 0.6846(4) 0.0281(17) Uani 1 1 d . . .
C20 C 0.7304(4) 0.7072(5) 0.6084(5) 0.0302(18) Uani 1 1 d . . .
C21 C 0.7337(5) 0.8599(5) 0.6444(5) 0.038(2) Uani 1 1 d . . .
H21 H 0.7352 0.9201 0.6290 0.045 Uiso 1 1 calc R . .
C22 C 0.7297(5) 0.7586(5) 0.7363(4) 0.0287(18) Uani 1 1 d . . .
C23 C 0.8373(6) 0.3086(6) 0.6152(6) 0.046(2) Uani 1 1 d . . .
H23A H 0.8756 0.2847 0.6572 0.056 Uiso 1 1 calc R . .
H23B H 0.8472 0.2931 0.5659 0.056 Uiso 1 1 calc R . .
C24 C 0.7692(5) 0.2647(6) 0.6185(5) 0.036(2) Uani 1 1 d . . .
H24A H 0.7323 0.3107 0.6090 0.044 Uiso 1 1 calc R . .
H24B H 0.7560 0.2204 0.5766 0.044 Uiso 1 1 calc R . .
N1 N 0.7339(4) 0.7973(4) 0.5903(4) 0.0338(17) Uani 1 1 d . . .
N3 N 0.7684(4) 0.3462(4) 0.7805(4) 0.0348(17) Uani 1 1 d . . .
N6 N 0.7288(4) 0.6465(5) 0.5538(4) 0.0366(17) Uani 1 1 d . . .
H6A H 0.7300 0.6634 0.5077 0.044 Uiso 1 1 calc R . .
H6B H 0.7267 0.5896 0.5642 0.044 Uiso 1 1 calc R . .
N7 N 0.7277(4) 0.6058(4) 0.7235(4) 0.0340(16) Uani 1 1 d . . .
N9 N 0.7282(4) 0.7192(5) 0.8067(3) 0.0303(16) Uani 1 1 d . . .
N10 N 0.8357(5) 0.4081(5) 0.6223(6) 0.054(2) Uani 1 1 d . . .
H10 H 0.8110 0.4252 0.5732 0.065 Uiso 1 1 calc R . .
N11 N 0.6790(5) 0.5585(5) 0.9759(5) 0.051(2) Uani 1 1 d . . .
O1 O 0.6640(4) 0.5347(4) 1.0374(5) 0.056(2) Uani 1 1 d . . .
O2 O 0.7392(4) 0.5441(4) 0.9670(4) 0.0451(16) Uani 1 1 d . . .
O3 O 0.6342(5) 0.5970(8) 0.9227(6) 0.101(4) Uani 1 1 d . . .
O1S O 0.0392(16) 0.130(2) 0.6019(18) 0.143(9) Uiso 0.50 1 d P A 1
O1SA O 0.0437(14) 0.2240(19) 0.6455(16) 0.127(8) Uiso 0.50 1 d P B 2
Ag1 Ag 0.76769(4) 0.46930(4) 0.69904(4) 0.0427(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 C17 129.3(17) . . ?
C2 C1 C6 117.1(17) . . ?
C17 C1 C6 113.5(14) . . ?
C1 C2 C3 119(2) . . ?
C1 C2 H2 120.2 . . ?
C3 C2 H2 120.3 . . ?
C4 C3 C2 125(2) . . ?
C4 C3 H3 117.7 . . ?
C2 C3 H3 117.7 . . ?
C3 C4 C5 113(2) . . ?
C3 C4 C16 120.4(18) . . ?
C5 C4 C16 127(2) . . ?
C6 C5 C4 128(2) . . ?
C6 C5 C9 115.4(19) . . ?
C4 C5 C9 115.8(19) . . ?
C5 C6 C7 129.3(17) . . ?
C5 C6 C1 117.6(17) . . ?
C7 C6 C1 113.0(14) . . ?
C8 C7 C6 114.2(15) . . ?
C8 C7 H7 122.9 . . ?
C6 C7 H7 122.9 . . ?
C10 C8 C7 114.2(15) . . ?
C10 C8 H8 122.9 . . ?
C7 C8 H8 122.9 . . ?
C14 C9 C5 119.8(17) . . ?
C14 C9 C10 120.7(16) . . ?
C5 C9 C10 119.5(17) . . ?
C11 C10 C8 118.7(16) . . ?
C11 C10 C9 113.8(16) . . ?
C8 C10 C9 127.0(15) . . ?
C12 C11 C10 121(2) . . ?
C12 C11 H11 119.7 . . ?
C10 C11 H11 119.7 . . ?
C13 C12 C11 125(2) . . ?
C13 C12 H12 117.3 . . ?
C11 C12 H12 117.3 . . ?
C14 C13 C12 117(2) . . ?
C14 C13 H13 121.5 . . ?
C12 C13 H13 121.5 . . ?
C13 C14 C9 122.3(19) . . ?
C13 C14 C15 115.9(18) . . ?
C9 C14 C15 121.8(12) . . ?
C16 C15 C14 120.0 . . ?
C16 C15 H15 120.0 . . ?
C14 C15 H15 120.0 . . ?
C15 C16 C4 115.6(14) . . ?
C15 C16 H16 122.2 . . ?
C4 C16 H16 122.2 . . ?
N10 C17 C1 114.3(11) . . ?
N10 C17 H17A 108.7 . . ?
C1 C17 H17A 108.7 . . ?
N10 C17 H17B 108.7 . . ?
C1 C17 H17B 108.7 . . ?
H17A C17 H17B 107.6 . . ?
N7 C18 N9 112.9(7) . . ?
N7 C18 H18 123.5 . . ?
N9 C18 H18 123.5 . . ?
N7 C19 C22 109.5(7) . . ?
N7 C19 C20 132.1(7) . . ?
C22 C19 C20 118.2(7) . . ?
N6 C20 N1 118.8(7) . . ?
N6 C20 C19 124.6(7) . . ?
N1 C20 C19 116.6(7) . . ?
N1 C21 N3 127.5(7) . 4_656 ?
N1 C21 H21 116.2 . . ?
N3 C21 H21 116.2 4_656 . ?
N3 C22 N9 128.2(7) 4_656 . ?
N3 C22 C19 126.0(7) 4_656 . ?
N9 C22 C19 105.7(7) . . ?
N10 C23 C24 112.8(8) . . ?
N10 C23 H23A 109.0 . . ?
C24 C23 H23A 109.0 . . ?
N10 C23 H23B 109.0 . . ?
C24 C23 H23B 109.0 . . ?
H23A C23 H23B 107.8 . . ?
N9 C24 C23 114.5(8) 4_646 . ?
N9 C24 H24A 108.6 4_646 . ?
C23 C24 H24A 108.6 . . ?
N9 C24 H24B 108.6 4_646 . ?
C23 C24 H24B 108.6 . . ?
H24A C24 H24B 107.6 . . ?
C21 N1 C20 119.5(7) . . ?
C22 N3 C21 112.0(7) 4_646 4_646 ?
C22 N3 Ag1 128.2(5) 4_646 . ?
C21 N3 Ag1 119.8(5) 4_646 . ?
C20 N6 H6A 120.0 . . ?
C20 N6 H6B 120.0 . . ?
H6A N6 H6B 120.0 . . ?
C18 N7 C19 105.2(7) . . ?
C18 N7 Ag1 120.2(5) . . ?
C19 N7 Ag1 129.5(5) . . ?
C18 N9 C22 106.6(6) . . ?
C18 N9 C24 125.3(6) . 4_656 ?
C22 N9 C24 128.0(7) . 4_656 ?
C17 N10 C23 110.0(9) . . ?
C17 N10 Ag1 119.2(9) . . ?
C23 N10 Ag1 117.8(6) . . ?
C17 N10 H10 102.2 . . ?
C23 N10 H10 102.2 . . ?
Ag1 N10 H10 102.2 . . ?
O3 N11 O2 118.9(9) . . ?
O3 N11 O1 120.5(10) . . ?
O2 N11 O1 120.7(8) . . ?
N7 Ag1 N3 121.8(2) . . ?
N7 Ag1 N10 138.2(3) . . ?
N3 Ag1 N10 98.7(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.370(15) . ?
C1 C17 1.465(19) . ?
C1 C6 1.50(2) . ?
C2 C3 1.444(17) . ?
C2 H2 0.9300 . ?
C3 C4 1.389(17) . ?
C3 H3 0.9300 . ?
C4 C5 1.3900 . ?
C4 C16 1.412(17) . ?
C5 C6 1.336(16) . ?
C5 C9 1.378(16) . ?
C6 C7 1.481(16) . ?
C7 C8 1.456(16) . ?
C7 H7 0.9300 . ?
C8 C10 1.417(15) . ?
C8 H8 0.9300 . ?
C9 C14 1.434(16) . ?
C9 C10 1.405(15) . ?
C10 C11 1.416(15) . ?
C11 C12 1.355(17) . ?
C11 H11 0.9300 . ?
C12 C13 1.334(17) . ?
C12 H12 0.9300 . ?
C13 C14 1.308(16) . ?
C13 H13 0.9300 . ?
C14 C15 1.3900 . ?
C15 C16 1.3900 . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C17 N10 1.452(15) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 N7 1.319(10) . ?
C18 N9 1.349(11) . ?
C18 H18 0.9300 . ?
C19 N7 1.380(10) . ?
C19 C22 1.389(11) . ?
C19 C20 1.397(11) . ?
C20 N6 1.309(10) . ?
C20 N1 1.370(10) . ?
C21 N1 1.330(10) . ?
C21 N3 1.356(10) 4_656 ?
C21 H21 0.9300 . ?
C22 N3 1.325(10) 4_656 ?
C22 N9 1.380(9) . ?
C23 N10 1.471(12) . ?
C23 C24 1.494(13) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 N9 1.471(10) 4_646 ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
N3 C22 1.325(10) 4_646 ?
N3 C21 1.356(10) 4_646 ?
N3 Ag1 2.313(6) . ?
N6 H6A 0.8600 . ?
N6 H6B 0.8600 . ?
N7 Ag1 2.239(7) . ?
N9 C24 1.471(10) 4_656 ?
N10 Ag1 2.320(8) . ?
N10 H10 0.9100 . ?
N11 O3 1.238(11) . ?
N11 O2 1.246(11) . ?
N11 O1 1.250(11) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C17 C1 C2 C3 176.1(12) . . . . ?
C6 C1 C2 C3 0.6(7) . . . . ?
C1 C2 C3 C4 1.4(12) . . . . ?
C2 C3 C4 C5 0(2) . . . . ?
C2 C3 C4 C16 180.0(13) . . . . ?
C3 C4 C5 C6 -4(3) . . . . ?
C16 C4 C5 C6 176.0(18) . . . . ?
C3 C4 C5 C9 -176.1(15) . . . . ?
C16 C4 C5 C9 4(3) . . . . ?
C4 C5 C6 C7 -178.9(16) . . . . ?
C9 C5 C6 C7 -7(2) . . . . ?
C4 C5 C6 C1 6(3) . . . . ?
C9 C5 C6 C1 178.1(12) . . . . ?
C2 C1 C6 C5 -3.9(15) . . . . ?
C17 C1 C6 C5 179.9(13) . . . . ?
C2 C1 C6 C7 -179.8(8) . . . . ?
C17 C1 C6 C7 4.0(15) . . . . ?
C5 C6 C7 C8 4(2) . . . . ?
C1 C6 C7 C8 179.4(11) . . . . ?
C6 C7 C8 C10 2.0(17) . . . . ?
C6 C5 C9 C14 -176.8(15) . . . . ?
C4 C5 C9 C14 -4(2) . . . . ?
C6 C5 C9 C10 3(2) . . . . ?
C4 C5 C9 C10 176.2(14) . . . . ?
C7 C8 C10 C11 -176.8(12) . . . . ?
C7 C8 C10 C9 -5(2) . . . . ?
C14 C9 C10 C11 -5(2) . . . . ?
C5 C9 C10 C11 174.7(14) . . . . ?
C14 C9 C10 C8 -177.2(15) . . . . ?
C5 C9 C10 C8 3(2) . . . . ?
C8 C10 C11 C12 178.6(15) . . . . ?
C9 C10 C11 C12 6(2) . . . . ?
C10 C11 C12 C13 -3(3) . . . . ?
C11 C12 C13 C14 -2(3) . . . . ?
C12 C13 C14 C9 3(3) . . . . ?
C12 C13 C14 C15 -177.9(19) . . . . ?
C5 C9 C14 C13 -179.0(17) . . . . ?
C10 C9 C14 C13 1(3) . . . . ?
C5 C9 C14 C15 2(3) . . . . ?
C10 C9 C14 C15 -178.1(16) . . . . ?
C13 C14 C15 C16 -179(2) . . . . ?
C9 C14 C15 C16 0(3) . . . . ?
C14 C15 C16 C4 0(3) . . . . ?
C3 C4 C16 C15 178.1(18) . . . . ?
C5 C4 C16 C15 -2(3) . . . . ?
C2 C1 C17 N10 -96.5(16) . . . . ?
C6 C1 C17 N10 79.1(16) . . . . ?
N7 C19 C20 N6 5.7(15) . . . . ?
C22 C19 C20 N6 179.9(8) . . . . ?
N7 C19 C20 N1 -175.6(9) . . . . ?
C22 C19 C20 N1 -1.4(12) . . . . ?
N7 C19 C22 N3 178.5(9) . . . 4_656 ?
C20 C19 C22 N3 3.0(13) . . . 4_656 ?
N7 C19 C22 N9 -2.6(9) . . . . ?
C20 C19 C22 N9 -178.1(8) . . . . ?
N10 C23 C24 N9 -104.6(9) . . . 4_646 ?
N3 C21 N1 C20 1.2(14) 4_656 . . . ?
N6 C20 N1 C21 178.3(8) . . . . ?
C19 C20 N1 C21 -0.5(12) . . . . ?
N9 C18 N7 C19 0.0(10) . . . . ?
N9 C18 N7 Ag1 157.0(6) . . . . ?
C22 C19 N7 C18 1.6(10) . . . . ?
C20 C19 N7 C18 176.2(9) . . . . ?
C22 C19 N7 Ag1 -152.4(6) . . . . ?
C20 C19 N7 Ag1 22.2(14) . . . . ?
N7 C18 N9 C22 -1.7(10) . . . . ?
N7 C18 N9 C24 -178.1(8) . . . 4_656 ?
N3 C22 N9 C18 -178.6(9) 4_656 . . . ?
C19 C22 N9 C18 2.5(9) . . . . ?
N3 C22 N9 C24 -2.2(14) 4_656 . . 4_656 ?
C19 C22 N9 C24 178.9(8) . . . 4_656 ?
C1 C17 N10 C23 174.7(13) . . . . ?
C1 C17 N10 Ag1 -44.9(18) . . . . ?
C24 C23 N10 C17 173.3(11) . . . . ?
C24 C23 N10 Ag1 32.2(11) . . . . ?
C18 N7 Ag1 N3 24.9(8) . . . . ?
C19 N7 Ag1 N3 175.6(7) . . . . ?
C18 N7 Ag1 N10 -138.8(7) . . . . ?
C19 N7 Ag1 N10 11.9(10) . . . . ?
C22 N3 Ag1 N7 158.6(7) 4_646 . . . ?
C21 N3 Ag1 N7 -21.0(8) 4_646 . . . ?
C22 N3 Ag1 N10 -32.3(8) 4_646 . . . ?
C21 N3 Ag1 N10 148.1(7) 4_646 . . . ?
C17 N10 Ag1 N7 53.5(11) . . . . ?
C23 N10 Ag1 N7 -169.1(6) . . . . ?
C17 N10 Ag1 N3 -112.6(9) . . . . ?
C23 N10 Ag1 N3 24.9(8) . . . . ?
