#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:05:22 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179230 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/50/4315030.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4315030
loop_
_publ_author_name
'Sabrina Sculfort'
'Richard Welter'
'Pierre Braunstein'
_publ_contact_author_address
;
Institut Le Bel, rue Blaise Pascal, 67081 STRASBOURG, FRANCE
;
_publ_contact_author_email       braunstein@unistra.fr
_publ_contact_author_fax         0368851322
_publ_contact_author_name
;
Pierre Braunstein
;
_publ_contact_author_phone       0368851308
_publ_section_title
;
 Heterometallic Chains and Clusters with Gold-Transition Metal Bonds:
 Synthesis and Interconversion
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2372
_journal_page_last               2382
_journal_paper_doi               10.1021/ic902245v
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety         'C20 H20 Ag Mo2 Na O8'
_chemical_formula_sum            'C20 H20 Ag Mo2 Na O8'
_chemical_formula_weight         711.10
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             10-03-06
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 129.984(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.9681(5)
_cell_length_b                   16.4950(6)
_cell_length_c                   11.9423(4)
_cell_measurement_reflns_used    4117
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      0.998
_cell_volume                     2410.18(16)
_computing_cell_refinement       'Denzo (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo (Nonius B.V., 1998)'
_computing_molecular_graphics    'PLATON 98 (Spek, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'π scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0542
_diffrn_reflns_av_sigmaI/netI    0.0884
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            7803
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.07
_exptl_absorpt_coefficient_mu    1.888
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.960
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1384
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.865
_refine_diff_density_min         -1.196
_refine_diff_density_rms         0.156
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.52(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.984
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         4010
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      0.983
_refine_ls_R_factor_all          0.0671
_refine_ls_R_factor_gt           0.0397
_refine_ls_shift/su_max          0.008
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0177P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0731
_refine_ls_wR_factor_ref         0.0831
_reflns_number_gt                3085
_reflns_number_total             4010
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic902245v_si_004.cif
_cod_data_source_block           mo2_ag_na_polymer
_cod_original_cell_volume        2410.18(14)
_cod_original_sg_symbol_H-M      'C c'
_cod_database_code               4315030
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.37425(5) 0.04630(4) 0.19518(6) 0.03174(19) Uani 1 1 d . . .
Mo1 Mo 0.58768(5) 0.03935(4) 0.29708(6) 0.0264(2) Uani 1 1 d . . .
Mo2 Mo 0.17018(6) 0.07711(4) 0.11390(7) 0.02731(18) Uani 1 1 d . . .
Na Na 0.2920(2) 0.19352(18) -0.1712(3) 0.0283(7) Uani 1 1 d . . .
O1 O 0.4127(5) 0.0779(3) -0.0357(6) 0.0366(14) Uani 1 1 d . . .
O2 O 0.5520(6) 0.1661(4) 0.4571(6) 0.0558(19) Uani 1 1 d . . .
O3 O 0.6752(5) 0.1932(4) 0.2519(7) 0.0507(18) Uani 1 1 d . . .
O4 O 0.1900(5) 0.1385(3) -0.1146(6) 0.0403(15) Uani 1 1 d . . .
O5 O 0.2195(5) -0.1075(3) 0.1301(6) 0.0322(14) Uani 1 1 d . . .
O6 O -0.0594(6) 0.0251(4) -0.1657(8) 0.063(2) Uani 1 1 d . . .
O7 O 0.4199(5) 0.2726(3) 0.0309(6) 0.0408(16) Uani 1 1 d . . .
O8 O 0.3768(6) 0.2708(4) -0.2303(7) 0.060(2) Uani 1 1 d . . .
C1 C 0.4720(7) 0.0624(5) 0.0909(9) 0.028(2) Uani 1 1 d . . .
C2 C 0.5565(7) 0.1178(5) 0.3895(9) 0.039(2) Uani 1 1 d . . .
C3 C 0.6452(7) 0.1342(5) 0.2722(9) 0.037(2) Uani 1 1 d . . .
C4 C 0.5906(9) -0.0941(5) 0.3734(12) 0.053(3) Uani 1 1 d . . .
H4 H 0.5298 -0.1150 0.3613 0.063 Uiso 1 1 calc . . .
C5 C 0.6802(12) -0.0512(6) 0.4962(11) 0.068(4) Uani 1 1 d . . .
H5 H 0.6905 -0.0382 0.5819 0.081 Uiso 1 1 calc . . .
C6 C 0.7500(9) -0.0316(6) 0.4694(14) 0.066(4) Uani 1 1 d . . .
H6 H 0.8168 -0.0027 0.5333 0.079 Uiso 1 1 calc . . .
C7 C 0.7051(10) -0.0618(6) 0.3317(12) 0.052(3) Uani 1 1 d . . .
H7 H 0.7361 -0.0569 0.2857 0.063 Uiso 1 1 calc . . .
C8 C 0.6080(9) -0.0999(5) 0.2739(10) 0.047(3) Uani 1 1 d . . .
H8 H 0.5608 -0.1259 0.1813 0.057 Uiso 1 1 calc . . .
C9 C 0.1878(7) 0.1136(5) -0.0251(9) 0.029(2) Uani 1 1 d . . .
C10 C 0.2067(8) -0.0373(5) 0.1243(9) 0.032(2) Uani 1 1 d . . .
C11 C 0.0261(8) 0.0435(5) -0.0626(11) 0.040(2) Uani 1 1 d . . .
C12 C 0.1096(10) 0.1788(6) 0.1826(11) 0.052(3) Uani 1 1 d . . .
H12 H 0.0430 0.2059 0.1090 0.063 Uiso 1 1 calc . . .
C13 C 0.1210(10) 0.1084(6) 0.2562(13) 0.060(3) Uani 1 1 d . . .
H13 H 0.0636 0.0799 0.2431 0.072 Uiso 1 1 calc . . .
C14 C 0.2303(12) 0.0873(6) 0.3513(12) 0.064(3) Uani 1 1 d . . .
H14 H 0.2604 0.0410 0.4130 0.077 Uiso 1 1 calc . . .
C15 C 0.2893(9) 0.1459(8) 0.3419(11) 0.065(3) Uani 1 1 d . . .
H15 H 0.3662 0.1472 0.3966 0.077 Uiso 1 1 calc . . .
C16 C 0.2133(11) 0.2019(6) 0.2364(12) 0.058(3) Uani 1 1 d . . .
H16 H 0.2297 0.2482 0.2063 0.069 Uiso 1 1 calc . . .
C17 C 0.4081(8) 0.2937(6) 0.1361(10) 0.051(3) Uani 1 1 d . . .
H17A H 0.4801 0.3062 0.2296 0.077 Uiso 1 1 calc . . .
H17B H 0.3757 0.2480 0.1490 0.077 Uiso 1 1 calc . . .
H17C H 0.3606 0.3412 0.1019 0.077 Uiso 1 1 calc . . .
C18 C 0.4538(7) 0.3375(5) -0.0068(9) 0.042(2) Uani 1 1 d . . .
H18A H 0.5233 0.3596 0.0824 0.050 Uiso 1 1 calc . . .
H18B H 0.3983 0.3811 -0.0518 0.050 Uiso 1 1 calc . . .
C19 C 0.4695(9) 0.3108(6) -0.1112(12) 0.065(3) Uani 1 1 d . . .
H19A H 0.4845 0.3586 -0.1460 0.077 Uiso 1 1 calc . . .
H19B H 0.5333 0.2741 -0.0607 0.077 Uiso 1 1 calc . . .
C20 C 0.3638(9) 0.2666(6) -0.3562(11) 0.056(3) Uani 1 1 d . . .
H20A H 0.3692 0.3212 -0.3835 0.084 Uiso 1 1 calc . . .
H20B H 0.2919 0.2436 -0.4354 0.084 Uiso 1 1 calc . . .
H20C H 0.4210 0.2321 -0.3390 0.084 Uiso 1 1 calc . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ag C2 72.5(3) . . ?
C1 Ag C10 135.4(2) . . ?
C2 Ag C10 149.8(3) . . ?
C1 Ag C9 97.0(3) . . ?
C2 Ag C9 127.4(3) . . ?
C10 Ag C9 68.6(3) . . ?
C1 Ag Mo2 138.95(19) . . ?
C2 Ag Mo2 128.7(2) . . ?
C10 Ag Mo2 42.29(19) . . ?
C9 Ag Mo2 42.04(19) . . ?
C1 Ag Mo1 42.31(19) . . ?
C2 Ag Mo1 42.7(2) . . ?
C10 Ag Mo1 145.79(19) . . ?
C9 Ag Mo1 137.07(19) . . ?
Mo2 Ag Mo1 171.02(3) . . ?
C3 Mo1 C1 78.8(3) . . ?
C3 Mo1 C2 82.5(4) . . ?
C1 Mo1 C2 101.9(3) . . ?
C3 Mo1 C6 99.9(4) . . ?
C1 Mo1 C6 145.8(4) . . ?
C2 Mo1 C6 112.0(4) . . ?
C3 Mo1 C7 101.5(4) . . ?
C1 Mo1 C7 111.4(4) . . ?
C2 Mo1 C7 146.7(4) . . ?
C6 Mo1 C7 34.7(4) . . ?
C3 Mo1 C5 128.1(4) . . ?
C1 Mo1 C5 150.7(4) . . ?
C2 Mo1 C5 94.1(4) . . ?
C6 Mo1 C5 34.2(4) . . ?
C7 Mo1 C5 57.2(4) . . ?
C3 Mo1 C8 130.9(4) . . ?
C1 Mo1 C8 97.6(3) . . ?
C2 Mo1 C8 144.3(4) . . ?
C6 Mo1 C8 57.2(3) . . ?
C7 Mo1 C8 34.1(4) . . ?
C5 Mo1 C8 57.2(3) . . ?
C3 Mo1 C4 156.5(4) . . ?
C1 Mo1 C4 115.9(4) . . ?
C2 Mo1 C4 110.2(4) . . ?
C6 Mo1 C4 57.4(4) . . ?
C7 Mo1 C4 56.9(4) . . ?
C5 Mo1 C4 34.8(4) . . ?
C8 Mo1 C4 34.1(3) . . ?
C3 Mo1 Ag 117.9(2) . . ?
C1 Mo1 Ag 62.6(2) . . ?
C2 Mo1 Ag 62.5(3) . . ?
C6 Mo1 Ag 139.2(4) . . ?
C7 Mo1 Ag 136.2(3) . . ?
C5 Mo1 Ag 105.3(4) . . ?
C8 Mo1 Ag 102.1(3) . . ?
C4 Mo1 Ag 85.6(3) . . ?
C9 Mo2 C11 83.3(4) . . ?
C9 Mo2 C10 98.8(3) . . ?
C11 Mo2 C10 83.8(4) . . ?
C9 Mo2 C12 113.4(3) . . ?
C11 Mo2 C12 96.7(4) . . ?
C10 Mo2 C12 147.7(3) . . ?
C9 Mo2 C13 148.1(3) . . ?
C11 Mo2 C13 97.7(4) . . ?
C10 Mo2 C13 113.0(3) . . ?
C12 Mo2 C13 34.8(3) . . ?
C9 Mo2 C14 146.9(4) . . ?
C11 Mo2 C14 127.5(5) . . ?
C10 Mo2 C14 96.8(3) . . ?
C12 Mo2 C14 57.5(3) . . ?
C13 Mo2 C14 34.3(4) . . ?
C9 Mo2 C16 96.6(3) . . ?
C11 Mo2 C16 126.1(4) . . ?
C10 Mo2 C16 147.9(4) . . ?
C12 Mo2 C16 34.5(4) . . ?
C13 Mo2 C16 57.2(4) . . ?
C14 Mo2 C16 57.1(3) . . ?
C9 Mo2 C15 112.3(4) . . ?
C11 Mo2 C15 153.1(4) . . ?
C10 Mo2 C15 113.6(4) . . ?
C12 Mo2 C15 57.5(4) . . ?
C13 Mo2 C15 57.3(4) . . ?
C14 Mo2 C15 34.6(4) . . ?
C16 Mo2 C15 34.3(4) . . ?
C9 Mo2 Ag 64.9(2) . . ?
C11 Mo2 Ag 128.9(3) . . ?
C10 Mo2 Ag 64.4(3) . . ?
C12 Mo2 Ag 131.7(3) . . ?
C13 Mo2 Ag 130.6(3) . . ?
C14 Mo2 Ag 96.5(3) . . ?
C16 Mo2 Ag 97.7(3) . . ?
C15 Mo2 Ag 78.0(3) . . ?
O8 Na O4 168.8(3) . . ?
O8 Na O7 72.9(2) . . ?
O4 Na O7 103.4(2) . . ?
O8 Na O5 91.7(2) . 2_554 ?
O4 Na O5 94.4(2) . 2_554 ?
O7 Na O5 158.5(3) . 2_554 ?
O8 Na O3 85.1(3) . 4_454 ?
O4 Na O3 84.0(2) . 4_454 ?
O7 Na O3 84.7(2) . 4_454 ?
O5 Na O3 109.4(2) 2_554 4_454 ?
O8 Na O1 105.6(3) . . ?
O4 Na O1 84.5(2) . . ?
O7 Na O1 87.6(2) . . ?
O5 Na O1 82.2(2) 2_554 . ?
O3 Na O1 164.3(3) 4_454 . ?
O8 Na C18 49.4(2) . . ?
O4 Na C18 124.8(2) . . ?
O7 Na C18 24.8(2) . . ?
O5 Na C18 140.7(2) 2_554 . ?
O3 Na C18 76.7(2) 4_454 . ?
O1 Na C18 101.3(2) . . ?
O8 Na C19 24.2(2) . . ?
O4 Na C19 152.3(3) . . ?
O7 Na C19 49.2(3) . . ?
O5 Na C19 113.3(3) 2_554 . ?
O3 Na C19 88.4(3) 4_454 . ?
O1 Na C19 96.8(3) . . ?
C18 Na C19 27.7(2) . . ?
C1 O1 Na 131.1(5) . . ?
C3 O3 Na 153.6(6) . 4 ?
C9 O4 Na 147.9(6) . . ?
C10 O5 Na 127.9(5) . 2 ?
C18 O7 C17 113.2(6) . . ?
C18 O7 Na 111.1(5) . . ?
C17 O7 Na 121.9(5) . . ?
C20 O8 C19 116.9(7) . . ?
C20 O8 Na 127.4(5) . . ?
C19 O8 Na 113.7(5) . . ?
O1 C1 Mo1 170.9(7) . . ?
O1 C1 Ag 113.9(6) . . ?
Mo1 C1 Ag 75.1(3) . . ?
O2 C2 Mo1 171.5(8) . . ?
O2 C2 Ag 113.6(7) . . ?
Mo1 C2 Ag 74.8(3) . . ?
O3 C3 Mo1 176.8(7) . . ?
C8 C4 C5 107.3(10) . . ?
C8 C4 Mo1 72.6(5) . . ?
C5 C4 Mo1 72.0(5) . . ?
C8 C4 H4 126.3 . . ?
C5 C4 H4 126.3 . . ?
Mo1 C4 H4 120.9 . . ?
C6 C5 C4 107.8(10) . . ?
C6 C5 Mo1 72.2(6) . . ?
C4 C5 Mo1 73.1(5) . . ?
C6 C5 H5 126.1 . . ?
C4 C5 H5 126.1 . . ?
Mo1 C5 H5 120.4 . . ?
C5 C6 C7 108.0(10) . . ?
C5 C6 Mo1 73.6(6) . . ?
C7 C6 Mo1 72.7(6) . . ?
C5 C6 H6 126.0 . . ?
C7 C6 H6 126.0 . . ?
Mo1 C6 H6 119.6 . . ?
C8 C7 C6 108.3(10) . . ?
C8 C7 Mo1 73.8(6) . . ?
C6 C7 Mo1 72.6(6) . . ?
C8 C7 H7 125.8 . . ?
C6 C7 H7 125.8 . . ?
Mo1 C7 H7 119.6 . . ?
C7 C8 C4 108.6(9) . . ?
C7 C8 Mo1 72.1(5) . . ?
C4 C8 Mo1 73.4(5) . . ?
C7 C8 H8 125.7 . . ?
C4 C8 H8 125.7 . . ?
Mo1 C8 H8 120.6 . . ?
O4 C9 Mo2 174.3(7) . . ?
O4 C9 Ag 112.6(6) . . ?
Mo2 C9 Ag 73.0(2) . . ?
O5 C10 Mo2 173.0(8) . . ?
O5 C10 Ag 113.4(7) . . ?
Mo2 C10 Ag 73.3(3) . . ?
O6 C11 Mo2 178.6(9) . . ?
C16 C12 C13 107.6(10) . . ?
C16 C12 Mo2 73.8(6) . . ?
C13 C12 Mo2 73.0(5) . . ?
C16 C12 H12 126.2 . . ?
C13 C12 H12 126.2 . . ?
Mo2 C12 H12 119.0 . . ?
C14 C13 C12 108.2(10) . . ?
C14 C13 Mo2 72.9(5) . . ?
C12 C13 Mo2 72.2(5) . . ?
C14 C13 H13 125.9 . . ?
C12 C13 H13 125.9 . . ?
Mo2 C13 H13 120.7 . . ?
C13 C14 C15 108.6(9) . . ?
C13 C14 Mo2 72.8(6) . . ?
C15 C14 Mo2 74.1(5) . . ?
C13 C14 H14 125.7 . . ?
C15 C14 H14 125.7 . . ?
Mo2 C14 H14 119.3 . . ?
C16 C15 C14 106.7(10) . . ?
C16 C15 Mo2 72.0(6) . . ?
C14 C15 Mo2 71.3(6) . . ?
C16 C15 H15 126.7 . . ?
C14 C15 H15 126.7 . . ?
Mo2 C15 H15 121.8 . . ?
C12 C16 C15 108.9(10) . . ?
C12 C16 Mo2 71.8(6) . . ?
C15 C16 Mo2 73.7(6) . . ?
C12 C16 H16 125.6 . . ?
C15 C16 H16 125.6 . . ?
Mo2 C16 H16 120.6 . . ?
O7 C17 H17A 109.5 . . ?
O7 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
O7 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
O7 C18 C19 110.6(7) . . ?
O7 C18 Na 44.1(3) . . ?
C19 C18 Na 76.3(5) . . ?
O7 C18 H18A 109.5 . . ?
C19 C18 H18A 109.5 . . ?
Na C18 H18A 149.7 . . ?
O7 C18 H18B 109.5 . . ?
C19 C18 H18B 109.5 . . ?
Na C18 H18B 97.0 . . ?
H18A C18 H18B 108.1 . . ?
O8 C19 C18 110.8(8) . . ?
O8 C19 Na 42.1(4) . . ?
C18 C19 Na 76.0(5) . . ?
O8 C19 H19A 109.5 . . ?
C18 C19 H19A 109.5 . . ?
Na C19 H19A 146.0 . . ?
O8 C19 H19B 109.5 . . ?
C18 C19 H19B 109.5 . . ?
Na C19 H19B 100.9 . . ?
H19A C19 H19B 108.1 . . ?
O8 C20 H20A 109.5 . . ?
O8 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
O8 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag C1 2.561(8) . ?
Ag C2 2.563(9) . ?
Ag C10 2.621(9) . ?
Ag C9 2.637(8) . ?
Ag Mo2 2.7846(11) . ?
Ag Mo1 2.7891(9) . ?
Mo1 C3 1.932(10) . ?
Mo1 C1 1.943(8) . ?
Mo1 C2 1.961(9) . ?
Mo1 C6 2.338(10) . ?
Mo1 C7 2.339(10) . ?
Mo1 C5 2.357(9) . ?
Mo1 C8 2.361(9) . ?
Mo1 C4 2.371(9) . ?
Mo2 C9 1.949(8) . ?
Mo2 C11 1.952(10) . ?
Mo2 C10 1.956(8) . ?
Mo2 C12 2.332(9) . ?
Mo2 C13 2.342(9) . ?
Mo2 C14 2.344(9) . ?
Mo2 C16 2.357(9) . ?
Mo2 C15 2.380(10) . ?
Na O8 2.277(7) . ?
Na O4 2.313(6) . ?
Na O7 2.316(6) . ?
Na O5 2.336(6) 2_554 ?
Na O3 2.369(6) 4_454 ?
Na O1 2.441(6) . ?
Na C18 3.107(8) . ?
Na C19 3.111(10) . ?
O1 C1 1.187(8) . ?
O2 C2 1.169(10) . ?
O3 C3 1.176(10) . ?
O3 Na 2.369(6) 4 ?
O4 C9 1.165(8) . ?
O5 C10 1.169(8) . ?
O5 Na 2.336(6) 2 ?
O6 C11 1.146(10) . ?
O7 C18 1.398(9) . ?
O7 C17 1.426(10) . ?
O8 C20 1.381(10) . ?
O8 C19 1.395(11) . ?
C4 C8 1.387(13) . ?
C4 C5 1.415(15) . ?
C4 H4 0.9500 . ?
C5 C6 1.382(16) . ?
C5 H5 0.9500 . ?
C6 C7 1.397(15) . ?
C6 H6 0.9500 . ?
C7 C8 1.379(14) . ?
C7 H7 0.9500 . ?
C8 H8 0.9500 . ?
C12 C16 1.390(15) . ?
C12 C13 1.396(13) . ?
C12 H12 0.9500 . ?
C13 C14 1.381(15) . ?
C13 H13 0.9500 . ?
C14 C15 1.405(16) . ?
C14 H14 0.9500 . ?
C15 C16 1.396(14) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 C19 1.487(12) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
