#------------------------------------------------------------------------------
#$Date: 2021-04-16 11:46:56 +0300 (Fri, 16 Apr 2021) $
#$Revision: 264242 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/31/51/4315151.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4315151
loop_
_publ_author_name
'Sayandev Chatterjee'
'Jeanette A. Krause'
'William B. Connick'
'Caroline Genre'
'Alexandre Rodrigue-Witchel'
'Christian Reber'
_publ_contact_author_address
;     Department of Chemistry
      University of Cincinnati
      Cincinnati, OH 45221-0172 USA
;
_publ_contact_author_email       bill.connick@uc.edu
_publ_contact_author_fax         '513 556 9239'
_publ_contact_author_name        'Dr. William B. Connick'
_publ_contact_author_phone       '513 556 0148'
_publ_section_title
;
 Interaction of SbCl52- and Thioether Groups at the Open Coordination
 Sites of Platinum(II) Diimine Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2808
_journal_page_last               2815
_journal_paper_doi               10.1021/ic9021917
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety         'C16 H20 N2 S3 Pt, Sb Cl4, Sb Cl3, Cl'
_chemical_formula_sum            'C16 H20 Cl8 N2 Pt S3 Sb2'
_chemical_formula_weight         1058.71
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.751(1)
_cell_angle_beta                 95.230(1)
_cell_angle_gamma                109.032(1)
_cell_formula_units_Z            2
_cell_length_a                   10.9771(9)
_cell_length_b                   11.7655(10)
_cell_length_c                   12.3481(10)
_cell_measurement_reflns_used    5212
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      31.12
_cell_measurement_theta_min      2.36
_cell_volume                     1431.2(2)
_computing_cell_refinement       'SAINT v7.23A'
_computing_data_collection       'APEX2 v2.0-2'
_computing_data_reduction        'SAINT v7.23A'
_computing_molecular_graphics    'Bruker SHELXTL v6.14'
_computing_publication_material  'Bruker SHELXTL v6.14'
_computing_structure_refinement  'Bruker SHELXTL v6.14'
_computing_structure_solution    'Bruker SHELXTL v6.14'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker Platinum 200'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  'Si-<111> channel cut crystal'
_diffrn_radiation_source         synchrotron
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.77490
_diffrn_reflns_av_R_equivalents  0.0334
_diffrn_reflns_av_sigmaI/netI    0.0388
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            16259
_diffrn_reflns_theta_full        31.10
_diffrn_reflns_theta_max         31.10
_diffrn_reflns_theta_min         1.89
_exptl_absorpt_coefficient_mu    9.616
_exptl_absorpt_correction_T_max  0.8309
_exptl_absorpt_correction_T_min  0.3916
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2.10 (Sheldrick)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.457
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blade
_exptl_crystal_F_000             988
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.696
_refine_diff_density_min         -2.044
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.067
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         7053
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.067
_refine_ls_R_factor_all          0.0289
_refine_ls_R_factor_gt           0.0271
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0382P)²+0.5852P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0706
_refine_ls_wR_factor_ref         0.0717
_reflns_number_gt                6668
_reflns_number_total             7053
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            ic9021917_si_002_1.cif
_cod_data_source_block           bpyPtttcnSb4Cl16
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

2021-04-13
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_sum            'C32 H40 Cl16 N4 Pt2 S6 Sb4'
_cod_original_formula_weight         2117.42
_cod_original_formula_moiety         '2(C16 H20 N2 S3 Pt), Sb4 Cl16'
_cod_original_formula_units_Z            1
_cod_database_code               4315151
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt 0.591324(12) 0.824705(12) 0.638289(11) 0.02123(5) Uani 1 1 d . . .
S1 S 0.80479(8) 0.91079(8) 0.72468(7) 0.02402(17) Uani 1 1 d . . .
S2 S 0.53978(9) 0.77948(8) 0.79894(8) 0.02521(17) Uani 1 1 d . . .
S3 S 0.64478(10) 0.58469(9) 0.59256(8) 0.02956(19) Uani 1 1 d . . .
N1 N 0.6184(3) 0.8870(3) 0.4990(3) 0.0239(6) Uani 1 1 d . . .
N2 N 0.4017(3) 0.7572(3) 0.5527(3) 0.0253(6) Uani 1 1 d . . .
C1 C 0.7295(4) 0.9659(4) 0.4836(3) 0.0290(7) Uani 1 1 d . . .
H1 H 0.8062 0.9959 0.5407 0.035 Uiso 1 1 calc R . .
C2 C 0.7370(4) 1.0054(4) 0.3878(4) 0.0340(8) Uani 1 1 d . . .
H2 H 0.8175 1.0616 0.3791 0.041 Uiso 1 1 calc R . .
C3 C 0.6262(5) 0.9625(4) 0.3051(4) 0.0372(9) Uani 1 1 d . . .
H3 H 0.6294 0.9882 0.2380 0.045 Uiso 1 1 calc R . .
C4 C 0.5110(5) 0.8821(4) 0.3203(3) 0.0354(9) Uani 1 1 d . . .
H4 H 0.4336 0.8517 0.2638 0.043 Uiso 1 1 calc R . .
C5 C 0.5082(4) 0.8456(3) 0.4183(3) 0.0275(7) Uani 1 1 d . . .
C6 C 0.3891(4) 0.7672(3) 0.4455(3) 0.0295(8) Uani 1 1 d . . .
C7 C 0.2679(4) 0.7102(4) 0.3724(4) 0.0383(9) Uani 1 1 d . . .
H7 H 0.2602 0.7134 0.2961 0.046 Uiso 1 1 calc R . .
C8 C 0.1580(5) 0.6485(4) 0.4114(4) 0.0437(11) Uani 1 1 d . . .
H8 H 0.0742 0.6098 0.3625 0.052 Uiso 1 1 calc R . .
C9 C 0.1724(4) 0.6445(4) 0.5214(4) 0.0389(10) Uani 1 1 d . . .
H9 H 0.0979 0.6050 0.5504 0.047 Uiso 1 1 calc R . .
C10 C 0.2955(4) 0.6980(4) 0.5902(4) 0.0331(8) Uani 1 1 d . . .
H10 H 0.3051 0.6927 0.6658 0.040 Uiso 1 1 calc R . .
C11 C 0.8067(4) 0.9115(4) 0.8733(3) 0.0277(7) Uani 1 1 d . . .
H11A H 0.8284 0.8392 0.8842 0.033 Uiso 1 1 calc R . .
H11B H 0.8753 0.9900 0.9242 0.033 Uiso 1 1 calc R . .
C12 C 0.6746(4) 0.9026(4) 0.9046(3) 0.0272(7) Uani 1 1 d . . .
H12A H 0.6637 0.9845 0.9130 0.033 Uiso 1 1 calc R . .
H12B H 0.6720 0.8858 0.9791 0.033 Uiso 1 1 calc R . .
C13 C 0.5722(4) 0.6402(4) 0.8111(3) 0.0299(8) Uani 1 1 d . . .
H13A H 0.6641 0.6676 0.8509 0.036 Uiso 1 1 calc R . .
H13B H 0.5146 0.6020 0.8594 0.036 Uiso 1 1 calc R . .
C14 C 0.5520(4) 0.5396(4) 0.6991(3) 0.0323(8) Uani 1 1 d . . .
H14A H 0.4575 0.5055 0.6643 0.039 Uiso 1 1 calc R . .
H14B H 0.5730 0.4698 0.7167 0.039 Uiso 1 1 calc R . .
C15 C 0.8124(4) 0.6620(4) 0.6715(3) 0.0293(7) Uani 1 1 d . . .
H15A H 0.8127 0.6629 0.7519 0.035 Uiso 1 1 calc R . .
H15B H 0.8649 0.6119 0.6396 0.035 Uiso 1 1 calc R . .
C16 C 0.8775(4) 0.7955(4) 0.6688(3) 0.0282(7) Uani 1 1 d . . .
H16A H 0.8824 0.7922 0.5884 0.034 Uiso 1 1 calc R . .
H16B H 0.9688 0.8276 0.7114 0.034 Uiso 1 1 calc R . .
Sb1 Sb 0.15488(2) 0.65039(2) 0.961246(19) 0.02220(6) Uani 1 1 d . . .
Sb2 Sb 0.13799(2) 0.28769(2) 0.82152(2) 0.02342(6) Uani 1 1 d . . .
Cl1 Cl 0.15619(10) 0.79787(9) 1.15101(8) 0.03232(19) Uani 1 1 d . . .
Cl2 Cl 0.15621(12) 0.80985(9) 0.87140(9) 0.0398(2) Uani 1 1 d . . .
Cl3 Cl 0.38835(10) 0.73329(12) 1.01930(9) 0.0417(2) Uani 1 1 d . . .
Cl4 Cl 0.12388(9) 0.09185(8) 0.86019(8) 0.02892(18) Uani 1 1 d . . .
Cl5 Cl 0.06924(11) 0.17829(10) 0.61722(8) 0.0354(2) Uani 1 1 d . . .
Cl6 Cl 0.36652(10) 0.33797(10) 0.83112(12) 0.0448(3) Uani 1 1 d . . .
Cl7 Cl 0.18282(10) 0.51647(9) 0.75490(8) 0.0351(2) Uani 1 1 d . . .
Cl8 Cl 0.15280(11) 0.43473(12) 1.06801(10) 0.0466(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C -0.0020 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N -0.0031 0.0040 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1206 0.1480 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -2.9671 9.6560 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.7961 1.8109 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1408 0.1896 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Pt N1 79.75(13) . . ?
N2 Pt S2 95.28(9) . . ?
N1 Pt S2 169.37(8) . . ?
N2 Pt S1 175.30(9) . . ?
N1 Pt S1 95.86(9) . . ?
S2 Pt S1 88.77(3) . . ?
N2 Pt S3 100.09(8) . . ?
N1 Pt S3 107.24(8) . . ?
S2 Pt S3 82.80(3) . . ?
S1 Pt S3 82.76(3) . . ?
C16 S1 C11 103.06(17) . . ?
C16 S1 Pt 106.31(13) . . ?
C11 S1 Pt 105.90(12) . . ?
C12 S2 C13 100.48(18) . . ?
C12 S2 Pt 100.58(13) . . ?
C13 S2 Pt 111.65(13) . . ?
C15 S3 C14 103.30(19) . . ?
C15 S3 Pt 93.74(12) . . ?
C14 S3 Pt 90.72(13) . . ?
C1 N1 C5 118.9(3) . . ?
C1 N1 Pt 126.7(3) . . ?
C5 N1 Pt 114.4(3) . . ?
C10 N2 C6 119.8(3) . . ?
C10 N2 Pt 125.7(3) . . ?
C6 N2 Pt 114.2(3) . . ?
N1 C1 C2 122.3(4) . . ?
C3 C2 C1 119.0(4) . . ?
C4 C3 C2 119.2(4) . . ?
C3 C4 C5 119.6(4) . . ?
N1 C5 C4 120.8(4) . . ?
N1 C5 C6 115.4(3) . . ?
C4 C5 C6 123.7(4) . . ?
N2 C6 C7 120.4(4) . . ?
N2 C6 C5 115.1(3) . . ?
C7 C6 C5 124.5(4) . . ?
C6 C7 C8 119.6(4) . . ?
C9 C8 C7 118.8(4) . . ?
C8 C9 C10 119.8(4) . . ?
N2 C10 C9 121.5(4) . . ?
C12 C11 S1 110.5(2) . . ?
C11 C12 S2 112.4(3) . . ?
C14 C13 S2 115.4(3) . . ?
C13 C14 S3 117.8(3) . . ?
C16 C15 S3 114.1(3) . . ?
C15 C16 S1 118.8(3) . . ?
Cl3 Sb1 Cl2 93.08(4) . . ?
Cl3 Sb1 Cl1 85.19(4) . . ?
Cl2 Sb1 Cl1 89.92(3) . . ?
Cl3 Sb1 Cl7 88.80(4) . . ?
Cl2 Sb1 Cl7 85.63(3) . . ?
Cl1 Sb1 Cl7 172.32(3) . . ?
Cl3 Sb1 Cl8 87.19(4) . . ?
Cl2 Sb1 Cl8 177.52(4) . . ?
Cl1 Sb1 Cl8 92.56(3) . . ?
Cl7 Sb1 Cl8 91.91(3) . . ?
Cl6 Sb2 Cl4 88.91(3) . . ?
Cl6 Sb2 Cl5 97.48(4) . . ?
Cl4 Sb2 Cl5 90.78(3) . . ?
Cl6 Sb2 Cl7 84.53(3) . . ?
Cl4 Sb2 Cl7 171.64(3) . . ?
Cl5 Sb2 Cl7 84.97(3) . . ?
Cl6 Sb2 Cl8 96.86(4) . . ?
Cl4 Sb2 Cl8 95.70(3) . . ?
Cl5 Sb2 Cl8 164.37(3) . . ?
Cl7 Sb2 Cl8 90.23(3) . . ?
Cl6 Sb2 Cl1 168.91(4) . 2_567 ?
Cl4 Sb2 Cl1 82.67(3) . 2_567 ?
Cl5 Sb2 Cl1 89.86(3) . 2_567 ?
Cl7 Sb2 Cl1 104.47(3) . 2_567 ?
Cl8 Sb2 Cl1 76.93(3) . 2_567 ?
Sb1 Cl7 Sb2 93.28(3) . . ?
Sb2 Cl8 Sb1 83.17(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt N2 2.043(3) . ?
Pt N1 2.044(3) . ?
Pt S2 2.2549(9) . ?
Pt S1 2.2585(9) . ?
Pt S3 2.9944(10) . ?
S1 C16 1.811(4) . ?
S1 C11 1.832(4) . ?
S2 C12 1.811(4) . ?
S2 C13 1.824(4) . ?
S3 C15 1.814(4) . ?
S3 C14 1.816(4) . ?
N1 C1 1.334(5) . ?
N1 C5 1.358(5) . ?
N2 C10 1.338(5) . ?
N2 C6 1.357(5) . ?
C1 C2 1.376(5) . ?
C2 C3 1.374(6) . ?
C3 C4 1.372(7) . ?
C4 C5 1.383(5) . ?
C5 C6 1.458(6) . ?
C6 C7 1.388(5) . ?
C7 C8 1.388(7) . ?
C8 C9 1.368(7) . ?
C9 C10 1.382(6) . ?
C11 C12 1.513(5) . ?
C13 C14 1.517(6) . ?
C15 C16 1.509(5) . ?
Sb1 Cl3 2.3899(10) . ?
Sb1 Cl2 2.4075(9) . ?
Sb1 Cl1 2.5315(10) . ?
Sb1 Cl7 2.7353(11) . ?
Sb1 Cl8 3.1380(12) . ?
Sb2 Cl6 2.3662(11) . ?
Sb2 Cl4 2.4295(9) . ?
Sb2 Cl5 2.4405(10) . ?
Sb2 Cl7 2.9158(10) . ?
Sb2 Cl8 3.0542(13) . ?
Sb2 Cl1 3.1321(11) 2_567 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 Pt S1 C16 -108.3(11) . . . . ?
N1 Pt S1 C16 -87.46(15) . . . . ?
S2 Pt S1 C16 102.13(13) . . . . ?
S3 Pt S1 C16 19.23(13) . . . . ?
N2 Pt S1 C11 142.5(11) . . . . ?
N1 Pt S1 C11 163.38(15) . . . . ?
S2 Pt S1 C11 -7.03(14) . . . . ?
S3 Pt S1 C11 -89.93(14) . . . . ?
N2 Pt S2 C12 -150.05(15) . . . . ?
N1 Pt S2 C12 -88.5(5) . . . . ?
S1 Pt S2 C12 27.56(13) . . . . ?
S3 Pt S2 C12 110.42(13) . . . . ?
N2 Pt S2 C13 104.10(17) . . . . ?
N1 Pt S2 C13 165.7(5) . . . . ?
S1 Pt S2 C13 -78.30(15) . . . . ?
S3 Pt S2 C13 4.56(15) . . . . ?
N2 Pt S3 C15 179.44(16) . . . . ?
N1 Pt S3 C15 97.14(16) . . . . ?
S2 Pt S3 C15 -86.44(13) . . . . ?
S1 Pt S3 C15 3.23(13) . . . . ?
N2 Pt S3 C14 -77.18(17) . . . . ?
N1 Pt S3 C14 -159.48(17) . . . . ?
S2 Pt S3 C14 16.93(14) . . . . ?
S1 Pt S3 C14 106.61(14) . . . . ?
N2 Pt N1 C1 171.1(3) . . . . ?
S2 Pt N1 C1 108.2(5) . . . . ?
S1 Pt N1 C1 -7.2(3) . . . . ?
S3 Pt N1 C1 -91.5(3) . . . . ?
N2 Pt N1 C5 -6.0(2) . . . . ?
S2 Pt N1 C5 -68.9(6) . . . . ?
S1 Pt N1 C5 175.7(2) . . . . ?
S3 Pt N1 C5 91.5(2) . . . . ?
N1 Pt N2 C10 -175.6(3) . . . . ?
S2 Pt N2 C10 -5.1(3) . . . . ?
S1 Pt N2 C10 -154.5(9) . . . . ?
S3 Pt N2 C10 78.5(3) . . . . ?
N1 Pt N2 C6 9.7(2) . . . . ?
S2 Pt N2 C6 -179.8(2) . . . . ?
S1 Pt N2 C6 30.8(12) . . . . ?
S3 Pt N2 C6 -96.2(2) . . . . ?
C5 N1 C1 C2 -1.0(5) . . . . ?
Pt N1 C1 C2 -178.0(3) . . . . ?
N1 C1 C2 C3 0.1(6) . . . . ?
C1 C2 C3 C4 0.4(6) . . . . ?
C2 C3 C4 C5 -0.1(6) . . . . ?
C1 N1 C5 C4 1.4(5) . . . . ?
Pt N1 C5 C4 178.7(3) . . . . ?
C1 N1 C5 C6 -175.7(3) . . . . ?
Pt N1 C5 C6 1.6(4) . . . . ?
C3 C4 C5 N1 -0.9(6) . . . . ?
C3 C4 C5 C6 175.9(4) . . . . ?
C10 N2 C6 C7 -3.6(5) . . . . ?
Pt N2 C6 C7 171.4(3) . . . . ?
C10 N2 C6 C5 173.3(3) . . . . ?
Pt N2 C6 C5 -11.6(4) . . . . ?
N1 C5 C6 N2 6.7(5) . . . . ?
C4 C5 C6 N2 -170.3(3) . . . . ?
N1 C5 C6 C7 -176.5(4) . . . . ?
C4 C5 C6 C7 6.5(6) . . . . ?
N2 C6 C7 C8 3.5(6) . . . . ?
C5 C6 C7 C8 -173.2(4) . . . . ?
C6 C7 C8 C9 -0.6(7) . . . . ?
C7 C8 C9 C10 -1.9(7) . . . . ?
C6 N2 C10 C9 1.0(6) . . . . ?
Pt N2 C10 C9 -173.4(3) . . . . ?
C8 C9 C10 N2 1.8(6) . . . . ?
C16 S1 C11 C12 -132.3(3) . . . . ?
Pt S1 C11 C12 -20.9(3) . . . . ?
S1 C11 C12 S2 47.5(3) . . . . ?
C13 S2 C12 C11 64.8(3) . . . . ?
Pt S2 C12 C11 -49.8(3) . . . . ?
C12 S2 C13 C14 -139.0(3) . . . . ?
Pt S2 C13 C14 -33.1(3) . . . . ?
S2 C13 C14 S3 57.4(4) . . . . ?
C15 S3 C14 C13 51.1(3) . . . . ?
Pt S3 C14 C13 -42.9(3) . . . . ?
C14 S3 C15 C16 -122.9(3) . . . . ?
Pt S3 C15 C16 -31.2(3) . . . . ?
S3 C15 C16 S1 59.7(4) . . . . ?
C11 S1 C16 C15 59.4(3) . . . . ?
Pt S1 C16 C15 -51.7(3) . . . . ?
