#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:16:01 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179238 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/58/4315869.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4315869
loop_
_publ_author_name
'Svetlana N. Ignatieva'
'Anna S. Balueva'
'Andrey A. Karasik'
'Shamil K. Latypov'
'Anna G. Nikonova'
'Olga E. Naumova'
'Peter Lönnecke'
'Evamarie Hey-Hawkins'
'Oleg G. Sinyashin'
_publ_section_title
;
 First Representative of Optically Active P-l-Menthyl-Substituted
 (Aminomethyl)phosphine and Its Borane and Metal Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5407
_journal_page_last               5412
_journal_paper_doi               10.1021/ic902564n
_journal_volume                  49
_journal_year                    2010
_chemical_absolute_configuration rmad
_chemical_formula_sum            'C40 H64 Cl6 N2 P2 Pt'
_chemical_formula_weight         1042.66
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2007-10-10T10:54:36-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.10170(10)
_cell_length_b                   21.4564(2)
_cell_length_c                   25.1560(2)
_cell_measurement_reflns_used    92476
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      32.2918
_cell_measurement_theta_min      2.5974
_cell_volume                     4372.95(8)
_computing_cell_refinement
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
        (compiled May  8 2007,13:10:02)
;
_computing_data_collection
;
        CrysAlis CCD, Oxford Diffraction Ltd.,
        Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
        (compiled May  8 2007,13:10:02)
;
_computing_data_reduction
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
        (compiled May  8 2007,13:10:02)
;
_computing_molecular_graphics    'ORTEP3 for Windows (L. J. Farrugia, 1997)'
_computing_publication_material  'WINGX  (L.J. Farrugia,1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Giacovazzo 1993)'
_diffrn_ambient_temperature      130(2)
_diffrn_detector_area_resol_mean 16.356
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'ccd Xcalibur S'
_diffrn_measurement_method       'ω- amd φ-scans'
_diffrn_orient_matrix_UB_11      0.0125734668
_diffrn_orient_matrix_UB_12      -0.0128276557
_diffrn_orient_matrix_UB_13      -0.025632019
_diffrn_orient_matrix_UB_21      0.0212010663
_diffrn_orient_matrix_UB_22      -0.0289795662
_diffrn_orient_matrix_UB_23      0.0116097426
_diffrn_orient_matrix_UB_31      -0.0838517873
_diffrn_orient_matrix_UB_32      -0.0092738299
_diffrn_orient_matrix_UB_33      -0.0009651859
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0337
_diffrn_reflns_av_unetI/netI     0.0182
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            142867
_diffrn_reflns_theta_full        30.51
_diffrn_reflns_theta_max         30.51
_diffrn_reflns_theta_min         2.61
_exptl_absorpt_coefficient_mu    3.68
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.64023
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlis RED, Oxford Diffraction Ltd.,
        Version 1.171.32.5 (release 08-05-2007 CrysAlis171 .NET)
        (compiled May  8 2007,13:10:02)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.584
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2112
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.2
_refine_diff_density_min         -0.814
_refine_diff_density_rms         0.077
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.014(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.107
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     468
_refine_ls_number_reflns         13363
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.107
_refine_ls_R_factor_all          0.0199
_refine_ls_R_factor_gt           0.0176
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0163P)²+2.0700P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0367
_refine_ls_wR_factor_ref         0.038
_reflns_number_gt                12776
_reflns_number_total             13363
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic902564n_si_001.cif
_cod_data_source_block           x0314fin
_cod_database_code               4315869
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.939311(9) 0.989759(3) 0.560498(3) 0.01217(2) Uani 1 1 d . . .
Cl1 Cl 1.15245(6) 0.91538(2) 0.55170(2) 0.02156(11) Uani 1 1 d . . .
Cl2 Cl 1.10925(6) 1.04069(2) 0.62246(2) 0.01917(10) Uani 1 1 d . . .
P1 P 0.77171(6) 0.94106(2) 0.50390(2) 0.01195(9) Uani 1 1 d . . .
P2 P 0.72529(6) 1.05286(2) 0.57470(2) 0.01263(10) Uani 1 1 d . . .
N1 N 0.5517(2) 1.03467(8) 0.48207(6) 0.0150(3) Uani 1 1 d . . .
N2 N 0.5904(2) 0.93583(8) 0.59767(7) 0.0147(3) Uani 1 1 d . . .
C1 C 0.6693(2) 0.99378(10) 0.45608(7) 0.0157(4) Uani 1 1 d . . .
H1A H 0.7539 1.0193 0.4378 0.019 Uiso 1 1 calc R . .
H1B H 0.6114 0.9686 0.4288 0.019 Uiso 1 1 calc R . .
C2 C 0.6258(3) 1.08406(10) 0.51419(8) 0.0162(4) Uani 1 1 d . . .
H2A H 0.5392 1.1143 0.5245 0.019 Uiso 1 1 calc R . .
H2B H 0.709 1.1065 0.4926 0.019 Uiso 1 1 calc R . .
C3 C 0.5535(3) 1.00179(8) 0.60006(7) 0.0159(4) Uani 1 1 d . . .
H3A H 0.5295 1.0132 0.6374 0.019 Uiso 1 1 calc R . .
H3B H 0.4528 1.01 0.5789 0.019 Uiso 1 1 calc R . .
C4 C 0.5948(2) 0.91021(10) 0.54480(8) 0.0149(4) Uani 1 1 d . . .
H4A H 0.4898 0.9201 0.5265 0.018 Uiso 1 1 calc R . .
H4B H 0.604 0.8643 0.5472 0.018 Uiso 1 1 calc R . .
C5 C 0.8730(3) 0.88378(9) 0.45973(8) 0.0147(4) Uani 1 1 d . . .
H5 H 0.9333 0.8537 0.4831 0.018 Uiso 1 1 calc R . .
C6 C 0.7678(3) 0.84472(10) 0.42048(8) 0.0172(4) Uani 1 1 d . . .
H6 H 0.7202 0.8744 0.3939 0.021 Uiso 1 1 calc R . .
C7 C 0.8846(3) 0.80090(11) 0.39010(10) 0.0233(5) Uani 1 1 d . . .
H7A H 0.9309 0.7701 0.4153 0.028 Uiso 1 1 calc R . .
H7B H 0.8201 0.7777 0.3631 0.028 Uiso 1 1 calc R . .
C8 C 1.0255(3) 0.83435(11) 0.36263(9) 0.0243(5) Uani 1 1 d . . .
H8A H 1.1012 0.8031 0.3471 0.029 Uiso 1 1 calc R . .
H8B H 0.9806 0.8598 0.3331 0.029 Uiso 1 1 calc R . .
C9 C 1.1214(3) 0.87594(11) 0.39955(10) 0.0219(5) Uani 1 1 d . . .
H9 H 1.177 0.8492 0.4268 0.026 Uiso 1 1 calc R . .
C10 C 1.0040(3) 0.92005(10) 0.42811(8) 0.0177(4) Uani 1 1 d . . .
H10A H 0.9487 0.9472 0.4017 0.021 Uiso 1 1 calc R . .
H10B H 1.0675 0.947 0.4526 0.021 Uiso 1 1 calc R . .
C11 C 0.6222(3) 0.80870(10) 0.44523(9) 0.0203(4) Uani 1 1 d . . .
H11 H 0.5477 0.84 0.4624 0.024 Uiso 1 1 calc R . .
C12 C 0.5220(3) 0.77519(13) 0.40243(10) 0.0307(6) Uani 1 1 d . . .
H12A H 0.5121 0.8021 0.3711 0.046 Uiso 1 1 calc R . .
H12B H 0.4117 0.7656 0.4162 0.046 Uiso 1 1 calc R . .
H12C H 0.5778 0.7364 0.3925 0.046 Uiso 1 1 calc R . .
C13 C 0.6748(3) 0.76246(11) 0.48812(10) 0.0272(5) Uani 1 1 d . . .
H13A H 0.5774 0.7484 0.5079 0.041 Uiso 1 1 calc R . .
H13B H 0.7522 0.7827 0.5125 0.041 Uiso 1 1 calc R . .
H13C H 0.7285 0.7265 0.4715 0.041 Uiso 1 1 calc R . .
C14 C 1.2535(4) 0.91308(13) 0.37018(12) 0.0350(6) Uani 1 1 d . . .
H14A H 1.3239 0.8845 0.35 0.053 Uiso 1 1 calc R . .
H14B H 1.3208 0.9361 0.3959 0.053 Uiso 1 1 calc R . .
H14C H 1.2005 0.9425 0.3458 0.053 Uiso 1 1 calc R . .
C15 C 0.4171(2) 1.05568(9) 0.44959(8) 0.0149(4) Uani 1 1 d . . .
C16 C 0.4320(3) 1.06549(10) 0.39505(8) 0.0190(4) Uani 1 1 d . . .
H16 H 0.5369 1.0621 0.3784 0.023 Uiso 1 1 calc R . .
C17 C 0.2931(3) 1.08028(11) 0.36509(9) 0.0207(4) Uani 1 1 d . . .
H17 H 0.3041 1.086 0.3278 0.025 Uiso 1 1 calc R . .
C18 C 0.1394(3) 1.08680(10) 0.38831(9) 0.0197(4) Uani 1 1 d . . .
C19 C 0.1290(3) 1.08034(10) 0.44314(10) 0.0201(4) Uani 1 1 d . . .
H19 H 0.0256 1.0867 0.4601 0.024 Uiso 1 1 calc R . .
C20 C 0.2648(3) 1.06490(10) 0.47366(9) 0.0186(4) Uani 1 1 d . . .
H20 H 0.254 1.0606 0.5111 0.022 Uiso 1 1 calc R . .
C21 C -0.0142(3) 1.09708(12) 0.35576(10) 0.0264(5) Uani 1 1 d . . .
H21A H 0.0157 1.1157 0.3215 0.04 Uiso 1 1 calc R . .
H21B H -0.0889 1.1251 0.3749 0.04 Uiso 1 1 calc R . .
H21C H -0.0694 1.0571 0.3497 0.04 Uiso 1 1 calc R . .
C22 C 0.7488(3) 1.12330(9) 0.61744(8) 0.0161(4) Uani 1 1 d . . .
H22 H 0.8408 1.1152 0.643 0.019 Uiso 1 1 calc R . .
C23 C 0.7931(3) 1.18278(10) 0.58529(9) 0.0200(4) Uani 1 1 d . . .
H23 H 0.7015 1.1896 0.5593 0.024 Uiso 1 1 calc R . .
C24 C 0.7960(4) 1.23956(11) 0.62210(10) 0.0304(6) Uani 1 1 d . . .
H24A H 0.8865 1.2346 0.6482 0.036 Uiso 1 1 calc R . .
H24B H 0.8191 1.2773 0.6008 0.036 Uiso 1 1 calc R . .
C25 C 0.6353(4) 1.24834(12) 0.65157(11) 0.0341(6) Uani 1 1 d . . .
H25A H 0.5452 1.2558 0.6258 0.041 Uiso 1 1 calc R . .
H25B H 0.6436 1.2853 0.6749 0.041 Uiso 1 1 calc R . .
C26 C 0.5953(3) 1.19128(11) 0.68482(9) 0.0273(5) Uani 1 1 d . . .
H26 H 0.6852 1.1858 0.7117 0.033 Uiso 1 1 calc R . .
C27 C 0.5902(3) 1.13299(11) 0.64984(9) 0.0230(5) Uani 1 1 d . . .
H27A H 0.4954 1.1362 0.6251 0.028 Uiso 1 1 calc R . .
H27B H 0.5719 1.0961 0.6727 0.028 Uiso 1 1 calc R . .
C28 C 0.9542(3) 1.17792(10) 0.55271(9) 0.0232(4) Uani 1 1 d . . .
H28 H 0.964 1.1338 0.5403 0.028 Uiso 1 1 calc R . .
C29 C 0.9464(4) 1.21916(11) 0.50308(10) 0.0312(5) Uani 1 1 d . . .
H29A H 0.8517 1.2069 0.4813 0.047 Uiso 1 1 calc R . .
H29B H 1.0482 1.2142 0.4825 0.047 Uiso 1 1 calc R . .
H29C H 0.9344 1.2629 0.5138 0.047 Uiso 1 1 calc R . .
C30 C 1.1104(3) 1.19299(13) 0.58396(12) 0.0324(6) Uani 1 1 d . . .
H30A H 1.115 1.2379 0.591 0.049 Uiso 1 1 calc R . .
H30B H 1.2074 1.1805 0.5632 0.049 Uiso 1 1 calc R . .
H30C H 1.1092 1.1702 0.6177 0.049 Uiso 1 1 calc R . .
C31 C 0.4335(4) 1.19833(14) 0.71429(10) 0.0386(6) Uani 1 1 d . . .
H31A H 0.4402 1.2341 0.7384 0.058 Uiso 1 1 calc R . .
H31B H 0.4114 1.1604 0.7348 0.058 Uiso 1 1 calc R . .
H31C H 0.3441 1.205 0.6887 0.058 Uiso 1 1 calc R . .
C32 C 0.6835(2) 0.90852(10) 0.63889(8) 0.0152(4) Uani 1 1 d . . .
C33 C 0.7333(3) 0.94261(11) 0.68305(9) 0.0227(5) Uani 1 1 d . . .
H33 H 0.7162 0.9864 0.6837 0.027 Uiso 1 1 calc R . .
C34 C 0.8076(3) 0.91373(12) 0.72608(10) 0.0263(5) Uani 1 1 d . . .
H34 H 0.8395 0.9384 0.7557 0.032 Uiso 1 1 calc R . .
C35 C 0.8367(3) 0.85048(11) 0.72741(9) 0.0209(4) Uani 1 1 d . . .
C36 C 0.7915(3) 0.81701(11) 0.68272(10) 0.0246(5) Uani 1 1 d . . .
H36 H 0.8127 0.7735 0.6818 0.03 Uiso 1 1 calc R . .
C37 C 0.7168(3) 0.84474(11) 0.63938(9) 0.0232(5) Uani 1 1 d . . .
H37 H 0.6876 0.82 0.6095 0.028 Uiso 1 1 calc R . .
C38 C 0.9119(3) 0.81932(12) 0.77525(10) 0.0301(5) Uani 1 1 d . . .
H38A H 1.0319 0.8249 0.7746 0.045 Uiso 1 1 calc R . .
H38B H 0.8857 0.7747 0.7746 0.045 Uiso 1 1 calc R . .
H38C H 0.8669 0.8381 0.8077 0.045 Uiso 1 1 calc R . .
Cl3 Cl 0.31676(11) 0.84108(4) 0.70984(4) 0.0507(2) Uani 1 1 d . . .
Cl4 Cl 0.32827(9) 0.97432(4) 0.73133(3) 0.04046(17) Uani 1 1 d . . .
C39 C 0.2585(3) 0.91582(14) 0.68740(11) 0.0338(6) Uani 1 1 d . . .
H39A H 0.1368 0.918 0.6845 0.041 Uiso 1 1 calc R . .
H39B H 0.3056 0.9232 0.6516 0.041 Uiso 1 1 calc R . .
Cl5 Cl 0.02694(12) 1.14818(4) 0.74841(4) 0.0589(2) Uani 1 1 d . . .
Cl6 Cl -0.22322(11) 1.06376(4) 0.78683(4) 0.0567(2) Uani 1 1 d . . .
C40 C -0.0290(4) 1.06984(14) 0.75659(12) 0.0386(7) Uani 1 1 d . . .
H40A H 0.0545 1.0485 0.7788 0.046 Uiso 1 1 calc R . .
H40B H -0.0316 1.049 0.7215 0.046 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P2 85.023(19) . . ?
P1 Pt1 Cl2 178.05(2) . . ?
P2 Pt1 Cl2 93.840(18) . . ?
P1 Pt1 Cl1 93.944(18) . . ?
P2 Pt1 Cl1 173.91(2) . . ?
Cl2 Pt1 Cl1 87.019(18) . . ?
C1 P1 C5 102.41(9) . . ?
C1 P1 C4 103.24(9) . . ?
C5 P1 C4 115.61(9) . . ?
C1 P1 Pt1 113.74(7) . . ?
C5 P1 Pt1 115.17(7) . . ?
C4 P1 Pt1 106.23(6) . . ?
C2 P2 C22 103.06(9) . . ?
C2 P2 C3 99.64(9) . . ?
C22 P2 C3 110.60(9) . . ?
C2 P2 Pt1 115.30(7) . . ?
C22 P2 Pt1 120.36(7) . . ?
C3 P2 Pt1 106.01(6) . . ?
C15 N1 C1 115.63(15) . . ?
C15 N1 C2 113.52(16) . . ?
C1 N1 C2 114.69(17) . . ?
C32 N2 C4 120.50(16) . . ?
C32 N2 C3 119.08(17) . . ?
C4 N2 C3 114.63(16) . . ?
N1 C1 P1 111.81(13) . . ?
N1 C2 P2 111.84(14) . . ?
N2 C3 P2 113.73(14) . . ?
N2 C4 P1 112.91(13) . . ?
C10 C5 C6 108.88(17) . . ?
C10 C5 P1 106.31(14) . . ?
C6 C5 P1 119.87(15) . . ?
C7 C6 C11 111.42(18) . . ?
C7 C6 C5 107.99(18) . . ?
C11 C6 C5 115.75(17) . . ?
C8 C7 C6 113.62(19) . . ?
C9 C8 C7 112.86(19) . . ?
C8 C9 C10 109.71(19) . . ?
C8 C9 C14 111.9(2) . . ?
C10 C9 C14 110.01(19) . . ?
C9 C10 C5 111.15(18) . . ?
C13 C11 C12 109.90(19) . . ?
C13 C11 C6 113.43(19) . . ?
C12 C11 C6 110.97(19) . . ?
C20 C15 C16 119.04(19) . . ?
C20 C15 N1 118.13(17) . . ?
C16 C15 N1 122.80(19) . . ?
C17 C16 C15 119.8(2) . . ?
C18 C17 C16 121.5(2) . . ?
C17 C18 C19 117.7(2) . . ?
C17 C18 C21 122.0(2) . . ?
C19 C18 C21 120.3(2) . . ?
C20 C19 C18 121.8(2) . . ?
C19 C20 C15 120.0(2) . . ?
C27 C22 C23 111.01(18) . . ?
C27 C22 P2 109.29(15) . . ?
C23 C22 P2 112.92(14) . . ?
C24 C23 C28 111.2(2) . . ?
C24 C23 C22 110.03(19) . . ?
C28 C23 C22 114.60(18) . . ?
C25 C24 C23 112.6(2) . . ?
C24 C25 C26 110.7(2) . . ?
C31 C26 C25 112.0(2) . . ?
C31 C26 C27 109.9(2) . . ?
C25 C26 C27 110.39(19) . . ?
C26 C27 C22 113.1(2) . . ?
C30 C28 C29 109.4(2) . . ?
C30 C28 C23 114.42(19) . . ?
C29 C28 C23 111.0(2) . . ?
C33 C32 C37 117.0(2) . . ?
C33 C32 N2 121.64(19) . . ?
C37 C32 N2 121.16(19) . . ?
C34 C33 C32 121.0(2) . . ?
C35 C34 C33 122.3(2) . . ?
C34 C35 C36 116.5(2) . . ?
C34 C35 C38 121.7(2) . . ?
C36 C35 C38 121.7(2) . . ?
C37 C36 C35 122.3(2) . . ?
C36 C37 C32 120.9(2) . . ?
Cl3 C39 Cl4 111.12(15) . . ?
Cl5 C40 Cl6 110.75(17) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.2277(5) . ?
Pt1 P2 2.2288(5) . ?
Pt1 Cl2 2.3493(5) . ?
Pt1 Cl1 2.3618(5) . ?
P1 C1 1.848(2) . ?
P1 C5 1.849(2) . ?
P1 C4 1.884(2) . ?
P2 C2 1.848(2) . ?
P2 C22 1.864(2) . ?
P2 C3 1.883(2) . ?
N1 C15 1.435(2) . ?
N1 C1 1.451(3) . ?
N1 C2 1.462(3) . ?
N2 C32 1.410(3) . ?
N2 C4 1.440(3) . ?
N2 C3 1.448(2) . ?
C5 C10 1.538(3) . ?
C5 C6 1.550(3) . ?
C6 C7 1.537(3) . ?
C6 C11 1.542(3) . ?
C7 C8 1.515(3) . ?
C8 C9 1.505(3) . ?
C9 C10 1.522(3) . ?
C9 C14 1.525(3) . ?
C11 C13 1.527(3) . ?
C11 C12 1.528(3) . ?
C15 C20 1.388(3) . ?
C15 C16 1.393(3) . ?
C16 C17 1.391(3) . ?
C17 C18 1.382(3) . ?
C18 C19 1.389(3) . ?
C18 C21 1.506(3) . ?
C19 C20 1.382(3) . ?
C22 C27 1.536(3) . ?
C22 C23 1.553(3) . ?
C23 C24 1.531(3) . ?
C23 C28 1.545(3) . ?
C24 C25 1.510(4) . ?
C25 C26 1.518(4) . ?
C26 C31 1.514(4) . ?
C26 C27 1.530(3) . ?
C28 C30 1.524(3) . ?
C28 C29 1.532(3) . ?
C32 C33 1.390(3) . ?
C32 C37 1.395(3) . ?
C33 C34 1.385(3) . ?
C34 C35 1.378(3) . ?
C35 C36 1.383(3) . ?
C35 C38 1.505(3) . ?
C36 C37 1.382(3) . ?
Cl3 C39 1.764(3) . ?
Cl4 C39 1.765(3) . ?
Cl5 C40 1.753(3) . ?
Cl6 C40 1.753(3) . ?
