#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:17:18 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179239 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/59/4315976.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4315976
loop_
_publ_author_name
'Richard D. Adams'
'William C. Pearl'
_publ_section_title
;
 Reactions of the Platinum (Tri-tert-butylphosphine) Group with Bridging
 SbPh2 Ligands in Rhenium-Antimony Carbonyl Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6188
_journal_page_last               6195
_journal_paper_doi               10.1021/ic1008335
_journal_volume                  49
_journal_year                    2010
_chemical_formula_sum            'C39 H43 O9 P Pt Re2 Sb2'
_chemical_formula_weight         1497.69
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.997(4)
_cell_angle_beta                 92.866(4)
_cell_angle_gamma                105.465(4)
_cell_formula_units_Z            2
_cell_length_a                   9.2812(17)
_cell_length_b                   13.585(3)
_cell_length_c                   19.413(4)
_cell_measurement_reflns_used    4334
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      23.26
_cell_measurement_theta_min      2.29
_cell_volume                     2332.8(8)
_computing_cell_refinement       'SAINT+  V6.45 (Bruker, 2003)'
_computing_data_collection       'SMART V5.632 (Bruker, 2005)'
_computing_data_reduction        'SAINT+  V6.45'
_computing_molecular_graphics    'SHELXTL V6.1 (Sheldrick, 2000)'
_computing_publication_material  'SHELXTL V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0775
_diffrn_reflns_av_sigmaI/netI    0.0873
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            29503
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.57
_diffrn_standards_decay_%        <1
_exptl_absorpt_coefficient_mu    9.381
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.568
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 1997)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    2.132
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1388
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.06
_refine_diff_density_max         2.884
_refine_diff_density_min         -2.720
_refine_diff_density_rms         0.303
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.997
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     499
_refine_ls_number_reflns         9533
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.997
_refine_ls_R_factor_all          0.1161
_refine_ls_R_factor_gt           0.0672
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0866P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1484
_refine_ls_wR_factor_ref         0.1717
_reflns_number_gt                5880
_reflns_number_total             9533
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic1008335_si_002_2.cif
_cod_data_source_block           3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        2332.8(7)
_cod_database_code               4315976
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.75582(7) 0.02392(5) 0.34059(3) 0.0511(2) Uani 1 1 d . . .
Re1 Re 1.04224(6) 0.30900(5) 0.24466(3) 0.04537(18) Uani 1 1 d . . .
Re2 Re 0.55708(7) 0.20072(5) 0.20258(3) 0.04845(19) Uani 1 1 d . . .
Sb1 Sb 0.81296(11) 0.29747(8) 0.14544(5) 0.0440(3) Uani 1 1 d . . .
Sb2 Sb 0.78481(11) 0.20672(8) 0.30462(5) 0.0435(2) Uani 1 1 d . . .
P1 P 0.7291(5) -0.1549(3) 0.3355(2) 0.0593(12) Uani 1 1 d . . .
O1 O 0.657(3) 0.0915(13) 0.4787(10) 0.152(9) Uani 1 1 d . . .
O11 O 0.9838(18) 0.5124(11) 0.3150(7) 0.099(5) Uani 1 1 d . . .
O12 O 1.2851(14) 0.4235(12) 0.1573(7) 0.092(4) Uani 1 1 d . . .
O13 O 1.0504(17) 0.0882(10) 0.1822(7) 0.084(4) Uani 1 1 d . . .
O14 O 1.2620(16) 0.3104(13) 0.3697(7) 0.099(5) Uani 1 1 d . . .
O21 O 0.5540(18) 0.4228(11) 0.2693(8) 0.095(4) Uani 1 1 d . . .
O22 O 0.3295(15) 0.1966(12) 0.0799(7) 0.093(4) Uani 1 1 d . . .
O23 O 0.6342(17) 0.0051(10) 0.1299(7) 0.090(4) Uani 1 1 d . . .
O24 O 0.3275(16) 0.0843(12) 0.2937(8) 0.101(5) Uani 1 1 d . . .
C1 C 0.698(3) 0.0616(19) 0.4252(12) 0.106(8) Uani 1 1 d . . .
C11 C 1.003(2) 0.4372(14) 0.2870(8) 0.062(4) Uani 1 1 d . . .
C12 C 1.194(2) 0.3812(13) 0.1894(8) 0.058(4) Uani 1 1 d . . .
C13 C 1.0472(18) 0.1694(15) 0.2037(9) 0.059(4) Uani 1 1 d . . .
C14 C 1.1793(18) 0.3125(14) 0.3243(8) 0.060(4) Uani 1 1 d . . .
C21 C 0.5576(19) 0.3409(15) 0.2460(9) 0.061(4) Uani 1 1 d . . .
C22 C 0.4161(18) 0.1958(14) 0.1240(9) 0.065(5) Uani 1 1 d . . .
C23 C 0.6021(18) 0.0755(13) 0.1558(9) 0.058(4) Uani 1 1 d . . .
C24 C 0.4119(18) 0.1277(14) 0.2599(10) 0.066(5) Uani 1 1 d . . .
C25 C 0.812(2) 0.4433(13) 0.1106(7) 0.053(4) Uani 1 1 d . . .
C26 C 0.936(2) 0.5054(14) 0.0962(10) 0.076(5) Uani 1 1 d . . .
H26 H 1.0275 0.4918 0.1047 0.091 Uiso 1 1 calc R . .
C27 C 0.927(3) 0.5976(17) 0.0663(11) 0.105(8) Uani 1 1 d . . .
H27 H 1.0135 0.6446 0.0565 0.125 Uiso 1 1 calc R . .
C28 C 0.788(3) 0.6144(15) 0.0528(10) 0.086(7) Uani 1 1 d . . .
H28 H 0.7823 0.6722 0.0328 0.103 Uiso 1 1 calc R . .
C29 C 0.664(3) 0.5502(17) 0.0677(12) 0.093(7) Uani 1 1 d . . .
H29 H 0.5719 0.5623 0.0580 0.111 Uiso 1 1 calc R . .
C30 C 0.672(2) 0.4641(13) 0.0979(10) 0.072(5) Uani 1 1 d . . .
H30 H 0.5847 0.4198 0.1100 0.086 Uiso 1 1 calc R . .
C31 C 0.8261(17) 0.2155(13) 0.0462(8) 0.053(4) Uani 1 1 d . . .
C32 C 0.944(3) 0.1733(15) 0.0307(10) 0.080(6) Uani 1 1 d . . .
H32 H 1.0234 0.1830 0.0645 0.096 Uiso 1 1 calc R . .
C33 C 0.947(3) 0.1170(17) -0.0339(11) 0.089(7) Uani 1 1 d . . .
H33 H 1.0275 0.0903 -0.0436 0.106 Uiso 1 1 calc R . .
C34 C 0.828(3) 0.1019(17) -0.0829(11) 0.101(8) Uani 1 1 d . . .
H34 H 0.8270 0.0626 -0.1257 0.121 Uiso 1 1 calc R . .
C35 C 0.712(3) 0.144(2) -0.0698(12) 0.112(9) Uani 1 1 d . . .
H35 H 0.6334 0.1361 -0.1036 0.135 Uiso 1 1 calc R . .
C36 C 0.714(2) 0.1981(17) -0.0048(10) 0.086(6) Uani 1 1 d . . .
H36 H 0.6337 0.2245 0.0046 0.103 Uiso 1 1 calc R . .
C37 C 0.7640(16) 0.3018(12) 0.3991(8) 0.051(4) Uani 1 1 d . . .
C38 C 0.883(2) 0.3364(15) 0.4503(8) 0.071(5) Uani 1 1 d . . .
H38 H 0.9718 0.3197 0.4424 0.085 Uiso 1 1 calc R . .
C39 C 0.874(3) 0.3936(17) 0.5113(11) 0.091(6) Uani 1 1 d . . .
H39 H 0.9543 0.4132 0.5452 0.109 Uiso 1 1 calc R . .
C40 C 0.743(3) 0.4226(16) 0.5228(12) 0.097(7) Uani 1 1 d . . .
H40 H 0.7362 0.4636 0.5639 0.117 Uiso 1 1 calc R . .
C41 C 0.624(3) 0.3895(16) 0.4720(11) 0.088(7) Uani 1 1 d . . .
H41 H 0.5350 0.4074 0.4796 0.105 Uiso 1 1 calc R . .
C42 C 0.634(2) 0.3311(14) 0.4112(9) 0.066(5) Uani 1 1 d . . .
H42 H 0.5531 0.3106 0.3774 0.079 Uiso 1 1 calc R . .
C43 C 0.780(2) -0.1926(14) 0.4226(10) 0.076(5) Uani 1 1 d . . .
C44 C 0.708(4) -0.147(2) 0.4799(11) 0.149(13) Uani 1 1 d . . .
H44A H 0.6045 -0.1560 0.4652 0.224 Uiso 1 1 calc R . .
H44B H 0.7582 -0.0753 0.4917 0.224 Uiso 1 1 calc R . .
H44C H 0.7142 -0.1818 0.5199 0.224 Uiso 1 1 calc R . .
C45 C 0.957(3) -0.156(2) 0.4411(15) 0.141(12) Uani 1 1 d . . .
H45A H 0.9921 -0.0827 0.4409 0.212 Uiso 1 1 calc R . .
H45B H 1.0045 -0.1906 0.4072 0.212 Uiso 1 1 calc R . .
H45C H 0.9800 -0.1717 0.4865 0.212 Uiso 1 1 calc R . .
C46 C 0.731(3) -0.3128(17) 0.4246(11) 0.113(8) Uani 1 1 d . . .
H46A H 0.7532 -0.3262 0.4708 0.170 Uiso 1 1 calc R . .
H46B H 0.7847 -0.3458 0.3925 0.170 Uiso 1 1 calc R . .
H46C H 0.6252 -0.3394 0.4118 0.170 Uiso 1 1 calc R . .
C47 C 0.525(2) -0.2208(14) 0.3047(12) 0.085(6) Uani 1 1 d . . .
C48 C 0.474(3) -0.1660(19) 0.2487(13) 0.127(10) Uani 1 1 d . . .
H48A H 0.3659 -0.1852 0.2431 0.191 Uiso 1 1 calc R . .
H48B H 0.5115 -0.1854 0.2055 0.191 Uiso 1 1 calc R . .
H48C H 0.5108 -0.0928 0.2621 0.191 Uiso 1 1 calc R . .
C49 C 0.487(3) -0.3378(18) 0.2799(18) 0.176(15) Uani 1 1 d . . .
H49A H 0.5010 -0.3729 0.3187 0.264 Uiso 1 1 calc R . .
H49B H 0.5527 -0.3507 0.2451 0.264 Uiso 1 1 calc R . .
H49C H 0.3851 -0.3626 0.2603 0.264 Uiso 1 1 calc R . .
C50 C 0.427(3) -0.206(2) 0.3657(14) 0.148(12) Uani 1 1 d . . .
H50A H 0.4435 -0.1336 0.3811 0.222 Uiso 1 1 calc R . .
H50B H 0.4538 -0.2387 0.4036 0.222 Uiso 1 1 calc R . .
H50C H 0.3230 -0.2363 0.3501 0.222 Uiso 1 1 calc R . .
C51 C 0.851(3) -0.1981(16) 0.2684(13) 0.099(8) Uani 1 1 d . . .
C52 C 1.009(3) -0.120(3) 0.2804(17) 0.167(14) Uani 1 1 d . . .
H52A H 1.0703 -0.1412 0.3137 0.251 Uiso 1 1 calc R . .
H52B H 0.9995 -0.0528 0.2979 0.251 Uiso 1 1 calc R . .
H52C H 1.0547 -0.1168 0.2372 0.251 Uiso 1 1 calc R . .
C53 C 0.863(4) -0.307(2) 0.2700(16) 0.188(17) Uani 1 1 d . . .
H53A H 0.9221 -0.3246 0.2337 0.281 Uiso 1 1 calc R . .
H53B H 0.7642 -0.3545 0.2630 0.281 Uiso 1 1 calc R . .
H53C H 0.9095 -0.3117 0.3144 0.281 Uiso 1 1 calc R . .
C54 C 0.797(3) -0.1873(18) 0.1936(11) 0.116(9) Uani 1 1 d . . .
H54A H 0.8620 -0.2074 0.1612 0.174 Uiso 1 1 calc R . .
H54B H 0.7977 -0.1169 0.1914 0.174 Uiso 1 1 calc R . .
H54C H 0.6964 -0.2311 0.1820 0.174 Uiso 1 1 calc R . .
H1 H 0.783(9) 0.019(7) 0.280(4) 0.000 Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 P1 104.6(7) . . ?
C1 Pt1 Sb2 92.4(7) . . ?
P1 Pt1 Sb2 162.21(12) . . ?
C1 Pt1 H1 164(4) . . ?
P1 Pt1 H1 90(4) . . ?
Sb2 Pt1 H1 73(4) . . ?
C14 Re1 C12 95.8(7) . . ?
C14 Re1 C11 90.7(7) . . ?
C12 Re1 C11 92.9(7) . . ?
C14 Re1 C13 93.1(7) . . ?
C12 Re1 C13 95.0(7) . . ?
C11 Re1 C13 170.8(7) . . ?
C14 Re1 Sb1 171.1(5) . . ?
C12 Re1 Sb1 92.6(4) . . ?
C11 Re1 Sb1 86.2(5) . . ?
C13 Re1 Sb1 88.8(4) . . ?
C14 Re1 Sb2 94.6(5) . . ?
C12 Re1 Sb2 169.5(4) . . ?
C11 Re1 Sb2 86.0(5) . . ?
C13 Re1 Sb2 85.4(5) . . ?
Sb1 Re1 Sb2 76.86(3) . . ?
C24 Re2 C22 96.8(7) . . ?
C24 Re2 C23 95.2(7) . . ?
C22 Re2 C23 89.8(7) . . ?
C24 Re2 C21 95.5(7) . . ?
C22 Re2 C21 95.0(7) . . ?
C23 Re2 C21 167.6(7) . . ?
C24 Re2 Sb1 165.9(5) . . ?
C22 Re2 Sb1 97.1(5) . . ?
C23 Re2 Sb1 82.2(5) . . ?
C21 Re2 Sb1 85.9(5) . . ?
C24 Re2 Sb2 88.8(5) . . ?
C22 Re2 Sb2 173.3(5) . . ?
C23 Re2 Sb2 86.2(5) . . ?
C21 Re2 Sb2 87.9(5) . . ?
Sb1 Re2 Sb2 77.14(3) . . ?
C31 Sb1 C25 97.4(5) . . ?
C31 Sb1 Re2 110.2(4) . . ?
C25 Sb1 Re2 115.1(5) . . ?
C31 Sb1 Re1 115.3(4) . . ?
C25 Sb1 Re1 114.9(4) . . ?
Re2 Sb1 Re1 104.37(4) . . ?
C37 Sb2 Pt1 104.7(4) . . ?
C37 Sb2 Re2 110.3(4) . . ?
Pt1 Sb2 Re2 110.52(4) . . ?
C37 Sb2 Re1 108.4(4) . . ?
Pt1 Sb2 Re1 121.15(4) . . ?
Re2 Sb2 Re1 101.62(4) . . ?
C47 P1 C43 110.7(9) . . ?
C47 P1 C51 108.4(12) . . ?
C43 P1 C51 108.7(10) . . ?
C47 P1 Pt1 105.7(6) . . ?
C43 P1 Pt1 112.9(6) . . ?
C51 P1 Pt1 110.3(7) . . ?
O1 C1 Pt1 175(2) . . ?
O11 C11 Re1 176.7(15) . . ?
O12 C12 Re1 179.3(15) . . ?
O13 C13 Re1 177.8(15) . . ?
O14 C14 Re1 176.7(16) . . ?
O21 C21 Re2 177.4(16) . . ?
O22 C22 Re2 176.1(17) . . ?
O23 C23 Re2 177.1(16) . . ?
O24 C24 Re2 179.4(15) . . ?
C26 C25 C30 121.1(16) . . ?
C26 C25 Sb1 120.1(14) . . ?
C30 C25 Sb1 118.5(13) . . ?
C25 C26 C27 118.0(19) . . ?
C25 C26 H26 121.0 . . ?
C27 C26 H26 121.0 . . ?
C28 C27 C26 120(2) . . ?
C28 C27 H27 120.2 . . ?
C26 C27 H27 120.2 . . ?
C29 C28 C27 121.2(18) . . ?
C29 C28 H28 119.4 . . ?
C27 C28 H28 119.4 . . ?
C28 C29 C30 119.8(19) . . ?
C28 C29 H29 120.1 . . ?
C30 C29 H29 120.1 . . ?
C29 C30 C25 120.4(18) . . ?
C29 C30 H30 119.8 . . ?
C25 C30 H30 119.8 . . ?
C36 C31 C32 116.2(17) . . ?
C36 C31 Sb1 120.6(14) . . ?
C32 C31 Sb1 123.1(12) . . ?
C33 C32 C31 122(2) . . ?
C33 C32 H32 119.1 . . ?
C31 C32 H32 119.1 . . ?
C34 C33 C32 118(2) . . ?
C34 C33 H33 120.8 . . ?
C32 C33 H33 120.8 . . ?
C35 C34 C33 121(2) . . ?
C35 C34 H34 119.4 . . ?
C33 C34 H34 119.4 . . ?
C34 C35 C36 118(2) . . ?
C34 C35 H35 121.2 . . ?
C36 C35 H35 121.2 . . ?
C31 C36 C35 125(2) . . ?
C31 C36 H36 117.7 . . ?
C35 C36 H36 117.7 . . ?
C38 C37 C42 117.4(16) . . ?
C38 C37 Sb2 120.3(12) . . ?
C42 C37 Sb2 122.3(12) . . ?
C39 C38 C37 123(2) . . ?
C39 C38 H38 118.7 . . ?
C37 C38 H38 118.7 . . ?
C38 C39 C40 119(2) . . ?
C38 C39 H39 120.3 . . ?
C40 C39 H39 120.3 . . ?
C41 C40 C39 119(2) . . ?
C41 C40 H40 120.6 . . ?
C39 C40 H40 120.6 . . ?
C42 C41 C40 121(2) . . ?
C42 C41 H41 119.6 . . ?
C40 C41 H41 119.6 . . ?
C41 C42 C37 120.7(18) . . ?
C41 C42 H42 119.6 . . ?
C37 C42 H42 119.6 . . ?
C44 C43 C46 105.5(18) . . ?
C44 C43 C45 108(2) . . ?
C46 C43 C45 106.3(17) . . ?
C44 C43 P1 112.0(14) . . ?
C46 C43 P1 113.7(13) . . ?
C45 C43 P1 110.6(15) . . ?
C43 C44 H44A 109.5 . . ?
C43 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C43 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C43 C45 H45A 109.5 . . ?
C43 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C43 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C43 C46 H46A 109.5 . . ?
C43 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C43 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C48 C47 C49 111(2) . . ?
C48 C47 C50 105(2) . . ?
C49 C47 C50 107(2) . . ?
C48 C47 P1 109.7(14) . . ?
C49 C47 P1 115.5(17) . . ?
C50 C47 P1 108.8(17) . . ?
C47 C48 H48A 109.5 . . ?
C47 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C47 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
C47 C49 H49A 109.5 . . ?
C47 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
C47 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
C47 C50 H50A 109.5 . . ?
C47 C50 H50B 109.5 . . ?
H50A C50 H50B 109.5 . . ?
C47 C50 H50C 109.5 . . ?
H50A C50 H50C 109.5 . . ?
H50B C50 H50C 109.5 . . ?
C53 C51 C52 111(2) . . ?
C53 C51 C54 109(2) . . ?
C52 C51 C54 103(2) . . ?
C53 C51 P1 114.2(17) . . ?
C52 C51 P1 107.8(17) . . ?
C54 C51 P1 111.3(15) . . ?
C51 C52 H52A 109.5 . . ?
C51 C52 H52B 109.5 . . ?
H52A C52 H52B 109.5 . . ?
C51 C52 H52C 109.5 . . ?
H52A C52 H52C 109.5 . . ?
H52B C52 H52C 109.5 . . ?
C51 C53 H53A 109.5 . . ?
C51 C53 H53B 109.5 . . ?
H53A C53 H53B 109.5 . . ?
C51 C53 H53C 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C51 C54 H54A 109.5 . . ?
C51 C54 H54B 109.5 . . ?
H54A C54 H54B 109.5 . . ?
C51 C54 H54C 109.5 . . ?
H54A C54 H54C 109.5 . . ?
H54B C54 H54C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.81(2) . ?
Pt1 P1 2.365(4) . ?
Pt1 Sb2 2.6100(12) . ?
Pt1 H1 1.21(8) . ?
Re1 C14 1.940(15) . ?
Re1 C12 1.943(19) . ?
Re1 C11 1.964(18) . ?
Re1 C13 1.98(2) . ?
Re1 Sb1 2.7572(11) . ?
Re1 Sb2 2.8099(12) . ?
Re2 C24 1.935(17) . ?
Re2 C22 1.942(17) . ?
Re2 C23 1.983(19) . ?
Re2 C21 1.99(2) . ?
Re2 Sb1 2.7480(12) . ?
Re2 Sb2 2.8015(11) . ?
Sb1 C31 2.131(16) . ?
Sb1 C25 2.173(16) . ?
Sb2 C37 2.158(16) . ?
P1 C47 1.90(2) . ?
P1 C43 1.899(18) . ?
P1 C51 1.91(2) . ?
O1 C1 1.19(2) . ?
O11 C11 1.159(19) . ?
O12 C12 1.144(19) . ?
O13 C13 1.14(2) . ?
O14 C14 1.148(17) . ?
O21 C21 1.16(2) . ?
O22 C22 1.148(18) . ?
O23 C23 1.142(19) . ?
O24 C24 1.136(18) . ?
C25 C26 1.30(2) . ?
C25 C30 1.41(2) . ?
C26 C27 1.46(3) . ?
C26 H26 0.9300 . ?
C27 C28 1.38(3) . ?
C27 H27 0.9300 . ?
C28 C29 1.31(3) . ?
C28 H28 0.9300 . ?
C29 C30 1.39(2) . ?
C29 H29 0.9300 . ?
C30 H30 0.9300 . ?
C31 C36 1.35(2) . ?
C31 C32 1.40(2) . ?
C32 C33 1.39(3) . ?
C32 H32 0.9300 . ?
C33 C34 1.38(3) . ?
C33 H33 0.9300 . ?
C34 C35 1.37(3) . ?
C34 H34 0.9300 . ?
C35 C36 1.38(3) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C37 C38 1.39(2) . ?
C37 C42 1.39(2) . ?
C38 C39 1.35(3) . ?
C38 H38 0.9300 . ?
C39 C40 1.39(3) . ?
C39 H39 0.9300 . ?
C40 C41 1.39(3) . ?
C40 H40 0.9300 . ?
C41 C42 1.36(2) . ?
C41 H41 0.9300 . ?
C42 H42 0.9300 . ?
C43 C44 1.48(3) . ?
C43 C46 1.58(3) . ?
C43 C45 1.59(3) . ?
C44 H44A 0.9600 . ?
C44 H44B 0.9600 . ?
C44 H44C 0.9600 . ?
C45 H45A 0.9600 . ?
C45 H45B 0.9600 . ?
C45 H45C 0.9600 . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C47 C48 1.52(3) . ?
C47 C49 1.54(3) . ?
C47 C50 1.56(3) . ?
C48 H48A 0.9600 . ?
C48 H48B 0.9600 . ?
C48 H48C 0.9600 . ?
C49 H49A 0.9600 . ?
C49 H49B 0.9600 . ?
C49 H49C 0.9600 . ?
C50 H50A 0.9600 . ?
C50 H50B 0.9600 . ?
C50 H50C 0.9600 . ?
C51 C53 1.52(3) . ?
C51 C52 1.55(4) . ?
C51 C54 1.55(3) . ?
C52 H52A 0.9600 . ?
C52 H52B 0.9600 . ?
C52 H52C 0.9600 . ?
C53 H53A 0.9600 . ?
C53 H53B 0.9600 . ?
C53 H53C 0.9600 . ?
C54 H54A 0.9600 . ?
C54 H54B 0.9600 . ?
C54 H54C 0.9600 . ?
