#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:17:18 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179239 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/59/4315978.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4315978
loop_
_publ_author_name
'Richard D. Adams'
'William C. Pearl'
_publ_section_title
;
 Reactions of the Platinum (Tri-tert-butylphosphine) Group with Bridging
 SbPh2 Ligands in Rhenium-Antimony Carbonyl Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6188
_journal_page_last               6195
_journal_paper_doi               10.1021/ic1008335
_journal_volume                  49
_journal_year                    2010
_chemical_formula_sum            'C49 H69 O7 P2 Pt2 Re2 Sb3'
_chemical_formula_weight         1959.81
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.339(2)
_cell_angle_beta                 94.029(2)
_cell_angle_gamma                111.518(2)
_cell_formula_units_Z            2
_cell_length_a                   12.3000(10)
_cell_length_b                   13.9922(11)
_cell_length_c                   18.8826(14)
_cell_measurement_reflns_used    2415
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      2.26
_cell_measurement_theta_min      20.28
_cell_volume                     2881.9(4)
_computing_cell_refinement       'SAINT+  V6.45 (Bruker, 2003)'
_computing_data_collection       'SMART V5.632 (Bruker, 2005)'
_computing_data_reduction        'SAINT+  V6.45'
_computing_molecular_graphics    'SHELXTL V6.1 (Sheldrick, 2000)'
_computing_publication_material  'SHELXTL V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0746
_diffrn_reflns_av_sigmaI/netI    0.1166
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            26490
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.13
_diffrn_standards_decay_%        <1
_exptl_absorpt_coefficient_mu    10.501
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.572
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 1997)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.258
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       bar
_exptl_crystal_F_000             1816
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.982
_refine_diff_density_min         -1.616
_refine_diff_density_rms         0.234
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     604
_refine_ls_number_reflns         11770
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.002
_refine_ls_R_factor_all          0.1186
_refine_ls_R_factor_gt           0.0630
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0378P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1086
_refine_ls_wR_factor_ref         0.1281
_reflns_number_gt                7148
_reflns_number_total             11770
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic1008335_si_002_4.cif
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4315978
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.64726(5) 0.45843(5) 0.24958(3) 0.04023(17) Uani 1 1 d . . .
Pt2 Pt 0.82769(5) 0.74721(5) 0.27616(3) 0.04255(17) Uani 1 1 d . . .
Re1 Re 0.42411(6) 0.64722(6) 0.18612(4) 0.04846(19) Uani 1 1 d . . .
Re2 Re 0.66905(5) 0.64756(5) 0.36864(3) 0.03724(16) Uani 1 1 d . . .
Sb1 Sb 0.47481(9) 0.51395(8) 0.25738(6) 0.0416(3) Uani 1 1 d . . .
Sb2 Sb 0.63729(9) 0.77487(8) 0.28261(6) 0.0415(3) Uani 1 1 d . . .
Sb3 Sb 0.85068(9) 0.59531(8) 0.31842(6) 0.0411(3) Uani 1 1 d . . .
P1 P 0.6188(4) 0.2956(3) 0.1735(2) 0.0477(11) Uani 1 1 d . . .
P2 P 0.9673(4) 0.8357(3) 0.2172(2) 0.0488(11) Uani 1 1 d . . .
O11 O 0.5792(12) 0.5856(11) 0.0714(7) 0.081(4) Uani 1 1 d . . .
O12 O 0.1897(14) 0.4787(13) 0.0886(9) 0.113(6) Uani 1 1 d . . .
O13 O 0.2979(12) 0.6989(12) 0.3212(9) 0.100(5) Uani 1 1 d . . .
O14 O 0.4123(12) 0.8341(12) 0.1325(7) 0.090(4) Uani 1 1 d . . .
O21 O 0.6429(11) 0.4886(10) 0.4606(6) 0.072(4) Uani 1 1 d . . .
O22 O 0.4886(12) 0.7151(12) 0.4493(8) 0.089(5) Uani 1 1 d . . .
O23 O 0.8683(11) 0.8359(9) 0.4829(6) 0.071(4) Uani 1 1 d . . .
C11 C 0.5216(15) 0.6082(15) 0.1129(11) 0.066(5) Uani 1 1 d . . .
C12 C 0.277(2) 0.5420(19) 0.1249(11) 0.082(6) Uani 1 1 d . . .
C13 C 0.3404(16) 0.6789(14) 0.2723(10) 0.058(5) Uani 1 1 d . . .
C14 C 0.4158(16) 0.7615(15) 0.1530(11) 0.070(5) Uani 1 1 d . . .
C21 C 0.6538(12) 0.5433(14) 0.4237(7) 0.043(4) Uani 1 1 d . . .
C22 C 0.5498(17) 0.6885(16) 0.4155(11) 0.074(6) Uani 1 1 d . . .
C23 C 0.7936(16) 0.7632(14) 0.4387(9) 0.055(5) Uani 1 1 d . . .
C24 C 0.3247(14) 0.4190(12) 0.2974(9) 0.046(4) Uani 1 1 d . . .
C25 C 0.3472(15) 0.3800(12) 0.3562(10) 0.063(5) Uani 1 1 d . . .
H25 H 0.4239 0.3976 0.3796 0.076 Uiso 1 1 calc R . .
C26 C 0.246(2) 0.3125(16) 0.3777(10) 0.082(6) Uani 1 1 d . . .
H26 H 0.2564 0.2864 0.4173 0.098 Uiso 1 1 calc R . .
C27 C 0.1378(19) 0.2855(16) 0.3434(13) 0.082(7) Uani 1 1 d . . .
H27 H 0.0743 0.2383 0.3580 0.098 Uiso 1 1 calc R . .
C28 C 0.116(2) 0.3233(19) 0.2887(16) 0.116(9) Uani 1 1 d . . .
H28 H 0.0380 0.3063 0.2677 0.139 Uiso 1 1 calc R . .
C29 C 0.2097(14) 0.3885(13) 0.2627(11) 0.064(5) Uani 1 1 d . . .
H29 H 0.1949 0.4114 0.2222 0.077 Uiso 1 1 calc R . .
C30 C 0.6449(15) 0.9200(13) 0.3593(9) 0.049(4) Uani 1 1 d . . .
C31 C 0.5438(18) 0.9449(15) 0.3617(11) 0.074(6) Uani 1 1 d . . .
H31 H 0.4734 0.9004 0.3286 0.088 Uiso 1 1 calc R . .
C32 C 0.551(2) 1.0375(17) 0.4148(13) 0.084(7) Uani 1 1 d . . .
H32 H 0.4844 1.0540 0.4173 0.101 Uiso 1 1 calc R . .
C33 C 0.651(2) 1.1014(18) 0.4611(12) 0.087(7) Uani 1 1 d . . .
H33 H 0.6532 1.1624 0.4962 0.104 Uiso 1 1 calc R . .
C34 C 0.749(2) 1.0807(17) 0.4589(10) 0.086(7) Uani 1 1 d . . .
H34 H 0.8187 1.1265 0.4923 0.104 Uiso 1 1 calc R . .
C35 C 0.7451(17) 0.9887(13) 0.4053(10) 0.066(5) Uani 1 1 d . . .
H35 H 0.8139 0.9758 0.4022 0.079 Uiso 1 1 calc R . .
C36 C 0.9827(13) 0.6029(12) 0.4045(9) 0.045(4) Uani 1 1 d . . .
C37 C 1.0703(15) 0.5756(15) 0.3830(9) 0.063(5) Uani 1 1 d . . .
H37 H 1.0722 0.5532 0.3326 0.075 Uiso 1 1 calc R . .
C38 C 1.1597(15) 0.5800(16) 0.4349(11) 0.074(6) Uani 1 1 d . . .
H38 H 1.2199 0.5593 0.4195 0.088 Uiso 1 1 calc R . .
C39 C 1.1574(16) 0.6150(15) 0.5081(12) 0.075(6) Uani 1 1 d . . .
H39 H 1.2171 0.6195 0.5435 0.089 Uiso 1 1 calc R . .
C40 C 1.0656(15) 0.6442(15) 0.5305(9) 0.063(5) Uani 1 1 d . . .
H40 H 1.0635 0.6679 0.5808 0.075 Uiso 1 1 calc R . .
C41 C 0.9793(16) 0.6379(15) 0.4786(10) 0.068(5) Uani 1 1 d . . .
H41 H 0.9178 0.6574 0.4932 0.082 Uiso 1 1 calc R . .
C42 C 0.4673(19) 0.2262(15) 0.1068(11) 0.078(6) Uani 1 1 d . . .
C43 C 0.4487(19) 0.1227(16) 0.0478(10) 0.101(8) Uani 1 1 d . . .
H43A H 0.3675 0.0886 0.0228 0.151 Uiso 1 1 calc R . .
H43B H 0.4671 0.0753 0.0709 0.151 Uiso 1 1 calc R . .
H43C H 0.4999 0.1389 0.0124 0.151 Uiso 1 1 calc R . .
C44 C 0.3683(16) 0.1933(15) 0.1544(11) 0.093(7) Uani 1 1 d . . .
H44A H 0.2916 0.1647 0.1235 0.140 Uiso 1 1 calc R . .
H44B H 0.3764 0.2553 0.1938 0.140 Uiso 1 1 calc R . .
H44C H 0.3763 0.1397 0.1753 0.140 Uiso 1 1 calc R . .
C45 C 0.446(2) 0.3029(15) 0.0711(11) 0.108(8) Uani 1 1 d . . .
H45A H 0.4871 0.3065 0.0299 0.162 Uiso 1 1 calc R . .
H45B H 0.4747 0.3729 0.1067 0.162 Uiso 1 1 calc R . .
H45C H 0.3624 0.2789 0.0539 0.162 Uiso 1 1 calc R . .
C46 C 0.6276(16) 0.2109(13) 0.2374(9) 0.055(4) Uani 1 1 d . . .
C47 C 0.7531(18) 0.2444(16) 0.2727(11) 0.094(7) Uani 1 1 d . . .
H47A H 0.7919 0.3214 0.2879 0.142 Uiso 1 1 calc R . .
H47B H 0.7935 0.2145 0.2377 0.142 Uiso 1 1 calc R . .
H47C H 0.7546 0.2189 0.3154 0.142 Uiso 1 1 calc R . .
C48 C 0.5727(18) 0.0888(13) 0.1999(10) 0.083(6) Uani 1 1 d . . .
H48A H 0.6224 0.0697 0.1670 0.125 Uiso 1 1 calc R . .
H48B H 0.4952 0.0683 0.1721 0.125 Uiso 1 1 calc R . .
H48C H 0.5663 0.0521 0.2372 0.125 Uiso 1 1 calc R . .
C49 C 0.563(2) 0.2362(17) 0.3010(11) 0.105(8) Uani 1 1 d . . .
H49A H 0.5785 0.2051 0.3385 0.158 Uiso 1 1 calc R . .
H49B H 0.4793 0.2068 0.2825 0.158 Uiso 1 1 calc R . .
H49C H 0.5912 0.3127 0.3220 0.158 Uiso 1 1 calc R . .
C50 C 0.7392(18) 0.2989(15) 0.1150(11) 0.074(6) Uani 1 1 d . . .
C51 C 0.8617(17) 0.3749(16) 0.1571(13) 0.103(8) Uani 1 1 d . . .
H51A H 0.8747 0.3609 0.2035 0.155 Uiso 1 1 calc R . .
H51B H 0.8685 0.4477 0.1664 0.155 Uiso 1 1 calc R . .
H51C H 0.9199 0.3646 0.1283 0.155 Uiso 1 1 calc R . .
C52 C 0.741(2) 0.1876(16) 0.0770(13) 0.124(10) Uani 1 1 d . . .
H52A H 0.8009 0.1963 0.0462 0.186 Uiso 1 1 calc R . .
H52B H 0.6649 0.1405 0.0469 0.186 Uiso 1 1 calc R . .
H52C H 0.7588 0.1571 0.1143 0.186 Uiso 1 1 calc R . .
C53 C 0.716(2) 0.3453(18) 0.0508(12) 0.134(11) Uani 1 1 d . . .
H53A H 0.7067 0.4112 0.0713 0.201 Uiso 1 1 calc R . .
H53B H 0.6455 0.2943 0.0166 0.201 Uiso 1 1 calc R . .
H53C H 0.7826 0.3590 0.0253 0.201 Uiso 1 1 calc R . .
C54 C 0.9921(19) 0.7361(17) 0.1372(11) 0.078(6) Uani 1 1 d . . .
C55 C 1.062(2) 0.7820(19) 0.0826(13) 0.156(13) Uani 1 1 d . . .
H55A H 1.1325 0.8436 0.1090 0.234 Uiso 1 1 calc R . .
H55B H 1.0143 0.8031 0.0523 0.234 Uiso 1 1 calc R . .
H55C H 1.0836 0.7287 0.0517 0.234 Uiso 1 1 calc R . .
C56 C 1.0536(18) 0.6746(15) 0.1673(11) 0.092(7) Uani 1 1 d . . .
H56A H 1.0510 0.6151 0.1277 0.137 Uiso 1 1 calc R . .
H56B H 1.0140 0.6481 0.2048 0.137 Uiso 1 1 calc R . .
H56C H 1.1348 0.7214 0.1886 0.137 Uiso 1 1 calc R . .
C57 C 0.871(2) 0.651(2) 0.0988(14) 0.148(12) Uani 1 1 d . . .
H57A H 0.8318 0.6782 0.0681 0.222 Uiso 1 1 calc R . .
H57B H 0.8238 0.6307 0.1355 0.222 Uiso 1 1 calc R . .
H57C H 0.8793 0.5886 0.0686 0.222 Uiso 1 1 calc R . .
C58 C 0.9267(18) 0.9333(17) 0.1773(11) 0.075(6) Uani 1 1 d . . .
C59 C 0.823(2) 0.866(2) 0.1126(12) 0.124(9) Uani 1 1 d . . .
H59A H 0.7551 0.8257 0.1310 0.186 Uiso 1 1 calc R . .
H59B H 0.8448 0.8170 0.0772 0.186 Uiso 1 1 calc R . .
H59C H 0.8032 0.9123 0.0891 0.186 Uiso 1 1 calc R . .
C60 C 0.8877(19) 1.0050(18) 0.2344(13) 0.112(9) Uani 1 1 d . . .
H60A H 0.8180 0.9616 0.2495 0.168 Uiso 1 1 calc R . .
H60B H 0.8699 1.0543 0.2131 0.168 Uiso 1 1 calc R . .
H60C H 0.9502 1.0444 0.2769 0.168 Uiso 1 1 calc R . .
C61 C 1.026(2) 1.0091(16) 0.1453(14) 0.125(10) Uani 1 1 d . . .
H61A H 1.0601 0.9675 0.1131 0.188 Uiso 1 1 calc R . .
H61B H 1.0867 1.0626 0.1854 0.188 Uiso 1 1 calc R . .
H61C H 0.9921 1.0437 0.1177 0.188 Uiso 1 1 calc R . .
C62 C 1.1099(13) 0.9160(14) 0.2859(10) 0.060(5) Uani 1 1 d . . .
C63 C 1.100(2) 1.011(2) 0.3420(12) 0.150(13) Uani 1 1 d . . .
H63A H 1.0258 0.9874 0.3587 0.225 Uiso 1 1 calc R . .
H63B H 1.1054 1.0660 0.3189 0.225 Uiso 1 1 calc R . .
H63C H 1.1641 1.0394 0.3837 0.225 Uiso 1 1 calc R . .
C64 C 1.2230(19) 0.959(2) 0.2532(15) 0.164(13) Uani 1 1 d . . .
H64A H 1.2917 0.9851 0.2911 0.246 Uiso 1 1 calc R . .
H64B H 1.2222 1.0174 0.2348 0.246 Uiso 1 1 calc R . .
H64C H 1.2254 0.9029 0.2132 0.246 Uiso 1 1 calc R . .
C65 C 1.1362(18) 0.8488(17) 0.3298(12) 0.106(8) Uani 1 1 d . . .
H65A H 1.2187 0.8816 0.3523 0.159 Uiso 1 1 calc R . .
H65B H 1.1184 0.7782 0.2974 0.159 Uiso 1 1 calc R . .
H65C H 1.0884 0.8435 0.3679 0.159 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 Sb1 119.12(12) . . ?
P1 Pt1 Sb3 122.47(12) . . ?
Sb1 Pt1 Sb3 118.14(4) . . ?
P1 Pt1 Re2 169.19(11) . . ?
Sb1 Pt1 Re2 60.69(3) . . ?
Sb3 Pt1 Re2 60.01(3) . . ?
P2 Pt2 Sb2 121.68(12) . . ?
P2 Pt2 Sb3 118.29(11) . . ?
Sb2 Pt2 Sb3 119.31(4) . . ?
P2 Pt2 Re2 173.03(12) . . ?
Sb2 Pt2 Re2 61.48(3) . . ?
Sb3 Pt2 Re2 60.10(3) . . ?
C14 Re1 C12 94.7(8) . . ?
C14 Re1 C11 95.3(8) . . ?
C12 Re1 C11 93.4(8) . . ?
C14 Re1 C13 92.9(7) . . ?
C12 Re1 C13 91.2(8) . . ?
C11 Re1 C13 170.2(7) . . ?
C14 Re1 Sb1 167.9(6) . . ?
C12 Re1 Sb1 97.2(6) . . ?
C11 Re1 Sb1 86.5(5) . . ?
C13 Re1 Sb1 84.4(5) . . ?
C14 Re1 Sb2 93.7(6) . . ?
C12 Re1 Sb2 171.6(6) . . ?
C11 Re1 Sb2 86.4(5) . . ?
C13 Re1 Sb2 87.8(5) . . ?
Sb1 Re1 Sb2 74.40(3) . . ?
C23 Re2 C22 91.6(8) . . ?
C23 Re2 C21 95.8(7) . . ?
C22 Re2 C21 91.4(6) . . ?
C23 Re2 Sb3 83.5(5) . . ?
C22 Re2 Sb3 173.6(6) . . ?
C21 Re2 Sb3 84.9(4) . . ?
C23 Re2 Sb1 167.1(5) . . ?
C22 Re2 Sb1 82.5(6) . . ?
C21 Re2 Sb1 95.8(4) . . ?
Sb3 Re2 Sb1 103.15(4) . . ?
C23 Re2 Sb2 93.9(5) . . ?
C22 Re2 Sb2 80.6(5) . . ?
C21 Re2 Sb2 167.6(4) . . ?
Sb3 Re2 Sb2 103.87(3) . . ?
Sb1 Re2 Sb2 73.88(3) . . ?
C23 Re2 Pt2 76.9(5) . . ?
C22 Re2 Pt2 129.6(5) . . ?
C21 Re2 Pt2 138.0(4) . . ?
Sb3 Re2 Pt2 53.32(3) . . ?
Sb1 Re2 Pt2 98.03(3) . . ?
Sb2 Re2 Pt2 52.24(3) . . ?
C23 Re2 Pt1 136.2(5) . . ?
C22 Re2 Pt1 131.6(6) . . ?
C21 Re2 Pt1 78.8(4) . . ?
Sb3 Re2 Pt1 52.83(3) . . ?
Sb1 Re2 Pt1 52.24(3) . . ?
Sb2 Re2 Pt1 99.32(3) . . ?
Pt2 Re2 Pt1 78.84(2) . . ?
C24 Sb1 Pt1 117.8(4) . . ?
C24 Sb1 Re1 112.9(4) . . ?
Pt1 Sb1 Re1 127.13(4) . . ?
C24 Sb1 Re2 113.6(4) . . ?
Pt1 Sb1 Re2 67.07(3) . . ?
Re1 Sb1 Re2 105.63(4) . . ?
C30 Sb2 Pt2 117.7(5) . . ?
C30 Sb2 Re1 116.6(5) . . ?
Pt2 Sb2 Re1 125.21(4) . . ?
C30 Sb2 Re2 106.3(4) . . ?
Pt2 Sb2 Re2 66.28(3) . . ?
Re1 Sb2 Re2 104.94(4) . . ?
C36 Sb3 Pt1 135.2(4) . . ?
C36 Sb3 Pt2 129.3(4) . . ?
Pt1 Sb3 Pt2 93.86(4) . . ?
C36 Sb3 Re2 115.1(4) . . ?
Pt1 Sb3 Re2 67.16(3) . . ?
Pt2 Sb3 Re2 66.59(3) . . ?
C50 P1 C46 106.6(8) . . ?
C50 P1 C42 107.7(9) . . ?
C46 P1 C42 109.9(8) . . ?
C50 P1 Pt1 113.6(6) . . ?
C46 P1 Pt1 105.7(5) . . ?
C42 P1 Pt1 113.1(6) . . ?
C62 P2 C58 107.6(9) . . ?
C62 P2 C54 109.4(9) . . ?
C58 P2 C54 107.7(9) . . ?
C62 P2 Pt2 108.5(5) . . ?
C58 P2 Pt2 113.2(6) . . ?
C54 P2 Pt2 110.4(6) . . ?
O11 C11 Re1 178.9(16) . . ?
O12 C12 Re1 179(2) . . ?
O13 C13 Re1 177.6(19) . . ?
O14 C14 Re1 179.1(17) . . ?
O21 C21 Re2 174.0(14) . . ?
O22 C22 Re2 172.9(19) . . ?
O23 C23 Re2 177.9(15) . . ?
C29 C24 C25 120.1(15) . . ?
C29 C24 Sb1 121.8(13) . . ?
C25 C24 Sb1 117.9(12) . . ?
C24 C25 C26 116.0(18) . . ?
C27 C26 C25 122(2) . . ?
C26 C27 C28 122(2) . . ?
C27 C28 C29 120(2) . . ?
C24 C29 C28 119.6(19) . . ?
C35 C30 C31 118.4(17) . . ?
C35 C30 Sb2 120.8(13) . . ?
C31 C30 Sb2 120.8(13) . . ?
C32 C31 C30 119.0(19) . . ?
C33 C32 C31 121(2) . . ?
C32 C33 C34 121(2) . . ?
C33 C34 C35 119(2) . . ?
C30 C35 C34 121.1(19) . . ?
C37 C36 C41 120.6(15) . . ?
C37 C36 Sb3 117.4(12) . . ?
C41 C36 Sb3 122.0(12) . . ?
C36 C37 C38 120.8(17) . . ?
C39 C38 C37 119.0(17) . . ?
C38 C39 C40 119.9(16) . . ?
C41 C40 C39 119.6(17) . . ?
C40 C41 C36 120.0(17) . . ?
C45 C42 C43 109.9(17) . . ?
C45 C42 C44 107.6(18) . . ?
C43 C42 C44 105.3(16) . . ?
C45 C42 P1 110.3(14) . . ?
C43 C42 P1 115.7(15) . . ?
C44 C42 P1 107.6(13) . . ?
C47 C46 C49 105.6(15) . . ?
C47 C46 C48 109.4(15) . . ?
C49 C46 C48 108.4(16) . . ?
C47 C46 P1 110.4(13) . . ?
C49 C46 P1 107.8(12) . . ?
C48 C46 P1 114.9(11) . . ?
C51 C50 C52 109.1(17) . . ?
C51 C50 C53 105.0(17) . . ?
C52 C50 C53 106.3(17) . . ?
C51 C50 P1 112.9(13) . . ?
C52 C50 P1 115.2(13) . . ?
C53 C50 P1 107.6(14) . . ?
C55 C54 C57 111(2) . . ?
C55 C54 C56 107.5(18) . . ?
C57 C54 C56 103.6(19) . . ?
C55 C54 P2 116.7(16) . . ?
C57 C54 P2 106.8(14) . . ?
C56 C54 P2 110.1(13) . . ?
C60 C58 C59 108.5(18) . . ?
C60 C58 C61 106.8(17) . . ?
C59 C58 C61 106.3(17) . . ?
C60 C58 P2 111.4(13) . . ?
C59 C58 P2 107.2(15) . . ?
C61 C58 P2 116.3(14) . . ?
C65 C62 C63 106.5(17) . . ?
C65 C62 C64 104.1(17) . . ?
C63 C62 C64 107.9(18) . . ?
C65 C62 P2 110.7(12) . . ?
C63 C62 P2 110.7(13) . . ?
C64 C62 P2 116.3(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.259(4) . ?
Pt1 Sb1 2.5139(11) . ?
Pt1 Sb3 2.5323(12) . ?
Pt1 Re2 2.9287(9) . ?
Pt2 P2 2.261(4) . ?
Pt2 Sb2 2.5161(11) . ?
Pt2 Sb3 2.5464(12) . ?
Pt2 Re2 2.9139(8) . ?
Re1 C14 1.888(19) . ?
Re1 C12 1.92(2) . ?
Re1 C11 2.00(2) . ?
Re1 C13 2.030(19) . ?
Re1 Sb1 2.7668(12) . ?
Re1 Sb2 2.7688(12) . ?
Re2 C23 1.885(18) . ?
Re2 C22 1.952(18) . ?
Re2 C21 1.955(17) . ?
Re2 Sb3 2.7526(11) . ?
Re2 Sb1 2.7729(12) . ?
Re2 Sb2 2.7965(12) . ?
Sb1 C24 2.153(15) . ?
Sb2 C30 2.148(16) . ?
Sb3 C36 2.170(15) . ?
P1 C50 1.903(16) . ?
P1 C46 1.912(16) . ?
P1 C42 1.93(2) . ?
P2 C62 1.880(16) . ?
P2 C58 1.908(19) . ?
P2 C54 1.910(19) . ?
O11 C11 1.156(19) . ?
O12 C12 1.14(2) . ?
O13 C13 1.119(19) . ?
O14 C14 1.187(19) . ?
O21 C21 1.135(17) . ?
O22 C22 1.126(18) . ?
O23 C23 1.167(18) . ?
C24 C29 1.38(2) . ?
C24 C25 1.41(2) . ?
C25 C26 1.42(2) . ?
C26 C27 1.31(2) . ?
C27 C28 1.33(3) . ?
C28 C29 1.39(3) . ?
C30 C35 1.33(2) . ?
C30 C31 1.41(2) . ?
C31 C32 1.40(2) . ?
C32 C33 1.31(3) . ?
C33 C34 1.35(3) . ?
C34 C35 1.41(2) . ?
C36 C37 1.33(2) . ?
C36 C41 1.37(2) . ?
C37 C38 1.39(2) . ?
C38 C39 1.35(2) . ?
C39 C40 1.39(2) . ?
C40 C41 1.36(2) . ?
C42 C45 1.49(2) . ?
C42 C43 1.52(2) . ?
C42 C44 1.57(3) . ?
C46 C47 1.49(2) . ?
C46 C49 1.52(2) . ?
C46 C48 1.54(2) . ?
C50 C51 1.51(3) . ?
C50 C52 1.56(2) . ?
C50 C53 1.56(3) . ?
C54 C55 1.50(2) . ?
C54 C57 1.52(3) . ?
C54 C56 1.52(3) . ?
C58 C60 1.51(3) . ?
C58 C59 1.53(3) . ?
C58 C61 1.57(2) . ?
C62 C65 1.50(2) . ?
C62 C63 1.53(2) . ?
C62 C64 1.54(2) . ?
