#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:17:18 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179239 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/59/4315993.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4315993
loop_
_publ_author_name
'Nicolas Leblanc'
'Wenhua Bi'
'Nicolas Mercier'
'Pascale Auban-Senzier'
'Claude Pasquier'
_publ_contact_author_address
;
Laboratoire Chimie Ingenierie Moleculaire Materiaux Angers
UMR CNRS 6501, Faculte des Sciences, 2 Bd Lavoisier, F-49045 Angers, France
;
_publ_contact_author_email       nicolas.mercier@univ-angers.fr
_publ_contact_author_fax         (33)2.41.73.54.05
_publ_contact_author_name        'Mercier, Nicolas'
_publ_contact_author_phone       (33)2.41.73.50.83
_publ_section_title
;
 Photochromism, Electrical Properties, and Structural Investigations of a
 Series of Hydrated Methylviologen Halobismuthate Hybrids: Influence of
 the Anionic Oligomer Size and Iodide Doping on the Photoinduced
 Properties and on the Dehydration Process
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5824
_journal_page_last               5833
_journal_paper_doi               10.1021/ic901525p
_journal_volume                  49
_journal_year                    2010
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         '3(C12 H14 N2), Bi4 Cl18'
_chemical_formula_sum            'C36 H42 Bi4 Cl18 N6'
_chemical_formula_weight         2032.83
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.3
_audit_creation_date             2009-12-03T14:27:44-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                72.336(5)
_cell_angle_beta                 89.811(6)
_cell_angle_gamma                71.266(6)
_cell_formula_units_Z            1
_cell_length_a                   9.2588(7)
_cell_length_b                   12.5306(9)
_cell_length_c                   14.5781(4)
_cell_measurement_reflns_used    16684
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30
_cell_measurement_theta_min      2
_cell_measurement_wavelength     0.71073
_cell_volume                     1517.87(18)
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1986)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  'horizontally mounted graphite crystal'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0766
_diffrn_reflns_av_unetI/netI     0.0557
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            61586
_diffrn_reflns_theta_full        30.02
_diffrn_reflns_theta_max         30.02
_diffrn_reflns_theta_min         2.34
_exptl_absorpt_coefficient_mu    12.408
_exptl_absorpt_correction_T_max  0.898
_exptl_absorpt_correction_T_min  0.305
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS (Sheldrick, Bruker, 2000))'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.224
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             938
_exptl_crystal_size_max          0.323
_exptl_crystal_size_mid          0.096
_exptl_crystal_size_min          0.066
_refine_diff_density_max         1.635
_refine_diff_density_min         -2.014
_refine_diff_density_rms         0.44
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.15
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     292
_refine_ls_number_reflns         8813
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.15
_refine_ls_R_factor_all          0.082
_refine_ls_R_factor_gt           0.0356
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0634P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0853
_refine_ls_wR_factor_ref         0.1257
_reflns_number_gt                5783
_reflns_number_total             8813
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic901525p_si_002_2.cif
_cod_data_source_block           1b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_hydrogen_treatment' value 'CONSTR' changed to 'constr'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        1517.87(16)
_cod_database_code               4315993
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.01718(3) 0.32495(3) 0.262965(19) 0.03130(9) Uani 1 1 d . . .
Bi2 Bi -0.13339(3) 0.70176(2) 0.116971(19) 0.02963(9) Uani 1 1 d . . .
Cl1 Cl 0.2887(3) 0.1627(2) 0.33657(18) 0.0582(6) Uani 1 1 d . . .
Cl2 Cl 0.0683(3) 0.3134(2) 0.07243(16) 0.0523(6) Uani 1 1 d . . .
Cl3 Cl -0.1187(3) 0.1629(3) 0.3043(2) 0.0666(7) Uani 1 1 d . . .
Cl4 Cl -0.0384(3) 0.3557(3) 0.42837(18) 0.0663(8) Uani 1 1 d . . .
Cl5 Cl -0.2591(2) 0.5076(2) 0.17775(16) 0.0422(5) Uani 1 1 d . . .
Cl6 Cl 0.1441(2) 0.5110(2) 0.21563(15) 0.0411(5) Uani 1 1 d . . .
Cl7 Cl -0.2025(3) 0.7449(2) 0.27883(17) 0.0557(6) Uani 1 1 d . . .
Cl8 Cl -0.3934(3) 0.8531(2) 0.03617(18) 0.0527(6) Uani 1 1 d . . .
Cl9 Cl -0.0022(3) 0.8595(2) 0.07956(17) 0.0548(6) Uani 1 1 d . . .
N1 N 0.6148(9) 0.1947(7) 0.1186(6) 0.0489(19) Uani 1 1 d . . .
N2 N 0.4727(12) 0.2682(8) 0.4872(6) 0.059(2) Uani 1 1 d . . .
N3 N 0.2476(9) 0.8757(8) 0.2342(5) 0.0483(19) Uani 1 1 d . . .
C1 C 0.6628(14) 0.0645(10) 0.1702(9) 0.067(3) Uani 1 1 d . . .
H1A H 0.6968 0.0486 0.2366 0.101 Uiso 1 1 calc R . .
H1B H 0.7451 0.0233 0.1401 0.101 Uiso 1 1 calc R . .
H1C H 0.5775 0.0374 0.1672 0.101 Uiso 1 1 calc R . .
C2 C 0.7037(12) 0.2417(11) 0.0620(9) 0.069(3) Uani 1 1 d . . .
H2 H 0.7994 0.1922 0.055 0.083 Uiso 1 1 calc R . .
C3 C 0.6615(12) 0.3590(11) 0.0136(9) 0.070(3) Uani 1 1 d . . .
H3 H 0.7263 0.3884 -0.0278 0.084 Uiso 1 1 calc R . .
C4 C 0.5242(9) 0.4354(8) 0.0247(6) 0.041(2) Uani 1 1 d . . .
C5 C 0.4322(13) 0.3865(10) 0.0804(10) 0.074(4) Uani 1 1 d . . .
H5 H 0.335 0.4342 0.0869 0.088 Uiso 1 1 calc R . .
C6 C 0.4793(14) 0.2686(11) 0.1273(11) 0.080(4) Uani 1 1 d . . .
H6 H 0.4144 0.2375 0.1674 0.096 Uiso 1 1 calc R . .
C7 C 0.5211(18) 0.1391(10) 0.5398(9) 0.096(5) Uani 1 1 d . . .
H7A H 0.569 0.1232 0.6031 0.144 Uiso 1 1 calc R . .
H7B H 0.5926 0.0965 0.5047 0.144 Uiso 1 1 calc R . .
H7C H 0.433 0.1138 0.5458 0.144 Uiso 1 1 calc R . .
C8 C 0.5699(14) 0.3121(11) 0.4331(9) 0.076(3) Uani 1 1 d . . .
H8 H 0.6667 0.2614 0.4294 0.091 Uiso 1 1 calc R . .
C9 C 0.5291(12) 0.4293(11) 0.3839(8) 0.070(3) Uani 1 1 d . . .
H9 H 0.5973 0.4583 0.3457 0.084 Uiso 1 1 calc R . .
C10 C 0.3851(10) 0.5078(9) 0.3898(6) 0.041(2) Uani 1 1 d . . .
C11 C 0.2874(12) 0.4555(10) 0.4473(7) 0.055(2) Uani 1 1 d . . .
H11 H 0.1894 0.5031 0.4527 0.066 Uiso 1 1 calc R . .
C12 C 0.3348(13) 0.3359(11) 0.4953(8) 0.063(3) Uani 1 1 d . . .
H12 H 0.2698 0.3026 0.5335 0.075 Uiso 1 1 calc R . .
C13 C 0.3365(10) 0.6376(8) 0.3356(6) 0.0403(19) Uani 1 1 d . . .
C14 C 0.4236(13) 0.6876(10) 0.2706(10) 0.078(4) Uani 1 1 d . . .
H14 H 0.5166 0.6387 0.2593 0.093 Uiso 1 1 calc R . .
C15 C 0.3789(15) 0.8031(11) 0.2238(10) 0.082(4) Uani 1 1 d . . .
H15 H 0.4428 0.8334 0.1822 0.098 Uiso 1 1 calc R . .
C16 C 0.1946(15) 1.0024(10) 0.1780(8) 0.070(3) Uani 1 1 d . . .
H16A H 0.1401 1.0144 0.1178 0.105 Uiso 1 1 calc R . .
H16B H 0.2812 1.0289 0.1653 0.105 Uiso 1 1 calc R . .
H16C H 0.1277 1.0468 0.2139 0.105 Uiso 1 1 calc R . .
C17 C 0.1558(12) 0.8353(11) 0.2972(7) 0.069(3) Uani 1 1 d . . .
H17 H 0.0638 0.8875 0.3063 0.082 Uiso 1 1 calc R . .
C18 C 0.1991(11) 0.7181(10) 0.3470(7) 0.060(3) Uani 1 1 d . . .
H18 H 0.1352 0.6903 0.3902 0.072 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Bi1 Cl2 Bi2 177.59(9) . 2_565 ?
Bi1 Cl5 Bi2 97.13(6) . . ?
Bi1 Cl6 Bi2 97.04(6) . . ?
C2 N1 C6 116.9(10) . . ?
C2 N1 C1 121.5(9) . . ?
C6 N1 C1 121.6(9) . . ?
C12 N2 C8 122.2(10) . . ?
C12 N2 C7 118.6(11) . . ?
C8 N2 C7 119.2(11) . . ?
C15 N3 C17 120.4(10) . . ?
C15 N3 C16 121.7(9) . . ?
C17 N3 C16 117.9(9) . . ?
N1 C1 H1A 109.5 . . ?
N1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
N1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
N1 C2 C3 122.4(10) . . ?
N1 C2 H2 118.8 . . ?
C3 C2 H2 118.8 . . ?
C2 C3 C4 120.7(10) . . ?
C2 C3 H3 119.7 . . ?
C4 C3 H3 119.7 . . ?
C5 C4 C3 116.6(10) . . ?
C5 C4 C4 121.1(10) . 2_665 ?
C3 C4 C4 122.3(10) . 2_665 ?
C4 C5 C6 120.5(10) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 H5 119.7 . . ?
N1 C6 C5 122.8(10) . . ?
N1 C6 H6 118.6 . . ?
C5 C6 H6 118.6 . . ?
N2 C7 H7A 109.5 . . ?
N2 C7 H7B 109.5 . . ?
H7A C7 H7B 109.5 . . ?
N2 C7 H7C 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
N2 C8 C9 120.7(11) . . ?
N2 C8 H8 119.7 . . ?
C9 C8 H8 119.7 . . ?
C8 C9 C10 120.8(11) . . ?
C8 C9 H9 119.6 . . ?
C10 C9 H9 119.6 . . ?
C9 C10 C11 115.7(10) . . ?
C9 C10 C13 121.9(9) . . ?
C11 C10 C13 122.4(8) . . ?
C12 C11 C10 121.0(10) . . ?
C12 C11 H11 119.5 . . ?
C10 C11 H11 119.5 . . ?
N2 C12 C11 119.7(10) . . ?
N2 C12 H12 120.2 . . ?
C11 C12 H12 120.2 . . ?
C14 C13 C18 114.6(9) . . ?
C14 C13 C10 122.9(8) . . ?
C18 C13 C10 122.5(8) . . ?
C15 C14 C13 121.9(10) . . ?
C15 C14 H14 119 . . ?
C13 C14 H14 119 . . ?
N3 C15 C14 121.9(10) . . ?
N3 C15 H15 119 . . ?
C14 C15 H15 119 . . ?
N3 C16 H16A 109.5 . . ?
N3 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
N3 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N3 C17 C18 119.1(10) . . ?
N3 C17 H17 120.4 . . ?
C18 C17 H17 120.4 . . ?
C17 C18 C13 122.0(9) . . ?
C17 C18 H18 119 . . ?
C13 C18 H18 119 . . ?
Cl4 Bi1 Cl3 89.41(9) . . ?
Cl4 Bi1 Cl1 91.56(9) . . ?
Cl3 Bi1 Cl1 91.95(9) . . ?
Cl4 Bi1 Cl5 89.85(8) . . ?
Cl3 Bi1 Cl5 91.93(8) . . ?
Cl1 Bi1 Cl5 175.89(7) . . ?
Cl4 Bi1 Cl6 89.79(8) . . ?
Cl3 Bi1 Cl6 176.24(8) . . ?
Cl1 Bi1 Cl6 91.75(7) . . ?
Cl5 Bi1 Cl6 84.39(6) . . ?
Cl4 Bi1 Cl2 174.89(9) . . ?
Cl3 Bi1 Cl2 94.02(8) . . ?
Cl1 Bi1 Cl2 92.10(8) . . ?
Cl5 Bi1 Cl2 86.25(7) . . ?
Cl6 Bi1 Cl2 86.54(6) . . ?
Cl8 Bi2 Cl9 92.99(9) . . ?
Cl8 Bi2 Cl7 88.90(8) . . ?
Cl9 Bi2 Cl7 88.75(8) . . ?
Cl8 Bi2 Cl2 86.46(7) . 2_565 ?
Cl9 Bi2 Cl2 85.84(7) . 2_565 ?
Cl7 Bi2 Cl2 172.67(8) . 2_565 ?
Cl8 Bi2 Cl6 173.64(7) . . ?
Cl9 Bi2 Cl6 93.33(8) . . ?
Cl7 Bi2 Cl6 90.49(7) . . ?
Cl2 Bi2 Cl6 94.75(7) 2_565 . ?
Cl8 Bi2 Cl5 92.37(8) . . ?
Cl9 Bi2 Cl5 173.89(7) . . ?
Cl7 Bi2 Cl5 88.43(7) . . ?
Cl2 Bi2 Cl5 97.41(6) 2_565 . ?
Cl6 Bi2 Cl5 81.28(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 Bi1 2.649(2) . ?
Cl2 Bi1 2.855(2) . ?
Cl2 Bi2 2.873(2) 2_565 ?
Cl3 Bi1 2.638(2) . ?
Cl4 Bi1 2.580(2) . ?
Cl5 Bi1 2.803(2) . ?
Cl5 Bi2 2.927(2) . ?
Cl6 Bi1 2.841(2) . ?
Cl6 Bi2 2.894(2) . ?
Cl7 Bi2 2.610(2) . ?
Cl8 Bi2 2.552(2) . ?
Cl9 Bi2 2.562(2) . ?
N1 C2 1.310(13) . ?
N1 C6 1.332(13) . ?
N1 C1 1.489(13) . ?
N2 C12 1.315(14) . ?
N2 C8 1.335(15) . ?
N2 C7 1.480(13) . ?
N3 C15 1.304(14) . ?
N3 C17 1.346(12) . ?
N3 C16 1.464(13) . ?
C1 H1A 0.96 . ?
C1 H1B 0.96 . ?
C1 H1C 0.96 . ?
C2 C3 1.348(16) . ?
C2 H2 0.93 . ?
C3 C4 1.367(13) . ?
C3 H3 0.93 . ?
C4 C5 1.338(13) . ?
C4 C4 1.473(19) 2_665 ?
C5 C6 1.347(17) . ?
C5 H5 0.93 . ?
C6 H6 0.93 . ?
C7 H7A 0.96 . ?
C7 H7B 0.96 . ?
C7 H7C 0.96 . ?
C8 C9 1.349(16) . ?
C8 H8 0.93 . ?
C9 C10 1.400(14) . ?
C9 H9 0.93 . ?
C10 C11 1.411(12) . ?
C10 C13 1.491(13) . ?
C11 C12 1.368(15) . ?
C11 H11 0.93 . ?
C12 H12 0.93 . ?
C13 C14 1.379(13) . ?
C13 C18 1.393(13) . ?
C14 C15 1.322(16) . ?
C14 H14 0.93 . ?
C15 H15 0.93 . ?
C16 H16A 0.96 . ?
C16 H16B 0.96 . ?
C16 H16C 0.96 . ?
C17 C18 1.349(15) . ?
C17 H17 0.93 . ?
C18 H18 0.93 . ?
Bi2 Cl2 2.873(2) 2_565 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 N1 C2 C3 -0.5(18) . . . . ?
C1 N1 C2 C3 179.0(11) . . . . ?
N1 C2 C3 C4 3(2) . . . . ?
C2 C3 C4 C5 -4.2(18) . . . . ?
C2 C3 C4 C4 178.2(12) . . . 2_665 ?
C3 C4 C5 C6 4.1(19) . . . . ?
C4 C4 C5 C6 -178.3(12) 2_665 . . . ?
C2 N1 C6 C5 0.4(19) . . . . ?
C1 N1 C6 C5 -179.1(12) . . . . ?
C4 C5 C6 N1 -2(2) . . . . ?
C12 N2 C8 C9 -0.2(18) . . . . ?
C7 N2 C8 C9 179.7(11) . . . . ?
N2 C8 C9 C10 1.2(19) . . . . ?
C8 C9 C10 C11 -1.7(15) . . . . ?
C8 C9 C10 C13 -179.5(10) . . . . ?
C9 C10 C11 C12 1.5(14) . . . . ?
C13 C10 C11 C12 179.2(9) . . . . ?
C8 N2 C12 C11 0.0(16) . . . . ?
C7 N2 C12 C11 -180.0(9) . . . . ?
C10 C11 C12 N2 -0.6(16) . . . . ?
C9 C10 C13 C14 5.3(14) . . . . ?
C11 C10 C13 C14 -172.3(10) . . . . ?
C9 C10 C13 C18 -174.5(10) . . . . ?
C11 C10 C13 C18 7.9(13) . . . . ?
C18 C13 C14 C15 0.3(18) . . . . ?
C10 C13 C14 C15 -179.5(12) . . . . ?
C17 N3 C15 C14 3(2) . . . . ?
C16 N3 C15 C14 -176.3(12) . . . . ?
C13 C14 C15 N3 -2(2) . . . . ?
C15 N3 C17 C18 -2.1(17) . . . . ?
C16 N3 C17 C18 177.3(10) . . . . ?
N3 C17 C18 C13 0.4(17) . . . . ?
C14 C13 C18 C17 0.5(16) . . . . ?
C10 C13 C18 C17 -179.7(10) . . . . ?
Bi2 Cl5 Bi1 Cl4 92.83(8) . . . . ?
Bi2 Cl5 Bi1 Cl3 -177.77(7) . . . . ?
Bi2 Cl5 Bi1 Cl1 -17.4(10) . . . . ?
Bi2 Cl5 Bi1 Cl6 3.02(6) . . . . ?
Bi2 Cl5 Bi1 Cl2 -83.86(7) . . . . ?
Bi2 Cl6 Bi1 Cl4 -92.93(8) . . . . ?
Bi2 Cl6 Bi1 Cl3 -15.3(11) . . . . ?
Bi2 Cl6 Bi1 Cl1 175.51(7) . . . . ?
Bi2 Cl6 Bi1 Cl5 -3.06(6) . . . . ?
Bi2 Cl6 Bi1 Cl2 83.51(7) . . . . ?
Bi2 Cl2 Bi1 Cl4 111(2) 2_565 . . . ?
Bi2 Cl2 Bi1 Cl3 -116(2) 2_565 . . . ?
Bi2 Cl2 Bi1 Cl1 -24(2) 2_565 . . . ?
Bi2 Cl2 Bi1 Cl5 152(2) 2_565 . . . ?
Bi2 Cl2 Bi1 Cl6 67(2) 2_565 . . . ?
Bi1 Cl6 Bi2 Cl8 6.9(6) . . . . ?
Bi1 Cl6 Bi2 Cl9 -179.94(6) . . . . ?
Bi1 Cl6 Bi2 Cl7 91.28(7) . . . . ?
Bi1 Cl6 Bi2 Cl2 -93.84(7) . . . 2_565 ?
Bi1 Cl6 Bi2 Cl5 2.95(5) . . . . ?
Bi1 Cl5 Bi2 Cl8 177.45(7) . . . . ?
Bi1 Cl5 Bi2 Cl9 -31.2(7) . . . . ?
Bi1 Cl5 Bi2 Cl7 -93.73(8) . . . . ?
Bi1 Cl5 Bi2 Cl2 90.71(7) . . . 2_565 ?
Bi1 Cl5 Bi2 Cl6 -2.99(5) . . . . ?
