#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:18:24 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179240 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/60/4316056.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4316056
loop_
_publ_author_name
'Tanaya Kundu'
'Biprajit Sarkar'
'Tapan Kumar Mondal'
'Jan Fiedler'
'Shaikh M. Mobin'
'Wolfgang Kaim'
'Goutam Kumar Lahiri'
_publ_section_title
;
 Carboxylate Tolerance of the Redox-Active Platform [Ru(μ-tppz)Ru]n,
 where tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, in the
 Electron-Transfer Series [(L)ClRu(μ-tppz)RuCl(L)]n,n= 2+, +, 0, -, 2-,
 with 2-Picolinato, Quinaldato, and 8-Quinolinecarboxylato Ligands (L-)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6565
_journal_page_last               6574
_journal_paper_doi               10.1021/ic100500p
_journal_volume                  49
_journal_year                    2010
_chemical_formula_sum            'C74 H57 Cl4 N17 O11 Ru4'
_chemical_formula_weight         1906.45
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.5080(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.4120(2)
_cell_length_b                   21.4214(3)
_cell_length_c                   22.6136(3)
_cell_measurement_reflns_used    4109
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      32.7402
_cell_measurement_theta_min      3.2294
_cell_volume                     7227.74(17)
_computing_cell_refinement       'CrysAlis RED, Oxford Diffraction Ltd.,'
_computing_data_collection       'CrysAlis CCD, Oxford Diffraction Ltd.,'
_computing_data_reduction        'CrysAlis RED, Oxford Diffraction Ltd.,'
_computing_molecular_graphics    Ortep3
_computing_publication_material  Shelx97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 15.9948
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.911
_diffrn_measurement_device_type  'OXFORD DIFFRACTION XCALIBUR-S'
_diffrn_measurement_method       ω/q-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0552
_diffrn_reflns_av_sigmaI/netI    0.1057
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            84198
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         32.80
_diffrn_reflns_theta_min         3.24
_exptl_absorpt_coefficient_mu    1.043
_exptl_absorpt_correction_T_max  0.8107
_exptl_absorpt_correction_T_min  0.7588
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.31.7 (release 18-10-2006 CrysAlis171 .NET)
(compiled Oct 18 2006,16:28:17)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.752
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3808
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.703
_refine_diff_density_min         -0.850
_refine_diff_density_rms         0.101
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.781
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1014
_refine_ls_number_reflns         24438
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.781
_refine_ls_R_factor_all          0.0758
_refine_ls_R_factor_gt           0.0332
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0199P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0543
_refine_ls_wR_factor_ref         0.0583
_reflns_number_gt                14089
_reflns_number_total             24438
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic100500p_si_005.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4316056
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.061550(11) 0.218338(10) 0.438190(8) 0.01902(4) Uani 1 1 d . . .
Ru2 Ru -0.318653(11) 0.222349(10) 0.515884(8) 0.01797(4) Uani 1 1 d . . .
Ru3 Ru 1.082012(11) 1.027539(9) 0.186519(8) 0.01612(4) Uani 1 1 d . . .
Ru4 Ru 0.697208(11) 0.949020(10) 0.240100(8) 0.01751(4) Uani 1 1 d . . .
Cl1 Cl 0.07857(4) 0.11354(3) 0.47450(3) 0.03048(15) Uani 1 1 d . . .
Cl2 Cl -0.32958(4) 0.32858(3) 0.54045(3) 0.02960(15) Uani 1 1 d . . .
Cl3 Cl 1.10550(4) 0.92093(3) 0.16567(3) 0.02471(13) Uani 1 1 d . . .
Cl4 Cl 0.63483(4) 1.05018(3) 0.21364(3) 0.02906(14) Uani 1 1 d . . .
O1 O 0.06823(10) 0.31047(8) 0.41169(7) 0.0240(4) Uani 1 1 d . . .
O2 O 0.16304(11) 0.38157(9) 0.39311(8) 0.0333(4) Uani 1 1 d . . .
O3 O -0.32182(10) 0.12865(8) 0.49573(7) 0.0249(4) Uani 1 1 d . . .
O4 O -0.39870(12) 0.04042(10) 0.49447(9) 0.0454(5) Uani 1 1 d . . .
O5 O 1.07831(9) 1.12270(8) 0.20109(7) 0.0224(4) Uani 1 1 d . . .
O6 O 1.16170(11) 1.20877(9) 0.21908(8) 0.0376(5) Uani 1 1 d . . .
O7 O 0.73909(10) 0.85843(8) 0.26610(7) 0.0237(4) Uani 1 1 d . . .
O8 O 0.69055(13) 0.76782(11) 0.29090(12) 0.0648(7) Uani 1 1 d . . .
N1 N 0.10614(11) 0.25002(10) 0.52544(8) 0.0213(4) Uani 1 1 d . . .
N2 N -0.05009(11) 0.22400(9) 0.46178(8) 0.0178(4) Uani 1 1 d . . .
N3 N -0.02611(11) 0.19272(10) 0.35744(8) 0.0206(4) Uani 1 1 d . . .
N4 N 0.17830(11) 0.21773(10) 0.40783(8) 0.0226(5) Uani 1 1 d . . .
N5 N -0.23348(11) 0.20526(9) 0.59860(8) 0.0198(4) Uani 1 1 d . . .
N6 N -0.20601(11) 0.22896(9) 0.49464(8) 0.0168(4) Uani 1 1 d . . .
N7 N -0.36253(11) 0.24599(10) 0.42611(8) 0.0205(4) Uani 1 1 d . . .
N8 N -0.43818(12) 0.19566(11) 0.53642(8) 0.0250(5) Uani 1 1 d . . .
N9 N 1.12300(11) 1.01147(9) 0.27858(8) 0.0182(4) Uani 1 1 d . . .
N10 N 0.96853(11) 1.00610(9) 0.20342(8) 0.0164(4) Uani 1 1 d . . .
N11 N 0.99828(11) 1.03889(9) 0.10112(8) 0.0178(4) Uani 1 1 d . . .
N12 N 1.20508(11) 1.05661(10) 0.17267(8) 0.0180(4) Uani 1 1 d . . .
N13 N 0.76273(11) 0.98014(9) 0.32500(8) 0.0178(4) Uani 1 1 d . . .
N14 N 0.81132(11) 0.97219(9) 0.22540(8) 0.0179(4) Uani 1 1 d . . .
N15 N 0.67294(11) 0.92661(9) 0.14950(8) 0.0190(4) Uani 1 1 d . . .
N16 N 0.57911(12) 0.91174(10) 0.25505(8) 0.0195(4) Uani 1 1 d . . .
C1 C 0.18697(15) 0.27475(13) 0.55139(11) 0.0309(6) Uani 1 1 d . . .
H1 H 0.2326 0.2719 0.5300 0.037 Uiso 1 1 calc R . .
C2 C 0.20662(17) 0.30393(14) 0.60725(12) 0.0372(7) Uani 1 1 d . . .
H2 H 0.2648 0.3204 0.6242 0.045 Uiso 1 1 calc R . .
C3 C 0.13993(16) 0.30904(13) 0.63875(12) 0.0327(6) Uani 1 1 d . . .
H3 H 0.1521 0.3285 0.6777 0.039 Uiso 1 1 calc R . .
C4 C 0.05637(15) 0.28547(12) 0.61254(11) 0.0254(6) Uani 1 1 d . . .
H4 H 0.0094 0.2899 0.6326 0.031 Uiso 1 1 calc R . .
C5 C 0.04079(14) 0.25513(11) 0.55676(10) 0.0200(5) Uani 1 1 d . . .
C6 C -0.04802(14) 0.23355(11) 0.52188(10) 0.0181(5) Uani 1 1 d . . .
C7 C -0.12803(13) 0.22530(11) 0.53944(10) 0.0177(5) Uani 1 1 d . . .
C8 C -0.20809(13) 0.22890(11) 0.43401(9) 0.0164(5) Uani 1 1 d . . .
C9 C -0.12803(13) 0.21589(11) 0.41786(10) 0.0178(5) Uani 1 1 d . . .
C10 C -0.11406(14) 0.19199(12) 0.36079(10) 0.0187(5) Uani 1 1 d . . .
C11 C -0.18014(15) 0.16484(12) 0.31533(10) 0.0218(5) Uani 1 1 d . . .
H11 H -0.2396 0.1620 0.3199 0.026 Uiso 1 1 calc R . .
C12 C -0.16039(15) 0.14197(12) 0.26364(11) 0.0242(6) Uani 1 1 d . . .
H12 H -0.2057 0.1235 0.2322 0.029 Uiso 1 1 calc R . .
C13 C -0.07303(15) 0.14631(12) 0.25812(11) 0.0254(6) Uani 1 1 d . . .
H13 H -0.0580 0.1327 0.2219 0.031 Uiso 1 1 calc R . .
C14 C -0.00841(15) 0.17067(12) 0.30585(11) 0.0240(6) Uani 1 1 d . . .
H14 H 0.0517 0.1720 0.3023 0.029 Uiso 1 1 calc R . .
C15 C -0.25475(15) 0.18580(12) 0.64964(10) 0.0239(6) Uani 1 1 d . . .
H15 H -0.3160 0.1864 0.6507 0.029 Uiso 1 1 calc R . .
C16 C -0.19268(15) 0.16513(12) 0.70019(10) 0.0257(6) Uani 1 1 d . . .
H16 H -0.2105 0.1520 0.7355 0.031 Uiso 1 1 calc R . .
C17 C -0.10363(15) 0.16365(12) 0.69888(10) 0.0259(6) Uani 1 1 d . . .
H17 H -0.0597 0.1474 0.7326 0.031 Uiso 1 1 calc R . .
C18 C -0.07886(14) 0.18599(12) 0.64802(10) 0.0227(5) Uani 1 1 d . . .
H18 H -0.0176 0.1866 0.6471 0.027 Uiso 1 1 calc R . .
C19 C -0.14423(14) 0.20749(12) 0.59846(10) 0.0197(5) Uani 1 1 d . . .
C20 C -0.44206(14) 0.27136(13) 0.39789(11) 0.0272(6) Uani 1 1 d . . .
H20 H -0.4887 0.2714 0.4185 0.033 Uiso 1 1 calc R . .
C21 C -0.45843(16) 0.29698(14) 0.34097(12) 0.0333(7) Uani 1 1 d . . .
H21 H -0.5156 0.3144 0.3227 0.040 Uiso 1 1 calc R . .
C22 C -0.39142(15) 0.29763(14) 0.30975(11) 0.0326(7) Uani 1 1 d . . .
H22 H -0.4023 0.3146 0.2697 0.039 Uiso 1 1 calc R . .
C23 C -0.30914(15) 0.27326(12) 0.33797(10) 0.0239(5) Uani 1 1 d . . .
H23 H -0.2617 0.2742 0.3180 0.029 Uiso 1 1 calc R . .
C24 C -0.29548(13) 0.24721(11) 0.39602(10) 0.0177(5) Uani 1 1 d . . .
C25 C 0.14111(15) 0.32708(13) 0.39876(10) 0.0242(6) Uani 1 1 d . . .
C26 C 0.20111(14) 0.27451(13) 0.39011(10) 0.0229(5) Uani 1 1 d . . .
C27 C 0.27275(15) 0.28239(14) 0.36423(11) 0.0324(6) Uani 1 1 d . . .
H27 H 0.2887 0.3227 0.3530 0.039 Uiso 1 1 calc R . .
C28 C 0.32072(16) 0.23027(16) 0.35505(13) 0.0406(8) Uani 1 1 d . . .
H28 H 0.3689 0.2343 0.3361 0.049 Uiso 1 1 calc R . .
C29 C 0.29857(16) 0.17304(15) 0.37335(13) 0.0394(7) Uani 1 1 d . . .
H29 H 0.3316 0.1371 0.3677 0.047 Uiso 1 1 calc R . .
C30 C 0.22707(15) 0.16789(13) 0.40033(12) 0.0307(6) Uani 1 1 d . . .
H30 H 0.2125 0.1281 0.4138 0.037 Uiso 1 1 calc R . .
C31 C -0.38902(16) 0.09697(14) 0.50375(11) 0.0292(6) Uani 1 1 d . . .
C32 C -0.45786(15) 0.13392(14) 0.52560(11) 0.0283(6) Uani 1 1 d . . .
C33 C -0.53510(16) 0.10705(15) 0.53508(13) 0.0412(8) Uani 1 1 d . . .
H33 H -0.5473 0.0640 0.5272 0.049 Uiso 1 1 calc R . .
C34 C -0.59405(18) 0.14448(17) 0.55633(14) 0.0475(9) Uani 1 1 d . . .
H34 H -0.6483 0.1275 0.5621 0.057 Uiso 1 1 calc R . .
C35 C -0.57363(17) 0.20622(16) 0.56907(13) 0.0428(8) Uani 1 1 d . . .
H35 H -0.6125 0.2319 0.5851 0.051 Uiso 1 1 calc R . .
C36 C -0.49514(15) 0.23082(14) 0.55828(11) 0.0318(7) Uani 1 1 d . . .
H36 H -0.4817 0.2737 0.5667 0.038 Uiso 1 1 calc R . .
C37 C 1.20767(14) 1.00914(12) 0.31341(10) 0.0229(5) Uani 1 1 d . . .
H37 H 1.2547 1.0226 0.2961 0.028 Uiso 1 1 calc R . .
C38 C 1.22959(15) 0.98817(12) 0.37300(10) 0.0254(6) Uani 1 1 d . . .
H38 H 1.2901 0.9881 0.3964 0.031 Uiso 1 1 calc R . .
C39 C 1.16155(15) 0.96719(12) 0.39784(10) 0.0252(6) Uani 1 1 d . . .
H39 H 1.1750 0.9513 0.4383 0.030 Uiso 1 1 calc R . .
C40 C 1.07423(14) 0.96954(12) 0.36352(10) 0.0217(5) Uani 1 1 d . . .
H40 H 1.0271 0.9546 0.3799 0.026 Uiso 1 1 calc R . .
C41 C 1.05527(14) 0.99394(11) 0.30461(9) 0.0169(5) Uani 1 1 d . . .
C42 C 0.96494(14) 0.99580(11) 0.26259(9) 0.0168(5) Uani 1 1 d . . .
C43 C 0.88013(13) 0.98876(11) 0.27401(9) 0.0163(5) Uani 1 1 d . . .
C44 C 0.81918(13) 0.97146(11) 0.16644(10) 0.0173(5) Uani 1 1 d . . .
C45 C 0.89571(14) 0.99883(11) 0.15488(9) 0.0166(5) Uani 1 1 d . . .
C46 C 0.91028(13) 1.02457(11) 0.09819(9) 0.0178(5) Uani 1 1 d . . .
C47 C 0.84284(15) 1.04117(11) 0.04747(10) 0.0212(5) Uani 1 1 d . . .
H47 H 0.7820 1.0328 0.0467 0.025 Uiso 1 1 calc R . .
C48 C 0.86383(15) 1.06987(12) -0.00181(10) 0.0253(6) Uani 1 1 d . . .
H48 H 0.8179 1.0814 -0.0366 0.030 Uiso 1 1 calc R . .
C49 C 0.95261(16) 1.08151(12) 0.00040(10) 0.0260(6) Uani 1 1 d . . .
H49 H 0.9689 1.1001 -0.0334 0.031 Uiso 1 1 calc R . .
C50 C 1.01758(15) 1.06579(12) 0.05233(10) 0.0229(5) Uani 1 1 d . . .
H50 H 1.0785 1.0744 0.0536 0.027 Uiso 1 1 calc R . .
C51 C 0.72784(15) 0.98931(12) 0.37330(10) 0.0230(6) Uani 1 1 d . . .
H51 H 0.6683 0.9756 0.3705 0.028 Uiso 1 1 calc R . .
C52 C 0.77396(15) 1.01747(13) 0.42643(11) 0.0280(6) Uani 1 1 d . . .
H52 H 0.7477 1.0219 0.4600 0.034 Uiso 1 1 calc R . .
C53 C 0.85991(15) 1.03924(12) 0.42981(10) 0.0265(6) Uani 1 1 d . . .
H53 H 0.8928 1.0602 0.4654 0.032 Uiso 1 1 calc R . .
C54 C 0.89700(14) 1.03019(12) 0.38112(10) 0.0209(5) Uani 1 1 d . . .
H54 H 0.9555 1.0455 0.3829 0.025 Uiso 1 1 calc R . .
C55 C 0.84935(14) 0.99890(11) 0.32957(9) 0.0181(5) Uani 1 1 d . . .
C56 C 0.60138(14) 0.89724(11) 0.11410(10) 0.0204(5) Uani 1 1 d . . .
H56 H 0.5519 0.8886 0.1308 0.025 Uiso 1 1 calc R . .
C57 C 0.59613(15) 0.87910(12) 0.05497(10) 0.0221(5) Uani 1 1 d . . .
H57 H 0.5429 0.8608 0.0307 0.026 Uiso 1 1 calc R . .
C58 C 0.66994(14) 0.88814(12) 0.03167(10) 0.0223(5) Uani 1 1 d . . .
H58 H 0.6694 0.8741 -0.0083 0.027 Uiso 1 1 calc R . .
C59 C 0.74435(14) 0.91775(11) 0.06708(10) 0.0202(5) Uani 1 1 d . . .
H59 H 0.7961 0.9233 0.0520 0.024 Uiso 1 1 calc R . .
C60 C 0.74371(13) 0.93930(11) 0.12448(10) 0.0167(5) Uani 1 1 d . . .
C61 C 1.15133(15) 1.15341(13) 0.20462(10) 0.0236(5) Uani 1 1 d . . .
C62 C 1.22527(14) 1.11672(12) 0.18821(10) 0.0203(5) Uani 1 1 d . . .
C63 C 1.30681(15) 1.14288(14) 0.18766(12) 0.0320(6) Uani 1 1 d . . .
H63 H 1.3199 1.1850 0.1999 0.038 Uiso 1 1 calc R . .
C64 C 1.36904(16) 1.10665(15) 0.16896(13) 0.0389(7) Uani 1 1 d . . .
H64 H 1.4262 1.1233 0.1690 0.047 Uiso 1 1 calc R . .
C65 C 1.34760(16) 1.04593(14) 0.15024(12) 0.0339(7) Uani 1 1 d . . .
H65 H 1.3887 1.0211 0.1355 0.041 Uiso 1 1 calc R . .
C66 C 1.26591(15) 1.02193(13) 0.15330(10) 0.0268(6) Uani 1 1 d . . .
H66 H 1.2519 0.9798 0.1415 0.032 Uiso 1 1 calc R . .
C67 C 0.67774(17) 0.82234(14) 0.27526(12) 0.0328(6) Uani 1 1 d . . .
C68 C 0.58556(16) 0.85012(13) 0.26748(10) 0.0247(6) Uani 1 1 d . . .
C69 C 0.51202(17) 0.81489(13) 0.27198(11) 0.0313(6) Uani 1 1 d . . .
H69 H 0.5186 0.7715 0.2808 0.038 Uiso 1 1 calc R . .
C70 C 0.42972(17) 0.84278(15) 0.26369(12) 0.0345(7) Uani 1 1 d . . .
H70 H 0.3785 0.8191 0.2657 0.041 Uiso 1 1 calc R . .
C71 C 0.42330(17) 0.90563(15) 0.25244(13) 0.0383(7) Uani 1 1 d . . .
H71 H 0.3674 0.9263 0.2473 0.046 Uiso 1 1 calc R . .
C72 C 0.49847(15) 0.93893(13) 0.24853(12) 0.0309(6) Uani 1 1 d . . .
H72 H 0.4931 0.9826 0.2410 0.037 Uiso 1 1 calc R . .
C111 C 0.56403(19) 0.11226(16) 0.34148(14) 0.0500(8) Uani 1 1 d . . .
H11A H 0.6051 0.1098 0.3822 0.075 Uiso 1 1 calc R . .
H11B H 0.5459 0.1558 0.3323 0.075 Uiso 1 1 calc R . .
H11C H 0.5942 0.0968 0.3110 0.075 Uiso 1 1 calc R . .
C222 C 0.4844(2) 0.07393(19) 0.33980(16) 0.0614(11) Uani 1 1 d . . .
N111 N 0.42380(19) 0.04382(19) 0.33967(18) 0.0965(14) Uani 1 1 d . . .
O111 O 0.11220(18) 0.46260(15) 0.48095(12) 0.0458(7) Uani 1 1 d . . .
O222 O 0.89552(13) 0.86717(11) 0.37221(10) 0.0459(6) Uani 1 1 d . . .
O333 O -0.01722(16) 0.55427(13) 0.42937(13) 0.0454(6) Uani 1 1 d . . .
H111 H 0.1142(17) 0.4409(13) 0.4575(12) 0.021(9) Uiso 1 1 d . . .
H555 H -0.045(2) 0.5554(17) 0.4052(14) 0.035(12) Uiso 1 1 d . . .
H222 H 0.083(2) 0.4837(17) 0.4676(15) 0.046(14) Uiso 1 1 d . . .
H666 H -0.049(2) 0.5519(18) 0.4528(16) 0.078(15) Uiso 1 1 d . . .
H444 H 0.897(3) 0.872(2) 0.4077(19) 0.117 Uiso 1 1 d . . .
H333 H 0.847(3) 0.862(2) 0.3483(19) 0.117 Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ru1 N1 79.57(7) . . ?
N2 Ru1 N3 80.16(7) . . ?
N1 Ru1 N3 159.55(7) . . ?
N2 Ru1 O1 97.61(7) . . ?
N1 Ru1 O1 86.19(7) . . ?
N3 Ru1 O1 93.82(7) . . ?
N2 Ru1 N4 175.54(8) . . ?
N1 Ru1 N4 102.24(7) . . ?
N3 Ru1 N4 97.78(7) . . ?
O1 Ru1 N4 78.51(7) . . ?
N2 Ru1 Cl1 89.58(6) . . ?
N1 Ru1 Cl1 89.93(6) . . ?
N3 Ru1 Cl1 92.62(6) . . ?
O1 Ru1 Cl1 171.07(4) . . ?
N4 Ru1 Cl1 94.48(6) . . ?
N6 Ru2 N5 80.06(7) . . ?
N6 Ru2 N7 80.06(7) . . ?
N5 Ru2 N7 159.96(7) . . ?
N6 Ru2 O3 89.38(7) . . ?
N5 Ru2 O3 90.13(7) . . ?
N7 Ru2 O3 92.19(7) . . ?
N6 Ru2 N8 168.30(9) . . ?
N5 Ru2 N8 98.54(7) . . ?
N7 Ru2 N8 101.45(7) . . ?
O3 Ru2 N8 78.98(8) . . ?
N6 Ru2 Cl2 96.33(6) . . ?
N5 Ru2 Cl2 91.42(6) . . ?
N7 Ru2 Cl2 88.25(6) . . ?
O3 Ru2 Cl2 174.26(4) . . ?
N8 Ru2 Cl2 95.32(6) . . ?
N10 Ru3 N9 79.83(7) . . ?
N10 Ru3 N11 80.07(7) . . ?
N9 Ru3 N11 159.80(7) . . ?
N10 Ru3 O5 98.05(7) . . ?
N9 Ru3 O5 91.00(7) . . ?
N11 Ru3 O5 89.84(7) . . ?
N10 Ru3 N12 175.61(8) . . ?
N9 Ru3 N12 98.15(7) . . ?
N11 Ru3 N12 101.76(7) . . ?
O5 Ru3 N12 78.04(7) . . ?
N10 Ru3 Cl3 90.07(6) . . ?
N9 Ru3 Cl3 90.95(6) . . ?
N11 Ru3 Cl3 91.05(6) . . ?
O5 Ru3 Cl3 171.86(4) . . ?
N12 Ru3 Cl3 93.86(6) . . ?
N14 Ru4 N13 79.71(7) . . ?
N14 Ru4 N15 80.45(7) . . ?
N13 Ru4 N15 160.15(7) . . ?
N14 Ru4 O7 93.25(7) . . ?
N13 Ru4 O7 89.63(7) . . ?
N15 Ru4 O7 91.72(7) . . ?
N14 Ru4 N16 172.41(8) . . ?
N13 Ru4 N16 102.59(7) . . ?
N15 Ru4 N16 97.13(7) . . ?
O7 Ru4 N16 79.59(7) . . ?
N14 Ru4 Cl4 92.89(6) . . ?
N13 Ru4 Cl4 90.71(6) . . ?
N15 Ru4 Cl4 90.05(6) . . ?
O7 Ru4 Cl4 173.81(4) . . ?
N16 Ru4 Cl4 94.31(6) . . ?
C25 O1 Ru1 116.15(16) . . ?
C31 O3 Ru2 117.27(16) . . ?
C61 O5 Ru3 117.04(15) . . ?
C67 O7 Ru4 114.83(16) . . ?
C1 N1 C5 117.5(2) . . ?
C1 N1 Ru1 127.20(16) . . ?
C5 N1 Ru1 114.41(14) . . ?
C9 N2 C6 122.67(17) . . ?
C9 N2 Ru1 118.32(14) . . ?
C6 N2 Ru1 118.96(14) . . ?
C14 N3 C10 117.34(19) . . ?
C14 N3 Ru1 129.18(14) . . ?
C10 N3 Ru1 113.03(14) . . ?
C30 N4 C26 118.8(2) . . ?
C30 N4 Ru1 127.26(17) . . ?
C26 N4 Ru1 113.71(15) . . ?
C15 N5 C19 118.15(18) . . ?
C15 N5 Ru2 127.37(15) . . ?
C19 N5 Ru2 114.02(14) . . ?
C8 N6 C7 122.71(17) . . ?
C8 N6 Ru2 117.18(13) . . ?
C7 N6 Ru2 119.54(14) . . ?
C20 N7 C24 117.8(2) . . ?
C20 N7 Ru2 127.46(15) . . ?
C24 N7 Ru2 113.31(14) . . ?
C36 N8 C32 118.2(2) . . ?
C36 N8 Ru2 128.55(19) . . ?
C32 N8 Ru2 113.20(16) . . ?
C37 N9 C41 117.97(19) . . ?
C37 N9 Ru3 127.47(15) . . ?
C41 N9 Ru3 114.06(14) . . ?
C45 N10 C42 122.64(17) . . ?
C45 N10 Ru3 117.94(13) . . ?
C42 N10 Ru3 119.34(13) . . ?
C50 N11 C46 118.34(18) . . ?
C50 N11 Ru3 127.46(15) . . ?
C46 N11 Ru3 113.52(13) . . ?
C62 N12 C66 118.3(2) . . ?
C62 N12 Ru3 113.78(14) . . ?
C66 N12 Ru3 127.80(17) . . ?
C51 N13 C55 118.33(18) . . ?
C51 N13 Ru4 127.25(14) . . ?
C55 N13 Ru4 114.10(13) . . ?
C44 N14 C43 123.04(17) . . ?
C44 N14 Ru4 118.08(13) . . ?
C43 N14 Ru4 118.89(13) . . ?
C56 N15 C60 117.64(19) . . ?
C56 N15 Ru4 128.50(15) . . ?
C60 N15 Ru4 113.62(14) . . ?
C72 N16 C68 117.6(2) . . ?
C72 N16 Ru4 129.34(17) . . ?
C68 N16 Ru4 112.71(15) . . ?
N1 C1 C2 123.2(2) . . ?
N1 C1 H1 118.4 . . ?
C2 C1 H1 118.4 . . ?
C1 C2 C3 119.0(2) . . ?
C1 C2 H2 120.5 . . ?
C3 C2 H2 120.5 . . ?
C4 C3 C2 118.9(2) . . ?
C4 C3 H3 120.6 . . ?
C2 C3 H3 120.6 . . ?
C3 C4 C5 119.7(2) . . ?
C3 C4 H4 120.1 . . ?
C5 C4 H4 120.1 . . ?
N1 C5 C4 121.7(2) . . ?
N1 C5 C6 113.7(2) . . ?
C4 C5 C6 124.1(2) . . ?
N2 C6 C7 117.45(19) . . ?
N2 C6 C5 111.51(18) . . ?
C7 C6 C5 130.9(2) . . ?
N6 C7 C6 117.17(19) . . ?
N6 C7 C19 111.75(17) . . ?
C6 C7 C19 130.83(19) . . ?
N6 C8 C9 117.54(19) . . ?
N6 C8 C24 112.20(18) . . ?
C9 C8 C24 130.11(19) . . ?
N2 C9 C8 117.23(19) . . ?
N2 C9 C10 113.07(18) . . ?
C8 C9 C10 129.65(19) . . ?
N3 C10 C11 121.1(2) . . ?
N3 C10 C9 114.32(18) . . ?
C11 C10 C9 124.30(19) . . ?
C12 C11 C10 120.4(2) . . ?
C12 C11 H11 119.8 . . ?
C10 C11 H11 119.8 . . ?
C11 C12 C13 118.8(2) . . ?
C11 C12 H12 120.6 . . ?
C13 C12 H12 120.6 . . ?
C14 C13 C12 118.9(2) . . ?
C14 C13 H13 120.5 . . ?
C12 C13 H13 120.5 . . ?
N3 C14 C13 123.3(2) . . ?
N3 C14 H14 118.4 . . ?
C13 C14 H14 118.4 . . ?
N5 C15 C16 123.3(2) . . ?
N5 C15 H15 118.4 . . ?
C16 C15 H15 118.4 . . ?
C15 C16 C17 118.7(2) . . ?
C15 C16 H16 120.6 . . ?
C17 C16 H16 120.6 . . ?
C16 C17 C18 119.5(2) . . ?
C16 C17 H17 120.3 . . ?
C18 C17 H17 120.3 . . ?
C19 C18 C17 119.4(2) . . ?
C19 C18 H18 120.3 . . ?
C17 C18 H18 120.3 . . ?
N5 C19 C18 120.7(2) . . ?
N5 C19 C7 114.11(18) . . ?
C18 C19 C7 124.56(19) . . ?
N7 C20 C21 122.8(2) . . ?
N7 C20 H20 118.6 . . ?
C21 C20 H20 118.6 . . ?
C20 C21 C22 119.9(2) . . ?
C20 C21 H21 120.1 . . ?
C22 C21 H21 120.1 . . ?
C23 C22 C21 118.5(2) . . ?
C23 C22 H22 120.7 . . ?
C21 C22 H22 120.7 . . ?
C22 C23 C24 119.7(2) . . ?
C22 C23 H23 120.2 . . ?
C24 C23 H23 120.2 . . ?
N7 C24 C23 121.3(2) . . ?
N7 C24 C8 113.69(19) . . ?
C23 C24 C8 124.21(19) . . ?
O2 C25 O1 124.5(2) . . ?
O2 C25 C26 120.3(2) . . ?
O1 C25 C26 115.2(2) . . ?
N4 C26 C27 121.9(2) . . ?
N4 C26 C25 114.91(19) . . ?
C27 C26 C25 123.1(2) . . ?
C28 C27 C26 118.6(3) . . ?
C28 C27 H27 120.7 . . ?
C26 C27 H27 120.7 . . ?
C29 C28 C27 119.7(2) . . ?
C29 C28 H28 120.1 . . ?
C27 C28 H28 120.1 . . ?
C28 C29 C30 119.3(3) . . ?
C28 C29 H29 120.3 . . ?
C30 C29 H29 120.3 . . ?
N4 C30 C29 121.5(3) . . ?
N4 C30 H30 119.2 . . ?
C29 C30 H30 119.2 . . ?
O4 C31 O3 124.1(2) . . ?
O4 C31 C32 120.6(2) . . ?
O3 C31 C32 115.3(2) . . ?
N8 C32 C33 122.4(2) . . ?
N8 C32 C31 115.2(2) . . ?
C33 C32 C31 122.4(3) . . ?
C34 C33 C32 118.5(3) . . ?
C34 C33 H33 120.8 . . ?
C32 C33 H33 120.8 . . ?
C35 C34 C33 119.6(3) . . ?
C35 C34 H34 120.2 . . ?
C33 C34 H34 120.2 . . ?
C34 C35 C36 119.3(3) . . ?
C34 C35 H35 120.3 . . ?
C36 C35 H35 120.3 . . ?
N8 C36 C35 121.9(3) . . ?
N8 C36 H36 119.1 . . ?
C35 C36 H36 119.1 . . ?
N9 C37 C38 123.2(2) . . ?
N9 C37 H37 118.4 . . ?
C38 C37 H37 118.4 . . ?
C37 C38 C39 118.5(2) . . ?
C37 C38 H38 120.7 . . ?
C39 C38 H38 120.7 . . ?
C40 C39 C38 119.6(2) . . ?
C40 C39 H39 120.2 . . ?
C38 C39 H39 120.2 . . ?
C39 C40 C41 119.6(2) . . ?
C39 C40 H40 120.2 . . ?
C41 C40 H40 120.2 . . ?
N9 C41 C40 120.86(19) . . ?
N9 C41 C42 114.35(18) . . ?
C40 C41 C42 124.3(2) . . ?
N10 C42 C43 117.67(18) . . ?
N10 C42 C41 111.75(18) . . ?
C43 C42 C41 130.58(19) . . ?
N14 C43 C42 116.75(18) . . ?
N14 C43 C55 111.99(17) . . ?
C42 C43 C55 131.19(19) . . ?
N14 C44 C45 117.50(19) . . ?
N14 C44 C60 112.58(18) . . ?
C45 C44 C60 129.90(19) . . ?
N10 C45 C44 117.28(18) . . ?
N10 C45 C46 112.64(18) . . ?
C44 C45 C46 130.01(19) . . ?
N11 C46 C47 120.5(2) . . ?
N11 C46 C45 114.04(18) . . ?
C47 C46 C45 124.97(19) . . ?
C48 C47 C46 120.2(2) . . ?
C48 C47 H47 119.9 . . ?
C46 C47 H47 119.9 . . ?
C49 C48 C47 118.8(2) . . ?
C49 C48 H48 120.6 . . ?
C47 C48 H48 120.6 . . ?
C48 C49 C50 119.2(2) . . ?
C48 C49 H49 120.4 . . ?
C50 C49 H49 120.4 . . ?
N11 C50 C49 122.8(2) . . ?
N11 C50 H50 118.6 . . ?
C49 C50 H50 118.6 . . ?
N13 C51 C52 123.3(2) . . ?
N13 C51 H51 118.3 . . ?
C52 C51 H51 118.3 . . ?
C51 C52 C53 118.3(2) . . ?
C51 C52 H52 120.9 . . ?
C53 C52 H52 120.9 . . ?
C54 C53 C52 119.4(2) . . ?
C54 C53 H53 120.3 . . ?
C52 C53 H53 120.3 . . ?
C53 C54 C55 120.2(2) . . ?
C53 C54 H54 119.9 . . ?
C55 C54 H54 119.9 . . ?
N13 C55 C54 120.35(19) . . ?
N13 C55 C43 114.18(18) . . ?
C54 C55 C43 125.15(19) . . ?
N15 C56 C57 123.4(2) . . ?
N15 C56 H56 118.3 . . ?
C57 C56 H56 118.3 . . ?
C56 C57 C58 118.5(2) . . ?
C56 C57 H57 120.7 . . ?
C58 C57 H57 120.7 . . ?
C59 C58 C57 119.2(2) . . ?
C59 C58 H58 120.4 . . ?
C57 C58 H58 120.4 . . ?
C58 C59 C60 120.0(2) . . ?
C58 C59 H59 120.0 . . ?
C60 C59 H59 120.0 . . ?
N15 C60 C59 120.9(2) . . ?
N15 C60 C44 113.98(18) . . ?
C59 C60 C44 124.83(19) . . ?
O6 C61 O5 124.2(2) . . ?
O6 C61 C62 120.9(2) . . ?
O5 C61 C62 114.9(2) . . ?
N12 C62 C63 122.4(2) . . ?
N12 C62 C61 115.0(2) . . ?
C63 C62 C61 122.6(2) . . ?
C62 C63 C64 118.6(3) . . ?
C62 C63 H63 120.7 . . ?
C64 C63 H63 120.7 . . ?
C63 C64 C65 119.5(2) . . ?
C63 C64 H64 120.3 . . ?
C65 C64 H64 120.3 . . ?
C66 C65 C64 119.1(2) . . ?
C66 C65 H65 120.4 . . ?
C64 C65 H65 120.4 . . ?
N12 C66 C65 121.9(3) . . ?
N12 C66 H66 119.1 . . ?
C65 C66 H66 119.1 . . ?
O8 C67 O7 123.6(3) . . ?
O8 C67 C68 119.3(3) . . ?
O7 C67 C68 117.1(2) . . ?
N16 C68 C69 122.0(2) . . ?
N16 C68 C67 115.4(2) . . ?
C69 C68 C67 122.7(3) . . ?
C70 C69 C68 119.8(3) . . ?
C70 C69 H69 120.1 . . ?
C68 C69 H69 120.1 . . ?
C71 C70 C69 118.4(2) . . ?
C71 C70 H70 120.8 . . ?
C69 C70 H70 120.8 . . ?
C70 C71 C72 119.8(3) . . ?
C70 C71 H71 120.1 . . ?
C72 C71 H71 120.1 . . ?
N16 C72 C71 122.4(3) . . ?
N16 C72 H72 118.8 . . ?
C71 C72 H72 118.8 . . ?
C222 C111 H11A 109.5 . . ?
C222 C111 H11B 109.5 . . ?
H11A C111 H11B 109.5 . . ?
C222 C111 H11C 109.5 . . ?
H11A C111 H11C 109.5 . . ?
H11B C111 H11C 109.5 . . ?
N111 C222 C111 178.5(5) . . ?
H111 O111 H222 105(4) . . ?
H444 O222 H333 118(4) . . ?
H555 O333 H666 100(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N2 1.9287(16) . ?
Ru1 N1 2.0363(19) . ?
Ru1 N3 2.0555(18) . ?
Ru1 O1 2.0727(17) . ?
Ru1 N4 2.0804(17) . ?
Ru1 Cl1 2.3822(7) . ?
Ru2 N6 1.9190(16) . ?
Ru2 N5 2.0312(18) . ?
Ru2 N7 2.0366(18) . ?
Ru2 O3 2.0562(17) . ?
Ru2 N8 2.0892(18) . ?
Ru2 Cl2 2.3584(7) . ?
Ru3 N10 1.9367(17) . ?
Ru3 N9 2.0476(17) . ?
Ru3 N11 2.0507(17) . ?
Ru3 O5 2.0680(17) . ?
Ru3 N12 2.0931(17) . ?
Ru3 Cl3 2.3779(7) . ?
Ru4 N14 1.9346(17) . ?
Ru4 N13 2.0443(18) . ?
Ru4 N15 2.0456(18) . ?
Ru4 O7 2.0828(18) . ?
Ru4 N16 2.0912(18) . ?
Ru4 Cl4 2.3854(7) . ?
O1 C25 1.280(3) . ?
O2 C25 1.231(3) . ?
O3 C31 1.289(3) . ?
O4 C31 1.232(3) . ?
O5 C61 1.289(3) . ?
O6 C61 1.230(3) . ?
O7 C67 1.278(3) . ?
O8 C67 1.222(3) . ?
N1 C1 1.346(3) . ?
N1 C5 1.373(3) . ?
N2 C9 1.365(3) . ?
N2 C6 1.367(3) . ?
N3 C14 1.348(3) . ?
N3 C10 1.376(3) . ?
N4 C30 1.341(3) . ?
N4 C26 1.354(3) . ?
N5 C15 1.343(3) . ?
N5 C19 1.377(3) . ?
N6 C8 1.363(3) . ?
N6 C7 1.366(3) . ?
N7 C20 1.346(3) . ?
N7 C24 1.373(3) . ?
N8 C36 1.341(3) . ?
N8 C32 1.365(3) . ?
N9 C37 1.346(3) . ?
N9 C41 1.373(3) . ?
N10 C45 1.368(3) . ?
N10 C42 1.371(3) . ?
N11 C50 1.342(3) . ?
N11 C46 1.376(3) . ?
N12 C62 1.350(3) . ?
N12 C66 1.352(3) . ?
N13 C51 1.347(3) . ?
N13 C55 1.373(3) . ?
N14 C44 1.369(3) . ?
N14 C43 1.369(3) . ?
N15 C56 1.346(3) . ?
N15 C60 1.376(3) . ?
N16 C72 1.347(3) . ?
N16 C68 1.348(3) . ?
C1 C2 1.374(3) . ?
C1 H1 0.9500 . ?
C2 C3 1.394(3) . ?
C2 H2 0.9500 . ?
C3 C4 1.372(3) . ?
C3 H3 0.9500 . ?
C4 C5 1.385(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.473(3) . ?
C6 C7 1.398(3) . ?
C7 C19 1.468(3) . ?
C8 C9 1.400(3) . ?
C8 C24 1.458(3) . ?
C9 C10 1.454(3) . ?
C10 C11 1.381(3) . ?
C11 C12 1.370(3) . ?
C11 H11 0.9500 . ?
C12 C13 1.386(3) . ?
C12 H12 0.9500 . ?
C13 C14 1.375(3) . ?
C13 H13 0.9500 . ?
C14 H14 0.9500 . ?
C15 C16 1.368(3) . ?
C15 H15 0.9500 . ?
C16 C17 1.380(3) . ?
C16 H16 0.9500 . ?
C17 C18 1.385(3) . ?
C17 H17 0.9500 . ?
C18 C19 1.385(3) . ?
C18 H18 0.9500 . ?
C20 C21 1.363(3) . ?
C20 H20 0.9500 . ?
C21 C22 1.389(3) . ?
C21 H21 0.9500 . ?
C22 C23 1.372(3) . ?
C22 H22 0.9500 . ?
C23 C24 1.393(3) . ?
C23 H23 0.9500 . ?
C25 C26 1.501(3) . ?
C26 C27 1.383(3) . ?
C27 C28 1.383(4) . ?
C27 H27 0.9500 . ?
C28 C29 1.364(4) . ?
C28 H28 0.9500 . ?
C29 C30 1.391(3) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C32 1.503(3) . ?
C32 C33 1.386(3) . ?
C33 C34 1.385(4) . ?
C33 H33 0.9500 . ?
C34 C35 1.373(4) . ?
C34 H34 0.9500 . ?
C35 C36 1.396(3) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 C38 1.380(3) . ?
C37 H37 0.9500 . ?
C38 C39 1.383(3) . ?
C38 H38 0.9500 . ?
C39 C40 1.376(3) . ?
C39 H39 0.9500 . ?
C40 C41 1.392(3) . ?
C40 H40 0.9500 . ?
C41 C42 1.476(3) . ?
C42 C43 1.403(3) . ?
C43 C55 1.466(3) . ?
C44 C45 1.399(3) . ?
C44 C60 1.475(3) . ?
C45 C46 1.464(3) . ?
C46 C47 1.387(3) . ?
C47 C48 1.380(3) . ?
C47 H47 0.9500 . ?
C48 C49 1.379(3) . ?
C48 H48 0.9500 . ?
C49 C50 1.381(3) . ?
C49 H49 0.9500 . ?
C50 H50 0.9500 . ?
C51 C52 1.373(3) . ?
C51 H51 0.9500 . ?
C52 C53 1.388(3) . ?
C52 H52 0.9500 . ?
C53 C54 1.375(3) . ?
C53 H53 0.9500 . ?
C54 C55 1.385(3) . ?
C54 H54 0.9500 . ?
C56 C57 1.375(3) . ?
C56 H56 0.9500 . ?
C57 C58 1.382(3) . ?
C57 H57 0.9500 . ?
C58 C59 1.378(3) . ?
C58 H58 0.9500 . ?
C59 C60 1.380(3) . ?
C59 H59 0.9500 . ?
C61 C62 1.505(3) . ?
C62 C63 1.379(3) . ?
C63 C64 1.380(4) . ?
C63 H63 0.9500 . ?
C64 C65 1.382(4) . ?
C64 H64 0.9500 . ?
C65 C66 1.378(3) . ?
C65 H65 0.9500 . ?
C66 H66 0.9500 . ?
C67 C68 1.509(3) . ?
C68 C69 1.386(3) . ?
C69 C70 1.372(3) . ?
C69 H69 0.9500 . ?
C70 C71 1.369(4) . ?
C70 H70 0.9500 . ?
C71 C72 1.382(3) . ?
C71 H71 0.9500 . ?
C72 H72 0.9500 . ?
C111 C222 1.470(5) . ?
C111 H11A 0.9800 . ?
C111 H11B 0.9800 . ?
C111 H11C 0.9800 . ?
C222 N111 1.134(4) . ?
O111 H111 0.71(3) . ?
O111 H222 0.65(3) . ?
O222 H444 0.80(4) . ?
O222 H333 0.82(4) . ?
O333 H555 0.61(3) . ?
O333 H666 0.81(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 Ru1 O1 C25 172.49(16) . . . . ?
N1 Ru1 O1 C25 93.55(16) . . . . ?
N3 Ru1 O1 C25 -106.94(16) . . . . ?
N4 Ru1 O1 C25 -9.76(16) . . . . ?
Cl1 Ru1 O1 C25 29.1(4) . . . . ?
N6 Ru2 O3 C31 178.55(17) . . . . ?
N5 Ru2 O3 C31 98.49(17) . . . . ?
N7 Ru2 O3 C31 -101.42(17) . . . . ?
N8 Ru2 O3 C31 -0.18(16) . . . . ?
Cl2 Ru2 O3 C31 -7.1(6) . . . . ?
N10 Ru3 O5 C61 168.11(16) . . . . ?
N9 Ru3 O5 C61 88.24(16) . . . . ?
N11 Ru3 O5 C61 -111.94(16) . . . . ?
N12 Ru3 O5 C61 -9.88(15) . . . . ?
Cl3 Ru3 O5 C61 -15.6(4) . . . . ?
N14 Ru4 O7 C67 -173.73(17) . . . . ?
N13 Ru4 O7 C67 106.60(17) . . . . ?
N15 Ru4 O7 C67 -93.20(17) . . . . ?
N16 Ru4 O7 C67 3.73(16) . . . . ?
Cl4 Ru4 O7 C67 13.4(5) . . . . ?
N2 Ru1 N1 C1 -165.0(2) . . . . ?
N3 Ru1 N1 C1 -157.3(2) . . . . ?
O1 Ru1 N1 C1 -66.6(2) . . . . ?
N4 Ru1 N1 C1 10.8(2) . . . . ?
Cl1 Ru1 N1 C1 105.4(2) . . . . ?
N2 Ru1 N1 C5 4.03(17) . . . . ?
N3 Ru1 N1 C5 11.8(3) . . . . ?
O1 Ru1 N1 C5 102.49(17) . . . . ?
N4 Ru1 N1 C5 179.86(17) . . . . ?
Cl1 Ru1 N1 C5 -85.56(17) . . . . ?
N1 Ru1 N2 C9 171.15(19) . . . . ?
N3 Ru1 N2 C9 -6.11(17) . . . . ?
O1 Ru1 N2 C9 86.47(18) . . . . ?
N4 Ru1 N2 C9 56.8(11) . . . . ?
Cl1 Ru1 N2 C9 -98.84(17) . . . . ?
N1 Ru1 N2 C6 -11.30(18) . . . . ?
N3 Ru1 N2 C6 171.44(19) . . . . ?
O1 Ru1 N2 C6 -95.98(18) . . . . ?
N4 Ru1 N2 C6 -125.6(10) . . . . ?
Cl1 Ru1 N2 C6 78.71(17) . . . . ?
N2 Ru1 N3 C14 -172.5(2) . . . . ?
N1 Ru1 N3 C14 179.8(2) . . . . ?
O1 Ru1 N3 C14 90.4(2) . . . . ?
N4 Ru1 N3 C14 11.5(2) . . . . ?
Cl1 Ru1 N3 C14 -83.4(2) . . . . ?
N2 Ru1 N3 C10 -0.53(17) . . . . ?
N1 Ru1 N3 C10 -8.3(3) . . . . ?
O1 Ru1 N3 C10 -97.60(17) . . . . ?
N4 Ru1 N3 C10 -176.52(17) . . . . ?
Cl1 Ru1 N3 C10 88.59(16) . . . . ?
N2 Ru1 N4 C30 -141.9(10) . . . . ?
N1 Ru1 N4 C30 104.6(2) . . . . ?
N3 Ru1 N4 C30 -79.6(2) . . . . ?
O1 Ru1 N4 C30 -171.9(2) . . . . ?
Cl1 Ru1 N4 C30 13.7(2) . . . . ?
N2 Ru1 N4 C26 33.0(11) . . . . ?
N1 Ru1 N4 C26 -80.51(16) . . . . ?
N3 Ru1 N4 C26 95.31(16) . . . . ?
O1 Ru1 N4 C26 2.98(15) . . . . ?
Cl1 Ru1 N4 C26 -171.42(15) . . . . ?
N6 Ru2 N5 C15 -171.3(2) . . . . ?
N7 Ru2 N5 C15 -178.7(2) . . . . ?
O3 Ru2 N5 C15 -81.9(2) . . . . ?
N8 Ru2 N5 C15 -3.1(2) . . . . ?
Cl2 Ru2 N5 C15 92.5(2) . . . . ?
N6 Ru2 N5 C19 0.68(16) . . . . ?
N7 Ru2 N5 C19 -6.7(3) . . . . ?
O3 Ru2 N5 C19 90.04(17) . . . . ?
N8 Ru2 N5 C19 168.92(17) . . . . ?
Cl2 Ru2 N5 C19 -95.49(16) . . . . ?
N5 Ru2 N6 C8 166.43(18) . . . . ?
N7 Ru2 N6 C8 -16.14(17) . . . . ?
O3 Ru2 N6 C8 76.20(17) . . . . ?
N8 Ru2 N6 C8 82.4(4) . . . . ?
Cl2 Ru2 N6 C8 -103.23(16) . . . . ?
N5 Ru2 N6 C7 -5.13(17) . . . . ?
N7 Ru2 N6 C7 172.31(19) . . . . ?
O3 Ru2 N6 C7 -95.36(18) . . . . ?
N8 Ru2 N6 C7 -89.2(4) . . . . ?
Cl2 Ru2 N6 C7 85.21(17) . . . . ?
N6 Ru2 N7 C20 -159.0(2) . . . . ?
N5 Ru2 N7 C20 -151.6(2) . . . . ?
O3 Ru2 N7 C20 112.0(2) . . . . ?
N8 Ru2 N7 C20 32.8(2) . . . . ?
Cl2 Ru2 N7 C20 -62.2(2) . . . . ?
N6 Ru2 N7 C24 6.97(17) . . . . ?
N5 Ru2 N7 C24 14.4(3) . . . . ?
O3 Ru2 N7 C24 -82.02(17) . . . . ?
N8 Ru2 N7 C24 -161.22(17) . . . . ?
Cl2 Ru2 N7 C24 103.71(16) . . . . ?
N6 Ru2 N8 C36 172.2(3) . . . . ?
N5 Ru2 N8 C36 90.1(2) . . . . ?
N7 Ru2 N8 C36 -91.5(2) . . . . ?
O3 Ru2 N8 C36 178.5(2) . . . . ?
Cl2 Ru2 N8 C36 -2.2(2) . . . . ?
N6 Ru2 N8 C32 -7.5(5) . . . . ?
N5 Ru2 N8 C32 -89.70(17) . . . . ?
N7 Ru2 N8 C32 88.77(17) . . . . ?
O3 Ru2 N8 C32 -1.25(16) . . . . ?
Cl2 Ru2 N8 C32 178.06(15) . . . . ?
N10 Ru3 N9 C37 172.4(2) . . . . ?
N11 Ru3 N9 C37 178.2(2) . . . . ?
O5 Ru3 N9 C37 -89.6(2) . . . . ?
N12 Ru3 N9 C37 -11.5(2) . . . . ?
Cl3 Ru3 N9 C37 82.5(2) . . . . ?
N10 Ru3 N9 C41 0.82(16) . . . . ?
N11 Ru3 N9 C41 6.5(3) . . . . ?
O5 Ru3 N9 C41 98.81(16) . . . . ?
N12 Ru3 N9 C41 176.87(16) . . . . ?
Cl3 Ru3 N9 C41 -89.09(16) . . . . ?
N9 Ru3 N10 C45 -172.23(18) . . . . ?
N11 Ru3 N10 C45 9.77(17) . . . . ?
O5 Ru3 N10 C45 98.20(17) . . . . ?
N12 Ru3 N10 C45 124.9(9) . . . . ?
Cl3 Ru3 N10 C45 -81.28(17) . . . . ?
N9 Ru3 N10 C42 4.55(17) . . . . ?
N11 Ru3 N10 C42 -173.44(19) . . . . ?
O5 Ru3 N10 C42 -85.02(17) . . . . ?
N12 Ru3 N10 C42 -58.4(10) . . . . ?
Cl3 Ru3 N10 C42 95.51(17) . . . . ?
N10 Ru3 N11 C50 168.3(2) . . . . ?
N9 Ru3 N11 C50 162.6(2) . . . . ?
O5 Ru3 N11 C50 70.1(2) . . . . ?
N12 Ru3 N11 C50 -7.6(2) . . . . ?
Cl3 Ru3 N11 C50 -101.8(2) . . . . ?
N10 Ru3 N11 C46 -1.99(16) . . . . ?
N9 Ru3 N11 C46 -7.7(3) . . . . ?
O5 Ru3 N11 C46 -100.19(16) . . . . ?
N12 Ru3 N11 C46 -177.94(16) . . . . ?
Cl3 Ru3 N11 C46 87.90(16) . . . . ?
N10 Ru3 N12 C62 -17.9(10) . . . . ?
N9 Ru3 N12 C62 -80.22(16) . . . . ?
N11 Ru3 N12 C62 96.38(16) . . . . ?
O5 Ru3 N12 C62 9.07(14) . . . . ?
Cl3 Ru3 N12 C62 -171.74(14) . . . . ?
N10 Ru3 N12 C66 158.7(9) . . . . ?
N9 Ru3 N12 C66 96.44(19) . . . . ?
N11 Ru3 N12 C66 -86.95(19) . . . . ?
O5 Ru3 N12 C66 -174.26(19) . . . . ?
Cl3 Ru3 N12 C66 4.92(18) . . . . ?
N14 Ru4 N13 C51 171.6(2) . . . . ?
N15 Ru4 N13 C51 171.0(2) . . . . ?
O7 Ru4 N13 C51 -95.0(2) . . . . ?
N16 Ru4 N13 C51 -15.7(2) . . . . ?
Cl4 Ru4 N13 C51 78.8(2) . . . . ?
N14 Ru4 N13 C55 -1.66(16) . . . . ?
N15 Ru4 N13 C55 -2.3(3) . . . . ?
O7 Ru4 N13 C55 91.71(16) . . . . ?
N16 Ru4 N13 C55 170.96(16) . . . . ?
Cl4 Ru4 N13 C55 -94.47(16) . . . . ?
N13 Ru4 N14 C44 -171.77(18) . . . . ?
N15 Ru4 N14 C44 8.00(17) . . . . ?
O7 Ru4 N14 C44 99.20(17) . . . . ?
N16 Ru4 N14 C44 79.9(6) . . . . ?
Cl4 Ru4 N14 C44 -81.57(17) . . . . ?
N13 Ru4 N14 C43 7.95(17) . . . . ?
N15 Ru4 N14 C43 -172.29(19) . . . . ?
O7 Ru4 N14 C43 -81.08(18) . . . . ?
N16 Ru4 N14 C43 -100.4(5) . . . . ?
Cl4 Ru4 N14 C43 98.15(17) . . . . ?
N14 Ru4 N15 C56 173.0(2) . . . . ?
N13 Ru4 N15 C56 173.6(2) . . . . ?
O7 Ru4 N15 C56 79.9(2) . . . . ?
N16 Ru4 N15 C56 0.2(2) . . . . ?
Cl4 Ru4 N15 C56 -94.1(2) . . . . ?
N14 Ru4 N15 C60 -1.16(16) . . . . ?
N13 Ru4 N15 C60 -0.5(3) . . . . ?
O7 Ru4 N15 C60 -94.16(16) . . . . ?
N16 Ru4 N15 C60 -173.89(16) . . . . ?
Cl4 Ru4 N15 C60 91.77(16) . . . . ?
N14 Ru4 N16 C72 -159.5(5) . . . . ?
N13 Ru4 N16 C72 93.7(2) . . . . ?
N15 Ru4 N16 C72 -88.6(2) . . . . ?
O7 Ru4 N16 C72 -179.0(2) . . . . ?
Cl4 Ru4 N16 C72 2.0(2) . . . . ?
N14 Ru4 N16 C68 13.9(6) . . . . ?
N13 Ru4 N16 C68 -92.93(16) . . . . ?
N15 Ru4 N16 C68 84.78(16) . . . . ?
O7 Ru4 N16 C68 -5.67(15) . . . . ?
Cl4 Ru4 N16 C68 175.37(15) . . . . ?
C5 N1 C1 C2 0.6(4) . . . . ?
Ru1 N1 C1 C2 169.3(2) . . . . ?
N1 C1 C2 C3 -0.7(5) . . . . ?
C1 C2 C3 C4 -0.9(4) . . . . ?
C2 C3 C4 C5 2.4(4) . . . . ?
C1 N1 C5 C4 1.1(4) . . . . ?
Ru1 N1 C5 C4 -169.09(19) . . . . ?
C1 N1 C5 C6 173.1(2) . . . . ?
Ru1 N1 C5 C6 3.0(3) . . . . ?
C3 C4 C5 N1 -2.6(4) . . . . ?
C3 C4 C5 C6 -173.8(2) . . . . ?
C9 N2 C6 C7 9.7(3) . . . . ?
Ru1 N2 C6 C7 -167.78(17) . . . . ?
C9 N2 C6 C5 -166.8(2) . . . . ?
Ru1 N2 C6 C5 15.7(3) . . . . ?
N1 C5 C6 N2 -11.5(3) . . . . ?
C4 C5 C6 N2 160.4(2) . . . . ?
N1 C5 C6 C7 172.6(2) . . . . ?
C4 C5 C6 C7 -15.5(4) . . . . ?
C8 N6 C7 C6 12.1(3) . . . . ?
Ru2 N6 C7 C6 -176.87(17) . . . . ?
C8 N6 C7 C19 -162.9(2) . . . . ?
Ru2 N6 C7 C19 8.2(3) . . . . ?
N2 C6 C7 N6 -21.1(3) . . . . ?
C5 C6 C7 N6 154.5(2) . . . . ?
N2 C6 C7 C19 152.7(2) . . . . ?
C5 C6 C7 C19 -31.6(4) . . . . ?
C7 N6 C8 C9 9.0(3) . . . . ?
Ru2 N6 C8 C9 -162.27(17) . . . . ?
C7 N6 C8 C24 -167.0(2) . . . . ?
Ru2 N6 C8 C24 21.7(3) . . . . ?
C6 N2 C9 C8 11.4(3) . . . . ?
Ru1 N2 C9 C8 -171.15(17) . . . . ?
C6 N2 C9 C10 -166.2(2) . . . . ?
Ru1 N2 C9 C10 11.2(3) . . . . ?
N6 C8 C9 N2 -20.5(3) . . . . ?
C24 C8 C9 N2 154.7(2) . . . . ?
N6 C8 C9 C10 156.6(2) . . . . ?
C24 C8 C9 C10 -28.2(4) . . . . ?
C14 N3 C10 C11 5.4(3) . . . . ?
Ru1 N3 C10 C11 -167.57(18) . . . . ?
C14 N3 C10 C9 179.5(2) . . . . ?
Ru1 N3 C10 C9 6.5(3) . . . . ?
N2 C9 C10 N3 -11.3(3) . . . . ?
C8 C9 C10 N3 171.5(2) . . . . ?
N2 C9 C10 C11 162.5(2) . . . . ?
C8 C9 C10 C11 -14.7(4) . . . . ?
N3 C10 C11 C12 -4.7(4) . . . . ?
C9 C10 C11 C12 -178.2(2) . . . . ?
C10 C11 C12 C13 0.4(4) . . . . ?
C11 C12 C13 C14 3.1(4) . . . . ?
C10 N3 C14 C13 -1.9(4) . . . . ?
Ru1 N3 C14 C13 169.76(19) . . . . ?
C12 C13 C14 N3 -2.3(4) . . . . ?
C19 N5 C15 C16 -3.4(4) . . . . ?
Ru2 N5 C15 C16 168.3(2) . . . . ?
N5 C15 C16 C17 -0.5(4) . . . . ?
C15 C16 C17 C18 3.3(4) . . . . ?
C16 C17 C18 C19 -2.2(4) . . . . ?
C15 N5 C19 C18 4.6(3) . . . . ?
Ru2 N5 C19 C18 -168.22(18) . . . . ?
C15 N5 C19 C7 176.1(2) . . . . ?
Ru2 N5 C19 C7 3.3(3) . . . . ?
C17 C18 C19 N5 -1.8(4) . . . . ?
C17 C18 C19 C7 -172.5(2) . . . . ?
N6 C7 C19 N5 -7.1(3) . . . . ?
C6 C7 C19 N5 178.8(2) . . . . ?
N6 C7 C19 C18 164.0(2) . . . . ?
C6 C7 C19 C18 -10.0(4) . . . . ?
C24 N7 C20 C21 1.0(4) . . . . ?
Ru2 N7 C20 C21 166.4(2) . . . . ?
N7 C20 C21 C22 -0.1(4) . . . . ?
C20 C21 C22 C23 -1.3(4) . . . . ?
C21 C22 C23 C24 1.7(4) . . . . ?
C20 N7 C24 C23 -0.6(4) . . . . ?
Ru2 N7 C24 C23 -168.00(19) . . . . ?
C20 N7 C24 C8 169.8(2) . . . . ?
Ru2 N7 C24 C8 2.4(3) . . . . ?
C22 C23 C24 N7 -0.8(4) . . . . ?
C22 C23 C24 C8 -170.1(2) . . . . ?
N6 C8 C24 N7 -14.9(3) . . . . ?
C9 C8 C24 N7 169.7(2) . . . . ?
N6 C8 C24 C23 155.1(2) . . . . ?
C9 C8 C24 C23 -20.3(4) . . . . ?
Ru1 O1 C25 O2 -166.20(19) . . . . ?
Ru1 O1 C25 C26 14.1(2) . . . . ?
C30 N4 C26 C27 0.4(3) . . . . ?
Ru1 N4 C26 C27 -174.97(18) . . . . ?
C30 N4 C26 C25 178.4(2) . . . . ?
Ru1 N4 C26 C25 3.0(2) . . . . ?
O2 C25 C26 N4 168.9(2) . . . . ?
O1 C25 C26 N4 -11.4(3) . . . . ?
O2 C25 C26 C27 -13.2(4) . . . . ?
O1 C25 C26 C27 166.6(2) . . . . ?
N4 C26 C27 C28 1.6(4) . . . . ?
C25 C26 C27 C28 -176.3(2) . . . . ?
C26 C27 C28 C29 -2.2(4) . . . . ?
C27 C28 C29 C30 0.8(4) . . . . ?
C26 N4 C30 C29 -1.8(4) . . . . ?
Ru1 N4 C30 C29 172.87(19) . . . . ?
C28 C29 C30 N4 1.2(4) . . . . ?
Ru2 O3 C31 O4 -178.8(2) . . . . ?
Ru2 O3 C31 C32 1.5(3) . . . . ?
C36 N8 C32 C33 1.5(4) . . . . ?
Ru2 N8 C32 C33 -178.7(2) . . . . ?
C36 N8 C32 C31 -177.5(2) . . . . ?
Ru2 N8 C32 C31 2.3(3) . . . . ?
O4 C31 C32 N8 177.7(2) . . . . ?
O3 C31 C32 N8 -2.6(3) . . . . ?
O4 C31 C32 C33 -1.3(4) . . . . ?
O3 C31 C32 C33 178.5(2) . . . . ?
N8 C32 C33 C34 -0.1(4) . . . . ?
C31 C32 C33 C34 178.8(2) . . . . ?
C32 C33 C34 C35 -1.9(4) . . . . ?
C33 C34 C35 C36 2.3(4) . . . . ?
C32 N8 C36 C35 -1.1(4) . . . . ?
Ru2 N8 C36 C35 179.17(19) . . . . ?
C34 C35 C36 N8 -0.8(4) . . . . ?
C41 N9 C37 C38 2.2(4) . . . . ?
Ru3 N9 C37 C38 -169.15(19) . . . . ?
N9 C37 C38 C39 1.5(4) . . . . ?
C37 C38 C39 C40 -2.0(4) . . . . ?
C38 C39 C40 C41 -1.1(4) . . . . ?
C37 N9 C41 C40 -5.3(3) . . . . ?
Ru3 N9 C41 C40 167.15(18) . . . . ?
C37 N9 C41 C42 -178.0(2) . . . . ?
Ru3 N9 C41 C42 -5.5(3) . . . . ?
C39 C40 C41 N9 4.8(4) . . . . ?
C39 C40 C41 C42 176.7(2) . . . . ?
C45 N10 C42 C43 -11.8(3) . . . . ?
Ru3 N10 C42 C43 171.55(17) . . . . ?
C45 N10 C42 C41 168.1(2) . . . . ?
Ru3 N10 C42 C41 -8.6(3) . . . . ?
N9 C41 C42 N10 8.8(3) . . . . ?
C40 C41 C42 N10 -163.5(2) . . . . ?
N9 C41 C42 C43 -171.3(2) . . . . ?
C40 C41 C42 C43 16.4(4) . . . . ?
C44 N14 C43 C42 -9.8(3) . . . . ?
Ru4 N14 C43 C42 170.46(17) . . . . ?
C44 N14 C43 C55 167.5(2) . . . . ?
Ru4 N14 C43 C55 -12.2(3) . . . . ?
N10 C42 C43 N14 21.0(3) . . . . ?
C41 C42 C43 N14 -158.9(2) . . . . ?
N10 C42 C43 C55 -155.7(2) . . . . ?
C41 C42 C43 C55 24.4(4) . . . . ?
C43 N14 C44 C45 -11.0(3) . . . . ?
Ru4 N14 C44 C45 168.69(17) . . . . ?
C43 N14 C44 C60 167.5(2) . . . . ?
Ru4 N14 C44 C60 -12.8(3) . . . . ?
C42 N10 C45 C44 -9.1(3) . . . . ?
Ru3 N10 C45 C44 167.54(17) . . . . ?
C42 N10 C45 C46 168.1(2) . . . . ?
Ru3 N10 C45 C46 -15.2(3) . . . . ?
N14 C44 C45 N10 20.3(3) . . . . ?
C60 C44 C45 N10 -157.9(2) . . . . ?
N14 C44 C45 C46 -156.4(2) . . . . ?
C60 C44 C45 C46 25.4(4) . . . . ?
C50 N11 C46 C47 -4.0(3) . . . . ?
Ru3 N11 C46 C47 167.31(18) . . . . ?
C50 N11 C46 C45 -176.6(2) . . . . ?
Ru3 N11 C46 C45 -5.3(3) . . . . ?
N10 C45 C46 N11 12.9(3) . . . . ?
C44 C45 C46 N11 -170.3(2) . . . . ?
N10 C45 C46 C47 -159.3(2) . . . . ?
C44 C45 C46 C47 17.5(4) . . . . ?
N11 C46 C47 C48 2.8(4) . . . . ?
C45 C46 C47 C48 174.6(2) . . . . ?
C46 C47 C48 C49 0.1(4) . . . . ?
C47 C48 C49 C50 -1.8(4) . . . . ?
C46 N11 C50 C49 2.3(4) . . . . ?
Ru3 N11 C50 C49 -167.65(19) . . . . ?
C48 C49 C50 N11 0.6(4) . . . . ?
C55 N13 C51 C52 1.2(4) . . . . ?
Ru4 N13 C51 C52 -171.82(19) . . . . ?
N13 C51 C52 C53 2.0(4) . . . . ?
C51 C52 C53 C54 -2.1(4) . . . . ?
C52 C53 C54 C55 -0.9(4) . . . . ?
C51 N13 C55 C54 -4.3(3) . . . . ?
Ru4 N13 C55 C54 169.66(18) . . . . ?
C51 N13 C55 C43 -178.1(2) . . . . ?
Ru4 N13 C55 C43 -4.2(2) . . . . ?
C53 C54 C55 N13 4.1(4) . . . . ?
C53 C54 C55 C43 177.3(2) . . . . ?
N14 C43 C55 N13 10.2(3) . . . . ?
C42 C43 C55 N13 -173.0(2) . . . . ?
N14 C43 C55 C54 -163.3(2) . . . . ?
C42 C43 C55 C54 13.5(4) . . . . ?
C60 N15 C56 C57 0.5(3) . . . . ?
Ru4 N15 C56 C57 -173.36(18) . . . . ?
N15 C56 C57 C58 3.9(4) . . . . ?
C56 C57 C58 C59 -3.3(4) . . . . ?
C57 C58 C59 C60 -1.6(4) . . . . ?
C56 N15 C60 C59 -5.6(3) . . . . ?
Ru4 N15 C60 C59 169.23(18) . . . . ?
C56 N15 C60 C44 -179.9(2) . . . . ?
Ru4 N15 C60 C44 -5.1(3) . . . . ?
C58 C59 C60 N15 6.1(4) . . . . ?
C58 C59 C60 C44 179.9(2) . . . . ?
N14 C44 C60 N15 11.3(3) . . . . ?
C45 C44 C60 N15 -170.4(2) . . . . ?
N14 C44 C60 C59 -162.8(2) . . . . ?
C45 C44 C60 C59 15.5(4) . . . . ?
Ru3 O5 C61 O6 -172.50(19) . . . . ?
Ru3 O5 C61 C62 8.7(2) . . . . ?
C66 N12 C62 C63 -3.0(3) . . . . ?
Ru3 N12 C62 C63 173.99(18) . . . . ?
C66 N12 C62 C61 175.50(19) . . . . ?
Ru3 N12 C62 C61 -7.5(2) . . . . ?
O6 C61 C62 N12 -179.4(2) . . . . ?
O5 C61 C62 N12 -0.6(3) . . . . ?
O6 C61 C62 C63 -0.9(4) . . . . ?
O5 C61 C62 C63 177.9(2) . . . . ?
N12 C62 C63 C64 1.8(4) . . . . ?
C61 C62 C63 C64 -176.6(2) . . . . ?
C62 C63 C64 C65 1.3(4) . . . . ?
C63 C64 C65 C66 -2.9(4) . . . . ?
C62 N12 C66 C65 1.3(3) . . . . ?
Ru3 N12 C66 C65 -175.28(18) . . . . ?
C64 C65 C66 N12 1.7(4) . . . . ?
Ru4 O7 C67 O8 -179.8(2) . . . . ?
Ru4 O7 C67 C68 -1.3(3) . . . . ?
C72 N16 C68 C69 1.7(3) . . . . ?
Ru4 N16 C68 C69 -172.54(18) . . . . ?
C72 N16 C68 C67 -179.1(2) . . . . ?
Ru4 N16 C68 C67 6.7(2) . . . . ?
O8 C67 C68 N16 174.8(3) . . . . ?
O7 C67 C68 N16 -3.8(3) . . . . ?
O8 C67 C68 C69 -6.0(4) . . . . ?
O7 C67 C68 C69 175.5(2) . . . . ?
N16 C68 C69 C70 0.0(4) . . . . ?
C67 C68 C69 C70 -179.2(2) . . . . ?
C68 C69 C70 C71 -1.5(4) . . . . ?
C69 C70 C71 C72 1.3(4) . . . . ?
C68 N16 C72 C71 -1.9(4) . . . . ?
Ru4 N16 C72 C71 171.21(19) . . . . ?
C70 C71 C72 N16 0.4(4) . . . . ?
