#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:19:42 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179241 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/61/4316139.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4316139
loop_
_publ_author_name
'William A. Merrill'
'Robert J. Wright'
'Corneliu S. Stanciu'
'Marilyn M. Olmstead'
'James C. Fettinger'
'Philip P. Power'
_publ_section_title
;
 Synthesis and Structural Characterization of a Series of Dimeric
 Metal(II) Imido Complexes {M(μ-NAr#)}2 [M = Ge, Sn, Pb; Ar#=
 C6H3-2,6-(C6H2-2,4,6-Me3)2] and the Related Monomeric Primary Amido
 Derivatives M{N(H)Ar#}2 (M = Ge, Sn, Pb): Spectroscopic Manifestations of
 Secondary Metal-Ligand Interactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              7097
_journal_page_last               7105
_journal_paper_doi               10.1021/ic100831c
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety         'C48 H50 Ge2 N2'
_chemical_formula_sum            'C48 H50 Ge2 N2'
_chemical_formula_weight         800.08
_chemical_melting_point          287
_chemical_name_common            {(2,6-dimesitylphenyl)imidogermanium(II)}2
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.649(2)
_cell_angle_beta                 91.118(2)
_cell_angle_gamma                95.606(2)
_cell_formula_units_Z            2
_cell_length_a                   11.1086(12)
_cell_length_b                   11.9616(13)
_cell_length_c                   15.657(2)
_cell_measurement_reflns_used    1015
_cell_measurement_temperature    90(2)
_cell_measurement_theta_max      30.5
_cell_measurement_theta_min      2.7
_cell_volume                     2065.6(4)
_computing_cell_refinement       'SAINT 6.45A (Bruker, 2003)'
_computing_data_collection       'SMART 5.054 (Bruker, 2003)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL 5.1, XP (Sheldrick, 1994)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      90(2)
_diffrn_detector_area_resol_mean 8.3
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker SMART 1000'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0176
_diffrn_reflns_av_sigmaI/netI    0.0217
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            23470
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         1.30
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.489
_exptl_absorpt_correction_T_max  0.696
_exptl_absorpt_correction_T_min  0.553
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2.10 (Sheldrick, 2004)'
_exptl_crystal_colour            red-orange
_exptl_crystal_density_diffrn    1.286
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             832
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.38
_exptl_crystal_size_min          0.26
_refine_diff_density_max         1.597
_refine_diff_density_min         -0.830
_refine_diff_density_rms         0.066
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     481
_refine_ls_number_reflns         9471
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0389
_refine_ls_R_factor_gt           0.0323
_refine_ls_shift/su_max          0.045
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0517P)²+1.3978P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0880
_refine_ls_wR_factor_ref         0.0920
_reflns_number_gt                8202
_reflns_number_total             9471
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic100831c_si_001_1.cif
_cod_data_source_block           rjw22
_cod_database_code               4316139
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge1 Ge 0.785144(17) 0.796224(18) 0.184742(13) 0.02295(7) Uani 1 1 d . . .
Ge2 Ge 0.701689(18) 0.650252(18) 0.313512(14) 0.02452(7) Uani 1 1 d . . .
N1 N 0.83976(13) 0.68131(12) 0.24826(10) 0.0162(3) Uani 1 1 d . . .
N2 N 0.65255(13) 0.77405(13) 0.25774(10) 0.0177(3) Uani 1 1 d . . .
C1 C 0.95252(15) 0.63894(15) 0.24619(11) 0.0162(3) Uani 1 1 d . . .
C2 C 0.96296(15) 0.52289(15) 0.25214(11) 0.0164(3) Uani 1 1 d . . .
C3 C 1.07753(16) 0.48407(15) 0.25107(13) 0.0205(4) Uani 1 1 d . . .
H3A H 1.0844 0.4060 0.2548 0.025 Uiso 1 1 calc R . .
C4 C 1.18154(16) 0.55696(16) 0.24470(14) 0.0234(4) Uani 1 1 d . . .
H4A H 1.2588 0.5291 0.2445 0.028 Uiso 1 1 calc R . .
C5 C 1.17161(16) 0.67085(16) 0.23870(13) 0.0213(4) Uani 1 1 d . . .
H5A H 1.2427 0.7211 0.2346 0.026 Uiso 1 1 calc R . .
C6 C 1.05920(16) 0.71248(15) 0.23866(12) 0.0173(3) Uani 1 1 d . . .
C7 C 0.85320(15) 0.44112(14) 0.25818(12) 0.0176(3) Uani 1 1 d . . .
C8 C 0.82317(16) 0.39703(15) 0.33711(13) 0.0205(4) Uani 1 1 d . . .
C9 C 0.72319(17) 0.31759(16) 0.34063(13) 0.0236(4) Uani 1 1 d . . .
H9A H 0.7033 0.2874 0.3938 0.028 Uiso 1 1 calc R . .
C10 C 0.65154(17) 0.28116(16) 0.26823(14) 0.0241(4) Uani 1 1 d . . .
C11 C 0.68172(17) 0.32712(16) 0.19116(14) 0.0245(4) Uani 1 1 d . . .
H11A H 0.6330 0.3040 0.1414 0.029 Uiso 1 1 calc R . .
C12 C 0.78141(17) 0.40610(16) 0.18485(12) 0.0210(4) Uani 1 1 d . . .
C13 C 1.04885(15) 0.83509(15) 0.22971(13) 0.0188(4) Uani 1 1 d . . .
C14 C 1.01977(16) 0.90417(16) 0.30078(13) 0.0229(4) Uani 1 1 d . . .
C15 C 0.99708(18) 1.01485(17) 0.28868(15) 0.0287(4) Uani 1 1 d . . .
H15A H 0.9759 1.0613 0.3365 0.034 Uiso 1 1 calc R . .
C16 C 1.00454(18) 1.05919(16) 0.20887(17) 0.0303(5) Uani 1 1 d . . .
C17 C 1.04108(17) 0.99223(17) 0.14054(15) 0.0279(4) Uani 1 1 d . . .
H17A H 1.0516 1.0231 0.0865 0.033 Uiso 1 1 calc R . .
C18 C 1.06287(16) 0.88032(16) 0.14930(13) 0.0222(4) Uani 1 1 d . . .
C19 C 0.89620(19) 0.43550(19) 0.41765(14) 0.0295(4) Uani 1 1 d . . .
H19A H 0.8585 0.4001 0.4665 0.044 Uiso 1 1 calc R . .
H19B H 0.8990 0.5175 0.4268 0.044 Uiso 1 1 calc R . .
H19C H 0.9787 0.4139 0.4119 0.044 Uiso 1 1 calc R . .
C20 C 0.54619(19) 0.19205(19) 0.27370(16) 0.0338(5) Uani 1 1 d . . .
H20A H 0.5010 0.2082 0.3254 0.051 Uiso 1 1 calc R . .
H20B H 0.5765 0.1181 0.2761 0.051 Uiso 1 1 calc R . .
H20C H 0.4928 0.1921 0.2232 0.051 Uiso 1 1 calc R . .
C21 C 0.8128(2) 0.45087(19) 0.09881(14) 0.0301(4) Uani 1 1 d . . .
H21A H 0.7612 0.4087 0.0539 0.045 Uiso 1 1 calc R . .
H21B H 0.8978 0.4421 0.0872 0.045 Uiso 1 1 calc R . .
H21C H 0.7996 0.5308 0.0997 0.045 Uiso 1 1 calc R . .
C22 C 1.0132(2) 0.85971(19) 0.38848(14) 0.0304(4) Uani 1 1 d . . .
H22A H 1.0029 0.9215 0.4310 0.046 Uiso 1 1 calc R . .
H22B H 1.0881 0.8265 0.4015 0.046 Uiso 1 1 calc R . .
H22C H 0.9443 0.8021 0.3900 0.046 Uiso 1 1 calc R . .
C23 C 0.9695(2) 1.17648(18) 0.1962(2) 0.0428(6) Uani 1 1 d . . .
H23A H 1.0222 1.2120 0.1542 0.064 Uiso 1 1 calc R . .
H23B H 0.9783 1.2216 0.2509 0.064 Uiso 1 1 calc R . .
H23C H 0.8852 1.1716 0.1755 0.064 Uiso 1 1 calc R . .
C24 C 1.0946(2) 0.80821(18) 0.07193(14) 0.0292(4) Uani 1 1 d . . .
H24A H 1.0340 0.7430 0.0630 0.044 Uiso 1 1 calc R . .
H24B H 1.1745 0.7824 0.0812 0.044 Uiso 1 1 calc R . .
H24C H 1.0957 0.8525 0.0213 0.044 Uiso 1 1 calc R . .
C25 C 0.54906(15) 0.83124(14) 0.26189(11) 0.0154(3) Uani 1 1 d . . .
C26 C 0.49374(15) 0.86434(14) 0.18657(11) 0.0151(3) Uani 1 1 d . . .
C27 C 0.39330(15) 0.92567(14) 0.19270(11) 0.0163(3) Uani 1 1 d . . .
H27A H 0.3570 0.9482 0.1420 0.020 Uiso 1 1 calc R . .
C28 C 0.34529(15) 0.95442(14) 0.27137(12) 0.0175(3) Uani 1 1 d . . .
H28A H 0.2777 0.9972 0.2746 0.021 Uiso 1 1 calc R . .
C29 C 0.39742(16) 0.91979(15) 0.34542(12) 0.0180(3) Uani 1 1 d . . .
H29A H 0.3640 0.9382 0.3993 0.022 Uiso 1 1 calc R . .
C30 C 0.49799(16) 0.85855(15) 0.34190(11) 0.0170(3) Uani 1 1 d . . .
C31 C 0.54261(15) 0.83035(16) 0.10143(11) 0.0179(3) Uani 1 1 d . . .
C32 C 0.52304(19) 0.71746(18) 0.07026(14) 0.0290(4) Uani 1 1 d . . .
C33 C 0.5770(2) 0.6833(2) -0.00536(16) 0.0400(6) Uani 1 1 d . . .
H33A H 0.5642 0.6065 -0.0259 0.048 Uiso 1 1 calc R . .
C34 C 0.6486(2) 0.7576(2) -0.05137(14) 0.0349(5) Uani 1 1 d . . .
C35 C 0.66511(18) 0.86926(19) -0.02108(13) 0.0272(4) Uani 1 1 d . . .
H35A H 0.7131 0.9215 -0.0526 0.033 Uiso 1 1 calc R . .
C36 C 0.61326(16) 0.90766(17) 0.05475(12) 0.0205(4) Uani 1 1 d . . .
C37 C 0.55537(16) 0.82152(16) 0.42118(11) 0.0199(4) Uani 1 1 d . . .
C38 C 0.50782(18) 0.72235(17) 0.45738(12) 0.0240(4) Uani 1 1 d . . .
C39 C 0.5702(2) 0.68432(19) 0.52647(13) 0.0302(5) Uani 1 1 d . . .
H39A H 0.5381 0.6179 0.5515 0.036 Uiso 1 1 calc R . .
C40 C 0.6774(2) 0.7406(2) 0.55946(13) 0.0322(5) Uani 1 1 d . . .
C41 C 0.72095(19) 0.8403(2) 0.52479(13) 0.0306(5) Uani 1 1 d . . .
H41A H 0.7932 0.8808 0.5482 0.037 Uiso 1 1 calc R . .
C42 C 0.66110(17) 0.88238(18) 0.45653(12) 0.0247(4) Uani 1 1 d . . .
C43 C 0.4473(3) 0.6311(2) 0.11819(19) 0.0465(7) Uani 1 1 d . . .
H43A H 0.4686 0.5555 0.1006 0.070 Uiso 1 1 calc R . .
H43B H 0.3614 0.6357 0.1051 0.070 Uiso 1 1 calc R . .
H43C H 0.4629 0.6460 0.1799 0.070 Uiso 1 1 calc R . .
C44 C 0.7088(3) 0.7160(3) -0.13165(17) 0.0533(7) Uani 1 1 d . . .
H44A H 0.7419 0.7805 -0.1623 0.080 Uiso 1 1 calc R . .
H44B H 0.6491 0.6691 -0.1686 0.080 Uiso 1 1 calc R . .
H44C H 0.7744 0.6715 -0.1160 0.080 Uiso 1 1 calc R . .
C45 C 0.63979(19) 1.02899(17) 0.08711(14) 0.0276(4) Uani 1 1 d . . .
H45A H 0.6917 1.0691 0.0468 0.041 Uiso 1 1 calc R . .
H45B H 0.6812 1.0330 0.1432 0.041 Uiso 1 1 calc R . .
H45C H 0.5638 1.0638 0.0924 0.041 Uiso 1 1 calc R . .
C46 C 0.3951(2) 0.65529(19) 0.42045(14) 0.0314(5) Uani 1 1 d . . .
H46A H 0.3717 0.5935 0.4568 0.047 Uiso 1 1 calc R . .
H46B H 0.4106 0.6245 0.3627 0.047 Uiso 1 1 calc R . .
H46C H 0.3295 0.7042 0.4178 0.047 Uiso 1 1 calc R . .
C47 C 0.7466(3) 0.6944(3) 0.63140(15) 0.0475(7) Uani 1 1 d . . .
H47A H 0.6897 0.6517 0.6672 0.071 Uiso 1 1 calc R . .
H47B H 0.7905 0.7568 0.6663 0.071 Uiso 1 1 calc R . .
H47C H 0.8042 0.6447 0.6073 0.071 Uiso 1 1 calc R . .
C48 C 0.70998(19) 0.9907(2) 0.42043(14) 0.0305(5) Uani 1 1 d . . .
H48A H 0.7857 1.0197 0.4508 0.046 Uiso 1 1 calc R . .
H48B H 0.6508 1.0459 0.4275 0.046 Uiso 1 1 calc R . .
H48C H 0.7253 0.9769 0.3594 0.046 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ge1 N2 81.01(6) . . ?
N1 Ge1 Ge2 40.50(4) . . ?
N2 Ge1 Ge2 40.72(4) . . ?
N1 Ge2 N2 81.32(6) . . ?
N1 Ge2 Ge1 40.70(4) . . ?
N2 Ge2 Ge1 40.84(5) . . ?
C1 N1 Ge2 133.01(12) . . ?
C1 N1 Ge1 128.16(12) . . ?
Ge2 N1 Ge1 98.80(7) . . ?
C25 N2 Ge2 133.17(12) . . ?
C25 N2 Ge1 128.29(12) . . ?
Ge2 N2 Ge1 98.44(7) . . ?
N1 C1 C6 120.20(15) . . ?
N1 C1 C2 121.10(16) . . ?
C6 C1 C2 118.70(15) . . ?
C3 C2 C1 119.36(16) . . ?
C3 C2 C7 119.68(16) . . ?
C1 C2 C7 120.96(15) . . ?
C4 C3 C2 121.49(17) . . ?
C4 C3 H3A 119.3 . . ?
C2 C3 H3A 119.3 . . ?
C5 C4 C3 119.30(16) . . ?
C5 C4 H4A 120.3 . . ?
C3 C4 H4A 120.4 . . ?
C6 C5 C4 120.89(17) . . ?
C6 C5 H5A 119.6 . . ?
C4 C5 H5A 119.6 . . ?
C5 C6 C1 120.25(16) . . ?
C5 C6 C13 120.64(16) . . ?
C1 C6 C13 119.12(15) . . ?
C12 C7 C8 119.77(17) . . ?
C12 C7 C2 120.14(17) . . ?
C8 C7 C2 120.08(16) . . ?
C9 C8 C7 119.14(18) . . ?
C9 C8 C19 119.75(18) . . ?
C7 C8 C19 121.11(17) . . ?
C8 C9 C10 121.81(19) . . ?
C8 C9 H9A 119.1 . . ?
C10 C9 H9A 119.1 . . ?
C11 C10 C9 118.10(18) . . ?
C11 C10 C20 121.44(19) . . ?
C9 C10 C20 120.4(2) . . ?
C12 C11 C10 121.84(18) . . ?
C12 C11 H11A 119.1 . . ?
C10 C11 H11A 119.1 . . ?
C11 C12 C7 119.33(18) . . ?
C11 C12 C21 119.79(18) . . ?
C7 C12 C21 120.86(17) . . ?
C18 C13 C14 119.82(17) . . ?
C18 C13 C6 120.07(17) . . ?
C14 C13 C6 120.05(17) . . ?
C15 C14 C13 118.88(19) . . ?
C15 C14 C22 120.49(19) . . ?
C13 C14 C22 120.63(18) . . ?
C16 C15 C14 122.0(2) . . ?
C16 C15 H15A 119.0 . . ?
C14 C15 H15A 119.0 . . ?
C17 C16 C15 118.38(18) . . ?
C17 C16 C23 120.8(2) . . ?
C15 C16 C23 120.7(2) . . ?
C16 C17 C18 121.6(2) . . ?
C16 C17 H17A 119.2 . . ?
C18 C17 H17A 119.2 . . ?
C17 C18 C13 119.15(19) . . ?
C17 C18 C24 119.81(19) . . ?
C13 C18 C24 120.97(17) . . ?
C8 C19 H19A 109.5 . . ?
C8 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C8 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C10 C20 H20A 109.5 . . ?
C10 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C10 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C12 C21 H21A 109.5 . . ?
C12 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C12 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C14 C22 H22A 109.5 . . ?
C14 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C14 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C16 C23 H23A 109.5 . . ?
C16 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C16 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C18 C24 H24A 109.5 . . ?
C18 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C18 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
N2 C25 C26 120.78(16) . . ?
N2 C25 C30 120.54(16) . . ?
C26 C25 C30 118.67(15) . . ?
C27 C26 C25 119.69(16) . . ?
C27 C26 C31 121.15(16) . . ?
C25 C26 C31 119.14(15) . . ?
C28 C27 C26 121.40(16) . . ?
C28 C27 H27A 119.3 . . ?
C26 C27 H27A 119.3 . . ?
C27 C28 C29 119.18(16) . . ?
C27 C28 H28A 120.4 . . ?
C29 C28 H28A 120.4 . . ?
C30 C29 C28 121.08(16) . . ?
C30 C29 H29A 119.5 . . ?
C28 C29 H29A 119.5 . . ?
C29 C30 C25 119.95(16) . . ?
C29 C30 C37 121.57(16) . . ?
C25 C30 C37 118.48(15) . . ?
C32 C31 C36 119.51(17) . . ?
C32 C31 C26 119.01(17) . . ?
C36 C31 C26 121.38(16) . . ?
C33 C32 C31 119.3(2) . . ?
C33 C32 C43 119.2(2) . . ?
C31 C32 C43 121.44(18) . . ?
C34 C33 C32 122.0(2) . . ?
C34 C33 H33A 119.0 . . ?
C32 C33 H33A 119.0 . . ?
C35 C34 C33 118.19(19) . . ?
C35 C34 C44 121.6(2) . . ?
C33 C34 C44 120.2(2) . . ?
C34 C35 C36 121.9(2) . . ?
C34 C35 H35A 119.0 . . ?
C36 C35 H35A 119.0 . . ?
C31 C36 C35 118.99(19) . . ?
C31 C36 C45 121.33(17) . . ?
C35 C36 C45 119.59(18) . . ?
C42 C37 C38 120.00(18) . . ?
C42 C37 C30 119.72(17) . . ?
C38 C37 C30 120.18(17) . . ?
C39 C38 C37 118.7(2) . . ?
C39 C38 C46 120.19(19) . . ?
C37 C38 C46 121.04(18) . . ?
C40 C39 C38 121.9(2) . . ?
C40 C39 H39A 119.0 . . ?
C38 C39 H39A 119.0 . . ?
C39 C40 C41 118.59(19) . . ?
C39 C40 C47 120.8(2) . . ?
C41 C40 C47 120.6(2) . . ?
C42 C41 C40 121.6(2) . . ?
C42 C41 H41A 119.2 . . ?
C40 C41 H41A 119.2 . . ?
C41 C42 C37 119.1(2) . . ?
C41 C42 C48 120.46(19) . . ?
C37 C42 C48 120.40(18) . . ?
C32 C43 H43A 109.5 . . ?
C32 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C32 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
C34 C44 H44A 109.5 . . ?
C34 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
C34 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
C36 C45 H45A 109.5 . . ?
C36 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C36 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
C38 C46 H46A 109.5 . . ?
C38 C46 H46B 109.5 . . ?
H46A C46 H46B 109.5 . . ?
C38 C46 H46C 109.5 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C40 C47 H47A 109.5 . . ?
C40 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C40 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C42 C48 H48A 109.5 . . ?
C42 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
C42 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge1 N1 1.8869(15) . ?
Ge1 N2 1.8906(15) . ?
Ge1 Ge2 2.8597(4) . ?
Ge2 N1 1.8795(15) . ?
Ge2 N2 1.8860(15) . ?
N1 C1 1.396(2) . ?
N2 C25 1.394(2) . ?
C1 C6 1.417(2) . ?
C1 C2 1.413(2) . ?
C2 C3 1.397(2) . ?
C2 C7 1.495(2) . ?
C3 C4 1.387(3) . ?
C3 H3A 0.9500 . ?
C4 C5 1.386(3) . ?
C4 H4A 0.9500 . ?
C5 C6 1.389(2) . ?
C5 H5A 0.9500 . ?
C6 C13 1.497(2) . ?
C7 C12 1.403(3) . ?
C7 C8 1.408(3) . ?
C8 C9 1.394(3) . ?
C8 C19 1.508(3) . ?
C9 C10 1.394(3) . ?
C9 H9A 0.9500 . ?
C10 C11 1.391(3) . ?
C10 C20 1.511(3) . ?
C11 C12 1.393(3) . ?
C11 H11A 0.9500 . ?
C12 C21 1.515(3) . ?
C13 C18 1.407(3) . ?
C13 C14 1.405(3) . ?
C14 C15 1.396(3) . ?
C14 C22 1.504(3) . ?
C15 C16 1.389(3) . ?
C15 H15A 0.9500 . ?
C16 C17 1.386(3) . ?
C16 C23 1.516(3) . ?
C17 C18 1.398(3) . ?
C17 H17A 0.9500 . ?
C18 C24 1.509(3) . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C20 H20A 0.9800 . ?
C20 H20B 0.9800 . ?
C20 H20C 0.9800 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 C26 1.416(2) . ?
C25 C30 1.418(2) . ?
C26 C27 1.396(2) . ?
C26 C31 1.496(2) . ?
C27 C28 1.388(3) . ?
C27 H27A 0.9500 . ?
C28 C29 1.390(3) . ?
C28 H28A 0.9500 . ?
C29 C30 1.395(2) . ?
C29 H29A 0.9500 . ?
C30 C37 1.496(2) . ?
C31 C32 1.401(3) . ?
C31 C36 1.404(3) . ?
C32 C33 1.394(3) . ?
C32 C43 1.514(3) . ?
C33 C34 1.381(4) . ?
C33 H33A 0.9500 . ?
C34 C35 1.382(3) . ?
C34 C44 1.515(3) . ?
C35 C36 1.400(3) . ?
C35 H35A 0.9500 . ?
C36 C45 1.506(3) . ?
C37 C42 1.404(3) . ?
C37 C38 1.408(3) . ?
C38 C39 1.397(3) . ?
C38 C46 1.504(3) . ?
C39 C40 1.383(3) . ?
C39 H39A 0.9500 . ?
C40 C41 1.389(4) . ?
C40 C47 1.514(3) . ?
C41 C42 1.394(3) . ?
C41 H41A 0.9500 . ?
C42 C48 1.503(3) . ?
C43 H43A 0.9800 . ?
C43 H43B 0.9800 . ?
C43 H43C 0.9800 . ?
C44 H44A 0.9800 . ?
C44 H44B 0.9800 . ?
C44 H44C 0.9800 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C46 H46A 0.9800 . ?
C46 H46B 0.9800 . ?
C46 H46C 0.9800 . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
