#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:26:45 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179246 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/66/4316685.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4316685
loop_
_publ_author_name
'D. B. Ambili Raj'
'Biju Francis'
'M. L. P. Reddy'
'Rachel R. Butorac'
'Vincent M. Lynch'
'Alan H. Cowley'
_publ_section_title
;
 Highly Luminescent Poly(Methyl Methacrylate)-Incorporated Europium
 Complex Supported by a Carbazole-Based Fluorinated β-Diketonate Ligand
 and a 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene Oxide Co-Ligand
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9055
_journal_page_last               9063
_journal_paper_doi               10.1021/ic1015324
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety
'3 C17 H9 N O2 F5, C39 H32 O3 P2, Eu, 2 C6 H16 O4'
_chemical_formula_sum            'C96 H75 Eu F15 N3 O13 P2'
_chemical_formula_weight         1977.49
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.751(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.4888(11)
_cell_length_b                   33.356(3)
_cell_length_c                   22.684(2)
_cell_measurement_reflns_used    53571
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      50.0
_cell_measurement_theta_min      2.0
_cell_volume                     8632.7(14)
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2008)'
_computing_molecular_graphics    'XP SHELXTL/PC, Siemens Analytical'
_computing_structure_refinement  'XL SHELXTL/PC, Siemens Analytical'
_computing_structure_solution
;

SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C., 
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Rigaku AFC-12 with Saturn 724+ CCD'
_diffrn_measurement_method       ω-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.1159
_diffrn_reflns_av_sigmaI/netI    0.1732
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       39
_diffrn_reflns_limit_k_min       -39
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            51107
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.01
_exptl_absorpt_coefficient_mu    0.863
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.373
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Abscor. T. Higashi. (2001). Rigaku Corp. Tokyo, Japan
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.522
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4016
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.287
_refine_diff_density_min         -1.015
_refine_diff_density_rms         0.118
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1134
_refine_ls_number_reflns         14791
_refine_ls_number_restraints     339
_refine_ls_restrained_S_all      2.040
_refine_ls_R_factor_all          0.1609
_refine_ls_R_factor_gt           0.0823
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0674P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1580
_refine_ls_wR_factor_ref         0.1810
_reflns_number_gt                7745
_reflns_number_total             14791
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic1015324_si_002.cif
_cod_data_source_block           shelxl
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        8632.6(14)
_cod_database_code               4316685
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.10387(8) 0.20207(2) 0.37829(3) 0.0310(3) Uani 1 1 d . A .
P1 P 0.0715(4) 0.29136(11) 0.27404(17) 0.0318(11) Uani 1 1 d . . .
P2 P 0.1353(5) 0.29169(13) 0.48419(19) 0.0463(14) Uani 1 1 d . . .
O1 O 0.0002(10) 0.3368(3) 0.3791(4) 0.036(3) Uani 1 1 d . . .
O2 O 0.0758(9) 0.2548(3) 0.3128(4) 0.033(3) Uani 1 1 d . . .
O3 O 0.1161(11) 0.2617(3) 0.4356(4) 0.051(3) Uani 1 1 d . . .
C1 C -0.0769(14) 0.3426(4) 0.3287(7) 0.032(4) Uani 1 1 d . . .
C2 C -0.0580(14) 0.3214(4) 0.2776(7) 0.034(4) Uani 1 1 d . . .
C3 C -0.1410(15) 0.3248(4) 0.2278(7) 0.036(4) Uani 1 1 d . . .
H3 H -0.1300 0.3107 0.1925 0.043 Uiso 1 1 calc R . .
C4 C -0.2389(16) 0.3485(5) 0.2292(8) 0.045(5) Uani 1 1 d . . .
H4 H -0.2973 0.3493 0.1959 0.054 Uiso 1 1 calc R . .
C5 C -0.2521(16) 0.3710(5) 0.2789(8) 0.044(5) Uani 1 1 d . . .
H5 H -0.3178 0.3883 0.2789 0.053 Uiso 1 1 calc R . .
C6 C -0.1716(15) 0.3688(5) 0.3286(7) 0.035(4) Uani 1 1 d . . .
C7 C -0.1758(16) 0.3977(5) 0.3803(8) 0.047(5) Uani 1 1 d . . .
C8 C -0.1244(18) 0.3766(5) 0.4357(8) 0.051(5) Uani 1 1 d . . .
C9 C -0.153(2) 0.3863(6) 0.4902(9) 0.080(7) Uani 1 1 d . . .
H9 H -0.2132 0.4054 0.4928 0.096 Uiso 1 1 calc R . .
C10 C -0.099(3) 0.3700(8) 0.5419(10) 0.112(11) Uani 1 1 d . . .
H10 H -0.1205 0.3784 0.5793 0.135 Uiso 1 1 calc R . .
C11 C -0.013(2) 0.3411(6) 0.5386(8) 0.090(9) Uani 1 1 d . . .
H11 H 0.0227 0.3289 0.5740 0.108 Uiso 1 1 calc R . .
C12 C 0.0215(17) 0.3295(5) 0.4837(7) 0.050(5) Uani 1 1 d . . .
C13 C -0.0357(16) 0.3477(5) 0.4335(7) 0.039(4) Uani 1 1 d . . .
C14 C -0.2994(18) 0.4130(6) 0.3856(9) 0.078(7) Uani 1 1 d . . .
H14A H -0.3514 0.3902 0.3902 0.117 Uiso 1 1 calc R . .
H14B H -0.3284 0.4280 0.3498 0.117 Uiso 1 1 calc R . .
H14C H -0.2979 0.4305 0.4204 0.117 Uiso 1 1 calc R . .
C15 C -0.0944(19) 0.4344(5) 0.3693(8) 0.066(6) Uani 1 1 d . . .
H15A H -0.0903 0.4527 0.4033 0.099 Uiso 1 1 calc R . .
H15B H -0.1267 0.4486 0.3333 0.099 Uiso 1 1 calc R . .
H15C H -0.0155 0.4246 0.3646 0.099 Uiso 1 1 calc R . .
C16 C 0.1950(15) 0.3238(4) 0.2905(6) 0.031(4) Uani 1 1 d . . .
C17 C 0.1905(16) 0.3647(5) 0.2933(7) 0.044(5) Uani 1 1 d . . .
H17 H 0.1156 0.3771 0.2908 0.053 Uiso 1 1 calc R . .
C18 C 0.2889(18) 0.3892(5) 0.2997(8) 0.057(5) Uani 1 1 d . . .
H18 H 0.2810 0.4176 0.3001 0.068 Uiso 1 1 calc R . .
C19 C 0.3978(19) 0.3716(6) 0.3053(8) 0.060(6) Uani 1 1 d . . .
H19 H 0.4667 0.3876 0.3113 0.072 Uiso 1 1 calc R . .
C20 C 0.4054(17) 0.3306(6) 0.3022(8) 0.060(6) Uani 1 1 d . . .
H20 H 0.4805 0.3184 0.3045 0.072 Uiso 1 1 calc R . .
C21 C 0.3073(18) 0.3068(5) 0.2959(8) 0.053(5) Uani 1 1 d . . .
H21 H 0.3157 0.2784 0.2952 0.063 Uiso 1 1 calc R . .
C22 C 0.0770(13) 0.2764(4) 0.1980(6) 0.030(4) Uani 1 1 d . . .
C23 C 0.1026(13) 0.3035(5) 0.1544(7) 0.036(4) Uani 1 1 d . . .
H23 H 0.1152 0.3309 0.1644 0.043 Uiso 1 1 calc R . .
C24 C 0.1098(14) 0.2910(5) 0.0973(7) 0.037(4) Uani 1 1 d . . .
H24 H 0.1261 0.3097 0.0677 0.045 Uiso 1 1 calc R . .
C25 C 0.0928(16) 0.2506(5) 0.0831(7) 0.049(5) Uani 1 1 d . . .
H25 H 0.0996 0.2414 0.0441 0.059 Uiso 1 1 calc R . .
C26 C 0.0663(19) 0.2245(5) 0.1256(8) 0.065(6) Uani 1 1 d . . .
H26 H 0.0541 0.1971 0.1155 0.078 Uiso 1 1 calc R . .
C27 C 0.0566(16) 0.2367(5) 0.1831(7) 0.047(5) Uani 1 1 d . . .
H27 H 0.0363 0.2181 0.2119 0.056 Uiso 1 1 calc R . .
C28 C 0.1370(18) 0.2690(5) 0.5571(8) 0.046(5) Uani 1 1 d . . .
C29 C 0.2275(18) 0.2734(5) 0.6024(8) 0.057(6) Uani 1 1 d . . .
H29 H 0.2960 0.2877 0.5955 0.069 Uiso 1 1 calc R . .
C30 C 0.219(2) 0.2572(7) 0.6572(9) 0.073(7) Uani 1 1 d . . .
H30 H 0.2831 0.2597 0.6877 0.087 Uiso 1 1 calc R . .
C31 C 0.119(3) 0.2374(6) 0.6683(9) 0.082(8) Uani 1 1 d . . .
H31 H 0.1123 0.2275 0.7070 0.099 Uiso 1 1 calc R . .
C32 C 0.030(2) 0.2318(6) 0.6234(9) 0.071(7) Uani 1 1 d . . .
H32 H -0.0376 0.2170 0.6302 0.086 Uiso 1 1 calc R . .
C33 C 0.040(2) 0.2478(6) 0.5686(8) 0.069(7) Uani 1 1 d . . .
H33 H -0.0221 0.2441 0.5377 0.082 Uiso 1 1 calc R . .
C34 C 0.2719(19) 0.3176(5) 0.4844(8) 0.053(5) Uani 1 1 d . . .
C35 C 0.289(2) 0.3533(7) 0.5158(12) 0.107(9) Uani 1 1 d . . .
H35 H 0.2265 0.3646 0.5341 0.129 Uiso 1 1 calc R . .
C36 C 0.397(3) 0.3726(7) 0.5206(13) 0.112(10) Uani 1 1 d . . .
H36 H 0.4095 0.3967 0.5426 0.134 Uiso 1 1 calc R . .
C37 C 0.489(2) 0.3553(8) 0.4916(11) 0.091(8) Uani 1 1 d . . .
H37 H 0.5634 0.3678 0.4936 0.109 Uiso 1 1 calc R . .
C38 C 0.467(2) 0.3208(7) 0.4613(9) 0.081(7) Uani 1 1 d . . .
H38 H 0.5270 0.3098 0.4404 0.097 Uiso 1 1 calc R . .
C39 C 0.360(2) 0.3007(6) 0.4595(8) 0.062(6) Uani 1 1 d . . .
H39 H 0.3501 0.2753 0.4408 0.075 Uiso 1 1 calc R . .
F12 F -0.3664(8) 0.2159(3) 0.4437(4) 0.054(3) Uani 1 1 d D . .
C89 C -0.2990(13) 0.2140(4) 0.3976(6) 0.036(7) Uani 0.59 1 d PDU A 1
F11 F -0.3421(14) 0.1863(4) 0.3580(6) 0.049(5) Uani 0.59 1 d PDU A 1
C90 C -0.3078(16) 0.2556(4) 0.3679(7) 0.053(8) Uani 0.59 1 d PDU A 1
F13 F -0.4238(17) 0.2649(7) 0.3568(13) 0.070(9) Uani 0.59 1 d PDU A 1
F14 F -0.2550(17) 0.2828(4) 0.4060(8) 0.061(7) Uani 0.59 1 d PDU A 1
F15 F -0.261(3) 0.2549(8) 0.3165(8) 0.065(9) Uani 0.59 1 d PDU A 1
C89A C -0.2807(14) 0.2326(5) 0.4153(8) 0.036(7) Uani 0.41 1 d PDU A 2
F11A F -0.258(2) 0.2702(4) 0.4330(12) 0.055(9) Uani 0.41 1 d PDU A 2
C90A C -0.339(2) 0.2368(7) 0.3514(11) 0.053(8) Uani 0.41 1 d PDU A 2
F13A F -0.345(2) 0.2001(7) 0.3260(9) 0.064(9) Uani 0.41 1 d PDU A 2
F14A F -0.276(4) 0.2620(11) 0.3205(11) 0.058(11) Uani 0.41 1 d PDU A 2
F15A F -0.448(2) 0.2517(10) 0.3521(17) 0.062(11) Uani 0.41 1 d PDU A 2
O8 O 0.0498(10) 0.1726(3) 0.4676(4) 0.041(3) Uani 1 1 d . . .
O9 O -0.0958(10) 0.2144(4) 0.3862(5) 0.050(3) Uani 1 1 d . A .
N3 N 0.1774(11) 0.0611(3) 0.6165(5) 0.032(3) Uani 1 1 d . . .
H3N H 0.2387 0.0571 0.5973 0.039 Uiso 1 1 calc R . .
C74 C 0.1553(15) 0.0412(4) 0.6679(7) 0.034(4) Uani 1 1 d . . .
C75 C 0.2229(15) 0.0111(4) 0.6987(7) 0.037(4) Uani 1 1 d . . .
H75 H 0.2942 0.0017 0.6862 0.044 Uiso 1 1 calc R . .
C76 C 0.1797(16) -0.0040(5) 0.7479(7) 0.039(4) Uani 1 1 d . . .
H76 H 0.2228 -0.0242 0.7703 0.047 Uiso 1 1 calc R . .
C77 C 0.0740(16) 0.0095(4) 0.7664(7) 0.041(5) Uani 1 1 d . . .
H77 H 0.0470 -0.0021 0.8005 0.049 Uiso 1 1 calc R . .
C78 C 0.0078(15) 0.0396(4) 0.7354(7) 0.037(4) Uani 1 1 d . . .
H78 H -0.0636 0.0487 0.7481 0.045 Uiso 1 1 calc R . .
C79 C 0.0497(14) 0.0558(4) 0.6858(7) 0.030(4) Uani 1 1 d . . .
C80 C 0.0078(14) 0.0858(4) 0.6429(6) 0.026(4) Uani 1 1 d . . .
C81 C -0.0931(14) 0.1108(4) 0.6358(6) 0.034(4) Uani 1 1 d . . .
H81 H -0.1494 0.1102 0.6633 0.041 Uiso 1 1 calc R . .
C82 C -0.1058(14) 0.1364(4) 0.5866(6) 0.032(4) Uani 1 1 d . . .
H82 H -0.1718 0.1538 0.5815 0.038 Uiso 1 1 calc R . .
C83 C -0.0268(15) 0.1376(4) 0.5448(7) 0.033(4) Uani 1 1 d . . .
C84 C 0.0721(14) 0.1134(4) 0.5513(7) 0.032(4) Uani 1 1 d . . .
H84 H 0.1271 0.1142 0.5232 0.038 Uiso 1 1 calc R . .
C85 C 0.0883(13) 0.0880(4) 0.6005(7) 0.028(4) Uani 1 1 d . . .
C86 C -0.0407(17) 0.1647(5) 0.4925(7) 0.035(4) Uani 1 1 d . . .
C87 C -0.1512(15) 0.1812(5) 0.4720(7) 0.037(4) Uani 1 1 d . A .
H87 H -0.2151 0.1753 0.4937 0.044 Uiso 1 1 calc R . .
C88 C -0.1727(11) 0.2057(4) 0.4215(6) 0.037(4) Uani 1 1 d D . .
F6 F -0.0637(9) 0.1506(3) 0.1801(4) 0.048(3) Uani 1 1 d . . .
F7 F -0.0838(8) 0.0873(3) 0.1988(4) 0.044(3) Uani 1 1 d . . .
F8 F -0.2861(9) 0.1259(3) 0.1714(4) 0.069(3) Uani 1 1 d . . .
F9 F -0.2635(9) 0.1038(3) 0.2614(4) 0.067(3) Uani 1 1 d . . .
F10 F -0.2468(10) 0.1669(3) 0.2438(5) 0.075(4) Uani 1 1 d . . .
O6 O 0.1511(9) 0.1320(3) 0.3836(5) 0.036(3) Uani 1 1 d . . .
O7 O 0.0022(10) 0.1669(3) 0.2947(4) 0.039(3) Uani 1 1 d . . .
N2 N 0.3659(11) 0.0254(3) 0.5183(5) 0.034(3) Uani 1 1 d . . .
H2N H 0.4273 0.0413 0.5241 0.041 Uiso 1 1 calc R . .
C57 C 0.3506(14) -0.0099(4) 0.5492(6) 0.029(4) Uani 1 1 d . . .
C58 C 0.4247(15) -0.0280(4) 0.5954(6) 0.036(4) Uani 1 1 d . . .
H58 H 0.4988 -0.0169 0.6095 0.044 Uiso 1 1 calc R . .
C59 C 0.3848(15) -0.0627(4) 0.6190(7) 0.035(4) Uani 1 1 d . . .
H59 H 0.4323 -0.0754 0.6508 0.042 Uiso 1 1 calc R . .
C60 C 0.2783(15) -0.0799(4) 0.5985(7) 0.035(4) Uani 1 1 d . . .
H60 H 0.2558 -0.1043 0.6155 0.042 Uiso 1 1 calc R . .
C61 C 0.2038(13) -0.0622(4) 0.5534(6) 0.026(4) Uani 1 1 d . . .
H61 H 0.1303 -0.0740 0.5396 0.031 Uiso 1 1 calc R . .
C62 C 0.2402(14) -0.0268(4) 0.5291(6) 0.027(4) Uani 1 1 d . . .
C63 C 0.1871(13) -0.0004(4) 0.4823(6) 0.027(4) Uani 1 1 d . . .
C64 C 0.0836(14) -0.0002(4) 0.4445(6) 0.029(4) Uani 1 1 d . . .
H64 H 0.0290 -0.0214 0.4464 0.035 Uiso 1 1 calc R . .
C65 C 0.0588(13) 0.0302(4) 0.4043(6) 0.026(4) Uani 1 1 d . . .
H65 H -0.0124 0.0295 0.3784 0.031 Uiso 1 1 calc R . .
C66 C 0.1372(14) 0.0624(4) 0.4009(7) 0.029(4) Uani 1 1 d . . .
C67 C 0.2425(15) 0.0633(4) 0.4374(7) 0.035(4) Uani 1 1 d . . .
H67 H 0.2961 0.0848 0.4357 0.042 Uiso 1 1 calc R . .
C68 C 0.2672(13) 0.0314(4) 0.4766(6) 0.026(4) Uani 1 1 d . . .
C69 C 0.1041(14) 0.0998(4) 0.3653(7) 0.032(4) Uani 1 1 d . . .
C70 C 0.0243(14) 0.0963(4) 0.3125(7) 0.034(4) Uani 1 1 d . . .
H70 H -0.0003 0.0705 0.2984 0.040 Uiso 1 1 calc R . .
C71 C -0.0180(14) 0.1303(5) 0.2815(7) 0.032(4) Uani 1 1 d . . .
C72 C -0.0948(16) 0.1248(5) 0.2211(7) 0.040(5) Uani 1 1 d . . .
C73 C -0.2252(18) 0.1312(5) 0.2251(8) 0.046(5) Uani 1 1 d . . .
F1 F 0.4952(8) 0.1380(3) 0.2784(4) 0.065(3) Uani 1 1 d D B .
C55 C 0.3928(10) 0.1586(3) 0.2694(5) 0.045(5) Uani 1 1 d D . .
F2 F 0.3105(12) 0.1352(5) 0.2378(8) 0.068(3) Uani 0.55 1 d PDU B 1
C56 C 0.4170(9) 0.1873(3) 0.2256(4) 0.068(3) Uani 0.55 1 d PGDU B 1
F3 F 0.4825(13) 0.2129(4) 0.2524(6) 0.066(6) Uani 0.55 1 d PGDU B 1
F4 F 0.3150(11) 0.2042(5) 0.2035(7) 0.095(7) Uani 0.55 1 d PGDU B 1
F5 F 0.4659(14) 0.1698(5) 0.1833(6) 0.080(6) Uani 0.55 1 d PGDU B 1
F2A F 0.4127(19) 0.1894(5) 0.2318(9) 0.068(3) Uani 0.45 1 d PDU B .
C56A C 0.3249(8) 0.1305(3) 0.2341(3) 0.068(3) Uani 0.45 1 d PGDU B 2
F3A F 0.2209(8) 0.1452(3) 0.2181(3) 0.080(8) Uani 0.45 1 d PGDU B 2
F4A F 0.3763(10) 0.1203(4) 0.1877(3) 0.083(8) Uani 0.45 1 d PGDU B 2
F5A F 0.3174(9) 0.0987(2) 0.2695(3) 0.082(8) Uani 0.45 1 d PGDU B 2
O4 O 0.2852(7) 0.1979(2) 0.4373(3) 0.031(3) Uani 1 1 d G . .
O5 O 0.2582(6) 0.19726(19) 0.3150(3) 0.040(3) Uani 1 1 d G . .
N1 N 0.6331(9) 0.0788(3) 0.5611(4) 0.033(3) Uani 1 1 d G . .
H1N H 0.6868 0.0722 0.5382 0.040 Uiso 1 1 calc R . .
C40 C 0.6197(14) 0.0638(4) 0.6189(6) 0.026(4) Uani 1 1 d . . .
C41 C 0.6922(14) 0.0360(4) 0.6511(7) 0.035(4) Uani 1 1 d . . .
H41 H 0.7607 0.0260 0.6364 0.042 Uiso 1 1 calc R . .
C42 C 0.6605(14) 0.0236(4) 0.7053(7) 0.035(4) Uani 1 1 d . . .
H42 H 0.7072 0.0044 0.7283 0.042 Uiso 1 1 calc R . .
C43 C 0.5599(14) 0.0392(5) 0.7265(7) 0.037(4) Uani 1 1 d . . .
H43 H 0.5390 0.0301 0.7635 0.045 Uiso 1 1 calc R . .
C44 C 0.4911(14) 0.0674(4) 0.6952(7) 0.031(4) Uani 1 1 d . . .
H44 H 0.4241 0.0779 0.7107 0.037 Uiso 1 1 calc R . .
C45 C 0.5205(13) 0.0804(4) 0.6406(6) 0.025(4) Uani 1 1 d . . .
C46 C 0.4725(13) 0.1074(4) 0.5951(6) 0.023(4) Uani 1 1 d . . .
C47 C 0.3735(14) 0.1324(4) 0.5893(6) 0.033(4) Uani 1 1 d . . .
H47 H 0.3250 0.1340 0.6204 0.039 Uiso 1 1 calc R . .
C48 C 0.3466(13) 0.1548(4) 0.5378(6) 0.028(4) Uani 1 1 d . . .
H48 H 0.2807 0.1723 0.5346 0.033 Uiso 1 1 calc R . .
C49 C 0.4149(13) 0.1522(4) 0.4905(6) 0.025(4) Uani 1 1 d . . .
C50 C 0.5145(14) 0.1280(4) 0.4949(6) 0.031(4) Uani 1 1 d . . .
H50 H 0.5615 0.1261 0.4633 0.037 Uiso 1 1 calc R . .
C51 C 0.5432(13) 0.1062(4) 0.5491(6) 0.028(4) Uani 1 1 d . . .
C52 C 0.3667(14) 0.1725(5) 0.4343(7) 0.031(4) Uani 1 1 d . B .
C53 C 0.4043(14) 0.1614(4) 0.3793(6) 0.030(4) Uani 1 1 d . . .
H53 H 0.4703 0.1442 0.3794 0.036 Uiso 1 1 calc R B .
C54 C 0.3484(16) 0.1746(4) 0.3256(7) 0.038(4) Uani 1 1 d D B .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Eu1 O4 117.5(3) . . ?
O2 Eu1 O9 81.5(4) . . ?
O4 Eu1 O9 140.7(3) . . ?
O2 Eu1 O3 73.0(3) . . ?
O4 Eu1 O3 75.3(3) . . ?
O9 Eu1 O3 78.9(4) . . ?
O2 Eu1 O8 145.9(4) . . ?
O4 Eu1 O8 78.1(3) . . ?
O9 Eu1 O8 69.9(4) . . ?
O3 Eu1 O8 83.4(4) . . ?
O2 Eu1 O6 142.3(3) . . ?
O4 Eu1 O6 74.5(3) . . ?
O9 Eu1 O6 112.5(4) . . ?
O3 Eu1 O6 142.3(3) . . ?
O8 Eu1 O6 68.8(4) . . ?
O2 Eu1 O7 81.1(3) . . ?
O4 Eu1 O7 137.4(3) . . ?
O9 Eu1 O7 76.0(4) . . ?
O3 Eu1 O7 146.2(3) . . ?
O8 Eu1 O7 108.4(4) . . ?
O6 Eu1 O7 69.6(3) . . ?
O2 Eu1 O5 74.0(3) . . ?
O4 Eu1 O5 70.75(19) . . ?
O9 Eu1 O5 147.7(3) . . ?
O3 Eu1 O5 112.4(4) . . ?
O8 Eu1 O5 139.1(3) . . ?
O6 Eu1 O5 77.7(3) . . ?
O7 Eu1 O5 79.7(3) . . ?
O2 P1 C16 113.5(6) . . ?
O2 P1 C2 113.3(7) . . ?
C16 P1 C2 107.1(7) . . ?
O2 P1 C22 109.4(6) . . ?
C16 P1 C22 104.5(7) . . ?
C2 P1 C22 108.5(7) . . ?
O3 P2 C34 112.4(9) . . ?
O3 P2 C12 114.8(7) . . ?
C34 P2 C12 107.1(9) . . ?
O3 P2 C28 112.4(7) . . ?
C34 P2 C28 106.4(9) . . ?
C12 P2 C28 103.0(8) . . ?
C1 O1 C13 118.1(13) . . ?
P1 O2 Eu1 172.7(6) . . ?
P2 O3 Eu1 164.9(7) . . ?
O1 C1 C6 121.1(15) . . ?
O1 C1 C2 118.1(14) . . ?
C6 C1 C2 120.8(14) . . ?
C3 C2 C1 118.2(15) . . ?
C3 C2 P1 119.9(13) . . ?
C1 C2 P1 121.8(12) . . ?
C4 C3 C2 120.7(16) . . ?
C4 C3 H3 119.7 . . ?
C2 C3 H3 119.7 . . ?
C3 C4 C5 120.0(16) . . ?
C3 C4 H4 120.0 . . ?
C5 C4 H4 120.0 . . ?
C6 C5 C4 120.9(16) . . ?
C6 C5 H5 119.5 . . ?
C4 C5 H5 119.5 . . ?
C5 C6 C1 119.1(16) . . ?
C5 C6 C7 121.3(15) . . ?
C1 C6 C7 119.2(15) . . ?
C8 C7 C6 107.7(13) . . ?
C8 C7 C14 111.7(16) . . ?
C6 C7 C14 112.7(15) . . ?
C8 C7 C15 108.3(15) . . ?
C6 C7 C15 107.2(14) . . ?
C14 C7 C15 109.2(15) . . ?
C9 C8 C13 116.7(17) . . ?
C9 C8 C7 122.6(17) . . ?
C13 C8 C7 120.5(16) . . ?
C8 C9 C10 124(2) . . ?
C8 C9 H9 118.2 . . ?
C10 C9 H9 118.2 . . ?
C9 C10 C11 118.6(19) . . ?
C9 C10 H10 120.7 . . ?
C11 C10 H10 120.7 . . ?
C10 C11 C12 121.1(18) . . ?
C10 C11 H11 119.4 . . ?
C12 C11 H11 119.4 . . ?
C13 C12 C11 116.8(17) . . ?
C13 C12 P2 125.5(13) . . ?
C11 C12 P2 117.7(14) . . ?
C12 C13 O1 116.9(15) . . ?
C12 C13 C8 123.1(15) . . ?
O1 C13 C8 120.0(14) . . ?
C7 C14 H14A 109.5 . . ?
C7 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C7 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C7 C15 H15A 109.5 . . ?
C7 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C7 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C17 C16 C21 116.1(16) . . ?
C17 C16 P1 125.4(13) . . ?
C21 C16 P1 118.3(12) . . ?
C16 C17 C18 123.9(17) . . ?
C16 C17 H17 118.0 . . ?
C18 C17 H17 118.0 . . ?
C19 C18 C17 118.6(17) . . ?
C19 C18 H18 120.7 . . ?
C17 C18 H18 120.7 . . ?
C20 C19 C18 118.9(19) . . ?
C20 C19 H19 120.6 . . ?
C18 C19 H19 120.6 . . ?
C19 C20 C21 121.8(19) . . ?
C19 C20 H20 119.1 . . ?
C21 C20 H20 119.1 . . ?
C20 C21 C16 120.7(16) . . ?
C20 C21 H21 119.7 . . ?
C16 C21 H21 119.7 . . ?
C27 C22 C23 119.4(14) . . ?
C27 C22 P1 118.5(12) . . ?
C23 C22 P1 122.1(12) . . ?
C24 C23 C22 120.9(15) . . ?
C24 C23 H23 119.6 . . ?
C22 C23 H23 119.6 . . ?
C23 C24 C25 119.2(15) . . ?
C23 C24 H24 120.4 . . ?
C25 C24 H24 120.4 . . ?
C26 C25 C24 119.6(15) . . ?
C26 C25 H25 120.2 . . ?
C24 C25 H25 120.2 . . ?
C25 C26 C27 121.9(16) . . ?
C25 C26 H26 119.0 . . ?
C27 C26 H26 119.0 . . ?
C22 C27 C26 118.9(16) . . ?
C22 C27 H27 120.5 . . ?
C26 C27 H27 120.5 . . ?
C33 C28 C29 118.0(18) . . ?
C33 C28 P2 117.8(15) . . ?
C29 C28 P2 124.1(16) . . ?
C30 C29 C28 121(2) . . ?
C30 C29 H29 119.7 . . ?
C28 C29 H29 119.7 . . ?
C29 C30 C31 120(2) . . ?
C29 C30 H30 119.9 . . ?
C31 C30 H30 119.9 . . ?
C32 C31 C30 120(2) . . ?
C32 C31 H31 120.1 . . ?
C30 C31 H31 120.1 . . ?
C31 C32 C33 119(2) . . ?
C31 C32 H32 120.5 . . ?
C33 C32 H32 120.5 . . ?
C28 C33 C32 122(2) . . ?
C28 C33 H33 119.0 . . ?
C32 C33 H33 119.0 . . ?
C39 C34 C35 120(2) . . ?
C39 C34 P2 120.1(16) . . ?
C35 C34 P2 119.2(18) . . ?
C34 C35 C36 121(3) . . ?
C34 C35 H35 119.7 . . ?
C36 C35 H35 119.7 . . ?
C35 C36 C37 118(2) . . ?
C35 C36 H36 120.8 . . ?
C37 C36 H36 120.8 . . ?
C38 C37 C36 119(2) . . ?
C38 C37 H37 120.6 . . ?
C36 C37 H37 120.6 . . ?
C37 C38 C39 122(2) . . ?
C37 C38 H38 119.0 . . ?
C39 C38 H38 119.0 . . ?
C34 C39 C38 120(2) . . ?
C34 C39 H39 120.2 . . ?
C38 C39 H39 120.2 . . ?
F11 C89 F12 110.1(12) . . ?
F11 C89 C88 111.9(10) . . ?
F12 C89 C88 109.9(10) . . ?
F11 C89 C90 109.1(10) . . ?
F12 C89 C90 106.2(9) . . ?
C88 C89 C90 109.5(13) . . ?
F15 C90 F14 111.9(12) . . ?
F15 C90 F13 109.1(12) . . ?
F14 C90 F13 108.8(12) . . ?
F15 C90 C89 110.6(12) . . ?
F14 C90 C89 108.9(10) . . ?
F13 C90 C89 107.4(11) . . ?
F11A C89A F12 111.5(14) . . ?
F11A C89A C88 113.7(13) . . ?
F12 C89A C88 110.0(12) . . ?
F11A C89A C90A 104.3(18) . . ?
F12 C89A C90A 103.1(14) . . ?
C88 C89A C90A 113.7(14) . . ?
F14A C90A F13A 110.2(14) . . ?
F14A C90A F15A 109.3(13) . . ?
F13A C90A F15A 109.5(14) . . ?
F14A C90A C89A 110.4(13) . . ?
F13A C90A C89A 108.3(12) . . ?
F15A C90A C89A 109.0(13) . . ?
C86 O8 Eu1 140.3(10) . . ?
C88 O9 Eu1 138.5(9) . . ?
C85 N3 C74 109.1(14) . . ?
C85 N3 H3N 125.4 . . ?
C74 N3 H3N 125.4 . . ?
N3 C74 C75 127.8(16) . . ?
N3 C74 C79 109.1(13) . . ?
C75 C74 C79 123.1(15) . . ?
C76 C75 C74 115.8(16) . . ?
C76 C75 H75 122.1 . . ?
C74 C75 H75 122.1 . . ?
C75 C76 C77 122.5(15) . . ?
C75 C76 H76 118.8 . . ?
C77 C76 H76 118.8 . . ?
C78 C77 C76 121.2(16) . . ?
C78 C77 H77 119.4 . . ?
C76 C77 H77 119.4 . . ?
C79 C78 C77 117.8(16) . . ?
C79 C78 H78 121.1 . . ?
C77 C78 H78 121.1 . . ?
C78 C79 C74 119.6(14) . . ?
C78 C79 C80 134.4(16) . . ?
C74 C79 C80 106.0(14) . . ?
C85 C80 C81 118.9(14) . . ?
C85 C80 C79 107.5(14) . . ?
C81 C80 C79 133.5(15) . . ?
C82 C81 C80 117.1(15) . . ?
C82 C81 H81 121.5 . . ?
C80 C81 H81 121.5 . . ?
C83 C82 C81 123.2(15) . . ?
C83 C82 H82 118.4 . . ?
C81 C82 H82 118.4 . . ?
C84 C83 C82 120.3(14) . . ?
C84 C83 C86 116.7(15) . . ?
C82 C83 C86 123.0(15) . . ?
C83 C84 C85 118.0(15) . . ?
C83 C84 H84 121.0 . . ?
C85 C84 H84 121.0 . . ?
N3 C85 C84 129.2(15) . . ?
N3 C85 C80 108.2(13) . . ?
C84 C85 C80 122.5(14) . . ?
O8 C86 C87 121.6(15) . . ?
O8 C86 C83 117.8(15) . . ?
C87 C86 C83 120.6(16) . . ?
C88 C87 C86 124.1(16) . . ?
C88 C87 H87 117.9 . . ?
C86 C87 H87 117.9 . . ?
O9 C88 C87 124.6(13) . . ?
O9 C88 C89 115.7(12) . . ?
C87 C88 C89 117.9(14) . . ?
O9 C88 C89A 114.7(13) . . ?
C87 C88 C89A 118.8(14) . . ?
C69 O6 Eu1 137.1(9) . . ?
C71 O7 Eu1 135.3(9) . . ?
C57 N2 C68 108.8(12) . . ?
C57 N2 H2N 125.6 . . ?
C68 N2 H2N 125.6 . . ?
N2 C57 C58 129.6(15) . . ?
N2 C57 C62 109.6(13) . . ?
C58 C57 C62 120.8(13) . . ?
C59 C58 C57 116.8(15) . . ?
C59 C58 H58 121.6 . . ?
C57 C58 H58 121.6 . . ?
C58 C59 C60 122.7(14) . . ?
C58 C59 H59 118.7 . . ?
C60 C59 H59 118.7 . . ?
C59 C60 C61 121.2(14) . . ?
C59 C60 H60 119.4 . . ?
C61 C60 H60 119.4 . . ?
C60 C61 C62 117.8(14) . . ?
C60 C61 H61 121.1 . . ?
C62 C61 H61 121.1 . . ?
C61 C62 C57 120.7(12) . . ?
C61 C62 C63 133.1(14) . . ?
C57 C62 C63 106.1(13) . . ?
C64 C63 C68 117.3(13) . . ?
C64 C63 C62 135.3(14) . . ?
C68 C63 C62 107.3(13) . . ?
C65 C64 C63 120.9(14) . . ?
C65 C64 H64 119.6 . . ?
C63 C64 H64 119.6 . . ?
C64 C65 C66 121.0(13) . . ?
C64 C65 H65 119.5 . . ?
C66 C65 H65 119.5 . . ?
C67 C66 C65 120.3(13) . . ?
C67 C66 C69 116.6(13) . . ?
C65 C66 C69 122.4(13) . . ?
C66 C67 C68 117.5(14) . . ?
C66 C67 H67 121.2 . . ?
C68 C67 H67 121.2 . . ?
C67 C68 N2 128.9(14) . . ?
C67 C68 C63 122.9(14) . . ?
N2 C68 C63 108.1(12) . . ?
O6 C69 C70 124.1(13) . . ?
O6 C69 C66 117.4(13) . . ?
C70 C69 C66 118.5(13) . . ?
C71 C70 C69 120.7(14) . . ?
C71 C70 H70 119.7 . . ?
C69 C70 H70 119.7 . . ?
O7 C71 C70 128.3(14) . . ?
O7 C71 C72 112.9(13) . . ?
C70 C71 C72 118.7(13) . . ?
F6 C72 F7 106.6(13) . . ?
F6 C72 C73 107.2(13) . . ?
F7 C72 C73 106.5(14) . . ?
F6 C72 C71 111.5(13) . . ?
F7 C72 C71 111.6(13) . . ?
C73 C72 C71 113.1(14) . . ?
F10 C73 F9 109.7(16) . . ?
F10 C73 F8 108.5(14) . . ?
F9 C73 F8 107.2(15) . . ?
F10 C73 C72 111.9(15) . . ?
F9 C73 C72 109.8(14) . . ?
F8 C73 C72 109.7(15) . . ?
F1 C55 F2 109.1(10) . . ?
F1 C55 F2A 105.5(11) . . ?
F2 C55 F2A 104.9(14) . . ?
F1 C55 C56A 99.4(8) . . ?
F2A C55 C56A 105.5(13) . . ?
F1 C55 C56 102.0(8) . . ?
F2 C55 C56 101.4(10) . . ?
C56A C55 C56 101.0(8) . . ?
F1 C55 C54 114.9(11) . . ?
F2 C55 C54 111.1(12) . . ?
F2A C55 C54 110.7(13) . . ?
C56A C55 C54 119.4(9) . . ?
C56 C55 C54 117.2(8) . . ?
F3 C56 F5 112.2 . . ?
F3 C56 F4 110.2 . . ?
F5 C56 F4 110.2 . . ?
F3 C56 C55 105.9(7) . . ?
F5 C56 C55 110.2(7) . . ?
F4 C56 C55 107.9(7) . . ?
C55 F2A F5 104.2(14) . . ?
F3A C56A F4A 111.0 . . ?
F3A C56A F5A 110.1 . . ?
F4A C56A F5A 110.0 . . ?
F3A C56A C55 109.7(5) . . ?
F4A C56A C55 111.0(5) . . ?
F5A C56A C55 104.9(4) . . ?
C52 O4 Eu1 128.3(8) . . ?
C54 O5 Eu1 124.2(8) . . ?
C51 N1 C40 104.7(12) . . ?
C51 N1 H1N 127.6 . . ?
C40 N1 H1N 127.6 . . ?
C41 C40 C45 122.5(14) . . ?
C41 C40 N1 126.3(14) . . ?
C45 C40 N1 111.2(12) . . ?
C42 C41 C40 117.4(15) . . ?
C42 C41 H41 121.3 . . ?
C40 C41 H41 121.3 . . ?
C41 C42 C43 120.4(14) . . ?
C41 C42 H42 119.8 . . ?
C43 C42 H42 119.8 . . ?
C44 C43 C42 121.7(15) . . ?
C44 C43 H43 119.1 . . ?
C42 C43 H43 119.1 . . ?
C43 C44 C45 119.2(15) . . ?
C43 C44 H44 120.4 . . ?
C45 C44 H44 120.4 . . ?
C44 C45 C40 118.7(13) . . ?
C44 C45 C46 136.5(15) . . ?
C40 C45 C46 104.8(13) . . ?
C51 C46 C47 118.9(14) . . ?
C51 C46 C45 108.1(13) . . ?
C47 C46 C45 133.0(14) . . ?
C48 C47 C46 119.8(15) . . ?
C48 C47 H47 120.1 . . ?
C46 C47 H47 120.1 . . ?
C47 C48 C49 121.2(15) . . ?
C47 C48 H48 119.4 . . ?
C49 C48 H48 119.4 . . ?
C50 C49 C48 120.6(14) . . ?
C50 C49 C52 122.9(14) . . ?
C48 C49 C52 116.1(14) . . ?
C49 C50 C51 117.4(14) . . ?
C49 C50 H50 121.3 . . ?
C51 C50 H50 121.3 . . ?
N1 C51 C46 111.1(13) . . ?
N1 C51 C50 126.5(14) . . ?
C46 C51 C50 122.0(14) . . ?
O4 C52 C53 121.8(13) . . ?
O4 C52 C49 117.2(13) . . ?
C53 C52 C49 120.9(14) . . ?
C54 C53 C52 122.3(15) . . ?
C54 C53 H53 118.8 . . ?
C52 C53 H53 118.8 . . ?
O5 C54 C53 129.4(14) . . ?
O5 C54 C55 113.1(12) . . ?
C53 C54 C55 117.3(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O2 2.300(9) . ?
Eu1 O4 2.345(7) . ?
Eu1 O9 2.358(12) . ?
Eu1 O3 2.372(10) . ?
Eu1 O8 2.399(11) . ?
Eu1 O6 2.400(9) . ?
Eu1 O7 2.411(10) . ?
Eu1 O5 2.414(7) . ?
P1 O2 1.501(10) . ?
P1 C16 1.788(16) . ?
P1 C2 1.803(17) . ?
P1 C22 1.804(15) . ?
P2 O3 1.485(11) . ?
P2 C34 1.79(2) . ?
P2 C12 1.815(18) . ?
P2 C28 1.817(18) . ?
O1 C1 1.374(17) . ?
O1 C13 1.394(17) . ?
C1 C6 1.40(2) . ?
C1 C2 1.40(2) . ?
C2 C3 1.39(2) . ?
C3 C4 1.38(2) . ?
C3 H3 0.9500 . ?
C4 C5 1.38(2) . ?
C4 H4 0.9500 . ?
C5 C6 1.37(2) . ?
C5 H5 0.9500 . ?
C6 C7 1.52(2) . ?
C7 C8 1.50(2) . ?
C7 C14 1.53(2) . ?
C7 C15 1.58(2) . ?
C8 C9 1.35(2) . ?
C8 C13 1.41(2) . ?
C9 C10 1.37(3) . ?
C9 H9 0.9500 . ?
C10 C11 1.39(3) . ?
C10 H10 0.9500 . ?
C11 C12 1.41(2) . ?
C11 H11 0.9500 . ?
C12 C13 1.39(2) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C17 1.37(2) . ?
C16 C21 1.40(2) . ?
C17 C18 1.39(2) . ?
C17 H17 0.9500 . ?
C18 C19 1.37(2) . ?
C18 H18 0.9500 . ?
C19 C20 1.37(2) . ?
C19 H19 0.9500 . ?
C20 C21 1.37(2) . ?
C20 H20 0.9500 . ?
C21 H21 0.9500 . ?
C22 C27 1.38(2) . ?
C22 C23 1.40(2) . ?
C23 C24 1.37(2) . ?
C23 H23 0.9500 . ?
C24 C25 1.39(2) . ?
C24 H24 0.9500 . ?
C25 C26 1.36(2) . ?
C25 H25 0.9500 . ?
C26 C27 1.38(2) . ?
C26 H26 0.9500 . ?
C27 H27 0.9500 . ?
C28 C33 1.37(3) . ?
C28 C29 1.38(2) . ?
C29 C30 1.37(3) . ?
C29 H29 0.9500 . ?
C30 C31 1.37(3) . ?
C30 H30 0.9500 . ?
C31 C32 1.37(3) . ?
C31 H31 0.9500 . ?
C32 C33 1.37(3) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C34 C39 1.34(3) . ?
C34 C35 1.39(3) . ?
C35 C36 1.39(3) . ?
C35 H35 0.9500 . ?
C36 C37 1.43(3) . ?
C36 H36 0.9500 . ?
C37 C38 1.35(3) . ?
C37 H37 0.9500 . ?
C38 C39 1.40(3) . ?
C38 H38 0.9500 . ?
C39 H39 0.9500 . ?
F12 C89A 1.358(14) . ?
F12 C89 1.372(13) . ?
C89 F11 1.345(13) . ?
C89 C88 1.513(16) . ?
C89 C90 1.540(18) . ?
C90 F15 1.342(13) . ?
C90 F14 1.348(13) . ?
C90 F13 1.363(14) . ?
C89A F11A 1.332(14) . ?
C89A C88 1.525(18) . ?
C89A C90A 1.53(2) . ?
C90A F14A 1.352(14) . ?
C90A F13A 1.354(14) . ?
C90A F15A 1.354(14) . ?
O8 C86 1.268(18) . ?
O9 C88 1.293(16) . ?
N3 C85 1.377(17) . ?
N3 C74 1.388(18) . ?
N3 H3N 0.8800 . ?
C74 C75 1.41(2) . ?
C74 C79 1.41(2) . ?
C75 C76 1.37(2) . ?
C75 H75 0.9500 . ?
C76 C77 1.40(2) . ?
C76 H76 0.9500 . ?
C77 C78 1.40(2) . ?
C77 H77 0.9500 . ?
C78 C79 1.39(2) . ?
C78 H78 0.9500 . ?
C79 C80 1.439(19) . ?
C80 C85 1.41(2) . ?
C80 C81 1.42(2) . ?
C81 C82 1.400(19) . ?
C81 H81 0.9500 . ?
C82 C83 1.39(2) . ?
C82 H82 0.9500 . ?
C83 C84 1.39(2) . ?
C83 C86 1.48(2) . ?
C84 C85 1.40(2) . ?
C84 H84 0.9500 . ?
C86 C87 1.41(2) . ?
C87 C88 1.41(2) . ?
C87 H87 0.9500 . ?
F6 C72 1.345(17) . ?
F7 C72 1.361(17) . ?
F8 C73 1.342(18) . ?
F9 C73 1.337(19) . ?
F10 C73 1.298(19) . ?
O6 C69 1.249(17) . ?
O7 C71 1.273(16) . ?
N2 C57 1.391(17) . ?
N2 C68 1.404(17) . ?
N2 H2N 0.8800 . ?
C57 C58 1.406(19) . ?
C57 C62 1.41(2) . ?
C58 C59 1.38(2) . ?
C58 H58 0.9500 . ?
C59 C60 1.38(2) . ?
C59 H59 0.9500 . ?
C60 C61 1.386(19) . ?
C60 H60 0.9500 . ?
C61 C62 1.390(19) . ?
C61 H61 0.9500 . ?
C62 C63 1.457(19) . ?
C63 C64 1.382(19) . ?
C63 C68 1.42(2) . ?
C64 C65 1.369(19) . ?
C64 H64 0.9500 . ?
C65 C66 1.409(19) . ?
C65 H65 0.9500 . ?
C66 C67 1.38(2) . ?
C66 C69 1.51(2) . ?
C67 C68 1.39(2) . ?
C67 H67 0.9500 . ?
C69 C70 1.42(2) . ?
C70 C71 1.39(2) . ?
C70 H70 0.9500 . ?
C71 C72 1.55(2) . ?
C72 C73 1.53(2) . ?
F1 C55 1.355(11) . ?
C55 F2 1.363(12) . ?
C55 F2A 1.373(14) . ?
C55 C56A 1.407(10) . ?
C55 C56 1.432(10) . ?
C55 C54 1.525(19) . ?
C56 F3 1.2463 . ?
C56 F5 1.3053 . ?
C56 F4 1.3437 . ?
F3 F2A 1.18(3) . ?
F4 F2A 1.32(2) . ?
F5 F2A 1.47(3) . ?
C56A F3A 1.3025 . ?
C56A F4A 1.3100 . ?
C56A F5A 1.3382 . ?
O4 C52 1.269(17) . ?
O5 C54 1.282(19) . ?
N1 C51 1.381(16) . ?
N1 C40 1.429(16) . ?
N1 H1N 0.8800 . ?
C40 C41 1.39(2) . ?
C40 C45 1.41(2) . ?
C41 C42 1.39(2) . ?
C41 H41 0.9500 . ?
C42 C43 1.40(2) . ?
C42 H42 0.9500 . ?
C43 C44 1.37(2) . ?
C43 H43 0.9500 . ?
C44 C45 1.39(2) . ?
C44 H44 0.9500 . ?
C45 C46 1.431(19) . ?
C46 C51 1.40(2) . ?
C46 C47 1.40(2) . ?
C47 C48 1.390(19) . ?
C47 H47 0.9500 . ?
C48 C49 1.40(2) . ?
C48 H48 0.9500 . ?
C49 C50 1.39(2) . ?
C49 C52 1.492(19) . ?
C50 C51 1.434(19) . ?
C50 H50 0.9500 . ?
C52 C53 1.42(2) . ?
C53 C54 1.38(2) . ?
C53 H53 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C34 P2 O3 Eu1 98(3) . . . . ?
C12 P2 O3 Eu1 -139(3) . . . . ?
C28 P2 O3 Eu1 -22(3) . . . . ?
O2 Eu1 O3 P2 -169(3) . . . . ?
O4 Eu1 O3 P2 -44(3) . . . . ?
O9 Eu1 O3 P2 106(3) . . . . ?
O8 Eu1 O3 P2 36(3) . . . . ?
O6 Eu1 O3 P2 -6(4) . . . . ?
O7 Eu1 O3 P2 149(3) . . . . ?
O5 Eu1 O3 P2 -105(3) . . . . ?
C13 O1 C1 C6 19(2) . . . . ?
C13 O1 C1 C2 -160.8(14) . . . . ?
O1 C1 C2 C3 175.1(13) . . . . ?
C6 C1 C2 C3 -5(2) . . . . ?
O1 C1 C2 P1 -7(2) . . . . ?
C6 C1 C2 P1 173.5(12) . . . . ?
O2 P1 C2 C3 -113.4(13) . . . . ?
C16 P1 C2 C3 120.7(13) . . . . ?
C22 P1 C2 C3 8.3(15) . . . . ?
O2 P1 C2 C1 68.6(14) . . . . ?
C16 P1 C2 C1 -57.3(14) . . . . ?
C22 P1 C2 C1 -169.7(12) . . . . ?
C1 C2 C3 C4 0(2) . . . . ?
P1 C2 C3 C4 -178.2(13) . . . . ?
C2 C3 C4 C5 4(2) . . . . ?
C3 C4 C5 C6 -3(3) . . . . ?
C4 C5 C6 C1 -1(2) . . . . ?
C4 C5 C6 C7 171.3(16) . . . . ?
O1 C1 C6 C5 -174.3(14) . . . . ?
C2 C1 C6 C5 5(2) . . . . ?
O1 C1 C6 C7 13(2) . . . . ?
C2 C1 C6 C7 -167.5(15) . . . . ?
C5 C6 C7 C8 151.5(16) . . . . ?
C1 C6 C7 C8 -36(2) . . . . ?
C5 C6 C7 C14 28(2) . . . . ?
C1 C6 C7 C14 -159.2(16) . . . . ?
C5 C6 C7 C15 -92.2(19) . . . . ?
C1 C6 C7 C15 80.6(17) . . . . ?
C6 C7 C8 C9 -154(2) . . . . ?
C14 C7 C8 C9 -30(3) . . . . ?
C15 C7 C8 C9 90(2) . . . . ?
C6 C7 C8 C13 31(2) . . . . ?
C14 C7 C8 C13 155.3(17) . . . . ?
C15 C7 C8 C13 -84(2) . . . . ?
C13 C8 C9 C10 1(4) . . . . ?
C7 C8 C9 C10 -174(2) . . . . ?
C8 C9 C10 C11 -2(4) . . . . ?
C9 C10 C11 C12 2(4) . . . . ?
C10 C11 C12 C13 -1(4) . . . . ?
C10 C11 C12 P2 180(2) . . . . ?
O3 P2 C12 C13 -39.2(19) . . . . ?
C34 P2 C12 C13 86.3(18) . . . . ?
C28 P2 C12 C13 -161.7(17) . . . . ?
O3 P2 C12 C11 140.0(17) . . . . ?
C34 P2 C12 C11 -94.5(19) . . . . ?
C28 P2 C12 C11 17(2) . . . . ?
C11 C12 C13 O1 178.7(18) . . . . ?
P2 C12 C13 O1 -2(2) . . . . ?
C11 C12 C13 C8 0(3) . . . . ?
P2 C12 C13 C8 179.4(15) . . . . ?
C1 O1 C13 C12 157.8(15) . . . . ?
C1 O1 C13 C8 -24(2) . . . . ?
C9 C8 C13 C12 0(3) . . . . ?
C7 C8 C13 C12 174.8(17) . . . . ?
C9 C8 C13 O1 -178.5(18) . . . . ?
C7 C8 C13 O1 -4(3) . . . . ?
O2 P1 C16 C17 -137.5(14) . . . . ?
C2 P1 C16 C17 -11.7(16) . . . . ?
C22 P1 C16 C17 103.4(15) . . . . ?
O2 P1 C16 C21 48.5(15) . . . . ?
C2 P1 C16 C21 174.3(13) . . . . ?
C22 P1 C16 C21 -70.7(14) . . . . ?
C21 C16 C17 C18 2(3) . . . . ?
P1 C16 C17 C18 -172.6(14) . . . . ?
C16 C17 C18 C19 -2(3) . . . . ?
C17 C18 C19 C20 2(3) . . . . ?
C18 C19 C20 C21 -3(3) . . . . ?
C19 C20 C21 C16 2(3) . . . . ?
C17 C16 C21 C20 -2(3) . . . . ?
P1 C16 C21 C20 173.1(14) . . . . ?
O2 P1 C22 C27 14.8(15) . . . . ?
C16 P1 C22 C27 136.7(13) . . . . ?
C2 P1 C22 C27 -109.3(14) . . . . ?
O2 P1 C22 C23 -164.3(12) . . . . ?
C16 P1 C22 C23 -42.4(15) . . . . ?
C2 P1 C22 C23 71.6(14) . . . . ?
C27 C22 C23 C24 -1(2) . . . . ?
P1 C22 C23 C24 178.0(12) . . . . ?
C22 C23 C24 C25 -1(2) . . . . ?
C23 C24 C25 C26 2(3) . . . . ?
C24 C25 C26 C27 -1(3) . . . . ?
C23 C22 C27 C26 2(3) . . . . ?
P1 C22 C27 C26 -176.8(15) . . . . ?
C25 C26 C27 C22 -1(3) . . . . ?
O3 P2 C28 C33 -57.7(17) . . . . ?
C34 P2 C28 C33 178.9(15) . . . . ?
C12 P2 C28 C33 66.3(16) . . . . ?
O3 P2 C28 C29 125.3(15) . . . . ?
C34 P2 C28 C29 1.9(17) . . . . ?
C12 P2 C28 C29 -110.7(16) . . . . ?
C33 C28 C29 C30 -1(3) . . . . ?
P2 C28 C29 C30 176.3(14) . . . . ?
C28 C29 C30 C31 -2(3) . . . . ?
C29 C30 C31 C32 4(3) . . . . ?
C30 C31 C32 C33 -3(3) . . . . ?
C29 C28 C33 C32 1(3) . . . . ?
P2 C28 C33 C32 -175.8(15) . . . . ?
C31 C32 C33 C28 0(3) . . . . ?
O3 P2 C34 C39 -23.8(17) . . . . ?
C12 P2 C34 C39 -150.7(15) . . . . ?
C28 P2 C34 C39 99.6(16) . . . . ?
O3 P2 C34 C35 162.8(17) . . . . ?
C12 P2 C34 C35 35.9(19) . . . . ?
C28 P2 C34 C35 -73.8(19) . . . . ?
C39 C34 C35 C36 2(4) . . . . ?
P2 C34 C35 C36 175(2) . . . . ?
C34 C35 C36 C37 1(4) . . . . ?
C35 C36 C37 C38 -1(4) . . . . ?
C36 C37 C38 C39 -3(4) . . . . ?
C35 C34 C39 C38 -5(3) . . . . ?
P2 C34 C39 C38 -178.4(15) . . . . ?
C37 C38 C39 C34 6(3) . . . . ?
C89A F12 C89 F11 -168(2) . . . . ?
C89A F12 C89 C88 68.2(15) . . . . ?
C89A F12 C89 C90 -50.1(17) . . . . ?
F11 C89 C90 F15 -51.1(17) . . . . ?
F12 C89 C90 F15 -169.7(14) . . . . ?
C88 C89 C90 F15 71.7(15) . . . . ?
F11 C89 C90 F14 -174.5(14) . . . . ?
F12 C89 C90 F14 66.9(15) . . . . ?
C88 C89 C90 F14 -51.7(15) . . . . ?
F11 C89 C90 F13 67.9(15) . . . . ?
F12 C89 C90 F13 -50.8(15) . . . . ?
C88 C89 C90 F13 -169.3(14) . . . . ?
C89 F12 C89A F11A 166(3) . . . . ?
C89 F12 C89A C88 -67.3(14) . . . . ?
C89 F12 C89A C90A 54.3(16) . . . . ?
F11A C89A C90A F14A 48(2) . . . . ?
F12 C89A C90A F14A 164.6(18) . . . . ?
C88 C89A C90A F14A -76(2) . . . . ?
F11A C89A C90A F13A 168.7(18) . . . . ?
F12 C89A C90A F13A -74.6(18) . . . . ?
C88 C89A C90A F13A 44(2) . . . . ?
F11A C89A C90A F15A -72.1(19) . . . . ?
F12 C89A C90A F15A 44.5(19) . . . . ?
C88 C89A C90A F15A 163.5(18) . . . . ?
O2 Eu1 O8 C86 45.7(18) . . . . ?
O4 Eu1 O8 C86 167.8(16) . . . . ?
O9 Eu1 O8 C86 11.0(15) . . . . ?
O3 Eu1 O8 C86 91.6(16) . . . . ?
O6 Eu1 O8 C86 -114.4(16) . . . . ?
O7 Eu1 O8 C86 -55.9(16) . . . . ?
O5 Eu1 O8 C86 -151.5(14) . . . . ?
O2 Eu1 O9 C88 -163.7(15) . . . . ?
O4 Eu1 O9 C88 -40.0(17) . . . . ?
O3 Eu1 O9 C88 -89.5(15) . . . . ?
O8 Eu1 O9 C88 -2.5(14) . . . . ?
O6 Eu1 O9 C88 52.8(15) . . . . ?
O7 Eu1 O9 C88 113.4(15) . . . . ?
O5 Eu1 O9 C88 155.8(12) . . . . ?
C85 N3 C74 C75 179.0(14) . . . . ?
C85 N3 C74 C79 -0.4(16) . . . . ?
N3 C74 C75 C76 -178.9(14) . . . . ?
C79 C74 C75 C76 0(2) . . . . ?
C74 C75 C76 C77 1(2) . . . . ?
C75 C76 C77 C78 -1(2) . . . . ?
C76 C77 C78 C79 0(2) . . . . ?
C77 C78 C79 C74 1(2) . . . . ?
C77 C78 C79 C80 178.8(15) . . . . ?
N3 C74 C79 C78 178.4(13) . . . . ?
C75 C74 C79 C78 -1(2) . . . . ?
N3 C74 C79 C80 -0.2(16) . . . . ?
C75 C74 C79 C80 -179.7(13) . . . . ?
C78 C79 C80 C85 -177.5(16) . . . . ?
C74 C79 C80 C85 0.7(15) . . . . ?
C78 C79 C80 C81 1(3) . . . . ?
C74 C79 C80 C81 179.1(15) . . . . ?
C85 C80 C81 C82 0(2) . . . . ?
C79 C80 C81 C82 -178.5(14) . . . . ?
C80 C81 C82 C83 1(2) . . . . ?
C81 C82 C83 C84 -2(2) . . . . ?
C81 C82 C83 C86 179.8(14) . . . . ?
C82 C83 C84 C85 1(2) . . . . ?
C86 C83 C84 C85 179.2(13) . . . . ?
C74 N3 C85 C84 -178.0(14) . . . . ?
C74 N3 C85 C80 0.9(16) . . . . ?
C83 C84 C85 N3 179.3(14) . . . . ?
C83 C84 C85 C80 1(2) . . . . ?
C81 C80 C85 N3 -179.7(12) . . . . ?
C79 C80 C85 N3 -1.0(16) . . . . ?
C81 C80 C85 C84 -1(2) . . . . ?
C79 C80 C85 C84 178.0(12) . . . . ?
Eu1 O8 C86 C87 -13(2) . . . . ?
Eu1 O8 C86 C83 167.3(10) . . . . ?
C84 C83 C86 O8 -20(2) . . . . ?
C82 C83 C86 O8 159.1(15) . . . . ?
C84 C83 C86 C87 160.9(14) . . . . ?
C82 C83 C86 C87 -20(2) . . . . ?
O8 C86 C87 C88 3(2) . . . . ?
C83 C86 C87 C88 -177.2(14) . . . . ?
Eu1 O9 C88 C87 -2(2) . . . . ?
Eu1 O9 C88 C89 -166.6(10) . . . . ?
Eu1 O9 C88 C89A 161.6(11) . . . . ?
C86 C87 C88 O9 4(2) . . . . ?
C86 C87 C88 C89 167.6(13) . . . . ?
C86 C87 C88 C89A -159.7(14) . . . . ?
F11 C89 C88 O9 76.4(16) . . . . ?
F12 C89 C88 O9 -161.0(12) . . . . ?
C90 C89 C88 O9 -44.7(15) . . . . ?
F11 C89 C88 C87 -89.0(15) . . . . ?
F12 C89 C88 C87 33.6(16) . . . . ?
C90 C89 C88 C87 149.9(13) . . . . ?
F11 C89 C88 C89A 171(2) . . . . ?
F12 C89 C88 C89A -66.0(15) . . . . ?
C90 C89 C88 C89A 50.3(15) . . . . ?
F11A C89A C88 O9 -68(2) . . . . ?
F12 C89A C88 O9 166.3(13) . . . . ?
C90A C89A C88 O9 51.2(16) . . . . ?
F11A C89A C88 C87 97(2) . . . . ?
F12 C89A C88 C87 -28.8(17) . . . . ?
C90A C89A C88 C87 -143.8(15) . . . . ?
F11A C89A C88 C89 -167(3) . . . . ?
F12 C89A C88 C89 67.4(15) . . . . ?
C90A C89A C88 C89 -47.6(16) . . . . ?
O2 Eu1 O6 C69 -67.2(17) . . . . ?
O4 Eu1 O6 C69 177.6(15) . . . . ?
O9 Eu1 O6 C69 38.6(16) . . . . ?
O3 Eu1 O6 C69 139.8(14) . . . . ?
O8 Eu1 O6 C69 94.6(15) . . . . ?
O7 Eu1 O6 C69 -25.8(14) . . . . ?
O5 Eu1 O6 C69 -109.3(15) . . . . ?
O2 Eu1 O7 C71 169.2(15) . . . . ?
O4 Eu1 O7 C71 47.7(17) . . . . ?
O9 Eu1 O7 C71 -107.5(15) . . . . ?
O3 Eu1 O7 C71 -150.8(14) . . . . ?
O8 Eu1 O7 C71 -44.6(15) . . . . ?
O6 Eu1 O7 C71 13.3(14) . . . . ?
O5 Eu1 O7 C71 94.0(15) . . . . ?
C68 N2 C57 C58 -179.3(15) . . . . ?
C68 N2 C57 C62 -1.7(17) . . . . ?
N2 C57 C58 C59 178.0(15) . . . . ?
C62 C57 C58 C59 1(2) . . . . ?
C57 C58 C59 C60 1(2) . . . . ?
C58 C59 C60 C61 -2(2) . . . . ?
C59 C60 C61 C62 1(2) . . . . ?
C60 C61 C62 C57 1(2) . . . . ?
C60 C61 C62 C63 179.7(15) . . . . ?
N2 C57 C62 C61 -179.7(13) . . . . ?
C58 C57 C62 C61 -2(2) . . . . ?
N2 C57 C62 C63 1.4(16) . . . . ?
C58 C57 C62 C63 179.3(13) . . . . ?
C61 C62 C63 C64 0(3) . . . . ?
C57 C62 C63 C64 178.3(17) . . . . ?
C61 C62 C63 C68 -179.3(16) . . . . ?
C57 C62 C63 C68 -0.6(16) . . . . ?
C68 C63 C64 C65 -2(2) . . . . ?
C62 C63 C64 C65 179.5(15) . . . . ?
C63 C64 C65 C66 -1(2) . . . . ?
C64 C65 C66 C67 2(2) . . . . ?
C64 C65 C66 C69 -168.9(14) . . . . ?
C65 C66 C67 C68 0(2) . . . . ?
C69 C66 C67 C68 171.3(13) . . . . ?
C66 C67 C68 N2 -179.1(15) . . . . ?
C66 C67 C68 C63 -3(2) . . . . ?
C57 N2 C68 C67 177.8(15) . . . . ?
C57 N2 C68 C63 1.2(16) . . . . ?
C64 C63 C68 C67 4(2) . . . . ?
C62 C63 C68 C67 -177.2(13) . . . . ?
C64 C63 C68 N2 -179.5(13) . . . . ?
C62 C63 C68 N2 -0.4(16) . . . . ?
Eu1 O6 C69 C70 29(2) . . . . ?
Eu1 O6 C69 C66 -152.6(11) . . . . ?
C67 C66 C69 O6 -22(2) . . . . ?
C65 C66 C69 O6 149.1(15) . . . . ?
C67 C66 C69 C70 156.7(15) . . . . ?
C65 C66 C69 C70 -32(2) . . . . ?
O6 C69 C70 C71 -8(2) . . . . ?
C66 C69 C70 C71 173.5(15) . . . . ?
Eu1 O7 C71 C70 -6(3) . . . . ?
Eu1 O7 C71 C72 177.5(10) . . . . ?
C69 C70 C71 O7 -2(3) . . . . ?
C69 C70 C71 C72 174.1(15) . . . . ?
O7 C71 C72 F6 40.9(19) . . . . ?
C70 C71 C72 F6 -136.2(15) . . . . ?
O7 C71 C72 F7 160.0(14) . . . . ?
C70 C71 C72 F7 -17(2) . . . . ?
O7 C71 C72 C73 -80.0(17) . . . . ?
C70 C71 C72 C73 103.0(17) . . . . ?
F6 C72 C73 F10 -63.6(18) . . . . ?
F7 C72 C73 F10 -177.4(13) . . . . ?
C71 C72 C73 F10 59.7(18) . . . . ?
F6 C72 C73 F9 174.4(13) . . . . ?
F7 C72 C73 F9 60.6(17) . . . . ?
C71 C72 C73 F9 -62.4(18) . . . . ?
F6 C72 C73 F8 56.9(17) . . . . ?
F7 C72 C73 F8 -57.0(17) . . . . ?
C71 C72 C73 F8 -179.9(13) . . . . ?
F1 C55 C56 F3 -74.7(9) . . . . ?
F2 C55 C56 F3 172.8(11) . . . . ?
F2A C55 C56 F3 49(9) . . . . ?
C56A C55 C56 F3 -176.9(8) . . . . ?
C54 C55 C56 F3 51.6(12) . . . . ?
F1 C55 C56 F5 46.9(9) . . . . ?
F2 C55 C56 F5 -65.7(12) . . . . ?
F2A C55 C56 F5 171(9) . . . . ?
C56A C55 C56 F5 -55.3(9) . . . . ?
C54 C55 C56 F5 173.2(11) . . . . ?
F1 C55 C56 F4 167.3(8) . . . . ?
F2 C55 C56 F4 54.8(12) . . . . ?
F2A C55 C56 F4 -69(9) . . . . ?
C56A C55 C56 F4 65.1(9) . . . . ?
C54 C55 C56 F4 -66.4(12) . . . . ?
F5 C56 F3 F2A -172(6) . . . . ?
F4 C56 F3 F2A 65(6) . . . . ?
C55 C56 F3 F2A -52(6) . . . . ?
F3 C56 F4 F2A -55(7) . . . . ?
C55 C56 F4 F2A 61(7) . . . . ?
C56 F3 F2A F4 -105(6) . . . . ?
C56 F3 F2A C55 121(7) . . . . ?
C56 F3 F2A F5 7(5) . . . . ?
C56 F4 F2A F3 115(8) . . . . ?
C56 F4 F2A C55 -110(8) . . . . ?
C56 F4 F2A F5 1(6) . . . . ?
F1 C55 F2A F3 -65(2) . . . . ?
F2 C55 F2A F3 179.8(18) . . . . ?
C56A C55 F2A F3 -169.7(17) . . . . ?
C56 C55 F2A F3 -123(10) . . . . ?
C54 C55 F2A F3 60(2) . . . . ?
F1 C55 F2A F4 159.4(16) . . . . ?
F2 C55 F2A F4 44(2) . . . . ?
C56A C55 F2A F4 55(2) . . . . ?
C56 C55 F2A F4 102(10) . . . . ?
C54 C55 F2A F4 -76(2) . . . . ?
F1 C55 F2A F5 49.5(17) . . . . ?
F2 C55 F2A F5 -65.6(18) . . . . ?
C56A C55 F2A F5 -55.1(16) . . . . ?
C56 C55 F2A F5 -8(8) . . . . ?
C54 C55 F2A F5 174.4(13) . . . . ?
F1 C55 C56A F3A -177.7(6) . . . . ?
F2 C55 C56A F3A 20(5) . . . . ?
F2A C55 C56A F3A -68.6(12) . . . . ?
C56 C55 C56A F3A -73.4(7) . . . . ?
C54 C55 C56A F3A 56.6(11) . . . . ?
F1 C55 C56A F4A -54.6(7) . . . . ?
F2 C55 C56A F4A 143(5) . . . . ?
F2A C55 C56A F4A 54.5(12) . . . . ?
C56 C55 C56A F4A 49.6(7) . . . . ?
C54 C55 C56A F4A 179.7(9) . . . . ?
F1 C55 C56A F5A 64.1(7) . . . . ?
F2 C55 C56A F5A -98(5) . . . . ?
F2A C55 C56A F5A 173.2(11) . . . . ?
C56 C55 C56A F5A 168.4(5) . . . . ?
C54 C55 C56A F5A -61.5(11) . . . . ?
O2 Eu1 O4 C52 -109.8(11) . . . . ?
O9 Eu1 O4 C52 138.3(11) . . . . ?
O3 Eu1 O4 C52 -171.2(12) . . . . ?
O8 Eu1 O4 C52 102.6(11) . . . . ?
O6 Eu1 O4 C52 31.6(11) . . . . ?
O7 Eu1 O4 C52 -1.7(13) . . . . ?
O5 Eu1 O4 C52 -50.5(11) . . . . ?
O2 Eu1 O5 C54 167.2(9) . . . . ?
O4 Eu1 O5 C54 39.7(9) . . . . ?
O9 Eu1 O5 C54 -150.9(9) . . . . ?
O3 Eu1 O5 C54 103.9(9) . . . . ?
O8 Eu1 O5 C54 -2.9(10) . . . . ?
O6 Eu1 O5 C54 -38.0(9) . . . . ?
O7 Eu1 O5 C54 -109.1(9) . . . . ?
C51 N1 C40 C41 -178.1(13) . . . . ?
C51 N1 C40 C45 2.4(15) . . . . ?
C45 C40 C41 C42 3(2) . . . . ?
N1 C40 C41 C42 -176.7(13) . . . . ?
C40 C41 C42 C43 -1(2) . . . . ?
C41 C42 C43 C44 -1(2) . . . . ?
C42 C43 C44 C45 1(2) . . . . ?
C43 C44 C45 C40 1(2) . . . . ?
C43 C44 C45 C46 178.1(15) . . . . ?
C41 C40 C45 C44 -3(2) . . . . ?
N1 C40 C45 C44 176.8(12) . . . . ?
C41 C40 C45 C46 179.1(12) . . . . ?
N1 C40 C45 C46 -1.3(15) . . . . ?
C44 C45 C46 C51 -177.9(16) . . . . ?
C40 C45 C46 C51 -0.3(15) . . . . ?
C44 C45 C46 C47 1(3) . . . . ?
C40 C45 C46 C47 178.7(15) . . . . ?
C51 C46 C47 C48 1(2) . . . . ?
C45 C46 C47 C48 -177.9(14) . . . . ?
C46 C47 C48 C49 2(2) . . . . ?
C47 C48 C49 C50 -2(2) . . . . ?
C47 C48 C49 C52 170.5(12) . . . . ?
C48 C49 C50 C51 0(2) . . . . ?
C52 C49 C50 C51 -172.2(13) . . . . ?
C40 N1 C51 C46 -2.6(15) . . . . ?
C40 N1 C51 C50 -176.3(13) . . . . ?
C47 C46 C51 N1 -177.3(12) . . . . ?
C45 C46 C51 N1 1.9(16) . . . . ?
C47 C46 C51 C50 -3(2) . . . . ?
C45 C46 C51 C50 175.9(12) . . . . ?
C49 C50 C51 N1 175.7(13) . . . . ?
C49 C50 C51 C46 3(2) . . . . ?
Eu1 O4 C52 C53 45.0(19) . . . . ?
Eu1 O4 C52 C49 -129.9(10) . . . . ?
C50 C49 C52 O4 -171.1(13) . . . . ?
C48 C49 C52 O4 16.2(19) . . . . ?
C50 C49 C52 C53 14(2) . . . . ?
C48 C49 C52 C53 -158.8(14) . . . . ?
O4 C52 C53 C54 -6(2) . . . . ?
C49 C52 C53 C54 169.0(13) . . . . ?
Eu1 O5 C54 C53 -28.4(18) . . . . ?
Eu1 O5 C54 C55 147.4(7) . . . . ?
C52 C53 C54 O5 -1(2) . . . . ?
C52 C53 C54 C55 -176.6(12) . . . . ?
F1 C55 C54 O5 173.3(9) . . . . ?
F2 C55 C54 O5 -62.3(14) . . . . ?
F2A C55 C54 O5 53.9(16) . . . . ?
C56A C55 C54 O5 -68.8(12) . . . . ?
C56 C55 C54 O5 53.6(14) . . . . ?
F1 C55 C54 C53 -10.4(15) . . . . ?
F2 C55 C54 C53 114.1(15) . . . . ?
F2A C55 C54 C53 -129.7(15) . . . . ?
C56A C55 C54 C53 107.6(14) . . . . ?
C56 C55 C54 C53 -130.0(12) . . . . ?
