#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:34:58 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179252 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/72/4317243.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4317243
loop_
_publ_author_name
'Brandon Kilduff'
'Dmitry Pogozhev'
'Stéphane A. Baudron'
'Mir Wais Hosseini'
_publ_contact_author
; Prof Mir Wais Hosseini
  Laboratoire de Chimie de Coordination Organique, 
  UMR CNRS 7140, Université de Strasbourg,
  CS 90032
  F-67081 Strasbourg Cedex, France 
;
_publ_contact_author_email       hosseini@unistra.fr
_publ_contact_author_fax         '33 3 68 85 13 23'
_publ_contact_author_phone       '33 3 68 85 13 25'
_publ_section_title
;
 Heterometallic Architectures Based on the Combination of Heteroleptic
 Copper and Cobalt Complexes with Silver Salts
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11231
_journal_page_last               11239
_journal_paper_doi               10.1021/ic1019235
_journal_volume                  49
_journal_year                    2010
_chemical_formula_moiety         'C41 H32 Ag Cu2 F3 N8 O7 S, 2(C2 H3 N) '
_chemical_formula_sum            'C45 H38 Ag Cu2 F3 N10 O7 S'
_chemical_formula_weight         1154.86
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 131.2770(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.2562(12)
_cell_length_b                   20.3813(14)
_cell_length_c                   14.5279(9)
_cell_measurement_reflns_used    5902
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.36
_cell_measurement_theta_min      2.73
_cell_volume                     4730.1(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_av_sigmaI/netI    0.0333
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            21218
_diffrn_reflns_theta_full        27.53
_diffrn_reflns_theta_max         27.53
_diffrn_reflns_theta_min         2.00
_exptl_absorpt_coefficient_mu    1.418
_exptl_absorpt_correction_T_max  0.9587
_exptl_absorpt_correction_T_min  0.9072
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            dark-red
_exptl_crystal_density_diffrn    1.622
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             2328
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.350
_refine_diff_density_min         -0.812
_refine_diff_density_rms         0.134
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     336
_refine_ls_number_reflns         5400
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0799
_refine_ls_R_factor_gt           0.0628
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0912P)²+40.9236P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1715
_refine_ls_wR_factor_ref         0.1868
_reflns_number_gt                4255
_reflns_number_total             5400
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic1019235_si_001_06.cif
_cod_data_source_block           compound7b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        4730.0(5)
_cod_original_sg_symbol_H-M      'C 1 2/c 1 '
_cod_database_code               4317243
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6758(4) 0.5869(3) 0.8549(5) 0.0414(12) Uani 1 1 d . . .
H1 H 0.6543 0.5731 0.8904 0.050 Uiso 1 1 calc R . .
C2 C 0.7030(4) 0.5444(3) 0.8116(6) 0.0464(14) Uani 1 1 d . . .
H2 H 0.7032 0.4988 0.8138 0.056 Uiso 1 1 calc R . .
C3 C 0.7294(3) 0.5830(3) 0.7655(5) 0.0386(12) Uani 1 1 d . . .
H3 H 0.7504 0.5686 0.7295 0.046 Uiso 1 1 calc R . .
C4 C 0.7187(3) 0.6492(2) 0.7831(4) 0.0304(10) Uani 1 1 d . . .
C5 C 0.7398(3) 0.7063(2) 0.7552(4) 0.0284(9) Uani 1 1 d . . .
C6 C 0.7348(3) 0.7703(2) 0.7853(4) 0.0319(10) Uani 1 1 d . . .
C7 C 0.7569(4) 0.8289(3) 0.7617(5) 0.0411(12) Uani 1 1 d . . .
H7 H 0.7797 0.8326 0.7251 0.049 Uiso 1 1 calc R . .
C8 C 0.7384(4) 0.8798(3) 0.8027(6) 0.0486(14) Uani 1 1 d . . .
H8 H 0.7465 0.9244 0.8000 0.058 Uiso 1 1 calc R . .
C9 C 0.7048(4) 0.8506(3) 0.8497(5) 0.0447(13) Uani 1 1 d . . .
H9 H 0.6863 0.8739 0.8829 0.054 Uiso 1 1 calc R . .
C10 C 0.7666(3) 0.6970(2) 0.6840(4) 0.0280(9) Uani 1 1 d . . .
C11 C 0.7136(3) 0.6677(2) 0.5696(5) 0.0342(11) Uani 1 1 d . . .
H11 H 0.6606 0.6537 0.5360 0.041 Uiso 1 1 calc R . .
C12 C 0.7409(3) 0.6595(3) 0.5056(5) 0.0363(11) Uani 1 1 d . . .
H12 H 0.7064 0.6396 0.4290 0.044 Uiso 1 1 calc R . .
C13 C 0.8194(3) 0.6813(2) 0.5569(5) 0.0344(11) Uani 1 1 d . . .
H13 H 0.8365 0.6769 0.5125 0.041 Uiso 1 1 calc R . .
C14 C 0.8452(3) 0.7167(2) 0.7296(4) 0.0310(10) Uani 1 1 d . . .
H14 H 0.8810 0.7365 0.8062 0.037 Uiso 1 1 calc R . .
C15 C 0.5228(5) 0.6245(4) 0.9681(7) 0.074(3) Uani 1 1 d . . .
H15A H 0.5521 0.5856 0.9774 0.112 Uiso 1 1 calc R . .
H15B H 0.4636 0.6177 0.9046 0.112 Uiso 1 1 calc R . .
H15C H 0.5357 0.6338 1.0438 0.112 Uiso 1 1 calc R . .
C16 C 0.5491(4) 0.6809(4) 0.9349(5) 0.0525(17) Uani 1 1 d . . .
C17 C 0.5250(4) 0.7459(4) 0.9350(5) 0.0487(16) Uani 1 1 d . . .
C18 C 0.5502(4) 0.8011(4) 0.9103(5) 0.0500(16) Uani 1 1 d . . .
C19 C 0.5241(5) 0.8684(4) 0.9142(7) 0.075(2) Uani 1 1 d . . .
H19A H 0.5693 0.8891 0.9904 0.112 Uiso 1 1 calc R . .
H19B H 0.4761 0.8654 0.9074 0.112 Uiso 1 1 calc R . .
H19C H 0.5103 0.8939 0.8475 0.112 Uiso 1 1 calc R . .
C20 C 0.4787(4) 0.7549(4) 0.9738(5) 0.0589(19) Uani 1 1 d . . .
N1 N 0.6843(3) 0.6494(2) 0.8389(4) 0.0338(9) Uani 1 1 d . . .
N2 N 0.7027(3) 0.7853(2) 0.8411(4) 0.0347(9) Uani 1 1 d . . .
N3 N 0.8722(3) 0.7086(2) 0.6686(4) 0.0305(8) Uani 1 1 d . . .
N4 N 0.4436(4) 0.7639(4) 1.0082(5) 0.076(2) Uani 1 1 d . . .
O1 O 0.5926(3) 0.6675(2) 0.9066(4) 0.0500(11) Uani 1 1 d . . .
O2 O 0.5963(3) 0.7992(2) 0.8835(4) 0.0494(10) Uani 1 1 d . . .
Cu1 Cu 0.64644(4) 0.72508(3) 0.87089(5) 0.03472(19) Uani 1 1 d . . .
Ag1 Ag 1.0000 0.73320(3) 0.7500 0.03603(18) Uani 1 2 d S . .
C21 C 1.0299(7) 0.9727(5) 0.8426(9) 0.035(2) Uani 0.50 1 d P . .
O3 O 0.9974(8) 0.8509(4) 0.7963(10) 0.073(3) Uani 0.50 1 d P . .
O4 O 0.9187(6) 0.9298(5) 0.6262(9) 0.079(3) Uani 0.50 1 d P . .
O5 O 1.0639(7) 0.9050(6) 0.7334(9) 0.066(3) Uani 0.50 1 d P . .
F1 F 1.0202(4) 1.0309(3) 0.7950(6) 0.0471(16) Uani 0.50 1 d P . .
F2 F 0.9844(7) 0.9729(4) 0.8750(10) 0.083(3) Uani 0.50 1 d P . .
F3 F 1.1101(5) 0.9683(4) 0.9438(7) 0.067(2) Uani 0.50 1 d P . .
S1 S 1.0000 0.90652(10) 0.7500 0.0535(6) Uani 1 2 d S . .
C22 C 0.9415(7) 0.5394(5) 0.6428(10) 0.092(3) Uiso 1 1 d . A -1
C23 C 0.9231(9) 0.5382(7) 0.7150(14) 0.129(4) Uiso 1 1 d . A -1
N5A N 0.9514(10) 0.5419(8) 0.5629(15) 0.088(5) Uiso 0.499(15) 1 d P A 1
N5B N 0.9160(8) 0.5388(6) 0.7873(11) 0.060(4) Uiso 0.501(15) 1 d P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 111.7(4) . . ?
N1 C1 H1 124.1 . . ?
C2 C1 H1 124.1 . . ?
C3 C2 C1 106.7(5) . . ?
C3 C2 H2 126.6 . . ?
C1 C2 H2 126.6 . . ?
C2 C3 C4 106.9(4) . . ?
C2 C3 H3 126.5 . . ?
C4 C3 H3 126.5 . . ?
C5 C4 N1 123.6(4) . . ?
C5 C4 C3 128.1(4) . . ?
N1 C4 C3 108.3(4) . . ?
C4 C5 C6 125.3(4) . . ?
C4 C5 C10 116.1(4) . . ?
C6 C5 C10 118.6(4) . . ?
N2 C6 C5 123.5(4) . . ?
N2 C6 C7 109.0(4) . . ?
C5 C6 C7 127.5(5) . . ?
C8 C7 C6 107.4(5) . . ?
C8 C7 H7 126.3 . . ?
C6 C7 H7 126.3 . . ?
C7 C8 C9 105.8(5) . . ?
C7 C8 H8 127.1 . . ?
C9 C8 H8 127.1 . . ?
N2 C9 C8 112.0(5) . . ?
N2 C9 H9 124.0 . . ?
C8 C9 H9 124.0 . . ?
C11 C10 C14 117.8(4) . . ?
C11 C10 C5 120.5(4) . . ?
C14 C10 C5 121.6(4) . . ?
C10 C11 C12 119.1(5) . . ?
C10 C11 H11 120.5 . . ?
C12 C11 H11 120.5 . . ?
C13 C12 C11 119.3(5) . . ?
C13 C12 H12 120.4 . . ?
C11 C12 H12 120.4 . . ?
N3 C13 C12 122.4(4) . . ?
N3 C13 H13 118.8 . . ?
C12 C13 H13 118.8 . . ?
N3 C14 C10 123.5(4) . . ?
N3 C14 H14 118.3 . . ?
C10 C14 H14 118.3 . . ?
C16 C15 H15A 109.5 . . ?
C16 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C16 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
O1 C16 C17 123.0(6) . . ?
O1 C16 C15 116.6(6) . . ?
C17 C16 C15 120.3(5) . . ?
C18 C17 C16 123.5(5) . . ?
C18 C17 C20 118.7(6) . . ?
C16 C17 C20 117.6(7) . . ?
O2 C18 C17 124.1(6) . . ?
O2 C18 C19 114.7(7) . . ?
C17 C18 C19 121.1(6) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
N4 C20 C17 177.5(9) . . ?
C1 N1 C4 106.4(4) . . ?
C1 N1 Cu1 126.6(3) . . ?
C4 N1 Cu1 126.8(3) . . ?
C9 N2 C6 105.9(4) . . ?
C9 N2 Cu1 126.4(4) . . ?
C6 N2 Cu1 126.7(3) . . ?
C13 N3 C14 117.9(4) . . ?
C13 N3 Ag1 119.9(3) . . ?
C14 N3 Ag1 122.2(3) . . ?
C16 O1 Cu1 130.1(5) . . ?
C18 O2 Cu1 129.7(5) . . ?
O2 Cu1 N1 173.28(19) . . ?
O2 Cu1 O1 89.34(19) . . ?
N1 Cu1 O1 89.67(17) . . ?
O2 Cu1 N2 89.22(19) . . ?
N1 Cu1 N2 91.97(17) . . ?
O1 Cu1 N2 177.59(18) . . ?
N3 Ag1 N3 153.5(2) . 2_756 ?
N3 Ag1 O3 97.2(3) . . ?
N3 Ag1 O3 108.3(3) 2_756 . ?
N3 Ag1 O3 108.3(3) . 2_756 ?
N3 Ag1 O3 97.2(3) 2_756 2_756 ?
O3 Ag1 O3 33.0(4) . 2_756 ?
O4 C21 F1 128.8(11) 2_756 . ?
O4 C21 F2 123.4(11) 2_756 . ?
F1 C21 F2 106.5(9) . . ?
O4 C21 F3 50.6(7) 2_756 . ?
F1 C21 F3 106.5(8) . . ?
F2 C21 F3 108.1(10) . . ?
O4 C21 S1 60.4(7) 2_756 . ?
F1 C21 S1 116.8(7) . . ?
F2 C21 S1 107.7(7) . . ?
F3 C21 S1 111.0(7) . . ?
S1 O3 O3 57.9(4) . 2_756 ?
S1 O3 O5 63.8(6) . 2_756 ?
O3 O3 O5 108.4(9) 2_756 2_756 ?
S1 O3 Ag1 131.4(6) . . ?
O3 O3 Ag1 73.5(2) 2_756 . ?
O5 O3 Ag1 141.1(8) 2_756 . ?
F3 O4 C21 69.5(10) 2_756 2_756 ?
F3 O4 S1 144.9(11) 2_756 . ?
C21 O4 S1 75.4(7) 2_756 . ?
S1 O5 O3 51.8(5) . 2_756 ?
F1 F1 C21 113.2(6) 2_756 . ?
O4 F3 C21 59.9(8) 2_756 . ?
O3 S1 O3 64.1(8) 2_756 . ?
O3 S1 O5 113.4(7) 2_756 2_756 ?
O3 S1 O5 64.4(6) . 2_756 ?
O3 S1 O5 64.4(6) 2_756 . ?
O3 S1 O5 113.4(7) . . ?
O5 S1 O5 177.7(9) 2_756 . ?
O3 S1 O4 117.7(7) 2_756 2_756 ?
O3 S1 O4 93.5(7) . 2_756 ?
O5 S1 O4 104.6(7) 2_756 2_756 ?
O5 S1 O4 76.1(7) . 2_756 ?
O3 S1 O4 93.5(7) 2_756 . ?
O3 S1 O4 117.7(7) . . ?
O5 S1 O4 76.1(7) 2_756 . ?
O5 S1 O4 104.6(7) . . ?
O4 S1 O4 143.9(8) 2_756 . ?
O3 S1 C21 161.8(7) 2_756 . ?
O3 S1 C21 113.0(5) . . ?
O5 S1 C21 78.4(6) 2_756 . ?
O5 S1 C21 103.5(6) . . ?
O4 S1 C21 44.2(5) 2_756 . ?
O4 S1 C21 103.1(6) . . ?
O3 S1 C21 113.0(5) 2_756 2_756 ?
O3 S1 C21 161.8(7) . 2_756 ?
O5 S1 C21 103.5(5) 2_756 2_756 ?
O5 S1 C21 78.4(5) . 2_756 ?
O4 S1 C21 103.1(6) 2_756 2_756 ?
O4 S1 C21 44.2(5) . 2_756 ?
C21 S1 C21 75.4(7) . 2_756 ?
N5A C22 C23 174.1(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.328(7) . ?
C1 C2 1.400(8) . ?
C1 H1 0.9300 . ?
C2 C3 1.370(7) . ?
C2 H2 0.9300 . ?
C3 C4 1.420(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.399(7) . ?
C4 N1 1.403(5) . ?
C5 C6 1.401(7) . ?
C5 C10 1.486(6) . ?
C6 N2 1.394(6) . ?
C6 C7 1.406(7) . ?
C7 C8 1.377(8) . ?
C7 H7 0.9300 . ?
C8 C9 1.404(8) . ?
C8 H8 0.9300 . ?
C9 N2 1.335(7) . ?
C9 H9 0.9300 . ?
C10 C11 1.384(7) . ?
C10 C14 1.389(7) . ?
C11 C12 1.393(6) . ?
C11 H11 0.9300 . ?
C12 C13 1.377(7) . ?
C12 H12 0.9300 . ?
C13 N3 1.342(6) . ?
C13 H13 0.9300 . ?
C14 N3 1.346(6) . ?
C14 H14 0.9300 . ?
C15 C16 1.493(10) . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 O1 1.264(6) . ?
C16 C17 1.422(10) . ?
C17 C18 1.389(10) . ?
C17 C20 1.431(7) . ?
C18 O2 1.273(7) . ?
C18 C19 1.494(10) . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 N4 1.154(8) . ?
N1 Cu1 1.933(4) . ?
N2 Cu1 1.951(5) . ?
N3 Ag1 2.189(4) . ?
O1 Cu1 1.935(4) . ?
O2 Cu1 1.926(4) . ?
Ag1 N3 2.189(4) 2_756 ?
Ag1 O3 2.502(9) . ?
Ag1 O3 2.502(9) 2_756 ?
C21 O4 1.229(15) 2_756 ?
C21 F1 1.320(12) . ?
C21 F2 1.325(13) . ?
C21 F3 1.330(13) . ?
C21 S1 1.704(10) . ?
O3 S1 1.338(9) . ?
O3 O3 1.42(2) 2_756 ?
O3 O5 1.536(16) 2_756 ?
O4 F3 1.096(12) 2_756 ?
O4 C21 1.229(15) 2_756 ?
O4 S1 1.532(10) . ?
O5 S1 1.528(10) . ?
O5 O3 1.536(16) 2_756 ?
F1 F1 0.983(12) 2_756 ?
F3 O4 1.096(12) 2_756 ?
S1 O3 1.338(9) 2_756 ?
S1 O5 1.528(10) 2_756 ?
S1 O4 1.532(10) 2_756 ?
S1 C21 1.704(10) 2_756 ?
C22 N5A 1.308(17) . ?
C22 C23 1.340(16) . ?
