#------------------------------------------------------------------------------
#$Date: 2023-12-08 16:16:31 +0200 (Fri, 08 Dec 2023) $
#$Revision: 288183 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/31/76/4317684.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4317684
loop_
_publ_author_name
'Graeme A. Horley'
'Mary F. Mahon'
'Kieran C. Molloy'
'Monica M. Venter'
'Peter W. Haycock'
'Christopher P. Myers'
_publ_section_title
;
 Structures of Sb(OC6H3Me2-2,6)3 and Sb(OEt)5.NH3: The First Authenticated
 Monomeric Sb(OR)n (n= 3, 5)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1652
_journal_page_last               1657
_journal_paper_doi               10.1021/ic0106726
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C45 H54 Cl15 N9 Sb2'
_chemical_formula_weight         1496.22
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                82.7650(7)
_cell_angle_beta                 77.5570(7)
_cell_angle_gamma                70.7670(7)
_cell_formula_units_Z            2
_cell_length_a                   13.4300(2)
_cell_length_b                   14.4180(2)
_cell_length_c                   17.4180(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      18
_cell_measurement_theta_min      12
_cell_volume                     3104.14(8)
_computing_data_reduction
'Denzo and Scalepack (otwinowski & Minor, 1997)'
_computing_molecular_graphics    'ORTEX (P.McArdle, 1995)'
_computing_publication_material  'SHELXL-97/2 (Sheldrick,1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       KappaCCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0626
_diffrn_reflns_av_sigmaI/netI    0.0775
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            51302
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         3.62
_exptl_absorpt_coefficient_mu    1.555
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.601
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1488
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.588
_refine_diff_density_min         -0.670
_refine_diff_density_rms         0.110
_refine_ls_extinction_coef       0.00098(14)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   0.844
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     644
_refine_ls_number_reflns         14158
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.844
_refine_ls_R_factor_all          0.0842
_refine_ls_R_factor_gt           0.0417
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0775P)²+1.6441P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1035
_refine_ls_wR_factor_ref         0.1281
_reflns_number_gt                9279
_reflns_number_total             14158
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0106726_3.cif
_cod_data_source_block           k00kcm37
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

data name '_atom_site_symetry_multiplicity' was replaced with
'_atom_site_symmetry_multiplicity' as specified in the replacement
file 'data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 9268 2022-04-12 08:56:07Z antanas 
;
_cod_database_code               4317684
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1A Sb 0.685935(19) 0.922590(18) 0.072043(14) 0.02041(9) Uani 1 1 d . . .
Sb1B Sb 0.80978(2) 0.085342(19) 0.420982(15) 0.02326(9) Uani 1 1 d . . .
Cl1A Cl 0.84336(8) 0.86746(8) 0.13924(6) 0.0290(2) Uani 1 1 d . . .
Cl2A Cl 0.59112(8) 1.06022(7) 0.16172(6) 0.0286(2) Uani 1 1 d . . .
Cl3A Cl 0.60060(9) 0.80469(8) 0.16181(6) 0.0344(3) Uani 1 1 d . . .
Cl4A Cl 0.76467(8) 1.05647(7) -0.03051(6) 0.0289(2) Uani 1 1 d . . .
Cl5A Cl 0.80402(8) 0.78052(7) -0.04509(6) 0.0310(2) Uani 1 1 d . . .
Cl6A Cl 0.5000 1.0000 0.0000 0.0309(3) Uani 1 2 d S . .
Cl1B Cl 0.65487(8) 0.14706(8) 0.35171(6) 0.0339(3) Uani 1 1 d . . .
Cl2B Cl 0.90422(8) -0.03934(8) 0.32427(6) 0.0307(2) Uani 1 1 d . . .
Cl3B Cl 0.72284(9) -0.03602(8) 0.50380(6) 0.0351(3) Uani 1 1 d . . .
Cl4B Cl 0.89290(9) 0.21737(9) 0.32380(7) 0.0413(3) Uani 1 1 d . . .
Cl5B Cl 0.67474(9) 0.24309(8) 0.53189(7) 0.0374(3) Uani 1 1 d . . .
Cl6B Cl 1.0000 0.0000 0.5000 0.0365(4) Uani 1 2 d S . .
Cl7 Cl -0.20176(8) 1.42415(8) -0.09221(6) 0.0308(2) Uani 1 1 d . . .
Cl8 Cl 1.31003(10) 0.41728(9) 0.42940(7) 0.0436(3) Uani 1 1 d . . .
Cl9 Cl -0.06792(9) 0.56877(9) 0.30001(7) 0.0410(3) Uani 1 1 d . . .
Cl10 Cl 0.56965(9) 0.37617(8) 0.17168(7) 0.0406(3) Uani 1 1 d . . .
N1A N 0.7635(3) 0.9337(3) -0.1837(2) 0.0366(9) Uani 1 1 d . . .
H1A H 0.7701 0.8980 -0.1391 0.044 Uiso 1 1 calc R . .
N2A N 0.5550(3) 1.2330(3) -0.0064(2) 0.0333(9) Uani 1 1 d . . .
H2A H 0.5968 1.1723 0.0004 0.040 Uiso 1 1 calc R . .
N1B N 0.8775(3) 0.3022(3) 0.5130(2) 0.0478(11) Uani 1 1 d . . .
H1B H 0.8156 0.2908 0.5199 0.057 Uiso 1 1 calc R . .
N2B N 0.6651(5) 0.3993(4) 0.3481(3) 0.0732(16) Uani 1 1 d . . .
H2B H 0.6978 0.3354 0.3476 0.088 Uiso 1 1 calc R . .
N3 N 0.0066(3) 1.4621(3) -0.1005(2) 0.0323(9) Uani 1 1 d . . .
H3 H -0.0489 1.4404 -0.0933 0.039 Uiso 1 1 calc R . .
N4 N 0.1001(3) 0.6667(3) 0.2734(2) 0.0372(9) Uani 1 1 d . . .
H4 H 0.0444 0.6449 0.2843 0.045 Uiso 1 1 calc R . .
N5 N 0.7755(3) 1.2043(3) 0.12799(19) 0.0294(8) Uani 1 1 d . . .
H5 H 0.7108 1.2341 0.1536 0.035 Uiso 1 1 calc R . .
N6 N 0.3752(3) 0.3127(3) 0.2420(2) 0.0387(10) Uani 1 1 d . . .
H6 H 0.4344 0.3268 0.2202 0.046 Uiso 1 1 calc R . .
N7 N 1.3717(4) 0.2358(3) 0.5415(2) 0.0450(11) Uani 1 1 d . . .
H7 H 1.3723 0.2791 0.5011 0.054 Uiso 1 1 calc R . .
C1A C 0.6666(4) 0.9939(4) -0.1930(3) 0.0417(12) Uani 1 1 d . . .
H1A1 H 0.6063 0.9984 -0.1518 0.050 Uiso 1 1 calc R . .
C2A C 0.6551(4) 1.0487(4) -0.2621(3) 0.0440(13) Uani 1 1 d . . .
H2A1 H 0.5865 1.0910 -0.2699 0.053 Uiso 1 1 calc R . .
C3A C 0.7436(4) 1.0421(4) -0.3204(3) 0.0436(13) Uani 1 1 d . . .
H3A H 0.7371 1.0805 -0.3687 0.052 Uiso 1 1 calc R . .
C4A C 0.8415(4) 0.9798(4) -0.3083(3) 0.0434(13) Uani 1 1 d . . .
H4A H 0.9032 0.9743 -0.3484 0.052 Uiso 1 1 calc R . .
C5A C 0.8501(4) 0.9259(4) -0.2391(3) 0.0389(11) Uani 1 1 d . . .
H5A H 0.9179 0.8827 -0.2304 0.047 Uiso 1 1 calc R . .
C6A C 0.4517(4) 1.2551(3) 0.0256(3) 0.0337(10) Uani 1 1 d . . .
H6A H 0.4237 1.2062 0.0552 0.040 Uiso 1 1 calc R . .
C7A C 0.3853(3) 1.3500(3) 0.0152(3) 0.0316(10) Uani 1 1 d . . .
H7A H 0.3112 1.3675 0.0381 0.038 Uiso 1 1 calc R . .
C8A C 0.4276(3) 1.4188(3) -0.0285(3) 0.0325(10) Uani 1 1 d . . .
H8A H 0.3824 1.4842 -0.0365 0.039 Uiso 1 1 calc R . .
C9A C 0.5357(3) 1.3932(3) -0.0609(3) 0.0338(10) Uani 1 1 d . . .
H9A H 0.5655 1.4405 -0.0913 0.041 Uiso 1 1 calc R . .
C10A C 0.5986(3) 1.2992(3) -0.0486(3) 0.0348(11) Uani 1 1 d . . .
H10A H 0.6733 1.2804 -0.0699 0.042 Uiso 1 1 calc R . .
C1B C 0.9569(4) 0.2371(4) 0.5428(3) 0.0455(13) Uani 1 1 d . . .
H1B1 H 0.9468 0.1792 0.5712 0.055 Uiso 1 1 calc R . .
C2B C 1.0522(4) 0.2533(4) 0.5329(3) 0.0474(13) Uani 1 1 d . . .
H2B1 H 1.1098 0.2071 0.5542 0.057 Uiso 1 1 calc R . .
C3B C 1.0652(4) 0.3377(4) 0.4914(3) 0.0481(13) Uani 1 1 d . . .
H3B H 1.1319 0.3500 0.4843 0.058 Uiso 1 1 calc R . .
C4B C 0.9827(5) 0.4034(4) 0.4605(3) 0.0520(14) Uani 1 1 d . . .
H4B H 0.9912 0.4613 0.4310 0.062 Uiso 1 1 calc R . .
C5B C 0.8878(5) 0.3840(4) 0.4732(3) 0.0525(15) Uani 1 1 d . . .
H5B H 0.8285 0.4295 0.4533 0.063 Uiso 1 1 calc R . .
C6B C 0.5590(6) 0.4334(6) 0.3821(3) 0.072(2) Uani 1 1 d . . .
H6B H 0.5202 0.3884 0.4020 0.086 Uiso 1 1 calc R . .
C7B C 0.5112(4) 0.5274(6) 0.3872(3) 0.0648(19) Uani 1 1 d . . .
H7B H 0.4391 0.5505 0.4144 0.078 Uiso 1 1 calc R . .
C8B C 0.5639(4) 0.5935(4) 0.3537(3) 0.0529(14) Uani 1 1 d . . .
H8B H 0.5279 0.6622 0.3554 0.063 Uiso 1 1 calc R . .
C9B C 0.6694(4) 0.5590(4) 0.3176(3) 0.0467(13) Uani 1 1 d . . .
H9B H 0.7072 0.6037 0.2941 0.056 Uiso 1 1 calc R . .
C10B C 0.7193(4) 0.4608(4) 0.3158(3) 0.0448(12) Uani 1 1 d . . .
H10B H 0.7927 0.4362 0.2916 0.054 Uiso 1 1 calc R . .
C31 C 0.1054(4) 1.3969(3) -0.1056(3) 0.0392(12) Uani 1 1 d . . .
H31 H 0.1149 1.3284 -0.1027 0.047 Uiso 1 1 calc R . .
C32 C 0.1921(4) 1.4295(4) -0.1148(3) 0.0412(12) Uani 1 1 d . . .
H32 H 0.2621 1.3837 -0.1170 0.049 Uiso 1 1 calc R . .
C33 C 0.1778(4) 1.5279(4) -0.1208(3) 0.0414(12) Uani 1 1 d . . .
H33 H 0.2379 1.5509 -0.1277 0.050 Uiso 1 1 calc R . .
C34 C 0.0748(4) 1.5950(4) -0.1169(3) 0.0456(13) Uani 1 1 d . . .
H34 H 0.0635 1.6639 -0.1216 0.055 Uiso 1 1 calc R . .
C35 C -0.0096(4) 1.5581(4) -0.1061(3) 0.0389(11) Uani 1 1 d . . .
H35 H -0.0807 1.6021 -0.1026 0.047 Uiso 1 1 calc R . .
C41 C 0.0908(4) 0.7522(4) 0.2327(3) 0.0439(13) Uani 1 1 d . . .
H41 H 0.0263 0.7886 0.2146 0.053 Uiso 1 1 calc R . .
C42 C 0.1801(5) 0.7873(4) 0.2172(3) 0.0558(16) Uani 1 1 d . . .
H42 H 0.1770 0.8487 0.1888 0.067 Uiso 1 1 calc R . .
C43 C 0.2712(5) 0.7310(5) 0.2439(4) 0.0599(16) Uani 1 1 d . . .
H43 H 0.3321 0.7534 0.2341 0.072 Uiso 1 1 calc R . .
C44 C 0.2752(5) 0.6429(5) 0.2847(3) 0.0609(16) Uani 1 1 d . . .
H44 H 0.3386 0.6036 0.3030 0.073 Uiso 1 1 calc R . .
C45 C 0.1882(4) 0.6128(4) 0.2985(3) 0.0460(13) Uani 1 1 d . . .
H45 H 0.1903 0.5515 0.3268 0.055 Uiso 1 1 calc R . .
C51 C 0.8332(3) 1.1194(3) 0.1591(3) 0.0345(11) Uani 1 1 d . . .
H51 H 0.8041 1.0918 0.2077 0.041 Uiso 1 1 calc R . .
C52 C 0.9354(3) 1.0718(3) 0.1205(3) 0.0330(10) Uani 1 1 d . . .
H52 H 0.9775 1.0115 0.1420 0.040 Uiso 1 1 calc R . .
C53 C 0.9753(3) 1.1138(3) 0.0496(3) 0.0319(10) Uani 1 1 d . . .
H53 H 1.0458 1.0828 0.0224 0.038 Uiso 1 1 calc R . .
C54 C 0.9124(3) 1.2008(3) 0.0184(2) 0.0305(10) Uani 1 1 d . . .
H54 H 0.9389 1.2288 -0.0309 0.037 Uiso 1 1 calc R . .
C55 C 0.8126(3) 1.2461(3) 0.0587(2) 0.0287(10) Uani 1 1 d . . .
H55 H 0.7693 1.3066 0.0383 0.034 Uiso 1 1 calc R . .
C61 C 0.3828(4) 0.2311(3) 0.2892(3) 0.0427(12) Uani 1 1 d . . .
H61 H 0.4506 0.1903 0.2998 0.051 Uiso 1 1 calc R . .
C62 C 0.2907(5) 0.2069(4) 0.3224(3) 0.0464(13) Uani 1 1 d . . .
H62 H 0.2943 0.1486 0.3553 0.056 Uiso 1 1 calc R . .
C63 C 0.1939(4) 0.2690(4) 0.3067(3) 0.0510(14) Uani 1 1 d . . .
H63 H 0.1297 0.2534 0.3287 0.061 Uiso 1 1 calc R . .
C64 C 0.1896(4) 0.3521(4) 0.2602(3) 0.0543(15) Uani 1 1 d . . .
H64 H 0.1225 0.3959 0.2506 0.065 Uiso 1 1 calc R . .
C65 C 0.2832(4) 0.3729(4) 0.2268(3) 0.0462(13) Uani 1 1 d . . .
H65 H 0.2812 0.4304 0.1929 0.055 Uiso 1 1 calc R . .
C71 C 1.2899(4) 0.2548(4) 0.5997(3) 0.0438(12) Uani 1 1 d . . .
H71 H 1.2339 0.3156 0.5988 0.053 Uiso 1 1 calc R . .
C72 C 1.2846(4) 0.1890(4) 0.6607(3) 0.0422(12) Uani 1 1 d . . .
H72 H 1.2243 0.2029 0.7026 0.051 Uiso 1 1 calc R . .
C73 C 1.3647(4) 0.1027(4) 0.6631(3) 0.0436(12) Uani 1 1 d . . .
H73 H 1.3604 0.0561 0.7064 0.052 Uiso 1 1 calc R . .
C74 C 1.4533(4) 0.0823(4) 0.6020(3) 0.0530(15) Uani 1 1 d . . .
H74 H 1.5103 0.0221 0.6026 0.064 Uiso 1 1 calc R . .
C75 C 1.4557(4) 0.1520(5) 0.5410(3) 0.0512(15) Uani 1 1 d . . .
H75 H 1.5155 0.1416 0.4988 0.061 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1A Sb1A Cl2A 91.83(3) . . ?
Cl1A Sb1A Cl3A 90.99(4) . . ?
Cl2A Sb1A Cl3A 92.39(3) . . ?
Cl1A Sb1A Cl4A 93.37(3) . . ?
Cl2A Sb1A Cl4A 87.07(3) . . ?
Cl3A Sb1A Cl4A 175.63(3) . . ?
Cl1A Sb1A Cl6A 175.67(3) . . ?
Cl2A Sb1A Cl6A 84.05(2) . . ?
Cl3A Sb1A Cl6A 90.50(3) . . ?
Cl4A Sb1A Cl6A 85.13(2) . . ?
Cl1A Sb1A Cl5A 89.01(3) . . ?
Cl2A Sb1A Cl5A 173.12(3) . . ?
Cl3A Sb1A Cl5A 94.42(3) . . ?
Cl4A Sb1A Cl5A 86.06(3) . . ?
Cl6A Sb1A Cl5A 94.92(2) . . ?
Cl2B Sb1B Cl1B 90.87(4) . . ?
Cl2B Sb1B Cl3B 89.47(4) . . ?
Cl1B Sb1B Cl3B 89.34(4) . . ?
Cl2B Sb1B Cl4B 89.22(3) . . ?
Cl1B Sb1B Cl4B 86.41(4) . . ?
Cl3B Sb1B Cl4B 175.54(4) . . ?
Sb1A Cl6A Sb1A 180.000(11) 2_675 . ?
C5A N1A C1A 122.4(4) . . ?
C6A N2A C10A 122.9(4) . . ?
C1B N1B C5B 122.2(5) . . ?
C10B N2B C6B 121.1(5) . . ?
C35 N3 C31 121.9(4) . . ?
C45 N4 C41 123.5(5) . . ?
C51 N5 C55 122.5(4) . . ?
C65 N6 C61 122.9(4) . . ?
C71 N7 C75 122.4(4) . . ?
N1A C1A C2A 119.4(4) . . ?
C1A C2A C3A 119.4(4) . . ?
C4A C3A C2A 119.3(4) . . ?
C5A C4A C3A 119.9(4) . . ?
N1A C5A C4A 119.7(4) . . ?
N2A C6A C7A 119.1(4) . . ?
C8A C7A C6A 119.3(4) . . ?
C7A C8A C9A 120.1(4) . . ?
C10A C9A C8A 118.8(4) . . ?
N2A C10A C9A 119.9(4) . . ?
N1B C1B C2B 119.7(5) . . ?
C1B C2B C3B 119.2(5) . . ?
C4B C3B C2B 120.2(5) . . ?
C5B C4B C3B 118.1(5) . . ?
N1B C5B C4B 120.5(5) . . ?
C7B C6B N2B 120.2(6) . . ?
C6B C7B C8B 120.5(5) . . ?
C7B C8B C9B 119.0(5) . . ?
C10B C9B C8B 119.6(5) . . ?
N2B C10B C9B 119.4(5) . . ?
N3 C31 C32 119.7(4) . . ?
C33 C32 C31 119.6(4) . . ?
C32 C33 C34 120.1(4) . . ?
C35 C34 C33 117.8(5) . . ?
N3 C35 C34 120.9(4) . . ?
N4 C41 C42 117.7(5) . . ?
C43 C42 C41 118.4(5) . . ?
C42 C43 C44 120.5(5) . . ?
C45 C44 C43 119.0(5) . . ?
N4 C45 C44 120.9(5) . . ?
N5 C51 C52 119.7(4) . . ?
C51 C52 C53 118.7(4) . . ?
C54 C53 C52 120.0(4) . . ?
C55 C54 C53 119.6(4) . . ?
N5 C55 C54 119.4(4) . . ?
N6 C61 C62 119.1(5) . . ?
C63 C62 C61 118.7(5) . . ?
C64 C63 C62 120.2(5) . . ?
C63 C64 C65 119.6(5) . . ?
N6 C65 C64 119.4(5) . . ?
N7 C71 C72 120.4(5) . . ?
C71 C72 C73 120.3(5) . . ?
C72 C73 C74 119.9(5) . . ?
C75 C74 C73 117.8(5) . . ?
N7 C75 C74 119.2(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1A Cl1A 2.4893(10) . ?
Sb1A Cl2A 2.5016(10) . ?
Sb1A Cl3A 2.5475(11) . ?
Sb1A Cl4A 2.7744(11) . ?
Sb1A Cl6A 2.8666(2) . ?
Sb1A Cl5A 2.8968(10) . ?
Sb1B Cl2B 2.4532(10) . ?
Sb1B Cl1B 2.4834(10) . ?
Sb1B Cl3B 2.5476(11) . ?
Sb1B Cl4B 2.7403(12) . ?
Cl6A Sb1A 2.8666(2) 2_675 ?
N1A C5A 1.325(6) . ?
N1A C1A 1.336(6) . ?
N2A C6A 1.325(5) . ?
N2A C10A 1.342(6) . ?
N1B C1B 1.321(6) . ?
N1B C5B 1.322(7) . ?
N2B C10B 1.326(7) . ?
N2B C6B 1.367(8) . ?
N3 C35 1.322(6) . ?
N3 C31 1.341(6) . ?
N4 C45 1.313(6) . ?
N4 C41 1.324(6) . ?
N5 C51 1.335(5) . ?
N5 C55 1.350(5) . ?
N6 C65 1.315(6) . ?
N6 C61 1.335(6) . ?
N7 C71 1.305(6) . ?
N7 C75 1.354(7) . ?
C1A C2A 1.364(7) . ?
C2A C3A 1.372(7) . ?
C3A C4A 1.368(7) . ?
C4A C5A 1.355(7) . ?
C6A C7A 1.380(6) . ?
C7A C8A 1.371(6) . ?
C8A C9A 1.382(6) . ?
C9A C10A 1.359(6) . ?
C1B C2B 1.346(7) . ?
C2B C3B 1.377(7) . ?
C3B C4B 1.360(7) . ?
C4B C5B 1.360(7) . ?
C6B C7B 1.300(9) . ?
C7B C8B 1.369(8) . ?
C8B C9B 1.371(7) . ?
C9B C10B 1.353(7) . ?
C31 C32 1.365(7) . ?
C32 C33 1.361(6) . ?
C33 C34 1.395(6) . ?
C34 C35 1.372(7) . ?
C41 C42 1.412(8) . ?
C42 C43 1.367(8) . ?
C43 C44 1.366(8) . ?
C44 C45 1.342(8) . ?
C51 C52 1.380(6) . ?
C52 C53 1.384(6) . ?
C53 C54 1.382(6) . ?
C54 C55 1.360(6) . ?
C61 C62 1.382(7) . ?
C62 C63 1.375(7) . ?
C63 C64 1.352(8) . ?
C64 C65 1.377(7) . ?
C71 C72 1.339(7) . ?
C72 C73 1.352(7) . ?
C73 C74 1.392(7) . ?
C74 C75 1.370(8) . ?
