#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:41:20 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179257 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/77/4317763.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4317763
loop_
_publ_author_name
'Robert Bender'
'Pierre Braunstein'
'Salah-Eddine Bouaoud'
'Djamil Rouag'
'Pierre D. Harvey'
'Stéphane Golhen'
'Lahcène Ouahab'
_publ_section_title
;
 Bonding Behavior of Co(CO)3L (L = CO, PPh3) Building Blocks in
 Platinum-Cobalt Carbonyl Clusters
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1739
_journal_page_last               1746
_journal_paper_doi               10.1021/ic010739p
_journal_volume                  41
_journal_year                    2002
_chemical_formula_sum            'C66 H56 Co O4 P3 Pt2'
_chemical_formula_weight         1455.13
_chemical_name_systematic
;
   ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                106.654(4)
_cell_angle_beta                 95.844(3)
_cell_angle_gamma                92.983(4)
_cell_formula_units_Z            2
_cell_length_a                   11.791(4)
_cell_length_b                   13.471(6)
_cell_length_c                   18.887(9)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    233(2)
_cell_measurement_theta_max      10.89
_cell_measurement_theta_min      4.98
_cell_volume                     2849(2)
_computing_cell_refinement       'Enraf-Nonius CAD4'
_computing_data_collection       'Enraf-Nonius CAD4'
_computing_data_reduction        MolEN
_computing_molecular_graphics    ORTEPIII
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      233(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Nonius CAD4'
_diffrn_measurement_method       q\2q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0361
_diffrn_reflns_av_sigmaI/netI    0.0714
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            10562
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.13
_diffrn_standards_interval_count 250
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.319
_exptl_absorpt_correction_T_max  99.8180
_exptl_absorpt_correction_T_min  85.0012
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.696
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1424
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.125
_refine_diff_density_max         1.499
_refine_diff_density_min         -2.007
_refine_diff_density_rms         0.182
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     685
_refine_ls_number_reflns         10028
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.021
_refine_ls_R_factor_all          0.0947
_refine_ls_R_factor_gt           0.0444
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0688P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1040
_refine_ls_wR_factor_ref         0.1192
_reflns_number_gt                6804
_reflns_number_total             10028
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic010739p.cif
_cod_data_source_block           CoPt2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0688P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0688P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_database_code               4317763
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.30359(3) 0.25290(3) 0.330107(19) 0.02768(11) Uani 1 d . . .
Pt2 Pt 0.38642(3) 0.30592(3) 0.21923(2) 0.03026(12) Uani 1 d . . .
Co Co 0.43750(12) 0.13904(10) 0.25124(7) 0.0372(3) Uani 1 d . . .
P1 P 0.2193(2) 0.24654(19) 0.43065(13) 0.0302(5) Uani 1 d . . .
P2 P 0.2416(2) 0.37745(18) 0.28027(13) 0.0294(5) Uani 1 d . . .
P3 P 0.4303(2) 0.3815(2) 0.13230(14) 0.0335(6) Uani 1 d . . .
C1 C 0.4531(8) 0.1870(7) 0.3546(6) 0.037(2) Uani 1 d . . .
O1 O 0.5107(6) 0.1927(7) 0.4087(4) 0.058(2) Uani 1 d . . .
C2 C 0.5349(8) 0.2252(8) 0.2183(6) 0.042(3) Uani 1 d . . .
O2 O 0.6263(7) 0.2359(6) 0.2046(5) 0.063(2) Uani 1 d . . .
C3 C 0.5226(11) 0.0352(9) 0.2472(6) 0.055(3) Uani 1 d . . .
O3 O 0.5774(9) -0.0318(7) 0.2468(6) 0.087(3) Uani 1 d . . .
C4 C 0.3058(12) 0.0799(8) 0.1921(7) 0.054(3) Uani 1 d . . .
O4 O 0.2232(9) 0.0432(8) 0.1543(6) 0.087(3) Uani 1 d . . .
C5 C 0.2359(8) 0.3717(7) 0.5027(5) 0.031(2) Uani 1 d . . .
C6 C 0.1462(9) 0.4153(9) 0.5385(6) 0.047(3) Uani 1 d . . .
H6 H 0.0732 0.3809 0.5264 0.056 Uiso 1 calc R . .
C7 C 0.1658(10) 0.5116(9) 0.5933(6) 0.051(3) Uani 1 d . . .
H7 H 0.1058 0.5415 0.6177 0.062 Uiso 1 calc R . .
C8 C 0.2746(12) 0.5626(9) 0.6112(6) 0.057(3) Uani 1 d . . .
H8 H 0.2879 0.6268 0.6474 0.069 Uiso 1 calc R . .
C9 C 0.3622(10) 0.5179(8) 0.5753(6) 0.045(3) Uani 1 d . . .
H9 H 0.4356 0.5514 0.5879 0.054 Uiso 1 calc R . .
C10 C 0.3434(9) 0.4244(8) 0.5209(6) 0.041(2) Uani 1 d . . .
H10 H 0.4037 0.3960 0.4960 0.049 Uiso 1 calc R . .
C11 C 0.2774(8) 0.1588(7) 0.4791(5) 0.034(2) Uani 1 d . . .
C12 C 0.3134(8) 0.1851(8) 0.5539(6) 0.041(2) Uani 1 d . . .
H12 H 0.3066 0.2521 0.5838 0.050 Uiso 1 calc R . .
C13 C 0.3603(9) 0.1127(9) 0.5856(7) 0.053(3) Uani 1 d . . .
H13 H 0.3844 0.1315 0.6364 0.063 Uiso 1 calc R . .
C14 C 0.3706(10) 0.0156(9) 0.5430(8) 0.059(3) Uani 1 d . . .
H14 H 0.4021 -0.0322 0.5647 0.070 Uiso 1 calc R . .
C15 C 0.3356(10) -0.0140(9) 0.4681(7) 0.055(3) Uani 1 d . . .
H15 H 0.3431 -0.0814 0.4391 0.066 Uiso 1 calc R . .
C16 C 0.2897(9) 0.0563(8) 0.4365(6) 0.050(3) Uani 1 d . . .
H16 H 0.2659 0.0360 0.3856 0.059 Uiso 1 calc R . .
C17 C 0.0666(8) 0.2059(7) 0.4147(5) 0.035(2) Uani 1 d . . .
C18 C 0.0154(9) 0.1546(8) 0.4587(6) 0.045(3) Uani 1 d . . .
H18 H 0.0593 0.1415 0.4982 0.054 Uiso 1 calc R . .
C19 C -0.0980(10) 0.1232(9) 0.4448(7) 0.056(3) Uani 1 d . . .
H19 H -0.1301 0.0871 0.4741 0.067 Uiso 1 calc R . .
C20 C -0.1660(10) 0.1438(9) 0.3881(7) 0.059(3) Uani 1 d . . .
H20 H -0.2444 0.1254 0.3804 0.071 Uiso 1 calc R . .
C21 C -0.1151(9) 0.1924(10) 0.3431(7) 0.058(3) Uani 1 d . . .
H21 H -0.1583 0.2025 0.3021 0.070 Uiso 1 calc R . .
C22 C -0.0013(9) 0.2257(9) 0.3584(6) 0.052(3) Uani 1 d . . .
H22 H 0.0305 0.2629 0.3296 0.062 Uiso 1 calc R . .
C23 C 0.0969(8) 0.3706(7) 0.2326(5) 0.037(2) Uani 1 d . . .
C24 C 0.0376(9) 0.4531(9) 0.2346(6) 0.046(3) Uani 1 d . . .
H24 H 0.0710 0.5192 0.2608 0.056 Uiso 1 calc R . .
C25 C -0.0732(11) 0.4420(14) 0.1984(7) 0.071(4) Uani 1 d . . .
H25 H -0.1134 0.5001 0.2000 0.086 Uiso 1 calc R . .
C26 C -0.1210(12) 0.3468(15) 0.1611(9) 0.082(5) Uani 1 d . . .
H26 H -0.1955 0.3386 0.1375 0.098 Uiso 1 calc R . .
C27 C -0.0616(15) 0.2615(15) 0.1573(8) 0.100(6) Uani 1 d . . .
H27 H -0.0960 0.1958 0.1307 0.120 Uiso 1 calc R . .
C28 C 0.0469(10) 0.2712(10) 0.1918(7) 0.065(4) Uani 1 d . . .
H28 H 0.0874 0.2129 0.1885 0.078 Uiso 1 calc R . .
C29 C 0.2645(8) 0.5076(7) 0.3446(5) 0.036(2) Uani 1 d . . .
C30 C 0.1908(9) 0.5413(7) 0.3966(5) 0.040(2) Uani 1 d . . .
H30 H 0.1258 0.4986 0.3958 0.048 Uiso 1 calc R . .
C31 C 0.2103(11) 0.6349(9) 0.4490(6) 0.053(3) Uani 1 d . . .
H31 H 0.1581 0.6568 0.4828 0.064 Uiso 1 calc R . .
C32 C 0.3060(10) 0.6965(9) 0.4519(7) 0.056(3) Uani 1 d . . .
H32 H 0.3202 0.7606 0.4882 0.067 Uiso 1 calc R . .
C33 C 0.3809(10) 0.6651(9) 0.4023(7) 0.062(3) Uani 1 d . . .
H33 H 0.4474 0.7072 0.4052 0.074 Uiso 1 calc R . .
C34 C 0.3599(9) 0.5711(8) 0.3472(7) 0.052(3) Uani 1 d . . .
H34 H 0.4105 0.5511 0.3121 0.063 Uiso 1 calc R . .
C35 C 0.5249(8) 0.5028(7) 0.1699(5) 0.035(2) Uani 1 d . . .
C36 C 0.6119(9) 0.5057(8) 0.2251(6) 0.046(3) Uani 1 d . . .
H36 H 0.6230 0.4476 0.2414 0.055 Uiso 1 calc R . .
C37 C 0.6829(10) 0.5971(9) 0.2562(6) 0.057(3) Uani 1 d . . .
H37 H 0.7406 0.6005 0.2945 0.069 Uiso 1 calc R . .
C38 C 0.6689(10) 0.6815(9) 0.2312(7) 0.055(3) Uani 1 d . . .
H38 H 0.7173 0.7419 0.2520 0.066 Uiso 1 calc R . .
C39 C 0.5833(11) 0.6773(9) 0.1754(7) 0.058(3) Uani 1 d . . .
H39 H 0.5746 0.7347 0.1579 0.069 Uiso 1 calc R . .
C40 C 0.5115(9) 0.5904(8) 0.1454(6) 0.046(3) Uani 1 d . . .
H40 H 0.4528 0.5889 0.1081 0.055 Uiso 1 calc R . .
C41 C 0.5025(9) 0.3018(8) 0.0601(5) 0.039(2) Uani 1 d . . .
C42 C 0.5978(8) 0.3359(8) 0.0333(6) 0.040(2) Uani 1 d . . .
H42 H 0.6276 0.4048 0.0530 0.048 Uiso 1 calc R . .
C43 C 0.6487(10) 0.2703(9) -0.0214(6) 0.056(3) Uani 1 d . . .
H43 H 0.7123 0.2950 -0.0387 0.067 Uiso 1 calc R . .
C44 C 0.6067(13) 0.1686(9) -0.0509(7) 0.067(4) Uani 1 d . . .
H44 H 0.6416 0.1241 -0.0881 0.080 Uiso 1 calc R . .
C45 C 0.5149(12) 0.1331(10) -0.0259(7) 0.069(4) Uani 1 d . . .
H45 H 0.4864 0.0640 -0.0462 0.083 Uiso 1 calc R . .
C46 C 0.4628(11) 0.1968(9) 0.0288(6) 0.055(3) Uani 1 d . . .
H46 H 0.4000 0.1702 0.0457 0.066 Uiso 1 calc R . .
C47 C 0.3108(8) 0.4245(8) 0.0814(6) 0.039(2) Uani 1 d . . .
C48 C 0.2993(10) 0.3969(10) 0.0024(6) 0.056(3) Uani 1 d . . .
H48 H 0.3472 0.3516 -0.0245 0.067 Uiso 1 calc R . .
C49 C 0.2148(10) 0.4392(11) -0.0334(7) 0.062(3) Uani 1 d . . .
H49 H 0.2052 0.4207 -0.0852 0.074 Uiso 1 calc R . .
C50 C 0.1476(10) 0.5052(11) 0.0039(8) 0.065(4) Uani 1 d . . .
H50 H 0.0928 0.5335 -0.0217 0.078 Uiso 1 calc R . .
C51 C 0.1579(9) 0.5328(10) 0.0811(8) 0.064(4) Uani 1 d . . .
H51 H 0.1111 0.5798 0.1075 0.077 Uiso 1 calc R . .
C52 C 0.2400(9) 0.4885(9) 0.1179(7) 0.049(3) Uani 1 d . . .
H52 H 0.2454 0.5042 0.1695 0.058 Uiso 1 calc R . .
C53 C 0.1662(13) 0.8196(11) 0.2705(8) 0.074(4) Uani 1 d . . .
C54 C 0.0979(17) 0.9025(12) 0.2696(9) 0.095(5) Uani 1 d . . .
H54 H 0.1202 0.9512 0.2462 0.114 Uiso 1 calc R . .
C55 C 0.0037(18) 0.9116(15) 0.3011(11) 0.108(6) Uani 1 d . . .
H55 H -0.0378 0.9684 0.3009 0.130 Uiso 1 calc R . .
C56 C -0.0364(17) 0.8411(17) 0.3343(9) 0.107(6) Uani 1 d . . .
H56 H -0.1055 0.8478 0.3543 0.129 Uiso 1 calc R . .
C57 C 0.0247(17) 0.7649(16) 0.3371(10) 0.107(6) Uani 1 d . . .
H57 H 0.0018 0.7184 0.3621 0.128 Uiso 1 calc R . .
C58 C 0.1260(15) 0.7517(13) 0.3024(8) 0.087(5) Uani 1 d . . .
H58 H 0.1656 0.6936 0.3020 0.104 Uiso 1 calc R . .
C59 C 0.9105(16) 0.8567(16) 0.0557(11) 0.100(5) Uani 1 d . . .
C60 C 0.8793(19) 0.9159(16) 0.0130(11) 0.114(6) Uani 1 d . . .
H60 H 0.9094 0.9077 -0.0317 0.137 Uiso 1 calc R . .
C61 C 0.803(2) 0.9888(16) 0.0343(15) 0.136(8) Uani 1 d . . .
H61 H 0.7828 1.0296 0.0036 0.163 Uiso 1 calc R . .
C62 C 0.757(2) 1.003(2) 0.0979(18) 0.170(15) Uani 1 d . . .
H62 H 0.7029 1.0502 0.1108 0.204 Uiso 1 calc R . .
C63 C 0.793(3) 0.946(3) 0.1424(16) 0.189(18) Uani 1 d . . .
H63 H 0.7703 0.9601 0.1897 0.227 Uiso 1 calc R . .
C64 C 0.865(2) 0.866(2) 0.1177(13) 0.130(8) Uani 1 d . . .
H64 H 0.8792 0.8193 0.1451 0.156 Uiso 1 calc R . .
C65 C 0.2805(17) 0.8078(16) 0.2391(10) 0.132(8) Uani 1 d . . .
H65A H 0.2954 0.8625 0.2173 0.198 Uiso 1 calc R . .
H65B H 0.2776 0.7417 0.2018 0.198 Uiso 1 calc R . .
H65C H 0.3404 0.8116 0.2785 0.198 Uiso 1 calc R . .
C66 C 0.9964(19) 0.7770(17) 0.0369(13) 0.150(9) Uani 1 d . . .
H66A H 1.0255 0.7788 -0.0084 0.226 Uiso 1 calc R . .
H66B H 0.9601 0.7090 0.0306 0.226 Uiso 1 calc R . .
H66C H 1.0584 0.7923 0.0765 0.226 Uiso 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 P1 97.8(3) . . ?
C1 Pt1 P2 140.9(3) . . ?
P1 Pt1 P2 113.22(9) . . ?
C1 Pt1 Co 46.0(3) . . ?
P1 Pt1 Co 134.19(7) . . ?
P2 Pt1 Co 112.20(7) . . ?
C1 Pt1 Pt2 92.1(3) . . ?
P1 Pt1 Pt2 166.28(6) . . ?
P2 Pt1 Pt2 54.00(6) . . ?
Co Pt1 Pt2 59.28(4) . . ?
C2 Pt2 P3 95.4(3) . . ?
C2 Pt2 P2 149.1(3) . . ?
P3 Pt2 P2 112.66(9) . . ?
C2 Pt2 Co 45.6(3) . . ?
P3 Pt2 Co 135.05(7) . . ?
P2 Pt2 Co 111.34(7) . . ?
C2 Pt2 Pt1 97.0(3) . . ?
P3 Pt2 Pt1 166.65(7) . . ?
P2 Pt2 Pt1 54.14(6) . . ?
Co Pt2 Pt1 58.26(3) . . ?
C3 Co C4 104.4(5) . . ?
C3 Co C1 95.1(5) . . ?
C4 Co C1 125.0(5) . . ?
C3 Co C2 99.8(5) . . ?
C4 Co C2 118.4(5) . . ?
C1 Co C2 107.7(5) . . ?
C3 Co Pt1 143.1(4) . . ?
C4 Co Pt1 83.6(4) . . ?
C1 Co Pt1 53.7(3) . . ?
C2 Co Pt1 107.8(3) . . ?
C3 Co Pt2 152.5(4) . . ?
C4 Co Pt2 85.2(3) . . ?
C1 Co Pt2 100.3(3) . . ?
C2 Co Pt2 53.9(3) . . ?
Pt1 Co Pt2 62.46(4) . . ?
C11 P1 C17 102.6(4) . . ?
C11 P1 C5 103.2(4) . . ?
C17 P1 C5 105.8(4) . . ?
C11 P1 Pt1 115.1(3) . . ?
C17 P1 Pt1 116.6(3) . . ?
C5 P1 Pt1 112.2(3) . . ?
C29 P2 C23 104.7(4) . . ?
C29 P2 Pt2 119.8(3) . . ?
C23 P2 Pt2 121.9(3) . . ?
C29 P2 Pt1 113.7(3) . . ?
C23 P2 Pt1 123.1(3) . . ?
Pt2 P2 Pt1 71.86(7) . . ?
C41 P3 C47 104.0(5) . . ?
C41 P3 C35 104.6(5) . . ?
C47 P3 C35 101.5(4) . . ?
C41 P3 Pt2 114.5(3) . . ?
C47 P3 Pt2 116.8(3) . . ?
C35 P3 Pt2 113.9(3) . . ?
O1 C1 Co 145.5(8) . . ?
O1 C1 Pt1 134.0(8) . . ?
Co C1 Pt1 80.3(4) . . ?
O2 C2 Co 142.9(8) . . ?
O2 C2 Pt2 136.5(8) . . ?
Co C2 Pt2 80.6(4) . . ?
O3 C3 Co 177.9(11) . . ?
O4 C4 Co 179.2(11) . . ?
C6 C5 C10 119.5(9) . . ?
C6 C5 P1 122.9(8) . . ?
C10 C5 P1 117.6(7) . . ?
C5 C6 C7 119.5(10) . . ?
C8 C7 C6 120.1(10) . . ?
C9 C8 C7 119.5(11) . . ?
C8 C9 C10 120.8(11) . . ?
C9 C10 C5 120.6(9) . . ?
C12 C11 C16 117.2(9) . . ?
C12 C11 P1 125.1(7) . . ?
C16 C11 P1 117.7(7) . . ?
C11 C12 C13 120.7(10) . . ?
C14 C13 C12 120.2(11) . . ?
C13 C14 C15 121.0(10) . . ?
C16 C15 C14 119.3(11) . . ?
C15 C16 C11 121.6(11) . . ?
C22 C17 C18 117.6(9) . . ?
C22 C17 P1 120.4(8) . . ?
C18 C17 P1 122.0(8) . . ?
C19 C18 C17 120.9(10) . . ?
C18 C19 C20 121.1(11) . . ?
C19 C20 C21 118.3(11) . . ?
C22 C21 C20 120.2(12) . . ?
C17 C22 C21 121.7(11) . . ?
C24 C23 C28 119.1(10) . . ?
C24 C23 P2 124.4(8) . . ?
C28 C23 P2 116.5(8) . . ?
C23 C24 C25 121.3(12) . . ?
C26 C25 C24 119.1(14) . . ?
C25 C26 C27 120.7(14) . . ?
C28 C27 C26 120.8(15) . . ?
C27 C28 C23 118.8(14) . . ?
C34 C29 C30 118.1(10) . . ?
C34 C29 P2 121.3(8) . . ?
C30 C29 P2 120.3(8) . . ?
C31 C30 C29 121.7(10) . . ?
C32 C31 C30 119.7(11) . . ?
C33 C32 C31 120.1(11) . . ?
C32 C33 C34 120.6(11) . . ?
C29 C34 C33 119.7(11) . . ?
C36 C35 C40 119.4(9) . . ?
C36 C35 P3 117.4(7) . . ?
C40 C35 P3 123.2(7) . . ?
C35 C36 C37 118.9(10) . . ?
C38 C37 C36 120.8(11) . . ?
C37 C38 C39 119.9(11) . . ?
C40 C39 C38 120.6(11) . . ?
C39 C40 C35 120.4(10) . . ?
C42 C41 C46 116.5(10) . . ?
C42 C41 P3 124.7(8) . . ?
C46 C41 P3 118.8(8) . . ?
C43 C42 C41 121.3(10) . . ?
C44 C43 C42 120.3(11) . . ?
C45 C44 C43 119.7(11) . . ?
C44 C45 C46 121.1(12) . . ?
C45 C46 C41 121.0(11) . . ?
C52 C47 C48 119.2(10) . . ?
C52 C47 P3 120.6(8) . . ?
C48 C47 P3 120.0(8) . . ?
C49 C48 C47 118.2(12) . . ?
C50 C49 C48 121.7(12) . . ?
C49 C50 C51 120.7(11) . . ?
C50 C51 C52 118.4(12) . . ?
C47 C52 C51 121.8(12) . . ?
C58 C53 C54 115.7(15) . . ?
C58 C53 C65 120.6(15) . . ?
C54 C53 C65 123.7(15) . . ?
C55 C54 C53 120.8(16) . . ?
C54 C55 C56 122.8(18) . . ?
C57 C56 C55 118(2) . . ?
C56 C57 C58 120.5(18) . . ?
C53 C58 C57 121.9(16) . . ?
C64 C59 C60 120(2) . . ?
C64 C59 C66 117(2) . . ?
C60 C59 C66 123(2) . . ?
C59 C60 C61 121(2) . . ?
C62 C61 C60 122(3) . . ?
C61 C62 C63 117(3) . . ?
C62 C63 C64 120(3) . . ?
C59 C64 C63 120(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 2.083(9) . ?
Pt1 P1 2.252(2) . ?
Pt1 P2 2.265(2) . ?
Pt1 Co 2.5468(15) . ?
Pt1 Pt2 2.6553(11) . ?
Pt2 C2 2.107(10) . ?
Pt2 P3 2.253(2) . ?
Pt2 P2 2.261(2) . ?
Pt2 Co 2.5743(16) . ?
Co C3 1.752(12) . ?
Co C4 1.818(14) . ?
Co C1 1.858(10) . ?
Co C2 1.864(10) . ?
P1 C11 1.812(9) . ?
P1 C17 1.823(9) . ?
P1 C5 1.825(9) . ?
P2 C29 1.813(10) . ?
P2 C23 1.831(10) . ?
P3 C41 1.797(10) . ?
P3 C47 1.837(10) . ?
P3 C35 1.844(9) . ?
C1 O1 1.149(11) . ?
C2 O2 1.145(11) . ?
C3 O3 1.136(13) . ?
C4 O4 1.143(14) . ?
C5 C6 1.380(13) . ?
C5 C10 1.381(13) . ?
C6 C7 1.399(15) . ?
C7 C8 1.385(17) . ?
C8 C9 1.365(15) . ?
C9 C10 1.369(14) . ?
C11 C12 1.370(13) . ?
C11 C16 1.408(14) . ?
C12 C13 1.393(13) . ?
C13 C14 1.344(16) . ?
C14 C15 1.367(16) . ?
C15 C16 1.363(14) . ?
C17 C22 1.362(14) . ?
C17 C18 1.385(13) . ?
C18 C19 1.357(14) . ?
C19 C20 1.373(16) . ?
C20 C21 1.376(16) . ?
C21 C22 1.368(15) . ?
C23 C24 1.337(14) . ?
C23 C28 1.403(15) . ?
C24 C25 1.391(16) . ?
C25 C26 1.34(2) . ?
C26 C27 1.37(2) . ?
C27 C28 1.358(19) . ?
C29 C34 1.365(14) . ?
C29 C30 1.372(13) . ?
C30 C31 1.353(14) . ?
C31 C32 1.353(16) . ?
C32 C33 1.348(16) . ?
C33 C34 1.381(15) . ?
C35 C36 1.377(13) . ?
C35 C40 1.397(13) . ?
C36 C37 1.393(15) . ?
C37 C38 1.361(16) . ?
C38 C39 1.370(16) . ?
C39 C40 1.352(15) . ?
C41 C42 1.387(13) . ?
C41 C46 1.402(14) . ?
C42 C43 1.368(14) . ?
C43 C44 1.367(16) . ?
C44 C45 1.343(17) . ?
C45 C46 1.362(16) . ?
C47 C52 1.330(14) . ?
C47 C48 1.421(14) . ?
C48 C49 1.386(15) . ?
C49 C50 1.321(17) . ?
C50 C51 1.387(17) . ?
C51 C52 1.392(14) . ?
C53 C58 1.324(18) . ?
C53 C54 1.41(2) . ?
C53 C65 1.52(2) . ?
C54 C55 1.31(2) . ?
C55 C56 1.37(2) . ?
C56 C57 1.29(2) . ?
C57 C58 1.42(2) . ?
C59 C64 1.32(2) . ?
C59 C60 1.33(2) . ?
C59 C66 1.51(2) . ?
C60 C61 1.37(3) . ?
C61 C62 1.34(3) . ?
C62 C63 1.34(4) . ?
C63 C64 1.41(4) . ?
