#------------------------------------------------------------------------------
#$Date: 2016-03-23 03:48:41 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179264 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/84/4318457.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4318457
loop_
_publ_author_name
'Alan K. Brisdon'
'Ian R. Crossley'
'Robin G. Pritchard'
'John E. Warren'
_publ_section_title
;
 Spectroscopic and Structural Assignment of the Absolute Stereochemistry
 in a Series of 1,2-Difluorovinyl Organometalloids. The First
 Crystallographic Characterization and Structural Series of Group 14
 Fluorovinyl Compounds
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4748
_journal_page_last               4755
_journal_paper_doi               10.1021/ic025593o
_journal_volume                  41
_journal_year                    2002
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C24 H24 F2 Ge1'
_chemical_formula_structural     'C24 H24 F2 GE1'
_chemical_formula_sum            'C24 H24 F2 Ge'
_chemical_formula_weight         423.02
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.2
_audit_creation_date             2001-11-20T07:20:34-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 93.7970(10)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   11.4276(2)
_cell_length_b                   11.4998(2)
_cell_length_c                   32.0449(5)
_cell_measurement_reflns_used    62938
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      0.998
_cell_measurement_wavelength     0.71073
_cell_volume                     4201.94(12)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Nonius BV, 1997-2000)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device       '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_orient_matrix_type       'by Nonius Collect from scalepack cell'
_diffrn_orient_matrix_UB_11      0.282686E-1
_diffrn_orient_matrix_UB_12      -0.76856E-2
_diffrn_orient_matrix_UB_13      -0.287408E-1
_diffrn_orient_matrix_UB_21      0.726528E-1
_diffrn_orient_matrix_UB_22      -0.39593E-1
_diffrn_orient_matrix_UB_23      0.119065E-1
_diffrn_orient_matrix_UB_31      -0.401715E-1
_diffrn_orient_matrix_UB_32      -0.770392E-1
_diffrn_orient_matrix_UB_33      -0.32126E-2
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.026
_diffrn_reflns_av_unetI/netI     0.0676
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            24763
_diffrn_reflns_reduction_process
;
 Scaled and merged with SORTAV
 R.H. Blessing, (1987) Cryst. Rev. 1, 3-58
 R.H. Blessing, (1989) J. Appl. Cryst. 22, 396-397
;
_diffrn_reflns_theta_full        27.46
_diffrn_reflns_theta_max         27.46
_diffrn_reflns_theta_min         2.55
_diffrn_source                   'Enraf Nonius FR590'
_exptl_absorpt_coefficient_mu    1.48
_exptl_absorpt_correction_T_max  0.866
_exptl_absorpt_correction_T_min  0.813
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 R.H. Blessing, Acta Cryst. (1995), A51, 33-38
;
_exptl_crystal_colour            colouress
_exptl_crystal_density_diffrn    1.337
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1744
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.743
_refine_diff_density_min         -0.432
_refine_diff_density_rms         0.076
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.988
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     679
_refine_ls_number_reflns         9427
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.988
_refine_ls_R_factor_all          0.0792
_refine_ls_R_factor_gt           0.0448
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0573P)²+0.5962P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0973
_refine_ls_wR_factor_ref         0.1111
_reflns_number_gt                6634
_reflns_number_total             9427
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic025593o_s1_5.cif
_cod_data_source_block           ph3gecfcfbu
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4318457
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8746(3) 0.5953(3) 0.84214(9) 0.0342(7) Uani 1 1 d . . .
C2 C 0.9116(2) 0.5577(2) 0.87907(9) 0.0295(6) Uani 1 1 d . . .
C3 C 1.0168(3) 0.5816(3) 0.90923(10) 0.0390(8) Uani 1 1 d . . .
C4 C 1.0992(3) 0.6718(4) 0.89274(15) 0.0514(10) Uani 1 1 d . . .
C5 C 1.0831(4) 0.4677(4) 0.91801(19) 0.0696(14) Uani 1 1 d . . .
C6 C 0.9698(5) 0.6252(7) 0.95061(15) 0.0861(19) Uani 1 1 d . . .
C7 C 0.5980(2) 0.5391(2) 0.84414(8) 0.0251(6) Uani 1 1 d . . .
C8 C 0.5804(3) 0.4360(3) 0.86666(9) 0.0294(6) Uani 1 1 d . . .
C9 C 0.4871(3) 0.4263(3) 0.89146(9) 0.0345(7) Uani 1 1 d . . .
C10 C 0.4093(3) 0.5172(3) 0.89474(10) 0.0380(8) Uani 1 1 d . . .
C11 C 0.4245(3) 0.6182(3) 0.87262(10) 0.0366(7) Uani 1 1 d . . .
C12 C 0.5174(3) 0.6290(3) 0.84776(9) 0.0287(6) Uani 1 1 d . . .
C13 C 0.7512(3) 0.4130(2) 0.77808(9) 0.0340(7) Uani 1 1 d . . .
C14 C 0.8571(4) 0.3880(3) 0.76214(13) 0.0586(11) Uani 1 1 d . . .
C15 C 0.8721(6) 0.2886(4) 0.73802(15) 0.0810(17) Uani 1 1 d . . .
C16 C 0.7803(6) 0.2130(4) 0.73056(13) 0.0781(18) Uani 1 1 d . . .
C17 C 0.6754(5) 0.2347(3) 0.74602(12) 0.0600(12) Uani 1 1 d . . .
C18 C 0.6597(4) 0.3348(3) 0.76953(10) 0.0442(9) Uani 1 1 d . . .
C19 C 0.7052(3) 0.6851(2) 0.77016(9) 0.0284(6) Uani 1 1 d . . .
C20 C 0.6786(3) 0.6653(3) 0.72789(10) 0.0403(8) Uani 1 1 d . . .
C21 C 0.6630(3) 0.7560(3) 0.69965(11) 0.0486(9) Uani 1 1 d . . .
C22 C 0.6736(3) 0.8691(3) 0.71348(11) 0.0446(9) Uani 1 1 d . . .
C23 C 0.6991(4) 0.8912(3) 0.75523(11) 0.0468(9) Uani 1 1 d . . .
C24 C 0.7152(3) 0.8002(3) 0.78345(10) 0.0388(8) Uani 1 1 d . . .
C31 C 0.9000(3) 0.5262(3) 0.57753(10) 0.0365(7) Uani 1 1 d . . .
C32 C 0.9301(3) 0.5874(3) 0.61086(11) 0.0457(8) Uani 1 1 d . . .
C33 C 1.0332(3) 0.5883(4) 0.64312(11) 0.0546(10) Uani 1 1 d . . .
C34 C 1.1297(5) 0.5048(5) 0.6304(2) 0.0800(16) Uani 1 1 d . . .
C35 C 1.0841(5) 0.7082(5) 0.64752(15) 0.0720(15) Uani 1 1 d . . .
C36 C 0.9880(5) 0.5475(6) 0.68425(15) 0.0869(19) Uani 1 1 d . . .
C37 C 0.6280(3) 0.5207(2) 0.58938(9) 0.0287(6) Uani 1 1 d . . .
C38 C 0.6436(3) 0.4538(3) 0.62592(10) 0.0372(8) Uani 1 1 d . . .
C39 C 0.5605(4) 0.4536(3) 0.65501(10) 0.0458(9) Uani 1 1 d . . .
C40 C 0.4604(4) 0.5204(3) 0.64886(11) 0.0495(10) Uani 1 1 d . . .
C41 C 0.4421(3) 0.5865(3) 0.61311(11) 0.0434(8) Uani 1 1 d . . .
C42 C 0.5249(3) 0.5857(3) 0.58349(10) 0.0336(7) Uani 1 1 d . . .
C43 C 0.7380(3) 0.3746(2) 0.51679(9) 0.0302(7) Uani 1 1 d . . .
C44 C 0.8219(3) 0.3473(3) 0.48856(11) 0.0414(8) Uani 1 1 d . . .
C45 C 0.8144(4) 0.2452(3) 0.46574(11) 0.0462(9) Uani 1 1 d . . .
C46 C 0.7242(3) 0.1683(3) 0.47035(10) 0.0422(9) Uani 1 1 d . . .
C47 C 0.6404(3) 0.1942(3) 0.49795(11) 0.0414(8) Uani 1 1 d . . .
C48 C 0.6471(3) 0.2961(3) 0.52099(10) 0.0335(7) Uani 1 1 d . . .
C49 C 0.7157(2) 0.6482(2) 0.50899(8) 0.0274(6) Uani 1 1 d . . .
C50 C 0.6894(3) 0.6274(3) 0.46680(9) 0.0341(7) Uani 1 1 d . . .
C51 C 0.6620(3) 0.7185(3) 0.43950(10) 0.0392(8) Uani 1 1 d . . .
C52 C 0.6596(3) 0.8309(3) 0.45409(10) 0.0381(8) Uani 1 1 d . . .
C53 C 0.6854(3) 0.8531(3) 0.49589(10) 0.0398(8) Uani 1 1 d . . .
C54 C 0.7137(3) 0.7631(3) 0.52331(10) 0.0343(7) Uani 1 1 d . . .
F1 F 0.94199(19) 0.6748(3) 0.82327(7) 0.0905(10) Uani 1 1 d . . .
F2 F 0.83813(17) 0.47784(18) 0.89486(6) 0.0562(6) Uani 1 1 d . . .
F31 F 0.98044(19) 0.44954(18) 0.56281(7) 0.0612(6) Uani 1 1 d . . .
F32 F 0.8450(2) 0.6641(2) 0.62145(7) 0.0656(6) Uani 1 1 d . . .
Ge1 Ge 0.72943(3) 0.55567(3) 0.809026(9) 0.02598(9) Uani 1 1 d . . .
Ge31 Ge 0.74467(3) 0.51978(3) 0.547872(9) 0.02851(10) Uani 1 1 d . . .
H4A H 1.161(4) 0.684(3) 0.9134(12) 0.067(12) Uiso 1 1 d . . .
H4B H 1.121(3) 0.653(3) 0.8666(12) 0.064(13) Uiso 1 1 d . . .
H4C H 1.061(4) 0.755(4) 0.8883(12) 0.073(13) Uiso 1 1 d . . .
H5A H 1.111(4) 0.447(3) 0.8887(13) 0.068(14) Uiso 1 1 d . . .
H5B H 1.027(4) 0.403(4) 0.9325(13) 0.087(14) Uiso 1 1 d . . .
H5C H 1.146(3) 0.486(3) 0.9418(11) 0.056(10) Uiso 1 1 d . . .
H6A H 0.920(6) 0.559(6) 0.9619(18) 0.15(3) Uiso 1 1 d . . .
H6B H 1.041(4) 0.645(4) 0.9692(14) 0.108(17) Uiso 1 1 d . . .
H6C H 0.927(5) 0.704(5) 0.9459(17) 0.12(2) Uiso 1 1 d . . .
H8 H 0.635(2) 0.370(2) 0.8637(7) 0.016(6) Uiso 1 1 d . . .
H9 H 0.477(2) 0.359(2) 0.9060(8) 0.025(7) Uiso 1 1 d . . .
H10 H 0.354(3) 0.515(2) 0.9112(9) 0.023(8) Uiso 1 1 d . . .
H11 H 0.370(3) 0.677(3) 0.8761(10) 0.049(10) Uiso 1 1 d . . .
H12 H 0.528(3) 0.687(3) 0.8330(9) 0.028(8) Uiso 1 1 d . . .
H14 H 0.913(3) 0.431(3) 0.7700(11) 0.045(12) Uiso 1 1 d . . .
H15 H 0.948(4) 0.279(4) 0.7321(12) 0.072(14) Uiso 1 1 d . . .
H16 H 0.786(4) 0.147(4) 0.7151(13) 0.089(15) Uiso 1 1 d . . .
H17 H 0.608(3) 0.181(3) 0.7441(10) 0.051(11) Uiso 1 1 d . . .
H18 H 0.587(3) 0.349(3) 0.7818(10) 0.050(11) Uiso 1 1 d . . .
H20 H 0.671(3) 0.595(3) 0.7180(10) 0.049(10) Uiso 1 1 d . . .
H21 H 0.645(3) 0.740(3) 0.6695(12) 0.071(12) Uiso 1 1 d . . .
H22 H 0.659(3) 0.934(3) 0.6945(11) 0.063(12) Uiso 1 1 d . . .
H23 H 0.695(3) 0.965(3) 0.7649(11) 0.052(11) Uiso 1 1 d . . .
H24 H 0.735(3) 0.820(3) 0.8122(9) 0.043(9) Uiso 1 1 d . . .
H34A H 1.153(5) 0.519(5) 0.6026(19) 0.14(3) Uiso 1 1 d . . .
H34B H 1.102(5) 0.425(5) 0.6247(16) 0.12(2) Uiso 1 1 d . . .
H34C H 1.196(4) 0.514(4) 0.6558(15) 0.095(15) Uiso 1 1 d . . .
H35A H 1.141(3) 0.713(3) 0.6704(11) 0.053(10) Uiso 1 1 d . . .
H35B H 1.017(4) 0.767(4) 0.6519(14) 0.092(17) Uiso 1 1 d . . .
H35C H 1.113(4) 0.737(4) 0.6186(14) 0.088(15) Uiso 1 1 d . . .
H36A H 0.933(4) 0.615(3) 0.6924(12) 0.065(14) Uiso 1 1 d . . .
H36B H 1.051(4) 0.547(4) 0.7098(14) 0.086(14) Uiso 1 1 d . . .
H36C H 0.954(6) 0.458(5) 0.6813(18) 0.14(2) Uiso 1 1 d . . .
H38 H 0.718(3) 0.410(3) 0.6295(9) 0.044(9) Uiso 1 1 d . . .
H39 H 0.574(3) 0.409(3) 0.6803(10) 0.049(10) Uiso 1 1 d . . .
H40 H 0.410(4) 0.527(3) 0.6670(12) 0.061(13) Uiso 1 1 d . . .
H41 H 0.373(3) 0.629(3) 0.6087(9) 0.037(9) Uiso 1 1 d . . .
H42 H 0.510(3) 0.623(3) 0.5596(9) 0.034(9) Uiso 1 1 d . . .
H44 H 0.889(3) 0.396(3) 0.4890(10) 0.051(10) Uiso 1 1 d . . .
H45 H 0.863(3) 0.226(3) 0.4480(11) 0.058(12) Uiso 1 1 d . . .
H46 H 0.722(3) 0.098(3) 0.4545(9) 0.041(9) Uiso 1 1 d . . .
H47 H 0.582(3) 0.148(3) 0.5009(11) 0.062(12) Uiso 1 1 d . . .
H48 H 0.596(3) 0.311(3) 0.5379(9) 0.025(8) Uiso 1 1 d . . .
H50 H 0.690(3) 0.550(3) 0.4567(10) 0.055(11) Uiso 1 1 d . . .
H51 H 0.650(3) 0.701(3) 0.4112(11) 0.058(11) Uiso 1 1 d . . .
H52 H 0.642(3) 0.892(3) 0.4355(9) 0.032(8) Uiso 1 1 d . . .
H53 H 0.682(3) 0.931(3) 0.5081(9) 0.036(9) Uiso 1 1 d . . .
H54 H 0.732(2) 0.779(2) 0.5540(9) 0.031(8) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 F1 117.8(3) . . ?
C2 C1 Ge1 128.7(2) . . ?
F1 C1 Ge1 113.46(19) . . ?
C1 C2 F2 112.9(3) . . ?
C1 C2 C3 135.5(3) . . ?
F2 C2 C3 111.5(2) . . ?
C2 C3 C4 112.7(3) . . ?
C2 C3 C5 108.9(3) . . ?
C4 C3 C5 109.7(3) . . ?
C2 C3 C6 107.4(3) . . ?
C4 C3 C6 109.6(4) . . ?
C5 C3 C6 108.4(4) . . ?
C12 C7 C8 117.7(3) . . ?
C12 C7 Ge1 121.0(2) . . ?
C8 C7 Ge1 121.3(2) . . ?
C9 C8 C7 120.3(3) . . ?
C8 C9 C10 120.8(3) . . ?
C9 C10 C11 119.7(3) . . ?
C12 C11 C10 120.2(3) . . ?
C11 C12 C7 121.4(3) . . ?
C14 C13 C18 117.4(3) . . ?
C14 C13 Ge1 120.8(3) . . ?
C18 C13 Ge1 121.8(3) . . ?
C13 C14 C15 121.4(5) . . ?
C16 C15 C14 119.6(5) . . ?
C17 C16 C15 120.4(4) . . ?
C16 C17 C18 120.0(5) . . ?
C13 C18 C17 121.2(4) . . ?
C20 C19 C24 117.6(3) . . ?
C20 C19 Ge1 120.8(2) . . ?
C24 C19 Ge1 121.7(2) . . ?
C19 C20 C21 121.7(3) . . ?
C22 C21 C20 119.7(3) . . ?
C21 C22 C23 119.8(3) . . ?
C22 C23 C24 120.4(3) . . ?
C23 C24 C19 120.9(3) . . ?
C32 C31 F31 118.6(3) . . ?
C32 C31 Ge31 126.7(3) . . ?
F31 C31 Ge31 114.4(2) . . ?
C31 C32 F32 113.4(3) . . ?
C31 C32 C33 135.4(4) . . ?
F32 C32 C33 111.1(3) . . ?
C35 C33 C32 110.4(3) . . ?
C35 C33 C36 110.7(4) . . ?
C32 C33 C36 107.2(3) . . ?
C35 C33 C34 108.6(4) . . ?
C32 C33 C34 110.7(4) . . ?
C36 C33 C34 109.2(5) . . ?
C42 C37 C38 117.7(3) . . ?
C42 C37 Ge31 121.3(2) . . ?
C38 C37 Ge31 120.9(2) . . ?
C39 C38 C37 120.8(3) . . ?
C38 C39 C40 120.4(3) . . ?
C39 C40 C41 120.3(4) . . ?
C40 C41 C42 119.5(4) . . ?
C41 C42 C37 121.3(3) . . ?
C48 C43 C44 117.8(3) . . ?
C48 C43 Ge31 120.9(2) . . ?
C44 C43 Ge31 121.3(2) . . ?
C45 C44 C43 120.8(3) . . ?
C46 C45 C44 120.7(4) . . ?
C45 C46 C47 119.2(3) . . ?
C46 C47 C48 120.6(4) . . ?
C47 C48 C43 120.9(3) . . ?
C50 C49 C54 118.4(3) . . ?
C50 C49 Ge31 120.7(2) . . ?
C54 C49 Ge31 120.8(2) . . ?
C49 C50 C51 120.7(3) . . ?
C52 C51 C50 120.3(3) . . ?
C53 C52 C51 119.8(3) . . ?
C52 C53 C54 120.4(3) . . ?
C53 C54 C49 120.5(3) . . ?
C13 Ge1 C7 110.06(13) . . ?
C13 Ge1 C19 109.67(12) . . ?
C7 Ge1 C19 111.23(12) . . ?
C13 Ge1 C1 109.87(14) . . ?
C7 Ge1 C1 111.56(12) . . ?
C19 Ge1 C1 104.31(12) . . ?
C37 Ge31 C43 110.46(12) . . ?
C37 Ge31 C49 109.80(12) . . ?
C43 Ge31 C49 108.94(12) . . ?
C37 Ge31 C31 107.95(13) . . ?
C43 Ge31 C31 106.54(13) . . ?
C49 Ge31 C31 113.10(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C2 1.304(4) . ?
C1 F1 1.363(3) . ?
C1 Ge1 1.963(3) . ?
C2 F2 1.364(3) . ?
C2 C3 1.517(4) . ?
C3 C4 1.519(5) . ?
C3 C5 1.530(5) . ?
C3 C6 1.547(6) . ?
C7 C12 1.394(4) . ?
C7 C8 1.410(4) . ?
C7 Ge1 1.945(3) . ?
C8 C9 1.376(4) . ?
C9 C10 1.381(5) . ?
C10 C11 1.378(5) . ?
C11 C12 1.375(4) . ?
C13 C14 1.375(5) . ?
C13 C18 1.392(5) . ?
C13 Ge1 1.941(3) . ?
C14 C15 1.396(6) . ?
C15 C16 1.372(8) . ?
C16 C17 1.350(7) . ?
C17 C18 1.394(5) . ?
C19 C20 1.387(4) . ?
C19 C24 1.393(4) . ?
C19 Ge1 1.949(3) . ?
C20 C21 1.384(4) . ?
C21 C22 1.377(5) . ?
C22 C23 1.374(5) . ?
C23 C24 1.387(4) . ?
C31 C32 1.306(5) . ?
C31 F31 1.379(4) . ?
C31 Ge31 1.959(3) . ?
C32 F32 1.371(4) . ?
C32 C33 1.515(5) . ?
C33 C35 1.500(6) . ?
C33 C36 1.521(6) . ?
C33 C34 1.538(7) . ?
C37 C42 1.398(4) . ?
C37 C38 1.402(4) . ?
C37 Ge31 1.944(3) . ?
C38 C39 1.375(5) . ?
C39 C40 1.381(6) . ?
C40 C41 1.380(5) . ?
C41 C42 1.384(5) . ?
C43 C48 1.389(4) . ?
C43 C44 1.397(5) . ?
C43 Ge31 1.943(3) . ?
C44 C45 1.383(5) . ?
C45 C46 1.374(5) . ?
C46 C47 1.378(5) . ?
C47 C48 1.384(4) . ?
C49 C50 1.386(4) . ?
C49 C54 1.399(4) . ?
C49 Ge31 1.946(3) . ?
C50 C51 1.387(4) . ?
C51 C52 1.376(4) . ?
C52 C53 1.376(4) . ?
C53 C54 1.382(4) . ?
