#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/86/4318627.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4318627
loop_
_publ_author_name
'Takashi Komuro'
'Hiroyuki Kawaguchi'
'Kazuyuki Tatsumi'
_publ_contact_author_address
;
Research Center for Materials Science, and Department of Chemistry, 
Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, 
Nagoya 464-8602, Japan,
;
_publ_contact_author_email       ' i45100a@nucc.cc.nagoya-u.ac.jp'
_publ_contact_author_fax         ' +81-52-789-2943'
_publ_contact_author_name        ' Kazuyuki Tatsumi'
_publ_section_title
;
 Synthesis and Reactions of Triphenylsilanethiolato Complexes of
 Manganese(II), Iron(II), Cobalt(II), and Nickel(II)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5083
_journal_page_last               5090
_journal_paper_doi               10.1021/ic025715c
_journal_volume                  41
_journal_year                    2002
_chemical_formula_moiety         'C18 H15 Cu S Si '
_chemical_formula_sum            'C18 H15 Cu S Si'
_chemical_formula_weight         355.01
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                98.06(2)
_cell_angle_beta                 109.63(2)
_cell_angle_gamma                96.91(2)
_cell_formula_units_Z            4
_cell_length_a                   12.308(5)
_cell_length_b                   13.154(2)
_cell_length_c                   11.090(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    296.2
_cell_measurement_theta_max      14.6
_cell_measurement_theta_min      13.0
_cell_volume                     1647.2(10)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalStructure
_computing_publication_material  'CrystalStructure Ver. 2.00'
_computing_structure_refinement  CRYSTALS
_computing_structure_solution    SHELXS97
_diffrn_measurement_device_type  'Rigaku AFC5S'
_diffrn_measurement_method       ω-2θ
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.7107
_diffrn_reflns_av_R_equivalents  0.012
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            6084
_diffrn_standards_decay_%        3.55
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.515
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.431
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_size_max          0.400
_exptl_crystal_size_mid          0.350
_exptl_crystal_size_min          0.200
_refine_diff_density_max         0.43
_refine_diff_density_min         -0.46
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    refall
_refine_ls_number_parameters     409
_refine_ls_number_reflns         3990
_refine_ls_R_factor_gt           0.0360
_refine_ls_shift/su_max          0.0000
_refine_ls_structure_factor_coef F
_refine_ls_weighting_details     'w = 1/[σ²(Fo) + 0.00001|Fo|²]'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0520
_reflns_number_gt                3990
_reflns_number_total             0
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            ic025715c_s1_10.cif
_cod_data_source_block           '[Cu(SSiPh3)]4'
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        'C18 H15 Cu S Si '
_cod_database_code               4318627
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,-y,-z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu(1) Cu 0.53193(4) 0.12848(4) 0.92538(5) 0.0483(1) Uani 1.00 d . . .
Cu(2) Cu 0.53563(4) 0.10456(4) 1.17829(5) 0.0481(1) Uani 1.00 d . . .
S(1) S 0.51929(8) 0.02770(8) 0.74710(9) 0.0449(3) Uani 1.00 d . . .
S(2) S 0.55080(8) 0.24236(7) 1.0959(1) 0.0441(3) Uani 1.00 d . . .
Si(1) Si 0.35448(9) 0.06746(8) 0.63808(9) 0.0370(3) Uani 1.00 d . . .
Si(2) Si 0.72659(9) 0.32133(8) 1.1420(1) 0.0383(3) Uani 1.00 d . . .
C(1) C 0.2874(3) 0.1240(3) 0.7554(4) 0.0381(10) Uani 1.00 d . . .
C(2) C 0.2719(4) 0.2277(3) 0.7704(4) 0.048(1) Uani 1.00 d . . .
C(3) C 0.2330(4) 0.2703(4) 0.8659(4) 0.058(1) Uani 1.00 d . . .
C(4) C 0.2064(4) 0.2105(4) 0.9469(4) 0.061(1) Uani 1.00 d . . .
C(5) C 0.2185(4) 0.1071(4) 0.9342(5) 0.062(1) Uani 1.00 d . . .
C(6) C 0.2578(4) 0.0644(3) 0.8381(4) 0.051(1) Uani 1.00 d . . .
C(7) C 0.2554(3) -0.0497(3) 0.5198(4) 0.041(1) Uani 1.00 d . . .
C(8) C 0.2990(4) -0.1244(4) 0.4568(5) 0.064(1) Uani 1.00 d . . .
C(9) C 0.2241(5) -0.2040(4) 0.3595(5) 0.076(2) Uani 1.00 d . . .
C(10) C 0.1056(5) -0.2105(4) 0.3216(5) 0.070(2) Uani 1.00 d . . .
C(11) C 0.0596(4) -0.1398(5) 0.3810(5) 0.075(2) Uani 1.00 d . . .
C(12) C 0.1352(4) -0.0587(4) 0.4796(5) 0.061(1) Uani 1.00 d . . .
C(13) C 0.3888(3) 0.1678(3) 0.5461(4) 0.043(1) Uani 1.00 d . . .
C(14) C 0.3392(4) 0.1526(3) 0.4103(4) 0.051(1) Uani 1.00 d . . .
C(15) C 0.3674(5) 0.2269(4) 0.3435(5) 0.077(2) Uani 1.00 d . . .
C(16) C 0.4444(5) 0.3169(4) 0.4095(5) 0.078(2) Uani 1.00 d . . .
C(17) C 0.4956(5) 0.3339(4) 0.5425(5) 0.075(2) Uani 1.00 d . . .
C(18) C 0.4677(4) 0.2609(3) 0.6107(4) 0.056(1) Uani 1.00 d . . .
C(19) C 0.7703(3) 0.4136(3) 1.3019(4) 0.043(1) Uani 1.00 d . . .
C(20) C 0.7408(6) 0.3892(5) 1.4045(5) 0.100(2) Uani 1.00 d . . .
C(21) C 0.7759(7) 0.4593(6) 1.5215(7) 0.141(3) Uani 1.00 d . . .
C(22) C 0.8415(6) 0.5540(5) 1.5383(6) 0.089(2) Uani 1.00 d . . .
C(23) C 0.8756(6) 0.5787(4) 1.4414(6) 0.097(2) Uani 1.00 d . . .
C(24) C 0.8414(5) 0.5088(4) 1.3245(5) 0.082(2) Uani 1.00 d . . .
C(25) C 0.7219(4) 0.4009(3) 1.0129(4) 0.046(1) Uani 1.00 d . . .
C(26) C 0.6226(4) 0.4398(3) 0.9512(4) 0.061(1) Uani 1.00 d . . .
C(27) C 0.6223(5) 0.5063(4) 0.8643(5) 0.079(2) Uani 1.00 d . . .
C(28) C 0.7233(5) 0.5353(4) 0.8377(5) 0.075(2) Uani 1.00 d . . .
C(29) C 0.8202(5) 0.4969(4) 0.8961(5) 0.074(2) Uani 1.00 d . . .
C(30) C 0.8202(4) 0.4302(4) 0.9830(5) 0.067(1) Uani 1.00 d . . .
C(31) C 0.8378(3) 0.2350(3) 1.1483(4) 0.044(1) Uani 1.00 d . . .
C(32) C 0.8549(4) 0.1899(3) 1.0366(5) 0.059(1) Uani 1.00 d . . .
C(33) C 0.9444(5) 0.1339(4) 1.0422(6) 0.075(2) Uani 1.00 d . . .
C(34) C 1.0170(5) 0.1209(4) 1.1585(6) 0.080(2) Uani 1.00 d . . .
C(35) C 1.0031(4) 0.1621(4) 1.2723(6) 0.073(2) Uani 1.00 d . . .
C(36) C 0.9135(4) 0.2199(3) 1.2664(4) 0.053(1) Uani 1.00 d . . .
H(1) H 0.2891(4) 0.2706(3) 0.7124(4) 0.058(2) Uiso 1.00 calc . . .
H(2) H 0.2241(4) 0.3429(4) 0.8755(4) 0.070(2) Uiso 1.00 calc . . .
H(3) H 0.1785(4) 0.2409(4) 1.0134(4) 0.073(2) Uiso 1.00 calc . . .
H(4) H 0.1995(4) 0.0646(4) 0.9917(5) 0.074(2) Uiso 1.00 calc . . .
H(5) H 0.2655(4) -0.0085(3) 0.8283(4) 0.061(2) Uiso 1.00 calc . . .
H(6) H 0.3832(4) -0.1196(4) 0.4819(5) 0.076(2) Uiso 1.00 calc . . .
H(7) H 0.2560(5) -0.2554(4) 0.3163(5) 0.091(2) Uiso 1.00 calc . . .
H(8) H 0.0539(5) -0.2666(4) 0.2521(5) 0.084(2) Uiso 1.00 calc . . .
H(9) H -0.0247(4) -0.1451(5) 0.3555(5) 0.086(2) Uiso 1.00 calc . . .
H(10) H 0.1028(4) -0.0071(4) 0.5218(5) 0.072(2) Uiso 1.00 calc . . .
H(11) H 0.2841(4) 0.0889(3) 0.3627(4) 0.061(2) Uiso 1.00 calc . . .
H(12) H 0.3313(5) 0.2152(4) 0.2492(5) 0.089(2) Uiso 1.00 calc . . .
H(13) H 0.4639(5) 0.3685(4) 0.3620(5) 0.093(2) Uiso 1.00 calc . . .
H(14) H 0.5512(5) 0.3976(4) 0.5892(5) 0.090(2) Uiso 1.00 calc . . .
H(15) H 0.5038(4) 0.2734(3) 0.7050(4) 0.067(2) Uiso 1.00 calc . . .
H(16) H 0.6918(6) 0.3222(5) 1.3920(5) 0.118(3) Uiso 1.00 calc . . .
H(17) H 0.7558(7) 0.4389(6) 1.5932(7) 0.165(4) Uiso 1.00 calc . . .
H(18) H 0.8628(6) 0.6044(5) 1.6189(6) 0.105(2) Uiso 1.00 calc . . .
H(19) H 0.9242(6) 0.6459(4) 1.4539(6) 0.105(2) Uiso 1.00 calc . . .
H(20) H 0.8684(5) 0.5263(4) 1.2560(5) 0.091(2) Uiso 1.00 calc . . .
H(21) H 0.5520(4) 0.4199(3) 0.9694(4) 0.072(2) Uiso 1.00 calc . . .
H(22) H 0.5518(5) 0.5329(4) 0.8222(5) 0.092(2) Uiso 1.00 calc . . .
H(23) H 0.7234(5) 0.5825(4) 0.7780(5) 0.084(2) Uiso 1.00 calc . . .
H(24) H 0.8902(5) 0.5155(4) 0.8763(5) 0.088(2) Uiso 1.00 calc . . .
H(25) H 0.8907(4) 0.4033(4) 1.0245(5) 0.080(2) Uiso 1.00 calc . . .
H(26) H 0.8017(4) 0.1975(3) 0.9525(5) 0.071(2) Uiso 1.00 calc . . .
H(27) H 0.9550(5) 0.1039(4) 0.9628(6) 0.089(2) Uiso 1.00 calc . . .
H(28) H 1.0806(5) 0.0829(4) 1.1625(6) 0.092(2) Uiso 1.00 calc . . .
H(29) H 1.0543(4) 0.1510(4) 1.3556(6) 0.086(2) Uiso 1.00 calc . . .
H(30) H 0.9033(4) 0.2495(3) 1.3462(4) 0.063(2) Uiso 1.00 calc . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.003 0.002
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
H H 0.000 0.000
;International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.2)
;
Si Si 0.082 0.070
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
S S 0.125 0.123
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
Cu Cu 0.320 1.265
;International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.1)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
S(1) Cu(1) S(2) 174.19(5) . . . yes
S(1) Cu(2) S(2) 167.13(5) 2_657 . . yes
Cu(1) S(1) Cu(2) 88.79(5) . . 2_657 yes
Cu(1) S(1) Si(1) 92.56(5) . . . yes
Cu(2) S(1) Si(1) 102.26(5) 2_657 . . yes
Cu(1) S(2) Cu(2) 82.50(4) . . . yes
Cu(1) S(2) Si(2) 100.03(6) . . . yes
Cu(2) S(2) Si(2) 115.10(5) . . . yes
S(1) Si(1) C(1) 108.9(1) . . . yes
S(1) Si(1) C(7) 110.4(1) . . . yes
S(1) Si(1) C(13) 106.4(1) . . . yes
C(1) Si(1) C(7) 111.8(2) . . . yes
C(1) Si(1) C(13) 110.0(2) . . . yes
C(7) Si(1) C(13) 109.2(2) . . . yes
S(2) Si(2) C(19) 107.7(1) . . . yes
S(2) Si(2) C(25) 106.6(1) . . . yes
S(2) Si(2) C(31) 115.5(1) . . . yes
C(19) Si(2) C(25) 107.9(2) . . . yes
C(19) Si(2) C(31) 110.1(2) . . . yes
C(25) Si(2) C(31) 108.7(2) . . . yes
Si(1) C(1) C(2) 122.5(3) . . . yes
Si(1) C(1) C(6) 120.4(3) . . . yes
C(2) C(1) C(6) 117.0(4) . . . yes
C(1) C(2) C(3) 121.4(4) . . . yes
C(2) C(3) C(4) 120.4(4) . . . yes
C(3) C(4) C(5) 120.3(5) . . . yes
C(4) C(5) C(6) 119.3(5) . . . yes
C(1) C(6) C(5) 121.7(4) . . . yes
Si(1) C(7) C(8) 121.3(3) . . . yes
Si(1) C(7) C(12) 121.0(3) . . . yes
C(8) C(7) C(12) 117.2(3) . . . yes
C(7) C(8) C(9) 120.6(5) . . . yes
C(8) C(9) C(10) 120.8(6) . . . yes
C(9) C(10) C(11) 120.4(4) . . . yes
C(10) C(11) C(12) 119.0(5) . . . yes
C(7) C(12) C(11) 122.0(5) . . . yes
Si(1) C(13) C(14) 121.9(3) . . . yes
Si(1) C(13) C(18) 121.2(3) . . . yes
C(14) C(13) C(18) 117.0(4) . . . yes
C(13) C(14) C(15) 121.1(4) . . . yes
C(14) C(15) C(16) 120.4(4) . . . yes
C(15) C(16) C(17) 120.1(6) . . . yes
C(16) C(17) C(18) 120.2(4) . . . yes
C(13) C(18) C(17) 121.2(4) . . . yes
Si(2) C(19) C(20) 123.1(3) . . . yes
Si(2) C(19) C(24) 120.4(4) . . . yes
C(20) C(19) C(24) 116.4(4) . . . yes
C(19) C(20) C(21) 121.2(6) . . . yes
C(20) C(21) C(22) 120.7(8) . . . yes
C(21) C(22) C(23) 119.4(6) . . . yes
C(22) C(23) C(24) 120.1(5) . . . yes
C(19) C(24) C(23) 121.9(6) . . . yes
Si(2) C(25) C(26) 121.2(4) . . . yes
Si(2) C(25) C(30) 121.5(3) . . . yes
C(26) C(25) C(30) 117.1(4) . . . yes
C(25) C(26) C(27) 121.3(5) . . . yes
C(26) C(27) C(28) 120.2(5) . . . yes
C(27) C(28) C(29) 119.1(5) . . . yes
C(28) C(29) C(30) 120.6(6) . . . yes
C(25) C(30) C(29) 121.8(5) . . . yes
Si(2) C(31) C(32) 121.9(3) . . . yes
Si(2) C(31) C(36) 121.1(3) . . . yes
C(32) C(31) C(36) 116.8(4) . . . yes
C(31) C(32) C(33) 122.0(4) . . . yes
C(32) C(33) C(34) 119.9(6) . . . yes
C(33) C(34) C(35) 120.7(5) . . . yes
C(34) C(35) C(36) 119.2(5) . . . yes
C(31) C(36) C(35) 121.4(5) . . . yes
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu(1) S(1) 2.168(1) . . yes
Cu(1) S(2) 2.168(1) . . yes
Cu(2) S(1) 2.160(1) . 2_657 yes
Cu(2) S(2) 2.157(1) . . yes
S(1) Si(1) 2.153(2) . . yes
S(2) Si(2) 2.142(2) . . yes
Si(1) C(1) 1.877(4) . . yes
Si(1) C(7) 1.868(3) . . yes
Si(1) C(13) 1.869(4) . . yes
Si(2) C(19) 1.873(4) . . yes
Si(2) C(25) 1.879(4) . . yes
Si(2) C(31) 1.871(4) . . yes
C(1) C(2) 1.395(6) . . yes
C(1) C(6) 1.395(6) . . yes
C(2) C(3) 1.379(7) . . yes
C(3) C(4) 1.366(8) . . yes
C(4) C(5) 1.379(7) . . yes
C(5) C(6) 1.389(7) . . yes
C(7) C(8) 1.389(7) . . yes
C(7) C(12) 1.378(6) . . yes
C(8) C(9) 1.376(6) . . yes
C(9) C(10) 1.363(8) . . yes
C(10) C(11) 1.351(9) . . yes
C(11) C(12) 1.396(6) . . yes
C(13) C(14) 1.396(5) . . yes
C(13) C(18) 1.399(5) . . yes
C(14) C(15) 1.385(8) . . yes
C(15) C(16) 1.362(7) . . yes
C(16) C(17) 1.368(8) . . yes
C(17) C(18) 1.383(8) . . yes
C(19) C(20) 1.371(9) . . yes
C(19) C(24) 1.378(6) . . yes
C(20) C(21) 1.383(9) . . yes
C(21) C(22) 1.35(1) . . yes
C(22) C(23) 1.34(1) . . yes
C(23) C(24) 1.382(7) . . yes
C(25) C(26) 1.383(6) . . yes
C(25) C(30) 1.384(8) . . yes
C(26) C(27) 1.388(7) . . yes
C(27) C(28) 1.393(9) . . yes
C(28) C(29) 1.347(8) . . yes
C(29) C(30) 1.391(8) . . yes
C(31) C(32) 1.388(7) . . yes
C(31) C(36) 1.386(6) . . yes
C(32) C(33) 1.386(8) . . yes
C(33) C(34) 1.347(8) . . yes
C(34) C(35) 1.376(9) . . yes
C(35) C(36) 1.402(7) . . yes
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_site_symmetry_1
_geom_contact_site_symmetry_2
_geom_contact_publ_flag
Cu(2) C(15) 3.572(6) . 1_556 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cu(1) S(1) Cu(2) S(2) -103.9(2) . . 2_657 2_657 yes
Cu(1) S(1) Si(1) C(1) -19.0(1) . . . . yes
Cu(1) S(1) Si(1) C(7) -142.0(2) . . . . yes
Cu(1) S(1) Si(1) C(13) 99.6(1) . . . . yes
Cu(1) S(2) Cu(2) S(1) -102.3(2) . . . 2_657 yes
Cu(1) S(2) Si(2) C(19) -172.6(1) . . . . yes
Cu(1) S(2) Si(2) C(25) 71.8(1) . . . . yes
Cu(1) S(2) Si(2) C(31) -49.1(2) . . . . yes
Cu(2) S(1) Cu(1) S(2) -177.9(4) . 2_657 2_657 2_657 yes
Cu(2) S(1) Si(1) C(1) -70.3(1) . 2_657 2_657 2_657 yes
Cu(2) S(1) Si(1) C(7) 52.7(2) . 2_657 2_657 2_657 yes
Cu(2) S(1) Si(1) C(13) 171.1(1) . 2_657 2_657 2_657 yes
Cu(2) S(2) Cu(1) S(1) -165.3(4) . . . . yes
Cu(2) S(2) Si(2) C(19) -86.3(1) . . . . yes
Cu(2) S(2) Si(2) C(25) 158.1(1) . . . . yes
Cu(2) S(2) Si(2) C(31) 37.2(2) . . . . yes
S(1) Cu(1) S(2) Si(2) -51.0(4) . . . . yes
S(1) Cu(2) S(2) Si(2) -160.1(2) . 2_657 2_657 2_657 yes
S(1) Si(1) C(1) C(2) 114.1(3) . . . . yes
S(1) Si(1) C(1) C(6) -61.7(3) . . . . yes
S(1) Si(1) C(7) C(8) -35.6(4) . . . . yes
S(1) Si(1) C(7) C(12) 152.6(4) . . . . yes
S(1) Si(1) C(13) C(14) 122.1(4) . . . . yes
S(1) Si(1) C(13) C(18) -56.7(4) . . . . yes
S(2) Cu(1) S(1) Si(1) -79.9(4) . . . . yes
S(2) Cu(2) S(1) Si(1) -163.8(2) . . 2_657 2_657 yes
S(2) Si(2) C(19) C(20) 39.7(5) . . . . yes
S(2) Si(2) C(19) C(24) -144.5(4) . . . . yes
S(2) Si(2) C(25) C(26) 29.5(3) . . . . yes
S(2) Si(2) C(25) C(30) -155.8(3) . . . . yes
S(2) Si(2) C(31) C(32) 83.5(4) . . . . yes
S(2) Si(2) C(31) C(36) -101.7(3) . . . . yes
Si(1) C(1) C(2) C(3) -173.6(3) . . . . yes
Si(1) C(1) C(6) C(5) 173.8(3) . . . . yes
Si(1) C(7) C(8) C(9) -172.8(4) . . . . yes
Si(1) C(7) C(12) C(11) 172.9(4) . . . . yes
Si(1) C(13) C(14) C(15) -178.7(4) . . . . yes
Si(1) C(13) C(18) C(17) 178.2(4) . . . . yes
Si(2) C(19) C(20) C(21) 179.3(6) . . . . yes
Si(2) C(19) C(24) C(23) -179.8(5) . . . . yes
Si(2) C(25) C(26) C(27) 174.2(3) . . . . yes
Si(2) C(25) C(30) C(29) -174.1(3) . . . . yes
Si(2) C(31) C(32) C(33) 173.9(4) . . . . yes
Si(2) C(31) C(36) C(35) -174.8(4) . . . . yes
C(1) Si(1) C(7) C(8) -156.9(4) . . . . yes
C(1) Si(1) C(7) C(12) 31.3(4) . . . . yes
C(1) Si(1) C(13) C(14) -120.1(4) . . . . yes
C(1) Si(1) C(13) C(18) 61.1(4) . . . . yes
C(1) C(2) C(3) C(4) -1.4(6) . . . . yes
C(1) C(6) C(5) C(4) 1.2(6) . . . . yes
C(2) C(1) Si(1) C(7) -123.7(3) . . . . yes
C(2) C(1) Si(1) C(13) -2.1(3) . . . . yes
C(2) C(1) C(6) C(5) -2.2(5) . . . . yes
C(2) C(3) C(4) C(5) 0.2(6) . . . . yes
C(3) C(2) C(1) C(6) 2.3(5) . . . . yes
C(3) C(4) C(5) C(6) -0.2(6) . . . . yes
C(6) C(1) Si(1) C(7) 60.5(3) . . . . yes
C(6) C(1) Si(1) C(13) -177.9(3) . . . . yes
C(7) Si(1) C(13) C(14) 3.0(4) . . . . yes
C(7) Si(1) C(13) C(18) -175.8(4) . . . . yes
C(7) C(8) C(9) C(10) 0.9(9) . . . . yes
C(7) C(12) C(11) C(10) -1.2(9) . . . . yes
C(8) C(7) Si(1) C(13) 81.1(4) . . . . yes
C(8) C(7) C(12) C(11) 0.8(8) . . . . yes
C(8) C(9) C(10) C(11) -1.3(9) . . . . yes
C(9) C(8) C(7) C(12) -0.6(8) . . . . yes
C(9) C(10) C(11) C(12) 1.4(9) . . . . yes
C(12) C(7) Si(1) C(13) -90.8(4) . . . . yes
C(13) C(14) C(15) C(16) -0.2(9) . . . . yes
C(13) C(18) C(17) C(16) 1.2(9) . . . . yes
C(14) C(13) C(18) C(17) -0.6(7) . . . . yes
C(14) C(15) C(16) C(17) 0.8(9) . . . . yes
C(15) C(14) C(13) C(18) 0.1(7) . . . . yes
C(15) C(16) C(17) C(18) -1.3(9) . . . . yes
C(19) Si(2) C(25) C(26) -85.9(3) . . . . yes
C(19) Si(2) C(25) C(30) 88.7(4) . . . . yes
C(19) Si(2) C(31) C(32) -154.3(3) . . . . yes
C(19) Si(2) C(31) C(36) 20.6(4) . . . . yes
C(19) C(20) C(21) C(22) 0(1) . . . . yes
C(19) C(24) C(23) C(22) 1.3(10) . . . . yes
C(20) C(19) Si(2) C(25) 154.4(4) . . . . yes
C(20) C(19) Si(2) C(31) -87.1(5) . . . . yes
C(20) C(19) C(24) C(23) -3.7(8) . . . . yes
C(20) C(21) C(22) C(23) -1(1) . . . . yes
C(21) C(20) C(19) C(24) 3.3(9) . . . . yes
C(21) C(22) C(23) C(24) 1(1) . . . . yes
C(24) C(19) Si(2) C(25) -29.8(4) . . . . yes
C(24) C(19) Si(2) C(31) 88.7(4) . . . . yes
C(25) Si(2) C(31) C(32) -36.2(4) . . . . yes
C(25) Si(2) C(31) C(36) 138.6(3) . . . . yes
C(25) C(26) C(27) C(28) -0.1(6) . . . . yes
C(25) C(30) C(29) C(28) 0.0(7) . . . . yes
C(26) C(25) Si(2) C(31) 154.7(3) . . . . yes
C(26) C(25) C(30) C(29) 0.8(6) . . . . yes
C(26) C(27) C(28) C(29) 0.9(7) . . . . yes
C(27) C(26) C(25) C(30) -0.7(6) . . . . yes
C(27) C(28) C(29) C(30) -0.8(7) . . . . yes
C(30) C(25) Si(2) C(31) -30.6(4) . . . . yes
C(31) C(32) C(33) C(34) 0.8(8) . . . . yes
C(31) C(36) C(35) C(34) 0.9(7) . . . . yes
C(32) C(31) C(36) C(35) 0.3(6) . . . . yes
C(32) C(33) C(34) C(35) 0.5(8) . . . . yes
C(33) C(32) C(31) C(36) -1.1(6) . . . . yes
C(33) C(34) C(35) C(36) -1.3(8) . . . . yes
C(33) C(34) C(35) C(36) -1.3(8) . . . . yes
