#------------------------------------------------------------------------------
#$Date: 2016-03-23 04:00:17 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179273 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/93/4319341.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4319341
loop_
_publ_author_name
'Cristina M. P. Ferreira'
'M. Fátima C. Guedes da Silva'
'João J. R. Fraústo da Silva'
'Armando J. L. Pombeiro'
'Vadim Yu. Kukushkin'
'Rino A. Michelin'
_publ_section_title
;
 Azametallacycles from Ag(I)- or Cu(II)-Promoted Coupling Reactions of
 Dialkylcyanamides with Oximes at Pt(II)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1134
_journal_page_last               1142
_journal_paper_doi               10.1021/ic000553a
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C46 H50 B2 F8 N4 P2 Pt'
_chemical_formula_weight         1089.55
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.10(3)
_cell_angle_beta                 100.87(3)
_cell_angle_gamma                93.88(3)
_cell_formula_units_Z            2
_cell_length_a                   12.154(2)
_cell_length_b                   12.569(3)
_cell_length_c                   16.013(3)
_cell_measurement_temperature    293(2)
_cell_volume                     2334.3(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.855
_diffrn_measured_fraction_theta_max 0.855
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54179
_diffrn_reflns_av_R_equivalents  0.0124
_diffrn_reflns_av_sigmaI/netI    0.0163
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            5305
_diffrn_reflns_theta_full        55.05
_diffrn_reflns_theta_max         55.05
_diffrn_reflns_theta_min         3.62
_exptl_absorpt_coefficient_mu    6.862
_exptl_absorpt_correction_T_max  0.706
_exptl_absorpt_correction_T_min  0.210
_exptl_absorpt_correction_type   numeric
_exptl_crystal_density_diffrn    1.550
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1088
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.924
_refine_diff_density_min         -0.801
_refine_diff_density_rms         0.093
_refine_ls_extinction_coef       0.00050(8)
_refine_ls_extinction_expression Fc^*^=3DkFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   1.081
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     511
_refine_ls_number_reflns         5019
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.0351
_refine_ls_R_factor_obs          0.0351
_refine_ls_shift/su_max          0.490
_refine_ls_shift/su_mean         0.012
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=3D1/[σ²(Fo²)+(0.0527P)²+9.4133P] where P=3D(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0946
_refine_ls_wR_factor_obs         0.0946
_reflns_number_gt                5019
_reflns_number_total             5019
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic000553a_1.cif
_cod_data_source_block           vk8
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=3D1/[\s^2^(Fo^2^)+(0.0527P)^2^+9.4133P] where P=3D(Fo^2^+2Fc^2^)/3'
was changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=3D1/[\s^2^(Fo^2^)+(0.0527P)^2^+9.4133P] where
P=3D(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2334.3(8)
_cod_database_code               4319341
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt 0.18268(2) 0.15859(2) 0.244215(19) 0.03962(15) Uani 1 d . . .
P1 P 0.09449(14) 0.09800(13) 0.34006(11) 0.0389(4) Uani 1 d . . .
P2 P 0.29711(14) 0.29675(13) 0.34416(12) 0.0411(4) Uani 1 d . . .
N1 N 0.2538(5) 0.2148(5) 0.1523(4) 0.0572(16) Uani 1 d . . .
N2 N 0.3723(8) 0.3107(7) 0.0780(7) 0.105(3) Uani 1 d . . .
N3 N 0.1025(6) 0.0305(6) 0.1444(4) 0.0593(17) Uani 1 d . . .
N4 N 0.0986(9) -0.1477(7) 0.0487(6) 0.105(3) Uani 1 d . . .
C1 C -0.0116(6) -0.0195(6) 0.2919(4) 0.0464(17) Uani 1 d . . .
C2 C 0.0041(8) -0.1227(7) 0.3050(6) 0.068(2) Uani 1 d . . .
C3 C -0.0810(10) -0.2093(8) 0.2687(7) 0.087(3) Uani 1 d . . .
C4 C -0.1801(10) -0.1919(10) 0.2204(7) 0.093(4) Uani 1 d . . .
C5 C -0.1986(8) -0.0884(10) 0.2078(6) 0.082(3) Uani 1 d . . .
C6 C -0.1141(7) -0.0020(7) 0.2437(6) 0.066(2) Uani 1 d . . .
C7 C 0.0118(5) 0.1975(5) 0.3908(5) 0.0417(16) Uani 1 d . . .
C8 C -0.0048(6) 0.2914(6) 0.3603(5) 0.0505(18) Uani 1 d . . .
C9 C -0.0684(7) 0.3677(7) 0.3972(7) 0.071(3) Uani 1 d . . .
C10 C -0.1148(8) 0.3505(8) 0.4661(7) 0.076(3) Uani 1 d . . .
C11 C -0.1032(7) 0.2545(8) 0.4946(6) 0.071(2) Uani 1 d . . .
C12 C -0.0416(6) 0.1765(6) 0.4555(5) 0.056(2) Uani 1 d . . .
C13 C 0.1938(5) 0.0521(5) 0.4204(4) 0.0408(16) Uani 1 d . . .
C14 C 0.1971(6) 0.0750(6) 0.5094(5) 0.0506(18) Uani 1 d . . .
C15 C 0.2780(7) 0.0338(7) 0.5649(5) 0.063(2) Uani 1 d . . .
C16 C 0.3521(7) -0.0310(8) 0.5305(6) 0.070(2) Uani 1 d . . .
C17 C 0.3501(7) -0.0545(7) 0.4428(6) 0.063(2) Uani 1 d . . .
C18 C 0.2722(6) -0.0118(6) 0.3873(5) 0.0508(18) Uani 1 d . . .
C19 C 0.2626(6) 0.4309(6) 0.3297(5) 0.0482(18) Uani 1 d . . .
C20 C 0.3181(6) 0.5245(6) 0.3890(6) 0.058(2) Uani 1 d . . .
C21 C 0.2966(8) 0.6276(6) 0.3757(7) 0.071(3) Uani 1 d . . .
C22 C 0.2179(9) 0.6360(7) 0.3039(8) 0.084(3) Uani 1 d . . .
C23 C 0.1594(9) 0.5452(8) 0.2465(7) 0.083(3) Uani 1 d . . .
C24 C 0.1816(7) 0.4413(7) 0.2589(6) 0.060(2) Uani 1 d . . .
C25 C 0.4371(6) 0.2813(6) 0.3213(5) 0.0455(17) Uani 1 d . . .
C26 C 0.5130(7) 0.3693(6) 0.3234(6) 0.068(2) Uani 1 d . . .
C27 C 0.6178(8) 0.3517(8) 0.3037(8) 0.088(3) Uani 1 d . . .
C28 C 0.6469(7) 0.2485(8) 0.2820(6) 0.073(2) Uani 1 d . . .
C29 C 0.5729(7) 0.1596(7) 0.2805(6) 0.061(2) Uani 1 d . . .
C30 C 0.4681(6) 0.1767(6) 0.2990(5) 0.0525(19) Uani 1 d . . .
C31 C 0.3150(6) 0.3089(5) 0.4608(5) 0.0443(17) Uani 1 d . . .
C32 C 0.4050(6) 0.2679(6) 0.5073(5) 0.0513(18) Uani 1 d . . .
C33 C 0.4183(7) 0.2796(7) 0.5967(5) 0.060(2) Uani 1 d . . .
C34 C 0.3424(7) 0.3305(7) 0.6408(5) 0.061(2) Uani 1 d . . .
C35 C 0.2525(7) 0.3705(6) 0.5964(5) 0.060(2) Uani 1 d . . .
C36 C 0.2376(6) 0.3599(6) 0.5060(5) 0.0513(18) Uani 1 d . . .
C37 C 0.3108(7) 0.2588(7) 0.1188(6) 0.064(2) Uani 1 d . . .
C38 C 0.3412(19) 0.4361(19) 0.0602(15) 0.194(8) Uiso 1 d . . .
C39 C 0.420(2) 0.492(2) 0.1250(16) 0.212(9) Uiso 1 d . . .
C40 C 0.4648(13) 0.2618(13) 0.0384(10) 0.129(5) Uiso 1 d . . .
C41 C 0.4653(13) 0.1438(13) 0.0350(10) 0.137(5) Uiso 1 d . . .
C42 C 0.1042(7) -0.0532(8) 0.1010(6) 0.067(2) Uani 1 d . . .
C43 C 0.1583(14) -0.1653(14) -0.0271(11) 0.144(5) Uiso 1 d . . .
C44 C 0.2182(15) -0.0750(15) -0.0360(12) 0.157(6) Uiso 1 d . . .
C45 C 0.0626(16) -0.2614(15) 0.0793(12) 0.155(6) Uiso 1 d . . .
C46 C -0.040(2) -0.2918(18) 0.0225(15) 0.196(8) Uiso 1 d . . .
B1 B 0.5717(12) 0.1448(12) -0.2003(9) 0.089(3) Uiso 1 d . . .
F1 F 0.5120(9) 0.0957(9) -0.2818(7) 0.089(3) Uiso 0.50 d P . .
F2 F 0.506(2) 0.224(2) -0.1729(16) 0.199(9) Uiso 0.50 d P . .
F3 F 0.682(2) 0.171(2) -0.2021(17) 0.204(9) Uiso 0.50 d P . .
F4 F 0.576(2) 0.0673(17) -0.1508(14) 0.171(7) Uiso 0.50 d P . .
F1A F 0.6485(13) 0.0674(12) -0.1819(10) 0.118(4) Uiso 0.50 d P . .
F2A F 0.6065(17) 0.2283(16) -0.1219(13) 0.160(6) Uiso 0.50 d P . .
F3A F 0.478(3) 0.117(3) -0.1769(19) 0.239(11) Uiso 0.50 d P . .
F4A F 0.615(2) 0.202(2) -0.2499(16) 0.192(8) Uiso 0.50 d P . .
B2 B 0.1751(13) -0.4567(13) -0.1637(10) 0.101(4) Uiso 1 d . . .
F5 F 0.0953(18) -0.4617(17) -0.1158(13) 0.152(7) Uiso 0.50 d P . .
F6 F 0.1058(14) -0.5176(12) -0.2531(10) 0.116(5) Uiso 0.50 d P . .
F7 F 0.2660(19) -0.5194(18) -0.1624(14) 0.178(7) Uiso 0.50 d P . .
F8 F 0.1980(18) -0.3570(16) -0.1752(12) 0.151(6) Uiso 0.50 d P . .
F5A F 0.2701(15) -0.4021(15) -0.1172(12) 0.145(5) Uiso 0.50 d P . .
F6A F 0.1055(18) -0.3689(16) -0.1843(13) 0.161(6) Uiso 0.50 d P . .
F7A F 0.1365(17) -0.5005(16) -0.1021(13) 0.141(6) Uiso 0.50 d P . .
F8A F 0.1716(18) -0.5273(15) -0.2324(13) 0.144(6) Uiso 0.50 d P . .
H2 H 0.0783 -0.1435 0.3370 0.085 Uiso 1 d . . .
H3 H -0.0534 -0.2791 0.2978 0.085 Uiso 1 d . . .
H4 H -0.2369 -0.2563 0.1985 0.085 Uiso 1 d . . .
H5 H -0.2873 -0.0636 0.1701 0.085 Uiso 1 d . . .
H6 H -0.1327 0.0653 0.2264 0.085 Uiso 1 d . . .
H8 H 0.0344 0.2869 0.3103 0.085 Uiso 1 d . . .
H9 H -0.0714 0.4439 0.3856 0.085 Uiso 1 d . . .
H10 H -0.1627 0.4077 0.4913 0.085 Uiso 1 d . . .
H11 H -0.1576 0.2377 0.5360 0.085 Uiso 1 d . . .
H12 H -0.0094 0.1368 0.5020 0.085 Uiso 1 d . . .
H14 H 0.1350 0.1133 0.5293 0.085 Uiso 1 d . . .
H15 H 0.2802 0.0608 0.6346 0.085 Uiso 1 d . . .
H16 H 0.3984 -0.0437 0.5760 0.085 Uiso 1 d . . .
H17 H 0.4263 -0.0680 0.4245 0.085 Uiso 1 d . . .
H18 H 0.2609 -0.0418 0.3265 0.085 Uiso 1 d . . .
H20 H 0.3883 0.5183 0.4437 0.085 Uiso 1 d . . .
H21 H 0.3416 0.6882 0.4403 0.085 Uiso 1 d . . .
H22 H 0.2033 0.7073 0.2930 0.085 Uiso 1 d . . .
H23 H 0.0945 0.5398 0.1964 0.085 Uiso 1 d . . .
H24 H 0.1312 0.3684 0.2143 0.085 Uiso 1 d . . .
H26 H 0.5010 0.4344 0.3428 0.085 Uiso 1 d . . .
H27 H 0.6724 0.4243 0.3038 0.085 Uiso 1 d . . .
H28 H 0.7002 0.2293 0.2413 0.085 Uiso 1 d . . .
H29 H 0.5930 0.0745 0.2631 0.085 Uiso 1 d . . .
H30 H 0.4087 0.1083 0.2961 0.085 Uiso 1 d . . .
H32 H 0.4718 0.2328 0.4763 0.085 Uiso 1 d . . .
H33 H 0.4822 0.2469 0.6429 0.085 Uiso 1 d . . .
H34 H 0.3776 0.3396 0.7162 0.085 Uiso 1 d . . .
H35 H 0.1884 0.4136 0.6242 0.085 Uiso 1 d . . .
H36 H 0.1786 0.4048 0.4804 0.085 Uiso 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N3 Pt N1 86.7(3) . . ?
N3 Pt P1 91.59(18) . . ?
N1 Pt P1 176.51(19) . . ?
N3 Pt P2 170.34(18) . . ?
N1 Pt P2 85.97(19) . . ?
P1 Pt P2 96.06(7) . . ?
C13 P1 C7 111.7(3) . . ?
C13 P1 C1 104.6(3) . . ?
C7 P1 C1 101.5(3) . . ?
C13 P1 Pt 110.7(2) . . ?
C7 P1 Pt 113.0(2) . . ?
C1 P1 Pt 114.7(2) . . ?
C31 P2 C19 103.8(3) . . ?
C31 P2 C25 105.0(3) . . ?
C19 P2 C25 107.4(3) . . ?
C31 P2 Pt 122.8(2) . . ?
C19 P2 Pt 112.3(3) . . ?
C25 P2 Pt 104.6(2) . . ?
C37 N1 Pt 163.7(7) . . ?
C37 N2 C40 123.0(10) . . ?
C37 N2 C38 119.9(10) . . ?
C40 N2 C38 116.9(11) . . ?
C42 N3 Pt 149.4(7) . . ?
C42 N4 C43 122.3(10) . . ?
C42 N4 C45 120.3(9) . . ?
C43 N4 C45 114.4(11) . . ?
C2 C1 C6 119.3(7) . . ?
C2 C1 P1 122.5(6) . . ?
C6 C1 P1 118.2(6) . . ?
C1 C2 C3 120.3(9) . . ?
C4 C3 C2 120.0(9) . . ?
C3 C4 C5 120.7(8) . . ?
C4 C5 C6 119.4(9) . . ?
C5 C6 C1 120.2(9) . . ?
C12 C7 C8 119.5(6) . . ?
C12 C7 P1 120.5(5) . . ?
C8 C7 P1 119.8(5) . . ?
C9 C8 C7 120.9(7) . . ?
C8 C9 C10 119.5(8) . . ?
C9 C10 C11 120.2(7) . . ?
C10 C11 C12 119.9(8) . . ?
C7 C12 C11 119.7(7) . . ?
C14 C13 C18 119.2(7) . . ?
C14 C13 P1 125.5(5) . . ?
C18 C13 P1 115.3(5) . . ?
C13 C14 C15 120.0(7) . . ?
C16 C15 C14 119.6(8) . . ?
C15 C16 C17 121.2(8) . . ?
C16 C17 C18 119.8(8) . . ?
C17 C18 C13 120.2(7) . . ?
C20 C19 C24 119.3(7) . . ?
C20 C19 P2 120.1(6) . . ?
C24 C19 P2 120.7(6) . . ?
C19 C20 C21 120.4(8) . . ?
C22 C21 C20 119.4(8) . . ?
C23 C22 C21 121.2(8) . . ?
C22 C23 C24 119.7(9) . . ?
C19 C24 C23 120.0(8) . . ?
C26 C25 C30 118.5(7) . . ?
C26 C25 P2 122.8(5) . . ?
C30 C25 P2 118.6(5) . . ?
C25 C26 C27 120.0(7) . . ?
C28 C27 C26 120.7(8) . . ?
C27 C28 C29 120.2(8) . . ?
C28 C29 C30 119.2(7) . . ?
C29 C30 C25 121.4(7) . . ?
C32 C31 C36 118.7(7) . . ?
C32 C31 P2 121.2(5) . . ?
C36 C31 P2 120.1(6) . . ?
C33 C32 C31 120.3(7) . . ?
C34 C33 C32 120.7(7) . . ?
C35 C34 C33 120.1(7) . . ?
C34 C35 C36 120.2(7) . . ?
C31 C36 C35 120.0(7) . . ?
N1 C37 N2 177.3(10) . . ?
C39 C38 N2 94.6(18) . . ?
C41 C40 N2 113.4(12) . . ?
N3 C42 N4 175.7(11) . . ?
C44 C43 N4 115.3(15) . . ?
C46 C45 N4 98.0(15) . . ?
F3A B1 F4A 143(2) . . ?
F3A B1 F3 164(2) . . ?
F4A B1 F3 50.9(14) . . ?
F3A B1 F4 63.6(16) . . ?
F4A B1 F4 153(2) . . ?
F3 B1 F4 103.8(18) . . ?
F3A B1 F2 60.3(16) . . ?
F4A B1 F2 93.3(17) . . ?
F3 B1 F2 121.0(19) . . ?
F4 B1 F2 111.1(18) . . ?
F3A B1 F1 83.2(16) . . ?
F4A B1 F1 77.8(14) . . ?
F3 B1 F1 110.7(16) . . ?
F4 B1 F1 107.4(14) . . ?
F2 B1 F1 102.3(15) . . ?
F3A B1 F1A 107.7(19) . . ?
F4A B1 F1A 107.1(16) . . ?
F3 B1 F1A 62.9(13) . . ?
F4 B1 F1A 45.6(11) . . ?
F2 B1 F1A 150.4(17) . . ?
F1 B1 F1A 102.7(12) . . ?
F3A B1 F2A 91.1(18) . . ?
F4A B1 F2A 94.5(16) . . ?
F3 B1 F2A 78.8(15) . . ?
F4 B1 F2A 89.2(14) . . ?
F2 B1 F2A 56.5(12) . . ?
F1 B1 F2A 157.5(15) . . ?
F1A B1 F2A 99.8(13) . . ?
B1 F1 F3A 47.2(11) . . ?
B1 F1 F4A 50.3(10) . . ?
F3A F1 F4A 92.6(14) . . ?
F2A F2 F3A 94(2) . . ?
F2A F2 B1 64.0(15) . . ?
F3A F2 B1 57.6(17) . . ?
F4A F3 B1 63.1(18) . . ?
F4A F3 F1A 116(3) . . ?
B1 F3 F1A 60.8(14) . . ?
F4A F3 F2A 85(2) . . ?
B1 F3 F2A 52.3(12) . . ?
F1A F3 F2A 84.7(16) . . ?
F1A F4 B1 69.7(16) . . ?
F1A F4 F3A 124(2) . . ?
B1 F4 F3A 55.9(15) . . ?
F4 F1A B1 64.6(15) . . ?
F4 F1A F3 115(2) . . ?
B1 F1A F3 56.3(12) . . ?
F2 F2A B1 59.5(14) . . ?
F2 F2A F3 99.2(18) . . ?
B1 F2A F3 48.9(11) . . ?
B1 F3A F2 62.1(18) . . ?
B1 F3A F4 60.5(17) . . ?
F2 F3A F4 110(3) . . ?
B1 F3A F1 49.6(13) . . ?
F2 F3A F1 85(2) . . ?
F4 F3A F1 86.8(19) . . ?
F3 F4A B1 66.0(19) . . ?
F3 F4A F1 102(2) . . ?
B1 F4A F1 52.0(11) . . ?
F8A B2 F5A 121.8(18) . . ?
F8A B2 F8 110.8(17) . . ?
F5A B2 F8 63.8(13) . . ?
F8A B2 F5 121.0(18) . . ?
F5A B2 F5 112.4(17) . . ?
F8 B2 F5 112.5(18) . . ?
F8A B2 F7A 112.0(17) . . ?
F5A B2 F7A 100.5(15) . . ?
F8 B2 F7A 136.0(18) . . ?
F5 B2 F7A 32.4(11) . . ?
F8A B2 F7 64.8(14) . . ?
F5A B2 F7 66.9(13) . . ?
F8 B2 F7 114.3(17) . . ?
F5 B2 F7 124.9(18) . . ?
F7A B2 F7 92.6(16) . . ?
F8A B2 F6A 109.2(17) . . ?
F5A B2 F6A 103.2(16) . . ?
F8 B2 F6A 45.7(11) . . ?
F5 B2 F6A 77.2(14) . . ?
F7A B2 F6A 109.3(16) . . ?
F7 B2 F6A 157.6(18) . . ?
F8A B2 F6 33.0(10) . . ?
F5A B2 F6 148.6(16) . . ?
F8 B2 F6 102.9(15) . . ?
F5 B2 F6 98.9(14) . . ?
F7A B2 F6 107.5(14) . . ?
F7 B2 F6 97.4(15) . . ?
F6A B2 F6 81.0(12) . . ?
F7A F5 B2 75(3) . . ?
F8A F6 B2 54.9(18) . . ?
B2 F7 F8A 52.6(12) . . ?
B2 F7 F5A 53.7(12) . . ?
F8A F7 F5A 100.1(17) . . ?
F6A F8 B2 75.1(18) . . ?
F6A F8 F5A 123(2) . . ?
B2 F8 F5A 57.6(12) . . ?
B2 F5A F8 58.6(12) . . ?
B2 F5A F7 59.5(13) . . ?
F8 F5A F7 104.9(17) . . ?
F8 F6A B2 59.2(15) . . ?
F5 F7A B2 73(3) . . ?
F6 F8A B2 92(2) . . ?
F6 F8A F7 153(3) . . ?
B2 F8A F7 62.6(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt N3 2.054(7) . ?
Pt N1 2.061(6) . ?
Pt P1 2.2549(18) . ?
Pt P2 2.276(2) . ?
P1 C13 1.806(7) . ?
P1 C7 1.813(7) . ?
P1 C1 1.824(7) . ?
P2 C31 1.811(7) . ?
P2 C19 1.816(7) . ?
P2 C25 1.822(7) . ?
N1 C37 1.134(10) . ?
N2 C37 1.308(11) . ?
N2 C40 1.497(16) . ?
N2 C38 1.71(2) . ?
N3 C42 1.136(10) . ?
N4 C42 1.291(12) . ?
N4 C43 1.513(18) . ?
N4 C45 1.663(19) . ?
C1 C2 1.377(11) . ?
C1 C6 1.393(11) . ?
C2 C3 1.395(13) . ?
C3 C4 1.362(15) . ?
C4 C5 1.384(15) . ?
C5 C6 1.390(12) . ?
C7 C12 1.381(10) . ?
C7 C8 1.383(10) . ?
C8 C9 1.378(11) . ?
C9 C10 1.378(13) . ?
C10 C11 1.384(12) . ?
C11 C12 1.391(11) . ?
C13 C14 1.387(10) . ?
C13 C18 1.396(9) . ?
C14 C15 1.398(11) . ?
C15 C16 1.370(12) . ?
C16 C17 1.368(13) . ?
C17 C18 1.388(11) . ?
C19 C20 1.388(11) . ?
C19 C24 1.389(11) . ?
C20 C21 1.390(11) . ?
C21 C22 1.378(14) . ?
C22 C23 1.363(15) . ?
C23 C24 1.398(12) . ?
C25 C26 1.382(10) . ?
C25 C30 1.385(10) . ?
C26 C27 1.390(12) . ?
C27 C28 1.360(13) . ?
C28 C29 1.379(12) . ?
C29 C30 1.382(10) . ?
C31 C32 1.395(10) . ?
C31 C36 1.402(10) . ?
C32 C33 1.385(11) . ?
C33 C34 1.377(12) . ?
C34 C35 1.373(12) . ?
C35 C36 1.401(11) . ?
C38 C39 1.31(3) . ?
C40 C41 1.473(19) . ?
C43 C44 1.35(2) . ?
C45 C46 1.37(2) . ?
B1 F3A 1.31(3) . ?
B1 F4A 1.33(3) . ?
B1 F3 1.36(3) . ?
B1 F4 1.38(2) . ?
B1 F2 1.37(3) . ?
B1 F1 1.362(17) . ?
B1 F1A 1.43(2) . ?
B1 F2A 1.43(2) . ?
F1 F3A 1.77(3) . ?
F1 F4A 1.69(2) . ?
F2 F2A 1.33(3) . ?
F2 F3A 1.35(3) . ?
F3 F4A 1.16(3) . ?
F3 F1A 1.46(3) . ?
F3 F2A 1.77(3) . ?
F4 F1A 1.09(2) . ?
F4 F3A 1.42(3) . ?
B2 F8A 1.25(2) . ?
B2 F5A 1.31(2) . ?
B2 F8 1.32(2) . ?
B2 F5 1.35(2) . ?
B2 F7A 1.36(2) . ?
B2 F7 1.40(2) . ?
B2 F6A 1.49(2) . ?
B2 F6 1.53(2) . ?
F5 F7A 0.76(2) . ?
F6 F8A 0.83(2) . ?
F7 F8A 1.43(2) . ?
F7 F5A 1.49(2) . ?
F8 F6A 1.10(2) . ?
F8 F5A 1.39(2) . ?
