#------------------------------------------------------------------------------
#$Date: 2016-03-23 14:43:16 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179303 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/00/4320097.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4320097
loop_
_publ_author_name
'Mario Barberis'
'Francisco Estevan'
'Pascual Lahuerta'
'Julia Pérez-Prieto'
'Mercedes Sanaú'
_publ_section_title
;
 New Dinuclear Catalysts Rh2(N-O)2[(C6H4)P(C6H5)2]2 with Imidate Ligands:
 Synthesis and Isomerization from Head-to-Tail to Head-to-Head
 Configuration of the Imidate Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4226
_journal_page_last               4229
_journal_paper_doi               10.1021/ic010257d
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C49 H43 Cl2 N3 O7 P2 Rh2'
_chemical_formula_weight         1124.52
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.774(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.8114(8)
_cell_length_b                   19.5510(12)
_cell_length_c                   18.6265(12)
_cell_measurement_temperature    293(2)
_cell_volume                     4583.2(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1959
_diffrn_reflns_av_sigmaI/netI    0.3403
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            37991
_diffrn_reflns_theta_full        30.57
_diffrn_reflns_theta_max         30.57
_diffrn_reflns_theta_min         1.52
_exptl_absorpt_coefficient_mu    0.963
_exptl_crystal_density_diffrn    1.630
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2272
_refine_diff_density_max         0.819
_refine_diff_density_min         -0.678
_refine_diff_density_rms         0.122
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.875
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     586
_refine_ls_number_reflns         13797
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.875
_refine_ls_R_factor_all          0.2566
_refine_ls_R_factor_gt           0.0658
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0243P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0847
_refine_ls_wR_factor_ref         0.1177
_reflns_number_gt                4596
_reflns_number_total             13797
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic010257d_1.cif
_cod_data_source_block           3(CH2Cl2)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4320097
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.47021(4) 0.21562(2) 0.75896(3) 0.02959(14) Uani 1 1 d . . .
Rh2 Rh 0.44363(4) 0.13430(2) 0.64967(3) 0.02933(14) Uani 1 1 d . . .
P1 P 0.37600(13) 0.14373(8) 0.81219(9) 0.0289(4) Uani 1 1 d . . .
P2 P 0.60696(13) 0.09250(8) 0.68964(10) 0.0327(4) Uani 1 1 d . . .
O6 O 0.4745(4) 0.1896(3) 0.4759(3) 0.0606(15) Uani 1 1 d . . .
O2 O 0.5595(3) 0.2824(2) 0.7018(3) 0.0408(12) Uani 1 1 d . . .
O3 O 0.4659(4) 0.3057(2) 0.8523(3) 0.0547(14) Uani 1 1 d . . .
O4 O 0.4091(3) 0.0788(2) 0.5399(2) 0.0462(12) Uani 1 1 d . . .
C12 C 0.3845(5) 0.0561(3) 0.6983(4) 0.0316(16) Uani 1 1 d . . .
N1 N 0.2915(4) 0.1798(3) 0.6208(3) 0.0346(14) Uani 1 1 d . . .
C11 C 0.3625(4) 0.0604(3) 0.7701(3) 0.0287(15) Uani 1 1 d . . .
C51 C 0.6334(5) -0.0006(3) 0.6954(4) 0.0344(17) Uani 1 1 d . . .
C31 C 0.2390(5) 0.1730(3) 0.8059(3) 0.0290(16) Uani 1 1 d . . .
C16 C 0.3213(5) 0.0043(3) 0.8028(4) 0.0367(17) Uani 1 1 d . . .
H16 H 0.3086 0.0083 0.8502 0.044 Uiso 1 1 calc R . .
C36 C 0.2172(5) 0.2371(3) 0.8325(4) 0.0415(19) Uani 1 1 d . . .
H36 H 0.2732 0.2664 0.8506 0.050 Uiso 1 1 calc R . .
C32 C 0.1525(5) 0.1323(3) 0.7774(4) 0.0472(19) Uani 1 1 d . . .
H32 H 0.1635 0.0893 0.7588 0.057 Uiso 1 1 calc R . .
O5 O 0.2019(4) 0.1075(3) 0.5332(3) 0.0664(16) Uani 1 1 d . . .
C8 C 0.5546(5) 0.2737(3) 0.6340(4) 0.0396(18) Uani 1 1 d . . .
C2 C 0.1153(5) 0.2080(4) 0.5696(4) 0.060(2) Uani 1 1 d . . .
H2A H 0.0560 0.1861 0.5859 0.072 Uiso 1 1 calc R . .
H2B H 0.0914 0.2258 0.5207 0.072 Uiso 1 1 calc R . .
C14 C 0.3180(6) -0.0612(3) 0.6958(4) 0.049(2) Uani 1 1 d . . .
H14 H 0.3019 -0.1015 0.6695 0.058 Uiso 1 1 calc R . .
C66 C 0.6791(5) 0.1056(3) 0.5581(4) 0.0457(19) Uani 1 1 d . . .
H66 H 0.6230 0.0764 0.5399 0.055 Uiso 1 1 calc R . .
C34 C 0.0309(6) 0.2171(4) 0.8050(4) 0.055(2) Uani 1 1 d . . .
H34 H -0.0380 0.2314 0.8060 0.066 Uiso 1 1 calc R . .
C15 C 0.2994(5) -0.0564(3) 0.7657(4) 0.0448(19) Uani 1 1 d . . .
H15 H 0.2726 -0.0935 0.7877 0.054 Uiso 1 1 calc R . .
C13 C 0.3600(5) -0.0069(3) 0.6642(4) 0.0430(19) Uani 1 1 d . . .
H13 H 0.3730 -0.0125 0.6171 0.052 Uiso 1 1 calc R . .
C33 C 0.0492(5) 0.1553(4) 0.7765(4) 0.058(2) Uani 1 1 d . . .
H33 H -0.0081 0.1279 0.7560 0.069 Uiso 1 1 calc R . .
C61 C 0.6972(5) 0.1232(3) 0.6314(4) 0.0336(16) Uani 1 1 d . . .
C52 C 0.6815(6) -0.0368(4) 0.6461(4) 0.058(2) Uani 1 1 d . . .
H52 H 0.6993 -0.0142 0.6061 0.070 Uiso 1 1 calc R . .
C65 C 0.7427(6) 0.1303(4) 0.5113(4) 0.059(2) Uani 1 1 d . . .
H65 H 0.7305 0.1169 0.4626 0.071 Uiso 1 1 calc R . .
C62 C 0.7799(5) 0.1686(3) 0.6558(4) 0.0457(19) Uani 1 1 d . . .
H62 H 0.7937 0.1820 0.7045 0.055 Uiso 1 1 calc R . .
C35 C 0.1152(6) 0.2578(3) 0.8323(4) 0.045(2) Uani 1 1 d . . .
H35 H 0.1032 0.3006 0.8511 0.054 Uiso 1 1 calc R . .
C1 C 0.2055(6) 0.1585(4) 0.5710(4) 0.048(2) Uani 1 1 d . . .
C7 C 0.6088(5) 0.3214(3) 0.5899(4) 0.048(2) Uani 1 1 d . . .
H7A H 0.6854 0.3196 0.6054 0.057 Uiso 1 1 calc R . .
H7B H 0.5849 0.3681 0.5936 0.057 Uiso 1 1 calc R . .
C64 C 0.8229(6) 0.1742(4) 0.5374(5) 0.060(2) Uani 1 1 d . . .
H64 H 0.8653 0.1908 0.5059 0.071 Uiso 1 1 calc R . .
C6 C 0.5748(6) 0.2938(4) 0.5130(4) 0.062(2) Uani 1 1 d . . .
H6C H 0.6360 0.2826 0.4915 0.075 Uiso 1 1 calc R . .
H6A H 0.5309 0.3266 0.4820 0.075 Uiso 1 1 calc R . .
C63 C 0.8426(6) 0.1945(4) 0.6078(5) 0.057(2) Uani 1 1 d . . .
H63 H 0.8972 0.2252 0.6244 0.068 Uiso 1 1 calc R . .
O1 O 0.3313(3) 0.2701(2) 0.7007(3) 0.0382(12) Uani 1 1 d . . .
N2 N 0.5044(4) 0.2211(3) 0.5967(3) 0.0369(14) Uani 1 1 d . . .
C41 C 0.6628(5) 0.1233(3) 0.7802(3) 0.0353(17) Uani 1 1 d . . .
C21 C 0.4199(5) 0.1263(3) 0.9096(3) 0.0296(15) Uani 1 1 d . . .
C43 C 0.6591(5) 0.2037(3) 0.8745(4) 0.0416(18) Uani 1 1 d . . .
H43 H 0.6248 0.2379 0.8960 0.050 Uiso 1 1 calc R . .
C42 C 0.6067(5) 0.1762(3) 0.8076(4) 0.0315(16) Uani 1 1 d . . .
C4 C 0.2699(5) 0.2396(3) 0.6523(4) 0.0356(18) Uani 1 1 d . . .
C22 C 0.5142(5) 0.0922(3) 0.9338(4) 0.0399(18) Uani 1 1 d . . .
H22 H 0.5545 0.0788 0.8997 0.048 Uiso 1 1 calc R . .
C46 C 0.7623(5) 0.1004(3) 0.8170(4) 0.0462(19) Uani 1 1 d . . .
H46 H 0.7969 0.0651 0.7976 0.055 Uiso 1 1 calc R . .
C26 C 0.3629(6) 0.1455(4) 0.9627(4) 0.056(2) Uani 1 1 d . . .
H26 H 0.2992 0.1691 0.9491 0.068 Uiso 1 1 calc R . .
C5 C 0.5116(5) 0.2297(4) 0.5241(4) 0.046(2) Uani 1 1 d . . .
C3 C 0.1613(5) 0.2650(3) 0.6219(4) 0.055(2) Uani 1 1 d . . .
H3A H 0.1639 0.3079 0.5962 0.066 Uiso 1 1 calc R . .
H3B H 0.1201 0.2711 0.6601 0.066 Uiso 1 1 calc R . .
Cl2 Cl 0.3681(2) 0.40882(12) 0.59697(16) 0.1043(9) Uani 1 1 d . . .
Cl1 Cl 0.3475(3) 0.52955(17) 0.5111(2) 0.1941(19) Uani 1 1 d . . .
N3 N 0.5158(5) 0.3939(3) 0.7890(3) 0.0552(18) Uani 1 1 d . . .
H3 H 0.5277 0.3702 0.7525 0.066 Uiso 1 1 calc R . .
C04 C 0.4838(5) 0.3667(4) 0.8471(4) 0.0421(18) Uani 1 1 d . . .
C24 C 0.4913(6) 0.0966(3) 1.0567(4) 0.052(2) Uani 1 1 d . . .
H24 H 0.5143 0.0868 1.1059 0.063 Uiso 1 1 calc R . .
C25 C 0.3981(7) 0.1305(4) 1.0337(4) 0.069(2) Uani 1 1 d . . .
H25 H 0.3577 0.1437 1.0680 0.082 Uiso 1 1 calc R . .
C23 C 0.5510(6) 0.0772(3) 1.0058(4) 0.0493(19) Uani 1 1 d . . .
H23 H 0.6151 0.0542 1.0202 0.059 Uiso 1 1 calc R . .
C03 C 0.4743(6) 0.4217(3) 0.9007(4) 0.061(2) Uani 1 1 d . . .
H03A H 0.5233 0.4140 0.9463 0.073 Uiso 1 1 calc R . .
H03B H 0.4026 0.4238 0.9104 0.073 Uiso 1 1 calc R . .
C45 C 0.8076(6) 0.1300(4) 0.8810(4) 0.058(2) Uani 1 1 d . . .
H45 H 0.8730 0.1143 0.9058 0.070 Uiso 1 1 calc R . .
C54 C 0.6773(6) -0.1398(4) 0.7131(5) 0.065(2) Uani 1 1 d . . .
H54 H 0.6928 -0.1861 0.7194 0.078 Uiso 1 1 calc R . .
C55 C 0.6293(7) -0.1062(4) 0.7602(5) 0.073(3) Uani 1 1 d . . .
H55 H 0.6107 -0.1298 0.7993 0.088 Uiso 1 1 calc R . .
C56 C 0.6066(6) -0.0366(4) 0.7522(4) 0.066(3) Uani 1 1 d . . .
H56 H 0.5729 -0.0145 0.7857 0.079 Uiso 1 1 calc R . .
C44 C 0.7577(6) 0.1832(4) 0.9098(4) 0.057(2) Uani 1 1 d . . .
H44 H 0.7905 0.2048 0.9526 0.068 Uiso 1 1 calc R . .
C53 C 0.7031(7) -0.1049(4) 0.6554(5) 0.071(3) Uani 1 1 d . . .
H53 H 0.7360 -0.1279 0.6220 0.085 Uiso 1 1 calc R . .
C02 C 0.5020(7) 0.4876(4) 0.8642(5) 0.085(3) Uani 1 1 d . . .
H02A H 0.4423 0.5189 0.8561 0.102 Uiso 1 1 calc R . .
H02B H 0.5626 0.5102 0.8938 0.102 Uiso 1 1 calc R . .
O7 O 0.5551(5) 0.4979(3) 0.7450(4) 0.097(2) Uani 1 1 d . . .
C01 C 0.5279(7) 0.4641(4) 0.7936(5) 0.066(3) Uani 1 1 d . . .
C10 C 0.4124(9) 0.4923(5) 0.5866(6) 0.129(4) Uani 1 1 d . . .
H10A H 0.4031 0.5194 0.6287 0.154 Uiso 1 1 calc R . .
H10B H 0.4877 0.4913 0.5852 0.154 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C42 Rh1 O2 87.5(2) . . ?
C42 Rh1 O1 172.50(19) . . ?
O2 Rh1 O1 85.25(16) . . ?
C42 Rh1 P1 93.30(16) . . ?
O2 Rh1 P1 176.87(13) . . ?
O1 Rh1 P1 94.05(11) . . ?
C42 Rh1 O3 95.1(2) . . ?
O2 Rh1 O3 90.00(16) . . ?
O1 Rh1 O3 83.06(16) . . ?
P1 Rh1 O3 92.94(11) . . ?
C42 Rh1 Rh2 95.62(18) . . ?
O2 Rh1 Rh2 89.27(12) . . ?
O1 Rh1 Rh2 86.15(12) . . ?
P1 Rh1 Rh2 87.65(5) . . ?
O3 Rh1 Rh2 169.21(11) . . ?
C12 Rh2 N1 91.6(2) . . ?
C12 Rh2 N2 178.5(2) . . ?
N1 Rh2 N2 87.00(18) . . ?
C12 Rh2 P2 88.83(18) . . ?
N1 Rh2 P2 174.57(16) . . ?
N2 Rh2 P2 92.51(14) . . ?
C12 Rh2 O4 90.9(2) . . ?
N1 Rh2 O4 87.53(18) . . ?
N2 Rh2 O4 89.44(18) . . ?
P2 Rh2 O4 97.87(11) . . ?
C12 Rh2 Rh1 96.93(18) . . ?
N1 Rh2 Rh1 85.43(15) . . ?
N2 Rh2 Rh1 82.55(15) . . ?
P2 Rh2 Rh1 89.15(5) . . ?
O4 Rh2 Rh1 169.59(11) . . ?
C11 P1 C21 104.5(3) . . ?
C11 P1 C31 104.0(3) . . ?
C21 P1 C31 103.6(3) . . ?
C11 P1 Rh1 113.3(2) . . ?
C21 P1 Rh1 118.19(19) . . ?
C31 P1 Rh1 111.79(19) . . ?
C41 P2 C61 105.1(3) . . ?
C41 P2 C51 103.7(3) . . ?
C61 P2 C51 103.2(3) . . ?
C41 P2 Rh2 111.8(2) . . ?
C61 P2 Rh2 109.7(2) . . ?
C51 P2 Rh2 121.8(2) . . ?
C8 O2 Rh1 118.8(4) . . ?
C04 O3 Rh1 127.4(5) . . ?
C13 C12 C11 114.5(5) . . ?
C13 C12 Rh2 122.8(5) . . ?
C11 C12 Rh2 122.7(4) . . ?
C4 N1 C1 110.6(6) . . ?
C4 N1 Rh2 120.2(5) . . ?
C1 N1 Rh2 129.2(5) . . ?
C16 C11 C12 121.3(5) . . ?
C16 C11 P1 122.0(5) . . ?
C12 C11 P1 116.4(4) . . ?
C56 C51 C52 117.1(6) . . ?
C56 C51 P2 118.8(5) . . ?
C52 C51 P2 124.1(5) . . ?
C32 C31 C36 117.0(6) . . ?
C32 C31 P1 122.2(5) . . ?
C36 C31 P1 120.8(5) . . ?
C15 C16 C11 120.9(6) . . ?
C35 C36 C31 121.3(6) . . ?
C31 C32 C33 120.5(6) . . ?
O2 C8 N2 123.5(6) . . ?
O2 C8 C7 121.5(7) . . ?
N2 C8 C7 114.9(6) . . ?
C1 C2 C3 104.8(6) . . ?
C15 C14 C13 120.5(6) . . ?
C61 C66 C65 121.5(7) . . ?
C33 C34 C35 119.0(6) . . ?
C14 C15 C16 118.7(6) . . ?
C14 C13 C12 124.2(6) . . ?
C34 C33 C32 120.9(7) . . ?
C66 C61 C62 117.2(6) . . ?
C66 C61 P2 119.7(5) . . ?
C62 C61 P2 122.8(5) . . ?
C53 C52 C51 121.1(7) . . ?
C64 C65 C66 119.3(7) . . ?
C61 C62 C63 120.9(7) . . ?
C34 C35 C36 121.2(6) . . ?
O5 C1 N1 125.5(7) . . ?
O5 C1 C2 124.9(7) . . ?
N1 C1 C2 109.6(7) . . ?
C8 C7 C6 102.5(6) . . ?
C63 C64 C65 121.7(7) . . ?
C7 C6 C5 103.3(6) . . ?
C64 C63 C62 119.2(7) . . ?
C4 O1 Rh1 118.5(4) . . ?
C8 N2 C5 107.6(6) . . ?
C8 N2 Rh2 122.8(4) . . ?
C5 N2 Rh2 129.2(5) . . ?
C46 C41 C42 122.4(6) . . ?
C46 C41 P2 121.0(5) . . ?
C42 C41 P2 116.3(5) . . ?
C22 C21 C26 116.2(6) . . ?
C22 C21 P1 120.2(5) . . ?
C26 C21 P1 123.5(5) . . ?
C44 C43 C42 123.9(7) . . ?
C43 C42 C41 114.2(6) . . ?
C43 C42 Rh1 119.6(5) . . ?
C41 C42 Rh1 126.1(5) . . ?
O1 C4 N1 125.3(6) . . ?
O1 C4 C3 122.8(7) . . ?
N1 C4 C3 111.9(7) . . ?
C23 C22 C21 123.1(7) . . ?
C45 C46 C41 119.7(6) . . ?
C25 C26 C21 121.2(7) . . ?
O6 C5 N2 123.6(7) . . ?
O6 C5 C6 124.9(7) . . ?
N2 C5 C6 111.4(7) . . ?
C4 C3 C2 102.9(6) . . ?
C04 N3 C01 113.1(7) . . ?
O3 C04 N3 122.9(7) . . ?
O3 C04 C03 127.7(7) . . ?
N3 C04 C03 109.4(6) . . ?
C25 C24 C23 119.0(7) . . ?
C26 C25 C24 121.8(7) . . ?
C22 C23 C24 118.7(7) . . ?
C04 C03 C02 104.8(6) . . ?
C46 C45 C44 120.7(7) . . ?
C55 C54 C53 118.8(8) . . ?
C54 C55 C56 121.5(8) . . ?
C51 C56 C55 120.5(7) . . ?
C43 C44 C45 119.1(7) . . ?
C54 C53 C52 121.0(8) . . ?
C01 C02 C03 104.0(6) . . ?
O7 C01 N3 122.3(8) . . ?
O7 C01 C02 128.9(8) . . ?
N3 C01 C02 108.7(7) . . ?
Cl1 C10 Cl2 112.3(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C42 1.970(7) . ?
Rh1 O2 2.145(4) . ?
Rh1 O1 2.181(4) . ?
Rh1 P1 2.2052(16) . ?
Rh1 O3 2.483(5) . ?
Rh1 Rh2 2.5551(7) . ?
Rh2 C12 1.997(6) . ?
Rh2 N1 2.119(5) . ?
Rh2 N2 2.178(5) . ?
Rh2 P2 2.2401(18) . ?
Rh2 O4 2.284(4) . ?
P1 C11 1.802(6) . ?
P1 C21 1.828(6) . ?
P1 C31 1.829(6) . ?
P2 C41 1.808(7) . ?
P2 C61 1.828(6) . ?
P2 C51 1.851(6) . ?
O6 C5 1.219(8) . ?
O2 C8 1.263(7) . ?
O3 C04 1.223(7) . ?
C12 C13 1.394(8) . ?
C12 C11 1.420(8) . ?
N1 C4 1.360(7) . ?
N1 C1 1.366(8) . ?
C11 C16 1.405(7) . ?
C51 C56 1.367(8) . ?
C51 C52 1.391(8) . ?
C31 C32 1.387(8) . ?
C31 C36 1.395(7) . ?
C16 C15 1.377(8) . ?
C36 C35 1.368(8) . ?
C32 C33 1.396(8) . ?
O5 C1 1.217(8) . ?
C8 N2 1.337(8) . ?
C8 C7 1.497(8) . ?
C2 C1 1.503(9) . ?
C2 C3 1.524(9) . ?
C14 C15 1.371(8) . ?
C14 C13 1.371(8) . ?
C66 C61 1.384(8) . ?
C66 C65 1.387(8) . ?
C34 C33 1.359(8) . ?
C34 C35 1.361(9) . ?
C61 C62 1.392(8) . ?
C52 C53 1.365(8) . ?
C65 C64 1.357(10) . ?
C62 C63 1.403(8) . ?
C7 C6 1.517(9) . ?
C64 C63 1.347(9) . ?
C6 C5 1.527(9) . ?
O1 C4 1.233(8) . ?
N2 C5 1.383(8) . ?
C41 C46 1.403(8) . ?
C41 C42 1.409(8) . ?
C21 C22 1.380(8) . ?
C21 C26 1.387(8) . ?
C43 C44 1.370(9) . ?
C43 C42 1.407(8) . ?
C4 C3 1.486(9) . ?
C22 C23 1.368(8) . ?
C46 C45 1.354(9) . ?
C26 C25 1.347(9) . ?
Cl2 C10 1.751(9) . ?
Cl1 C10 1.663(10) . ?
N3 C04 1.337(7) . ?
N3 C01 1.381(8) . ?
C04 C03 1.487(9) . ?
C24 C25 1.363(9) . ?
C24 C23 1.377(9) . ?
C03 C02 1.530(9) . ?
C45 C44 1.382(9) . ?
C54 C55 1.335(9) . ?
C54 C53 1.363(9) . ?
C55 C56 1.393(9) . ?
C02 C01 1.487(10) . ?
O7 C01 1.222(8) . ?
