#------------------------------------------------------------------------------
#$Date: 2016-03-23 14:47:32 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179306 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/03/4320327.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4320327
loop_
_publ_author_name
'Franck Gascoin'
'Slavi C. Sevov'
_publ_section_title
;
 Synthesis and Characterization of the "Metallic Salts" A5Pn4 (A = K, Rb,
 Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn44- and an
 Extra Delocalized Electron
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5177
_journal_page_last               5181
_journal_paper_doi               10.1021/ic0104499
_journal_volume                  40
_journal_year                    2001
_chemical_formula_moiety         Rb5Sb4
_chemical_formula_sum            'Rb5 Sb4'
_chemical_formula_weight         914.35
_chemical_melting_point          ?
_chemical_name_common            Rb5Sb4
_chemical_name_systematic
;
   ?
;
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 113.7010(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.7803(9)
_cell_length_b                   5.7518(4)
_cell_length_c                   11.6310(8)
_cell_measurement_temperature    250(2)
_cell_volume                     782.88(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      250(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0473
_diffrn_reflns_av_sigmaI/netI    0.0569
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            4215
_diffrn_reflns_theta_full        28.38
_diffrn_reflns_theta_max         28.38
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    22.221
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.468324
_exptl_absorpt_correction_type   semi-empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            'gray, metallic luster'
_exptl_crystal_density_diffrn    3.879
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             778
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.04
_refine_diff_density_max         2.315
_refine_diff_density_min         -0.861
_refine_diff_density_rms         0.271
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     31
_refine_ls_number_reflns         1074
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.064
_refine_ls_R_factor_all          0.0407
_refine_ls_R_factor_gt           0.0341
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0373P)²+0.8608P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0859
_refine_ls_wR_factor_ref         0.0901
_reflns_number_gt                920
_reflns_number_total             1074
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0104499_3.cif
_cod_data_source_block           Rb5Sb4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_database_code               4320327
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.10179(4) 0.0000 0.11056(4) 0.02492(17) Uani 1 2 d S . .
Sb2 Sb 0.04299(4) 0.0000 0.31800(4) 0.02743(17) Uani 1 2 d S . .
Rb1 Rb 0.39354(6) 0.0000 0.10149(6) 0.0281(2) Uani 1 2 d S . .
Rb2 Rb 0.24667(7) 0.5000 0.33398(7) 0.0368(2) Uani 1 2 d S . .
Rb3 Rb 0.0353(2) 0.5000 0.5211(3) 0.0585(10) Uani 0.50 2 d SP . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Sb2 Sb1 Sb1 108.42(3) . 5 ?
Sb2 Sb1 Rb1 129.39(2) . . ?
Sb1 Sb1 Rb1 122.19(2) 5 . ?
Sb2 Sb1 Rb1 129.644(11) . 7_545 ?
Sb1 Sb1 Rb1 70.064(15) 5 7_545 ?
Rb1 Sb1 Rb1 73.061(15) . 7_545 ?
Sb2 Sb1 Rb1 129.644(11) . 7 ?
Sb1 Sb1 Rb1 70.064(15) 5 7 ?
Rb1 Sb1 Rb1 73.061(15) . 7 ?
Rb1 Sb1 Rb1 98.20(2) 7_545 7 ?
Sb2 Sb1 Rb2 68.801(15) . . ?
Sb1 Sb1 Rb2 129.475(11) 5 . ?
Rb1 Sb1 Rb2 78.736(15) . . ?
Rb1 Sb1 Rb2 151.73(2) 7_545 . ?
Rb1 Sb1 Rb2 75.061(13) 7 . ?
Sb2 Sb1 Rb2 68.802(15) . 1_545 ?
Sb1 Sb1 Rb2 129.476(11) 5 1_545 ?
Rb1 Sb1 Rb2 78.735(15) . 1_545 ?
Rb1 Sb1 Rb2 75.061(13) 7_545 1_545 ?
Rb1 Sb1 Rb2 151.72(2) 7 1_545 ?
Rb2 Sb1 Rb2 97.715(19) . 1_545 ?
Sb2 Sb1 Rb1 66.789(14) . 3_445 ?
Sb1 Sb1 Rb1 66.815(15) 5 3_445 ?
Rb1 Sb1 Rb1 132.241(10) . 3_445 ?
Rb1 Sb1 Rb1 67.202(18) 7_545 3_445 ?
Rb1 Sb1 Rb1 136.879(13) 7 3_445 ?
Rb2 Sb1 Rb1 135.589(17) . 3_445 ?
Rb2 Sb1 Rb1 66.491(15) 1_545 3_445 ?
Sb2 Sb1 Rb1 66.789(14) . 3_455 ?
Sb1 Sb1 Rb1 66.815(15) 5 3_455 ?
Rb1 Sb1 Rb1 132.240(10) . 3_455 ?
Rb1 Sb1 Rb1 136.879(13) 7_545 3_455 ?
Rb1 Sb1 Rb1 67.202(18) 7 3_455 ?
Rb2 Sb1 Rb1 66.490(15) . 3_455 ?
Rb2 Sb1 Rb1 135.590(17) 1_545 3_455 ?
Rb1 Sb1 Rb1 95.316(19) 3_445 3_455 ?
Sb1 Sb2 Rb3 128.84(4) . 1_545 ?
Sb1 Sb2 Rb3 128.84(4) . . ?
Rb3 Sb2 Rb3 100.22(8) 1_545 . ?
Sb1 Sb2 Rb3 130.00(4) . 5_566 ?
Rb3 Sb2 Rb3 101.104(13) 1_545 5_566 ?
Rb3 Sb2 Rb3 12.74(7) . 5_566 ?
Sb1 Sb2 Rb3 130.00(4) . 5_556 ?
Rb3 Sb2 Rb3 12.74(7) 1_545 5_556 ?
Rb3 Sb2 Rb3 101.103(13) . 5_556 ?
Rb3 Sb2 Rb3 99.12(8) 5_566 5_556 ?
Sb1 Sb2 Rb2 130.45(2) . 3_445 ?
Rb3 Sb2 Rb2 72.26(4) 1_545 3_445 ?
Rb3 Sb2 Rb2 72.26(4) . 3_445 ?
Rb3 Sb2 Rb2 61.10(4) 5_566 3_445 ?
Rb3 Sb2 Rb2 61.10(4) 5_556 3_445 ?
Sb1 Sb2 Rb1 70.488(14) . 3_445 ?
Rb3 Sb2 Rb1 72.72(4) 1_545 3_445 ?
Rb3 Sb2 Rb1 150.02(4) . 3_445 ?
Rb3 Sb2 Rb1 137.97(4) 5_566 3_445 ?
Rb3 Sb2 Rb1 65.73(4) 5_556 3_445 ?
Rb2 Sb2 Rb1 77.899(15) 3_445 3_445 ?
Sb1 Sb2 Rb1 70.488(14) . 3_455 ?
Rb3 Sb2 Rb1 150.02(4) 1_545 3_455 ?
Rb3 Sb2 Rb1 72.72(4) . 3_455 ?
Rb3 Sb2 Rb1 65.73(4) 5_566 3_455 ?
Rb3 Sb2 Rb1 137.97(4) 5_556 3_455 ?
Rb2 Sb2 Rb1 77.899(15) 3_445 3_455 ?
Rb1 Sb2 Rb1 98.584(19) 3_445 3_455 ?
Sb1 Sb2 Rb2 126.10(2) . 7_556 ?
Rb3 Sb2 Rb2 61.45(4) 1_545 7_556 ?
Rb3 Sb2 Rb2 61.45(4) . 7_556 ?
Rb3 Sb2 Rb2 72.04(4) 5_566 7_556 ?
Rb3 Sb2 Rb2 72.04(4) 5_556 7_556 ?
Rb2 Sb2 Rb2 103.453(18) 3_445 7_556 ?
Rb1 Sb2 Rb2 130.498(10) 3_445 7_556 ?
Rb1 Sb2 Rb2 130.498(10) 3_455 7_556 ?
Sb1 Sb2 Rb2 68.261(15) . . ?
Rb3 Sb2 Rb2 137.27(4) 1_545 . ?
Rb3 Sb2 Rb2 65.36(4) . . ?
Rb3 Sb2 Rb2 73.43(4) 5_566 . ?
Rb3 Sb2 Rb2 148.96(4) 5_556 . ?
Rb2 Sb2 Rb2 131.073(11) 3_445 . ?
Rb1 Sb2 Rb2 138.747(18) 3_445 . ?
Rb1 Sb2 Rb2 67.313(15) 3_455 . ?
Rb2 Sb2 Rb2 77.043(17) 7_556 . ?
Sb1 Sb2 Rb2 68.260(15) . 1_545 ?
Rb3 Sb2 Rb2 65.36(4) 1_545 1_545 ?
Rb3 Sb2 Rb2 137.27(4) . 1_545 ?
Rb3 Sb2 Rb2 148.96(4) 5_566 1_545 ?
Rb3 Sb2 Rb2 73.43(4) 5_556 1_545 ?
Rb2 Sb2 Rb2 131.074(11) 3_445 1_545 ?
Rb1 Sb2 Rb2 67.314(15) 3_445 1_545 ?
Rb1 Sb2 Rb2 138.747(18) 3_455 1_545 ?
Rb2 Sb2 Rb2 77.042(17) 7_556 1_545 ?
Rb2 Sb2 Rb2 97.23(2) . 1_545 ?
Sb1 Rb1 Sb2 102.768(16) . 3 ?
Sb1 Rb1 Sb2 102.768(16) . 3_545 ?
Sb2 Rb1 Sb2 98.583(19) 3 3_545 ?
Sb1 Rb1 Sb1 106.939(15) . 7_545 ?
Sb2 Rb1 Sb1 150.27(2) 3 7_545 ?
Sb2 Rb1 Sb1 73.883(10) 3_545 7_545 ?
Sb1 Rb1 Sb1 106.939(15) . 7 ?
Sb2 Rb1 Sb1 73.883(10) 3 7 ?
Sb2 Rb1 Sb1 150.27(2) 3_545 7 ?
Sb1 Rb1 Sb1 98.21(2) 7_545 7 ?
Sb1 Rb1 Sb1 132.242(10) . 3 ?
Sb2 Rb1 Sb1 42.723(10) 3 3 ?
Sb2 Rb1 Sb1 112.700(19) 3_545 3 ?
Sb1 Rb1 Sb1 112.797(18) 7_545 3 ?
Sb1 Rb1 Sb1 43.121(13) 7 3 ?
Sb1 Rb1 Sb1 132.242(10) . 3_545 ?
Sb2 Rb1 Sb1 112.700(19) 3 3_545 ?
Sb2 Rb1 Sb1 42.723(11) 3_545 3_545 ?
Sb1 Rb1 Sb1 43.121(13) 7_545 3_545 ?
Sb1 Rb1 Sb1 112.797(18) 7 3_545 ?
Sb1 Rb1 Sb1 95.312(19) 3 3_545 ?
Sb1 Rb1 Rb3 76.53(4) . 7_556 ?
Sb2 Rb1 Rb3 56.96(2) 3 7_556 ?
Sb2 Rb1 Rb3 56.96(2) 3_545 7_556 ?
Sb1 Rb1 Rb3 129.646(13) 7_545 7_556 ?
Sb1 Rb1 Rb3 129.646(13) 7 7_556 ?
Sb1 Rb1 Rb3 96.65(3) 3 7_556 ?
Sb1 Rb1 Rb3 96.65(3) 3_545 7_556 ?
Sb1 Rb1 Rb1 150.97(3) . 5_655 ?
Sb2 Rb1 Rb1 96.002(18) 3 5_655 ?
Sb2 Rb1 Rb1 96.002(18) 3_545 5_655 ?
Sb1 Rb1 Rb1 57.365(12) 7_545 5_655 ?
Sb1 Rb1 Rb1 57.365(12) 7 5_655 ?
Sb1 Rb1 Rb1 55.431(12) 3 5_655 ?
Sb1 Rb1 Rb1 55.431(12) 3_545 5_655 ?
Rb3 Rb1 Rb1 132.51(5) 7_556 5_655 ?
Sb1 Rb1 Rb2 142.68(2) . 3_545 ?
Sb2 Rb1 Rb2 56.785(12) 3 3_545 ?
Sb2 Rb1 Rb2 56.785(12) 3_545 3_545 ?
Sb1 Rb1 Rb2 97.109(17) 7_545 3_545 ?
Sb1 Rb1 Rb2 97.109(17) 7 3_545 ?
Sb1 Rb1 Rb2 55.937(12) 3 3_545 ?
Sb1 Rb1 Rb2 55.937(12) 3_545 3_545 ?
Rb3 Rb1 Rb2 66.15(4) 7_556 3_545 ?
Rb1 Rb1 Rb2 66.35(2) 5_655 3_545 ?
Sb1 Rb1 Rb3 86.61(4) . 3_545 ?
Sb2 Rb1 Rb3 53.168(15) 3 3_545 ?
Sb2 Rb1 Rb3 53.168(15) 3_545 3_545 ?
Sb1 Rb1 Rb3 127.051(15) 7_545 3_545 ?
Sb1 Rb1 Rb3 127.051(15) 7 3_545 ?
Sb1 Rb1 Rb3 89.88(3) 3 3_545 ?
Sb1 Rb1 Rb3 89.88(3) 3_545 3_545 ?
Rb3 Rb1 Rb3 10.08(7) 7_556 3_545 ?
Rb1 Rb1 Rb3 122.43(4) 5_655 3_545 ?
Rb2 Rb1 Rb3 56.07(4) 3_545 3_545 ?
Sb1 Rb1 Rb1 53.800(15) . 7_545 ?
Sb2 Rb1 Rb1 156.54(3) 3 7_545 ?
Sb2 Rb1 Rb1 87.173(10) 3_545 7_545 ?
Sb1 Rb1 Rb1 53.139(12) 7_545 7_545 ?
Sb1 Rb1 Rb1 111.35(2) 7 7_545 ?
Sb1 Rb1 Rb1 152.76(3) 3 7_545 ?
Sb1 Rb1 Rb1 86.936(11) 3_545 7_545 ?
Rb3 Rb1 Rb1 110.08(4) 7_556 7_545 ?
Rb1 Rb1 Rb1 106.04(2) 5_655 7_545 ?
Rb2 Rb1 Rb1 140.312(12) 3_545 7_545 ?
Rb3 Rb1 Rb1 117.31(3) 3_545 7_545 ?
Sb2 Rb2 Sb2 76.546(18) 3 7_556 ?
Sb2 Rb2 Sb1 100.585(17) 3 1_565 ?
Sb2 Rb2 Sb1 131.084(10) 7_556 1_565 ?
Sb2 Rb2 Sb1 100.586(16) 3 . ?
Sb2 Rb2 Sb1 131.084(10) 7_556 . ?
Sb1 Rb2 Sb1 97.716(19) 1_565 . ?
Sb2 Rb2 Rb3 58.35(5) 3 7_566 ?
Sb2 Rb2 Rb3 57.91(4) 7_556 7_566 ?
Sb1 Rb2 Rb3 78.75(3) 1_565 7_566 ?
Sb1 Rb2 Rb3 156.85(6) . 7_566 ?
Sb2 Rb2 Rb3 58.35(4) 3 7_556 ?
Sb2 Rb2 Rb3 57.91(4) 7_556 7_556 ?
Sb1 Rb2 Rb3 156.85(6) 1_565 7_556 ?
Sb1 Rb2 Rb3 78.75(3) . 7_556 ?
Rb3 Rb2 Rb3 95.47(6) 7_566 7_556 ?
Sb2 Rb2 Sb2 131.073(11) 3 1_565 ?
Sb2 Rb2 Sb2 102.958(17) 7_556 1_565 ?
Sb1 Rb2 Sb2 42.939(11) 1_565 1_565 ?
Sb1 Rb2 Sb2 113.45(2) . 1_565 ?
Rb3 Rb2 Sb2 79.65(3) 7_566 1_565 ?
Rb3 Rb2 Sb2 158.58(6) 7_556 1_565 ?
Sb2 Rb2 Sb2 131.073(11) 3 . ?
Sb2 Rb2 Sb2 102.958(17) 7_556 . ?
Sb1 Rb2 Sb2 113.45(2) 1_565 . ?
Sb1 Rb2 Sb2 42.938(11) . . ?
Rb3 Rb2 Sb2 158.58(6) 7_566 . ?
Rb3 Rb2 Sb2 79.65(3) 7_556 . ?
Sb2 Rb2 Sb2 97.23(2) 1_565 . ?
Sb2 Rb2 Rb3 153.39(4) 3 . ?
Sb2 Rb2 Rb3 76.85(4) 7_556 . ?
Sb1 Rb2 Rb3 96.82(3) 1_565 . ?
Sb1 Rb2 Rb3 96.82(3) . . ?
Rb3 Rb2 Rb3 106.31(5) 7_566 . ?
Rb3 Rb2 Rb3 106.31(5) 7_556 . ?
Sb2 Rb2 Rb3 56.318(19) 1_565 . ?
Sb2 Rb2 Rb3 56.318(19) . . ?
Sb2 Rb2 Rb1 141.62(3) 3 3_455 ?
Sb2 Rb2 Rb1 141.83(3) 7_556 3_455 ?
Sb1 Rb2 Rb1 57.573(12) 1_565 3_455 ?
Sb1 Rb2 Rb1 57.572(12) . 3_455 ?
Rb3 Rb2 Rb1 132.26(3) 7_566 3_455 ?
Rb3 Rb2 Rb1 132.26(3) 7_556 3_455 ?
Sb2 Rb2 Rb1 55.901(12) 1_565 3_455 ?
Sb2 Rb2 Rb1 55.901(12) . 3_455 ?
Rb3 Rb2 Rb1 64.98(4) . 3_455 ?
Sb2 Rb2 Rb3 52.66(4) 3 3 ?
Sb2 Rb2 Rb3 53.19(4) 7_556 3 ?
Sb1 Rb2 Rb3 85.79(3) 1_565 3 ?
Sb1 Rb2 Rb3 153.04(4) . 3 ?
Rb3 Rb2 Rb3 7.93(5) 7_566 3 ?
Rb3 Rb2 Rb3 87.570(17) 7_556 3 ?
Sb2 Rb2 Rb3 87.28(3) 1_565 3 ?
Sb2 Rb2 Rb3 156.01(4) . 3 ?
Rb3 Rb2 Rb3 109.35(6) . 3 ?
Rb1 Rb2 Rb3 140.17(2) 3_455 3 ?
Sb2 Rb2 Rb3 52.66(4) 3 3_545 ?
Sb2 Rb2 Rb3 53.19(4) 7_556 3_545 ?
Sb1 Rb2 Rb3 153.04(4) 1_565 3_545 ?
Sb1 Rb2 Rb3 85.79(3) . 3_545 ?
Rb3 Rb2 Rb3 87.570(17) 7_566 3_545 ?
Rb3 Rb2 Rb3 7.93(5) 7_556 3_545 ?
Sb2 Rb2 Rb3 156.01(4) 1_565 3_545 ?
Sb2 Rb2 Rb3 87.28(3) . 3_545 ?
Rb3 Rb2 Rb3 109.35(6) . 3_545 ?
Rb1 Rb2 Rb3 140.17(2) 3_455 3_545 ?
Rb3 Rb2 Rb3 79.66(4) 3 3_545 ?
Rb3 Rb3 Sb2 85.7(3) 5_566 . ?
Rb3 Rb3 Sb2 85.7(3) 5_566 1_565 ?
Sb2 Rb3 Sb2 100.22(8) . 1_565 ?
Rb3 Rb3 Sb2 81.5(3) 5_566 5_566 ?
Sb2 Rb3 Sb2 167.26(7) . 5_566 ?
Sb2 Rb3 Sb2 78.897(13) 1_565 5_566 ?
Rb3 Rb3 Sb2 81.5(3) 5_566 5_556 ?
Sb2 Rb3 Sb2 78.896(13) . 5_556 ?
Sb2 Rb3 Sb2 167.26(7) 1_565 5_556 ?
Sb2 Rb3 Sb2 99.12(8) 5_566 5_556 ?
Rb3 Rb3 Rb2 132.16(4) 5_566 7_566 ?
Sb2 Rb3 Rb2 130.18(9) . 7_566 ?
Sb2 Rb3 Rb2 60.63(3) 1_565 7_566 ?
Sb2 Rb3 Rb2 60.55(3) 5_566 7_566 ?
Sb2 Rb3 Rb2 129.41(8) 5_556 7_566 ?
Rb3 Rb3 Rb2 132.16(4) 5_566 7_556 ?
Sb2 Rb3 Rb2 60.63(3) . 7_556 ?
Sb2 Rb3 Rb2 130.18(9) 1_565 7_556 ?
Sb2 Rb3 Rb2 129.41(8) 5_566 7_556 ?
Sb2 Rb3 Rb2 60.55(3) 5_556 7_556 ?
Rb2 Rb3 Rb2 95.47(6) 7_566 7_556 ?
Rb3 Rb3 Rb1 110.5(5) 5_566 7_556 ?
Sb2 Rb3 Rb1 128.51(4) . 7_556 ?
Sb2 Rb3 Rb1 128.51(4) 1_565 7_556 ?
Sb2 Rb3 Rb1 57.31(4) 5_566 7_556 ?
Sb2 Rb3 Rb1 57.31(4) 5_556 7_556 ?
Rb2 Rb3 Rb1 74.01(5) 7_566 7_556 ?
Rb2 Rb3 Rb1 74.01(5) 7_556 7_556 ?
Rb3 Rb3 Rb2 118.3(5) 5_566 . ?
Sb2 Rb3 Rb2 58.32(5) . . ?
Sb2 Rb3 Rb2 58.32(5) 1_565 . ?
Sb2 Rb3 Rb2 128.75(4) 5_566 . ?
Sb2 Rb3 Rb2 128.75(4) 5_556 . ?
Rb2 Rb3 Rb2 73.69(5) 7_566 . ?
Rb2 Rb3 Rb2 73.69(5) 7_556 . ?
Rb1 Rb3 Rb2 131.13(6) 7_556 . ?
Rb3 Rb3 Rb2 39.91(3) 5_566 3_445 ?
Sb2 Rb3 Rb2 55.08(2) . 3_445 ?
Sb2 Rb3 Rb2 114.24(6) 1_565 3_445 ?
Sb2 Rb3 Rb2 113.46(7) 5_566 3_445 ?
Sb2 Rb3 Rb2 54.77(3) 5_556 3_445 ?
Rb2 Rb3 Rb2 172.07(5) 7_566 3_445 ?
Rb2 Rb3 Rb2 92.430(18) 7_556 3_445 ?
Rb1 Rb3 Rb2 107.69(6) 7_556 3_445 ?
Rb2 Rb3 Rb2 109.35(6) . 3_445 ?
Rb3 Rb3 Rb2 39.91(3) 5_566 3_455 ?
Sb2 Rb3 Rb2 114.24(6) . 3_455 ?
Sb2 Rb3 Rb2 55.08(2) 1_565 3_455 ?
Sb2 Rb3 Rb2 54.77(3) 5_566 3_455 ?
Sb2 Rb3 Rb2 113.46(7) 5_556 3_455 ?
Rb2 Rb3 Rb2 92.430(17) 7_566 3_455 ?
Rb2 Rb3 Rb2 172.07(5) 7_556 3_455 ?
Rb1 Rb3 Rb2 107.69(6) 7_556 3_455 ?
Rb2 Rb3 Rb2 109.35(6) . 3_455 ?
Rb2 Rb3 Rb2 79.66(4) 3_445 3_455 ?
Rb3 Rb3 Rb1 59.4(5) 5_566 3_455 ?
Sb2 Rb3 Rb1 54.11(4) . 3_455 ?
Sb2 Rb3 Rb1 54.11(4) 1_565 3_455 ?
Sb2 Rb3 Rb1 117.96(4) 5_566 3_455 ?
Sb2 Rb3 Rb1 117.96(4) 5_556 3_455 ?
Rb2 Rb3 Rb1 112.25(6) 7_566 3_455 ?
Rb2 Rb3 Rb1 112.25(6) 7_556 3_455 ?
Rb1 Rb3 Rb1 169.92(7) 7_556 3_455 ?
Rb2 Rb3 Rb1 58.94(5) . 3_455 ?
Rb2 Rb3 Rb1 65.01(3) 3_445 3_455 ?
Rb2 Rb3 Rb1 65.01(3) 3_455 3_455 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 Sb2 2.8006(7) . ?
Sb1 Sb1 2.8292(9) 5 ?
Sb1 Rb1 3.7724(9) . ?
Sb1 Rb1 3.8047(6) 7_545 ?
Sb1 Rb1 3.8047(6) 7 ?
Sb1 Rb2 3.8189(6) . ?
Sb1 Rb2 3.8189(6) 1_545 ?
Sb1 Rb1 3.8909(6) 3_445 ?
Sb1 Rb1 3.8909(6) 3_455 ?
Sb2 Rb3 3.748(2) 1_545 ?
Sb2 Rb3 3.748(2) . ?
Sb2 Rb3 3.779(2) 5_566 ?
Sb2 Rb3 3.779(2) 5_556 ?
Sb2 Rb2 3.8655(9) 3_445 ?
Sb2 Rb1 3.7939(6) 3_445 ?
Sb2 Rb1 3.7939(6) 3_455 ?
Sb2 Rb2 3.8553(9) 7_556 ?
Sb2 Rb2 3.8331(6) . ?
Sb2 Rb2 3.8331(6) 1_545 ?
Rb1 Sb2 3.7939(5) 3 ?
Rb1 Sb2 3.7939(6) 3_545 ?
Rb1 Sb1 3.8047(6) 7_545 ?
Rb1 Sb1 3.8047(6) 7 ?
Rb1 Sb1 3.8910(6) 3 ?
Rb1 Sb1 3.8910(6) 3_545 ?
Rb1 Rb3 4.109(3) 7_556 ?
Rb1 Rb1 4.2595(14) 5_655 ?
Rb1 Rb2 4.2272(12) 3_545 ?
Rb1 Rb3 4.471(3) 3_545 ?
Rb1 Rb1 4.5103(11) 7_545 ?
Rb2 Sb2 3.8656(9) 3 ?
Rb2 Sb2 3.8553(9) 7_556 ?
Rb2 Sb1 3.8189(6) 1_565 ?
Rb2 Rb3 3.8861(17) 7_566 ?
Rb2 Rb3 3.8861(17) 7_556 ?
Rb2 Sb2 3.8330(6) 1_565 ?
Rb2 Rb3 4.094(3) . ?
Rb2 Rb1 4.2271(12) 3_455 ?
Rb2 Rb3 4.4899(19) 3 ?
Rb2 Rb3 4.4899(19) 3_545 ?
Rb3 Rb3 0.836(5) 5_566 ?
Rb3 Sb2 3.748(2) 1_565 ?
Rb3 Sb2 3.779(2) 5_566 ?
Rb3 Sb2 3.779(2) 5_556 ?
Rb3 Rb2 3.8861(17) 7_566 ?
Rb3 Rb2 3.8861(17) 7_556 ?
Rb3 Rb1 4.109(3) 7_556 ?
Rb3 Rb2 4.4899(19) 3_445 ?
Rb3 Rb2 4.4899(19) 3_455 ?
Rb3 Rb1 4.471(3) 3_455 ?
