#------------------------------------------------------------------------------
#$Date: 2016-03-23 14:47:32 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179306 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/03/4320329.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4320329
loop_
_publ_author_name
'Franck Gascoin'
'Slavi C. Sevov'
_publ_section_title
;
 Synthesis and Characterization of the "Metallic Salts" A5Pn4 (A = K, Rb,
 Cs and Pn = As, Sb, Bi) with Isolated Zigzag Tetramers of Pn44- and an
 Extra Delocalized Electron
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5177
_journal_page_last               5181
_journal_paper_doi               10.1021/ic0104499
_journal_volume                  40
_journal_year                    2001
_chemical_formula_moiety         Rb5Bi4
_chemical_formula_sum            'Bi4 Rb5'
_chemical_formula_weight         1263.27
_chemical_melting_point          ?
_chemical_name_common            Rb5Bi4
_chemical_name_systematic
;
   ?
;
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 112.78(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   12.945(4)
_cell_length_b                   5.7851(9)
_cell_length_c                   12.018(5)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      16.535
_cell_measurement_theta_min      9.899
_cell_volume                     829.8(5)
_computing_cell_refinement       'CAD4_(Enraf Nonius,_1977)'
_computing_data_collection       'CAD4_(Enraf Nonius,_1977)'
_computing_data_reduction        SDS_Package_(Enraf-Nonius,_1985)
_computing_molecular_graphics    'SHELXTL (Siemens, 1994)'
_computing_publication_material  'SHELXTL (Siemens, 1994)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  Enraf_Nonius_CAD4
_diffrn_measurement_method       omega-2theta
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            807
_diffrn_reflns_theta_full        24.95
_diffrn_reflns_theta_max         24.95
_diffrn_reflns_theta_min         3.19
_diffrn_standards_interval_count 200
_diffrn_standards_interval_time  120
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    56.811
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.3170
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   Xabs
_exptl_crystal_colour            'gray, metallic luster'
_exptl_crystal_density_diffrn    5.056
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1034
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         3.185
_refine_diff_density_min         -3.710
_refine_diff_density_rms         0.535
_refine_ls_extinction_coef       0.00004(16)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     32
_refine_ls_number_reflns         807
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.0666
_refine_ls_R_factor_gt           0.0510
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1053P)²+16.2596P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1395
_refine_ls_wR_factor_ref         0.1491
_reflns_number_gt                633
_reflns_number_total             807
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0104499_5.cif
_cod_data_source_block           Rb5Bi4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        829.8(4)
_cod_database_code               4320329
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.10893(8) 0.0000 0.11276(10) 0.0306(5) Uani 1 2 d S . .
Bi2 Bi 0.04725(9) 0.0000 0.32835(10) 0.0339(5) Uani 1 2 d S . .
Rb1 Rb 0.4011(2) 0.0000 0.1063(3) 0.0333(7) Uani 1 2 d S . .
Rb2 Rb 0.2468(2) 0.5000 0.3319(3) 0.0453(8) Uani 1 2 d S . .
Rb3 Rb 0.0374(8) 0.5000 0.5221(10) 0.065(4) Uani 0.50 2 d SP . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Bi2 Bi1 Bi1 107.66(6) . 5 ?
Bi2 Bi1 Rb1 128.10(6) . . ?
Bi1 Bi1 Rb1 124.25(7) 5 . ?
Bi2 Bi1 Rb2 67.46(5) . 1_545 ?
Bi1 Bi1 Rb2 128.97(4) 5 1_545 ?
Rb1 Bi1 Rb2 79.23(6) . 1_545 ?
Bi2 Bi1 Rb2 67.46(5) . . ?
Bi1 Bi1 Rb2 128.97(4) 5 . ?
Rb1 Bi1 Rb2 79.23(6) . . ?
Rb2 Bi1 Rb2 97.30(8) 1_545 . ?
Bi2 Bi1 Rb1 129.62(4) . 7_545 ?
Bi1 Bi1 Rb1 67.80(5) 5 7_545 ?
Rb1 Bi1 Rb1 76.05(6) . 7_545 ?
Rb2 Bi1 Rb1 77.81(6) 1_545 7_545 ?
Rb2 Bi1 Rb1 155.28(7) . 7_545 ?
Bi2 Bi1 Rb1 129.62(4) . 7 ?
Bi1 Bi1 Rb1 67.80(5) 5 7 ?
Rb1 Bi1 Rb1 76.05(6) . 7 ?
Rb2 Bi1 Rb1 155.28(7) 1_545 7 ?
Rb2 Bi1 Rb1 77.81(6) . 7 ?
Rb1 Bi1 Rb1 96.42(7) 7_545 7 ?
Bi2 Bi1 Rb1 66.86(5) . 3_445 ?
Bi1 Bi1 Rb1 66.03(5) 5 3_445 ?
Rb1 Bi1 Rb1 132.56(3) . 3_445 ?
Rb2 Bi1 Rb1 66.02(6) 1_545 3_445 ?
Rb2 Bi1 Rb1 134.30(7) . 3_445 ?
Rb1 Bi1 Rb1 66.12(7) 7_545 3_445 ?
Rb1 Bi1 Rb1 133.83(4) 7 3_445 ?
Bi2 Bi1 Rb1 66.86(5) . 3_455 ?
Bi1 Bi1 Rb1 66.03(5) 5 3_455 ?
Rb1 Bi1 Rb1 132.56(3) . 3_455 ?
Rb2 Bi1 Rb1 134.30(7) 1_545 3_455 ?
Rb2 Bi1 Rb1 66.02(6) . 3_455 ?
Rb1 Bi1 Rb1 133.83(4) 7_545 3_455 ?
Rb1 Bi1 Rb1 66.12(7) 7 3_455 ?
Rb1 Bi1 Rb1 94.77(6) 3_445 3_455 ?
Bi1 Bi2 Rb3 128.53(14) . 1_545 ?
Bi1 Bi2 Rb3 128.53(14) . . ?
Rb3 Bi2 Rb3 101.1(3) 1_545 . ?
Bi1 Bi2 Rb3 129.39(14) . 5_566 ?
Rb3 Bi2 Rb3 102.07(4) 1_545 5_566 ?
Rb3 Bi2 Rb3 13.8(3) . 5_566 ?
Bi1 Bi2 Rb3 129.39(14) . 5_556 ?
Rb3 Bi2 Rb3 13.8(3) 1_545 5_556 ?
Rb3 Bi2 Rb3 102.07(4) . 5_556 ?
Rb3 Bi2 Rb3 99.7(3) 5_566 5_556 ?
Bi1 Bi2 Rb2 66.94(6) . 1_545 ?
Rb3 Bi2 Rb2 66.37(15) 1_545 1_545 ?
Rb3 Bi2 Rb2 138.94(15) . 1_545 ?
Rb3 Bi2 Rb2 151.82(16) 5_566 1_545 ?
Rb3 Bi2 Rb2 74.82(13) 5_556 1_545 ?
Bi1 Bi2 Rb2 66.94(6) . . ?
Rb3 Bi2 Rb2 138.94(15) 1_545 . ?
Rb3 Bi2 Rb2 66.37(15) . . ?
Rb3 Bi2 Rb2 74.82(13) 5_566 . ?
Rb3 Bi2 Rb2 151.82(16) 5_556 . ?
Rb2 Bi2 Rb2 96.82(7) 1_545 . ?
Bi1 Bi2 Rb1 68.18(5) . 3_445 ?
Rb3 Bi2 Rb1 74.21(15) 1_545 3_445 ?
Rb3 Bi2 Rb1 151.07(15) . 3_445 ?
Rb3 Bi2 Rb1 137.74(14) 5_566 3_445 ?
Rb3 Bi2 Rb1 66.69(16) 5_556 3_445 ?
Rb2 Bi2 Rb1 66.24(6) 1_545 3_445 ?
Rb2 Bi2 Rb1 135.11(7) . 3_445 ?
Bi1 Bi2 Rb1 68.18(5) . 3_455 ?
Rb3 Bi2 Rb1 151.07(15) 1_545 3_455 ?
Rb3 Bi2 Rb1 74.21(15) . 3_455 ?
Rb3 Bi2 Rb1 66.69(16) 5_566 3_455 ?
Rb3 Bi2 Rb1 137.74(14) 5_556 3_455 ?
Rb2 Bi2 Rb1 135.11(7) 1_545 3_455 ?
Rb2 Bi2 Rb1 66.24(6) . 3_455 ?
Rb1 Bi2 Rb1 95.97(7) 3_445 3_455 ?
Bi1 Bi2 Rb2 127.59(7) . 3_445 ?
Rb3 Bi2 Rb2 73.72(15) 1_545 3_445 ?
Rb3 Bi2 Rb2 73.72(15) . 3_445 ?
Rb3 Bi2 Rb2 61.46(13) 5_566 3_445 ?
Rb3 Bi2 Rb2 61.46(13) 5_556 3_445 ?
Rb2 Bi2 Rb2 131.58(4) 1_545 3_445 ?
Rb2 Bi2 Rb2 131.58(4) . 3_445 ?
Rb1 Bi2 Rb2 77.62(6) 3_445 3_445 ?
Rb1 Bi2 Rb2 77.62(6) 3_455 3_445 ?
Bi1 Bi2 Rb2 126.91(6) . 7_556 ?
Rb3 Bi2 Rb2 61.66(14) 1_545 7_556 ?
Rb3 Bi2 Rb2 61.66(14) . 7_556 ?
Rb3 Bi2 Rb2 73.17(16) 5_566 7_556 ?
Rb3 Bi2 Rb2 73.17(16) 5_556 7_556 ?
Rb2 Bi2 Rb2 78.85(7) 1_545 7_556 ?
Rb2 Bi2 Rb2 78.85(7) . 7_556 ?
Rb1 Bi2 Rb2 131.94(4) 3_445 7_556 ?
Rb1 Bi2 Rb2 131.94(4) 3_455 7_556 ?
Rb2 Bi2 Rb2 105.50(6) 3_445 7_556 ?
Bi1 Rb1 Bi1 103.95(6) . 7_545 ?
Bi1 Rb1 Bi1 103.95(6) . 7 ?
Bi1 Rb1 Bi1 96.42(7) 7_545 7 ?
Bi1 Rb1 Bi2 102.05(6) . 3 ?
Bi1 Rb1 Bi2 153.99(8) 7_545 3 ?
Bi1 Rb1 Bi2 77.93(3) 7 3 ?
Bi1 Rb1 Bi2 102.05(6) . 3_545 ?
Bi1 Rb1 Bi2 77.93(3) 7_545 3_545 ?
Bi1 Rb1 Bi2 153.99(8) 7 3_545 ?
Bi2 Rb1 Bi2 95.97(7) 3 3_545 ?
Bi1 Rb1 Bi1 132.56(3) . 3 ?
Bi1 Rb1 Bi1 113.88(7) 7_545 3 ?
Bi1 Rb1 Bi1 46.17(4) 7 3 ?
Bi2 Rb1 Bi1 44.96(3) 3 3 ?
Bi2 Rb1 Bi1 112.70(7) 3_545 3 ?
Bi1 Rb1 Bi1 132.56(3) . 3_545 ?
Bi1 Rb1 Bi1 46.17(4) 7_545 3_545 ?
Bi1 Rb1 Bi1 113.88(7) 7 3_545 ?
Bi2 Rb1 Bi1 112.70(7) 3 3_545 ?
Bi2 Rb1 Bi1 44.96(3) 3_545 3_545 ?
Bi1 Rb1 Bi1 94.77(6) 3 3_545 ?
Bi1 Rb1 Rb3 76.16(15) . 7_556 ?
Bi1 Rb1 Rb3 131.37(4) 7_545 7_556 ?
Bi1 Rb1 Rb3 131.37(4) 7 7_556 ?
Bi2 Rb1 Rb3 55.42(7) 3 7_556 ?
Bi2 Rb1 Rb3 55.42(7) 3_545 7_556 ?
Bi1 Rb1 Rb3 97.57(10) 3 7_556 ?
Bi1 Rb1 Rb3 97.57(10) 3_545 7_556 ?
Bi1 Rb1 Rb2 142.82(10) . 3_545 ?
Bi1 Rb1 Rb2 100.57(6) 7_545 3_545 ?
Bi1 Rb1 Rb2 100.57(6) 7 3_545 ?
Bi2 Rb1 Rb2 56.59(4) 3 3_545 ?
Bi2 Rb1 Rb2 56.59(4) 3_545 3_545 ?
Bi1 Rb1 Rb2 56.11(4) 3 3_545 ?
Bi1 Rb1 Rb2 56.11(4) 3_545 3_545 ?
Rb3 Rb1 Rb2 66.66(15) 7_556 3_545 ?
Bi1 Rb1 Rb1 147.51(12) . 5_655 ?
Bi1 Rb1 Rb1 57.52(5) 7_545 5_655 ?
Bi1 Rb1 Rb1 57.52(5) 7 5_655 ?
Bi2 Rb1 Rb1 99.53(7) 3 5_655 ?
Bi2 Rb1 Rb1 99.53(7) 3_545 5_655 ?
Bi1 Rb1 Rb1 56.36(4) 3 5_655 ?
Bi1 Rb1 Rb1 56.36(4) 3_545 5_655 ?
Rb3 Rb1 Rb1 136.33(17) 7_556 5_655 ?
Rb2 Rb1 Rb1 69.68(9) 3_545 5_655 ?
Bi1 Rb1 Rb3 86.81(13) . 3_545 ?
Bi1 Rb1 Rb3 129.33(5) 7_545 3_545 ?
Bi1 Rb1 Rb3 129.33(5) 7 3_545 ?
Bi2 Rb1 Rb3 51.44(5) 3 3_545 ?
Bi2 Rb1 Rb3 51.44(5) 3_545 3_545 ?
Bi1 Rb1 Rb3 90.39(10) 3 3_545 ?
Bi1 Rb1 Rb3 90.39(10) 3_545 3_545 ?
Rb3 Rb1 Rb3 10.7(2) 7_556 3_545 ?
Rb2 Rb1 Rb3 56.01(14) 3_545 3_545 ?
Rb1 Rb1 Rb3 125.68(15) 5_655 3_545 ?
Bi1 Rb1 Rb1 52.61(5) . 7_545 ?
Bi1 Rb1 Rb1 51.34(4) 7_545 7_545 ?
Bi1 Rb1 Rb1 106.59(9) 7 7_545 ?
Bi2 Rb1 Rb1 154.65(10) 3 7_545 ?
Bi2 Rb1 Rb1 89.81(4) 3_545 7_545 ?
Bi1 Rb1 Rb1 151.12(11) 3 7_545 ?
Bi1 Rb1 Rb1 88.70(4) 3_545 7_545 ?
Rb3 Rb1 Rb1 110.40(13) 7_556 7_545 ?
Rb2 Rb1 Rb1 142.30(4) 3_545 7_545 ?
Rb1 Rb1 Rb1 103.83(11) 5_655 7_545 ?
Rb3 Rb1 Rb1 118.30(12) 3_545 7_545 ?
Bi1 Rb2 Bi1 97.30(8) . 1_565 ?
Bi1 Rb2 Bi2 45.60(3) . . ?
Bi1 Rb2 Bi2 115.04(8) 1_565 . ?
Bi1 Rb2 Bi2 115.04(8) . 1_565 ?
Bi1 Rb2 Bi2 45.60(3) 1_565 1_565 ?
Bi2 Rb2 Bi2 96.81(7) . 1_565 ?
Bi1 Rb2 Bi2 101.10(7) . 3 ?
Bi1 Rb2 Bi2 101.09(7) 1_565 3 ?
Bi2 Rb2 Bi2 131.58(4) . 3 ?
Bi2 Rb2 Bi2 131.58(4) 1_565 3 ?
Bi1 Rb2 Bi2 131.33(4) . 7_556 ?
Bi1 Rb2 Bi2 131.33(4) 1_565 7_556 ?
Bi2 Rb2 Bi2 101.15(7) . 7_556 ?
Bi2 Rb2 Bi2 101.15(7) 1_565 7_556 ?
Bi2 Rb2 Bi2 74.50(6) 3 7_556 ?
Bi1 Rb2 Rb3 156.72(19) . 7_566 ?
Bi1 Rb2 Rb3 79.27(12) 1_565 7_566 ?
Bi2 Rb2 Rb3 155.7(2) . 7_566 ?
Bi2 Rb2 Rb3 79.09(11) 1_565 7_566 ?
Bi2 Rb2 Rb3 57.75(14) 3 7_566 ?
Bi2 Rb2 Rb3 57.02(15) 7_556 7_566 ?
Bi1 Rb2 Rb3 79.27(12) . 7_556 ?
Bi1 Rb2 Rb3 156.72(19) 1_565 7_556 ?
Bi2 Rb2 Rb3 79.09(11) . 7_556 ?
Bi2 Rb2 Rb3 155.7(2) 1_565 7_556 ?
Bi2 Rb2 Rb3 57.75(14) 3 7_556 ?
Bi2 Rb2 Rb3 57.02(15) 7_556 7_556 ?
Rb3 Rb2 Rb3 94.8(2) 7_566 7_556 ?
Bi1 Rb2 Rb3 98.47(11) . . ?
Bi1 Rb2 Rb3 98.47(11) 1_565 . ?
Bi2 Rb2 Rb3 55.42(7) . . ?
Bi2 Rb2 Rb3 55.42(7) 1_565 . ?
Bi2 Rb2 Rb3 150.19(17) 3 . ?
Bi2 Rb2 Rb3 75.69(16) 7_556 . ?
Rb3 Rb2 Rb3 104.81(17) 7_566 . ?
Rb3 Rb2 Rb3 104.81(17) 7_556 . ?
Bi1 Rb2 Rb1 57.87(5) . 3_455 ?
Bi1 Rb2 Rb1 57.87(5) 1_565 3_455 ?
Bi2 Rb2 Rb1 57.17(5) . 3_455 ?
Bi2 Rb2 Rb1 57.17(5) 1_565 3_455 ?
Bi2 Rb2 Rb1 143.32(11) 3 3_455 ?
Bi2 Rb2 Rb1 142.18(10) 7_556 3_455 ?
Rb3 Rb2 Rb1 132.61(10) 7_566 3_455 ?
Rb3 Rb2 Rb1 132.61(11) 7_556 3_455 ?
Rb3 Rb2 Rb1 66.49(15) . 3_455 ?
Bi1 Rb2 Rb3 152.45(15) . 3 ?
Bi1 Rb2 Rb3 86.61(10) 1_565 3 ?
Bi2 Rb2 Rb3 153.06(16) . 3 ?
Bi2 Rb2 Rb3 87.09(9) 1_565 3 ?
Bi2 Rb2 Rb3 51.55(13) 3 3 ?
Bi2 Rb2 Rb3 52.08(13) 7_556 3 ?
Rb3 Rb2 Rb3 8.38(17) 7_566 3 ?
Rb3 Rb2 Rb3 86.43(7) 7_556 3 ?
Rb3 Rb2 Rb3 107.9(2) . 3 ?
Rb1 Rb2 Rb3 140.96(8) 3_455 3 ?
Bi1 Rb2 Rb3 86.61(10) . 3_545 ?
Bi1 Rb2 Rb3 152.45(15) 1_565 3_545 ?
Bi2 Rb2 Rb3 87.09(9) . 3_545 ?
Bi2 Rb2 Rb3 153.06(16) 1_565 3_545 ?
Bi2 Rb2 Rb3 51.55(13) 3 3_545 ?
Bi2 Rb2 Rb3 52.08(13) 7_556 3_545 ?
Rb3 Rb2 Rb3 86.43(6) 7_566 3_545 ?
Rb3 Rb2 Rb3 8.38(17) 7_556 3_545 ?
Rb3 Rb2 Rb3 107.9(2) . 3_545 ?
Rb1 Rb2 Rb3 140.96(8) 3_455 3_545 ?
Rb3 Rb2 Rb3 78.09(15) 3 3_545 ?
Rb3 Rb3 Bi2 85.5(10) 5_566 1_565 ?
Rb3 Rb3 Bi2 85.5(10) 5_566 . ?
Bi2 Rb3 Bi2 101.1(3) 1_565 . ?
Rb3 Rb3 Bi2 80.7(9) 5_566 5_566 ?
Bi2 Rb3 Bi2 77.93(4) 1_565 5_566 ?
Bi2 Rb3 Bi2 166.2(3) . 5_566 ?
Rb3 Rb3 Bi2 80.7(9) 5_566 5_556 ?
Bi2 Rb3 Bi2 166.2(3) 1_565 5_556 ?
Bi2 Rb3 Bi2 77.93(4) . 5_556 ?
Bi2 Rb3 Bi2 99.7(3) 5_566 5_556 ?
Rb3 Rb3 Rb2 132.45(16) 5_566 7_566 ?
Bi2 Rb3 Rb2 61.32(9) 1_565 7_566 ?
Bi2 Rb3 Rb2 131.0(3) . 7_566 ?
Bi2 Rb3 Rb2 60.79(9) 5_566 7_566 ?
Bi2 Rb3 Rb2 129.6(3) 5_556 7_566 ?
Rb3 Rb3 Rb2 132.45(16) 5_566 7_556 ?
Bi2 Rb3 Rb2 131.0(3) 1_565 7_556 ?
Bi2 Rb3 Rb2 61.32(9) . 7_556 ?
Bi2 Rb3 Rb2 129.6(3) 5_566 7_556 ?
Bi2 Rb3 Rb2 60.79(9) 5_556 7_556 ?
Rb2 Rb3 Rb2 94.8(2) 7_566 7_556 ?
Rb3 Rb3 Rb2 116.9(16) 5_566 . ?
Bi2 Rb3 Rb2 58.21(16) 1_565 . ?
Bi2 Rb3 Rb2 58.21(16) . . ?
Bi2 Rb3 Rb2 129.04(13) 5_566 . ?
Bi2 Rb3 Rb2 129.04(13) 5_556 . ?
Rb2 Rb3 Rb2 75.18(17) 7_566 . ?
Rb2 Rb3 Rb2 75.18(17) 7_556 . ?
Rb3 Rb3 Rb1 110.0(16) 5_566 7_556 ?
Bi2 Rb3 Rb1 128.29(14) 1_565 7_556 ?
Bi2 Rb3 Rb1 128.29(14) . 7_556 ?
Bi2 Rb3 Rb1 57.89(16) 5_566 7_556 ?
Bi2 Rb3 Rb1 57.89(16) 5_556 7_556 ?
Rb2 Rb3 Rb1 73.58(18) 7_566 7_556 ?
Rb2 Rb3 Rb1 73.58(18) 7_556 7_556 ?
Rb2 Rb3 Rb1 133.1(2) . 7_556 ?
Rb3 Rb3 Rb2 39.18(14) 5_566 3_445 ?
Bi2 Rb3 Rb2 113.3(2) 1_565 3_445 ?
Bi2 Rb3 Rb2 54.73(10) . 3_445 ?
Bi2 Rb3 Rb2 112.7(2) 5_566 3_445 ?
Bi2 Rb3 Rb2 54.76(9) 5_556 3_445 ?
Rb2 Rb3 Rb2 171.62(17) 7_566 3_445 ?
Rb2 Rb3 Rb2 93.57(7) 7_556 3_445 ?
Rb2 Rb3 Rb2 107.9(2) . 3_445 ?
Rb1 Rb3 Rb2 108.0(2) 7_556 3_445 ?
Rb3 Rb3 Rb2 39.18(13) 5_566 3_455 ?
Bi2 Rb3 Rb2 54.73(10) 1_565 3_455 ?
Bi2 Rb3 Rb2 113.3(2) . 3_455 ?
Bi2 Rb3 Rb2 54.76(9) 5_566 3_455 ?
Bi2 Rb3 Rb2 112.7(2) 5_556 3_455 ?
Rb2 Rb3 Rb2 93.57(7) 7_566 3_455 ?
Rb2 Rb3 Rb2 171.62(17) 7_556 3_455 ?
Rb2 Rb3 Rb2 107.9(2) . 3_455 ?
Rb1 Rb3 Rb2 108.0(2) 7_556 3_455 ?
Rb2 Rb3 Rb2 78.09(15) 3_445 3_455 ?
Rb3 Rb3 Rb1 59.4(14) 5_566 3_455 ?
Bi2 Rb3 Rb1 54.35(15) 1_565 3_455 ?
Bi2 Rb3 Rb1 54.35(15) . 3_455 ?
Bi2 Rb3 Rb1 117.06(17) 5_566 3_455 ?
Bi2 Rb3 Rb1 117.06(17) 5_556 3_455 ?
Rb2 Rb3 Rb1 113.0(2) 7_566 3_455 ?
Rb2 Rb3 Rb1 113.0(2) 7_556 3_455 ?
Rb2 Rb3 Rb1 57.50(16) . 3_455 ?
Rb1 Rb3 Rb1 169.3(2) 7_556 3_455 ?
Rb2 Rb3 Rb1 64.17(14) 3_445 3_455 ?
Rb2 Rb3 Rb1 64.17(14) 3_455 3_455 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Bi1 Bi2 2.9919(19) . ?
Bi1 Bi1 3.063(2) 5 ?
Bi1 Rb1 3.813(3) . ?
Bi1 Rb2 3.853(2) 1_545 ?
Bi1 Rb2 3.853(2) . ?
Bi1 Rb1 3.879(2) 7_545 ?
Bi1 Rb1 3.879(2) 7 ?
Bi1 Rb1 3.931(2) 3_445 ?
Bi1 Rb1 3.931(2) 3_455 ?
Bi2 Rb3 3.746(8) 1_545 ?
Bi2 Rb3 3.746(8) . ?
Bi2 Rb3 3.784(8) 5_566 ?
Bi2 Rb3 3.784(8) 5_556 ?
Bi2 Rb2 3.868(2) 1_545 ?
Bi2 Rb2 3.868(2) . ?
Bi2 Rb1 3.893(2) 3_445 ?
Bi2 Rb1 3.893(2) 3_455 ?
Bi2 Rb2 3.906(3) 3_445 ?
Bi2 Rb2 3.918(4) 7_556 ?
Rb1 Bi1 3.879(2) 7_545 ?
Rb1 Bi1 3.879(2) 7 ?
Rb1 Bi2 3.893(2) 3 ?
Rb1 Bi2 3.893(2) 3_545 ?
Rb1 Bi1 3.931(2) 3 ?
Rb1 Bi1 3.931(2) 3_545 ?
Rb1 Rb3 4.221(12) 7_556 ?
Rb1 Rb2 4.241(4) 3_545 ?
Rb1 Rb1 4.261(6) 5_655 ?
Rb1 Rb3 4.611(12) 3_545 ?
Rb1 Rb1 4.739(4) 7_545 ?
Rb2 Bi1 3.853(2) 1_565 ?
Rb2 Bi2 3.868(2) 1_565 ?
Rb2 Bi2 3.906(3) 3 ?
Rb2 Bi2 3.918(4) 7_556 ?
Rb2 Rb3 3.931(7) 7_566 ?
Rb2 Rb3 3.931(7) 7_556 ?
Rb2 Rb3 4.169(12) . ?
Rb2 Rb1 4.241(4) 3_455 ?
Rb2 Rb3 4.592(8) 3 ?
Rb2 Rb3 4.592(8) 3_545 ?
Rb3 Rb3 0.907(18) 5_566 ?
Rb3 Bi2 3.746(8) 1_565 ?
Rb3 Bi2 3.784(8) 5_566 ?
Rb3 Bi2 3.784(8) 5_556 ?
Rb3 Rb2 3.931(7) 7_566 ?
Rb3 Rb2 3.931(7) 7_556 ?
Rb3 Rb1 4.221(12) 7_556 ?
Rb3 Rb2 4.592(8) 3_445 ?
Rb3 Rb2 4.592(8) 3_455 ?
Rb3 Rb1 4.611(12) 3_455 ?
