#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/03/4320345.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4320345
loop_
_publ_author_name
'José Ruiz'
'Venancio Rodríguez'
'Consuelo Vicente'
'José M. Martí'
'Gregorio López'
'José Pérez'
_publ_section_title
;
 Synthesis and Reactivity of Bridging and Terminal Hydrosulfido Palladium
 and Platinum Complexes. Crystal Structures of
 [NBu4]2[{Pt(C6F5)2(μ-SH)}2], [Pt(C6F5)2(PPh3){S(H)AgPPh3}], and
 [Pt(C6F5)2(PPh3){S(AuPPh3)2}]
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5354
_journal_page_last               5360
_journal_paper_doi               10.1021/ic0013633
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C66.25 H45.5 Au2 Cl0.5 F10 P3 Pt S'
_chemical_formula_weight         1763.24
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     Patterson
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 104.7030(10)
_cell_angle_gamma                90
_cell_formula_units_Z            16
_cell_length_a                   62.6035(9)
_cell_length_b                   13.0329(2)
_cell_length_c                   32.0828(5)
_cell_measurement_temperature    293(2)
_cell_volume                     25319.4(7)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.000
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0804
_diffrn_reflns_limit_h_max       74
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -38
_diffrn_reflns_number            22862
_diffrn_reflns_theta_full        0.50
_diffrn_reflns_theta_max         25.24
_diffrn_reflns_theta_min         0.67
_exptl_absorpt_coefficient_mu    7.027
_exptl_absorpt_correction_type   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.850
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             13416
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.429
_refine_diff_density_min         -1.512
_refine_diff_density_rms         0.300
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.081
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           fullcycle
_refine_ls_number_parameters     1524
_refine_ls_number_reflns         22862
_refine_ls_number_restraints     63
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.1079
_refine_ls_R_factor_gt           0.0619
_refine_ls_shift/su_max          0.031
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0756P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1374
_refine_ls_wR_factor_ref         0.1594
_reflns_number_gt                15334
_reflns_number_total             22862
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0013633_3.cif
_cod_data_source_block           complex12
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        25319.3(7)
_cod_original_formula_sum        'C66.25 H45.50 Au2 Cl0.50 F10 P3 Pt S'
_cod_database_code               4320345
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.189345(8) 0.33786(3) 0.130249(14) 0.04101(13) Uani 1 1 d . . .
C1 C 0.18383(19) 0.4882(8) 0.1425(3) 0.042(3) Uani 1 1 d . . .
C2 C 0.19766(18) 0.5460(8) 0.1744(4) 0.044(3) Uani 1 1 d . . .
F2 F 0.21528(12) 0.4989(5) 0.2003(2) 0.070(2) Uani 1 1 d . . .
C3 C 0.1954(2) 0.6481(9) 0.1800(4) 0.060(4) Uani 1 1 d . . .
F3 F 0.21068(16) 0.6984(6) 0.2115(3) 0.095(3) Uani 1 1 d . . .
C4 C 0.1784(3) 0.7009(9) 0.1550(5) 0.075(4) Uani 1 1 d . . .
F4 F 0.17565(16) 0.8020(6) 0.1606(3) 0.106(3) Uani 1 1 d . . .
C5 C 0.1639(2) 0.6487(9) 0.1223(5) 0.064(4) Uani 1 1 d . . .
F5 F 0.14699(16) 0.7006(6) 0.0965(3) 0.107(3) Uani 1 1 d . . .
C6 C 0.1661(2) 0.5463(9) 0.1174(4) 0.049(3) Uani 1 1 d . . .
F6 F 0.15139(13) 0.4989(6) 0.0853(2) 0.076(2) Uani 1 1 d . . .
C7 C 0.2100(2) 0.3956(8) 0.0976(4) 0.054(3) Uani 1 1 d . . .
C8 C 0.2033(2) 0.4351(9) 0.0552(4) 0.062(4) Uani 1 1 d D . .
F8 F 0.18213(15) 0.4285(7) 0.0344(2) 0.085(3) Uani 1 1 d . . .
C9 C 0.2179(3) 0.4794(10) 0.0338(4) 0.084(5) Uani 1 1 d D . .
F9 F 0.21037(19) 0.5133(7) -0.0057(3) 0.122(4) Uani 1 1 d D . .
C10 C 0.2398(3) 0.4882(11) 0.0537(5) 0.102(7) Uani 1 1 d D . .
F10 F 0.2539(2) 0.5345(8) 0.0353(4) 0.146(5) Uani 1 1 d . . .
C11 C 0.2472(3) 0.4536(12) 0.0944(6) 0.103(7) Uani 1 1 d D . .
F11 F 0.26959(18) 0.4530(10) 0.1168(4) 0.147(5) Uani 1 1 d . . .
C12 C 0.2327(3) 0.4063(9) 0.1162(4) 0.065(4) Uani 1 1 d D . .
F12 F 0.24161(14) 0.3673(7) 0.1561(3) 0.091(3) Uani 1 1 d . . .
P1 P 0.19768(5) 0.1713(2) 0.11946(9) 0.0415(7) Uani 1 1 d . . .
C13 C 0.1755(2) 0.0913(8) 0.0891(3) 0.046(3) Uani 1 1 d . . .
C14 C 0.1548(2) 0.1292(10) 0.0757(4) 0.062(4) Uani 1 1 d . . .
H14 H 0.1520 0.1968 0.0822 0.074 Uiso 1 1 calc R . .
C15 C 0.1374(2) 0.0678(13) 0.0524(4) 0.078(5) Uani 1 1 d . . .
H15 H 0.1231 0.0937 0.0442 0.094 Uiso 1 1 calc R . .
C16 C 0.1417(3) -0.0328(12) 0.0413(4) 0.077(5) Uani 1 1 d . . .
H16 H 0.1305 -0.0742 0.0255 0.093 Uiso 1 1 calc R . .
C17 C 0.1628(3) -0.0685(11) 0.0542(4) 0.073(4) Uani 1 1 d . . .
H17 H 0.1659 -0.1354 0.0476 0.087 Uiso 1 1 calc R . .
C18 C 0.1793(2) -0.0082(9) 0.0766(4) 0.060(4) Uani 1 1 d . . .
H18 H 0.1937 -0.0336 0.0838 0.071 Uiso 1 1 calc R . .
C19 C 0.2185(2) 0.1518(8) 0.0891(3) 0.043(3) Uani 1 1 d . . .
C20 C 0.2126(2) 0.1794(9) 0.0455(4) 0.058(4) Uani 1 1 d . . .
H20 H 0.1985 0.2030 0.0326 0.070 Uiso 1 1 calc R . .
C21 C 0.2285(3) 0.1708(10) 0.0217(4) 0.070(4) Uani 1 1 d . . .
H21 H 0.2248 0.1904 -0.0071 0.085 Uiso 1 1 calc R . .
C22 C 0.2486(3) 0.1353(11) 0.0392(5) 0.072(4) Uani 1 1 d . . .
H22 H 0.2586 0.1306 0.0223 0.086 Uiso 1 1 calc R . .
C23 C 0.2551(3) 0.1054(12) 0.0811(6) 0.091(5) Uani 1 1 d . . .
H23 H 0.2692 0.0791 0.0926 0.109 Uiso 1 1 calc R . .
C24 C 0.2398(3) 0.1156(10) 0.1067(4) 0.072(4) Uani 1 1 d . . .
H24 H 0.2441 0.0978 0.1357 0.087 Uiso 1 1 calc R . .
C25 C 0.2098(2) 0.1096(8) 0.1714(3) 0.045(3) Uani 1 1 d . . .
C26 C 0.2037(2) 0.0117(10) 0.1806(4) 0.066(4) Uani 1 1 d . . .
H26 H 0.1926 -0.0230 0.1609 0.079 Uiso 1 1 calc R . .
C27 C 0.2144(3) -0.0358(11) 0.2204(5) 0.080(5) Uani 1 1 d . . .
H27 H 0.2107 -0.1022 0.2265 0.096 Uiso 1 1 calc R . .
C28 C 0.2302(3) 0.0177(12) 0.2492(4) 0.080(5) Uani 1 1 d . . .
H28 H 0.2370 -0.0117 0.2756 0.096 Uiso 1 1 calc R . .
C29 C 0.2362(3) 0.1138(12) 0.2398(5) 0.089(5) Uani 1 1 d . . .
H29 H 0.2474 0.1489 0.2590 0.107 Uiso 1 1 calc R . .
C30 C 0.2251(2) 0.1582(11) 0.2013(4) 0.073(4) Uani 1 1 d . . .
H30 H 0.2286 0.2255 0.1960 0.088 Uiso 1 1 calc R . .
S1 S 0.16516(6) 0.2730(2) 0.17003(9) 0.0497(8) Uani 1 1 d . . .
Au1 Au 0.130750(9) 0.34807(4) 0.148293(16) 0.05172(14) Uani 1 1 d . . .
P2 P 0.09487(6) 0.3963(3) 0.12805(11) 0.0556(9) Uani 1 1 d . . .
C31 C 0.0805(2) 0.3536(9) 0.0741(4) 0.057(3) Uani 1 1 d D . .
C32 C 0.0632(2) 0.4053(12) 0.0492(4) 0.075(4) Uani 1 1 d . . .
H32 H 0.0586 0.4667 0.0590 0.090 Uiso 1 1 calc R . .
C33 C 0.0523(3) 0.3670(13) 0.0092(5) 0.089(5) Uani 1 1 d . . .
H33 H 0.0398 0.4005 -0.0069 0.107 Uiso 1 1 calc R . .
C34 C 0.0595(3) 0.2817(13) -0.0068(5) 0.095(6) Uani 1 1 d . . .
H34 H 0.0524 0.2589 -0.0343 0.114 Uiso 1 1 calc R . .
C35 C 0.0774(3) 0.2278(12) 0.0176(5) 0.098(6) Uani 1 1 d . . .
H35 H 0.0824 0.1687 0.0068 0.117 Uiso 1 1 calc R . .
C36 C 0.0874(3) 0.2627(9) 0.0570(5) 0.086(5) Uani 1 1 d D . .
H36 H 0.0992 0.2260 0.0737 0.104 Uiso 1 1 calc R . .
C37 C 0.0894(2) 0.5338(9) 0.1253(4) 0.056(3) Uani 1 1 d . . .
C38 C 0.1009(2) 0.5963(10) 0.1046(5) 0.072(4) Uani 1 1 d . . .
H38 H 0.1124 0.5685 0.0948 0.087 Uiso 1 1 calc R . .
C39 C 0.0962(3) 0.6976(12) 0.0979(5) 0.098(6) Uani 1 1 d . . .
H39 H 0.1041 0.7379 0.0831 0.118 Uiso 1 1 calc R . .
C40 C 0.0796(3) 0.7391(12) 0.1130(5) 0.098(6) Uani 1 1 d . . .
H40 H 0.0764 0.8086 0.1089 0.118 Uiso 1 1 calc R . .
C41 C 0.0676(3) 0.6806(11) 0.1342(5) 0.096(6) Uani 1 1 d . . .
H41 H 0.0564 0.7101 0.1444 0.115 Uiso 1 1 calc R . .
C42 C 0.0723(3) 0.5768(11) 0.1403(4) 0.081(5) Uani 1 1 d . . .
H42 H 0.0641 0.5361 0.1543 0.097 Uiso 1 1 calc R . .
C43 C 0.0785(3) 0.3410(9) 0.1628(4) 0.067(4) Uani 1 1 d . . .
C44 C 0.0877(3) 0.3552(11) 0.2075(5) 0.084(5) Uani 1 1 d . . .
H44 H 0.1009 0.3902 0.2177 0.101 Uiso 1 1 calc R . .
C45 C 0.0758(3) 0.3132(14) 0.2362(6) 0.105(6) Uani 1 1 d . . .
H45 H 0.0805 0.3262 0.2656 0.126 Uiso 1 1 calc R . .
C46 C 0.0578(3) 0.2551(14) 0.2206(6) 0.101(6) Uani 1 1 d . . .
H46 H 0.0506 0.2251 0.2394 0.121 Uiso 1 1 calc R . .
C47 C 0.0502(3) 0.2398(13) 0.1778(6) 0.102(6) Uani 1 1 d . . .
H47 H 0.0376 0.1999 0.1681 0.123 Uiso 1 1 calc R . .
C48 C 0.0603(3) 0.2808(12) 0.1472(5) 0.088(5) Uani 1 1 d . . .
H48 H 0.0550 0.2678 0.1179 0.105 Uiso 1 1 calc R . .
Au2 Au 0.172638(9) 0.36717(4) 0.232667(15) 0.05177(15) Uani 1 1 d . . .
P3 P 0.18106(6) 0.4461(3) 0.29748(10) 0.0541(9) Uani 1 1 d . . .
C49 C 0.1840(2) 0.5839(10) 0.2957(4) 0.056(3) Uani 1 1 d . . .
C50 C 0.1652(3) 0.6423(12) 0.2771(6) 0.099(6) Uani 1 1 d . . .
H50 H 0.1515 0.6110 0.2662 0.119 Uiso 1 1 calc R . .
C51 C 0.1674(3) 0.7480(14) 0.2753(6) 0.112(7) Uani 1 1 d . . .
H51 H 0.1551 0.7876 0.2630 0.135 Uiso 1 1 calc R . .
C52 C 0.1866(3) 0.7941(13) 0.2905(5) 0.095(6) Uani 1 1 d . . .
H52 H 0.1875 0.8651 0.2884 0.113 Uiso 1 1 calc R . .
C53 C 0.2047(3) 0.7413(12) 0.3087(5) 0.098(6) Uani 1 1 d . . .
H53 H 0.2181 0.7754 0.3190 0.117 Uiso 1 1 calc R . .
C54 C 0.2037(2) 0.6354(10) 0.3126(4) 0.068(4) Uani 1 1 d . . .
H54 H 0.2163 0.5990 0.3264 0.082 Uiso 1 1 calc R . .
C55 C 0.1606(2) 0.4255(9) 0.3271(4) 0.056(3) Uani 1 1 d . . .
C56 C 0.1455(2) 0.3475(10) 0.3148(4) 0.063(4) Uani 1 1 d . . .
H56 H 0.1462 0.3057 0.2916 0.076 Uiso 1 1 calc R . .
C57 C 0.1291(3) 0.3300(10) 0.3368(5) 0.076(4) Uani 1 1 d . . .
H57 H 0.1188 0.2778 0.3277 0.092 Uiso 1 1 calc R . .
C58 C 0.1281(3) 0.3887(12) 0.3711(5) 0.083(5) Uani 1 1 d . . .
H58 H 0.1175 0.3759 0.3863 0.099 Uiso 1 1 calc R . .
C59 C 0.1429(3) 0.4673(12) 0.3830(5) 0.084(5) Uani 1 1 d . . .
H59 H 0.1421 0.5090 0.4061 0.100 Uiso 1 1 calc R . .
C60 C 0.1592(2) 0.4865(10) 0.3618(4) 0.063(4) Uani 1 1 d . . .
H60 H 0.1692 0.5399 0.3707 0.076 Uiso 1 1 calc R . .
C61 C 0.2066(2) 0.3958(10) 0.3319(4) 0.063(4) Uani 1 1 d . . .
C62 C 0.2089(3) 0.3710(11) 0.3737(4) 0.079(5) Uani 1 1 d . . .
H62 H 0.1971 0.3846 0.3856 0.095 Uiso 1 1 calc R . .
C63 C 0.2267(4) 0.3291(16) 0.3986(7) 0.136(9) Uani 1 1 d D . .
H63 H 0.2270 0.3078 0.4264 0.163 Uiso 1 1 calc R . .
C64 C 0.2442(3) 0.3183(14) 0.3827(5) 0.135(10) Uani 1 1 d D . .
H64 H 0.2572 0.2934 0.4007 0.162 Uiso 1 1 calc R . .
C65 C 0.2440(3) 0.3428(14) 0.3398(6) 0.124(8) Uani 1 1 d D . .
H65 H 0.2563 0.3317 0.3289 0.148 Uiso 1 1 calc R . .
C66 C 0.2241(3) 0.3854(11) 0.3141(5) 0.080(5) Uani 1 1 d . . .
H66 H 0.2230 0.4056 0.2858 0.096 Uiso 1 1 calc R . .
Pt2 Pt 0.068738(8) -0.09218(3) -0.083043(14) 0.04332(13) Uani 1 1 d . . .
C67 C 0.0729(2) 0.0583(8) -0.0972(3) 0.045(3) Uani 1 1 d . . .
C68 C 0.0906(2) 0.1194(9) -0.0744(4) 0.053(3) Uani 1 1 d D . .
F68 F 0.10560(14) 0.0771(6) -0.0411(2) 0.074(2) Uani 1 1 d . . .
C69 C 0.0936(3) 0.2192(9) -0.0817(5) 0.080(5) Uani 1 1 d D . .
F69 F 0.11062(18) 0.2739(6) -0.0580(4) 0.119(4) Uani 1 1 d . . .
C70 C 0.0788(3) 0.2665(11) -0.1137(6) 0.095(6) Uani 1 1 d . . .
F70 F 0.0809(2) 0.3674(6) -0.1225(4) 0.142(5) Uani 1 1 d . . .
C71 C 0.0615(3) 0.2133(12) -0.1388(5) 0.076(5) Uani 1 1 d . . .
F71 F 0.0457(2) 0.2568(8) -0.1722(3) 0.134(4) Uani 1 1 d . . .
C72 C 0.0587(3) 0.1106(10) -0.1306(4) 0.065(4) Uani 1 1 d . . .
F72 F 0.04157(13) 0.0596(7) -0.1560(2) 0.081(2) Uani 1 1 d . . .
C73 C 0.0548(2) -0.0422(9) -0.0357(3) 0.053(3) Uani 1 1 d . . .
C74 C 0.0659(2) -0.0425(9) 0.0069(4) 0.063(4) Uani 1 1 d D . .
F74 F 0.08612(14) -0.0885(6) 0.0194(2) 0.083(2) Uani 1 1 d . . .
C75 C 0.0568(3) -0.0017(11) 0.0393(4) 0.075(5) Uani 1 1 d D . .
F75 F 0.0694(2) -0.0051(8) 0.0806(3) 0.121(4) Uani 1 1 d . . .
C76 C 0.0373(4) 0.0443(11) 0.0280(5) 0.113(8) Uani 1 1 d . . .
F76 F 0.0300(2) 0.0879(8) 0.0602(3) 0.132(4) Uani 1 1 d U . .
C77 C 0.0262(3) 0.0468(15) -0.0123(5) 0.113(8) Uani 1 1 d D . .
F77 F 0.0063(2) 0.0942(9) -0.0230(4) 0.135(4) Uani 1 1 d U . .
C78 C 0.0348(3) 0.0048(11) -0.0428(4) 0.080(5) Uani 1 1 d D . .
F78 F 0.02205(16) 0.0106(9) -0.0848(3) 0.123(4) Uani 1 1 d . . .
P4 P 0.06123(6) -0.2602(2) -0.07351(9) 0.0473(8) Uani 1 1 d . . .
C79 C 0.0841(2) -0.3397(9) -0.0474(4) 0.055(3) Uani 1 1 d . . .
C80 C 0.1044(2) -0.2941(11) -0.0341(4) 0.062(4) Uani 1 1 d . . .
H80 H 0.1058 -0.2241 -0.0386 0.075 Uiso 1 1 calc R . .
C81 C 0.1234(2) -0.3507(13) -0.0137(4) 0.080(5) Uani 1 1 d . . .
H81 H 0.1372 -0.3194 -0.0050 0.096 Uiso 1 1 calc R . .
C82 C 0.1208(3) -0.4555(12) -0.0070(4) 0.085(5) Uani 1 1 d D . .
H82 H 0.1330 -0.4959 0.0058 0.102 Uiso 1 1 calc R . .
C83 C 0.1006(3) -0.4968(11) -0.0192(5) 0.088(5) Uani 1 1 d D . .
H83 H 0.0989 -0.5659 -0.0136 0.105 Uiso 1 1 calc R . .
C84 C 0.0823(2) -0.4420(10) -0.0396(4) 0.067(4) Uani 1 1 d . . .
H84 H 0.0687 -0.4743 -0.0482 0.080 Uiso 1 1 calc R . .
C85 C 0.0412(2) -0.2904(10) -0.0437(4) 0.054(3) Uani 1 1 d . . .
C86 C 0.0462(3) -0.2956(12) -0.0013(4) 0.081(5) Uani 1 1 d . . .
H86 H 0.0609 -0.2851 0.0134 0.097 Uiso 1 1 calc R . .
C87 C 0.0316(3) -0.3152(15) 0.0227(5) 0.107(6) Uani 1 1 d . . .
H87 H 0.0366 -0.3213 0.0525 0.129 Uiso 1 1 calc R . .
C88 C 0.0099(3) -0.3257(18) 0.0032(6) 0.138(9) Uani 1 1 d D . .
H88 H -0.0005 -0.3383 0.0189 0.165 Uiso 1 1 calc R . .
C89 C 0.0039(4) -0.3172(18) -0.0400(7) 0.157(9) Uani 1 1 d DU . .
H89 H -0.0109 -0.3187 -0.0549 0.189 Uiso 1 1 calc R . .
C90 C 0.0207(3) -0.3059(16) -0.0626(6) 0.120(7) Uani 1 1 d DU . .
H90 H 0.0166 -0.3098 -0.0925 0.144 Uiso 1 1 calc R . .
C91 C 0.0487(2) -0.3155(9) -0.1276(4) 0.053(3) Uani 1 1 d . . .
C92 C 0.0555(3) -0.4078(10) -0.1407(4) 0.075(4) Uani 1 1 d . . .
H92 H 0.0662 -0.4477 -0.1225 0.090 Uiso 1 1 calc R . .
C93 C 0.0452(3) -0.4385(12) -0.1835(5) 0.094(6) Uani 1 1 d . . .
H93 H 0.0492 -0.5008 -0.1935 0.113 Uiso 1 1 calc R . .
C94 C 0.0303(3) -0.3818(14) -0.2095(5) 0.100(6) Uani 1 1 d . . .
H94 H 0.0241 -0.4047 -0.2374 0.119 Uiso 1 1 calc R . .
C95 C 0.0236(3) -0.2881(13) -0.1961(5) 0.092(5) Uani 1 1 d . . .
H95 H 0.0128 -0.2489 -0.2144 0.111 Uiso 1 1 calc R . .
C96 C 0.0335(3) -0.2555(11) -0.1552(4) 0.073(4) Uani 1 1 d . . .
H96 H 0.0299 -0.1917 -0.1460 0.087 Uiso 1 1 calc R . .
S2 S 0.08741(6) -0.1529(2) -0.13401(10) 0.0507(8) Uani 1 1 d . . .
Au3 Au 0.122934(9) -0.08703(4) -0.111412(15) 0.05066(14) Uani 1 1 d . . .
P5 P 0.15882(6) -0.0419(2) -0.09760(10) 0.0517(8) Uani 1 1 d . . .
C97 C 0.1690(2) -0.0670(9) -0.1446(4) 0.052(3) Uani 1 1 d . . .
C98 C 0.1543(2) -0.0524(10) -0.1849(4) 0.067(4) Uani 1 1 d . . .
H98 H 0.1400 -0.0299 -0.1871 0.080 Uiso 1 1 calc R . .
C99 C 0.1616(3) -0.0724(12) -0.2216(4) 0.080(5) Uani 1 1 d . . .
H99 H 0.1521 -0.0613 -0.2486 0.096 Uiso 1 1 calc R . .
C100 C 0.1825(3) -0.1081(10) -0.2188(5) 0.076(5) Uani 1 1 d . . .
H100 H 0.1871 -0.1216 -0.2436 0.091 Uiso 1 1 calc R . .
C101 C 0.1965(3) -0.1235(10) -0.1787(4) 0.071(4) Uani 1 1 d . . .
H101 H 0.2107 -0.1484 -0.1762 0.085 Uiso 1 1 calc R . .
C102 C 0.1897(2) -0.1026(11) -0.1430(4) 0.069(4) Uani 1 1 d . . .
H102 H 0.1994 -0.1129 -0.1162 0.083 Uiso 1 1 calc R . .
C103 C 0.1659(2) 0.0883(9) -0.0837(4) 0.053(3) Uani 1 1 d . . .
C104 C 0.1569(3) 0.1381(11) -0.0536(4) 0.076(4) Uani 1 1 d . . .
H104 H 0.1471 0.1025 -0.0415 0.091 Uiso 1 1 calc R . .
C105 C 0.1620(3) 0.2371(10) -0.0412(5) 0.076(4) Uani 1 1 d . . .
H105 H 0.1561 0.2677 -0.0205 0.091 Uiso 1 1 calc R . .
C106 C 0.1761(3) 0.2912(10) -0.0599(5) 0.091(6) Uani 1 1 d . . .
H106 H 0.1795 0.3592 -0.0522 0.109 Uiso 1 1 calc R . .
C107 C 0.1850(3) 0.2453(11) -0.0890(5) 0.086(5) Uani 1 1 d . . .
H107 H 0.1947 0.2812 -0.1011 0.103 Uiso 1 1 calc R . .
C108 C 0.1796(3) 0.1451(10) -0.1011(4) 0.071(4) Uani 1 1 d . . .
H108 H 0.1856 0.1154 -0.1219 0.085 Uiso 1 1 calc R . .
C109 C 0.1770(2) -0.1141(9) -0.0543(4) 0.052(3) Uani 1 1 d . . .
C110 C 0.1713(3) -0.2176(11) -0.0491(4) 0.080(5) Uani 1 1 d . . .
H110 H 0.1585 -0.2458 -0.0667 0.095 Uiso 1 1 calc R . .
C111 C 0.1848(3) -0.2752(11) -0.0181(5) 0.086(5) Uani 1 1 d . . .
H111 H 0.1811 -0.3432 -0.0148 0.103 Uiso 1 1 calc R . .
C112 C 0.2033(3) -0.2372(12) 0.0079(5) 0.094(5) Uani 1 1 d . . .
H112 H 0.2124 -0.2791 0.0284 0.113 Uiso 1 1 calc R . .
C113 C 0.2090(3) -0.1341(11) 0.0042(5) 0.078(4) Uani 1 1 d . . .
H113 H 0.2216 -0.1065 0.0225 0.094 Uiso 1 1 calc R . .
C114 C 0.1955(2) -0.0742(10) -0.0272(4) 0.061(4) Uani 1 1 d . . .
H114 H 0.1991 -0.0057 -0.0298 0.073 Uiso 1 1 calc R . .
Au4 Au 0.085218(9) -0.04104(4) -0.190793(15) 0.05234(15) Uani 1 1 d . . .
P6 P 0.08268(6) 0.0658(3) -0.24706(10) 0.0527(9) Uani 1 1 d . B .
C115 C 0.0896(3) 0.1963(10) -0.2294(4) 0.064(4) Uani 1 1 d . . .
C116 C 0.1081(2) 0.2105(11) -0.1945(5) 0.077(4) Uani 1 1 d . . .
H116 H 0.1156 0.1542 -0.1800 0.092 Uiso 1 1 calc R . .
C117 C 0.1152(3) 0.3097(13) -0.1818(6) 0.107(6) Uani 1 1 d . . .
H117 H 0.1272 0.3201 -0.1584 0.128 Uiso 1 1 calc R . .
C118 C 0.1040(3) 0.3947(14) -0.2048(6) 0.122(8) Uani 1 1 d D . .
H118 H 0.1090 0.4611 -0.1976 0.147 Uiso 1 1 calc R . .
C119 C 0.0862(4) 0.3784(13) -0.2367(6) 0.131(9) Uani 1 1 d D . .
H119 H 0.0787 0.4348 -0.2510 0.157 Uiso 1 1 calc R . .
C120 C 0.0784(3) 0.2801(11) -0.2499(4) 0.082(5) Uani 1 1 d . . .
H120 H 0.0657 0.2716 -0.2723 0.098 Uiso 1 1 calc R . .
C121 C 0.1007(2) 0.0367(10) -0.2809(4) 0.052(3) Uani 1 1 d . . .
C122 C 0.1115(3) 0.1105(11) -0.2978(4) 0.077(5) Uani 1 1 d D . .
H122 H 0.1099 0.1787 -0.2907 0.092 Uiso 1 1 calc R . .
C123 C 0.1250(3) 0.0877(13) -0.3252(5) 0.095(6) Uani 1 1 d D . .
H123 H 0.1326 0.1391 -0.3356 0.114 Uiso 1 1 calc R . .
C124 C 0.1266(3) -0.0103(14) -0.3362(5) 0.096(6) Uani 1 1 d D . .
H124 H 0.1354 -0.0261 -0.3548 0.116 Uiso 1 1 calc R . .
C125 C 0.1160(3) -0.0883(13) -0.3211(5) 0.101(6) Uani 1 1 d . . .
H125 H 0.1177 -0.1560 -0.3290 0.121 Uiso 1 1 calc R . .
C126 C 0.1025(3) -0.0632(11) -0.2931(5) 0.084(5) Uani 1 1 d . . .
H126 H 0.0948 -0.1146 -0.2830 0.101 Uiso 1 1 calc R . .
C127 C 0.0550(3) 0.0688(13) -0.2829(5) 0.084(5) Uani 1 1 d . . .
C128 C 0.0503(2) 0.0632(11) -0.3267(4) 0.074(4) Uani 1 1 d . B .
H128 H 0.0619 0.0581 -0.3399 0.089 Uiso 1 1 calc R . .
C129 C 0.0295(3) 0.0646(15) -0.3513(6) 0.125(8) Uani 1 1 d . . .
H129 H 0.0264 0.0398 -0.3793 0.149 Uiso 1 1 calc R A 1
C130 C 0.0124(6) 0.104(2) -0.3348(10) 0.078(10) Uani 0.486(18) 1 d PU B 1
H130 H -0.0015 0.1177 -0.3524 0.093 Uiso 0.486(18) 1 calc PR B 1
C131 C 0.0175(6) 0.120(3) -0.2910(11) 0.091(11) Uani 0.486(18) 1 d PU B 1
H131 H 0.0066 0.1435 -0.2784 0.109 Uiso 0.486(18) 1 calc PR B 1
C132 C 0.0368(5) 0.102(3) -0.2671(8) 0.084(13) Uani 0.486(18) 1 d P B 1
H132 H 0.0392 0.1117 -0.2376 0.101 Uiso 0.486(18) 1 calc PR B 1
C130 C 0.0123(8) 0.031(3) -0.3231(15) 0.139(17) Uani 0.514(18) 1 d PU B 2
H13A H -0.0021 0.0163 -0.3381 0.167 Uiso 0.514(18) 1 calc PR B 2
C131 C 0.0172(7) 0.023(3) -0.2823(12) 0.112(13) Uani 0.514(18) 1 d PU B 2
H13B H 0.0058 0.0117 -0.2689 0.134 Uiso 0.514(18) 1 calc PR B 2
C132 C 0.0387(2) 0.0292(10) -0.2570(4) 0.122(17) Uani 0.514(18) 1 d P B 2
H13C H 0.0429 0.0121 -0.2279 0.147 Uiso 0.514(18) 1 calc PR B 2
Cl1 Cl -0.0054(2) -0.3580(10) 0.1106(4) 0.241(6) Uiso 0.50 1 d PRD . .
Cl2 Cl 0.0181(2) -0.4765(10) 0.1713(4) 0.241(6) Uiso 0.50 1 d PRD . .
C200 C -0.0036(2) -0.4094(10) 0.1519(4) 0.241(6) Uiso 0.50 1 d PRD . .
H20A H -0.0163 -0.4539 0.1487 0.289 Uiso 0.50 1 calc PR . .
H20B H -0.0046 -0.3574 0.1730 0.289 Uiso 0.50 1 calc PR . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Pt1 C1 84.5(4) . . ?
C7 Pt1 P1 94.3(3) . . ?
C1 Pt1 P1 176.3(3) . . ?
C7 Pt1 S1 178.6(3) . . ?
C1 Pt1 S1 94.4(3) . . ?
P1 Pt1 S1 86.78(10) . . ?
C2 C1 C6 112.6(10) . . ?
C2 C1 Pt1 124.0(9) . . ?
C6 C1 Pt1 123.4(8) . . ?
F2 C2 C3 117.5(11) . . ?
F2 C2 C1 117.9(10) . . ?
C3 C2 C1 124.4(11) . . ?
C4 C3 C2 121.1(12) . . ?
C4 C3 F3 119.5(11) . . ?
C2 C3 F3 119.4(12) . . ?
F4 C4 C3 122.0(13) . . ?
F4 C4 C5 120.1(14) . . ?
C3 C4 C5 117.9(12) . . ?
F5 C5 C6 120.8(13) . . ?
F5 C5 C4 118.8(12) . . ?
C6 C5 C4 120.3(13) . . ?
F6 C6 C5 117.9(12) . . ?
F6 C6 C1 118.6(10) . . ?
C5 C6 C1 123.5(12) . . ?
C12 C7 C8 113.3(12) . . ?
C12 C7 Pt1 122.2(10) . . ?
C8 C7 Pt1 124.4(10) . . ?
F8 C8 C9 118.3(13) . . ?
F8 C8 C7 118.3(11) . . ?
C9 C8 C7 123.4(13) . . ?
F9 C9 C10 120.0(14) . . ?
F9 C9 C8 119.4(15) . . ?
C10 C9 C8 120.6(14) . . ?
F10 C10 C11 118.6(15) . . ?
F10 C10 C9 122.2(14) . . ?
C11 C10 C9 119.1(14) . . ?
C10 C11 F11 123.5(14) . . ?
C10 C11 C12 121.0(16) . . ?
F11 C11 C12 115.3(16) . . ?
F12 C12 C7 119.7(11) . . ?
F12 C12 C11 117.6(15) . . ?
C7 C12 C11 122.7(14) . . ?
C13 P1 C25 108.7(5) . . ?
C13 P1 C19 100.8(5) . . ?
C25 P1 C19 103.7(5) . . ?
C13 P1 Pt1 117.1(4) . . ?
C25 P1 Pt1 109.8(4) . . ?
C19 P1 Pt1 115.7(3) . . ?
C14 C13 C18 118.2(11) . . ?
C14 C13 P1 120.2(9) . . ?
C18 C13 P1 121.5(10) . . ?
C13 C14 C15 120.7(13) . . ?
C16 C15 C14 119.7(14) . . ?
C17 C16 C15 118.5(13) . . ?
C18 C17 C16 121.0(14) . . ?
C17 C18 C13 121.8(14) . . ?
C24 C19 C20 118.5(11) . . ?
C24 C19 P1 124.6(9) . . ?
C20 C19 P1 116.9(10) . . ?
C19 C20 C21 118.7(13) . . ?
C22 C21 C20 121.5(13) . . ?
C21 C22 C23 122.6(14) . . ?
C22 C23 C24 117.7(16) . . ?
C19 C24 C23 121.1(13) . . ?
C30 C25 C26 118.0(11) . . ?
C30 C25 P1 120.1(9) . . ?
C26 C25 P1 121.9(10) . . ?
C25 C26 C27 120.1(13) . . ?
C28 C27 C26 118.8(14) . . ?
C27 C28 C29 120.9(14) . . ?
C28 C29 C30 118.7(15) . . ?
C25 C30 C29 123.5(14) . . ?
Au2 S1 Au1 90.31(11) . . ?
Au2 S1 Pt1 105.33(12) . . ?
Au1 S1 Pt1 111.13(12) . . ?
P2 Au1 S1 170.83(12) . . ?
C31 P2 C37 102.2(6) . . ?
C31 P2 C43 103.9(6) . . ?
C37 P2 C43 106.7(6) . . ?
C31 P2 Au1 113.7(4) . . ?
C37 P2 Au1 116.7(5) . . ?
C43 P2 Au1 112.5(5) . . ?
C32 C31 C36 117.6(13) . . ?
C32 C31 P2 122.5(10) . . ?
C36 C31 P2 119.9(11) . . ?
C31 C32 C33 120.1(15) . . ?
C34 C33 C32 120.9(17) . . ?
C33 C34 C35 120.3(15) . . ?
C36 C35 C34 118.5(16) . . ?
C35 C36 C31 122.4(16) . . ?
C38 C37 C42 118.1(12) . . ?
C38 C37 P2 119.7(10) . . ?
C42 C37 P2 121.9(11) . . ?
C39 C38 C37 122.7(15) . . ?
C38 C39 C40 118.8(16) . . ?
C39 C40 C41 121.4(15) . . ?
C40 C41 C42 119.3(16) . . ?
C41 C42 C37 119.7(15) . . ?
C48 C43 C44 122.3(14) . . ?
C48 C43 P2 122.7(11) . . ?
C44 C43 P2 114.5(12) . . ?
C43 C44 C45 117.1(17) . . ?
C46 C45 C44 119.8(17) . . ?
C45 C46 C47 120.6(16) . . ?
C46 C47 C48 123.5(17) . . ?
C43 C48 C47 116.2(15) . . ?
P3 Au2 S1 174.72(12) . . ?
C55 P3 C49 104.8(6) . . ?
C55 P3 C61 105.1(6) . . ?
C49 P3 C61 107.4(6) . . ?
C55 P3 Au2 112.7(4) . . ?
C49 P3 Au2 115.1(4) . . ?
C61 P3 Au2 111.0(4) . . ?
C54 C49 C50 118.1(13) . . ?
C54 C49 P3 123.6(11) . . ?
C50 C49 P3 118.3(11) . . ?
C51 C50 C49 118.3(17) . . ?
C52 C51 C50 121.9(18) . . ?
C51 C52 C53 121.4(18) . . ?
C52 C53 C54 120.2(17) . . ?
C53 C54 C49 120.0(15) . . ?
C56 C55 C60 118.4(12) . . ?
C56 C55 P3 119.3(9) . . ?
C60 C55 P3 122.3(10) . . ?
C55 C56 C57 120.8(12) . . ?
C58 C57 C56 120.5(14) . . ?
C57 C58 C59 118.6(14) . . ?
C58 C59 C60 122.0(13) . . ?
C59 C60 C55 119.6(13) . . ?
C62 C61 C66 119.7(15) . . ?
C62 C61 P3 123.1(12) . . ?
C66 C61 P3 117.2(10) . . ?
C63 C62 C61 124.5(18) . . ?
C62 C63 C64 117.6(19) . . ?
C63 C64 C65 123.2(18) . . ?
C64 C65 C66 116.3(16) . . ?
C61 C66 C65 118.4(15) . . ?
C73 Pt2 C67 87.8(4) . . ?
C73 Pt2 P4 93.7(3) . . ?
C67 Pt2 P4 174.1(3) . . ?
C73 Pt2 S2 175.7(4) . . ?
C67 Pt2 S2 93.0(3) . . ?
P4 Pt2 S2 85.82(11) . . ?
C72 C67 C68 112.9(11) . . ?
C72 C67 Pt2 123.5(10) . . ?
C68 C67 Pt2 123.6(8) . . ?
C69 C68 F68 115.8(13) . . ?
C69 C68 C67 125.6(13) . . ?
F68 C68 C67 118.5(10) . . ?
F69 C69 C68 122.7(16) . . ?
F69 C69 C70 118.9(13) . . ?
C68 C69 C70 118.4(16) . . ?
C69 C70 F70 120.9(18) . . ?
C69 C70 C71 120.6(14) . . ?
F70 C70 C71 118.4(17) . . ?
C70 C71 F71 123.6(15) . . ?
C70 C71 C72 119.9(15) . . ?
F71 C71 C72 116.5(16) . . ?
F72 C72 C71 118.7(13) . . ?
F72 C72 C67 118.8(12) . . ?
C71 C72 C67 122.5(15) . . ?
C78 C73 C74 112.3(11) . . ?
C78 C73 Pt2 124.6(9) . . ?
C74 C73 Pt2 122.7(10) . . ?
F74 C74 C73 119.5(12) . . ?
F74 C74 C75 117.9(11) . . ?
C73 C74 C75 122.6(12) . . ?
C76 C75 F75 123.3(13) . . ?
C76 C75 C74 119.1(12) . . ?
F75 C75 C74 117.4(13) . . ?
C77 C76 C75 120.3(12) . . ?
C77 C76 F76 123.3(17) . . ?
C75 C76 F76 116.4(17) . . ?
C76 C77 C78 119.9(14) . . ?
C76 C77 F77 119.1(14) . . ?
C78 C77 F77 121.0(14) . . ?
C77 C78 C73 125.7(12) . . ?
C77 C78 F78 116.3(12) . . ?
C73 C78 F78 117.9(12) . . ?
C79 P4 C85 101.9(6) . . ?
C79 P4 C91 108.1(6) . . ?
C85 P4 C91 103.0(6) . . ?
C79 P4 Pt2 116.8(4) . . ?
C85 P4 Pt2 118.5(4) . . ?
C91 P4 Pt2 107.4(4) . . ?
C84 C79 C80 118.6(13) . . ?
C84 C79 P4 123.7(11) . . ?
C80 C79 P4 117.6(10) . . ?
C79 C80 C81 121.6(13) . . ?
C82 C81 C80 117.8(14) . . ?
C83 C82 C81 118.9(15) . . ?
C82 C83 C84 123.0(15) . . ?
C83 C84 C79 120.0(15) . . ?
C90 C85 C86 115.2(13) . . ?
C90 C85 P4 121.8(12) . . ?
C86 C85 P4 122.9(11) . . ?
C85 C86 C87 125.1(16) . . ?
C88 C87 C86 120.0(17) . . ?
C89 C88 C87 116.7(18) . . ?
C88 C89 C90 119(2) . . ?
C85 C90 C89 123.3(19) . . ?
C96 C91 C92 121.4(12) . . ?
C96 C91 P4 116.2(10) . . ?
C92 C91 P4 122.1(10) . . ?
C91 C92 C93 116.2(15) . . ?
C94 C93 C92 122.1(15) . . ?
C93 C94 C95 121.4(15) . . ?
C96 C95 C94 117.9(16) . . ?
C91 C96 C95 120.9(14) . . ?
Au4 S2 Au3 82.73(10) . . ?
Au4 S2 Pt2 113.07(13) . . ?
Au3 S2 Pt2 105.21(12) . . ?
P5 Au3 S2 170.24(11) . . ?
C103 P5 C97 105.2(5) . . ?
C103 P5 C109 103.7(6) . . ?
C97 P5 C109 105.0(6) . . ?
C103 P5 Au3 117.9(4) . . ?
C97 P5 Au3 109.5(4) . . ?
C109 P5 Au3 114.4(4) . . ?
C102 C97 C98 118.5(12) . . ?
C102 C97 P5 124.2(10) . . ?
C98 C97 P5 117.2(10) . . ?
C99 C98 C97 118.6(14) . . ?
C100 C99 C98 121.3(14) . . ?
C99 C100 C101 119.0(13) . . ?
C102 C101 C100 119.8(14) . . ?
C101 C102 C97 122.8(14) . . ?
C108 C103 C104 116.1(12) . . ?
C108 C103 P5 124.0(10) . . ?
C104 C103 P5 119.9(10) . . ?
C105 C104 C103 122.4(13) . . ?
C104 C105 C106 119.0(13) . . ?
C107 C106 C105 119.8(14) . . ?
C106 C107 C108 120.3(14) . . ?
C103 C108 C107 122.4(13) . . ?
C114 C109 C110 119.1(12) . . ?
C114 C109 P5 123.7(10) . . ?
C110 C109 P5 117.2(10) . . ?
C111 C110 C109 119.0(14) . . ?
C112 C111 C110 122.2(14) . . ?
C111 C112 C113 119.8(15) . . ?
C114 C113 C112 119.0(14) . . ?
C109 C114 C113 120.8(13) . . ?
P6 Au4 S2 178.89(13) . . ?
C121 P6 C115 104.5(6) . . ?
C121 P6 C127 105.4(6) . . ?
C115 P6 C127 106.8(7) . . ?
C121 P6 Au4 115.2(4) . . ?
C115 P6 Au4 111.6(4) . . ?
C127 P6 Au4 112.5(5) . . ?
C120 C115 C116 119.8(13) . . ?
C120 C115 P6 123.1(12) . . ?
C116 C115 P6 117.1(11) . . ?
C117 C116 C115 119.3(16) . . ?
C116 C117 C118 119.8(18) . . ?
C119 C118 C117 119.1(17) . . ?
C118 C119 C120 122.8(18) . . ?
C115 C120 C119 119.1(16) . . ?
C122 C121 C126 118.1(12) . . ?
C122 C121 P6 123.0(10) . . ?
C126 C121 P6 118.8(10) . . ?
C121 C122 C123 122.7(13) . . ?
C124 C123 C122 117.9(15) . . ?
C123 C124 C125 122.9(15) . . ?
C124 C125 C126 118.2(15) . . ?
C121 C126 C125 120.2(15) . . ?
C128 C127 C132 113.5(17) . . ?
C128 C127 C132 122.2(14) . . ?
C132 C127 C132 38.9(15) . . ?
C128 C127 P6 125.0(12) . . ?
C132 C127 P6 120.0(14) . . ?
C132 C127 P6 107.5(10) . . ?
C129 C128 C127 121.9(16) . . ?
C128 C129 C130 120(2) . . ?
C128 C129 C130 110(2) . . ?
C130 C129 C130 38.4(17) . . ?
C131 C130 C129 116(3) . . ?
C132 C131 C130 122(3) . . ?
C131 C132 C127 124(3) . . ?
C131 C130 C129 125(4) . . ?
C130 C131 C132 123(4) . . ?
C131 C132 C127 112.2(19) . . ?
Cl1 C200 Cl2 117.7 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C7 2.007(12) . ?
Pt1 C1 2.045(11) . ?
Pt1 P1 2.279(3) . ?
Pt1 S1 2.370(3) . ?
C1 C2 1.382(14) . ?
C1 C6 1.413(16) . ?
C2 F2 1.348(12) . ?
C2 C3 1.355(15) . ?
C3 C4 1.349(19) . ?
C3 F3 1.368(14) . ?
C4 F4 1.347(14) . ?
C4 C5 1.380(19) . ?
C5 F5 1.350(15) . ?
C5 C6 1.355(16) . ?
C6 F6 1.346(13) . ?
C7 C12 1.398(18) . ?
C7 C8 1.416(17) . ?
C8 F8 1.328(15) . ?
C8 C9 1.400(17) . ?
C9 F9 1.312(13) . ?
C9 C10 1.358(16) . ?
C10 F10 1.329(16) . ?
C10 C11 1.348(16) . ?
C11 F11 1.40(2) . ?
C11 C12 1.422(17) . ?
C12 F12 1.360(15) . ?
P1 C13 1.812(12) . ?
P1 C25 1.832(11) . ?
P1 C19 1.835(11) . ?
C13 C14 1.350(17) . ?
C13 C18 1.396(15) . ?
C14 C15 1.402(17) . ?
C15 C16 1.402(19) . ?
C16 C17 1.36(2) . ?
C17 C18 1.349(17) . ?
C19 C24 1.392(17) . ?
C19 C20 1.400(15) . ?
C20 C21 1.401(17) . ?
C21 C22 1.326(19) . ?
C22 C23 1.36(2) . ?
C23 C24 1.418(18) . ?
C25 C30 1.332(17) . ?
C25 C26 1.385(16) . ?
C26 C27 1.425(18) . ?
C27 C28 1.36(2) . ?
C28 C29 1.36(2) . ?
C29 C30 1.382(18) . ?
S1 Au2 2.298(3) . ?
S1 Au1 2.307(3) . ?
Au1 P2 2.263(4) . ?
P2 C31 1.821(13) . ?
P2 C37 1.823(12) . ?
P2 C43 1.845(14) . ?
C31 C32 1.354(18) . ?
C31 C36 1.417(13) . ?
C32 C33 1.386(19) . ?
C33 C34 1.35(2) . ?
C34 C35 1.39(2) . ?
C35 C36 1.34(2) . ?
C37 C38 1.365(17) . ?
C37 C42 1.398(18) . ?
C38 C39 1.358(19) . ?
C39 C40 1.36(2) . ?
C40 C41 1.37(2) . ?
C41 C42 1.388(18) . ?
C43 C48 1.366(19) . ?
C43 C44 1.414(19) . ?
C44 C45 1.44(2) . ?
C45 C46 1.34(2) . ?
C46 C47 1.35(2) . ?
C47 C48 1.403(19) . ?
Au2 P3 2.258(3) . ?
P3 C55 1.799(13) . ?
P3 C49 1.806(13) . ?
P3 C61 1.819(15) . ?
C49 C54 1.390(18) . ?
C49 C50 1.40(2) . ?
C50 C51 1.39(2) . ?
C51 C52 1.32(2) . ?
C52 C53 1.33(2) . ?
C53 C54 1.389(19) . ?
C55 C56 1.373(17) . ?
C55 C60 1.387(16) . ?
C56 C57 1.406(18) . ?
C57 C58 1.355(19) . ?
C58 C59 1.37(2) . ?
C59 C60 1.385(18) . ?
C61 C62 1.352(17) . ?
C61 C66 1.363(19) . ?
C62 C63 1.31(2) . ?
C63 C64 1.332(16) . ?
C64 C65 1.410(16) . ?
C65 C66 1.42(2) . ?
Pt2 C73 2.037(11) . ?
Pt2 C67 2.045(11) . ?
Pt2 P4 2.277(3) . ?
Pt2 S2 2.373(3) . ?
C67 C72 1.385(16) . ?
C67 C68 1.411(17) . ?
C68 C69 1.343(13) . ?
C68 F68 1.347(14) . ?
C69 F69 1.342(18) . ?
C69 C70 1.35(2) . ?
C70 F70 1.360(15) . ?
C70 C71 1.36(2) . ?
C71 F71 1.382(17) . ?
C71 C72 1.384(19) . ?
C72 F72 1.347(16) . ?
C73 C78 1.361(18) . ?
C73 C74 1.368(16) . ?
C74 F74 1.366(15) . ?
C74 C75 1.409(17) . ?
C75 C76 1.33(2) . ?
C75 F75 1.362(16) . ?
C76 C77 1.30(2) . ?
C76 F76 1.356(14) . ?
C77 C78 1.349(18) . ?
C77 F77 1.352(17) . ?
C78 F78 1.382(15) . ?
P4 C79 1.796(13) . ?
P4 C85 1.804(11) . ?
P4 C91 1.859(12) . ?
C79 C84 1.368(16) . ?
C79 C80 1.368(18) . ?
C80 C81 1.412(18) . ?
C81 C82 1.399(19) . ?
C82 C83 1.340(15) . ?
C83 C84 1.366(19) . ?
C85 C90 1.29(2) . ?
C85 C86 1.318(17) . ?
C86 C87 1.360(19) . ?
C87 C88 1.35(2) . ?
C88 C89 1.346(16) . ?
C89 C90 1.427(16) . ?
C91 C96 1.366(17) . ?
C91 C92 1.377(17) . ?
C92 C93 1.417(19) . ?
C93 C94 1.31(2) . ?
C94 C95 1.39(2) . ?
C95 C96 1.369(18) . ?
S2 Au4 2.311(3) . ?
S2 Au3 2.321(3) . ?
Au3 P5 2.255(4) . ?
P5 C103 1.781(12) . ?
P5 C97 1.808(12) . ?
P5 C109 1.819(13) . ?
C97 C102 1.362(17) . ?
C97 C98 1.398(17) . ?
C98 C99 1.390(17) . ?
C99 C100 1.37(2) . ?
C100 C101 1.38(2) . ?
C101 C102 1.350(16) . ?
C103 C108 1.357(17) . ?
C103 C104 1.393(17) . ?
C104 C105 1.363(17) . ?
C105 C106 1.381(19) . ?
C106 C107 1.339(18) . ?
C107 C108 1.380(18) . ?
C109 C114 1.364(17) . ?
C109 C110 1.415(17) . ?
C110 C111 1.358(18) . ?
C111 C112 1.34(2) . ?
C112 C113 1.402(19) . ?
C113 C114 1.380(18) . ?
Au4 P6 2.255(3) . ?
P6 C121 1.794(12) . ?
P6 C115 1.809(13) . ?
P6 C127 1.819(16) . ?
C115 C120 1.372(18) . ?
C115 C116 1.407(19) . ?
C116 C117 1.392(19) . ?
C117 C118 1.41(2) . ?
C118 C119 1.322(17) . ?
C119 C120 1.40(2) . ?
C121 C122 1.366(17) . ?
C121 C126 1.371(17) . ?
C122 C123 1.396(14) . ?
C123 C124 1.334(15) . ?
C124 C125 1.37(2) . ?
C125 C126 1.42(2) . ?
C127 C128 1.361(18) . ?
C127 C132 1.43(3) . ?
C127 C132 1.56(2) . ?
C128 C129 1.34(2) . ?
C129 C130 1.40(3) . ?
C129 C130 1.63(5) . ?
C130 C131 1.37(4) . ?
C131 C132 1.28(4) . ?
C130 C131 1.27(5) . ?
C131 C132 1.39(4) . ?
Cl1 C200 1.4641 . ?
Cl2 C200 1.6033 . ?
