#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/07/4320716.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4320716
loop_
_publ_author_name
'Ludmila Scoles'
'John H. Yamamoto'
'Luc Brissieux'
'Brian T. Sterenberg'
'Konstantin A. Udachin'
'Arthur J. Carty'
_publ_section_title
;
 Synthesis and Characterization of Mixed Ruthenium/Platinum
 μ4-Phosphinidene, Phosphorus Monoxide, and Related Clusters
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6731
_journal_page_last               6736
_journal_paper_doi               10.1021/ic0106423
_journal_volume                  40
_journal_year                    2001
_chemical_formula_sum            'C33.5 H20 Cl1.5 O14 P2 Pt Ru4'
_chemical_formula_weight         1360.98
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                83.95(3)
_cell_angle_beta                 86.58(4)
_cell_angle_gamma                64.96(5)
_cell_formula_units_Z            2
_cell_length_a                   13.046(6)
_cell_length_b                   13.156(4)
_cell_length_c                   13.607(9)
_cell_measurement_temperature    173(2)
_cell_volume                     2104(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0601
_diffrn_reflns_av_sigmaI/netI    0.0945
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            14744
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.51
_exptl_absorpt_coefficient_mu    4.948
_exptl_crystal_density_diffrn    2.148
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1285
_refine_diff_density_max         2.808
_refine_diff_density_min         -1.675
_refine_diff_density_rms         0.216
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.919
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     543
_refine_ls_number_reflns         7319
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      0.919
_refine_ls_R_factor_all          0.1013
_refine_ls_R_factor_gt           0.0535
_refine_ls_shift/su_max          0.244
_refine_ls_shift/su_mean         0.035
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0714P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1189
_refine_ls_wR_factor_ref         0.1316
_reflns_number_gt                4611
_reflns_number_total             7319
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0106423_5.cif
_cod_data_source_block           ld28
_cod_original_cell_volume        2103.9(17)
_cod_original_formula_sum        'C33.50 H20 Cl1.50 O14 P2 Pt Ru4'
_cod_database_code               4320716
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.235440(4) 0.261040(5) 0.155970(4) 0.03138(2) Uani 1 1 d . . .
Ru1 Ru 0.351628(9) 0.080459(9) 0.302561(9) 0.03085(4) Uani 1 1 d . . .
Ru2 Ru 0.166898(9) 0.165793(9) 0.437760(8) 0.02884(4) Uani 1 1 d . . .
Ru3 Ru 0.037800(9) 0.347663(9) 0.296740(9) 0.02975(4) Uani 1 1 d . . .
Ru4 Ru 0.132560(9) 0.127223(9) 0.239181(9) 0.03244(4) Uani 1 1 d . . .
P1 P 0.23144(3) 0.27153(3) 0.32384(3) 0.02735(11) Uani 1 1 d . . .
P2 P 0.34357(3) 0.35794(3) 0.09505(3) 0.02688(11) Uani 1 1 d . . .
O1 O 0.13154(10) 0.27338(11) -0.03870(9) 0.0815(5) Uani 1 1 d . . .
O2 O 0.48913(12) 0.02549(11) 0.11269(10) 0.0841(6) Uani 1 1 d . . .
O3 O 0.53763(9) 0.08370(10) 0.42438(10) 0.0678(5) Uani 1 1 d . . .
O4 O 0.40528(11) -0.16476(9) 0.36715(11) 0.0708(5) Uani 1 1 d . . .
O5 O 0.22498(10) -0.07557(10) 0.52336(10) 0.0638(5) Uani 1 1 d . . .
O6 O 0.29765(11) 0.20744(12) 0.59115(10) 0.0805(5) Uani 1 1 d . . .
O7 O -0.05346(9) 0.25215(10) 0.55785(8) 0.0529(4) Uani 1 1 d . . .
O8 O -0.04131(12) 0.56872(10) 0.38822(11) 0.0791(6) Uani 1 1 d . . .
O9 O -0.17318(8) 0.30900(10) 0.35472(9) 0.0578(4) Uani 1 1 d . . .
O10 O -0.06056(9) 0.47709(10) 0.10209(9) 0.0617(5) Uani 1 1 d . . .
O11 O 0.27716(11) -0.07255(9) 0.12211(11) 0.0780(5) Uani 1 1 d . . .
O12 O 0.01137(9) 0.00305(9) 0.35940(10) 0.0719(5) Uani 1 1 d . . .
O13 O -0.05633(9) 0.22380(10) 0.08748(9) 0.0659(4) Uani 1 1 d . . .
O14 O 0.29528(7) 0.33697(7) 0.36533(7) 0.0344(3) Uani 1 1 d . . .
C1 C 0.17634(12) 0.26198(13) 0.03548(11) 0.0503(5) Uani 1 1 d . . .
C1A C 0.2181(2) 0.0415(3) 0.87858(19) 0.0702(19) Uani 0.40 1 d PD A -2
C1B C 0.19949(19) 0.0338(4) 0.9135(3) 0.402(15) Uani 0.30 1 d PD A -2
C2 C 0.43237(14) 0.05223(13) 0.18226(12) 0.0480(6) Uani 1 1 d . . .
C3 C 0.46940(12) 0.08148(13) 0.37569(12) 0.0444(6) Uani 1 1 d . . .
C4 C 0.38405(14) -0.07137(12) 0.34504(14) 0.0504(6) Uani 1 1 d . . .
C5 C 0.20539(12) 0.01338(13) 0.49024(12) 0.0424(6) Uani 1 1 d . . .
C6 C 0.24286(13) 0.19508(15) 0.53789(11) 0.0514(6) Uani 1 1 d . . .
C7 C 0.02590(13) 0.22185(13) 0.50878(12) 0.0449(6) Uani 1 1 d . . .
C8 C -0.00872(14) 0.48666(15) 0.35406(14) 0.0563(7) Uani 1 1 d . . .
C9 C -0.09470(13) 0.32353(13) 0.33320(11) 0.0417(5) Uani 1 1 d . . .
C10 C -0.02030(11) 0.42479(13) 0.17331(13) 0.0439(5) Uani 1 1 d . . .
C11 C 0.22752(14) -0.00039(13) 0.16748(14) 0.0549(6) Uani 1 1 d . . .
C12 C 0.05872(12) 0.05022(13) 0.31882(13) 0.0480(6) Uani 1 1 d . . .
C13 C 0.01310(12) 0.18940(12) 0.14634(12) 0.0463(5) Uani 1 1 d . . .
C14 C 0.24569(15) 0.44535(17) 0.40389(16) 0.0812(8) Uani 1 1 d . . .
H14B H 0.1894 0.4458 0.4562 0.097 Uiso 1 1 calc R . .
H14A H 0.2055 0.5036 0.3504 0.097 Uiso 1 1 calc R . .
C15 C 0.33659(17) 0.47508(18) 0.44765(16) 0.0804(9) Uani 1 1 d . . .
H15C H 0.3746 0.4191 0.5023 0.121 Uiso 1 1 calc R . .
H15B H 0.2998 0.5499 0.4721 0.121 Uiso 1 1 calc R . .
H15A H 0.3924 0.4749 0.3961 0.121 Uiso 1 1 calc R . .
C20 C 0.49192(10) 0.29640(11) 0.12934(11) 0.0324(5) Uani 1 1 d . . .
C21 C 0.51939(11) 0.27662(12) 0.22916(11) 0.0355(5) Uani 1 1 d . . .
H21 H 0.4605 0.2915 0.2776 0.043 Uiso 1 1 calc R . .
C22 C 0.63024(12) 0.23587(12) 0.25943(13) 0.0452(5) Uani 1 1 d . . .
H22 H 0.6477 0.2219 0.3277 0.054 Uiso 1 1 calc R . .
C23 C 0.71599(12) 0.21571(15) 0.18722(14) 0.0567(7) Uani 1 1 d . . .
H23 H 0.7927 0.1877 0.2062 0.068 Uiso 1 1 calc R . .
C24 C 0.68880(12) 0.23672(15) 0.08805(13) 0.0521(6) Uani 1 1 d . . .
H24 H 0.7477 0.2229 0.0397 0.062 Uiso 1 1 calc R . .
C25 C 0.57900(12) 0.27699(13) 0.05777(12) 0.0450(6) Uani 1 1 d . . .
H25 H 0.5620 0.2915 -0.0106 0.054 Uiso 1 1 calc R . .
C26 C 0.28761(11) 0.49994(11) 0.13044(10) 0.0314(5) Uani 1 1 d . . .
C27 C 0.35667(12) 0.54520(12) 0.16500(12) 0.0411(5) Uani 1 1 d . . .
H27 H 0.4362 0.5018 0.1684 0.049 Uiso 1 1 calc R . .
C28 C 0.30718(14) 0.65697(14) 0.19511(14) 0.0546(7) Uani 1 1 d . . .
H28 H 0.3535 0.6904 0.2152 0.065 Uiso 1 1 calc R . .
C29 C 0.19180(14) 0.71516(13) 0.19457(14) 0.0535(6) Uani 1 1 d . . .
H29 H 0.1575 0.7876 0.2187 0.064 Uiso 1 1 calc R . .
C30 C 0.12555(14) 0.66999(14) 0.15970(15) 0.0576(7) Uani 1 1 d . . .
H30 H 0.0462 0.7141 0.1557 0.069 Uiso 1 1 calc R . .
C31 C 0.16934(11) 0.56497(12) 0.13092(13) 0.0405(5) Uani 1 1 d . . .
H31 H 0.1206 0.5344 0.1108 0.049 Uiso 1 1 calc R . .
C32 C 0.35082(10) 0.37129(11) -0.04027(11) 0.0314(5) Uani 1 1 d . . .
C33 C 0.37643(12) 0.28021(14) -0.08971(12) 0.0483(6) Uani 1 1 d . . .
H33 H 0.3867 0.2109 -0.0535 0.058 Uiso 1 1 calc R . .
C34 C 0.38829(13) 0.28403(15) -0.19108(13) 0.0512(6) Uani 1 1 d . . .
H34 H 0.4083 0.2179 -0.2241 0.061 Uiso 1 1 calc R . .
C35 C 0.37034(13) 0.38715(15) -0.24509(12) 0.0531(6) Uani 1 1 d . . .
H35 H 0.3759 0.3927 -0.3152 0.064 Uiso 1 1 calc R . .
C36 C 0.34511(12) 0.47783(14) -0.19489(12) 0.0507(6) Uani 1 1 d . . .
H36 H 0.3340 0.5471 -0.2317 0.061 Uiso 1 1 calc R . .
C37 C 0.33431(11) 0.47655(12) -0.09332(11) 0.0349(5) Uani 1 1 d . . .
H37 H 0.3168 0.5423 -0.0604 0.042 Uiso 1 1 calc R . .
Cl1A Cl 0.09073(9) 0.03648(10) 0.91999(9) 0.0620(5) Uani 0.40 1 d PD A -2
Cl1B Cl 0.06935(11) 0.03940(10) 0.88030(11) 0.0524(5) Uani 0.30 1 d PD A -2
Cl2A Cl 0.1989(2) 0.10051(16) 0.75715(11) 0.1514(11) Uani 0.40 1 d PD A -2
Cl2B Cl 0.28347(14) 0.05170(16) 0.81394(17) 0.1055(9) Uani 0.30 1 d PD A -2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 P1 155.49(5) . . ?
C1 Pt1 P2 95.88(7) . . ?
P1 Pt1 P2 103.42(3) . . ?
C1 Pt1 Ru4 88.77(7) . . ?
P1 Pt1 Ru4 73.67(3) . . ?
P2 Pt1 Ru4 172.762(10) . . ?
C1 Pt1 Ru1 131.43(6) . . ?
P1 Pt1 Ru1 53.25(4) . . ?
P2 Pt1 Ru1 112.58(3) . . ?
Ru4 Pt1 Ru1 60.29(3) . . ?
C1 Pt1 Ru3 106.26(6) . . ?
P1 Pt1 Ru3 49.97(4) . . ?
P2 Pt1 Ru3 125.15(3) . . ?
Ru4 Pt1 Ru3 58.22(3) . . ?
Ru1 Pt1 Ru3 88.97(5) . . ?
C2 Ru1 C3 96.16(9) . . ?
C2 Ru1 C4 96.45(8) . . ?
C3 Ru1 C4 93.68(9) . . ?
C2 Ru1 P1 116.23(6) . . ?
C3 Ru1 P1 93.39(6) . . ?
C4 Ru1 P1 145.53(6) . . ?
C2 Ru1 Ru4 100.35(7) . . ?
C3 Ru1 Ru4 161.20(5) . . ?
C4 Ru1 Ru4 93.34(8) . . ?
P1 Ru1 Ru4 71.27(4) . . ?
C2 Ru1 Ru2 159.86(5) . . ?
C3 Ru1 Ru2 100.71(6) . . ?
C4 Ru1 Ru2 93.37(7) . . ?
P1 Ru1 Ru2 52.16(3) . . ?
Ru4 Ru1 Ru2 61.46(4) . . ?
C2 Ru1 Pt1 70.76(6) . . ?
C3 Ru1 Pt1 120.82(6) . . ?
C4 Ru1 Pt1 143.68(6) . . ?
P1 Ru1 Pt1 50.96(4) . . ?
Ru4 Ru1 Pt1 57.82(4) . . ?
Ru2 Ru1 Pt1 91.03(5) . . ?
C6 Ru2 C7 92.54(8) . . ?
C6 Ru2 C5 93.75(8) . . ?
C7 Ru2 C5 93.02(8) . . ?
C6 Ru2 P1 88.79(7) . . ?
C7 Ru2 P1 125.76(6) . . ?
C5 Ru2 P1 141.02(5) . . ?
C6 Ru2 Ru1 98.31(6) . . ?
C7 Ru2 Ru1 169.06(6) . . ?
C5 Ru2 Ru1 87.73(6) . . ?
P1 Ru2 Ru1 53.50(4) . . ?
C6 Ru2 Ru3 118.78(6) . . ?
C7 Ru2 Ru3 81.32(7) . . ?
C5 Ru2 Ru3 147.07(6) . . ?
P1 Ru2 Ru3 51.86(3) . . ?
Ru1 Ru2 Ru3 92.13(5) . . ?
C6 Ru2 Ru4 155.46(5) . . ?
C7 Ru2 Ru4 110.06(7) . . ?
C5 Ru2 Ru4 94.46(6) . . ?
P1 Ru2 Ru4 70.49(4) . . ?
Ru1 Ru2 Ru4 59.01(4) . . ?
Ru3 Ru2 Ru4 58.25(4) . . ?
C10 Ru3 C8 90.90(9) . . ?
C10 Ru3 C9 93.58(8) . . ?
C8 Ru3 C9 96.76(9) . . ?
C10 Ru3 P1 120.00(6) . . ?
C8 Ru3 P1 100.04(7) . . ?
C9 Ru3 P1 141.82(5) . . ?
C10 Ru3 Ru4 98.26(7) . . ?
C8 Ru3 Ru4 170.14(5) . . ?
C9 Ru3 Ru4 86.35(6) . . ?
P1 Ru3 Ru4 72.22(5) . . ?
C10 Ru3 Ru2 158.97(5) . . ?
C8 Ru3 Ru2 109.23(7) . . ?
C9 Ru3 Ru2 90.14(6) . . ?
P1 Ru3 Ru2 51.97(4) . . ?
Ru4 Ru3 Ru2 61.29(4) . . ?
C10 Ru3 Pt1 75.65(6) . . ?
C8 Ru3 Pt1 123.21(7) . . ?
C9 Ru3 Pt1 138.19(5) . . ?
P1 Ru3 Pt1 49.16(4) . . ?
Ru4 Ru3 Pt1 56.48(3) . . ?
Ru2 Ru3 Pt1 87.83(5) . . ?
C12 Ru4 C13 92.56(8) . . ?
C12 Ru4 C11 95.45(8) . . ?
C13 Ru4 C11 96.21(9) . . ?
C12 Ru4 Pt1 168.74(6) . . ?
C13 Ru4 Pt1 92.69(7) . . ?
C11 Ru4 Pt1 93.88(7) . . ?
C12 Ru4 Ru3 105.55(6) . . ?
C13 Ru4 Ru3 82.80(7) . . ?
C11 Ru4 Ru3 159.01(6) . . ?
Pt1 Ru4 Ru3 65.30(3) . . ?
C12 Ru4 Ru1 114.20(6) . . ?
C13 Ru4 Ru1 152.83(6) . . ?
C11 Ru4 Ru1 77.46(7) . . ?
Pt1 Ru4 Ru1 61.89(4) . . ?
Ru3 Ru4 Ru1 93.83(5) . . ?
C12 Ru4 Ru2 77.09(7) . . ?
C13 Ru4 Ru2 136.38(6) . . ?
C11 Ru4 Ru2 126.61(6) . . ?
Pt1 Ru4 Ru2 92.27(3) . . ?
Ru3 Ru4 Ru2 60.46(3) . . ?
Ru1 Ru4 Ru2 59.53(4) . . ?
O14 P1 Pt1 118.16(5) . . ?
O14 P1 Ru3 124.56(5) . . ?
Pt1 P1 Ru3 80.87(4) . . ?
O14 P1 Ru2 117.62(5) . . ?
Pt1 P1 Ru2 123.32(3) . . ?
Ru3 P1 Ru2 76.17(4) . . ?
O14 P1 Ru1 113.05(5) . . ?
Pt1 P1 Ru1 75.79(4) . . ?
Ru3 P1 Ru1 122.25(4) . . ?
Ru2 P1 Ru1 74.34(4) . . ?
C26 P2 C20 104.72(8) . . ?
C26 P2 C32 105.42(7) . . ?
C20 P2 C32 102.99(8) . . ?
C26 P2 Pt1 113.09(6) . . ?
C20 P2 Pt1 117.24(6) . . ?
C32 P2 Pt1 112.20(6) . . ?
C14 O14 P1 127.52(11) . . ?
O1 C1 Pt1 173.20(12) . . ?
C1B C1A Cl2B 163.9(5) . . ?
C1B C1A Cl2A 148.4(4) . . ?
Cl2B C1A Cl2A 47.23(16) . . ?
C1B C1A Cl1A 42.9(4) . . ?
Cl2B C1A Cl1A 153.1(2) . . ?
Cl2A C1A Cl1A 107.10(18) . . ?
C1B C1A Cl1B 60.8(5) . . ?
Cl2B C1A Cl1B 135.1(2) . . ?
Cl2A C1A Cl1B 90.19(16) . . ?
Cl1A C1A Cl1B 18.01(7) . . ?
C1A C1B Cl1A 121.8(5) . . ?
C1A C1B Cl2B 11.2(4) . . ?
Cl1A C1B Cl2B 133.0(3) . . ?
C1A C1B Cl1B 103.6(5) . . ?
Cl1A C1B Cl1B 18.46(9) . . ?
Cl2B C1B Cl1B 114.6(2) . . ?
C1A C1B Cl2A 24.2(3) . . ?
Cl1A C1B Cl2A 99.13(19) . . ?
Cl2B C1B Cl2A 35.10(12) . . ?
Cl1B C1B Cl2A 81.61(16) . . ?
O2 C2 Ru1 173.55(13) . . ?
O3 C3 Ru1 176.53(14) . . ?
O4 C4 Ru1 177.29(17) . . ?
O5 C5 Ru2 177.65(13) . . ?
O6 C6 Ru2 172.72(14) . . ?
O7 C7 Ru2 174.59(14) . . ?
O8 C8 Ru3 176.60(18) . . ?
O9 C9 Ru3 179.84(16) . . ?
O10 C10 Ru3 175.42(13) . . ?
O11 C11 Ru4 175.73(17) . . ?
O12 C12 Ru4 174.36(17) . . ?
O13 C13 Ru4 177.12(13) . . ?
O14 C14 C15 111.89(14) . . ?
C21 C20 C25 119.02(13) . . ?
C21 C20 P2 119.20(11) . . ?
C25 C20 P2 121.58(12) . . ?
C22 C21 C20 121.68(14) . . ?
C21 C22 C23 118.54(16) . . ?
C24 C23 C22 119.89(15) . . ?
C25 C24 C23 121.73(15) . . ?
C24 C25 C20 119.12(15) . . ?
C27 C26 C31 118.46(14) . . ?
C27 C26 P2 122.10(10) . . ?
C31 C26 P2 119.25(14) . . ?
C26 C27 C28 119.66(13) . . ?
C29 C28 C27 118.86(19) . . ?
C30 C29 C28 120.60(16) . . ?
C31 C30 C29 121.94(15) . . ?
C30 C31 C26 120.26(18) . . ?
C33 C32 C37 119.79(15) . . ?
C33 C32 P2 119.63(12) . . ?
C37 C32 P2 120.52(12) . . ?
C32 C33 C34 122.19(17) . . ?
C33 C34 C35 119.07(17) . . ?
C36 C35 C34 118.28(16) . . ?
C35 C36 C37 124.12(16) . . ?
C36 C37 C32 116.53(15) . . ?
Cl1B Cl1A C1B 115.1(3) . . ?
Cl1B Cl1A C1A 100.1(2) . . ?
C1B Cl1A C1A 15.24(17) . . ?
Cl1A Cl1B C1B 46.4(2) . . ?
Cl1A Cl1B C1A 61.91(19) . . ?
C1B Cl1B C1A 15.63(14) . . ?
Cl2B Cl2A C1A 44.89(14) . . ?
Cl2B Cl2A C1B 52.20(13) . . ?
C1A Cl2A C1B 7.35(10) . . ?
C1A Cl2B Cl2A 87.88(19) . . ?
C1A Cl2B C1B 4.92(16) . . ?
Cl2A Cl2B C1B 92.70(18) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 1.8496(19) . ?
Pt1 P1 2.2989(15) . ?
Pt1 P2 2.3371(10) . ?
Pt1 Ru4 2.7534(10) . ?
Pt1 Ru1 2.8693(16) . ?
Pt1 Ru3 3.0002(17) . ?
Ru1 C2 1.8758(19) . ?
Ru1 C3 1.885(2) . ?
Ru1 C4 1.8903(18) . ?
Ru1 P1 2.3716(14) . ?
Ru1 Ru4 2.8256(14) . ?
Ru1 Ru2 2.8408(16) . ?
Ru2 C6 1.893(2) . ?
Ru2 C7 1.9110(19) . ?
Ru2 C5 1.9160(18) . ?
Ru2 P1 2.3298(10) . ?
Ru2 Ru3 2.8722(17) . ?
Ru2 Ru4 2.8956(17) . ?
Ru3 C10 1.8884(19) . ?
Ru3 C8 1.904(2) . ?
Ru3 C9 1.914(2) . ?
Ru3 P1 2.3266(14) . ?
Ru3 Ru4 2.8074(13) . ?
Ru4 C12 1.897(2) . ?
Ru4 C13 1.9056(19) . ?
Ru4 C11 1.9355(19) . ?
P1 O14 1.5871(14) . ?
P2 C26 1.8023(17) . ?
P2 C20 1.8224(17) . ?
P2 C32 1.8317(19) . ?
O1 C1 1.161(2) . ?
O2 C2 1.155(2) . ?
O3 C3 1.153(2) . ?
O4 C4 1.149(2) . ?
O5 C5 1.134(2) . ?
O6 C6 1.117(3) . ?
O7 C7 1.141(2) . ?
O8 C8 1.121(2) . ?
O9 C9 1.135(2) . ?
O10 C10 1.141(2) . ?
O11 C11 1.121(2) . ?
O12 C12 1.133(2) . ?
O13 C13 1.153(2) . ?
O14 C14 1.436(2) . ?
C1A C1B 0.541(5) . ?
C1A Cl2B 1.225(4) . ?
C1A Cl2A 1.735(3) . ?
C1A Cl1A 1.749(3) . ?
C1A Cl1B 1.951(4) . ?
C1B Cl1A 1.402(4) . ?
C1B Cl2B 1.751(4) . ?
C1B Cl1B 1.752(4) . ?
C1B Cl2A 2.214(4) . ?
C14 C15 1.562(4) . ?
C20 C21 1.395(2) . ?
C20 C25 1.407(2) . ?
C21 C22 1.385(2) . ?
C22 C23 1.400(2) . ?
C23 C24 1.385(3) . ?
C24 C25 1.373(2) . ?
C26 C27 1.397(3) . ?
C26 C31 1.413(2) . ?
C27 C28 1.428(2) . ?
C28 C29 1.370(2) . ?
C29 C30 1.367(3) . ?
C30 C31 1.345(2) . ?
C32 C33 1.343(2) . ?
C32 C37 1.428(2) . ?
C33 C34 1.377(3) . ?
C34 C35 1.406(3) . ?
C35 C36 1.346(3) . ?
C36 C37 1.380(2) . ?
Cl1A Cl1B 0.613(2) . ?
Cl2A Cl2B 1.274(3) . ?
