#------------------------------------------------------------------------------
#$Date: 2016-03-23 14:53:57 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179311 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/08/4320869.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4320869
loop_
_publ_author_name
'Bing Luo'
'Victor G. Young'
'Wayne L. Gladfelter'
_publ_section_title
;
 Syntheses and Structures of Quinuclidine-Stabilized Amido- and
 Azidogallanes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1705
_journal_page_last               1709
_journal_paper_doi               10.1021/ic9910110
_journal_volume                  39
_journal_year                    2000
_chemical_compound_source        'Bing Luo, Prof. Gladfelter'
_chemical_formula_sum            'C13 H33 Ga N2 Si2'
_chemical_formula_weight         343.31
_chemical_name_common            98253
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   'geom but difmap for H1GA, H2GA'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 112.3670(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.33920(1)
_cell_length_b                   14.78540(1)
_cell_length_c                   12.0588(2)
_cell_measurement_reflns_used    80
_cell_measurement_temperature    173(2)
_cell_volume                     1869.61(3)
_computing_cell_refinement       'SMART, Bruker'
_computing_data_collection       'SMART, Bruker'
_computing_data_reduction        'SAINT, Bruker'
_computing_molecular_graphics    'SHELXTL, Bruker'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measurement_device       'CCD, Bruker'
_diffrn_measurement_method       ω-θ-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0264
_diffrn_reflns_av_sigmaI/netI    0.0318
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            9484
_diffrn_reflns_theta_max         25.04
_diffrn_reflns_theta_min         2.10
_exptl_absorpt_coefficient_mu    1.589
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.903578
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.220
_exptl_crystal_description       block
_exptl_crystal_F_000             736
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.3
_refine_diff_density_max         0.305
_refine_diff_density_min         -0.270
_refine_diff_density_rms         0.051
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.044
_refine_ls_goodness_of_fit_obs   1.062
_refine_ls_hydrogen_treatment    'rfxyz but refall for H1GA, H2GA'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     169
_refine_ls_number_reflns         3305
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.044
_refine_ls_restrained_S_obs      1.062
_refine_ls_R_factor_all          0.0353
_refine_ls_R_factor_obs          0.0258
_refine_ls_shift/esd_max         -0.002
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0228P)²+0.9775P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0613
_refine_ls_wR_factor_obs         0.0574
_reflns_number_observed          2829
_reflns_number_total             3305
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic9910110_2.cif
_cod_data_source_block           253a_Compound2:H2Ga[N(TMS)2](quin)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0228P)^2^+0.9775P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0228P)^2^+0.9775P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        1869.61(4)
_cod_database_code               4320869
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Ga1 Ga 0.24400(2) 0.10735(2) 0.61700(2) 0.02245(8) Uani 1 d . .
Si1 Si 0.52104(5) 0.15972(4) 0.77017(5) 0.02221(14) Uani 1 d . .
Si2 Si 0.46422(6) -0.03897(4) 0.71228(5) 0.02329(14) Uani 1 d . .
N1 N 0.1360(2) 0.08451(11) 0.7231(2) 0.0214(4) Uani 1 d . .
N2 N 0.4147(2) 0.07120(12) 0.71217(15) 0.0209(4) Uani 1 d . .
C1 C 0.0096(2) 0.1298(2) 0.6634(2) 0.0336(6) Uani 1 d . .
H1A H -0.0383(2) 0.0994(2) 0.5860(2) 0.040 Uiso 1 calc R .
H1B H 0.0230(2) 0.1936(2) 0.6463(2) 0.040 Uiso 1 calc R .
C2 C -0.0691(2) 0.1263(2) 0.7431(2) 0.0438(7) Uani 1 d . .
H2A H -0.0758(2) 0.1876(2) 0.7732(2) 0.053 Uiso 1 calc R .
H2B H -0.1563(2) 0.1042(2) 0.6959(2) 0.053 Uiso 1 calc R .
C3 C -0.0029(2) 0.0624(2) 0.8486(2) 0.0312(5) Uani 1 d . .
H3 H -0.0566(2) 0.0539(2) 0.8970(2) 0.037 Uiso 1 calc R .
C4 C 0.0206(2) -0.0279(2) 0.8003(2) 0.0383(6) Uani 1 d . .
H4A H -0.0610(2) -0.0531(2) 0.7437(2) 0.046 Uiso 1 calc R .
H4B H 0.0577(2) -0.0713(2) 0.8671(2) 0.046 Uiso 1 calc R .
C5 C 0.1131(2) -0.01347(15) 0.7357(2) 0.0305(5) Uani 1 d . .
H5A H 0.1952(2) -0.04362(15) 0.7816(2) 0.037 Uiso 1 calc R .
H5B H 0.0770(2) -0.04158(15) 0.6552(2) 0.037 Uiso 1 calc R .
C6 C 0.2004(2) 0.1239(2) 0.8447(2) 0.0286(5) Uani 1 d . .
H6A H 0.2079(2) 0.1902(2) 0.8378(2) 0.034 Uiso 1 calc R .
H6B H 0.2875(2) 0.0987(2) 0.8821(2) 0.034 Uiso 1 calc R .
C7 C 0.1257(2) 0.1036(2) 0.9256(2) 0.0348(6) Uani 1 d . .
H7A H 0.1744(2) 0.0609(2) 0.9899(2) 0.042 Uiso 1 calc R .
H7B H 0.1126(2) 0.1601(2) 0.9635(2) 0.042 Uiso 1 calc R .
C8 C 0.5592(2) 0.2164(2) 0.6488(2) 0.0368(6) Uani 1 d . .
H8A H 0.5914(2) 0.1714(2) 0.6076(2) 0.055 Uiso 1 calc R .
H8B H 0.6243(2) 0.2630(2) 0.6841(2) 0.055 Uiso 1 calc R .
H8C H 0.4819(2) 0.2445(2) 0.5911(2) 0.055 Uiso 1 calc R .
C9 C 0.6754(2) 0.1220(2) 0.8896(2) 0.0360(6) Uani 1 d . .
H9A H 0.7135(2) 0.0743(2) 0.8576(2) 0.054 Uiso 1 calc R .
H9B H 0.6591(2) 0.0987(2) 0.9585(2) 0.054 Uiso 1 calc R .
H9C H 0.7341(2) 0.1735(2) 0.9150(2) 0.054 Uiso 1 calc R .
C10 C 0.4605(2) 0.24978(15) 0.8438(2) 0.0282(5) Uani 1 d . .
H10A H 0.4393(2) 0.22296(15) 0.9082(2) 0.042 Uiso 1 calc R .
H10B H 0.3841(2) 0.27755(15) 0.7844(2) 0.042 Uiso 1 calc R .
H10C H 0.5265(2) 0.29603(15) 0.8774(2) 0.042 Uiso 1 calc R .
C11 C 0.6060(2) -0.0512(2) 0.6680(3) 0.0396(6) Uani 1 d . .
H11A H 0.6807(8) -0.0228(20) 0.7289(15) 0.059 Uiso 0.73(3) calc PR .
H11B H 0.5877(12) -0.0217(20) 0.5904(15) 0.059 Uiso 0.73(3) calc PR .
H11C H 0.6233(20) -0.1155(2) 0.6616(30) 0.059 Uiso 0.73(3) calc PR .
H11D H 0.5804(8) -0.0839(20) 0.5917(16) 0.059 Uiso 0.27(3) calc PR .
H11E H 0.6735(13) -0.0850(20) 0.7302(15) 0.059 Uiso 0.27(3) calc PR .
H11F H 0.6378(20) 0.0089(2) 0.6590(30) 0.059 Uiso 0.27(3) calc PR .
C12 C 0.5073(3) -0.0927(2) 0.8639(2) 0.0414(6) Uani 1 d . .
H12A H 0.5578(18) -0.0501(6) 0.9261(3) 0.062 Uiso 0.88(3) calc PR .
H12B H 0.5573(18) -0.1476(8) 0.8683(7) 0.062 Uiso 0.88(3) calc PR .
H12C H 0.4293(3) -0.1084(14) 0.8764(8) 0.062 Uiso 0.88(3) calc PR .
H12D H 0.4718(18) -0.1539(6) 0.8544(3) 0.062 Uiso 0.12(3) calc PR .
H12E H 0.4723(18) -0.0564(8) 0.9122(7) 0.062 Uiso 0.12(3) calc PR .
H12F H 0.6004(3) -0.0957(14) 0.9042(8) 0.062 Uiso 0.12(3) calc PR .
C13 C 0.3383(2) -0.1122(2) 0.6045(2) 0.0333(6) Uani 1 d . .
H13A H 0.3124(2) -0.0869(2) 0.5235(2) 0.050 Uiso 1 calc R .
H13B H 0.2644(2) -0.1147(2) 0.6276(2) 0.050 Uiso 1 calc R .
H13C H 0.3721(2) -0.1733(2) 0.6057(2) 0.050 Uiso 1 calc R .
H1GA H 0.2224(2) 0.2055(2) 0.5994(2) 0.035(7) Uiso 1 d R .
H2GA H 0.1813(2) 0.0485(2) 0.5139(2) 0.040(7) Uiso 1 d R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ga1 N1 106.26(7) . . ?
N2 Ga1 H1GA 115.87(11) . . ?
N1 Ga1 H1GA 98.16(10) . . ?
N2 Ga1 H2GA 113.42(11) . . ?
N1 Ga1 H2GA 102.36(10) . . ?
H1GA Ga1 H2GA 117.6(2) . . ?
N2 Si1 C10 113.83(9) . . ?
N2 Si1 C8 110.72(10) . . ?
C10 Si1 C8 106.73(11) . . ?
N2 Si1 C9 112.76(10) . . ?
C10 Si1 C9 104.49(11) . . ?
C8 Si1 C9 107.86(12) . . ?
N2 Si2 C13 112.63(10) . . ?
N2 Si2 C12 111.36(10) . . ?
C13 Si2 C12 106.23(12) . . ?
N2 Si2 C11 113.78(10) . . ?
C13 Si2 C11 104.80(11) . . ?
C12 Si2 C11 107.51(13) . . ?
C6 N1 C5 108.7(2) . . ?
C6 N1 C1 108.7(2) . . ?
C5 N1 C1 108.2(2) . . ?
C6 N1 Ga1 110.83(12) . . ?
C5 N1 Ga1 112.45(13) . . ?
C1 N1 Ga1 107.91(13) . . ?
Si2 N2 Si1 122.42(10) . . ?
Si2 N2 Ga1 121.32(10) . . ?
Si1 N2 Ga1 114.85(9) . . ?
N1 C1 C2 111.1(2) . . ?
N1 C1 H1A 109.41(12) . . ?
C2 C1 H1A 109.41(14) . . ?
N1 C1 H1B 109.41(12) . . ?
C2 C1 H1B 109.41(14) . . ?
H1A C1 H1B 108.0 . . ?
C3 C2 C1 108.8(2) . . ?
C3 C2 H2A 109.94(15) . . ?
C1 C2 H2A 109.94(15) . . ?
C3 C2 H2B 109.94(14) . . ?
C1 C2 H2B 109.94(14) . . ?
H2A C2 H2B 108.3 . . ?
C4 C3 C7 108.5(2) . . ?
C4 C3 C2 109.0(2) . . ?
C7 C3 C2 108.2(2) . . ?
C4 C3 H3 110.34(12) . . ?
C7 C3 H3 110.34(12) . . ?
C2 C3 H3 110.34(12) . . ?
C3 C4 C5 108.9(2) . . ?
C3 C4 H4A 109.91(13) . . ?
C5 C4 H4A 109.91(14) . . ?
C3 C4 H4B 109.91(14) . . ?
C5 C4 H4B 109.91(13) . . ?
H4A C4 H4B 108.3 . . ?
N1 C5 C4 111.4(2) . . ?
N1 C5 H5A 109.35(11) . . ?
C4 C5 H5A 109.35(14) . . ?
N1 C5 H5B 109.35(12) . . ?
C4 C5 H5B 109.35(13) . . ?
H5A C5 H5B 108.0 . . ?
N1 C6 C7 111.4(2) . . ?
N1 C6 H6A 109.34(11) . . ?
C7 C6 H6A 109.34(13) . . ?
N1 C6 H6B 109.34(11) . . ?
C7 C6 H6B 109.34(13) . . ?
H6A C6 H6B 108.0 . . ?
C3 C7 C6 108.6(2) . . ?
C3 C7 H7A 109.97(13) . . ?
C6 C7 H7A 109.97(13) . . ?
C3 C7 H7B 109.97(13) . . ?
C6 C7 H7B 109.97(13) . . ?
H7A C7 H7B 108.3 . . ?
Si1 C8 H8A 109.47(8) . . ?
Si1 C8 H8B 109.47(8) . . ?
H8A C8 H8B 109.5 . . ?
Si1 C8 H8C 109.47(8) . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
Si1 C9 H9A 109.47(8) . . ?
Si1 C9 H9B 109.47(8) . . ?
H9A C9 H9B 109.5 . . ?
Si1 C9 H9C 109.47(8) . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
Si1 C10 H10A 109.47(7) . . ?
Si1 C10 H10B 109.47(7) . . ?
H10A C10 H10B 109.5 . . ?
Si1 C10 H10C 109.47(7) . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
Si2 C11 H11A 109.47(8) . . ?
Si2 C11 H11B 109.47(9) . . ?
H11A C11 H11B 109.5 . . ?
Si2 C11 H11C 109.47(8) . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Si2 C11 H11D 109.47(8) . . ?
H11A C11 H11D 141.1 . . ?
H11B C11 H11D 56.3 . . ?
H11C C11 H11D 56.3 . . ?
Si2 C11 H11E 109.47(9) . . ?
H11A C11 H11E 56.3 . . ?
H11B C11 H11E 141.1 . . ?
H11C C11 H11E 56.3 . . ?
H11D C11 H11E 109.5 . . ?
Si2 C11 H11F 109.47(8) . . ?
H11A C11 H11F 56.3 . . ?
H11B C11 H11F 56.3 . . ?
H11C C11 H11F 141.1 . . ?
H11D C11 H11F 109.5 . . ?
H11E C11 H11F 109.5 . . ?
Si2 C12 H12A 109.47(8) . . ?
Si2 C12 H12B 109.47(8) . . ?
H12A C12 H12B 109.5 . . ?
Si2 C12 H12C 109.47(9) . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
Si2 C12 H12D 109.47(8) . . ?
H12A C12 H12D 141.1 . . ?
H12B C12 H12D 56.3 . . ?
H12C C12 H12D 56.3 . . ?
Si2 C12 H12E 109.47(8) . . ?
H12A C12 H12E 56.3 . . ?
H12B C12 H12E 141.1 . . ?
H12C C12 H12E 56.3 . . ?
H12D C12 H12E 109.5 . . ?
Si2 C12 H12F 109.47(9) . . ?
H12A C12 H12F 56.3 . . ?
H12B C12 H12F 56.3 . . ?
H12C C12 H12F 141.1 . . ?
H12D C12 H12F 109.5 . . ?
H12E C12 H12F 109.5 . . ?
Si2 C13 H13A 109.47(8) . . ?
Si2 C13 H13B 109.47(7) . . ?
H13A C13 H13B 109.5 . . ?
Si2 C13 H13C 109.47(8) . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ga1 N2 1.913(2) . ?
Ga1 N1 2.108(2) . ?
Ga1 H1GA 1.473(2) . ?
Ga1 H2GA 1.462(2) . ?
Si1 N2 1.736(2) . ?
Si1 C10 1.870(2) . ?
Si1 C8 1.875(2) . ?
Si1 C9 1.879(2) . ?
Si2 N2 1.723(2) . ?
Si2 C13 1.867(2) . ?
Si2 C12 1.880(3) . ?
Si2 C11 1.886(2) . ?
N1 C6 1.486(3) . ?
N1 C5 1.490(3) . ?
N1 C1 1.496(3) . ?
C1 C2 1.542(3) . ?
C1 H1A 0.99 . ?
C1 H1B 0.99 . ?
C2 C3 1.531(3) . ?
C2 H2A 0.99 . ?
C2 H2B 0.99 . ?
C3 C4 1.520(3) . ?
C3 C7 1.526(3) . ?
C3 H3 1.00 . ?
C4 C5 1.541(3) . ?
C4 H4A 0.99 . ?
C4 H4B 0.99 . ?
C5 H5A 0.99 . ?
C5 H5B 0.99 . ?
C6 C7 1.546(3) . ?
C6 H6A 0.99 . ?
C6 H6B 0.99 . ?
C7 H7A 0.99 . ?
C7 H7B 0.99 . ?
C8 H8A 0.98 . ?
C8 H8B 0.98 . ?
C8 H8C 0.98 . ?
C9 H9A 0.98 . ?
C9 H9B 0.98 . ?
C9 H9C 0.98 . ?
C10 H10A 0.98 . ?
C10 H10B 0.98 . ?
C10 H10C 0.98 . ?
C11 H11A 0.98 . ?
C11 H11B 0.98 . ?
C11 H11C 0.98 . ?
C11 H11D 0.98 . ?
C11 H11E 0.98 . ?
C11 H11F 0.98 . ?
C12 H12A 0.98 . ?
C12 H12B 0.98 . ?
C12 H12C 0.98 . ?
C12 H12D 0.98 . ?
C12 H12E 0.98 . ?
C12 H12F 0.98 . ?
C13 H13A 0.98 . ?
C13 H13B 0.98 . ?
C13 H13C 0.98 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N2 Ga1 N1 C6 49.16(15) . . . . ?
N2 Ga1 N1 C5 -72.7(2) . . . . ?
N2 Ga1 N1 C1 168.08(14) . . . . ?
C13 Si2 N2 Si1 -161.96(11) . . . . ?
C12 Si2 N2 Si1 78.82(15) . . . . ?
C11 Si2 N2 Si1 -42.9(2) . . . . ?
C13 Si2 N2 Ga1 3.79(14) . . . . ?
C12 Si2 N2 Ga1 -115.43(13) . . . . ?
C11 Si2 N2 Ga1 122.88(13) . . . . ?
C10 Si1 N2 Si2 -145.29(12) . . . . ?
C8 Si1 N2 Si2 94.47(14) . . . . ?
C9 Si1 N2 Si2 -26.5(2) . . . . ?
C10 Si1 N2 Ga1 48.11(13) . . . . ?
C8 Si1 N2 Ga1 -72.13(13) . . . . ?
C9 Si1 N2 Ga1 166.92(10) . . . . ?
N1 Ga1 N2 Si2 87.70(11) . . . . ?
N1 Ga1 N2 Si1 -105.54(10) . . . . ?
C6 N1 C1 C2 -52.8(3) . . . . ?
C5 N1 C1 C2 65.1(3) . . . . ?
Ga1 N1 C1 C2 -173.0(2) . . . . ?
N1 C1 C2 C3 -10.2(3) . . . . ?
C1 C2 C3 C4 -52.8(3) . . . . ?
C1 C2 C3 C7 65.0(3) . . . . ?
C7 C3 C4 C5 -54.0(3) . . . . ?
C2 C3 C4 C5 63.6(3) . . . . ?
C6 N1 C5 C4 63.9(2) . . . . ?
C1 N1 C5 C4 -54.0(2) . . . . ?
Ga1 N1 C5 C4 -173.0(2) . . . . ?
C3 C4 C5 N1 -8.7(3) . . . . ?
C5 N1 C6 C7 -53.1(2) . . . . ?
C1 N1 C6 C7 64.4(2) . . . . ?
Ga1 N1 C6 C7 -177.17(15) . . . . ?
C4 C3 C7 C6 64.3(2) . . . . ?
C2 C3 C7 C6 -53.9(3) . . . . ?
N1 C6 C7 C3 -9.3(3) . . . . ?
