#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:06:27 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179313 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/10/4321082.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4321082
loop_
_publ_author_name
'Michael Gerken'
'Peter Kolb'
'Andreas Wegner'
'Hélène P. A. Mercier'
'Horst Borrmann'
'David A. Dixon'
'Gary J. Schrobilgen'
_publ_section_title
;
 Tetrachloro- and Tetrabromoarsonium(V) Cations: Raman and 75As, 19F NMR
 Spectroscopic Characterization and X-ray Crystal Structures of
 [AsCl4][As(OTeF5)6] and [AsBr4][AsF(OTeF5)5]
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2813
_journal_page_last               2824
_journal_paper_doi               10.1021/ic000118g
_journal_volume                  39
_journal_year                    2000
_chemical_formula_sum            'As2 Br4 F26 O5 Te5'
_chemical_formula_weight         1681.48
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                103.53(4)
_cell_angle_beta                 103.53(4)
_cell_angle_gamma                105.10(4)
_cell_formula_units_Z            4
_cell_length_a                   9.778(4)
_cell_length_b                   17.731(7)
_cell_length_c                   18.870(8)
_cell_measurement_temperature    90(2)
_cell_volume                     2915(2)
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      90(2)
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0739
_diffrn_reflns_av_sigmaI/netI    0.0875
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            33411
_diffrn_reflns_theta_max         25.91
_diffrn_reflns_theta_min         2.70
_exptl_absorpt_coefficient_mu    12.863
_exptl_crystal_density_diffrn    3.831
_exptl_crystal_F_000             2960
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.11
_refine_diff_density_max         2.533
_refine_diff_density_min         -2.120
_refine_diff_density_rms         0.227
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   0.920
_refine_ls_goodness_of_fit_obs   1.026
_refine_ls_matrix_type           full
_refine_ls_number_parameters     757
_refine_ls_number_reflns         10391
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.932
_refine_ls_restrained_S_obs      1.026
_refine_ls_R_factor_all          0.0754
_refine_ls_R_factor_obs          0.0368
_refine_ls_shift/esd_max         0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0140P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0582
_refine_ls_wR_factor_obs         0.0513
_reflns_number_observed          7008
_reflns_number_total             10508
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic000118g_3.cif
_cod_data_source_block           As2Br4F26O5Te5(-183C)
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0140P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0140P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2915.2(21)
_cod_database_code               4321082
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
As1 As 0.62843(11) 0.53023(6) 0.78205(5) 0.0133(2) Uani 1 d . .
Br1 Br 0.76097(12) 0.50724(7) 0.70271(5) 0.0209(2) Uani 1 d . .
Br2 Br 0.74631(11) 0.53090(7) 0.89912(5) 0.0191(2) Uani 1 d . .
Br3 Br 0.59550(12) 0.65163(7) 0.79078(6) 0.0214(2) Uani 1 d . .
Br4 Br 0.40899(12) 0.42927(7) 0.73565(5) 0.0203(2) Uani 1 d . .
As2 As 0.91673(11) 0.99362(7) 0.26289(5) 0.0148(2) Uani 1 d . .
Br5 Br 0.99964(12) 1.11723(7) 0.35161(6) 0.0246(2) Uani 1 d . .
Br6 Br 1.02934(11) 0.99705(7) 0.17288(5) 0.0191(2) Uani 1 d . .
Br7 Br 0.97600(12) 0.90352(7) 0.31911(6) 0.0250(3) Uani 1 d . .
As3 As 0.62014(11) 0.27680(6) 0.48644(5) 0.0101(2) Uani 1 d . .
F1 F 0.6834(6) 0.3794(3) 0.5392(3) 0.0144(12) Uani 1 d . .
O1 O 0.5879(7) 0.2532(4) 0.5704(3) 0.017(2) Uani 1 d . .
Te1 Te 0.45118(8) 0.17689(4) 0.59329(3) 0.0176(2) Uani 1 d . .
F11 F 0.3082(6) 0.1395(4) 0.4999(3) 0.0244(14) Uani 1 d . .
F12 F 0.5246(7) 0.0939(4) 0.5626(4) 0.031(2) Uani 1 d . .
F13 F 0.5784(7) 0.2080(5) 0.6899(3) 0.038(2) Uani 1 d . .
F14 F 0.3642(7) 0.2531(4) 0.6250(3) 0.030(2) Uani 1 d . .
F15 F 0.3218(8) 0.1061(4) 0.6232(4) 0.035(2) Uani 1 d . .
O2 O 0.8074(7) 0.2730(4) 0.5145(3) 0.0137(15) Uani 1 d . .
Te2 Te 0.94981(7) 0.28568(4) 0.60440(3) 0.01511(14) Uani 1 d . .
F21 F 0.8359(6) 0.2018(4) 0.6286(3) 0.0222(14) Uani 1 d . .
F22 F 1.0163(6) 0.2103(4) 0.5504(3) 0.0218(13) Uani 1 d . .
F23 F 1.0832(6) 0.3687(4) 0.5895(3) 0.0239(14) Uani 1 d . .
F24 F 0.8950(7) 0.3607(4) 0.6663(3) 0.0247(14) Uani 1 d . .
F25 F 1.0997(6) 0.2976(4) 0.6901(3) 0.0263(15) Uani 1 d . .
O3 O 0.6501(7) 0.3004(4) 0.4020(3) 0.0110(14) Uani 1 d . .
Te3 Te 0.80591(7) 0.36309(4) 0.37824(3) 0.01233(14) Uani 1 d . .
F31 F 0.9152(6) 0.4213(4) 0.4778(3) 0.0213(14) Uani 1 d . .
F32 F 0.7163(7) 0.4418(4) 0.3732(3) 0.0226(14) Uani 1 d . .
F33 F 0.7043(6) 0.3081(4) 0.2760(3) 0.0171(13) Uani 1 d . .
F34 F 0.9070(6) 0.2891(4) 0.3790(3) 0.0184(13) Uani 1 d . .
F35 F 0.9511(6) 0.4239(4) 0.3486(3) 0.0203(14) Uani 1 d . .
O4 O 0.4295(7) 0.2748(4) 0.4524(3) 0.0130(15) Uani 1 d . .
Te4 Te 0.33646(7) 0.35306(4) 0.45360(3) 0.01086(13) Uani 1 d . .
F41 F 0.4837(6) 0.4273(3) 0.4368(3) 0.0153(12) Uani 1 d . .
F42 F 0.2472(6) 0.3089(4) 0.3501(3) 0.0190(13) Uani 1 d . .
F43 F 0.1795(6) 0.2817(4) 0.4664(3) 0.0173(13) Uani 1 d . .
F44 F 0.4148(6) 0.4018(3) 0.5577(3) 0.0162(12) Uani 1 d . .
F45 F 0.2320(6) 0.4246(4) 0.4519(3) 0.0226(14) Uani 1 d . .
O5 O 0.5552(7) 0.1674(4) 0.4373(3) 0.0140(15) Uani 1 d . .
Te5 Te 0.47614(7) 0.09990(4) 0.33597(3) 0.01305(14) Uani 1 d . .
F51 F 0.3099(7) 0.0441(4) 0.3547(3) 0.0276(15) Uani 1 d . .
F52 F 0.5666(7) 0.0287(4) 0.3637(3) 0.028(2) Uani 1 d . .
F53 F 0.6341(6) 0.1457(3) 0.3063(3) 0.0197(13) Uani 1 d . .
F54 F 0.3753(6) 0.1642(4) 0.3010(3) 0.0233(14) Uani 1 d . .
F55 F 0.3964(6) 0.0266(4) 0.2380(3) 0.0205(13) Uani 1 d . .
As4 As 1.36980(11) 0.76327(7) 0.98470(5) 0.0133(2) Uani 1 d . .
F2 F 1.3953(6) 0.8656(4) 1.0288(3) 0.0224(14) Uani 1 d . .
O6 O 1.2118(8) 0.7298(5) 1.0174(4) 0.023(2) Uani 1 d . .
Te6 Te 1.16936(8) 0.74922(5) 1.10896(3) 0.0197(2) Uani 1 d . .
F61 F 1.0693(7) 0.8172(4) 1.0838(3) 0.034(2) Uani 1 d . .
F62 F 0.9984(8) 0.6599(5) 1.0591(3) 0.043(2) Uani 1 d . .
F63 F 1.2640(8) 0.6809(4) 1.1405(3) 0.035(2) Uani 1 d . .
F64 F 1.3352(7) 0.8388(4) 1.1647(3) 0.0258(14) Uani 1 d . .
F65 F 1.1113(7) 0.7608(4) 1.1947(3) 0.034(2) Uani 1 d . .
O7 O 1.4978(7) 0.7660(4) 1.0736(3) 0.0149(15) Uani 1 d . .
Te7 Te 1.63462(7) 0.71557(4) 1.10232(3) 0.01275(14) Uani 1 d . .
F72 F 1.6248(6) 0.7478(4) 1.2000(3) 0.0205(14) Uani 1 d . .
F73 F 1.4920(6) 0.6160(4) 1.0815(3) 0.0217(13) Uani 1 d . .
F74 F 1.6600(6) 0.6812(4) 1.0086(3) 0.0232(14) Uani 1 d . .
F75 F 1.7735(7) 0.6711(4) 1.1401(3) 0.0261(14) Uani 1 d . .
O8 O 1.5244(8) 0.7917(5) 0.9493(4) 0.026(2) Uani 1 d . .
Te8 Te 1.63940(8) 0.88659(5) 0.93904(4) 0.0186(2) Uani 1 d . .
F81 F 1.6912(7) 0.9489(4) 1.0389(3) 0.028(2) Uani 1 d . .
F82 F 1.4912(7) 0.9276(4) 0.9125(3) 0.034(2) Uani 1 d . .
F83 F 1.6023(7) 0.8298(4) 0.8378(3) 0.032(2) Uani 1 d . .
F84 F 1.8009(7) 0.8521(4) 0.9639(4) 0.034(2) Uani 1 d . .
F85 F 1.7652(7) 0.9720(4) 0.9237(3) 0.028(2) Uani 1 d . .
O9 O 1.2462(8) 0.7602(5) 0.8958(4) 0.021(2) Uani 1 d . .
Te9 Te 1.07906(7) 0.78902(4) 0.86240(4) 0.01542(15) Uani 1 d . .
F91 F 1.1247(7) 0.8758(4) 0.9484(3) 0.030(2) Uani 1 d . .
F92 F 1.1769(7) 0.8568(4) 0.8174(3) 0.033(2) Uani 1 d . .
F93 F 1.0175(7) 0.7048(4) 0.7736(3) 0.0256(14) Uani 1 d . .
F94 F 0.9612(6) 0.7244(4) 0.9024(3) 0.0198(13) Uani 1 d . .
F95 F 0.9136(6) 0.8145(4) 0.8213(3) 0.0243(14) Uani 1 d . .
O10 O 1.3571(8) 0.6594(5) 0.9429(4) 0.025(2) Uani 1 d . .
Te10 Te 1.21367(7) 0.55679(4) 0.88949(3) 0.01451(14) Uani 1 d . .
F101 F 1.2500(7) 0.5639(4) 0.8007(3) 0.027(2) Uani 1 d . .
F102 F 1.3628(7) 0.5124(4) 0.9098(3) 0.0276(15) Uani 1 d . .
F103 F 1.1651(7) 0.5416(4) 0.9745(3) 0.033(2) Uani 1 d . .
F104 F 1.0571(6) 0.5932(4) 0.8651(3) 0.0241(14) Uani 1 d . .
F105 F 1.0857(7) 0.4528(4) 0.8353(3) 0.0296(15) Uani 1 d . .
Br8 Br 1.67077(11) 0.95643(6) 1.21079(5) 0.0166(2) Uani 1 d . .
F71 F 0.7893(6) 0.8114(4) 0.1253(3) 0.0187(13) Uani 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Br4 As1 Br3 110.32(7) . . ?
Br4 As1 Br1 108.29(7) . . ?
Br3 As1 Br1 109.88(6) . . ?
Br4 As1 Br2 108.88(7) . . ?
Br3 As1 Br2 108.92(7) . . ?
Br1 As1 Br2 110.54(6) . . ?
Br8 As2 Br5 109.24(8) 1_454 . ?
Br8 As2 Br6 110.52(7) 1_454 . ?
Br5 As2 Br6 110.19(7) . . ?
Br8 As2 Br7 110.69(7) 1_454 . ?
Br5 As2 Br7 108.63(7) . . ?
Br6 As2 Br7 107.53(6) . . ?
F1 As3 O1 88.0(3) . . ?
F1 As3 O2 90.6(3) . . ?
O1 As3 O2 91.4(3) . . ?
F1 As3 O5 175.9(2) . . ?
O1 As3 O5 88.0(3) . . ?
O2 As3 O5 88.4(3) . . ?
F1 As3 O3 92.0(3) . . ?
O1 As3 O3 179.3(3) . . ?
O2 As3 O3 89.3(3) . . ?
O5 As3 O3 91.9(3) . . ?
F1 As3 O4 92.9(3) . . ?
O1 As3 O4 90.5(3) . . ?
O2 As3 O4 176.1(3) . . ?
O5 As3 O4 88.2(3) . . ?
O3 As3 O4 88.8(3) . . ?
As3 O1 Te1 138.2(4) . . ?
F13 Te1 F11 173.8(2) . . ?
F13 Te1 F15 86.7(3) . . ?
F11 Te1 F15 87.2(3) . . ?
F13 Te1 F12 90.6(3) . . ?
F11 Te1 F12 90.2(3) . . ?
F15 Te1 F12 87.9(3) . . ?
F13 Te1 F14 90.0(3) . . ?
F11 Te1 F14 88.6(3) . . ?
F15 Te1 F14 87.1(3) . . ?
F12 Te1 F14 174.9(3) . . ?
F13 Te1 O1 89.6(3) . . ?
F11 Te1 O1 96.5(3) . . ?
F15 Te1 O1 175.8(3) . . ?
F12 Te1 O1 93.9(3) . . ?
F14 Te1 O1 91.1(3) . . ?
As3 O2 Te2 137.1(3) . . ?
F23 Te2 F21 172.7(3) . . ?
F23 Te2 F24 90.4(3) . . ?
F21 Te2 F24 90.8(3) . . ?
F23 Te2 F22 90.2(3) . . ?
F21 Te2 F22 88.0(3) . . ?
F24 Te2 F22 174.8(2) . . ?
F23 Te2 F25 86.7(3) . . ?
F21 Te2 F25 86.2(3) . . ?
F24 Te2 F25 87.5(3) . . ?
F22 Te2 F25 87.3(3) . . ?
F23 Te2 O2 91.1(3) . . ?
F21 Te2 O2 96.0(3) . . ?
F24 Te2 O2 95.5(3) . . ?
F22 Te2 O2 89.7(3) . . ?
F25 Te2 O2 176.2(2) . . ?
As3 O3 Te3 136.6(4) . . ?
F31 Te3 F35 88.7(2) . . ?
F31 Te3 F33 176.6(2) . . ?
F35 Te3 F33 87.9(2) . . ?
F31 Te3 F34 90.6(3) . . ?
F35 Te3 F34 87.7(2) . . ?
F33 Te3 F34 89.3(2) . . ?
F31 Te3 F32 90.1(3) . . ?
F35 Te3 F32 87.1(2) . . ?
F33 Te3 F32 89.6(3) . . ?
F34 Te3 F32 174.7(2) . . ?
F31 Te3 O3 94.7(2) . . ?
F35 Te3 O3 176.2(3) . . ?
F33 Te3 O3 88.7(2) . . ?
F34 Te3 O3 93.9(3) . . ?
F32 Te3 O3 91.2(3) . . ?
As3 O4 Te4 135.4(4) . . ?
F42 Te4 F43 88.8(3) . . ?
F42 Te4 F41 88.9(2) . . ?
F43 Te4 F41 175.8(2) . . ?
F42 Te4 F45 87.6(3) . . ?
F43 Te4 F45 88.4(2) . . ?
F41 Te4 F45 87.9(2) . . ?
F42 Te4 F44 175.2(2) . . ?
F43 Te4 F44 90.0(2) . . ?
F41 Te4 F44 92.0(2) . . ?
F45 Te4 F44 87.8(3) . . ?
F42 Te4 O4 90.4(3) . . ?
F43 Te4 O4 88.1(3) . . ?
F41 Te4 O4 95.5(2) . . ?
F45 Te4 O4 176.0(3) . . ?
F44 Te4 O4 94.2(3) . . ?
As3 O5 Te5 136.1(3) . . ?
F53 Te5 F52 89.5(3) . . ?
F53 Te5 F54 91.6(3) . . ?
F52 Te5 F54 175.2(3) . . ?
F53 Te5 F51 173.1(2) . . ?
F52 Te5 F51 89.3(3) . . ?
F54 Te5 F51 89.1(3) . . ?
F53 Te5 F55 86.4(2) . . ?
F52 Te5 F55 88.0(3) . . ?
F54 Te5 F55 87.4(3) . . ?
F51 Te5 F55 86.8(2) . . ?
F53 Te5 O5 95.9(3) . . ?
F52 Te5 O5 88.6(3) . . ?
F54 Te5 O5 95.9(3) . . ?
F51 Te5 O5 90.9(3) . . ?
F55 Te5 O5 175.9(3) . . ?
F2 As4 O10 176.0(3) . . ?
F2 As4 O8 91.5(3) . . ?
O10 As4 O8 86.1(3) . . ?
F2 As4 O9 93.0(3) . . ?
O10 As4 O9 90.2(3) . . ?
O8 As4 O9 89.3(3) . . ?
F2 As4 O6 91.1(3) . . ?
O10 As4 O6 91.3(3) . . ?
O8 As4 O6 177.3(4) . . ?
O9 As4 O6 90.0(3) . . ?
F2 As4 O7 87.5(3) . . ?
O10 As4 O7 89.2(3) . . ?
O8 As4 O7 89.6(3) . . ?
O9 As4 O7 178.8(3) . . ?
O6 As4 O7 91.1(3) . . ?
As4 O6 Te6 137.4(4) . . ?
F61 Te6 F65 87.6(3) . . ?
F61 Te6 F64 89.6(3) . . ?
F65 Te6 F64 87.7(3) . . ?
F61 Te6 F63 175.5(2) . . ?
F65 Te6 F63 87.9(3) . . ?
F64 Te6 F63 90.8(3) . . ?
F61 Te6 F62 90.3(3) . . ?
F65 Te6 F62 88.1(3) . . ?
F64 Te6 F62 175.9(2) . . ?
F63 Te6 F62 89.0(3) . . ?
F61 Te6 O6 92.0(3) . . ?
F65 Te6 O6 174.8(3) . . ?
F64 Te6 O6 97.5(3) . . ?
F63 Te6 O6 92.4(3) . . ?
F62 Te6 O6 86.7(3) . . ?
As4 O7 Te7 137.4(4) . . ?
F74 Te7 F75 88.0(3) . . ?
F74 Te7 F73 90.4(3) . . ?
F75 Te7 F73 87.7(3) . . ?
F74 Te7 F72 174.6(3) . . ?
F75 Te7 F72 86.8(3) . . ?
F73 Te7 F72 90.5(3) . . ?
F74 Te7 F71 88.8(3) . 1_656 ?
F75 Te7 F71 87.6(3) . 1_656 ?
F73 Te7 F71 175.3(3) . 1_656 ?
F72 Te7 F71 89.9(3) . 1_656 ?
F74 Te7 O7 97.1(3) . . ?
F75 Te7 O7 174.6(3) . . ?
F73 Te7 O7 94.0(3) . . ?
F72 Te7 O7 88.1(3) . . ?
F71 Te7 O7 90.8(3) 1_656 . ?
As4 O8 Te8 136.5(4) . . ?
F82 Te8 F85 88.7(3) . . ?
F82 Te8 F81 90.8(3) . . ?
F85 Te8 F81 88.4(3) . . ?
F82 Te8 F83 90.7(3) . . ?
F85 Te8 F83 86.9(3) . . ?
F81 Te8 F83 174.9(3) . . ?
F82 Te8 F84 175.0(3) . . ?
F85 Te8 F84 86.3(3) . . ?
F81 Te8 F84 89.5(3) . . ?
F83 Te8 F84 88.6(3) . . ?
F82 Te8 O8 97.0(3) . . ?
F85 Te8 O8 172.7(3) . . ?
F81 Te8 O8 96.0(3) . . ?
F83 Te8 O8 88.6(3) . . ?
F84 Te8 O8 87.9(3) . . ?
As4 O9 Te9 138.9(4) . . ?
F93 Te9 F94 90.3(3) . . ?
F93 Te9 F91 174.5(3) . . ?
F94 Te9 F91 88.9(3) . . ?
F93 Te9 F92 89.3(3) . . ?
F94 Te9 F92 173.0(3) . . ?
F91 Te9 F92 90.9(3) . . ?
F93 Te9 F95 86.5(3) . . ?
F94 Te9 F95 86.6(2) . . ?
F91 Te9 F95 88.1(3) . . ?
F92 Te9 F95 86.4(3) . . ?
F93 Te9 O9 89.5(3) . . ?
F94 Te9 O9 95.9(3) . . ?
F91 Te9 O9 95.9(3) . . ?
F92 Te9 O9 91.1(3) . . ?
F95 Te9 O9 175.4(3) . . ?
As4 O10 Te10 139.8(4) . . ?
F104 Te10 F101 89.9(2) . . ?
F104 Te10 F105 87.8(3) . . ?
F101 Te10 F105 87.4(3) . . ?
F104 Te10 F103 89.3(3) . . ?
F101 Te10 F103 175.4(3) . . ?
F105 Te10 F103 88.0(3) . . ?
F104 Te10 F102 175.8(3) . . ?
F101 Te10 F102 89.6(3) . . ?
F105 Te10 F102 88.0(3) . . ?
F103 Te10 F102 90.8(3) . . ?
F104 Te10 O10 96.6(3) . . ?
F101 Te10 O10 90.4(3) . . ?
F105 Te10 O10 175.1(3) . . ?
F103 Te10 O10 94.2(3) . . ?
F102 Te10 O10 87.5(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
As1 Br4 2.227(2) . ?
As1 Br3 2.233(2) . ?
As1 Br1 2.233(2) . ?
As1 Br2 2.235(2) . ?
As2 Br8 2.225(2) 1_454 ?
As2 Br5 2.233(2) . ?
As2 Br6 2.234(2) . ?
As2 Br7 2.236(2) . ?
As3 F1 1.721(6) . ?
As3 O1 1.806(5) . ?
As3 O2 1.807(6) . ?
As3 O5 1.807(7) . ?
As3 O3 1.807(5) . ?
As3 O4 1.812(6) . ?
O1 Te1 1.845(6) . ?
Te1 F13 1.812(6) . ?
Te1 F11 1.821(6) . ?
Te1 F15 1.826(6) . ?
Te1 F12 1.833(6) . ?
Te1 F14 1.834(6) . ?
O2 Te2 1.850(6) . ?
Te2 F23 1.820(6) . ?
Te2 F21 1.831(5) . ?
Te2 F24 1.832(6) . ?
Te2 F22 1.837(6) . ?
Te2 F25 1.837(5) . ?
O3 Te3 1.852(5) . ?
Te3 F31 1.821(6) . ?
Te3 F35 1.829(5) . ?
Te3 F33 1.838(5) . ?
Te3 F34 1.838(6) . ?
Te3 F32 1.840(6) . ?
O4 Te4 1.845(6) . ?
Te4 F42 1.822(5) . ?
Te4 F43 1.822(5) . ?
Te4 F41 1.824(5) . ?
Te4 F45 1.826(6) . ?
Te4 F44 1.831(5) . ?
O5 Te5 1.856(6) . ?
Te5 F53 1.823(5) . ?
Te5 F52 1.823(6) . ?
Te5 F54 1.828(6) . ?
Te5 F51 1.828(5) . ?
Te5 F55 1.840(5) . ?
As4 F2 1.734(6) . ?
As4 O10 1.784(8) . ?
As4 O8 1.794(6) . ?
As4 O9 1.803(7) . ?
As4 O6 1.805(6) . ?
As4 O7 1.824(6) . ?
O6 Te6 1.846(6) . ?
Te6 F61 1.817(6) . ?
Te6 F65 1.821(5) . ?
Te6 F64 1.827(7) . ?
Te6 F63 1.829(7) . ?
Te6 F62 1.836(7) . ?
O7 Te7 1.843(7) . ?
Te7 F74 1.827(5) . ?
Te7 F75 1.829(6) . ?
Te7 F73 1.831(6) . ?
Te7 F72 1.832(5) . ?
Te7 F71 1.836(6) 1_656 ?
O8 Te8 1.844(7) . ?
Te8 F82 1.806(6) . ?
Te8 F85 1.815(6) . ?
Te8 F81 1.821(6) . ?
Te8 F83 1.838(6) . ?
Te8 F84 1.838(6) . ?
O9 Te9 1.853(7) . ?
Te9 F93 1.814(6) . ?
Te9 F94 1.825(5) . ?
Te9 F91 1.826(6) . ?
Te9 F92 1.827(5) . ?
Te9 F95 1.839(6) . ?
O10 Te10 1.856(8) . ?
Te10 F104 1.816(6) . ?
Te10 F101 1.817(5) . ?
Te10 F105 1.824(7) . ?
Te10 F103 1.834(5) . ?
Te10 F102 1.836(6) . ?
Br8 As2 2.225(2) 1_656 ?
F71 Te7 1.836(6) 1_454 ?
