#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:09:40 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179315 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/12/4321266.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4321266
loop_
_publ_author_name
'H. V. Rasika Dias'
'Ziyun Wang'
_publ_section_title
;
 Adduct Formation or Metathesis Reactions of Silver Complexes Containing
 the Fluorinated Ligands [HB(3,5-(CF3)2Pz)3]- and [CF3SO3]-: Formation of
 Silver Adducts Containing Unsupported Silver-Germanium Bonds
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3890
_journal_page_last               3893
_journal_paper_doi               10.1021/ic000414t
_journal_volume                  39
_journal_year                    2000
_chemical_formula_sum            'C25 H15 Ag B F21 Ge N8 O3 S'
_chemical_formula_weight         1097.78
_chemical_name_common            '[HB(CF3)2Tp]AgGe(OTf)[(Me)2ATI]'
_chemical_name_systematic
; 

 ? 

;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.248(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.279(3)
_cell_length_b                   9.142(2)
_cell_length_c                   23.008(4)
_cell_measurement_reflns_used    37
_cell_measurement_temperature    183(2)
_cell_measurement_theta_max      12.50
_cell_measurement_theta_min      4.98
_cell_volume                     3651.4(12)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      183(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0749
_diffrn_reflns_av_sigmaI/netI    0.0561
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -1
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            5412
_diffrn_reflns_theta_full        21.50
_diffrn_reflns_theta_max         21.50
_diffrn_reflns_theta_min         1.86
_diffrn_standards_decay_%        34.41
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.568
_exptl_absorpt_correction_T_max  0.9833
_exptl_absorpt_correction_T_min  0.7334
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.997
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plates
_exptl_crystal_F_000             2136
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.716
_refine_diff_density_min         -1.651
_refine_diff_density_rms         0.130
_refine_ls_extinction_coef       0.0000(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     582
_refine_ls_number_reflns         4191
_refine_ls_number_restraints     60
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0682
_refine_ls_R_factor_gt           0.0527
_refine_ls_shift/su_max          0.385
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1024P)²+1.1995P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1311
_refine_ls_wR_factor_ref         0.1434
_reflns_number_gt                3407
_reflns_number_total             4191
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic000414t_2.cif
_cod_data_source_block           rd184
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_original_cell_volume        3651.5(13)
_cod_database_code               4321266
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.24993(3) 0.11701(6) 0.30018(2) 0.0284(3) Uani 1 1 d . . .
Ge Ge 0.32471(4) 0.17748(9) 0.40379(3) 0.0275(3) Uani 1 1 d . . .
N11 N 0.1004(3) -0.0612(6) 0.2158(3) 0.0242(14) Uani 1 1 d . . .
N12 N 0.1437(3) -0.0504(7) 0.2756(3) 0.0287(15) Uani 1 1 d . . .
N21 N 0.1287(3) 0.1684(6) 0.1638(3) 0.0247(14) Uani 1 1 d . . .
N22 N 0.1668(3) 0.2446(7) 0.2152(3) 0.0262(14) Uani 1 1 d . . .
N31 N 0.2107(3) -0.0617(6) 0.1711(3) 0.0237(14) Uani 1 1 d . . .
N32 N 0.2715(3) -0.0239(7) 0.2208(3) 0.0254(14) Uani 1 1 d . . .
N1 N 0.2968(3) 0.2856(6) 0.4623(3) 0.0296(15) Uani 1 1 d . . .
N9 N 0.3637(3) 0.0456(7) 0.4690(3) 0.0275(15) Uani 1 1 d . . .
C13 C 0.1057(4) -0.1185(9) 0.3076(4) 0.0335(19) Uani 1 1 d . A .
C14 C 0.0363(5) -0.1752(9) 0.2706(4) 0.040(2) Uani 1 1 d . . .
H14 H -0.0003 -0.2272 0.2826 0.048 Uiso 1 1 calc R . .
C15 C 0.0341(4) -0.1373(9) 0.2131(4) 0.034(2) Uani 1 1 d . . .
C16 C 0.1395(5) -0.1319(9) 0.3746(4) 0.047(2) Uani 1 1 d D . .
C17 C -0.0274(5) -0.1736(11) 0.1544(4) 0.047(2) Uani 1 1 d . . .
C23 C 0.1555(4) 0.3848(8) 0.2007(4) 0.0319(19) Uani 1 1 d . B .
C24 C 0.1115(4) 0.4038(8) 0.1401(4) 0.035(2) Uani 1 1 d . . .
H24 H 0.0961 0.4914 0.1193 0.042 Uiso 1 1 calc R . .
C25 C 0.0958(4) 0.2635(9) 0.1177(3) 0.0314(19) Uani 1 1 d . . .
C26 C 0.1873(4) 0.5018(9) 0.2461(4) 0.045(2) Uani 1 1 d D . .
C27 C 0.0550(5) 0.2235(10) 0.0533(4) 0.042(2) Uani 1 1 d . . .
C33 C 0.3324(4) -0.0885(8) 0.2134(3) 0.0287(18) Uani 1 1 d . . .
C34 C 0.3145(4) -0.1684(9) 0.1590(4) 0.036(2) Uani 1 1 d . . .
H34 H 0.3475 -0.2225 0.1437 0.044 Uiso 1 1 calc R . .
C35 C 0.2360(4) -0.1477(8) 0.1332(4) 0.0320(19) Uani 1 1 d . . .
C36 C 0.4100(4) -0.0712(10) 0.2582(4) 0.039(2) Uani 1 1 d . . .
C37 C 0.1882(4) -0.2086(9) 0.0746(4) 0.038(2) Uani 1 1 d . . .
F16A F 0.0951(5) -0.1954(14) 0.4007(3) 0.126(6) Uani 0.879(15) 1 d PD A 1
F16B F 0.2061(5) -0.2046(11) 0.3905(3) 0.099(4) Uani 0.879(15) 1 d PD A 1
F16C F 0.1614(5) -0.0070(8) 0.4034(3) 0.084(3) Uani 0.879(15) 1 d PD A 1
F16D F 0.133(2) -0.265(2) 0.3940(18) 0.046(15) Uiso 0.121(15) 1 d PD A 2
F16E F 0.2112(11) -0.095(4) 0.3992(14) 0.033(13) Uiso 0.121(15) 1 d PD A 2
F16F F 0.1006(19) -0.050(4) 0.4019(16) 0.049(15) Uiso 0.121(15) 1 d PD A 2
F17A F -0.0562(3) -0.0554(7) 0.1222(2) 0.0629(15) Uani 1 1 d . . .
F17B F -0.0854(3) -0.2411(7) 0.1677(2) 0.0649(15) Uani 1 1 d . . .
F17C F -0.0033(3) -0.2624(7) 0.1188(2) 0.0651(16) Uani 1 1 d . . .
F26A F 0.1489(5) 0.5130(8) 0.2873(4) 0.091(4) Uani 0.844(13) 1 d PD B 1
F26B F 0.2579(4) 0.4793(9) 0.2797(4) 0.109(5) Uani 0.844(13) 1 d PD B 1
F26C F 0.1809(5) 0.6322(6) 0.2215(3) 0.064(3) Uani 0.844(13) 1 d PD B 1
F26D F 0.2144(17) 0.461(3) 0.3023(8) 0.033(10) Uiso 0.156(13) 1 d PD B 2
F26E F 0.2466(14) 0.563(3) 0.2327(13) 0.048(11) Uiso 0.156(13) 1 d PD B 2
F26F F 0.1393(18) 0.609(4) 0.2439(18) 0.093(17) Uiso 0.156(13) 1 d PD B 2
F27A F 0.1018(3) 0.1625(7) 0.0262(2) 0.0655(16) Uani 1 1 d . . .
F27B F -0.0030(3) 0.1329(6) 0.0464(2) 0.0532(13) Uani 1 1 d . . .
F27C F 0.0269(4) 0.3436(6) 0.0217(2) 0.0722(17) Uani 1 1 d . . .
F36A F 0.4450(3) 0.0517(7) 0.2477(3) 0.0802(19) Uani 1 1 d . . .
F36B F 0.4099(3) -0.0615(8) 0.3148(2) 0.0697(17) Uani 1 1 d . . .
F36C F 0.4569(3) -0.1783(6) 0.2550(2) 0.0639(16) Uani 1 1 d . . .
F37A F 0.2284(3) -0.3040(8) 0.0528(3) 0.084(2) Uani 1 1 d . . .
F37B F 0.1260(3) -0.2806(5) 0.0773(2) 0.0503(13) Uani 1 1 d . . .
F37C F 0.1622(3) -0.1075(6) 0.0314(2) 0.0575(14) Uani 1 1 d . . .
B B 0.1284(5) -0.0020(9) 0.1633(4) 0.026(2) Uani 1 1 d . . .
H H 0.095(5) -0.038(9) 0.121(4) 0.050 Uiso 1 1 d . . .
C2 C 0.3177(4) 0.2282(9) 0.5187(3) 0.0302(19) Uani 1 1 d . . .
C3 C 0.2986(5) 0.2923(9) 0.5674(4) 0.039(2) Uani 1 1 d . . .
H3 H 0.2706 0.3785 0.5569 0.047 Uiso 1 1 calc R . .
C4 C 0.3130(5) 0.2528(11) 0.6273(4) 0.048(2) Uani 1 1 d . . .
H4 H 0.2909 0.3123 0.6500 0.058 Uiso 1 1 calc R . .
C5 C 0.3555(5) 0.1380(11) 0.6583(4) 0.050(2) Uani 1 1 d . . .
H5 H 0.3607 0.1316 0.6997 0.060 Uiso 1 1 calc R . .
C6 C 0.3916(4) 0.0302(10) 0.6350(3) 0.039(2) Uani 1 1 d . . .
H6 H 0.4200 -0.0372 0.6634 0.047 Uiso 1 1 calc R . .
C7 C 0.3912(4) 0.0090(9) 0.5765(3) 0.035(2) Uani 1 1 d . . .
H7 H 0.4172 -0.0749 0.5712 0.042 Uiso 1 1 calc R . .
C8 C 0.3590(4) 0.0899(8) 0.5220(3) 0.0282(18) Uani 1 1 d . . .
C10 C 0.2560(5) 0.4257(10) 0.4484(4) 0.051(2) Uani 1 1 d . . .
H10A H 0.2135 0.4257 0.4646 0.077 Uiso 1 1 calc R . .
H10B H 0.2371 0.4394 0.4049 0.077 Uiso 1 1 calc R . .
H10C H 0.2906 0.5039 0.4667 0.077 Uiso 1 1 calc R . .
C11 C 0.3970(5) -0.0969(9) 0.4607(4) 0.042(2) Uani 1 1 d . . .
H11A H 0.3711 -0.1736 0.4750 0.064 Uiso 1 1 calc R . .
H11B H 0.4508 -0.0982 0.4836 0.064 Uiso 1 1 calc R . .
H11C H 0.3907 -0.1116 0.4181 0.064 Uiso 1 1 calc R . .
C12 C 0.4625(8) 0.5413(12) 0.3946(6) 0.075(3) Uani 1 1 d . . .
S S 0.45857(12) 0.3483(2) 0.37362(10) 0.0380(6) Uani 1 1 d . . .
O1 O 0.4273(3) 0.2778(6) 0.4179(2) 0.0388(14) Uani 1 1 d . . .
O2 O 0.5364(4) 0.3105(8) 0.3846(4) 0.078(2) Uani 1 1 d . . .
O3 O 0.4089(4) 0.3406(8) 0.3136(3) 0.068(2) Uani 1 1 d . . .
F12A F 0.3912(5) 0.5809(8) 0.3930(5) 0.140(4) Uani 1 1 d . . .
F12B F 0.5079(6) 0.5658(11) 0.4482(4) 0.152(4) Uani 1 1 d . . .
F12C F 0.4858(6) 0.6193(7) 0.3572(4) 0.126(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N32 Ag N22 81.4(2) . . ?
N32 Ag N12 77.82(19) . . ?
N22 Ag N12 81.8(2) . . ?
N32 Ag Ge 135.03(14) . . ?
N22 Ag Ge 136.07(15) . . ?
N12 Ag Ge 123.12(15) . . ?
N1 Ge N9 83.4(3) . . ?
N1 Ge O1 95.3(2) . . ?
N9 Ge O1 93.6(2) . . ?
N1 Ge Ag 129.54(18) . . ?
N9 Ge Ag 126.68(19) . . ?
O1 Ge Ag 118.22(14) . . ?
N12 N11 C15 107.9(6) . . ?
N12 N11 B 122.2(5) . . ?
C15 N11 B 129.8(6) . . ?
C13 N12 N11 106.9(6) . . ?
C13 N12 Ag 134.4(5) . . ?
N11 N12 Ag 117.2(4) . . ?
C25 N21 N22 109.4(6) . . ?
C25 N21 B 129.4(6) . . ?
N22 N21 B 121.2(6) . . ?
C23 N22 N21 106.2(6) . . ?
C23 N22 Ag 133.9(5) . . ?
N21 N22 Ag 119.0(4) . . ?
C35 N31 N32 109.4(6) . . ?
C35 N31 B 129.8(6) . . ?
N32 N31 B 120.8(6) . . ?
C33 N32 N31 106.1(5) . . ?
C33 N32 Ag 134.1(5) . . ?
N31 N32 Ag 119.6(4) . . ?
C2 N1 C10 121.7(6) . . ?
C2 N1 Ge 115.6(5) . . ?
C10 N1 Ge 122.8(5) . . ?
C8 N9 C11 122.9(6) . . ?
C8 N9 Ge 115.1(5) . . ?
C11 N9 Ge 122.0(5) . . ?
N12 C13 C14 112.0(7) . . ?
N12 C13 C16 120.2(7) . . ?
C14 C13 C16 127.8(7) . . ?
C15 C14 C13 104.2(7) . . ?
C14 C15 N11 109.1(7) . . ?
C14 C15 C17 127.4(7) . . ?
N11 C15 C17 123.5(7) . . ?
F16A C16 F16E 127.7(16) . . ?
F16A C16 F16D 44.8(15) . . ?
F16E C16 F16D 105.9(15) . . ?
F16A C16 F16F 61.4(16) . . ?
F16E C16 F16F 105.6(15) . . ?
F16D C16 F16F 104.3(14) . . ?
F16A C16 F16C 107.0(8) . . ?
F16E C16 F16C 56.8(16) . . ?
F16D C16 F16C 132.6(19) . . ?
F16F C16 F16C 52.7(16) . . ?
F16A C16 F16B 107.6(8) . . ?
F16E C16 F16B 45.4(16) . . ?
F16D C16 F16B 67.3(16) . . ?
F16F C16 F16B 137.3(18) . . ?
F16C C16 F16B 100.7(7) . . ?
F16A C16 C13 113.9(7) . . ?
F16E C16 C13 117.9(16) . . ?
F16D C16 C13 112.3(19) . . ?
F16F C16 C13 109.8(18) . . ?
F16C C16 C13 114.5(7) . . ?
F16B C16 C13 112.0(7) . . ?
F17A C17 F17C 107.8(8) . . ?
F17A C17 F17B 107.3(7) . . ?
F17C C17 F17B 107.3(7) . . ?
F17A C17 C15 112.3(8) . . ?
F17C C17 C15 113.1(7) . . ?
F17B C17 C15 108.7(7) . . ?
N22 C23 C24 111.8(7) . . ?
N22 C23 C26 121.6(7) . . ?
C24 C23 C26 126.5(7) . . ?
C25 C24 C23 104.3(7) . . ?
N21 C25 C24 108.3(6) . . ?
N21 C25 C27 125.8(7) . . ?
C24 C25 C27 125.8(7) . . ?
F26D C26 F26B 50.0(12) . . ?
F26D C26 F26C 130.5(15) . . ?
F26B C26 F26C 109.9(8) . . ?
F26D C26 F26F 107.2(15) . . ?
F26B C26 F26F 132(2) . . ?
F26C C26 F26F 47.9(15) . . ?
F26D C26 F26E 105.5(13) . . ?
F26B C26 F26E 58.4(13) . . ?
F26C C26 F26E 59.5(13) . . ?
F26F C26 F26E 105.1(15) . . ?
F26D C26 F26A 55.6(13) . . ?
F26B C26 F26A 103.5(8) . . ?
F26C C26 F26A 103.7(7) . . ?
F26F C26 F26A 58.6(15) . . ?
F26E C26 F26A 140.2(15) . . ?
F26D C26 C23 116.4(14) . . ?
F26B C26 C23 113.8(7) . . ?
F26C C26 C23 113.0(7) . . ?
F26F C26 C23 114(2) . . ?
F26E C26 C23 107.8(15) . . ?
F26A C26 C23 112.0(7) . . ?
F27B C27 F27A 107.0(7) . . ?
F27B C27 F27C 107.2(7) . . ?
F27A C27 F27C 106.6(7) . . ?
F27B C27 C25 114.3(7) . . ?
F27A C27 C25 112.2(7) . . ?
F27C C27 C25 109.3(7) . . ?
N32 C33 C34 112.4(6) . . ?
N32 C33 C36 121.8(7) . . ?
C34 C33 C36 125.8(7) . . ?
C35 C34 C33 103.5(7) . . ?
N31 C35 C34 108.7(7) . . ?
N31 C35 C37 125.8(7) . . ?
C34 C35 C37 125.5(7) . . ?
F36B C36 F36C 108.1(7) . . ?
F36B C36 F36A 105.7(7) . . ?
F36C C36 F36A 104.8(6) . . ?
F36B C36 C33 113.7(6) . . ?
F36C C36 C33 112.3(7) . . ?
F36A C36 C33 111.6(7) . . ?
F37B C37 F37C 105.5(6) . . ?
F37B C37 F37A 105.9(7) . . ?
F37C C37 F37A 106.4(7) . . ?
F37B C37 C35 114.6(7) . . ?
F37C C37 C35 113.1(7) . . ?
F37A C37 C35 110.6(6) . . ?
N11 B N31 109.3(6) . . ?
N11 B N21 110.2(6) . . ?
N31 B N21 110.4(6) . . ?
N1 C2 C3 122.9(7) . . ?
N1 C2 C8 112.1(6) . . ?
C3 C2 C8 125.0(7) . . ?
C4 C3 C2 132.6(8) . . ?
C5 C4 C3 128.9(8) . . ?
C4 C5 C6 127.3(8) . . ?
C7 C6 C5 129.0(8) . . ?
C6 C7 C8 132.5(8) . . ?
N9 C8 C7 122.1(7) . . ?
N9 C8 C2 113.7(6) . . ?
C7 C8 C2 124.2(7) . . ?
F12B C12 F12C 107.4(11) . . ?
F12B C12 F12A 108.2(10) . . ?
F12C C12 F12A 110.8(11) . . ?
F12B C12 S 112.7(10) . . ?
F12C C12 S 110.6(8) . . ?
F12A C12 S 107.2(8) . . ?
O3 S O2 118.2(5) . . ?
O3 S O1 113.0(4) . . ?
O2 S O1 111.1(4) . . ?
O3 S C12 105.7(6) . . ?
O2 S C12 103.7(5) . . ?
O1 S C12 103.5(4) . . ?
S O1 Ge 129.3(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag N32 2.367(6) . ?
Ag N22 2.373(6) . ?
Ag N12 2.397(6) . ?
Ag Ge 2.4116(10) . ?
Ge N1 1.865(6) . ?
Ge N9 1.883(6) . ?
Ge O1 2.020(5) . ?
N11 N12 1.358(8) . ?
N11 C15 1.380(9) . ?
N11 B 1.550(10) . ?
N12 C13 1.316(9) . ?
N21 C25 1.358(9) . ?
N21 N22 1.361(8) . ?
N21 B 1.558(11) . ?
N22 C23 1.325(10) . ?
N31 C35 1.359(9) . ?
N31 N32 1.367(8) . ?
N31 B 1.556(10) . ?
N32 C33 1.317(9) . ?
N1 C2 1.339(9) . ?
N1 C10 1.467(10) . ?
N9 C8 1.311(9) . ?
N9 C11 1.476(10) . ?
C13 C14 1.388(11) . ?
C13 C16 1.476(12) . ?
C14 C15 1.356(11) . ?
C15 C17 1.500(12) . ?
C16 F16A 1.289(9) . ?
C16 F16E 1.297(15) . ?
C16 F16D 1.309(15) . ?
C16 F16F 1.317(15) . ?
C16 F16C 1.318(9) . ?
C16 F16B 1.334(9) . ?
C17 F17A 1.322(11) . ?
C17 F17C 1.322(10) . ?
C17 F17B 1.343(9) . ?
C23 C24 1.384(11) . ?
C23 C26 1.481(12) . ?
C24 C25 1.379(11) . ?
C25 C27 1.481(11) . ?
C26 F26D 1.286(14) . ?
C26 F26B 1.296(9) . ?
C26 F26C 1.309(8) . ?
C26 F26F 1.309(15) . ?
C26 F26E 1.337(14) . ?
C26 F26A 1.350(9) . ?
C27 F27B 1.315(10) . ?
C27 F27A 1.327(10) . ?
C27 F27C 1.329(10) . ?
C33 C34 1.398(11) . ?
C33 C36 1.478(11) . ?
C34 C35 1.384(11) . ?
C35 C37 1.467(11) . ?
C36 F36B 1.306(9) . ?
C36 F36C 1.318(10) . ?
C36 F36A 1.352(10) . ?
C37 F37B 1.331(9) . ?
C37 F37C 1.332(9) . ?
C37 F37A 1.336(9) . ?
C2 C3 1.403(11) . ?
C2 C8 1.461(11) . ?
C3 C4 1.367(12) . ?
C4 C5 1.366(13) . ?
C5 C6 1.384(12) . ?
C6 C7 1.358(11) . ?
C7 C8 1.416(11) . ?
C12 F12B 1.273(15) . ?
C12 F12C 1.289(12) . ?
C12 F12A 1.343(14) . ?
C12 S 1.825(12) . ?
S O3 1.398(7) . ?
S O2 1.407(7) . ?
S O1 1.464(6) . ?
