#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:09:40 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179315 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/12/4321276.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4321276
loop_
_publ_author_name
'Christophe Lescop'
'Dominique Luneau'
'Guillaume Bussière'
'Myriam Triest'
'Christian Reber'
_publ_contact_author
;
      Christian Reber
      Department of Chemistry
      University of Bern
      3012 Bern
      Switzerland
;
_publ_contact_author_email       reber@chimie.umontreal.ca
_publ_contact_author_fax         '01141 31 631 43 22'
_publ_contact_author_phone       '01141 31 631 43 17'
_publ_section_title
;
 Ligand-Centered Near-Infrared Luminescence from Lanthanide Complexes with
 Chelating Nitronyl Nitroxide Free Radicals
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3740
_journal_page_last               3741
_journal_paper_doi               10.1021/ic0004941
_journal_volume                  39
_journal_year                    2000
_chemical_formula_sum            'C28 H34 Eu N11 O13'
_chemical_formula_weight         884.62
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           33
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2c -2n'
_symmetry_space_group_name_H-M   'P n a 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.2109(10)
_cell_length_b                   13.1447(7)
_cell_length_c                   14.4200(7)
_cell_measurement_temperature    298(2)
_cell_volume                     3641.4(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.818
_diffrn_measured_fraction_theta_max 0.818
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0519
_diffrn_reflns_av_sigmaI/netI    0.0722
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            13092
_diffrn_reflns_theta_full        29.62
_diffrn_reflns_theta_max         29.62
_diffrn_reflns_theta_min         2.12
_exptl_absorpt_coefficient_mu    1.799
_exptl_absorpt_correction_T_max  0.9154
_exptl_absorpt_correction_T_min  0.8406
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.614
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1784
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.743
_refine_diff_density_min         -1.126
_refine_diff_density_rms         0.130
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.271(18)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.696
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     478
_refine_ls_number_reflns         4769
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.696
_refine_ls_R_factor_all          0.0632
_refine_ls_R_factor_gt           0.0347
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0867
_refine_ls_wR_factor_ref         0.1048
_reflns_number_gt                3334
_reflns_number_total             4769
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0004941_3.cif
_cod_data_source_block           cl311
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to the built-in table from CIF Core
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1646 2011-03-28 12:23:43Z adriana 
;
_cod_database_code               4321276
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu 0.326371(14) 0.79548(3) 0.71168(4) 0.02659(10) Uani 1 1 d . . .
O1A O 0.3655(3) 0.8331(5) 0.8636(3) 0.0352(13) Uani 1 1 d . . .
O2A O 0.3426(4) 0.5813(7) 1.0829(5) 0.079(3) Uani 1 1 d . . .
N1A N 0.3775(4) 0.7754(6) 0.9345(4) 0.0359(17) Uani 1 1 d . . .
N2A N 0.3650(5) 0.6582(7) 1.0416(5) 0.051(2) Uani 1 1 d . . .
N3A N 0.2618(4) 0.6771(6) 0.8266(4) 0.0333(17) Uani 1 1 d . . .
N4A N 0.2340(4) 0.5942(7) 0.9563(5) 0.052(2) Uani 1 1 d . . .
H4AA H 0.2365 0.5741 1.0130 0.062 Uiso 1 1 calc R . .
C1A C 0.3402(4) 0.6967(7) 0.9605(5) 0.037(2) Uani 1 1 d . . .
C2A C 0.4405(5) 0.7934(8) 0.9949(6) 0.046(2) Uani 1 1 d . . .
C3A C 0.4200(6) 0.7289(8) 1.0814(7) 0.056(3) Uani 1 1 d . . .
C4A C 0.5015(5) 0.7507(11) 0.9378(8) 0.070(3) Uani 1 1 d . . .
H4AB H 0.5104 0.7946 0.8860 0.106 Uiso 1 1 calc R . .
H4AC H 0.4898 0.6839 0.9158 0.106 Uiso 1 1 calc R . .
H4AD H 0.5423 0.7469 0.9761 0.106 Uiso 1 1 calc R . .
C5A C 0.4498(6) 0.9047(9) 1.0129(7) 0.060(3) Uani 1 1 d . . .
H5AA H 0.4637 0.9381 0.9567 0.090 Uiso 1 1 calc R . .
H5AB H 0.4849 0.9143 1.0594 0.090 Uiso 1 1 calc R . .
H5AC H 0.4066 0.9331 1.0342 0.090 Uiso 1 1 calc R . .
C6A C 0.4784(8) 0.6655(12) 1.1207(11) 0.105(6) Uani 1 1 d . . .
H6AA H 0.4621 0.6292 1.1742 0.158 Uiso 1 1 calc R . .
H6AB H 0.5163 0.7090 1.1381 0.158 Uiso 1 1 calc R . .
H6AC H 0.4940 0.6178 1.0747 0.158 Uiso 1 1 calc R . .
C7A C 0.3855(11) 0.7864(12) 1.1574(10) 0.114(7) Uani 1 1 d . . .
H7AA H 0.3740 0.7406 1.2070 0.171 Uiso 1 1 calc R . .
H7AB H 0.3437 0.8175 1.1344 0.171 Uiso 1 1 calc R . .
H7AC H 0.4164 0.8381 1.1800 0.171 Uiso 1 1 calc R . .
C8A C 0.2799(4) 0.6551(8) 0.9136(5) 0.036(2) Uani 1 1 d . . .
C9A C 0.2017(4) 0.6222(7) 0.8119(5) 0.0355(19) Uani 1 1 d . . .
C10A C 0.1597(4) 0.6107(8) 0.7335(6) 0.046(2) Uani 1 1 d . . .
H10A H 0.1714 0.6416 0.6776 0.055 Uiso 1 1 calc R . .
C11A C 0.1011(4) 0.5529(9) 0.7412(7) 0.051(3) Uani 1 1 d . . .
H11A H 0.0720 0.5467 0.6900 0.061 Uiso 1 1 calc R . .
C12A C 0.0831(5) 0.5033(10) 0.8222(8) 0.061(3) Uani 1 1 d . . .
H12A H 0.0428 0.4642 0.8234 0.073 Uiso 1 1 calc R . .
C13A C 0.1223(5) 0.5098(10) 0.8994(7) 0.060(3) Uani 1 1 d . . .
H13A H 0.1099 0.4763 0.9538 0.072 Uiso 1 1 calc R . .
C14A C 0.1821(4) 0.5689(9) 0.8943(6) 0.043(2) Uani 1 1 d . . .
O1B O 0.2575(3) 0.7438(7) 0.5799(4) 0.0399(14) Uani 1 1 d . . .
O2B O 0.0489(3) 0.8986(7) 0.5170(5) 0.069(2) Uani 1 1 d . . .
N1B N 0.2044(3) 0.7771(5) 0.5358(4) 0.0298(16) Uani 1 1 d . . .
N2B N 0.1041(3) 0.8478(7) 0.5052(5) 0.044(2) Uani 1 1 d . . .
N3B N 0.1994(3) 0.8605(5) 0.7299(3) 0.0245(15) Uani 1 1 d . . .
N4B N 0.0905(3) 0.9115(5) 0.6993(5) 0.0325(16) Uani 1 1 d . . .
H4BA H 0.0525 0.9218 0.6690 0.039 Uiso 1 1 calc R . .
C1B C 0.1520(4) 0.8325(8) 0.5729(5) 0.0341(19) Uani 1 1 d . . .
C2B C 0.1873(4) 0.7375(8) 0.4409(5) 0.037(2) Uani 1 1 d . . .
C3B C 0.1282(5) 0.8112(8) 0.4125(5) 0.045(2) Uani 1 1 d . . .
C4B C 0.1644(5) 0.6272(9) 0.4549(6) 0.047(2) Uani 1 1 d . . .
H4BB H 0.1235 0.6256 0.4932 0.071 Uiso 1 1 calc R . .
H4BC H 0.2010 0.5898 0.4846 0.071 Uiso 1 1 calc R . .
H4BD H 0.1542 0.5971 0.3959 0.071 Uiso 1 1 calc R . .
C5B C 0.2532(5) 0.7401(10) 0.3814(6) 0.055(3) Uani 1 1 d . . .
H5BA H 0.2676 0.8093 0.3725 0.083 Uiso 1 1 calc R . .
H5BB H 0.2439 0.7095 0.3223 0.083 Uiso 1 1 calc R . .
H5BC H 0.2896 0.7030 0.4120 0.083 Uiso 1 1 calc R . .
C6B C 0.1527(7) 0.9049(10) 0.3622(8) 0.077(4) Uani 1 1 d . . .
H6BA H 0.1902 0.9355 0.3960 0.115 Uiso 1 1 calc R . .
H6BB H 0.1149 0.9524 0.3571 0.115 Uiso 1 1 calc R . .
H6BC H 0.1685 0.8865 0.3013 0.115 Uiso 1 1 calc R . .
C7B C 0.0672(5) 0.7620(10) 0.3608(8) 0.064(3) Uani 1 1 d . . .
H7BA H 0.0530 0.7015 0.3929 0.096 Uiso 1 1 calc R . .
H7BB H 0.0815 0.7448 0.2990 0.096 Uiso 1 1 calc R . .
H7BC H 0.0290 0.8090 0.3582 0.096 Uiso 1 1 calc R . .
C8B C 0.1492(4) 0.8663(6) 0.6669(5) 0.0284(17) Uani 1 1 d . . .
C9B C 0.1720(3) 0.9040(7) 0.8078(5) 0.0308(18) Uani 1 1 d . . .
C10B C 0.2030(5) 0.9219(8) 0.8957(5) 0.043(2) Uani 1 1 d . . .
H10B H 0.2480 0.9005 0.9091 0.052 Uiso 1 1 calc R . .
C11B C 0.1630(4) 0.9727(9) 0.9600(6) 0.049(3) Uani 1 1 d . . .
H11B H 0.1814 0.9848 1.0186 0.059 Uiso 1 1 calc R . .
C12B C 0.0956(5) 1.0066(9) 0.9404(7) 0.051(3) Uani 1 1 d . . .
H12B H 0.0710 1.0411 0.9862 0.062 Uiso 1 1 calc R . .
C13B C 0.0648(4) 0.9910(7) 0.8570(6) 0.042(2) Uani 1 1 d . . .
H13B H 0.0201 1.0145 0.8444 0.051 Uiso 1 1 calc R . .
C14B C 0.1037(4) 0.9379(7) 0.7908(5) 0.0301(18) Uani 1 1 d . . .
N5 N 0.3988(3) 0.5958(6) 0.6997(5) 0.0359(16) Uani 1 1 d . . .
O3 O 0.3410(3) 0.6074(5) 0.6610(4) 0.0387(15) Uani 1 1 d . . .
O4 O 0.4192(3) 0.6692(5) 0.7524(4) 0.0415(15) Uani 1 1 d . . .
O5 O 0.4354(3) 0.5213(6) 0.6874(4) 0.0535(19) Uani 1 1 d . . .
N6 N 0.3178(4) 1.0188(8) 0.6768(6) 0.042(2) Uani 1 1 d . . .
O6 O 0.3090(3) 0.9537(6) 0.6093(4) 0.0470(17) Uani 1 1 d . . .
O7 O 0.3260(3) 0.9802(6) 0.7555(5) 0.0403(18) Uani 1 1 d . . .
O8 O 0.3166(5) 1.1095(8) 0.6613(6) 0.092(3) Uani 1 1 d . . .
N7 N 0.4517(4) 0.8378(8) 0.6015(6) 0.054(2) Uani 1 1 d . . .
O9 O 0.4060(4) 0.7807(6) 0.5718(5) 0.0529(19) Uani 1 1 d . . .
O10 O 0.4416(3) 0.8778(6) 0.6811(4) 0.054(2) Uani 1 1 d . . .
O11 O 0.5034(4) 0.8588(9) 0.5566(6) 0.094(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1A Eu O1B 164.0(2) . . ?
O1A Eu O10 78.0(2) . . ?
O1B Eu O10 117.9(2) . . ?
O1A Eu O4 72.29(19) . . ?
O1B Eu O4 112.8(2) . . ?
O10 Eu O4 72.4(2) . . ?
O1A Eu O7 64.3(2) . . ?
O1B Eu O7 118.0(2) . . ?
O10 Eu O7 68.2(2) . . ?
O4 Eu O7 125.73(19) . . ?
O1A Eu O9 124.0(2) . . ?
O1B Eu O9 71.5(2) . . ?
O10 Eu O9 50.2(2) . . ?
O4 Eu O9 72.9(2) . . ?
O7 Eu O9 106.0(2) . . ?
O1A Eu O6 113.8(2) . . ?
O1B Eu O6 72.8(2) . . ?
O10 Eu O6 70.4(2) . . ?
O4 Eu O6 139.7(2) . . ?
O7 Eu O6 50.3(2) . . ?
O9 Eu O6 71.6(2) . . ?
O1A Eu N3A 71.7(2) . . ?
O1B Eu N3A 94.1(2) . . ?
O10 Eu N3A 142.7(2) . . ?
O4 Eu N3A 78.0(2) . . ?
O7 Eu N3A 114.8(2) . . ?
O9 Eu N3A 138.7(3) . . ?
O6 Eu N3A 142.3(2) . . ?
O1A Eu O3 115.2(2) . . ?
O1B Eu O3 64.5(2) . . ?
O10 Eu O3 105.5(2) . . ?
O4 Eu O3 50.02(18) . . ?
O7 Eu O3 173.66(18) . . ?
O9 Eu O3 68.8(2) . . ?
O6 Eu O3 128.56(19) . . ?
N3A Eu O3 70.1(2) . . ?
O1A Eu N3B 97.82(18) . . ?
O1B Eu N3B 69.97(18) . . ?
O10 Eu N3B 134.9(2) . . ?
O4 Eu N3B 149.6(2) . . ?
O7 Eu N3B 69.7(2) . . ?
O9 Eu N3B 132.1(2) . . ?
O6 Eu N3B 70.73(19) . . ?
N3A Eu N3B 71.6(2) . . ?
O3 Eu N3B 116.35(19) . . ?
O1A Eu N7 101.5(2) . . ?
O1B Eu N7 94.4(2) . . ?
O10 Eu N7 25.6(2) . . ?
O4 Eu N7 70.7(3) . . ?
O7 Eu N7 87.4(2) . . ?
O9 Eu N7 24.7(2) . . ?
O6 Eu N7 69.1(2) . . ?
N3A Eu N7 148.5(3) . . ?
O3 Eu N7 86.5(2) . . ?
N3B Eu N7 139.6(2) . . ?
O1A Eu N5 95.1(2) . . ?
O1B Eu N5 87.8(2) . . ?
O10 Eu N5 87.6(2) . . ?
O4 Eu N5 25.40(18) . . ?
O7 Eu N5 150.41(19) . . ?
O9 Eu N5 66.7(2) . . ?
O6 Eu N5 137.8(2) . . ?
N3A Eu N5 74.4(2) . . ?
O3 Eu N5 24.79(17) . . ?
N3B Eu N5 137.3(2) . . ?
N7 Eu N5 75.7(2) . . ?
N1A O1A Eu 131.7(5) . . ?
O1A N1A C1A 126.2(7) . . ?
O1A N1A C2A 120.4(8) . . ?
C1A N1A C2A 113.3(7) . . ?
O2A N2A C1A 126.1(9) . . ?
O2A N2A C3A 123.6(7) . . ?
C1A N2A C3A 110.0(8) . . ?
C8A N3A C9A 104.5(7) . . ?
C8A N3A Eu 127.4(6) . . ?
C9A N3A Eu 128.1(5) . . ?
C8A N4A C14A 108.7(7) . . ?
N1A C1A N2A 110.3(8) . . ?
N1A C1A C8A 126.9(7) . . ?
N2A C1A C8A 122.8(9) . . ?
C5A C2A N1A 110.4(8) . . ?
C5A C2A C4A 111.0(10) . . ?
N1A C2A C4A 104.2(7) . . ?
C5A C2A C3A 115.0(8) . . ?
N1A C2A C3A 100.0(8) . . ?
C4A C2A C3A 114.9(10) . . ?
C7A C3A C6A 109.6(12) . . ?
C7A C3A N2A 106.2(10) . . ?
C6A C3A N2A 108.8(10) . . ?
C7A C3A C2A 115.2(11) . . ?
C6A C3A C2A 114.4(10) . . ?
N2A C3A C2A 101.9(7) . . ?
N3A C8A N4A 113.0(7) . . ?
N3A C8A C1A 124.5(8) . . ?
N4A C8A C1A 122.4(7) . . ?
N3A C9A C10A 131.7(8) . . ?
N3A C9A C14A 110.4(7) . . ?
C10A C9A C14A 117.9(8) . . ?
C11A C10A C9A 118.1(8) . . ?
C10A C11A C12A 122.6(9) . . ?
C13A C12A C11A 121.9(10) . . ?
C12A C13A C14A 117.0(9) . . ?
N4A C14A C13A 134.3(8) . . ?
N4A C14A C9A 103.4(7) . . ?
C13A C14A C9A 122.4(8) . . ?
N1B O1B Eu 137.1(6) . . ?
O1B N1B C1B 125.5(6) . . ?
O1B N1B C2B 120.6(7) . . ?
C1B N1B C2B 112.6(6) . . ?
O2B N2B C1B 123.4(7) . . ?
O2B N2B C3B 123.4(6) . . ?
C1B N2B C3B 112.6(7) . . ?
C8B N3B C9B 105.0(6) . . ?
C8B N3B Eu 129.2(4) . . ?
C9B N3B Eu 125.6(4) . . ?
C8B N4B C14B 106.5(6) . . ?
N1B C1B N2B 107.5(7) . . ?
N1B C1B C8B 124.9(7) . . ?
N2B C1B C8B 127.7(8) . . ?
N1B C2B C4B 105.8(7) . . ?
N1B C2B C5B 108.8(7) . . ?
C4B C2B C5B 109.5(9) . . ?
N1B C2B C3B 100.7(7) . . ?
C4B C2B C3B 114.7(7) . . ?
C5B C2B C3B 116.4(8) . . ?
N2B C3B C6B 105.3(9) . . ?
N2B C3B C7B 109.5(8) . . ?
C6B C3B C7B 110.5(9) . . ?
N2B C3B C2B 101.0(6) . . ?
C6B C3B C2B 114.3(9) . . ?
C7B C3B C2B 115.2(9) . . ?
N3B C8B N4B 113.2(7) . . ?
N3B C8B C1B 127.2(7) . . ?
N4B C8B C1B 119.6(7) . . ?
N3B C9B C14B 110.4(6) . . ?
N3B C9B C10B 130.0(7) . . ?
C14B C9B C10B 119.5(7) . . ?
C11B C10B C9B 116.6(8) . . ?
C10B C11B C12B 122.3(8) . . ?
C13B C12B C11B 122.4(8) . . ?
C12B C13B C14B 116.5(8) . . ?
N4B C14B C13B 132.5(7) . . ?
N4B C14B C9B 104.9(6) . . ?
C13B C14B C9B 122.6(7) . . ?
O5 N5 O3 123.0(8) . . ?
O5 N5 O4 120.7(7) . . ?
O3 N5 O4 116.2(7) . . ?
O5 N5 Eu 170.8(6) . . ?
O3 N5 Eu 60.3(4) . . ?
O4 N5 Eu 56.5(4) . . ?
N5 O3 Eu 94.9(5) . . ?
N5 O4 Eu 98.1(4) . . ?
O8 N6 O7 124.6(8) . . ?
O8 N6 O6 120.3(9) . . ?
O7 N6 O6 115.2(10) . . ?
O8 N6 Eu 177.7(8) . . ?
O7 N6 Eu 56.1(5) . . ?
O6 N6 Eu 59.2(5) . . ?
N6 O6 Eu 94.9(5) . . ?
N6 O7 Eu 99.4(6) . . ?
O11 N7 O9 122.4(9) . . ?
O11 N7 O10 120.6(9) . . ?
O9 N7 O10 117.0(7) . . ?
O11 N7 Eu 177.8(9) . . ?
O9 N7 Eu 59.2(4) . . ?
O10 N7 Eu 57.8(4) . . ?
N7 O9 Eu 96.1(5) . . ?
N7 O10 Eu 96.6(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu O1A 2.369(5) . ?
Eu O1B 2.413(5) . ?
Eu O10 2.504(6) . ?
Eu O4 2.507(6) . ?
Eu O7 2.509(8) . ?
Eu O9 2.539(6) . ?
Eu O6 2.572(7) . ?
Eu N3A 2.590(7) . ?
Eu O3 2.594(7) . ?
Eu N3B 2.598(6) . ?
Eu N7 2.938(7) . ?
Eu N5 2.976(7) . ?
O1A N1A 1.294(8) . ?
O2A N2A 1.250(11) . ?
N1A C1A 1.314(11) . ?
N1A C2A 1.510(11) . ?
N2A C1A 1.360(10) . ?
N2A C3A 1.519(13) . ?
N3A C8A 1.333(9) . ?
N3A C9A 1.378(11) . ?
N4A C8A 1.341(11) . ?
N4A C14A 1.379(11) . ?
C1A C8A 1.448(12) . ?
C2A C5A 1.496(15) . ?
C2A C4A 1.538(15) . ?
C2A C3A 1.559(15) . ?
C3A C7A 1.488(17) . ?
C3A C6A 1.509(15) . ?
C9A C10A 1.397(11) . ?
C9A C14A 1.430(12) . ?
C10A C11A 1.363(13) . ?
C11A C12A 1.381(15) . ?
C12A C13A 1.348(14) . ?
C13A C14A 1.388(13) . ?
O1B N1B 1.280(8) . ?
O2B N2B 1.263(9) . ?
N1B C1B 1.353(11) . ?
N1B C2B 1.500(10) . ?
N2B C1B 1.357(10) . ?
N2B C3B 1.496(11) . ?
N3B C8B 1.327(9) . ?
N3B C9B 1.366(9) . ?
N4B C8B 1.358(10) . ?
N4B C14B 1.389(10) . ?
C1B C8B 1.427(10) . ?
C2B C4B 1.528(15) . ?
C2B C5B 1.531(11) . ?
C2B C3B 1.548(13) . ?
C3B C6B 1.504(15) . ?
C3B C7B 1.531(13) . ?
C9B C14B 1.407(10) . ?
C9B C10B 1.420(10) . ?
C10B C11B 1.377(12) . ?
C11B C12B 1.398(13) . ?
C12B C13B 1.356(13) . ?
C13B C14B 1.398(11) . ?
N5 O5 1.219(8) . ?
N5 O3 1.252(8) . ?
N5 O4 1.289(9) . ?
N6 O8 1.213(12) . ?
N6 O7 1.253(9) . ?
N6 O6 1.306(10) . ?
N7 O11 1.217(9) . ?
N7 O9 1.233(10) . ?
N7 O10 1.278(10) . ?
