#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:15:55 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179319 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/16/4321640.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4321640
loop_
_publ_author_name
'Chi-Wing Tsang'
'Qingchuan Yang'
'Eric Tung-Po Sze'
'Thomas C. W. Mak'
'Dominic T. W. Chan'
'Zuowei Xie'
_publ_section_title
;
 Weakly Coordinating Nature of a Carborane Cage Bearing Different Halogen
 Atoms. Synthesis and Structural Characterization of Icosahedral Mixed
 Halocarborane Anions, 1-H-CB11Y5X6- (X, Y = Cl, Br, I)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5851
_journal_page_last               5858
_journal_paper_doi               10.1021/ic000354r
_journal_volume                  39
_journal_year                    2000
_chemical_formula_sum            'C21 H26 Ag B11 Cl11'
_chemical_formula_weight         895.15
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.155(1)
_cell_angle_beta                 102.772(1)
_cell_angle_gamma                100.957(1)
_cell_formula_units_Z            2
_cell_length_a                   9.3794(5)
_cell_length_b                   11.6817(6)
_cell_length_c                   18.0382(9)
_cell_measurement_temperature    294(2)
_cell_volume                     1842.50(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Siemens SHELXTL'
_computing_publication_material  'Siemens SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi ang omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0149
_diffrn_reflns_av_sigmaI/netI    0.0190
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            12958
_diffrn_reflns_theta_full        28.33
_diffrn_reflns_theta_max         28.33
_diffrn_reflns_theta_min         1.82
_exptl_absorpt_coefficient_mu    1.362
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7409
_exptl_absorpt_correction_type   abscor
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.613
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             882
_exptl_crystal_size_max          0.90
_exptl_crystal_size_mid          0.82
_exptl_crystal_size_min          0.46
_refine_diff_density_max         0.761
_refine_diff_density_min         -0.689
_refine_diff_density_rms         0.058
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         9023
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0499
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0474P)²+1.1097P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0959
_refine_ls_wR_factor_ref         0.1032
_reflns_number_gt                7273
_reflns_number_total             9023
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic000354r_4.cif
_cod_data_source_block           Ag[1-HCB11Cl11](p-xylene)2.5
_cod_original_cell_volume        1842.5(2)
_cod_database_code               4321640
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.17958(3) 0.90621(2) 0.216017(13) 0.06756(9) Uani 1 1 d . . .
Cl2 Cl 0.88265(8) 1.42823(7) 0.20233(6) 0.0652(2) Uani 1 1 d . . .
Cl3 Cl 0.65711(10) 1.59170(6) 0.28860(6) 0.0750(2) Uani 1 1 d . . .
Cl4 Cl 0.50880(12) 1.42660(9) 0.41593(5) 0.0872(3) Uani 1 1 d . . .
Cl5 Cl 0.64576(10) 1.16073(8) 0.40530(4) 0.0698(2) Uani 1 1 d . . .
Cl6 Cl 0.87720(8) 1.16396(8) 0.26997(6) 0.0682(2) Uani 1 1 d . . .
Cl7 Cl 0.49575(9) 1.41549(7) 0.08484(5) 0.06316(19) Uani 1 1 d . . .
Cl8 Cl 0.25837(9) 1.41421(8) 0.22299(7) 0.0782(3) Uani 1 1 d . . .
Cl9 Cl 0.25208(7) 1.13777(6) 0.29537(4) 0.05563(17) Uani 1 1 d . . .
Cl10 Cl 0.48458(8) 0.97092(5) 0.20602(4) 0.05093(15) Uani 1 1 d . . .
Cl11 Cl 0.63352(11) 1.13832(7) 0.07411(4) 0.0661(2) Uani 1 1 d . . .
Cl12 Cl 0.24878(8) 1.13359(7) 0.09252(4) 0.06113(19) Uani 1 1 d . . .
B2 B 0.7152(3) 1.3520(2) 0.21854(17) 0.0406(5) Uani 1 1 d . . .
B3 B 0.6023(3) 1.4336(2) 0.26296(19) 0.0452(6) Uani 1 1 d . . .
B4 B 0.5291(3) 1.3518(3) 0.32662(18) 0.0473(6) Uani 1 1 d . . .
B5 B 0.5983(3) 1.2184(3) 0.32138(16) 0.0412(6) Uani 1 1 d . . .
B6 B 0.7125(3) 1.2183(2) 0.25399(17) 0.0400(5) Uani 1 1 d . . .
B7 B 0.5296(3) 1.3471(2) 0.16544(17) 0.0403(5) Uani 1 1 d . . .
B8 B 0.4135(3) 1.3468(2) 0.23305(19) 0.0437(6) Uani 1 1 d . . .
B9 B 0.4118(3) 1.2128(2) 0.26855(16) 0.0388(5) Uani 1 1 d . . .
B10 B 0.5252(3) 1.1309(2) 0.22456(15) 0.0351(5) Uani 1 1 d . . .
B11 B 0.5977(3) 1.2126(2) 0.16026(16) 0.0379(5) Uani 1 1 d . . .
B12 B 0.4110(3) 1.2101(2) 0.16944(15) 0.0363(5) Uani 1 1 d . . .
C1 C 0.7034(3) 1.3488(2) 0.31216(15) 0.0436(5) Uani 1 1 d . . .
H1 H 0.8025 1.3958 0.3608 0.052 Uiso 1 1 calc R . .
C11 C 0.3007(4) 0.8273(3) 0.3647(2) 0.0727(9) Uani 1 1 d . . .
C12 C 0.2819(4) 0.9186(3) 0.41878(19) 0.0666(8) Uani 1 1 d . . .
H12A H 0.3641 0.9638 0.4591 0.080 Uiso 1 1 calc R . .
C13 C 0.1434(4) 0.9438(3) 0.41385(17) 0.0598(7) Uani 1 1 d . . .
H13A H 0.1340 1.0056 0.4514 0.072 Uiso 1 1 calc R . .
C14 C 0.0183(3) 0.8806(3) 0.35529(18) 0.0553(7) Uani 1 1 d . . .
C15 C 0.0354(4) 0.7901(3) 0.30054(18) 0.0623(8) Uani 1 1 d . . .
H15A H -0.0471 0.7465 0.2598 0.075 Uiso 1 1 calc R . .
C16 C 0.1754(5) 0.7629(3) 0.3053(2) 0.0710(9) Uani 1 1 d . . .
H16A H 0.1846 0.7006 0.2681 0.085 Uiso 1 1 calc R . .
C17 C 0.4518(6) 0.7966(6) 0.3726(4) 0.132(2) Uani 1 1 d . . .
H17A H 0.4446 0.7315 0.3302 0.197 Uiso 1 1 calc R . .
H17B H 0.4814 0.7737 0.4212 0.197 Uiso 1 1 calc R . .
H17C H 0.5254 0.8652 0.3713 0.197 Uiso 1 1 calc R . .
C18 C -0.1348(5) 0.9053(4) 0.3533(3) 0.0861(12) Uani 1 1 d . . .
H18A H -0.2081 0.8528 0.3085 0.129 Uiso 1 1 calc R . .
H18B H -0.1315 0.9870 0.3503 0.129 Uiso 1 1 calc R . .
H18C H -0.1620 0.8919 0.3999 0.129 Uiso 1 1 calc R . .
C21 C 0.1238(3) 0.6987(2) 0.07541(16) 0.0503(6) Uani 1 1 d . . .
C22 C 0.1127(3) 0.8163(2) 0.07476(15) 0.0500(6) Uani 1 1 d . . .
H22A H 0.1921 0.8702 0.0674 0.060 Uiso 1 1 calc R . .
C23 C -0.0153(3) 0.8539(2) 0.08498(15) 0.0511(6) Uani 1 1 d . . .
H23A H -0.0191 0.9329 0.0852 0.061 Uiso 1 1 calc R . .
C24 C -0.1381(3) 0.7752(3) 0.09497(16) 0.0511(6) Uani 1 1 d . . .
C25 C -0.1271(3) 0.6586(3) 0.09317(17) 0.0537(6) Uani 1 1 d . . .
H25A H -0.2082 0.6035 0.0981 0.064 Uiso 1 1 calc R . .
C26 C 0.0007(3) 0.6211(2) 0.08424(17) 0.0537(6) Uani 1 1 d . . .
H26A H 0.0039 0.5420 0.0842 0.064 Uiso 1 1 calc R . .
C27 C 0.2634(4) 0.6585(4) 0.0656(3) 0.0792(10) Uani 1 1 d . . .
H27A H 0.2510 0.5758 0.0677 0.119 Uiso 1 1 calc R . .
H27B H 0.3486 0.7060 0.1068 0.119 Uiso 1 1 calc R . .
H27C H 0.2796 0.6682 0.0161 0.119 Uiso 1 1 calc R . .
C28 C -0.2765(4) 0.8156(4) 0.1062(2) 0.0761(10) Uani 1 1 d . . .
H28A H -0.3482 0.7497 0.1122 0.114 Uiso 1 1 calc R . .
H28B H -0.3202 0.8435 0.0614 0.114 Uiso 1 1 calc R . .
H28C H -0.2495 0.8794 0.1520 0.114 Uiso 1 1 calc R . .
C31 C 0.0611(4) 0.3986(3) 0.49157(19) 0.0642(8) Uani 1 1 d . . .
C32 C 0.0889(4) 0.4849(3) 0.4502(2) 0.0689(8) Uani 1 1 d . . .
H32A H 0.1487 0.4758 0.4157 0.083 Uiso 1 1 calc R . .
C33 C -0.0296(4) 0.4149(3) 0.5413(2) 0.0702(9) Uani 1 1 d . . .
H33A H -0.0514 0.3577 0.5697 0.084 Uiso 1 1 calc R . .
C34 C 0.1257(6) 0.2891(4) 0.4828(3) 0.0958(13) Uani 1 1 d . . .
H34A H 0.1854 0.2925 0.4460 0.144 Uiso 1 1 calc R . .
H34B H 0.0450 0.2183 0.4644 0.144 Uiso 1 1 calc R . .
H34C H 0.1875 0.2872 0.5325 0.144 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C22 Ag1 C16 116.55(10) . . ?
C22 Ag1 C23 32.23(10) . . ?
C16 Ag1 C23 119.89(11) . . ?
C22 Ag1 C15 116.71(9) . . ?
C16 Ag1 C15 31.34(12) . . ?
C23 Ag1 C15 102.28(10) . . ?
C22 Ag1 Cl9 131.13(7) . . ?
C16 Ag1 Cl9 112.30(8) . . ?
C23 Ag1 Cl9 116.27(7) . . ?
C15 Ag1 Cl9 103.97(7) . . ?
C22 Ag1 Cl10 86.57(7) . . ?
C16 Ag1 Cl10 106.38(10) . . ?
C23 Ag1 Cl10 113.87(7) . . ?
C15 Ag1 Cl10 136.68(8) . . ?
Cl9 Ag1 Cl10 81.265(19) . . ?
B9 Cl9 Ag1 107.01(9) . . ?
B10 Cl10 Ag1 103.39(8) . . ?
C1 B2 Cl2 120.28(18) . . ?
C1 B2 B7 105.11(18) . . ?
Cl2 B2 B7 125.64(19) . . ?
C1 B2 B3 58.85(16) . . ?
Cl2 B2 B3 120.20(18) . . ?
B7 B2 B3 60.01(16) . . ?
C1 B2 B11 104.56(18) . . ?
Cl2 B2 B11 125.56(19) . . ?
B7 B2 B11 60.78(15) . . ?
B3 B2 B11 108.39(18) . . ?
C1 B2 B6 58.64(15) . . ?
Cl2 B2 B6 119.54(17) . . ?
B7 B2 B6 108.58(18) . . ?
B3 B2 B6 108.17(19) . . ?
B11 B2 B6 59.67(15) . . ?
C1 B3 Cl3 121.16(19) . . ?
C1 B3 B8 104.8(2) . . ?
Cl3 B3 B8 125.22(19) . . ?
C1 B3 B2 58.97(16) . . ?
Cl3 B3 B2 119.43(18) . . ?
B8 B3 B2 108.74(19) . . ?
C1 B3 B7 105.15(18) . . ?
Cl3 B3 B7 124.2(2) . . ?
B8 B3 B7 61.06(16) . . ?
B2 B3 B7 59.95(16) . . ?
C1 B3 B4 58.62(17) . . ?
Cl3 B3 B4 120.65(19) . . ?
B8 B3 B4 59.85(17) . . ?
B2 B3 B4 108.4(2) . . ?
B7 B3 B4 108.88(19) . . ?
C1 B4 Cl4 121.5(2) . . ?
C1 B4 B9 103.99(18) . . ?
Cl4 B4 B9 125.23(19) . . ?
C1 B4 B8 104.9(2) . . ?
Cl4 B4 B8 125.0(2) . . ?
B9 B4 B8 60.56(16) . . ?
C1 B4 B3 58.80(16) . . ?
Cl4 B4 B3 120.86(19) . . ?
B9 B4 B3 107.7(2) . . ?
B8 B4 B3 59.81(17) . . ?
C1 B4 B5 58.10(15) . . ?
Cl4 B4 B5 120.0(2) . . ?
B9 B4 B5 59.82(15) . . ?
B8 B4 B5 108.51(19) . . ?
B3 B4 B5 107.60(19) . . ?
C1 B5 Cl5 121.66(18) . . ?
C1 B5 B10 104.51(18) . . ?
Cl5 B5 B10 124.99(19) . . ?
C1 B5 B9 104.32(19) . . ?
Cl5 B5 B9 125.19(18) . . ?
B10 B5 B9 60.14(15) . . ?
C1 B5 B6 58.88(15) . . ?
Cl5 B5 B6 120.58(18) . . ?
B10 B5 B6 59.51(15) . . ?
B9 B5 B6 107.56(18) . . ?
C1 B5 B4 58.73(16) . . ?
Cl5 B5 B4 120.50(19) . . ?
B10 B5 B4 107.87(19) . . ?
B9 B5 B4 59.62(16) . . ?
B6 B5 B4 108.02(19) . . ?
C1 B6 Cl6 121.12(18) . . ?
C1 B6 B10 104.14(18) . . ?
Cl6 B6 B10 126.27(18) . . ?
C1 B6 B11 104.98(18) . . ?
Cl6 B6 B11 124.14(18) . . ?
B10 B6 B11 60.78(15) . . ?
C1 B6 B2 58.84(15) . . ?
Cl6 B6 B2 118.93(17) . . ?
B10 B6 B2 108.23(18) . . ?
B11 B6 B2 60.01(15) . . ?
C1 B6 B5 58.15(15) . . ?
Cl6 B6 B5 121.43(18) . . ?
B10 B6 B5 59.76(15) . . ?
B11 B6 B5 108.59(18) . . ?
B2 B6 B5 107.82(19) . . ?
Cl7 B7 B2 121.61(17) . . ?
Cl7 B7 B3 121.61(18) . . ?
B2 B7 B3 60.03(16) . . ?
Cl7 B7 B12 122.98(18) . . ?
B2 B7 B12 107.21(18) . . ?
B3 B7 B12 106.85(19) . . ?
Cl7 B7 B11 122.22(19) . . ?
B2 B7 B11 59.72(15) . . ?
B3 B7 B11 107.56(19) . . ?
B12 B7 B11 59.85(14) . . ?
Cl7 B7 B8 122.04(18) . . ?
B2 B7 B8 107.5(2) . . ?
B3 B7 B8 59.43(16) . . ?
B12 B7 B8 59.62(15) . . ?
B11 B7 B8 107.67(18) . . ?
Cl8 B8 B3 121.80(18) . . ?
Cl8 B8 B4 121.16(19) . . ?
B3 B8 B4 60.34(17) . . ?
Cl8 B8 B12 122.78(19) . . ?
B3 B8 B12 106.99(18) . . ?
B4 B8 B12 107.51(19) . . ?
Cl8 B8 B9 122.15(17) . . ?
B3 B8 B9 107.5(2) . . ?
B4 B8 B9 59.70(16) . . ?
B12 B8 B9 59.70(15) . . ?
Cl8 B8 B7 122.1(2) . . ?
B3 B8 B7 59.51(16) . . ?
B4 B8 B7 108.04(19) . . ?
B12 B8 B7 59.73(15) . . ?
B9 B8 B7 107.55(18) . . ?
B4 B9 B10 108.27(18) . . ?
B4 B9 B5 60.56(16) . . ?
B10 B9 B5 59.70(15) . . ?
B4 B9 B12 107.80(19) . . ?
B10 B9 B12 60.54(14) . . ?
B5 B9 B12 108.17(18) . . ?
B4 B9 B8 59.75(17) . . ?
B10 B9 B8 108.65(18) . . ?
B5 B9 B8 108.46(18) . . ?
B12 B9 B8 60.02(16) . . ?
B4 B9 Cl9 121.52(18) . . ?
B10 B9 Cl9 121.19(17) . . ?
B5 B9 Cl9 120.85(18) . . ?
B12 B9 Cl9 122.20(17) . . ?
B8 B9 Cl9 122.02(17) . . ?
B6 B10 B5 60.73(15) . . ?
B6 B10 B9 108.54(18) . . ?
B5 B10 B9 60.16(15) . . ?
B6 B10 Cl10 121.38(17) . . ?
B5 B10 Cl10 120.39(17) . . ?
B9 B10 Cl10 121.18(16) . . ?
B6 B10 B11 59.82(15) . . ?
B5 B10 B11 108.60(18) . . ?
B9 B10 B11 108.14(18) . . ?
Cl10 B10 B11 122.38(17) . . ?
B6 B10 B12 107.64(17) . . ?
B5 B10 B12 107.92(18) . . ?
B9 B10 B12 59.77(15) . . ?
Cl10 B10 B12 122.76(17) . . ?
B11 B10 B12 59.88(14) . . ?
Cl11 B11 B6 121.17(17) . . ?
Cl11 B11 B2 122.37(17) . . ?
B6 B11 B2 60.31(16) . . ?
Cl11 B11 B12 122.44(18) . . ?
B6 B11 B12 107.52(18) . . ?
B2 B11 B12 106.97(18) . . ?
Cl11 B11 B10 121.43(17) . . ?
B6 B11 B10 59.40(14) . . ?
B2 B11 B10 107.38(19) . . ?
B12 B11 B10 60.14(14) . . ?
Cl11 B11 B7 122.40(18) . . ?
B6 B11 B7 108.07(19) . . ?
B2 B11 B7 59.50(15) . . ?
B12 B11 B7 59.77(14) . . ?
B10 B11 B7 107.99(18) . . ?
Cl12 B12 B9 120.72(16) . . ?
Cl12 B12 B8 120.80(17) . . ?
B9 B12 B8 60.28(16) . . ?
Cl12 B12 B7 121.82(17) . . ?
B9 B12 B7 108.75(18) . . ?
B8 B12 B7 60.65(15) . . ?
Cl12 B12 B11 122.18(18) . . ?
B9 B12 B11 108.15(18) . . ?
B8 B12 B11 108.91(18) . . ?
B7 B12 B11 60.38(14) . . ?
Cl12 B12 B10 121.69(16) . . ?
B9 B12 B10 59.69(15) . . ?
B8 B12 B10 108.19(19) . . ?
B7 B12 B10 108.33(17) . . ?
B11 B12 B10 59.97(14) . . ?
B5 C1 B4 63.17(17) . . ?
B5 C1 B6 62.97(15) . . ?
B4 C1 B6 114.99(18) . . ?
B5 C1 B3 114.89(19) . . ?
B4 C1 B3 62.59(17) . . ?
B6 C1 B3 114.10(19) . . ?
B5 C1 B2 114.83(19) . . ?
B4 C1 B2 114.3(2) . . ?
B6 C1 B2 62.52(16) . . ?
B3 C1 B2 62.18(16) . . ?
C12 C11 C16 117.6(3) . . ?
C12 C11 C17 120.6(4) . . ?
C16 C11 C17 121.7(4) . . ?
C13 C12 C11 120.9(3) . . ?
C14 C13 C12 122.1(3) . . ?
C15 C14 C13 117.8(3) . . ?
C15 C14 C18 120.9(3) . . ?
C13 C14 C18 121.2(3) . . ?
C14 C15 C16 120.7(3) . . ?
C14 C15 Ag1 103.13(19) . . ?
C16 C15 Ag1 69.87(18) . . ?
C11 C16 C15 120.9(3) . . ?
C11 C16 Ag1 98.1(2) . . ?
C15 C16 Ag1 78.8(2) . . ?
C26 C21 C22 117.1(3) . . ?
C26 C21 C27 121.8(3) . . ?
C22 C21 C27 121.1(3) . . ?
C23 C22 C21 121.1(2) . . ?
C23 C22 Ag1 76.79(16) . . ?
C21 C22 Ag1 100.85(17) . . ?
C22 C23 C24 121.3(3) . . ?
C22 C23 Ag1 70.98(15) . . ?
C24 C23 Ag1 104.61(17) . . ?
C25 C24 C23 116.9(3) . . ?
C25 C24 C28 121.7(3) . . ?
C23 C24 C28 121.4(3) . . ?
C24 C25 C26 122.1(3) . . ?
C21 C26 C25 121.5(3) . . ?
C32 C31 C33 117.4(3) . . ?
C32 C31 C34 121.8(4) . . ?
C33 C31 C34 120.8(4) . . ?
C31 C32 C33 121.4(3) . 2_566 ?
C31 C33 C32 121.2(3) . 2_566 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 C22 2.468(3) . ?
Ag1 C16 2.521(3) . ?
Ag1 C23 2.541(3) . ?
Ag1 C15 2.633(3) . ?
Ag1 Cl9 2.7079(8) . ?
Ag1 Cl10 2.8708(7) . ?
Cl2 B2 1.763(3) . ?
Cl3 B3 1.767(3) . ?
Cl4 B4 1.760(3) . ?
Cl5 B5 1.766(3) . ?
Cl6 B6 1.765(3) . ?
Cl7 B7 1.776(3) . ?
Cl8 B8 1.772(3) . ?
Cl9 B9 1.793(3) . ?
Cl10 B10 1.790(3) . ?
Cl11 B11 1.774(3) . ?
Cl12 B12 1.775(3) . ?
B2 C1 1.723(4) . ?
B2 B7 1.777(4) . ?
B2 B3 1.778(4) . ?
B2 B11 1.781(4) . ?
B2 B6 1.786(4) . ?
B3 C1 1.721(4) . ?
B3 B8 1.776(4) . ?
B3 B7 1.778(4) . ?
B3 B4 1.786(4) . ?
B4 C1 1.718(4) . ?
B4 B9 1.776(4) . ?
B4 B8 1.777(5) . ?
B4 B5 1.793(4) . ?
B5 C1 1.706(4) . ?
B5 B10 1.772(4) . ?
B5 B9 1.780(4) . ?
B5 B6 1.789(4) . ?
B6 C1 1.719(4) . ?
B6 B10 1.767(4) . ?
B6 B11 1.775(4) . ?
B7 B12 1.789(4) . ?
B7 B11 1.800(4) . ?
B7 B8 1.806(4) . ?
B8 B12 1.787(4) . ?
B8 B9 1.792(4) . ?
B9 B10 1.780(4) . ?
B9 B12 1.781(4) . ?
B10 B11 1.792(4) . ?
B10 B12 1.795(4) . ?
B11 B12 1.790(4) . ?
C11 C12 1.378(5) . ?
C11 C16 1.386(6) . ?
C11 C17 1.509(6) . ?
C12 C13 1.373(5) . ?
C13 C14 1.373(4) . ?
C14 C15 1.373(4) . ?
C14 C18 1.512(5) . ?
C15 C16 1.397(5) . ?
C21 C26 1.384(4) . ?
C21 C22 1.399(4) . ?
C21 C27 1.508(4) . ?
C22 C23 1.392(4) . ?
C23 C24 1.397(4) . ?
C24 C25 1.381(4) . ?
C24 C28 1.504(4) . ?
C25 C26 1.384(4) . ?
C31 C32 1.376(5) . ?
C31 C33 1.380(5) . ?
C31 C34 1.515(5) . ?
C32 C33 1.387(5) 2_566 ?
C33 C32 1.387(5) 2_566 ?
