#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:22:11 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179324 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/21/4322107.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4322107
loop_
_publ_author_name
'Guy N. Richardson'
'Udo Brand'
'Heinrich Vahrenkamp'
_publ_section_title
;
 Linear and Bent M(μ-CN)Pt(μ-CN)M Chains: Probes for Remote Metal-Metal
 Interactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3070
_journal_page_last               3079
_journal_paper_doi               10.1021/ic981384l
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C86 H92 F12 Fe2 N4 O4 P4 Pt Sb2'
_chemical_formula_weight         2147.81
_chemical_name_common            trans-diironcyanide-platinum(II)di-pyridine
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.03(3)
_cell_angle_beta                 91.25(3)
_cell_angle_gamma                94.73(3)
_cell_formula_units_Z            1
_cell_length_a                   11.846(2)
_cell_length_b                   11.918(2)
_cell_length_c                   15.130(3)
_cell_measurement_temperature    293(2)
_cell_volume                     2119.7(7)
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.921
_diffrn_measured_fraction_theta_max 0.921
_diffrn_measurement_device_type  NONIUS-TURBO-CAD4
_diffrn_measurement_method       Omega-2Theta
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0185
_diffrn_reflns_av_sigmaI/netI    0.0076
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            5368
_diffrn_reflns_theta_full        22.53
_diffrn_reflns_theta_max         22.53
_diffrn_reflns_theta_min         3.07
_diffrn_standards_interval_count 'OCR every 200 refl.'
_diffrn_standards_interval_time  'ICR every 1800s'
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    2.761
_exptl_absorpt_correction_T_max  0.791
_exptl_absorpt_correction_T_min  0.614
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.683
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1068
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_refine_diff_density_max         2.344
_refine_diff_density_min         -3.617
_refine_diff_density_rms         0.167
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.107
_refine_ls_hydrogen_treatment    Riding-Model
_refine_ls_matrix_type           full
_refine_ls_number_parameters     520
_refine_ls_number_reflns         5135
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.107
_refine_ls_R_factor_all          0.0405
_refine_ls_R_factor_gt           0.0402
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0863P)²+3.1908P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1102
_refine_ls_wR_factor_ref         0.1108
_reflns_number_gt                5107
_reflns_number_total             5135
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic981384l_3.cif
_cod_data_source_block           g6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0863P)^2^+3.1908P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0863P)^2^+3.1908P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_database_code               4322107
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.0000 0.0000 0.0000 0.01765(15) Uani 1 d S . .
Fe1 Fe 0.25799(5) 0.08328(6) 0.26161(5) 0.0164(2) Uani 1 d . . .
P1 P 0.14503(10) 0.21851(11) 0.27492(9) 0.0187(3) Uani 1 d . . .
P2 P 0.14758(10) -0.00575(11) 0.35043(8) 0.0176(3) Uani 1 d . . .
C9 C 0.3999(5) 0.1243(5) 0.1874(4) 0.0344(15) Uani 1 d . . .
H9A H 0.3995 0.1529 0.1300 0.080 Uiso 1 d R . .
C20 C 0.1661(4) 0.3380(4) 0.3598(3) 0.0236(12) Uani 1 d . . .
C36 C 0.0856(5) -0.3139(5) 0.2092(4) 0.0337(14) Uani 1 d . . .
H36A H 0.1227 -0.3580 0.1642 0.080 Uiso 1 d R . .
C31 C 0.2426(4) 0.0561(5) 0.5199(3) 0.0267(13) Uani 1 d . . .
H31A H 0.2349 0.1317 0.5048 0.080 Uiso 1 d R . .
C11 C 0.4081(4) 0.1132(5) 0.3374(4) 0.0277(13) Uani 1 d . . .
H11A H 0.4141 0.1344 0.4001 0.080 Uiso 1 d R . .
C10 C 0.4089(4) 0.1887(5) 0.2701(4) 0.0297(13) Uani 1 d . . .
H10A H 0.4147 0.2697 0.2793 0.080 Uiso 1 d R . .
C17 C 0.0893(6) 0.3909(5) 0.0195(4) 0.0442(17) Uani 1 d . . .
H17A H 0.0789 0.4264 -0.0343 0.080 Uiso 1 d R . .
C19 C 0.2099(5) 0.3389(5) 0.1337(4) 0.0338(14) Uani 1 d . . .
H19A H 0.2846 0.3391 0.1596 0.080 Uiso 1 d R . .
N2 N 0.1022(4) 0.0065(4) 0.1040(3) 0.0224(10) Uani 1 d . . .
C35 C -0.0142(5) -0.3573(5) 0.2423(4) 0.0330(14) Uani 1 d . . .
H35A H -0.0487 -0.4293 0.2176 0.080 Uiso 1 d R . .
C32 C 0.0807(4) -0.1450(4) 0.3088(3) 0.0221(11) Uani 1 d . . .
C25 C 0.0939(5) 0.4248(5) 0.3616(4) 0.0320(13) Uani 1 d . . .
H25A H 0.0366 0.4243 0.3157 0.080 Uiso 1 d R . .
C14 C 0.1179(4) 0.2888(4) 0.1755(3) 0.0219(12) Uani 1 d . . .
C30 C 0.2906(5) 0.0393(5) 0.6016(4) 0.0335(14) Uani 1 d . . .
H30A H 0.3150 0.1027 0.6430 0.080 Uiso 1 d R . .
C23 C 0.1830(6) 0.5140(5) 0.4942(4) 0.0432(16) Uani 1 d . . .
H23A H 0.1859 0.5724 0.5423 0.080 Uiso 1 d R . .
C37 C 0.1334(5) -0.2071(5) 0.2414(4) 0.0280(13) Uani 1 d . . .
H37A H 0.2021 -0.1765 0.2169 0.080 Uiso 1 d R . .
C24 C 0.1046(6) 0.5115(5) 0.4273(4) 0.0370(15) Uani 1 d . . .
H24A H 0.0556 0.5716 0.4263 0.080 Uiso 1 d R . .
C8 C 0.3953(4) 0.0087(5) 0.2041(4) 0.0330(14) Uani 1 d . . .
H8A H 0.3893 -0.0546 0.1598 0.080 Uiso 1 d R . .
C22 C 0.2581(6) 0.4302(5) 0.4933(4) 0.0404(15) Uani 1 d . . .
H22A H 0.3165 0.4327 0.5387 0.080 Uiso 1 d R . .
C33 C -0.0186(4) -0.1908(5) 0.3424(4) 0.0282(13) Uani 1 d . . .
H33A H -0.0548 -0.1494 0.3895 0.080 Uiso 1 d R . .
C6 C 0.1639(4) 0.0328(4) 0.1656(4) 0.0202(11) Uani 1 d . . .
C18 C 0.1948(6) 0.3899(5) 0.0559(4) 0.0403(16) Uani 1 d . . .
H18A H 0.2588 0.4244 0.0275 0.080 Uiso 1 d R . .
C27 C 0.2198(5) -0.1427(5) 0.4807(4) 0.0291(13) Uani 1 d . . .
H27A H 0.1975 -0.2062 0.4387 0.080 Uiso 1 d R . .
C21 C 0.2495(5) 0.3439(5) 0.4268(4) 0.0283(13) Uani 1 d . . .
H21A H 0.3022 0.2867 0.4261 0.080 Uiso 1 d R . .
C29 C 0.3027(5) -0.0704(5) 0.6226(4) 0.0356(14) Uani 1 d . . .
H29A H 0.3365 -0.0830 0.6787 0.080 Uiso 1 d R . .
C28 C 0.2671(5) -0.1591(6) 0.5634(4) 0.0375(16) Uani 1 d . . .
H28A H 0.2737 -0.2347 0.5789 0.080 Uiso 1 d R . .
C7 C 0.4002(4) 0.0024(5) 0.2957(4) 0.0304(13) Uani 1 d . . .
H7A H 0.4000 -0.0658 0.3250 0.080 Uiso 1 d R . .
C16 C -0.0039(6) 0.3414(5) 0.0599(4) 0.0420(16) Uani 1 d . . .
H16A H -0.0782 0.3421 0.0335 0.080 Uiso 1 d R . .
C34 C -0.0651(5) -0.2976(5) 0.3090(4) 0.0342(14) Uani 1 d . . .
H34A H -0.1338 -0.3295 0.3329 0.080 Uiso 1 d R . .
C15 C 0.0112(5) 0.2904(5) 0.1374(4) 0.0326(14) Uani 1 d . . .
H15A H -0.0530 0.2555 0.1653 0.080 Uiso 1 d R . .
C26 C 0.2057(4) -0.0343(4) 0.4593(3) 0.0214(12) Uani 1 d . . .
Sb1 Sb 0.68094(3) 0.41530(3) 0.23136(3) 0.03057(17) Uani 1 d . . .
F2 F 0.6133(3) 0.3733(4) 0.3351(3) 0.0533(11) Uani 1 d . . .
F6 F 0.8233(3) 0.4190(3) 0.2884(3) 0.0505(10) Uani 1 d . . .
F5 F 0.5385(3) 0.4098(4) 0.1752(3) 0.0572(11) Uani 1 d . . .
F4 F 0.6717(3) 0.5659(3) 0.2731(3) 0.0585(10) Uani 1 d . . .
F1 F 0.6918(4) 0.2660(4) 0.1909(3) 0.0778(14) Uani 1 d . . .
N1 N 0.1358(4) 0.0415(4) -0.0733(3) 0.0212(10) Uani 1 d . . .
C12 C 0.0058(4) 0.1525(5) 0.3041(4) 0.0228(12) Uani 1 d . . .
H12A H -0.0281 0.1056 0.2541 0.080 Uiso 1 d R . .
H12B H -0.0442 0.2093 0.3218 0.080 Uiso 1 d R . .
F3 F 0.7498(4) 0.4637(4) 0.1305(3) 0.0724(13) Uani 1 d . . .
C13 C 0.0282(4) 0.0807(4) 0.3802(4) 0.0236(12) Uani 1 d . . .
H13A H 0.0478 0.1291 0.4333 0.080 Uiso 1 d R . .
H13B H -0.0381 0.0324 0.3908 0.080 Uiso 1 d R . .
C1 C 0.1412(5) 0.1342(5) -0.1169(4) 0.0293(13) Uani 1 d . . .
H1A H 0.0768 0.1779 -0.1186 0.080 Uiso 1 d R . .
C2 C 0.2364(5) 0.1679(5) -0.1604(4) 0.0360(14) Uani 1 d . . .
H2A H 0.2399 0.2365 -0.1895 0.080 Uiso 1 d R . .
C4 C 0.3222(5) 0.0088(5) -0.1191(4) 0.0403(15) Uani 1 d . . .
H4A H 0.3842 -0.0383 -0.1210 0.080 Uiso 1 d R . .
C5 C 0.2246(5) -0.0211(5) -0.0741(4) 0.0312(13) Uani 1 d . . .
H5A H 0.2215 -0.0871 -0.0418 0.080 Uiso 1 d R . .
C3 C 0.3275(5) 0.1045(5) -0.1619(4) 0.0352(14) Uani 1 d . . .
H3A H 0.3946 0.1279 -0.1922 0.080 Uiso 1 d R . .
O1 O 0.4622(5) -0.2556(4) 0.2662(4) 0.0771(17) Uani 1 d . . .
C39 C 0.4402(5) -0.3229(6) 0.3205(5) 0.0493(18) Uani 1 d . . .
C38 C 0.3712(7) -0.4284(7) 0.2935(6) 0.072(2) Uani 1 d . . .
H38A H 0.3532 -0.4326 0.2311 0.080 Uiso 1 d R . .
H38B H 0.4123 -0.4916 0.3061 0.080 Uiso 1 d R . .
H38C H 0.3024 -0.4301 0.3260 0.080 Uiso 1 d R . .
C42 C 0.4324(6) -0.2521(7) 0.0314(4) 0.0518(18) Uani 1 d . . .
C43 C 0.3199(8) -0.2905(8) 0.0582(6) 0.073(2) Uani 1 d . . .
H43A H 0.2725 -0.2293 0.0547 0.080 Uiso 1 d R . .
H43B H 0.2890 -0.3545 0.0198 0.080 Uiso 1 d R . .
H43C H 0.3231 -0.3107 0.1182 0.080 Uiso 1 d R . .
C40 C 0.4796(7) -0.3011(8) 0.4141(6) 0.074(2) Uani 1 d . . .
H40A H 0.5243 -0.2299 0.4225 0.080 Uiso 1 d R . .
H40B H 0.4143 -0.2987 0.4505 0.080 Uiso 1 d R . .
H40C H 0.5242 -0.3601 0.4305 0.080 Uiso 1 d R . .
O2 O 0.4538(5) -0.1559(5) 0.0108(4) 0.0711(15) Uani 1 d . . .
C41 C 0.5211(8) -0.3297(7) 0.0303(6) 0.069(2) Uani 1 d . . .
H41A H 0.5889 -0.2910 0.0105 0.080 Uiso 1 d R . .
H41B H 0.5343 -0.3519 0.0889 0.080 Uiso 1 d R . .
H41C H 0.5002 -0.3957 -0.0096 0.080 Uiso 1 d R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Pt1 N2 180.0 . 2 ?
N2 Pt1 N1 88.63(17) . . y
N2 Pt1 N1 91.37(17) 2 . y
N2 Pt1 N1 91.37(17) . 2 ?
N2 Pt1 N1 88.63(17) 2 2 ?
N1 Pt1 N1 180.0 . 2 ?
C6 Fe1 C11 158.0(2) . . y
C6 Fe1 C7 122.9(2) . . y
C11 Fe1 C7 39.5(2) . . y
C6 Fe1 C8 92.1(2) . . y
C11 Fe1 C8 66.0(2) . . y
C7 Fe1 C8 39.1(2) . . y
C6 Fe1 C9 95.7(2) . . y
C11 Fe1 C9 66.4(2) . . y
C7 Fe1 C9 66.3(2) . . y
C8 Fe1 C9 39.7(2) . . y
C6 Fe1 C10 130.6(2) . . y
C11 Fe1 C10 39.6(2) . . y
C7 Fe1 C10 66.2(2) . . y
C8 Fe1 C10 66.0(2) . . y
C9 Fe1 C10 39.3(2) . . y
C6 Fe1 P1 82.97(16) . . y
C11 Fe1 P1 114.95(16) . . y
C7 Fe1 P1 154.04(17) . . y
C8 Fe1 P1 151.47(18) . . y
C9 Fe1 P1 112.57(18) . . y
C10 Fe1 P1 96.11(16) . . y
C6 Fe1 P2 91.31(15) . . y
C11 Fe1 P2 101.75(16) . . y
C7 Fe1 P2 94.01(15) . . y
C8 Fe1 P2 121.22(18) . . y
C9 Fe1 P2 159.77(17) . . y
C10 Fe1 P2 138.08(17) . . y
P1 Fe1 P2 87.08(6) . . y
C14 P1 C20 101.9(2) . . y
C14 P1 C12 105.3(2) . . y
C20 P1 C12 101.5(2) . . y
C14 P1 Fe1 116.50(16) . . y
C20 P1 Fe1 123.10(17) . . y
C12 P1 Fe1 106.36(18) . . y
C32 P2 C26 101.8(2) . . y
C32 P2 C13 105.1(2) . . y
C26 P2 C13 103.1(2) . . y
C32 P2 Fe1 117.53(17) . . y
C26 P2 Fe1 118.56(16) . . y
C13 P2 Fe1 109.10(17) . . y
C10 C9 C8 107.4(5) . . y
C10 C9 Fe1 70.5(3) . . y
C8 C9 Fe1 70.0(3) . . y
C21 C20 C25 117.6(5) . . y
C21 C20 P1 122.3(4) . . y
C25 C20 P1 120.1(4) . . y
C35 C36 C37 120.3(6) . . y
C30 C31 C26 121.3(5) . . y
C7 C11 C10 107.8(5) . . y
C7 C11 Fe1 70.4(3) . . y
C10 C11 Fe1 70.6(3) . . y
C9 C10 C11 108.1(5) . . y
C9 C10 Fe1 70.2(3) . . y
C11 C10 Fe1 69.8(3) . . y
C18 C17 C16 120.3(5) . . y
C18 C19 C14 120.8(6) . . y
C6 N2 Pt1 166.9(4) . . y
C34 C35 C36 120.2(5) . . y
C33 C32 C37 119.2(5) . . y
C33 C32 P2 122.4(4) . . y
C37 C32 P2 118.4(4) . . y
C24 C25 C20 120.8(6) . . y
C15 C14 C19 118.5(5) . . y
C15 C14 P1 123.2(4) . . y
C19 C14 P1 118.2(4) . . y
C31 C30 C29 119.2(5) . . y
C24 C23 C22 119.5(6) . . y
C36 C37 C32 119.8(5) . . y
C23 C24 C25 121.2(6) . . y
C7 C8 C9 108.4(5) . . y
C7 C8 Fe1 70.4(3) . . y
C9 C8 Fe1 70.2(3) . . y
C21 C22 C23 119.8(6) . . y
C32 C33 C34 120.0(5) . . y
N2 C6 Fe1 176.4(4) . . y
C17 C18 C19 119.9(6) . . y
C26 C27 C28 119.6(5) . . y
C22 C21 C20 121.1(5) . . y
C28 C29 C30 119.7(5) . . y
C29 C28 C27 121.4(6) . . y
C8 C7 C11 108.3(5) . . y
C8 C7 Fe1 70.6(3) . . y
C11 C7 Fe1 70.1(3) . . y
C15 C16 C17 119.8(6) . . y
C35 C34 C33 120.5(5) . . y
C14 C15 C16 120.7(5) . . y
C27 C26 C31 118.8(5) . . y
C27 C26 P2 122.1(4) . . y
C31 C26 P2 119.1(4) . . y
F1 Sb1 F3 91.1(2) . . y
F1 Sb1 F4 179.2(2) . . y
F3 Sb1 F4 89.0(2) . . y
F1 Sb1 F5 89.7(2) . . y
F3 Sb1 F5 90.66(19) . . y
F4 Sb1 F5 91.05(19) . . y
F1 Sb1 F2 91.4(2) . . y
F3 Sb1 F2 177.4(2) . . y
F4 Sb1 F2 88.51(19) . . y
F5 Sb1 F2 90.13(17) . . y
F1 Sb1 F6 89.7(2) . . y
F3 Sb1 F6 89.92(19) . . y
F4 Sb1 F6 89.49(18) . . y
F5 Sb1 F6 179.22(17) . . y
F2 Sb1 F6 89.31(17) . . y
C1 N1 C5 119.1(5) . . y
C1 N1 Pt1 121.0(4) . . y
C5 N1 Pt1 119.8(4) . . y
C13 C12 P1 106.4(3) . . y
C12 C13 P2 108.5(3) . . y
N1 C1 C2 121.4(5) . . y
C3 C2 C1 120.0(5) . . y
C3 C4 C5 118.9(5) . . y
N1 C5 C4 121.4(5) . . y
C4 C3 C2 119.2(5) . . y
O1 C39 C38 119.7(8) . . y
O1 C39 C40 122.0(7) . . y
C38 C39 C40 118.3(7) . . y
O2 C42 C43 121.1(8) . . y
O2 C42 C41 119.9(8) . . y
C43 C42 C41 119.0(8) . . y
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N2 1.956(5) . y
Pt1 N2 1.956(5) 2 ?
Pt1 N1 2.026(4) . y
Pt1 N1 2.026(4) 2 ?
Fe1 C6 1.839(6) . y
Fe1 C11 2.082(5) . y
Fe1 C7 2.085(5) . y
Fe1 C8 2.088(5) . y
Fe1 C9 2.090(5) . y
Fe1 C10 2.093(5) . y
Fe1 P1 2.1769(16) . y
Fe1 P2 2.1773(15) . y
P1 C14 1.820(5) . y
P1 C20 1.830(5) . y
P1 C12 1.847(5) . y
P2 C32 1.832(5) . y
P2 C26 1.841(5) . y
P2 C13 1.857(5) . y
C9 C10 1.406(9) . y
C9 C8 1.420(9) . y
C20 C21 1.393(8) . y
C20 C25 1.394(8) . y
C36 C35 1.373(8) . y
C36 C37 1.392(8) . y
C31 C30 1.386(8) . y
C31 C26 1.387(8) . y
C11 C7 1.408(8) . y
C11 C10 1.416(8) . y
C17 C18 1.356(10) . y
C17 C16 1.388(9) . y
C19 C18 1.387(8) . y
C19 C14 1.390(8) . y
N2 C6 1.176(7) . y
C35 C34 1.364(9) . y
C32 C33 1.382(7) . y
C32 C37 1.395(8) . y
C25 C24 1.365(9) . y
C14 C15 1.380(8) . y
C30 C29 1.390(9) . y
C23 C24 1.355(9) . y
C23 C22 1.391(9) . y
C8 C7 1.395(9) . y
C22 C21 1.371(8) . y
C33 C34 1.393(8) . y
C27 C26 1.382(8) . y
C27 C28 1.396(9) . y
C29 C28 1.358(9) . y
C16 C15 1.382(8) . y
Sb1 F1 1.846(4) . y
Sb1 F3 1.859(4) . y
Sb1 F4 1.863(4) . y
Sb1 F5 1.866(3) . y
Sb1 F2 1.867(4) . y
Sb1 F6 1.873(3) . y
N1 C1 1.334(7) . y
N1 C5 1.338(7) . y
C12 C13 1.525(8) . y
C1 C2 1.369(8) . y
C2 C3 1.367(9) . y
C4 C3 1.358(9) . y
C4 C5 1.393(8) . y
O1 C39 1.215(8) . y
C39 C38 1.463(11) . y
C39 C40 1.476(11) . y
C42 O2 1.223(9) . y
C42 C43 1.452(12) . y
C42 C41 1.455(11) . y
