#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:22:11 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179324 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/21/4322158.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4322158
loop_
_publ_author_name
'Alan L. Balch'
'Marilyn M. Olmstead'
'Jess C. Vickery'
_publ_contact_author
; Dr. Alan L. Balch
  Department of Chemistry
  University of California
  Davis, CA 95616
  USA
;
_publ_contact_author_email       balch@indigo.ucdavis.edu
_publ_contact_author_fax         530-752-8995
_publ_contact_author_phone       530-752-0941
_publ_section_title
;
 Gold(I) Compounds without Significant Aurophilic Intermolecular
 Interactions: Synthesis, Structure, and Electronic Properties of
 Ph₃PAuC(O)NHCH₃ and Au₃(PhCH₂N=COCH₃)₃: Comparative Monomeric
 and Trimeric Analogues of the Solvoluminescent Trimer,
 Au₃(CH₃N=COCH₃)₃.
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3494
_journal_page_last               3499
_journal_paper_doi               10.1021/ic990080b
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C27 H30 Au3 N3 O3'
_chemical_formula_weight         1035.44
_chemical_name_common            Au₃(PhCH₂N=COCH₃)₃
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 94.73(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   17.311(6)
_cell_length_b                   34.761(10)
_cell_length_c                   18.052(6)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    133(2)
_cell_measurement_theta_max      18.5
_cell_measurement_theta_min      2.35
_cell_volume                     10826(6)
_computing_cell_refinement       'Siemens P3'
_computing_data_collection       'Siemens P3'
_computing_data_reduction        'Siemens XDISK'
_computing_molecular_graphics    'SHELXTL V.5.03 (Sheldrick, 1995) XP'
_computing_publication_material  'SHELXTL V.5.03 (Sheldrick, 1995) XCIF'
_computing_structure_refinement  'SHELXTL V.5.03 (Sheldrick, 1995) XL'
_computing_structure_solution    'SHELXTL V.5.03 (Sheldrick, 1995) XS'
_diffrn_ambient_temperature      130(2)
_diffrn_measurement_device_type  'Siemens R3m/v'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1572
_diffrn_reflns_av_sigmaI/netI    0.0880
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -37
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            16250
_diffrn_reflns_theta_max         22.51
_diffrn_reflns_theta_min         1.17
_diffrn_standards_decay_%        <0.1
_diffrn_standards_interval_count 198
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    16.255
_exptl_absorpt_correction_T_max  0.444
_exptl_absorpt_correction_T_min  0.214
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;XABS2: an empirical absorption correction program. Parkin,S.;
Moezzi, B.; Hope, H. J. Appl. Cryst. 1995, 28, 53-56. 
;
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    2.541
_exptl_crystal_density_meas      ?
_exptl_crystal_description       Needle
_exptl_crystal_F_000             7584
_exptl_crystal_size_max          0.54
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         2.809
_refine_diff_density_min         -3.235
_refine_diff_density_rms         0.412
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.01(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.002
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           fullcycle
_refine_ls_number_parameters     985
_refine_ls_number_reflns         14434
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.018
_refine_ls_restrained_S_obs      1.032
_refine_ls_R_factor_all          0.1145
_refine_ls_R_factor_obs          0.0735
_refine_ls_shift/su_max          -0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1210P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.2149
_refine_ls_wR_factor_obs         0.1775
_reflns_number_gt                9762
_reflns_number_total             14448
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic990080b_1.cif
_cod_data_source_block           jv02q
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.1210P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.1210P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        10825.8(61)
_cod_database_code               4322158
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Au1 Au 0.62148(11) 0.11413(6) 1.17179(13) 0.0276(5) Uani 1 d . .
O1 O 0.7624(20) 0.1991(11) 1.2611(22) 0.036(10) Uiso 1 d . .
N1 N 0.6656(25) 0.1642(14) 1.2111(28) 0.038(12) Uiso 1 d . .
C1 C 0.7433(26) 0.1680(14) 1.2315(29) 0.020(11) Uiso 1 d . .
Au2 Au 0.80950(11) 0.12386(6) 1.21474(12) 0.0256(5) Uani 1 d . .
N2 N 0.8791(20) 0.0807(10) 1.1938(22) 0.014(9) Uiso 1 d . .
O2 O 0.9087(18) 0.0192(9) 1.1633(20) 0.028(8) Uiso 1 d . .
C2 C 0.8561(34) 0.0483(18) 1.1696(38) 0.048(17) Uiso 1 d . .
Au3 Au 0.73876(11) 0.03922(6) 1.15421(12) 0.0273(5) Uani 1 d . .
N3 N 0.6149(22) 0.0337(12) 1.1299(23) 0.026(10) Uiso 1 d . .
O3 O 0.5030(22) 0.0558(12) 1.1163(25) 0.048(11) Uiso 1 d . .
C3 C 0.5815(23) 0.0684(12) 1.1470(26) 0.012(10) Uiso 1 d . .
C4 C 0.8462(24) 0.2050(13) 1.2758(27) 0.014(10) Uiso 1 d . .
H4A H 0.8669 0.1857 1.3125 0.021 Uiso 1 d . .
H4B H 0.8562 0.2307 1.2964 0.021 Uiso 1 d . .
H4C H 0.8717 0.2019 1.2300 0.021 Uiso 1 d . .
C5 C 0.8821(36) -0.0189(19) 1.1348(40) 0.053(18) Uiso 1 d . .
H5A H 0.9092 -0.0394 1.1642 0.080 Uiso 1 d . .
H5B H 0.8926 -0.0216 1.0826 0.080 Uiso 1 d . .
H5C H 0.8259 -0.0215 1.1389 0.080 Uiso 1 d . .
C6 C 0.4482(31) 0.0863(17) 1.1173(34) 0.039(15) Uiso 1 d . .
H6A H 0.4239 0.0895 1.0663 0.058 Uiso 1 d . .
H6B H 0.4735 0.1095 1.1344 0.058 Uiso 1 d . .
H6C H 0.4079 0.0788 1.1499 0.058 Uiso 1 d . .
C7 C 0.6111(28) 0.1956(15) 1.2267(32) 0.030(13) Uiso 1 d . .
H7A H 0.6418(28) 0.2192(15) 1.2387(32) 0.036 Uiso 1 calc R .
H7B H 0.5777(28) 0.2008(15) 1.1806(32) 0.036 Uiso 1 calc R .
C8 C 0.5613(16) 0.1888(10) 1.2865(15) 0.022(12) Uiso 1 d G .
C9 C 0.4866(17) 0.1744(11) 1.2724(14) 0.038(14) Uiso 1 d G .
H9 H 0.4656(24) 0.1708(16) 1.2226(16) 0.045 Uiso 1 calc R .
C10 C 0.4427(13) 0.1654(10) 1.3311(19) 0.042(15) Uiso 1 d G .
H10 H 0.3917(16) 0.1555(15) 1.3214(26) 0.050 Uiso 1 calc R .
C11 C 0.4735(17) 0.1707(10) 1.4039(16) 0.026(12) Uiso 1 d G .
H11 H 0.4435(23) 0.1645(15) 1.4440(20) 0.031 Uiso 1 calc R .
C12 C 0.5482(18) 0.1851(10) 1.4181(14) 0.057(18) Uiso 1 d G .
H12 H 0.5692(25) 0.1888(15) 1.4678(15) 0.068 Uiso 1 calc R .
C13 C 0.5921(13) 0.1942(9) 1.3594(17) 0.015(10) Uiso 1 d G .
H13 H 0.6431(15) 0.2040(13) 1.3690(24) 0.018 Uiso 1 calc R .
C14 C 0.9685(26) 0.0851(14) 1.1994(30) 0.023(12) Uiso 1 d . .
H14A H 0.9911(26) 0.0737(14) 1.2465(30) 0.027 Uiso 1 calc R .
H14B H 0.9899(26) 0.0713(14) 1.1576(30) 0.027 Uiso 1 calc R .
C15 C 0.9899(19) 0.1282(7) 1.1966(20) 0.029(13) Uiso 1 d G .
C16 C 0.9752(19) 0.1479(9) 1.1300(16) 0.032(13) Uiso 1 d G .
H16 H 0.9525(28) 0.1349(13) 1.0873(20) 0.039 Uiso 1 calc R .
C17 C 0.9936(21) 0.1867(9) 1.1257(17) 0.043(15) Uiso 1 d G .
H17 H 0.9835(31) 0.2002(13) 1.0802(20) 0.051 Uiso 1 calc R .
C18 C 1.0268(22) 0.2058(7) 1.1881(22) 0.052(17) Uiso 1 d G .
H18 H 1.0394(31) 0.2323(8) 1.1852(30) 0.063 Uiso 1 calc R .
C19 C 1.0415(20) 0.1861(9) 1.2548(18) 0.042(15) Uiso 1 d G .
H19 H 1.0642(29) 0.1991(13) 1.2974(22) 0.051 Uiso 1 calc R .
C20 C 1.0231(19) 0.1473(9) 1.2590(16) 0.035(14) Uiso 1 d G .
H20 H 1.0332(29) 0.1338(13) 1.3045(19) 0.042 Uiso 1 calc R .
C21 C 0.5827(28) -0.0044(15) 1.1018(32) 0.032(13) Uiso 1 d . .
H21A H 0.5580(28) -0.0008(15) 1.0508(32) 0.038 Uiso 1 calc R .
H21B H 0.5418(28) -0.0126(15) 1.1336(32) 0.038 Uiso 1 calc R .
C22 C 0.6432(18) -0.0364(8) 1.1004(20) 0.034(13) Uiso 1 d G .
C23 C 0.6495(19) -0.0638(10) 1.1567(17) 0.041(14) Uiso 1 d G .
H23 H 0.6221(28) -0.0605(14) 1.1997(21) 0.049 Uiso 1 calc R .
C24 C 0.6962(20) -0.0960(9) 1.1501(18) 0.043(15) Uiso 1 d G .
H24 H 0.7005(29) -0.1147(12) 1.1885(23) 0.051 Uiso 1 calc R .
C25 C 0.7364(18) -0.1008(8) 1.0872(20) 0.031(13) Uiso 1 d G .
H25 H 0.7682(25) -0.1228(10) 1.0826(28) 0.037 Uiso 1 calc R .
C26 C 0.7300(19) -0.0734(10) 1.0309(17) 0.046(15) Uiso 1 d G .
H26 H 0.7575(27) -0.0766(14) 0.9879(21) 0.055 Uiso 1 calc R .
C27 C 0.6834(19) -0.0412(9) 1.0375(18) 0.035(13) Uiso 1 d G .
H27 H 0.6790(28) -0.0225(12) 0.9991(22) 0.043 Uiso 1 calc R .
Au4 Au -0.16224(11) 0.11459(6) 0.41724(13) 0.0276(5) Uani 1 d . .
N4 N -0.1084(26) 0.1640(14) 0.4531(29) 0.039(12) Uiso 1 d . .
O4 O -0.0050(16) 0.1962(9) 0.5049(18) 0.015(7) Uiso 1 d . .
Au5 Au 0.03141(11) 0.11823(6) 0.45085(12) 0.0253(5) Uani 1 d . .
N5 N 0.0977(21) 0.0731(11) 0.4208(24) 0.021(9) Uiso 1 d . .
O5 O 0.0997(19) 0.0162(10) 0.3593(21) 0.034(9) Uiso 1 d . .
Au6 Au -0.05810(11) 0.03956(7) 0.38558(12) 0.0278(5) Uani 1 d . .
N6 N -0.1769(25) 0.0339(15) 0.3827(28) 0.041(12) Uiso 1 d . .
O6 O -0.2944(21) 0.0620(11) 0.3738(23) 0.043(10) Uiso 1 d . .
C28 C -0.0323(25) 0.1639(13) 0.4715(28) 0.018(11) Uiso 1 d . .
C29 C 0.0516(25) 0.0413(14) 0.3842(28) 0.021(11) Uiso 1 d . .
C30 C -0.2170(34) 0.0690(18) 0.3900(37) 0.045(16) Uiso 1 d . .
C31 C 0.0789(29) 0.1975(15) 0.5202(32) 0.029(13) Uiso 1 d . .
H31A H 0.0935 0.2237 0.5369 0.044 Uiso 1 d . .
H31B H 0.1029 0.1917 0.4746 0.044 Uiso 1 d . .
H31C H 0.0945 0.1791 0.5588 0.044 Uiso 1 d . .
C32 C 0.0608(25) -0.0182(13) 0.3245(28) 0.020(11) Uiso 1 d . .
H32A H 0.1000 -0.0359 0.3082 0.030 Uiso 1 d . .
H32B H 0.0280 -0.0095 0.2794 0.030 Uiso 1 d . .
H32C H 0.0288 -0.0304 0.3584 0.030 Uiso 1 d . .
C33 C -0.3413(23) 0.0927(13) 0.3723(26) 0.013(10) Uiso 1 d . .
H33A H -0.3948 0.0842 0.3611 0.019 Uiso 1 d . .
H33B H -0.3264 0.1105 0.3345 0.019 Uiso 1 d . .
H33C H -0.3359 0.1050 0.4213 0.019 Uiso 1 d . .
C34 C -0.1619(29) 0.1965(16) 0.4722(32) 0.031(13) Uiso 1 d . .
H34A H -0.1316(29) 0.2206(16) 0.4782(32) 0.037 Uiso 1 calc R .
H34B H -0.2022(29) 0.2001(16) 0.4307(32) 0.037 Uiso 1 calc R .
C35 C -0.1986(18) 0.1890(11) 0.5394(16) 0.034(14) Uiso 1 d G .
C36 C -0.2721(19) 0.1727(11) 0.5309(15) 0.041(15) Uiso 1 d G .
H36 H -0.2956(26) 0.1673(16) 0.4826(17) 0.049 Uiso 1 calc R .
C37 C -0.3114(15) 0.1644(10) 0.5931(20) 0.044(16) Uiso 1 d G .
H37 H -0.3617(17) 0.1533(15) 0.5873(27) 0.053 Uiso 1 calc R .
C38 C -0.2770(18) 0.1723(10) 0.6638(17) 0.025(12) Uiso 1 d G .
H38 H -0.3039(25) 0.1666(15) 0.7063(20) 0.031 Uiso 1 calc R .
C39 C -0.2035(18) 0.1886(10) 0.6723(15) 0.045(16) Uiso 1 d G .
H39 H -0.1800(25) 0.1940(15) 0.7206(17) 0.054 Uiso 1 calc R .
C40 C -0.1642(14) 0.1969(10) 0.6101(20) 0.033(13) Uiso 1 d G .
H40 H -0.1139(17) 0.2080(15) 0.6159(27) 0.039 Uiso 1 calc R .
C41 C 0.1830(32) 0.0725(17) 0.4190(38) 0.045(16) Uiso 1 d . .
H41A H 0.1971(32) 0.0619(17) 0.3710(38) 0.054 Uiso 1 calc R .
H41B H 0.2066(32) 0.0560(17) 0.4595(38) 0.054 Uiso 1 calc R .
C42 C 0.2127(18) 0.1136(7) 0.4287(18) 0.024(11) Uiso 1 d G .
C43 C 0.2106(18) 0.1373(9) 0.3666(15) 0.025(12) Uiso 1 d G .
H43 H 0.1899(27) 0.1280(12) 0.3196(17) 0.030 Uiso 1 calc R .
C44 C 0.2390(20) 0.1747(8) 0.3731(17) 0.034(14) Uiso 1 d G .
H44 H 0.2375(29) 0.1909(11) 0.3307(21) 0.041 Uiso 1 calc R .
C45 C 0.2694(21) 0.1883(7) 0.4418(21) 0.040(15) Uiso 1 d G .
H45 H 0.2887(30) 0.2138(9) 0.4463(29) 0.048 Uiso 1 calc R .
C46 C 0.2715(21) 0.1646(10) 0.5040(16) 0.068(21) Uiso 1 d G .
H46 H 0.2923(31) 0.1739(14) 0.5509(19) 0.081 Uiso 1 calc R .
C47 C 0.2431(20) 0.1272(10) 0.4974(15) 0.035(14) Uiso 1 d G .
H47 H 0.2446(29) 0.1110(13) 0.5398(19) 0.043 Uiso 1 calc R .
C48 C -0.2208(37) -0.0028(19) 0.3654(42) 0.059(19) Uiso 1 d . .
H48A H -0.2502(37) -0.0006(19) 0.3162(42) 0.071 Uiso 1 calc R .
H48B H -0.2583(37) -0.0071(19) 0.4031(42) 0.071 Uiso 1 calc R .
C49 C -0.1658(18) -0.0369(8) 0.3650(19) 0.035(14) Uiso 1 d G .
C50 C -0.1611(20) -0.0591(10) 0.3015(16) 0.031(13) Uiso 1 d G .
H50 H -0.1920(27) -0.0528(15) 0.2571(19) 0.037 Uiso 1 calc R .
C51 C -0.1114(23) -0.0905(10) 0.3028(19) 0.077(23) Uiso 1 d G .
H51 H -0.1082(33) -0.1057(14) 0.2594(23) 0.092 Uiso 1 calc R .
C52 C -0.0663(21) -0.0997(9) 0.3677(23) 0.061(20) Uiso 1 d G .
H52 H -0.0322(30) -0.1212(12) 0.3686(32) 0.074 Uiso 1 calc R .
C53 C -0.0709(18) -0.0775(10) 0.4312(18) 0.040(14) Uiso 1 d G .
H53 H -0.0401(26) -0.0838(14) 0.4755(22) 0.048 Uiso 1 calc R .
C54 C -0.1207(19) -0.0461(9) 0.4298(16) 0.024(12) Uiso 1 d G .
H54 H -0.1238(28) -0.0309(13) 0.4732(19) 0.029 Uiso 1 calc R .
Au7 Au 0.08570(11) 0.11635(6) 0.66318(12) 0.0241(5) Uani 1 d . .
O7 O 0.2473(18) 0.1987(10) 0.7486(21) 0.027(8) Uiso 1 d . .
N7 N 0.1408(21) 0.1645(11) 0.7009(23) 0.020(9) Uiso 1 d . .
Au8 Au 0.27855(11) 0.11966(6) 0.69871(12) 0.0234(5) Uani 1 d . .
N8 N 0.3408(22) 0.0718(11) 0.6735(24) 0.024(10) Uiso 1 d . .
O8 O 0.3502(19) 0.0107(10) 0.6375(21) 0.033(9) Uiso 1 d . .
Au9 Au 0.18878(11) 0.03905(6) 0.63909(12) 0.0238(5) Uani 1 d . .
O9 O -0.0488(19) 0.0641(10) 0.6198(21) 0.030(9) Uiso 1 d . .
N9 N 0.0670(25) 0.0356(14) 0.6279(27) 0.040(12) Uiso 1 d . .
C55 C 0.2136(36) 0.1658(19) 0.7130(39) 0.050(17) Uiso 1 d . .
C56 C 0.3008(25) 0.0406(14) 0.6502(28) 0.023(11) Uiso 1 d . .
C57 C 0.0330(27) 0.0670(14) 0.6336(30) 0.024(12) Uiso 1 d . .
C58 C 0.3303(32) 0.2003(17) 0.7595(36) 0.041(15) Uiso 1 d . .
H58A H 0.3491 0.1773 0.7886 0.061 Uiso 1 d . .
H58B H 0.3455 0.2233 0.7895 0.061 Uiso 1 d . .
H58C H 0.3531 0.2010 0.7129 0.061 Uiso 1 d . .
C59 C 0.3029(29) -0.0228(15) 0.6103(33) 0.035(14) Uiso 1 d . .
H59A H 0.2571 -0.0246 0.6390 0.052 Uiso 1 d . .
H59B H 0.3336 -0.0462 0.6168 0.052 Uiso 1 d . .
H59C H 0.2860 -0.0190 0.5578 0.052 Uiso 1 d . .
C60 C -0.0938(27) 0.0959(14) 0.6182(29) 0.023(12) Uiso 1 d . .
H60A H -0.1107 0.1008 0.6682 0.035 Uiso 1 d . .
H60B H -0.1400 0.0918 0.5836 0.035 Uiso 1 d . .
H60C H -0.0651 0.1182 0.6022 0.035 Uiso 1 d . .
C61 C 0.0967(33) 0.1999(18) 0.7210(37) 0.047(17) Uiso 1 d . .
H61A H 0.1334(33) 0.2208(18) 0.7365(37) 0.056 Uiso 1 calc R .
H61B H 0.0631(33) 0.2088(18) 0.6774(37) 0.056 Uiso 1 calc R .
C62 C 0.0485(16) 0.1902(10) 0.7830(16) 0.013(10) Uiso 1 d G .
C63 C -0.0253(16) 0.1741(10) 0.7759(15) 0.024(12) Uiso 1 d G .
H63 H -0.0495(23) 0.1684(14) 0.7280(17) 0.029 Uiso 1 calc R .
C64 C -0.0637(14) 0.1663(10) 0.8389(19) 0.040(15) Uiso 1 d G .
H64 H -0.1141(17) 0.1553(15) 0.8340(26) 0.047 Uiso 1 calc R .
C65 C -0.0283(19) 0.1746(11) 0.9090(16) 0.040(15) Uiso 1 d G .
H65 H -0.0545(26) 0.1693(16) 0.9520(19) 0.048 Uiso 1 calc R .
C66 C 0.0455(19) 0.1907(11) 0.9161(15) 0.044(16) Uiso 1 d G .
H66 H 0.0697(27) 0.1963(16) 0.9640(17) 0.053 Uiso 1 calc R .
C67 C 0.0839(14) 0.1984(11) 0.8531(19) 0.056(18) Uiso 1 d G .
H67 H 0.1343(18) 0.2094(16) 0.8579(26) 0.067 Uiso 1 calc R .
C68 C 0.4283(23) 0.0723(12) 0.6834(26) 0.011(10) Uiso 1 d . .
H68A H 0.4456(23) 0.0598(12) 0.7312(26) 0.013 Uiso 1 calc R .
H68B H 0.4490(23) 0.0572(12) 0.6430(26) 0.013 Uiso 1 calc R .
C69 C 0.4599(17) 0.1116(7) 0.6828(18) 0.015(10) Uiso 1 d G .
C70 C 0.4506(20) 0.1342(9) 0.6192(15) 0.043(16) Uiso 1 d G .
H70 H 0.4262(29) 0.1238(13) 0.5746(18) 0.052 Uiso 1 calc R .
C71 C 0.4769(21) 0.1719(9) 0.6210(17) 0.055(18) Uiso 1 d G .
H71 H 0.4706(31) 0.1874(12) 0.5775(20) 0.066 Uiso 1 calc R .
C72 C 0.5126(19) 0.1871(7) 0.6863(21) 0.025(12) Uiso 1 d G .
H72 H 0.5307(28) 0.2129(8) 0.6875(28) 0.030 Uiso 1 calc R .
C73 C 0.5220(19) 0.1645(9) 0.7500(16) 0.050(17) Uiso 1 d G .
H73 H 0.5464(29) 0.1749(13) 0.7946(20) 0.061 Uiso 1 calc R .
C74 C 0.4956(19) 0.1267(9) 0.7482(15) 0.034(14) Uiso 1 d G .
H74 H 0.5020(28) 0.1113(12) 0.7917(19) 0.041 Uiso 1 calc R .
C75 C 0.0285(24) 0.0008(12) 0.6074(28) 0.016(11) Uiso 1 d . .
H75A H -0.0075(24) 0.0057(12) 0.5629(28) 0.020 Uiso 1 calc R .
H75B H -0.0033(24) -0.0069(12) 0.6481(28) 0.020 Uiso 1 calc R .
C76 C 0.0816(16) -0.0335(8) 0.5904(18) 0.022(11) Uiso 1 d G .
C77 C 0.1028(18) -0.0632(9) 0.6394(15) 0.024(12) Uiso 1 d G .
H77 H 0.0848(27) -0.0634(13) 0.6877(17) 0.029 Uiso 1 calc R .
C78 C 0.1504(19) -0.0927(8) 0.6177(19) 0.042(15) Uiso 1 d G .
H78 H 0.1649(28) -0.1130(11) 0.6512(24) 0.051 Uiso 1 calc R .
C79 C 0.1767(19) -0.0924(9) 0.5470(21) 0.050(17) Uiso 1 d G .
H79 H 0.2093(27) -0.1125(11) 0.5322(28) 0.060 Uiso 1 calc R .
C80 C 0.1555(20) -0.0627(10) 0.4980(16) 0.051(17) Uiso 1 d G .
H80 H 0.1735(29) -0.0625(14) 0.4497(18) 0.061 Uiso 1 calc R .
C81 C 0.1079(18) -0.0332(8) 0.5197(16) 0.027(12) Uiso 1 d G .
H81 H 0.0934(27) -0.0129(11) 0.4862(22) 0.033 Uiso 1 calc R .
Au10 Au 0.34979(11) 0.11516(6) 0.91057(12) 0.0266(5) Uani 1 d . .
O10 O 0.5027(21) 0.1976(11) 1.0050(23) 0.038(10) Uiso 1 d . .
N10 N 0.3970(26) 0.1648(14) 0.9434(28) 0.038(12) Uiso 1 d . .
Au11 Au 0.54160(11) 0.12034(6) 0.95192(12) 0.0247(5) Uani 1 d . .
O11 O 0.6219(21) 0.0124(11) 0.9012(23) 0.042(10) Uiso 1 d . .
N11 N 0.6084(19) 0.0747(10) 0.9348(21) 0.011(8) Uiso 1 d . .
Au12 Au 0.45764(11) 0.03877(7) 0.89244(12) 0.0269(5) Uani 1 d . .
O12 O 0.2211(19) 0.0616(10) 0.8558(21) 0.033(9) Uiso 1 d . .
N12 N 0.3360(25) 0.0348(14) 0.8679(27) 0.039(12) Uiso 1 d . .
C82 C 0.4780(25) 0.1656(13) 0.9706(28) 0.017(11) Uiso 1 d . .
C83 C 0.5756(27) 0.0417(15) 0.9138(30) 0.029(13) Uiso 1 d . .
C84 C 0.2953(24) 0.0657(13) 0.8720(27) 0.014(10) Uiso 1 d . .
C85 C 0.5874(28) 0.2008(15) 1.0195(31) 0.026(12) Uiso 1 d . .
H85A H 0.6012 0.2097 1.0700 0.039 Uiso 1 d . .
H85B H 0.6074 0.2193 0.9840 0.039 Uiso 1 d . .
H85C H 0.6117 0.1756 1.0120 0.039 Uiso 1 d . .
C86 C 0.5823(35) -0.0223(18) 0.8738(38) 0.049(17) Uiso 1 d . .
H86A H 0.6162 -0.0435 0.8821 0.073 Uiso 1 d . .
H86B H 0.5680 -0.0182 0.8203 0.073 Uiso 1 d . .
H86C H 0.5353 -0.0246 0.8998 0.073 Uiso 1 d . .
C87 C 0.1702(28) 0.0961(15) 0.8615(32) 0.031(13) Uiso 1 d . .
H87A H 0.1472 0.0958 0.9086 0.046 Uiso 1 d . .
H87B H 0.1286 0.0953 0.8203 0.046 Uiso 1 d . .
H87C H 0.2009 0.1194 0.8565 0.046 Uiso 1 d . .
C88 C 0.3589(25) 0.1984(13) 0.9652(28) 0.018(11) Uiso 1 d . .
H88A H 0.3263(25) 0.2088(13) 0.9221(28) 0.022 Uiso 1 calc R .
H88B H 0.3979(25) 0.2181(13) 0.9813(28) 0.022 Uiso 1 calc R .
C89 C 0.3043(16) 0.1895(10) 1.0334(16) 0.029(13) Uiso 1 d G .
C90 C 0.2300(16) 0.1743(9) 1.0231(15) 0.016(10) Uiso 1 d G .
H90 H 0.2069(22) 0.1699(14) 0.9742(16) 0.019 Uiso 1 calc R .
C91 C 0.1894(14) 0.1654(10) 1.0842(19) 0.030(13) Uiso 1 d G .
H91 H 0.1386(16) 0.1550(14) 1.0771(26) 0.036 Uiso 1 calc R .
C92 C 0.2232(20) 0.1719(12) 1.1556(16) 0.057(18) Uiso 1 d G .
H92 H 0.1955(27) 0.1658(17) 1.1974(20) 0.069 Uiso 1 calc R .
C93 C 0.2975(20) 0.1871(12) 1.1660(15) 0.060(19) Uiso 1 d G .
H93 H 0.3206(28) 0.1915(17) 1.2148(16) 0.072 Uiso 1 calc R .
C94 C 0.3381(14) 0.1959(10) 1.1049(19) 0.024(12) Uiso 1 d G .
H94 H 0.3889(17) 0.2063(14) 1.1120(26) 0.028 Uiso 1 calc R .
C95 C 0.6950(27) 0.0746(14) 0.9389(31) 0.026(12) Uiso 1 d . .
H95A H 0.7128(27) 0.0619(14) 0.8943(31) 0.031 Uiso 1 calc R .
H95B H 0.7158(27) 0.0600(14) 0.9832(31) 0.031 Uiso 1 calc R .
C96 C 0.7251(17) 0.1163(6) 0.9438(17) 0.013(10) Uiso 1 d G .
C97 C 0.7161(17) 0.1396(8) 0.8810(14) 0.028(13) Uiso 1 d G .
H97 H 0.6939(25) 0.1293(11) 0.8353(16) 0.033 Uiso 1 calc R .
C98 C 0.7395(17) 0.1778(7) 0.8851(15) 0.016(11) Uiso 1 d G .
H98 H 0.7334(25) 0.1937(10) 0.8422(18) 0.019 Uiso 1 calc R .
C99 C 0.7720(18) 0.1928(6) 0.9520(18) 0.026(12) Uiso 1 d G .
H99 H 0.7880(26) 0.2189(7) 0.9548(24) 0.031 Uiso 1 calc R .
C100 C 0.7810(19) 0.1695(9) 1.0148(14) 0.038(14) Uiso 1 d G .
H100 H 0.8031(27) 0.1798(12) 1.0605(17) 0.045 Uiso 1 calc R .
C101 C 0.7575(18) 0.1313(8) 1.0107(14) 0.039(15) Uiso 1 d G .
H101 H 0.7636(27) 0.1154(11) 1.0535(17) 0.047 Uiso 1 calc R .
C102 C 0.3012(35) -0.0033(18) 0.8536(39) 0.050(17) Uiso 1 d . .
H10A H 0.2683(35) -0.0022(18) 0.8061(39) 0.060 Uiso 1 calc R .
H10B H 0.2669(35) -0.0090(18) 0.8935(39) 0.060 Uiso 1 calc R .
C103 C 0.3565(20) -0.0353(9) 0.8496(23) 0.027(12) Uiso 1 d G .
C104 C 0.3628(25) -0.0590(13) 0.9117(20) 0.076(23) Uiso 1 d G .
H104 H 0.3360(36) -0.0528(18) 0.9540(24) 0.091 Uiso 1 calc R .
C105 C 0.4082(27) -0.0920(12) 0.9120(25) 0.070(21) Uiso 1 d G .
H105 H 0.4125(40) -0.1083(17) 0.9545(31) 0.084 Uiso 1 calc R .
C106 C 0.4474(26) -0.1012(11) 0.8502(31) 0.093(29) Uiso 1 d G .
H106 H 0.4785(36) -0.1237(14) 0.8504(43) 0.112 Uiso 1 calc R .
C107 C 0.4411(26) -0.0774(14) 0.7881(25) 0.108(31) Uiso 1 d G .
H107 H 0.4678(38) -0.0837(19) 0.7458(31) 0.129 Uiso 1 calc R .
C108 C 0.3956(23) -0.0445(12) 0.7878(20) 0.047(16) Uiso 1 d G .
H108 H 0.3913(35) -0.0282(16) 0.7453(24) 0.056 Uiso 1 calc R .
Au13 Au 0.33021(11) -0.14361(6) 0.36343(13) 0.0284(5) Uani 1 d . .
O13 O 0.4802(22) -0.2271(12) 0.4518(24) 0.045(11) Uiso 1 d . .
N13 N 0.3806(25) -0.1941(13) 0.4030(27) 0.034(11) Uiso 1 d . .
Au14 Au 0.52224(11) -0.15023(6) 0.40822(13) 0.0263(5) Uani 1 d . .
O14 O 0.6069(19) -0.0416(10) 0.3539(21) 0.034(9) Uiso 1 d . .
N14 N 0.5892(28) -0.1032(15) 0.3877(31) 0.050(14) Uiso 1 d . .
Au15 Au 0.44210(11) -0.06842(7) 0.34784(13) 0.0295(5) Uani 1 d . .
O15 O 0.2054(18) -0.0867(10) 0.3102(21) 0.030(9) Uiso 1 d . .
N15 N 0.3269(26) -0.0612(14) 0.3279(29) 0.044(13) Uiso 1 d . .
C109 C 0.4489(26) -0.1958(14) 0.4256(30) 0.022(12) Uiso 1 d . .
C110 C 0.5580(26) -0.0707(14) 0.3663(29) 0.024(11) Uiso 1 d . .
C111 C 0.2840(25) -0.0938(13) 0.3399(28) 0.017(11) Uiso 1 d . .
C112 C 0.5621(31) -0.2332(17) 0.4666(34) 0.038(15) Uiso 1 d . .
H11A H 0.5883 -0.2249 0.4210 0.057 Uiso 1 d . .
H11B H 0.5733 -0.2599 0.4756 0.057 Uiso 1 d . .
H11C H 0.5825 -0.2171 0.5077 0.057 Uiso 1 d . .
C113 C 0.5691(34) -0.0063(18) 0.3257(38) 0.050(17) Uiso 1 d . .
H11D H 0.6073 0.0102 0.3019 0.075 Uiso 1 d . .
H11E H 0.5484 0.0083 0.3656 0.075 Uiso 1 d . .
H11F H 0.5268 -0.0124 0.2874 0.075 Uiso 1 d . .
C114 C 0.1550(31) -0.1205(16) 0.3160(34) 0.036(14) Uiso 1 d . .
H11G H 0.1314 -0.1275 0.2664 0.055 Uiso 1 d . .
H11H H 0.1127 -0.1138 0.3477 0.055 Uiso 1 d . .
H11I H 0.1843 -0.1419 0.3379 0.055 Uiso 1 d . .
C115 C 0.3337(29) -0.2262(15) 0.4249(32) 0.029(13) Uiso 1 d . .
H11J H 0.3686(29) -0.2477(15) 0.4412(32) 0.035 Uiso 1 calc R .
H11K H 0.3008(29) -0.2351(15) 0.3808(32) 0.035 Uiso 1 calc R .
C116 C 0.2832(18) -0.2175(10) 0.4851(18) 0.022(12) Uiso 1 d G .
C117 C 0.2095(18) -0.2017(11) 0.4731(15) 0.063(20) Uiso 1 d G .
H117 H 0.1878(26) -0.1971(16) 0.4238(16) 0.076 Uiso 1 calc R .
C118 C 0.1676(14) -0.1924(9) 0.5331(19) 0.017(11) Uiso 1 d G .
H118 H 0.1172(16) -0.1816(14) 0.5248(25) 0.021 Uiso 1 calc R .
C119 C 0.1993(18) -0.1991(10) 0.6052(16) 0.028(13) Uiso 1 d G .
H119 H 0.1707(25) -0.1928(15) 0.6462(19) 0.034 Uiso 1 calc R .
C120 C 0.2730(19) -0.2150(12) 0.6173(16) 0.067(21) Uiso 1 d G .
H120 H 0.2947(27) -0.2196(17) 0.6666(17) 0.080 Uiso 1 calc R .
C121 C 0.3149(15) -0.2242(10) 0.5573(21) 0.039(15) Uiso 1 d G .
H121 H 0.3652(17) -0.2350(15) 0.5655(28) 0.047 Uiso 1 calc R .
C122 C 0.6780(26) -0.1071(14) 0.3999(31) 0.026(12) Uiso 1 d . .
H12A H 0.7024(26) -0.0919(14) 0.3617(31) 0.032 Uiso 1 calc R .
H12B H 0.6960(26) -0.0965(14) 0.4492(31) 0.032 Uiso 1 calc R .
C123 C 0.7027(19) -0.1476(7) 0.3957(18) 0.032(13) Uiso 1 d G .
C124 C 0.7344(20) -0.1649(9) 0.4606(15) 0.044(16) Uiso 1 d G .
H124 H 0.7395(29) -0.1507(13) 0.5057(17) 0.053 Uiso 1 calc R .
C125 C 0.7587(20) -0.2030(10) 0.4595(15) 0.035(14) Uiso 1 d G .
H125 H 0.7804(28) -0.2148(13) 0.5039(18) 0.042 Uiso 1 calc R .
C126 C 0.7513(20) -0.2238(7) 0.3935(19) 0.045(16) Uiso 1 d G .
H126 H 0.7679(29) -0.2498(8) 0.3928(26) 0.054 Uiso 1 calc R .
C127 C 0.7196(18) -0.2064(8) 0.3286(15) 0.017(11) Uiso 1 d G .
H127 H 0.7145(26) -0.2206(11) 0.2835(18) 0.021 Uiso 1 calc R .
C128 C 0.6953(17) -0.1683(8) 0.3297(15) 0.019(11) Uiso 1 d G .
H128 H 0.6736(25) -0.1565(11) 0.2853(17) 0.022 Uiso 1 calc R .
C129 C 0.2911(27) -0.0267(14) 0.3143(31) 0.025(12) Uiso 1 d . .
H12C H 0.2411(27) -0.0267(14) 0.3373(31) 0.030 Uiso 1 calc R .
H12D H 0.2796(27) -0.0237(14) 0.2600(31) 0.030 Uiso 1 calc R .
C130 C 0.3372(21) 0.0063(10) 0.3428(23) 0.044(16) Uiso 1 d G .
C131 C 0.3687(23) 0.0343(12) 0.2994(17) 0.064(19) Uiso 1 d G .
H131 H 0.3600(34) 0.0333(17) 0.2468(17) 0.077 Uiso 1 calc R .
C132 C 0.4128(22) 0.0639(10) 0.3331(22) 0.040(15) Uiso 1 d G .
H132 H 0.4343(31) 0.0831(13) 0.3035(29) 0.047 Uiso 1 calc R .
C133 C 0.4255(22) 0.0654(10) 0.4101(23) 0.060(19) Uiso 1 d G .
H133 H 0.4557(32) 0.0856(14) 0.4331(31) 0.072 Uiso 1 calc R .
C134 C 0.3940(24) 0.0373(13) 0.4534(17) 0.068(20) Uiso 1 d G .
H134 H 0.4027(35) 0.0383(18) 0.5060(17) 0.082 Uiso 1 calc R .
C135 C 0.3499(22) 0.0077(11) 0.4198(22) 0.049(17) Uiso 1 d G .
H135 H 0.3284(32) -0.0114(14) 0.4494(29) 0.058 Uiso 1 calc R .
Au16 Au -0.42480(11) -0.14361(6) -0.38579(13) 0.0259(5) Uani 1 d . .
N16 N -0.3803(21) -0.1947(11) -0.3470(23) 0.020(9) Uiso 1 d . .
O16 O -0.2734(22) -0.2290(12) -0.3043(24) 0.043(11) Uiso 1 d . .
Au17 Au -0.23264(11) -0.14976(6) -0.34429(12) 0.0253(5) Uani 1 d . .
O17 O -0.1514(19) -0.0399(10) -0.3822(21) 0.034(9) Uiso 1 d . .
N17 N -0.1665(23) -0.1029(12) -0.3631(25) 0.028(11) Uiso 1 d . .
Au18 Au -0.31480(11) -0.06752(6) -0.39873(13) 0.0275(5) Uani 1 d . .
N18 N -0.4308(18) -0.0644(10) -0.4188(19) 0.006(8) Uiso 1 d . .
O18 O -0.5501(18) -0.0895(10) -0.4399(20) 0.028(8) Uiso 1 d . .
C136 C -0.2975(22) -0.1939(12) -0.3275(26) 0.009(10) Uiso 1 d . .
C137 C -0.1970(22) -0.0704(12) -0.3734(24) 0.009(9) Uiso 1 d . .
C138 C -0.4783(32) -0.0949(17) -0.4182(35) 0.037(15) Uiso 1 d . .
C139 C -0.1919(38) -0.2343(20) -0.2825(41) 0.057(19) Uiso 1 d . .
H13A H -0.1704 -0.2515 -0.3189 0.085 Uiso 1 d . .
H13B H -0.1852 -0.2447 -0.2335 0.085 Uiso 1 d . .
H13C H -0.1664 -0.2090 -0.2850 0.085 Uiso 1 d . .
C140 C -0.1866(29) -0.0036(15) -0.3985(32) 0.032(13) Uiso 1 d . .
H14C H -0.2019 -0.0017 -0.4514 0.048 Uiso 1 d . .
H14D H -0.1493 0.0170 -0.3838 0.048 Uiso 1 d . .
H14E H -0.2322 -0.0007 -0.3700 0.048 Uiso 1 d . .
C141 C -0.5985(34) -0.1236(18) -0.4345(37) 0.046(16) Uiso 1 d . .
H14F H -0.6511 -0.1178 -0.4586 0.068 Uiso 1 d . .
H14G H -0.6026 -0.1300 -0.3829 0.068 Uiso 1 d . .
H14H H -0.5766 -0.1449 -0.4609 0.068 Uiso 1 d . .
C142 C -0.4226(29) -0.2261(15) -0.3318(32) 0.030(13) Uiso 1 d . .
H14I H -0.3878(29) -0.2486(15) -0.3228(32) 0.035 Uiso 1 calc R .
H14J H -0.4599(29) -0.2320(15) -0.3748(32) 0.035 Uiso 1 calc R .
C143 C -0.4664(17) -0.2186(11) -0.2631(16) 0.037(15) Uiso 1 d G .
C144 C -0.5408(17) -0.2033(10) -0.2710(15) 0.029(13) Uiso 1 d G .
H144 H -0.5647(24) -0.1979(15) -0.3191(17) 0.034 Uiso 1 calc R .
C145 C -0.5802(14) -0.1959(10) -0.2085(19) 0.027(12) Uiso 1 d G .
H145 H -0.6310(16) -0.1854(14) -0.2139(26) 0.033 Uiso 1 calc R .
C146 C -0.5452(19) -0.2038(11) -0.1381(16) 0.057(19) Uiso 1 d G .
H146 H -0.5721(26) -0.1987(17) -0.0953(19) 0.069 Uiso 1 calc R .
C147 C -0.4708(19) -0.2191(11) -0.1301(15) 0.035(14) Uiso 1 d G .
H147 H -0.4468(26) -0.2245(15) -0.0820(17) 0.042 Uiso 1 calc R .
C148 C -0.4314(14) -0.2265(10) -0.1927(19) 0.027(12) Uiso 1 d G .
H148 H -0.3805(17) -0.2370(14) -0.1872(26) 0.033 Uiso 1 calc R .
C149 C -0.0742(46) -0.1044(24) -0.3535(53) 0.088(27) Uiso 1 d . .
H14K H -0.0517(46) -0.0899(24) -0.3937(53) 0.106 Uiso 1 calc R .
H14L H -0.0544(46) -0.0934(24) -0.3050(53) 0.106 Uiso 1 calc R .
C150 C -0.0541(19) -0.1469(7) -0.3575(19) 0.031(13) Uiso 1 d G .
C151 C -0.0165(19) -0.1652(9) -0.2962(15) 0.043(15) Uiso 1 d G .
H151 H -0.0086(28) -0.1520(12) -0.2501(17) 0.052 Uiso 1 calc R .
C152 C 0.0094(18) -0.2028(9) -0.3023(16) 0.025(12) Uiso 1 d G .
H152 H 0.0351(26) -0.2153(12) -0.2604(19) 0.031 Uiso 1 calc R .
C153 C -0.0023(19) -0.2222(7) -0.3697(19) 0.043(16) Uiso 1 d G .
H153 H 0.0155(28) -0.2479(8) -0.3739(26) 0.052 Uiso 1 calc R .
C154 C -0.0398(19) -0.2039(8) -0.4310(15) 0.023(12) Uiso 1 d G .
H154 H -0.0478(27) -0.2171(12) -0.4770(18) 0.028 Uiso 1 calc R .
C155 C -0.0658(17) -0.1663(8) -0.4249(15) 0.027(12) Uiso 1 d G .
H155 H -0.0914(25) -0.1538(11) -0.4667(19) 0.033 Uiso 1 calc R .
C156 C -0.4713(32) -0.0245(16) -0.4427(36) 0.041(15) Uiso 1 d . .
H15A H -0.4768(32) -0.0222(16) -0.4975(36) 0.049 Uiso 1 calc R .
H15B H -0.5235(32) -0.0231(16) -0.4242(36) 0.049 Uiso 1 calc R .
C157 C -0.4191(17) 0.0083(8) -0.4083(18) 0.020(11) Uiso 1 d G .
C158 C -0.3835(20) 0.0341(10) -0.4533(15) 0.036(13) Uiso 1 d G .
H158 H -0.3903(29) 0.0316(15) -0.5059(15) 0.044 Uiso 1 calc R .
C159 C -0.3381(21) 0.0637(10) -0.4215(22) 0.059(19) Uiso 1 d G .
H159 H -0.3138(30) 0.0814(13) -0.4523(28) 0.071 Uiso 1 calc R .
C160 C -0.3283(22) 0.0675(10) -0.3447(23) 0.071(22) Uiso 1 d G .
H160 H -0.2972(30) 0.0877(13) -0.3229(30) 0.085 Uiso 1 calc R .
C161 C -0.3638(22) 0.0416(11) -0.2996(16) 0.052(16) Uiso 1 d G .
H161 H -0.3571(31) 0.0441(16) -0.2471(16) 0.063 Uiso 1 calc R .
C162 C -0.4092(19) 0.0120(10) -0.3314(17) 0.035(14) Uiso 1 d G .
H162 H -0.4335(27) -0.0057(13) -0.3006(23) 0.042 Uiso 1 calc R .
Au19 Au -0.16067(11) -0.14095(6) -0.13774(13) 0.0275(5) Uani 1 d . .
O19 O -0.0142(20) -0.2263(11) -0.0433(22) 0.036(10) Uiso 1 d . .
N19 N -0.1129(25) -0.1925(13) -0.0996(27) 0.036(12) Uiso 1 d . .
Au20 Au 0.03051(11) -0.14858(6) -0.09898(12) 0.0261(5) Uani 1 d . .
O20 O 0.1218(19) -0.0430(10) -0.1578(21) 0.030(9) Uiso 1 d . .
N20 N 0.1018(23) -0.1023(12) -0.1244(26) 0.029(11) Uiso 1 d . .
Au21 Au -0.04690(11) -0.06574(7) -0.15503(13) 0.0272(5) Uani 1 d . .
N21 N -0.1643(21) -0.0615(11) -0.1654(24) 0.023(10) Uiso 1 d . .
O21 O -0.2824(22) -0.0821(12) -0.1829(25) 0.050(11) Uiso 1 d . .
C163 C -0.0327(32) -0.1924(17) -0.0790(36) 0.040(15) Uiso 1 d . .
C164 C 0.0649(26) -0.0726(15) -0.1500(29) 0.026(12) Uiso 1 d . .
C165 C -0.2029(31) -0.0919(17) -0.1620(35) 0.037(14) Uiso 1 d . .
C166 C 0.0701(24) -0.2312(13) -0.0318(27) 0.015(11) Uiso 1 d . .
H16A H 0.0904 -0.2382 -0.0780 0.022 Uiso 1 d . .
H16B H 0.0816 -0.2506 0.0063 0.022 Uiso 1 d . .
H16C H 0.0926 -0.2062 -0.0141 0.022 Uiso 1 d . .
C167 C 0.0813(35) -0.0039(19) -0.1783(39) 0.050(17) Uiso 1 d . .
H16D H 0.1204 0.0159 -0.1823 0.075 Uiso 1 d . .
H16E H 0.0458 0.0026 -0.1422 0.075 Uiso 1 d . .
H16F H 0.0521 -0.0070 -0.2282 0.075 Uiso 1 d . .
C168 C -0.3374(25) -0.1170(13) -0.1837(28) 0.018(11) Uiso 1 d . .
H16G H -0.3825 -0.1125 -0.2198 0.026 Uiso 1 d . .
H16H H -0.3560 -0.1206 -0.1342 0.026 Uiso 1 d . .
H16I H -0.3105 -0.1403 -0.1979 0.026 Uiso 1 d . .
C169 C -0.1645(26) -0.2223(14) -0.0764(29) 0.023(12) Uiso 1 d . .
H16J H -0.1985(26) -0.2299(14) -0.1207(29) 0.028 Uiso 1 calc R .
H16K H -0.1321(26) -0.2449(14) -0.0616(29) 0.028 Uiso 1 calc R .
C170 C -0.2131(18) -0.2151(11) -0.0180(18) 0.026(12) Uiso 1 d G .
C171 C -0.2869(19) -0.1993(11) -0.0296(17) 0.046(16) Uiso 1 d G .
H171 H -0.3079(28) -0.1935(17) -0.0786(19) 0.056 Uiso 1 calc R .
C172 C -0.3300(16) -0.1921(11) 0.0306(22) 0.057(18) Uiso 1 d G .
H172 H -0.3804(19) -0.1813(16) 0.0227(30) 0.068 Uiso 1 calc R .
C173 C -0.2992(20) -0.2006(12) 0.1023(19) 0.035(14) Uiso 1 d G .
H173 H -0.3287(28) -0.1957(17) 0.1434(23) 0.042 Uiso 1 calc R .
C174 C -0.2254(22) -0.2164(12) 0.1138(17) 0.072(22) Uiso 1 d G .
H174 H -0.2044(30) -0.2222(18) 0.1628(19) 0.087 Uiso 1 calc R .
C175 C -0.1823(16) -0.2236(11) 0.0537(22) 0.047(16) Uiso 1 d G .
H175 H -0.1319(19) -0.2344(16) 0.0615(30) 0.056 Uiso 1 calc R .
C176 C 0.1863(25) -0.1073(13) -0.1151(29) 0.020(11) Uiso 1 d . .
H17A H 0.2089(25) -0.0951(13) -0.1579(29) 0.024 Uiso 1 calc R .
H17B H 0.2063(25) -0.0932(13) -0.0698(29) 0.024 Uiso 1 calc R .
C177 C 0.2145(19) -0.1469(7) -0.1089(19) 0.022(11) Uiso 1 d G .
C178 C 0.2478(20) -0.1621(9) -0.0426(16) 0.035(14) Uiso 1 d G .
H178 H 0.2559(29) -0.1462(13) 0.0001(20) 0.042 Uiso 1 calc R .
C179 C 0.2692(21) -0.2006(10) -0.0388(18) 0.050(17) Uiso 1 d G .
H179 H 0.2919(31) -0.2111(14) 0.0065(22) 0.060 Uiso 1 calc R .
C180 C 0.2573(22) -0.2239(8) -0.1013(23) 0.048(17) Uiso 1 d G .
H180 H 0.2720(32) -0.2503(8) -0.0987(32) 0.057 Uiso 1 calc R .
C181 C 0.2241(23) -0.2087(10) -0.1676(19) 0.055(18) Uiso 1 d G .
H181 H 0.2160(33) -0.2246(13) -0.2103(23) 0.066 Uiso 1 calc R .
C182 C 0.2027(21) -0.1701(10) -0.1714(16) 0.046(16) Uiso 1 d G .
H182 H 0.1800(30) -0.1597(14) -0.2168(19) 0.055 Uiso 1 calc R .
C183 C -0.2089(35) -0.0206(18) -0.1808(40) 0.051(17) Uiso 1 d . .
H18A H -0.2232(35) -0.0170(18) -0.2346(40) 0.061 Uiso 1 calc R .
H18B H -0.2566(35) -0.0195(18) -0.1541(40) 0.061 Uiso 1 calc R .
C184 C -0.1510(17) 0.0103(8) -0.1516(18) 0.033(13) Uiso 1 d G .
C185 C -0.1128(19) 0.0347(10) -0.1975(14) 0.031(12) Uiso 1 d G .
H185 H -0.1214(28) 0.0324(15) -0.2499(14) 0.037 Uiso 1 calc R .
C186 C -0.0621(18) 0.0625(9) -0.1665(18) 0.050(17) Uiso 1 d G .
H186 H -0.0360(26) 0.0791(13) -0.1978(24) 0.060 Uiso 1 calc R .
C187 C -0.0497(18) 0.0658(9) -0.0897(19) 0.027(12) Uiso 1 d G .
H187 H -0.0150(25) 0.0848(12) -0.0685(26) 0.032 Uiso 1 calc R .
C188 C -0.0879(20) 0.0414(11) -0.0439(14) 0.069(20) Uiso 1 d G .
H188 H -0.0793(29) 0.0437(15) 0.0086(14) 0.083 Uiso 1 calc R .
C189 C -0.1386(18) 0.0136(9) -0.0748(17) 0.025(12) Uiso 1 d G .
H189 H -0.1647(27) -0.0031(13) -0.0435(23) 0.030 Uiso 1 calc R .
Au22 Au 0.10488(12) -0.13958(6) 0.11157(13) 0.0281(5) Uani 1 d . .
O22 O 0.2390(17) -0.2300(9) 0.2020(19) 0.020(8) Uiso 1 d . .
N22 N 0.1439(29) -0.1914(15) 0.1529(31) 0.049(14) Uiso 1 d . .
Au23 Au 0.29279(11) -0.15245(6) 0.15949(13) 0.0263(5) Uani 1 d . .
N23 N 0.3710(24) -0.1098(12) 0.1418(26) 0.030(11) Uiso 1 d . .
O23 O 0.3945(19) -0.0478(10) 0.1143(21) 0.031(9) Uiso 1 d . .
Au24 Au 0.22856(11) -0.06785(6) 0.09676(13) 0.0305(5) Uani 1 d . .
O24 O -0.0070(21) -0.0807(11) 0.0477(22) 0.041(10) Uiso 1 d . .
N24 N 0.1143(20) -0.0615(10) 0.0686(22) 0.016(9) Uiso 1 d . .
C190 C 0.2225(26) -0.1971(14) 0.1751(29) 0.020(11) Uiso 1 d . .
C191 C 0.3402(27) -0.0754(15) 0.1223(30) 0.027(12) Uiso 1 d . .
C192 C 0.0664(22) -0.0899(12) 0.0784(25) 0.010(10) Uiso 1 d . .
C193 C 0.3218(33) -0.2369(18) 0.2236(37) 0.044(16) Uiso 1 d . .
H19A H 0.3485 -0.2424 0.1798 0.066 Uiso 1 d . .
H19B H 0.3269 -0.2581 0.2588 0.066 Uiso 1 d . .
H19C H 0.3437 -0.2133 0.2479 0.066 Uiso 1 d . .
C194 C 0.3674(34) -0.0113(18) 0.0976(38) 0.048(17) Uiso 1 d . .
H19D H 0.3883 -0.0017 0.0526 0.072 Uiso 1 d . .
H19E H 0.3816 0.0063 0.1391 0.072 Uiso 1 d . .
H19F H 0.3098 -0.0118 0.0894 0.072 Uiso 1 d . .
C195 C -0.0678(37) -0.1150(20) 0.0536(40) 0.054(18) Uiso 1 d . .
H19G H -0.1173 -0.1079 0.0253 0.081 Uiso 1 d . .
H19H H -0.0786 -0.1181 0.1065 0.081 Uiso 1 d . .
H19I H -0.0482 -0.1385 0.0350 0.081 Uiso 1 d . .
C196 C 0.0920(30) -0.2253(16) 0.1646(34) 0.036(14) Uiso 1 d . .
H19J H 0.1232(30) -0.2484(16) 0.1787(34) 0.043 Uiso 1 calc R .
H19K H 0.0587(30) -0.2310(16) 0.1187(34) 0.043 Uiso 1 calc R .
C197 C 0.0407(18) -0.2133(11) 0.2298(16) 0.031(13) Uiso 1 d G .
C198 C -0.0337(18) -0.1985(10) 0.2158(15) 0.042(15) Uiso 1 d G .
H198 H -0.0534(25) -0.1930(15) 0.1662(16) 0.050 Uiso 1 calc R .
C199 C -0.0795(14) -0.1918(10) 0.2743(19) 0.032(13) Uiso 1 d G .
H199 H -0.1303(16) -0.1818(15) 0.2647(25) 0.039 Uiso 1 calc R .
C200 C -0.0508(16) -0.1999(10) 0.3468(16) 0.042(15) Uiso 1 d G .
H200 H -0.0820(22) -0.1954(15) 0.3867(20) 0.050 Uiso 1 calc R .
C201 C 0.0236(17) -0.2147(9) 0.3608(15) 0.016(11) Uiso 1 d G .
H201 H 0.0432(23) -0.2202(14) 0.4104(16) 0.019 Uiso 1 calc R .
C202 C 0.0693(14) -0.2213(10) 0.3023(19) 0.041(15) Uiso 1 d G .
H202 H 0.1202(16) -0.2314(14) 0.3119(25) 0.050 Uiso 1 calc R .
C203 C 0.4553(29) -0.1161(15) 0.1581(33) 0.032(13) Uiso 1 d . .
H20A H 0.4839(29) -0.1008(15) 0.1231(33) 0.039 Uiso 1 calc R .
H20B H 0.4710(29) -0.1070(15) 0.2091(33) 0.039 Uiso 1 calc R .
C204 C 0.4760(21) -0.1568(7) 0.1519(21) 0.039(15) Uiso 1 d G .
C205 C 0.4626(19) -0.1766(8) 0.0851(17) 0.037(14) Uiso 1 d G .
H205 H 0.4421(28) -0.1634(11) 0.0418(20) 0.044 Uiso 1 calc R .
C206 C 0.4792(18) -0.2156(8) 0.0818(14) 0.025(12) Uiso 1 d G .
H206 H 0.4701(27) -0.2291(11) 0.0361(16) 0.030 Uiso 1 calc R .
C207 C 0.5092(17) -0.2349(6) 0.1452(17) 0.009(9) Uiso 1 d G .
H207 H 0.5206(25) -0.2616(7) 0.1429(24) 0.011 Uiso 1 calc R .
C208 C 0.5226(19) -0.2152(9) 0.2120(14) 0.038(14) Uiso 1 d G .
H208 H 0.5431(27) -0.2284(12) 0.2553(17) 0.045 Uiso 1 calc R .
C209 C 0.5060(21) -0.1761(9) 0.2153(16) 0.054(18) Uiso 1 d G .
H209 H 0.5151(31) -0.1626(13) 0.2610(19) 0.064 Uiso 1 calc R .
C210 C 0.0812(29) -0.0237(15) 0.0398(33) 0.034(14) Uiso 1 d . .
H21C H 0.0271(29) -0.0209(15) 0.0531(33) 0.041 Uiso 1 calc R .
H21D H 0.0810(29) -0.0228(15) -0.0151(33) 0.041 Uiso 1 calc R .
C211 C 0.1321(17) 0.0097(8) 0.0750(19) 0.029(13) Uiso 1 d G .
C212 C 0.1775(18) 0.0337(10) 0.0349(16) 0.020(11) Uiso 1 d G .
H212 H 0.1795(28) 0.0300(14) -0.0170(16) 0.024 Uiso 1 calc R .
C213 C 0.2200(19) 0.0632(10) 0.0709(22) 0.067(21) Uiso 1 d G .
H213 H 0.2511(28) 0.0796(13) 0.0435(29) 0.081 Uiso 1 calc R .
C214 C 0.2171(23) 0.0687(10) 0.1469(22) 0.061(19) Uiso 1 d G .
H214 H 0.2462(32) 0.0888(14) 0.1714(30) 0.074 Uiso 1 calc R .
C215 C 0.1716(24) 0.0447(12) 0.1869(16) 0.068(21) Uiso 1 d G .
H215 H 0.1696(35) 0.0484(17) 0.2389(17) 0.081 Uiso 1 calc R .
C216 C 0.1291(21) 0.0152(11) 0.1510(19) 0.051(17) Uiso 1 d G .
H216 H 0.0981(30) -0.0012(15) 0.1784(25) 0.062 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C3 Au1 N1 173.9(21) . . ?
C3 Au1 Au2 120.5(13) . . ?
N1 Au1 Au2 59.2(13) . . ?
C3 Au1 Au3 60.3(13) . . ?
N1 Au1 Au3 119.6(13) . . ?
Au2 Au1 Au3 60.38(6) . . ?
C1 O1 C4 115.2(38) . . ?
C1 N1 C7 120.2(44) . . ?
C1 N1 Au1 121.0(35) . . ?
C7 N1 Au1 118.4(32) . . ?
O1 C1 N1 114.9(43) . . ?
O1 C1 Au2 127.8(35) . . ?
N1 C1 Au2 117.3(35) . . ?
C1 Au2 N2 177.1(18) . . ?
C1 Au2 Au1 62.4(14) . . ?
N2 Au2 Au1 118.8(10) . . ?
C1 Au2 Au3 122.6(14) . . ?
N2 Au2 Au3 58.8(10) . . ?
Au1 Au2 Au3 60.29(6) . . ?
C2 N2 C14 113.4(41) . . ?
C2 N2 Au2 124.3(36) . . ?
C14 N2 Au2 122.1(27) . . ?
C2 O2 C5 120.0(42) . . ?
N2 C2 O2 119.6(50) . . ?
N2 C2 Au3 117.8(42) . . ?
O2 C2 Au3 122.1(40) . . ?
C2 Au3 N3 174.6(21) . . ?
C2 Au3 Au1 118.1(18) . . ?
N3 Au3 Au1 59.1(11) . . ?
C2 Au3 Au2 59.1(18) . . ?
N3 Au3 Au2 118.4(11) . . ?
Au1 Au3 Au2 59.33(6) . . ?
C3 N3 C21 133.7(37) . . ?
C3 N3 Au3 107.7(28) . . ?
C21 N3 Au3 118.6(29) . . ?
C6 O3 C3 111.5(39) . . ?
N3 C3 O3 92.7(34) . . ?
N3 C3 Au1 132.5(31) . . ?
O3 C3 Au1 132.8(31) . . ?
C8 C7 N1 116.5(43) . . ?
C9 C8 C13 120.0 . . ?
C9 C8 C7 121.4(29) . . ?
C13 C8 C7 118.4(30) . . ?
C8 C9 C10 120.0 . . ?
C11 C10 C9 120.0 . . ?
C10 C11 C12 120.0 . . ?
C13 C12 C11 120.0 . . ?
C12 C13 C8 120.0 . . ?
C15 C14 N2 109.6(35) . . ?
C16 C15 C20 120.0 . . ?
C16 C15 C14 118.6(30) . . ?
C20 C15 C14 121.4(29) . . ?
C15 C16 C17 120.0 . . ?
C16 C17 C18 120.0 . . ?
C19 C18 C17 120.0 . . ?
C18 C19 C20 120.0 . . ?
C19 C20 C15 120.0 . . ?
N3 C21 C22 114.2(37) . . ?
C23 C22 C27 120.0 . . ?
C23 C22 C21 120.0(30) . . ?
C27 C22 C21 119.3(30) . . ?
C24 C23 C22 120.0 . . ?
C23 C24 C25 120.0 . . ?
C26 C25 C24 120.0 . . ?
C25 C26 C27 120.0 . . ?
C26 C27 C22 120.0 . . ?
C30 Au4 N4 175.6(24) . . ?
C30 Au4 Au6 63.5(18) . . ?
N4 Au4 Au6 119.2(13) . . ?
C30 Au4 Au5 123.3(18) . . ?
N4 Au4 Au5 59.1(13) . . ?
Au6 Au4 Au5 60.13(6) . . ?
C28 N4 C34 123.7(45) . . ?
C28 N4 Au4 119.6(35) . . ?
C34 N4 Au4 115.4(33) . . ?
C28 O4 C31 114.8(35) . . ?
C28 Au5 N5 175.2(19) . . ?
C28 Au5 Au6 118.4(13) . . ?
N5 Au5 Au6 61.8(11) . . ?
C28 Au5 Au4 60.2(13) . . ?
N5 Au5 Au4 119.8(11) . . ?
Au6 Au5 Au4 58.27(6) . . ?
C41 N5 C29 118.7(39) . . ?
C41 N5 Au5 126.8(32) . . ?
C29 N5 Au5 113.4(27) . . ?
C29 O5 C32 113.6(35) . . ?
C29 Au6 N6 175.8(20) . . ?
C29 Au6 Au4 123.1(15) . . ?
N6 Au6 Au4 60.9(14) . . ?
C29 Au6 Au5 62.6(15) . . ?
N6 Au6 Au5 121.6(14) . . ?
Au4 Au6 Au5 61.61(7) . . ?
C30 N6 C48 120.5(44) . . ?
C30 N6 Au6 114.3(38) . . ?
C48 N6 Au6 124.8(38) . . ?
C33 O6 C30 116.3(42) . . ?
N4 C28 O4 114.5(41) . . ?
N4 C28 Au5 120.6(36) . . ?
O4 C28 Au5 124.9(31) . . ?
O5 C29 N5 108.3(36) . . ?
O5 C29 Au6 130.3(36) . . ?
N5 C29 Au6 121.2(32) . . ?
O6 C30 N6 107.8(49) . . ?
O6 C30 Au4 131.7(44) . . ?
N6 C30 Au4 120.5(41) . . ?
C35 C34 N4 112.1(43) . . ?
C36 C35 C40 120.0 . . ?
C36 C35 C34 116.5(31) . . ?
C40 C35 C34 123.5(31) . . ?
C35 C36 C37 120.0 . . ?
C38 C37 C36 120.0 . . ?
C37 C38 C39 120.0 . . ?
C38 C39 C40 120.0 . . ?
C39 C40 C35 120.0 . . ?
N5 C41 C42 108.3(41) . . ?
C43 C42 C47 120.0 . . ?
C43 C42 C41 118.5(33) . . ?
C47 C42 C41 121.4(33) . . ?
C42 C43 C44 120.0 . . ?
C45 C44 C43 120.0 . . ?
C44 C45 C46 120.0 . . ?
C47 C46 C45 120.0 . . ?
C46 C47 C42 120.0 . . ?
N6 C48 C49 110.9(45) . . ?
C50 C49 C54 120.0 . . ?
C50 C49 C48 121.1(35) . . ?
C54 C49 C48 118.9(35) . . ?
C51 C50 C49 120.0 . . ?
C50 C51 C52 120.0 . . ?
C53 C52 C51 120.0 . . ?
C52 C53 C54 120.0 . . ?
C53 C54 C49 120.0 . . ?
C57 Au7 N7 175.6(20) . . ?
C57 Au7 Au9 60.1(14) . . ?
N7 Au7 Au9 118.5(11) . . ?
C57 Au7 Au8 120.5(14) . . ?
N7 Au7 Au8 58.0(10) . . ?
Au9 Au7 Au8 60.53(6) . . ?
C55 O7 C58 117.7(42) . . ?
C55 N7 C61 116.6(47) . . ?
C55 N7 Au7 121.8(39) . . ?
C61 N7 Au7 121.5(31) . . ?
C55 Au8 N8 174.4(24) . . ?
C55 Au8 Au9 117.8(19) . . ?
N8 Au8 Au9 59.1(11) . . ?
C55 Au8 Au7 59.1(19) . . ?
N8 Au8 Au7 117.5(11) . . ?
Au9 Au8 Au7 58.62(6) . . ?
C56 N8 C68 122.4(38) . . ?
C56 N8 Au8 117.4(30) . . ?
C68 N8 Au8 120.2(28) . . ?
C56 O8 C59 108.3(35) . . ?
C56 Au9 N9 178.3(20) . . ?
C56 Au9 Au7 121.1(15) . . ?
N9 Au9 Au7 60.4(14) . . ?
C56 Au9 Au8 60.5(15) . . ?
N9 Au9 Au8 120.9(14) . . ?
Au7 Au9 Au8 60.85(6) . . ?
C60 O9 C57 120.7(38) . . ?
C57 N9 C75 123.6(42) . . ?
C57 N9 Au9 114.8(37) . . ?
C75 N9 Au9 121.3(33) . . ?
N7 C55 O7 118.5(53) . . ?
N7 C55 Au8 121.1(47) . . ?
O7 C55 Au8 119.7(40) . . ?
N8 C56 O8 110.6(37) . . ?
N8 C56 Au9 123.0(35) . . ?
O8 C56 Au9 126.4(34) . . ?
N9 C57 O9 113.2(44) . . ?
N9 C57 Au7 124.4(38) . . ?
O9 C57 Au7 122.3(33) . . ?
C62 C61 N7 108.8(44) . . ?
C63 C62 C67 120.0 . . ?
C63 C62 C61 126.1(32) . . ?
C67 C62 C61 113.9(32) . . ?
C62 C63 C64 120.0 . . ?
C65 C64 C63 120.0 . . ?
C64 C65 C66 120.0 . . ?
C65 C66 C67 120.0 . . ?
C66 C67 C62 120.0 . . ?
C69 C68 N8 112.4(32) . . ?
C70 C69 C74 120.0 . . ?
C70 C69 C68 120.9(28) . . ?
C74 C69 C68 119.0(28) . . ?
C69 C70 C71 120.0 . . ?
C70 C71 C72 120.0 . . ?
C73 C72 C71 120.0 . . ?
C74 C73 C72 120.0 . . ?
C73 C74 C69 120.0 . . ?
N9 C75 C76 115.8(35) . . ?
C77 C76 C81 120.0 . . ?
C77 C76 C75 125.1(27) . . ?
C81 C76 C75 114.9(27) . . ?
C78 C77 C76 120.0 . . ?
C77 C78 C79 120.0 . . ?
C80 C79 C78 120.0 . . ?
C79 C80 C81 120.0 . . ?
C80 C81 C76 120.0 . . ?
N10 Au10 C84 176.1(18) . . ?
N10 Au10 Au12 120.8(13) . . ?
C84 Au10 Au12 62.5(12) . . ?
N10 Au10 Au11 60.6(13) . . ?
C84 Au10 Au11 122.7(12) . . ?
Au12 Au10 Au11 60.22(6) . . ?
C82 O10 C85 115.2(37) . . ?
C88 N10 C82 110.6(42) . . ?
C88 N10 Au10 127.8(33) . . ?
C82 N10 Au10 118.9(33) . . ?
C82 Au11 N11 178.6(18) . . ?
C82 Au11 Au12 120.2(13) . . ?
N11 Au11 Au12 61.1(10) . . ?
C82 Au11 Au10 61.5(13) . . ?
N11 Au11 Au10 119.8(10) . . ?
Au12 Au11 Au10 58.85(6) . . ?
C83 O11 C86 114.9(41) . . ?
C83 N11 C95 114.7(37) . . ?
C83 N11 Au11 119.5(30) . . ?
C95 N11 Au11 125.7(27) . . ?
C83 Au12 N12 178.5(19) . . ?
C83 Au12 Au10 120.5(15) . . ?
N12 Au12 Au10 60.7(13) . . ?
C83 Au12 Au11 59.6(15) . . ?
N12 Au12 Au11 121.6(14) . . ?
Au10 Au12 Au11 60.93(7) . . ?
C84 O12 C87 118.2(37) . . ?
C84 N12 C102 122.8(42) . . ?
C84 N12 Au12 118.1(35) . . ?
C102 N12 Au12 118.8(36) . . ?
O10 C82 N10 116.2(40) . . ?
O10 C82 Au11 125.9(32) . . ?
N10 C82 Au11 117.8(33) . . ?
N11 C83 O11 117.7(41) . . ?
N11 C83 Au12 119.7(35) . . ?
O11 C83 Au12 122.4(37) . . ?
N12 C84 O12 115.5(42) . . ?
N12 C84 Au10 118.6(33) . . ?
O12 C84 Au10 125.8(32) . . ?
N10 C88 C89 111.4(37) . . ?
C90 C89 C94 120.0 . . ?
C90 C89 C88 123.7(25) . . ?
C94 C89 C88 116.2(25) . . ?
C89 C90 C91 120.0 . . ?
C92 C91 C90 120.0 . . ?
C91 C92 C93 120.0 . . ?
C92 C93 C94 120.0 . . ?
C93 C94 C89 120.0 . . ?
N11 C95 C96 109.5(34) . . ?
C97 C96 C101 120.0 . . ?
C97 C96 C95 119.1(28) . . ?
C101 C96 C95 120.8(28) . . ?
C98 C97 C96 120.0 . . ?
C99 C98 C97 120.0 . . ?
C98 C99 C100 120.0 . . ?
C101 C100 C99 120.0 . . ?
C100 C101 C96 120.0 . . ?
N12 C102 C103 115.5(46) . . ?
C104 C103 C108 120.0 . . ?
C104 C103 C102 114.7(38) . . ?
C108 C103 C102 125.1(38) . . ?
C105 C104 C103 120.0 . . ?
C104 C105 C106 120.0 . . ?
C107 C106 C105 120.0 . . ?
C106 C107 C108 120.0 . . ?
C107 C108 C103 120.0 . . ?
C111 Au13 N13 172.3(20) . . ?
C111 Au13 Au15 60.4(13) . . ?
N13 Au13 Au15 118.2(12) . . ?
C111 Au13 Au14 119.7(13) . . ?
N13 Au13 Au14 58.5(12) . . ?
Au15 Au13 Au14 59.74(6) . . ?
C109 O13 C112 124.9(44) . . ?
C109 N13 C115 114.7(47) . . ?
C109 N13 Au13 122.0(38) . . ?
C115 N13 Au13 121.2(33) . . ?
N14 Au14 C109 176.4(20) . . ?
N14 Au14 Au15 59.0(14) . . ?
C109 Au14 Au15 117.6(13) . . ?
N14 Au14 Au13 117.6(14) . . ?
C109 Au14 Au13 58.9(13) . . ?
Au15 Au14 Au13 58.86(6) . . ?
C110 O14 C113 114.7(38) . . ?
C110 N14 C122 120.4(45) . . ?
C110 N14 Au14 121.3(37) . . ?
C122 N14 Au14 118.3(34) . . ?
C110 Au15 N15 175.1(20) . . ?
C110 Au15 Au13 122.9(14) . . ?
N15 Au15 Au13 62.0(14) . . ?
C110 Au15 Au14 61.7(14) . . ?
N15 Au15 Au14 123.2(14) . . ?
Au13 Au15 Au14 61.40(7) . . ?
C111 O15 C114 112.6(37) . . ?
C129 N15 C111 120.5(42) . . ?
C129 N15 Au15 124.8(36) . . ?
C111 N15 Au15 114.1(34) . . ?
N13 C109 O13 122.1(48) . . ?
N13 C109 Au14 120.0(39) . . ?
O13 C109 Au14 117.3(34) . . ?
N14 C110 O14 116.8(42) . . ?
N14 C110 Au15 118.0(38) . . ?
O14 C110 Au15 125.0(35) . . ?
N15 C111 O15 107.7(39) . . ?
N15 C111 Au13 123.3(33) . . ?
O15 C111 Au13 126.4(31) . . ?
N13 C115 C116 114.8(42) . . ?
C117 C116 C121 120.0 . . ?
C117 C116 C115 123.7(31) . . ?
C121 C116 C115 116.2(31) . . ?
C116 C117 C118 120.0 . . ?
C117 C118 C119 120.0 . . ?
C120 C119 C118 120.0 . . ?
C119 C120 C121 120.0 . . ?
C120 C121 C116 120.0 . . ?
C123 C122 N14 111.6(38) . . ?
C124 C123 C128 120.0 . . ?
C124 C123 C122 117.8(30) . . ?
C128 C123 C122 122.2(30) . . ?
C125 C124 C123 120.0 . . ?
C126 C125 C124 120.0 . . ?
C125 C126 C127 120.0 . . ?
C126 C127 C128 120.0 . . ?
C127 C128 C123 120.0 . . ?
N15 C129 C130 113.5(42) . . ?
C131 C130 C135 120.0 . . ?
C131 C130 C129 125.4(35) . . ?
C135 C130 C129 114.6(35) . . ?
C130 C131 C132 120.0 . . ?
C133 C132 C131 120.0 . . ?
C132 C133 C134 120.0 . . ?
C135 C134 C133 120.0 . . ?
C134 C135 C130 120.0 . . ?
C138 Au16 N16 174.0(20) . . ?
C138 Au16 Au18 63.4(16) . . ?
N16 Au16 Au18 121.5(10) . . ?
C138 Au16 Au17 123.2(16) . . ?
N16 Au16 Au17 61.8(10) . . ?
Au18 Au16 Au17 59.77(6) . . ?
C142 N16 C136 120.3(39) . . ?
C142 N16 Au16 125.2(32) . . ?
C136 N16 Au16 114.1(27) . . ?
C136 O16 C139 118.1(42) . . ?
C136 Au17 N17 178.8(17) . . ?
C136 Au17 Au18 119.4(12) . . ?
N17 Au17 Au18 59.5(11) . . ?
C136 Au17 Au16 60.7(12) . . ?
N17 Au17 Au16 118.2(11) . . ?
Au18 Au17 Au16 58.96(6) . . ?
C137 O17 C140 118.7(35) . . ?
C137 N17 C149 116.9(45) . . ?
C137 N17 Au17 120.7(31) . . ?
C149 N17 Au17 121.8(38) . . ?
N18 Au18 C137 177.5(16) . . ?
N18 Au18 Au16 58.7(9) . . ?
C137 Au18 Au16 121.1(12) . . ?
N18 Au18 Au17 119.9(9) . . ?
C137 Au18 Au17 59.8(12) . . ?
Au16 Au18 Au17 61.28(7) . . ?
C138 N18 C156 115.6(37) . . ?
C138 N18 Au18 123.9(31) . . ?
C156 N18 Au18 120.3(27) . . ?
C138 O18 C141 114.2(43) . . ?
O16 C136 N16 109.6(35) . . ?
O16 C136 Au17 126.7(30) . . ?
N16 C136 Au17 123.3(30) . . ?
N17 C137 O17 119.0(36) . . ?
N17 C137 Au18 118.3(31) . . ?
O17 C137 Au18 121.3(30) . . ?
O18 C138 N18 117.5(48) . . ?
O18 C138 Au16 128.7(41) . . ?
N18 C138 Au16 113.8(36) . . ?
N16 C142 C143 109.8(42) . . ?
C144 C143 C148 120.0 . . ?
C144 C143 C142 120.0(29) . . ?
C148 C143 C142 120.0(29) . . ?
C145 C144 C143 120.0 . . ?
C144 C145 C146 120.0 . . ?
C147 C146 C145 120.0 . . ?
C148 C147 C146 120.0 . . ?
C147 C148 C143 120.0 . . ?
C150 C149 N17 105.0(53) . . ?
C151 C150 C155 120.0 . . ?
C151 C150 C149 120.0(41) . . ?
C155 C150 C149 119.6(41) . . ?
C152 C151 C150 120.0 . . ?
C151 C152 C153 120.0 . . ?
C154 C153 C152 120.0 . . ?
C155 C154 C153 120.0 . . ?
C154 C155 C150 120.0 . . ?
C157 C156 N18 107.5(38) . . ?
C158 C157 C162 120.0 . . ?
C158 C157 C156 120.8(32) . . ?
C162 C157 C156 119.2(32) . . ?
C157 C158 C159 120.0 . . ?
C160 C159 C158 120.0 . . ?
C159 C160 C161 120.0 . . ?
C160 C161 C162 120.0 . . ?
C161 C162 C157 120.0 . . ?
C165 Au19 N19 173.9(23) . . ?
C165 Au19 Au21 59.1(16) . . ?
N19 Au19 Au21 119.5(12) . . ?
C165 Au19 Au20 118.5(16) . . ?
N19 Au19 Au20 59.9(12) . . ?
Au21 Au19 Au20 59.59(6) . . ?
C163 O19 C166 110.9(39) . . ?
C163 N19 C169 122.9(46) . . ?
C163 N19 Au19 116.4(36) . . ?
C169 N19 Au19 118.4(32) . . ?
C163 Au20 N20 177.4(22) . . ?
C163 Au20 Au21 121.6(17) . . ?
N20 Au20 Au21 59.7(11) . . ?
C163 Au20 Au19 62.1(17) . . ?
N20 Au20 Au19 118.9(11) . . ?
Au21 Au20 Au19 59.71(6) . . ?
C164 O20 C167 110.4(36) . . ?
C164 N20 C176 126.9(42) . . ?
C164 N20 Au20 114.3(32) . . ?
C176 N20 Au20 118.8(30) . . ?
C164 Au21 N21 176.1(19) . . ?
C164 Au21 Au20 60.0(15) . . ?
N21 Au21 Au20 118.0(11) . . ?
C164 Au21 Au19 119.8(15) . . ?
N21 Au21 Au19 57.8(11) . . ?
Au20 Au21 Au19 60.69(7) . . ?
C165 N21 C183 119.7(41) . . ?
C165 N21 Au21 117.9(35) . . ?
C183 N21 Au21 122.4(30) . . ?
C165 O21 C168 113.1(39) . . ?
O19 C163 N19 108.0(45) . . ?
O19 C163 Au20 130.8(40) . . ?
N19 C163 Au20 121.1(41) . . ?
N20 C164 O20 106.6(38) . . ?
N20 C164 Au21 125.6(38) . . ?
O20 C164 Au21 126.4(34) . . ?
N21 C165 O21 106.9(47) . . ?
N21 C165 Au19 124.9(40) . . ?
O21 C165 Au19 128.1(40) . . ?
C170 C169 N19 120.2(42) . . ?
C171 C170 C175 120.0 . . ?
C171 C170 C169 123.4(32) . . ?
C175 C170 C169 116.6(32) . . ?
C172 C171 C170 120.0 . . ?
C173 C172 C171 120.0 . . ?
C172 C173 C174 120.0 . . ?
C175 C174 C173 120.0 . . ?
C174 C175 C170 120.0 . . ?
C177 C176 N20 116.4(37) . . ?
C178 C177 C182 120.0 . . ?
C178 C177 C176 122.4(31) . . ?
C182 C177 C176 117.4(31) . . ?
C179 C178 C177 120.0 . . ?
C180 C179 C178 120.0 . . ?
C179 C180 C181 120.0 . . ?
C182 C181 C180 120.0 . . ?
C181 C182 C177 120.0 . . ?
C184 C183 N21 105.4(40) . . ?
C185 C184 C189 120.0 . . ?
C185 C184 C183 123.6(34) . . ?
C189 C184 C183 116.4(34) . . ?
C186 C185 C184 120.0 . . ?
C187 C186 C185 120.0 . . ?
C188 C187 C186 120.0 . . ?
C189 C188 C187 120.0 . . ?
C188 C189 C184 120.0 . . ?
C192 Au22 N22 176.6(20) . . ?
C192 Au22 Au24 60.6(11) . . ?
N22 Au22 Au24 119.8(14) . . ?
C192 Au22 Au23 120.4(11) . . ?
N22 Au22 Au23 60.0(14) . . ?
Au24 Au22 Au23 59.83(7) . . ?
C190 O22 C193 115.6(38) . . ?
C190 N22 C196 115.2(46) . . ?
C190 N22 Au22 120.9(37) . . ?
C196 N22 Au22 123.9(36) . . ?
C190 Au23 N23 175.6(18) . . ?
C190 Au23 Au24 123.0(13) . . ?
N23 Au23 Au24 60.8(12) . . ?
C190 Au23 Au22 63.2(13) . . ?
N23 Au23 Au22 120.4(12) . . ?
Au24 Au23 Au22 59.86(6) . . ?
C191 N23 C203 123.2(42) . . ?
C191 N23 Au23 115.5(32) . . ?
C203 N23 Au23 121.0(32) . . ?
C191 O23 C194 116.5(41) . . ?
C191 Au24 N24 178.3(18) . . ?
C191 Au24 Au23 60.4(15) . . ?
N24 Au24 Au23 118.6(10) . . ?
C191 Au24 Au22 120.7(15) . . ?
N24 Au24 Au22 58.3(10) . . ?
Au23 Au24 Au22 60.31(7) . . ?
C192 O24 C195 112.9(39) . . ?
C192 N24 C210 118.4(35) . . ?
C192 N24 Au24 120.2(29) . . ?
C210 N24 Au24 121.3(28) . . ?
O22 C190 N22 114.9(42) . . ?
O22 C190 Au23 129.2(33) . . ?
N22 C190 Au23 115.9(36) . . ?
N23 C191 O23 113.0(41) . . ?
N23 C191 Au24 122.8(36) . . ?
O23 C191 Au24 123.8(36) . . ?
N24 C192 O24 110.1(37) . . ?
N24 C192 Au22 120.7(29) . . ?
O24 C192 Au22 127.9(30) . . ?
N22 C196 C197 105.9(42) . . ?
C198 C197 C202 120.0 . . ?
C198 C197 C196 121.9(29) . . ?
C202 C197 C196 117.8(29) . . ?
C199 C198 C197 120.0 . . ?
C198 C199 C200 120.0 . . ?
C201 C200 C199 120.0 . . ?
C200 C201 C202 120.0 . . ?
C201 C202 C197 120.0 . . ?
C204 C203 N23 111.7(41) . . ?
C205 C204 C209 120.0 . . ?
C205 C204 C203 121.3(33) . . ?
C209 C204 C203 118.7(33) . . ?
C204 C205 C206 120.0 . . ?
C207 C206 C205 120.0 . . ?
C206 C207 C208 120.0 . . ?
C209 C208 C207 120.0 . . ?
C208 C209 C204 120.0 . . ?
N24 C210 C211 108.8(37) . . ?
C212 C211 C216 120.0 . . ?
C212 C211 C210 124.0(31) . . ?
C216 C211 C210 116.0(31) . . ?
C211 C212 C213 120.0 . . ?
C214 C213 C212 120.0 . . ?
C213 C214 C215 120.0 . . ?
C216 C215 C214 120.0 . . ?
C215 C216 C211 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C3 1.78(4) . ?
Au1 N1 2.01(5) . ?
Au1 Au2 3.301(3) . ?
Au1 Au3 3.333(3) . ?
O1 C1 1.24(6) . ?
O1 C4 1.47(5) . ?
N1 C1 1.37(6) . ?
N1 C7 1.48(7) . ?
C1 Au2 1.95(5) . ?
Au2 N2 1.98(4) . ?
Au2 Au3 3.336(3) . ?
N2 C2 1.26(7) . ?
N2 C14 1.55(6) . ?
O2 C2 1.37(7) . ?
O2 C5 1.48(7) . ?
C2 Au3 2.05(6) . ?
Au3 N3 2.16(4) . ?
N3 C3 1.38(6) . ?
N3 C21 1.51(6) . ?
O3 C6 1.42(7) . ?
O3 C3 1.49(6) . ?
C7 C8 1.46(6) . ?
C8 C9 1.39 . ?
C8 C13 1.39 . ?
C9 C10 1.39 . ?
C10 C11 1.39 . ?
C11 C12 1.39 . ?
C12 C13 1.39 . ?
C14 C15 1.54(5) . ?
C15 C16 1.39 . ?
C15 C20 1.39 . ?
C16 C17 1.39 . ?
C17 C18 1.39 . ?
C18 C19 1.39 . ?
C19 C20 1.39 . ?
C21 C22 1.53(5) . ?
C22 C23 1.39 . ?
C22 C27 1.39 . ?
C23 C24 1.39 . ?
C24 C25 1.39 . ?
C25 C26 1.39 . ?
C26 C27 1.39 . ?
Au4 C30 1.89(6) . ?
Au4 N4 2.03(5) . ?
Au4 Au6 3.248(3) . ?
Au4 Au5 3.360(3) . ?
N4 C28 1.33(6) . ?
N4 C34 1.52(7) . ?
O4 C28 1.34(6) . ?
O4 C31 1.46(6) . ?
Au5 C28 1.99(5) . ?
Au5 N5 2.04(4) . ?
Au5 Au6 3.311(3) . ?
N5 C41 1.48(7) . ?
N5 C29 1.48(6) . ?
O5 C29 1.31(6) . ?
O5 C32 1.49(6) . ?
Au6 C29 1.90(4) . ?
Au6 N6 2.06(4) . ?
N6 C30 1.41(8) . ?
N6 C48 1.51(8) . ?
O6 C33 1.34(6) . ?
O6 C30 1.37(7) . ?
C34 C35 1.44(6) . ?
C35 C36 1.39 . ?
C35 C40 1.39 . ?
C36 C37 1.39 . ?
C37 C38 1.39 . ?
C38 C39 1.39 . ?
C39 C40 1.39 . ?
C41 C42 1.52(6) . ?
C42 C43 1.39 . ?
C42 C47 1.39 . ?
C43 C44 1.39 . ?
C44 C45 1.39 . ?
C45 C46 1.39 . ?
C46 C47 1.39 . ?
C48 C49 1.52(7) . ?
C49 C50 1.39 . ?
C49 C54 1.39 . ?
C50 C51 1.39 . ?
C51 C52 1.39 . ?
C52 C53 1.39 . ?
C53 C54 1.39 . ?
Au7 C57 1.99(5) . ?
Au7 N7 2.02(4) . ?
Au7 Au9 3.274(3) . ?
Au7 Au8 3.349(3) . ?
O7 C55 1.41(7) . ?
O7 C58 1.43(6) . ?
N7 C55 1.26(7) . ?
N7 C61 1.51(7) . ?
Au8 C55 1.99(7) . ?
Au8 N8 2.05(4) . ?
Au8 Au9 3.339(3) . ?
N8 C56 1.33(6) . ?
N8 C68 1.51(5) . ?
O8 C56 1.38(6) . ?
O8 C59 1.48(6) . ?
Au9 C56 1.93(4) . ?
Au9 N9 2.10(4) . ?
O9 C60 1.35(6) . ?
O9 C57 1.42(6) . ?
N9 C57 1.25(7) . ?
N9 C75 1.42(6) . ?
C61 C62 1.49(6) . ?
C62 C63 1.39 . ?
C62 C67 1.39 . ?
C63 C64 1.39 . ?
C64 C65 1.39 . ?
C65 C66 1.39 . ?
C66 C67 1.39 . ?
C68 C69 1.47(5) . ?
C69 C70 1.39 . ?
C69 C74 1.39 . ?
C70 C71 1.39 . ?
C71 C72 1.39 . ?
C72 C73 1.39 . ?
C73 C74 1.39 . ?
C75 C76 1.55(5) . ?
C76 C77 1.39 . ?
C76 C81 1.39 . ?
C77 C78 1.39 . ?
C78 C79 1.39 . ?
C79 C80 1.39 . ?
C80 C81 1.39 . ?
Au10 N10 1.98(5) . ?
Au10 C84 2.06(5) . ?
Au10 Au12 3.278(3) . ?
Au10 Au11 3.348(3) . ?
O10 C82 1.33(6) . ?
O10 C85 1.47(6) . ?
N10 C88 1.41(6) . ?
N10 C82 1.45(6) . ?
Au11 C82 1.97(5) . ?
Au11 N11 2.00(3) . ?
Au11 Au12 3.324(3) . ?
O11 C83 1.33(6) . ?
O11 C86 1.45(7) . ?
N11 C83 1.32(6) . ?
N11 C95 1.50(6) . ?
Au12 C83 2.05(5) . ?
Au12 N12 2.12(4) . ?
O12 C84 1.30(5) . ?
O12 C87 1.50(6) . ?
N12 C84 1.29(6) . ?
N12 C102 1.47(8) . ?
C88 C89 1.64(5) . ?
C89 C90 1.39 . ?
C89 C94 1.39 . ?
C90 C91 1.39 . ?
C91 C92 1.39 . ?
C92 C93 1.39 . ?
C93 C94 1.39 . ?
C95 C96 1.54(5) . ?
C96 C97 1.39 . ?
C96 C101 1.39 . ?
C97 C98 1.39 . ?
C98 C99 1.39 . ?
C99 C100 1.39 . ?
C100 C101 1.39 . ?
C102 C103 1.47(7) . ?
C103 C104 1.39 . ?
C103 C108 1.39 . ?
C104 C105 1.39 . ?
C105 C106 1.39 . ?
C106 C107 1.39 . ?
C107 C108 1.39 . ?
Au13 C111 1.94(5) . ?
Au13 N13 2.06(5) . ?
Au13 Au15 3.279(3) . ?
Au13 Au14 3.363(3) . ?
O13 C109 1.29(6) . ?
O13 C112 1.44(6) . ?
N13 C109 1.22(6) . ?
N13 C115 1.45(7) . ?
Au14 N14 2.06(5) . ?
Au14 C109 2.07(5) . ?
Au14 Au15 3.309(3) . ?
O14 C110 1.35(6) . ?
O14 C113 1.46(7) . ?
N14 C110 1.30(7) . ?
N14 C122 1.54(7) . ?
Au15 C110 2.01(4) . ?
Au15 N15 2.01(5) . ?
O15 C111 1.44(5) . ?
O15 C114 1.47(6) . ?
N15 C129 1.36(7) . ?
N15 C111 1.38(6) . ?
C115 C116 1.48(6) . ?
C116 C117 1.39 . ?
C116 C121 1.39 . ?
C117 C118 1.39 . ?
C118 C119 1.39 . ?
C119 C120 1.39 . ?
C120 C121 1.39 . ?
C122 C123 1.47(5) . ?
C123 C124 1.39 . ?
C123 C128 1.39 . ?
C124 C125 1.39 . ?
C125 C126 1.39 . ?
C126 C127 1.39 . ?
C127 C128 1.39 . ?
C129 C130 1.47(5) . ?
C130 C131 1.39 . ?
C130 C135 1.39 . ?
C131 C132 1.39 . ?
C132 C133 1.39 . ?
C133 C134 1.39 . ?
C134 C135 1.39 . ?
Au16 C138 2.00(6) . ?
Au16 N16 2.04(4) . ?
Au16 Au18 3.279(3) . ?
Au16 Au17 3.356(3) . ?
N16 C142 1.36(6) . ?
N16 C136 1.45(5) . ?
O16 C136 1.34(6) . ?
O16 C139 1.44(7) . ?
Au17 C136 1.94(4) . ?
Au17 N17 2.04(4) . ?
Au17 Au18 3.306(3) . ?
O17 C137 1.34(5) . ?
O17 C140 1.42(6) . ?
N17 C137 1.25(6) . ?
N17 C149 1.59(9) . ?
Au18 N18 2.01(3) . ?
Au18 C137 2.06(4) . ?
N18 C138 1.34(6) . ?
N18 C156 1.60(6) . ?
O18 C138 1.28(6) . ?
O18 C141 1.46(7) . ?
C142 C143 1.53(6) . ?
C143 C144 1.39 . ?
C143 C148 1.39 . ?
C144 C145 1.39 . ?
C145 C146 1.39 . ?
C146 C147 1.39 . ?
C147 C148 1.39 . ?
C149 C150 1.52(8) . ?
C150 C151 1.39 . ?
C150 C155 1.39 . ?
C151 C152 1.39 . ?
C152 C153 1.39 . ?
C153 C154 1.39 . ?
C154 C155 1.39 . ?
C156 C157 1.55(6) . ?
C157 C158 1.39 . ?
C157 C162 1.39 . ?
C158 C159 1.39 . ?
C159 C160 1.39 . ?
C160 C161 1.39 . ?
C161 C162 1.39 . ?
Au19 C165 1.89(6) . ?
Au19 N19 2.07(5) . ?
Au19 Au21 3.304(3) . ?
Au19 Au20 3.336(3) . ?
O19 C163 1.37(7) . ?
O19 C166 1.47(5) . ?
N19 C163 1.41(7) . ?
N19 C169 1.45(6) . ?
Au20 C163 1.93(6) . ?
Au20 N20 2.10(4) . ?
Au20 Au21 3.300(3) . ?
O20 C164 1.44(6) . ?
O20 C167 1.56(7) . ?
N20 C164 1.28(6) . ?
N20 C176 1.47(6) . ?
Au21 C164 1.94(5) . ?
Au21 N21 2.03(4) . ?
N21 C165 1.26(7) . ?
N21 C183 1.63(7) . ?
O21 C165 1.44(6) . ?
O21 C168 1.54(6) . ?
C169 C170 1.42(6) . ?
C170 C171 1.39 . ?
C170 C175 1.39 . ?
C171 C172 1.39 . ?
C172 C173 1.39 . ?
C173 C174 1.39 . ?
C174 C175 1.39 . ?
C176 C177 1.46(5) . ?
C177 C178 1.39 . ?
C177 C182 1.39 . ?
C178 C179 1.39 . ?
C179 C180 1.39 . ?
C180 C181 1.39 . ?
C181 C182 1.39 . ?
C183 C184 1.53(6) . ?
C184 C185 1.39 . ?
C184 C189 1.39 . ?
C185 C186 1.39 . ?
C186 C187 1.39 . ?
C187 C188 1.39 . ?
C188 C189 1.39 . ?
Au22 C192 1.93(4) . ?
Au22 N22 2.04(5) . ?
Au22 Au24 3.312(3) . ?
Au22 Au23 3.326(3) . ?
O22 C190 1.26(6) . ?
O22 C193 1.47(6) . ?
N22 C190 1.40(7) . ?
N22 C196 1.51(7) . ?
Au23 C190 2.01(5) . ?
Au23 N23 2.05(4) . ?
Au23 Au24 3.310(3) . ?
N23 C191 1.35(6) . ?
N23 C203 1.48(6) . ?
O23 C191 1.36(6) . ?
O23 C194 1.38(7) . ?
Au24 C191 1.97(5) . ?
Au24 N24 2.01(3) . ?
O24 C192 1.38(5) . ?
O24 C195 1.60(7) . ?
N24 C192 1.31(5) . ?
N24 C210 1.51(6) . ?
C196 C197 1.59(6) . ?
C197 C198 1.39 . ?
C197 C202 1.39 . ?
C198 C199 1.39 . ?
C199 C200 1.39 . ?
C200 C201 1.39 . ?
C201 C202 1.39 . ?
C203 C204 1.47(6) . ?
C204 C205 1.39 . ?
C204 C209 1.39 . ?
C205 C206 1.39 . ?
C206 C207 1.39 . ?
C207 C208 1.39 . ?
C208 C209 1.39 . ?
C210 C211 1.56(6) . ?
C211 C212 1.39 . ?
C211 C216 1.39 . ?
C212 C213 1.39 . ?
C213 C214 1.39 . ?
C214 C215 1.39 . ?
C215 C216 1.39 . ?
