#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:24:39 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179326 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/23/4322390.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4322390
loop_
_publ_author_name
'Lutz H. Gade'
'Stefan Friedrich'
'Dominique J. M. Trösch'
'Ian J. Scowen'
'Mary McPartlin'
_publ_section_title
;
 Heterodi- and Heterotrinuclear Complexes Containing Highly Polar
 Metal-Metal Bonds
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5295
_journal_page_last               5307
_journal_paper_doi               10.1021/ic990350q
_journal_volume                  38
_journal_year                    1999
_chemical_formula_sum            'C25 H37 N3 O4 Ru2 Si2 Zr'
_chemical_formula_weight         793.12
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.720(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.8252(9)
_cell_length_b                   13.0511(9)
_cell_length_c                   23.089(2)
_cell_measurement_temperature    571(2)
_cell_volume                     3245.8(5)
_computing_cell_refinement       XSCANS
_computing_data_collection       XSCANS
_computing_data_reduction        XSCANS
_computing_molecular_graphics    SHELXTL/SCHAKAL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      571(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Siemens P4'
_diffrn_measurement_method       theta/2theta
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0212
_diffrn_reflns_av_sigmaI/netI    0.0325
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -1
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            7239
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.77
_diffrn_standards_decay_%        0.1
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.339
_exptl_absorpt_correction_T_max  0.30025
_exptl_absorpt_correction_T_min  0.23282
_exptl_absorpt_correction_type   psi-scans
_exptl_crystal_density_diffrn    1.623
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1584
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.38
_refine_diff_density_max         0.542
_refine_diff_density_min         -0.388
_refine_diff_density_rms         0.083
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     328
_refine_ls_number_reflns         5660
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0529
_refine_ls_R_factor_gt           0.0335
_refine_ls_shift/su_max          0.167
_refine_ls_shift/su_mean         0.035
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0343P)²+4.6990P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0764
_refine_ls_wR_factor_ref         0.0848
_reflns_number_gt                4424
_reflns_number_total             5660
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic990350q_4.cif
_cod_data_source_block           sm027
_cod_original_cell_volume        3245.8(4)
_cod_database_code               4322390
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zr Zr 0.26667(4) 0.21110(3) 0.382872(18) 0.03287(11) Uani 1 1 d . A .
Ru1 Ru 0.14434(4) 0.02531(3) 0.344009(17) 0.04274(11) Uani 1 1 d . . .
Ru2 Ru 0.19539(3) 0.52315(3) 0.397202(17) 0.04051(11) Uani 1 1 d . . .
Si1 Si 0.23182(14) 0.19906(11) 0.52746(6) 0.0482(3) Uani 1 1 d . . .
C1 C 0.2109(7) 0.0697(5) 0.5600(3) 0.086(2) Uani 1 1 d . . .
H1A H 0.1854 0.0217 0.5297 0.129 Uiso 1 1 calc R . .
H1B H 0.1486 0.0735 0.5868 0.129 Uiso 1 1 calc R . .
H1C H 0.2880 0.0476 0.5803 0.129 Uiso 1 1 calc R . .
C2 C 0.0773(5) 0.2509(5) 0.4989(2) 0.0663(15) Uani 1 1 d . . .
H2A H 0.0248 0.2549 0.5300 0.099 Uiso 1 1 calc R . .
H2B H 0.0400 0.2065 0.4690 0.099 Uiso 1 1 calc R . .
H2C H 0.0874 0.3181 0.4831 0.099 Uiso 1 1 calc R . .
C3 C 0.3006(6) 0.2846(5) 0.5871(2) 0.0757(18) Uani 1 1 d . . .
H3A H 0.2427 0.2928 0.6157 0.114 Uiso 1 1 calc R . .
H3B H 0.3186 0.3503 0.5713 0.114 Uiso 1 1 calc R . .
H3C H 0.3759 0.2546 0.6051 0.114 Uiso 1 1 calc R . .
N1 N 0.3246(3) 0.1929(3) 0.47025(16) 0.0410(9) Uani 1 1 d . . .
C7 C 0.4538(4) 0.1599(4) 0.4881(2) 0.0518(13) Uani 1 1 d . . .
H7A H 0.4542 0.0860 0.4926 0.062 Uiso 1 1 calc R . .
H7B H 0.4793 0.1892 0.5261 0.062 Uiso 1 1 calc R . .
C8 C 0.5499(4) 0.1883(5) 0.4474(2) 0.0601(14) Uani 1 1 d . . .
H8A H 0.5575 0.2623 0.4470 0.072 Uiso 1 1 calc R . .
H8B H 0.6294 0.1608 0.4633 0.072 Uiso 1 1 calc R . .
C9 C 0.5249(5) 0.1522(5) 0.3855(2) 0.0604(14) Uani 1 1 d . . .
H9A H 0.6023 0.1521 0.3677 0.072 Uiso 1 1 calc R . .
H9B H 0.4949 0.0821 0.3856 0.072 Uiso 1 1 calc R . .
N2 N 0.4326(3) 0.2161(3) 0.34944(16) 0.0452(9) Uani 1 1 d . . .
Si2 Si 0.48853(14) 0.27815(13) 0.29103(7) 0.0567(4) Uani 1 1 d . . .
C4 C 0.5397(7) 0.1821(6) 0.2387(3) 0.091(2) Uani 1 1 d . . .
H4A H 0.5739 0.2169 0.2073 0.137 Uiso 1 1 calc R . .
H4B H 0.4699 0.1416 0.2235 0.137 Uiso 1 1 calc R . .
H4C H 0.6017 0.1383 0.2583 0.137 Uiso 1 1 calc R . .
C5 C 0.3641(6) 0.3578(5) 0.2525(3) 0.0803(19) Uani 1 1 d . . .
H5A H 0.2915 0.3166 0.2431 0.120 Uiso 1 1 calc R . .
H5B H 0.3922 0.3845 0.2173 0.120 Uiso 1 1 calc R . .
H5C H 0.3445 0.4136 0.2771 0.120 Uiso 1 1 calc R . .
C6 C 0.6224(6) 0.3622(6) 0.3176(3) 0.100(2) Uani 1 1 d . . .
H6A H 0.6428 0.4060 0.2866 0.150 Uiso 1 1 calc R . .
H6B H 0.6928 0.3204 0.3304 0.150 Uiso 1 1 calc R . .
H6C H 0.6002 0.4032 0.3495 0.150 Uiso 1 1 calc R . .
N30 N 0.1249(3) 0.3138(3) 0.34141(16) 0.0420(9) Uani 1 1 d . . .
C30 C 0.1935(4) 0.3714(3) 0.37592(19) 0.0357(10) Uani 1 1 d . A .
C31 C 0.0169(5) 0.3407(4) 0.3008(3) 0.0686(17) Uani 1 1 d . A .
H31A H -0.0116 0.2809 0.2792 0.103 Uiso 1 1 calc R . .
H31B H 0.0400 0.3925 0.2744 0.103 Uiso 1 1 calc R . .
H31C H -0.0482 0.3661 0.3222 0.103 Uiso 1 1 calc R .. .
C20 C 0.0262(5) 0.5145(4) 0.4060(3) 0.0633(15) Uani 1 1 d . A .
O20 O -0.0766(4) 0.5093(4) 0.4122(2) 0.1031(17) Uani 1 1 d . . .
C21 C 0.1618(5) 0.5648(4) 0.3200(3) 0.0581(14) Uani 1 1 d . A .
O21 O 0.1459(4) 0.5956(4) 0.27355(19) 0.0879(15) Uani 1 1 d . . .
C22 C 0.2766(9) 0.5402(9) 0.4919(4) 0.056(2) Uiso 0.70 1 d P A 1
C23 C 0.2616(8) 0.6424(7) 0.4670(5) 0.054(2) Uiso 0.70 1 d P A 1
C24 C 0.3396(9) 0.6505(7) 0.4199(4) 0.0484(19) Uiso 0.70 1 d P A 1
C25 C 0.4032(7) 0.5536(9) 0.4151(4) 0.049(2) Uiso 0.70 1 d P A 1
C26 C 0.3649(9) 0.4873(6) 0.4617(5) 0.0453(19) Uiso 0.70 1 d P A 1
C22A C 0.3092(18) 0.5064(13) 0.4853(7) 0.047(5) Uiso 0.30 1 d PG A 2
C23A C 0.2569(13) 0.6032(18) 0.4831(7) 0.056(5) Uiso 0.30 1 d PG A 2
C24A C 0.3048(16) 0.6571(10) 0.4388(9) 0.039(4) Uiso 0.30 1 d PG A 2
C25A C 0.3868(15) 0.5936(15) 0.4137(6) 0.057(6) Uiso 0.30 1 d PG A 2
C26A C 0.3895(13) 0.5005(13) 0.4424(8) 0.036(4) Uiso 0.30 1 d PG A 2
C10 C 0.0020(5) 0.0973(4) 0.3576(2) 0.0526(12) Uani 1 1 d . . .
O10 O -0.0885(4) 0.1381(3) 0.3657(2) 0.0774(12) Uani 1 1 d . . .
C11 C 0.1514(5) 0.0932(4) 0.2748(2) 0.0559(13) Uani 1 1 d . . .
O11 O 0.1538(5) 0.1334(4) 0.22990(18) 0.0894(14) Uani 1 1 d . . .
C12 C 0.1103(6) -0.1458(4) 0.3619(3) 0.0645(16) Uani 1 1 d . . .
C13 C 0.2055(5) -0.1396(4) 0.3245(3) 0.0622(15) Uani 1 1 d . . .
C14 C 0.3087(5) -0.0851(4) 0.3547(3) 0.0612(15) Uani 1 1 d . . .
C15 C 0.2770(5) -0.0586(4) 0.4114(3) 0.0623(15) Uani 1 1 d . . .
C16 C 0.1525(6) -0.0943(4) 0.4159(3) 0.0642(15) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zr Zr -2.9673 0.5597 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Zr N1 100.47(15) . . ?
N2 Zr N30 115.08(15) . . ?
N1 Zr N30 129.05(15) . . ?
N2 Zr C30 105.28(16) . . ?
N1 Zr C30 104.40(15) . . ?
N30 Zr C30 33.57(14) . . ?
N2 Zr Ru1 107.93(12) . . ?
N1 Zr Ru1 107.11(11) . . ?
N30 Zr Ru1 95.71(10) . . ?
C30 Zr Ru1 128.31(11) . . ?
C11 Ru1 C10 90.6(2) . . ?
C11 Ru1 C16 164.8(2) . . ?
C10 Ru1 C16 101.3(2) . . ?
C11 Ru1 C14 107.4(2) . . ?
C10 Ru1 C14 162.0(2) . . ?
C16 Ru1 C14 61.0(2) . . ?
C11 Ru1 C15 138.2(2) . . ?
C10 Ru1 C15 127.0(2) . . ?
C16 Ru1 C15 36.8(2) . . ?
C14 Ru1 C15 36.4(2) . . ?
C11 Ru1 C12 130.1(2) . . ?
C10 Ru1 C12 108.0(2) . . ?
C16 Ru1 C12 36.9(2) . . ?
C14 Ru1 C12 60.4(2) . . ?
C15 Ru1 C12 61.0(2) . . ?
C11 Ru1 C13 104.0(2) . . ?
C10 Ru1 C13 139.7(2) . . ?
C16 Ru1 C13 60.8(2) . . ?
C14 Ru1 C13 36.66(19) . . ?
C15 Ru1 C13 60.9(2) . . ?
C12 Ru1 C13 35.6(2) . . ?
C11 Ru1 Zr 78.80(16) . . ?
C10 Ru1 Zr 83.35(16) . . ?
C16 Ru1 Zr 111.67(15) . . ?
C14 Ru1 Zr 99.74(14) . . ?
C15 Ru1 Zr 87.29(14) . . ?
C12 Ru1 Zr 147.19(15) . . ?
C13 Ru1 Zr 135.85(14) . . ?
C21 Ru2 C20 91.2(3) . . ?
C21 Ru2 C30 93.2(2) . . ?
C20 Ru2 C30 88.9(2) . . ?
C21 Ru2 C25A 97.5(4) . . ?
C20 Ru2 C25A 153.9(5) . . ?
C30 Ru2 C25A 115.0(6) . . ?
C21 Ru2 C24A 102.9(5) . . ?
C20 Ru2 C24A 118.5(5) . . ?
C30 Ru2 C24A 147.3(4) . . ?
C25A Ru2 C24A 35.5(3) . . ?
C21 Ru2 C26A 124.1(6) . . ?
C20 Ru2 C26A 144.6(6) . . ?
C30 Ru2 C26A 88.3(4) . . ?
C25A Ru2 C26A 35.5(3) . . ?
C24A Ru2 C26A 59.1(4) . . ?
C21 Ru2 C23A 135.2(6) . . ?
C20 Ru2 C23A 97.9(4) . . ?
C30 Ru2 C23A 130.5(6) . . ?
C25A Ru2 C23A 59.0(4) . . ?
C24A Ru2 C23A 35.4(3) . . ?
C26A Ru2 C23A 58.9(4) . . ?
C21 Ru2 C22A 156.5(4) . . ?
C20 Ru2 C22A 110.3(6) . . ?
C30 Ru2 C22A 96.5(5) . . ?
C25A Ru2 C22A 59.0(4) . . ?
C24A Ru2 C22A 58.9(4) . . ?
C26A Ru2 C22A 35.4(3) . . ?
C23A Ru2 C22A 35.3(3) . . ?
C21 Ru2 C25 102.5(3) . . ?
C20 Ru2 C25 162.1(3) . . ?
C30 Ru2 C25 101.5(3) . . ?
C25A Ru2 C25 13.9(4) . . ?
C24A Ru2 C25 47.6(4) . . ?
C26A Ru2 C25 24.3(4) . . ?
C23A Ru2 C25 64.3(4) . . ?
C22A Ru2 C25 54.6(4) . . ?
C21 Ru2 C22 155.0(3) . . ?
C20 Ru2 C22 101.0(3) . . ?
C30 Ru2 C22 108.6(3) .. . ?
C25A Ru2 C22 62.7(4) . . ?
C24A Ru2 C22 52.0(4) . . ?
C26A Ru2 C22 47.3(4) . . ?
C23A Ru2 C22 21.9(4) . . ?
C22A Ru2 C22 14.9(4) . . ?
C25 Ru2 C22 62.1(3) . . ?
C21 Ru2 C26 138.4(4) . . ?
C20 Ru2 C26 130.4(4) . . ?
C30 Ru2 C26 87.0(2) . . ?
C25A Ru2 C26 46.7(4) . . ?
C24A Ru2 C26 62.1(4) . . ?
C26A Ru2 C26 14.3(4) . . ?
C23A Ru2 C26 51.9(4) . . ?
C22A Ru2 C26 22.4(4) . . ?
C25 Ru2 C26 37.6(3) . . ?
C22 Ru2 C26 36.1(3) . . ?
C21 Ru2 C23 119.3(3) . . ?
C20 Ru2 C23 101.8(3) . . ?
C30 Ru2 C23 145.0(3) . . ?
C25A Ru2 C23 52.6(4) . . ?
C24A Ru2 C23 21.7(4) . . ?
C26A Ru2 C23 63.7(4) . . ?
C23A Ru2 C23 16.0(4) . . ?
C22A Ru2 C23 48.5(4) . . ?
C25 Ru2 C23 61.5(3) . . ?
C22 Ru2 C23 37.0(3) . . ?
C26 Ru2 C23 60.7(3) . . ?
N1 Si1 C2 108.3(2) . . ?
N1 Si1 C3 111.7(2) . . ?
C2 Si1 C3 108.8(3) . . ?
N1 Si1 C1 111.4(3) . . ?
C2 Si1 C1 109.2(3) . . ?
C3 Si1 C1 107.3(3) . . ?
C7 N1 Si1 113.7(3) . . ?
C7 N1 Zr 119.4(3) . . ?
Si1 N1 Zr 126.5(2) . . ?
N1 C7 C8 116.3(4) . . ?
C9 C8 C7 116.3(4) . . ?
N2 C9 C8 113.7(4) . . ?
C9 N2 Si2 115.4(3) . . ?
C9 N2 Zr 109.8(3) . . ?
Si2 N2 Zr 134.7(2) . . ?
N2 Si2 C5 110.0(2) . . ?
N2 Si2 C4 109.9(3) . . ?
C5 Si2 C4 108.3(3) . . ?
N2 Si2 C6 109.8(3) . . ?
C5 Si2 C6 109.3(4) . . ?
C4 Si2 C6 109.6(3) . . ?
C30 N30 C31 129.4(4) . . ?
C30 N30 Zr 75.5(2) . . ?
C31 N30 Zr 155.1(3) . . ?
N30 C30 Ru2 135.4(3) . . ?
N30 C30 Zr 71.0(2) . . ?
Ru2 C30 Zr 153.6(2) . . ?
O20 C20 Ru2 179.0(6) . . ?
O21 C21 Ru2 175.7(5) . . ?
C26 C22 C23 107.9(7) . . ?
C26 C22 Ru2 72.3(5) . . ?
C23 C22 Ru2 72.2(4) . . ?
C24 C23 C22 108.2(7) . . ?
C24 C23 Ru2 71.7(4) . . ?
C22 C23 Ru2 70.8(4) . . ?
C25 C24 C23 108.1(7) . . ?
C25 C24 Ru2 70.7(4) . . ?
C23 C24 Ru2 71.6(4) . . ?
C24 C25 C26 106.6(7) . . ?
C24 C25 Ru2 72.4(4) . . ?
C26 C25 Ru2 71.6(4) . . ?
C22 C26 C25 109.1(7) . . ?
C22 C26 Ru2 71.6(4) . . ?
C25 C26 Ru2 70.8(4) . . ?
C26A C22A C23A 108.0 . . ?
C26A C22A Ru2 71.9(5) .. . ?
C23A C22A Ru2 72.4(5) . . ?
C24A C23A C22A 108.0 . . ?
C24A C23A Ru2 71.9(5) . . ?
C22A C23A Ru2 72.3(5) . . ?
C25A C24A C23A 108.0 . . ?
C25A C24A Ru2 72.0(5) . . ?
C23A C24A Ru2 72.7(6) . . ?
C24A C25A C26A 108.0 . . ?
C24A C25A Ru2 72.5(5) . . ?
C26A C25A Ru2 72.5(5) . . ?
C22A C26A C25A 108.0 . . ?
C22A C26A Ru2 72.7(6) . . ?
C25A C26A Ru2 72.0(5) . . ?
O10 C10 Ru1 177.2(5) . . ?
O11 C11 Ru1 177.6(5) . . ?
C13 C12 C16 108.2(5) . . ?
C13 C12 Ru1 72.2(3) . . ?
C16 C12 Ru1 70.3(3) . . ?
C12 C13 C14 108.0(5) . . ?
C12 C13 Ru1 72.1(3) . . ?
C14 C13 Ru1 70.7(3) . . ?
C15 C14 C13 108.5(5) . . ?
C15 C14 Ru1 72.0(3) . . ?
C13 C14 Ru1 72.6(3) . . ?
C14 C15 C16 107.5(5) . . ?
C14 C15 Ru1 71.6(3) . . ?
C16 C15 Ru1 71.1(3) . . ?
C15 C16 C12 107.8(5) . . ?
C15 C16 Ru1 72.2(3) . . ?
C12 C16 Ru1 72.8(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zr N2 2.025(4) . ?
Zr N1 2.066(4) . ?
Zr N30 2.185(3) . ?
Zr C30 2.237(4) . ?
Zr Ru1 2.8639(6) . ?
Ru1 C11 1.835(6) . ?
Ru1 C10 1.858(6) . ?
Ru1 C16 2.274(5) . ?
Ru1 C14 2.284(5) . ?
Ru1 C15 2.288(5) . ?
Ru1 C12 2.307(5) . ?
Ru1 C13 2.309(5) . ?
Ru2 C21 1.865(6) . ?
Ru2 C20 1.866(6) . ?
Ru2 C30 2.040(4) . ?
Ru2 C25A 2.264(14) . ?
Ru2 C24A 2.270(14) . ?
Ru2 C26A 2.270(13) . ?
Ru2 C23A 2.281(14) . ?
Ru2 C22A 2.280(14) . ?
Ru2 C25 2.281(8) . ?
Ru2 C22 2.284(9) . ?
Ru2 C26 2.293(7) . ?
Ru2 C23 2.303(8) . ?
Si1 N1 1.739(4) . ?
Si1 C2 1.863(5) . ?
Si1 C3 1.869(6) . ?
Si1 C1 1.871(6) . ?
N1 C7 1.482(6) . ?
C7 C8 1.517(7) . ?
C8 C9 1.502(7) . ?
C9 N2 1.492(6) . ?
N2 Si2 1.733(4) . ?
Si2 C5 1.857(6) . ?
Si2 C4 1.863(6) . ?
Si2 C6 1.871(7) . ?
N30 C30 1.278(5) . ?
N30 C31 1.467(5) . ?
C20 O20 1.138(7) . ?
C21 O21 1.141(6) . ?
C22 C26 1.416(13) . ?
C22 C23 1.454(13) . ?
C23 C24 1.447(12) . ?
C24 C25 1.449(12) . ?
C25 C26 1.473(12) . ?
C22A C26A 1.383(11) . ?
C22A C23A 1.383(11) . ?
C23A C24A 1.383(11) . ?
C24A C25A 1.383(11) . ?
C25A C26A 1.383(11) . ?
C10 O10 1.146(6) . ?
C11 O11 1.165(6) . ?
C12 C13 1.412(8) . ?
C12 C16 1.450(8) . ?
C13 C14 1.445(7) . ?
C14 C15 1.428(8) . ?
C15 C16 1.440(8) . ?
