#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/30/4323040.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4323040
loop_
_publ_author_name
'J. Le Bras'
'H. Amouri'
'J. Vaissermann'
_publ_contact_author
;
 Dr H. Amouri, E.N.S.C.P., 11, rue P. et M. Curie, 75231 Paris Cedex 05, France
;
_publ_contact_author_fax         ' (33) 1 43 25 79 75 '
_publ_contact_author_phone       ' (33) 1 44 27 66 99 '
_publ_section_title
;
 Regioselective Phosphine Addition to
 [(η5-C5Me5)Ir(η5-oxocyclohexadienyl)]+ and X-ray Structure of the
 Stable Phenol Tautomer Complex [(η5-C5Me5)Ir(η4-exo-2-(PMe3)C6H5O)]+: A
 Key Intermediate for the Nucleophilic Phenol Functionalization Reaction
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5056
_journal_page_last               5060
_journal_paper_doi               10.1021/ic971427i
_journal_volume                  37
_journal_year                    1998
_chemical_compound_source
;
?
;
_chemical_formula_moiety         ' C19 H29 Ir1 P1 O1 B1 F4 '
_chemical_formula_sum            'C19 H29 B F4 Ir O P'
_chemical_formula_weight         583.44
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             98-06-03
_audit_creation_method           CRYSTALS
_cell_angle_alpha                95.90(1)
_cell_angle_beta                 99.47(1)
_cell_angle_gamma                99.20(1)
_cell_formula_units_Z            2
_cell_length_a                   8.599(1)
_cell_length_b                   9.0173(9)
_cell_length_c                   14.448(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    295
_cell_measurement_theta_max      15.2
_cell_measurement_theta_min      15
_cell_volume                     1081.2(3)
_computing_cell_refinement       'CAD-4 software (Enraf-Nonius, 1989)'
_computing_data_collection       'CAD-4 software (Enraf-Nonius, 1989)'
_computing_data_reduction
;
RC93 (Watkin, D.J., Prout, C.K., Lilley, P.M.deQ. 1994)
;
_computing_molecular_graphics
;
 CAMERON (Watkin, Prout & Pearce,  1996)
;
_computing_publication_material
;
CRYSTALS Issue 10 (Watkin, Prout, Carruthers & Betteridge, 1996)
;
_computing_structure_refinement
;
CRYSTALS Issue 10 (Watkin, Prout, Carruthers & Betteridge, 1996)
;
_diffrn_ambient_temperature      295
_diffrn_measurement_device       '  Enraf-nonius CAD4 '
_diffrn_measurement_method       2θ/ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.015
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            4081
_diffrn_reflns_theta_max         25
_diffrn_reflns_theta_min         1
_diffrn_standards_decay_%        43.14
_diffrn_standards_interval_time  3600
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    6.26
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.92
_exptl_absorpt_correction_type   DIFABS
_exptl_absorpt_process_details   'refined from delta-F'
_exptl_crystal_colour            ' off white '
_exptl_crystal_density_diffrn    1.79
_exptl_crystal_description       ' prism '
_exptl_crystal_F_000             564.11
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.80
_refine_diff_density_min         -2.68
_refine_ls_extinction_coef       40.4(30)
_refine_ls_extinction_method
'Larson 1970 Crystallographic Computing eq 22'
_refine_ls_goodness_of_fit_obs   4.8034
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     262
_refine_ls_number_reflns         3304
_refine_ls_R_factor_obs          0.0444
_refine_ls_shift/esd_max         1.76
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      unit
_refine_ls_wR_factor_obs         0.0519
_reflns_limit_h_max              9
_reflns_limit_h_min              -10
_reflns_limit_k_max              10
_reflns_limit_k_min              -10
_reflns_limit_l_max              17
_reflns_limit_l_min              0
_reflns_number_observed          3304
_reflns_number_total             3803
_reflns_observed_criterion       >3.00\s(I)
_cod_data_source_file            ic971427i_1.cif
_cod_data_source_block           CRYSTALS_cif
_cod_original_cell_volume        1081.1(3)
_cod_original_sg_symbol_H-M      'P -1 '
_cod_original_formula_sum        ' C19 H29 Ir1 P1 O1 B1 F4 '
_cod_database_code               4323040
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,-y,-z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_occupancy
_atom_site_thermal_displace_type
IR1 0.27324(5) 0.33642(5) 0.17794(3) 0.0288 1.0000 Uani
P1 0.7292(4) 0.6540(3) 0.3476(2) 0.0391 1.0000 Uani
O1 0.686(1) 0.498(1) 0.1279(6) 0.0561 1.0000 Uani
C1 0.581(1) 0.504(1) 0.1739(7) 0.0318 1.0000 Uani
C2 0.601(1) 0.487(1) 0.2773(7) 0.0276 1.0000 Uani
C3 0.438(1) 0.442(1) 0.3032(7) 0.0295 1.0000 Uani
C4 0.323(1) 0.535(1) 0.280(1) 0.0457 1.0000 Uani
C5 0.311(1) 0.575(1) 0.188(1) 0.0374 1.0000 Uani
C6 0.419(1) 0.523(1) 0.1345(9) 0.0393 1.0000 Uani
C7 0.718(2) 0.656(2) 0.4689(9) 0.0649 1.0000 Uani
C8 0.669(2) 0.819(2) 0.309(1) 0.0690 1.0000 Uani
C9 0.931(2) 0.654(2) 0.333(1) 0.0680 1.0000 Uani
C11 0.062(1) 0.209(1) 0.077(1) 0.0411 1.0000 Uani
C12 0.048(2) 0.179(1) 0.170(1) 0.0447 1.0000 Uani
C13 0.177(2) 0.110(1) 0.2057(8) 0.0437 1.0000 Uani
C14 0.273(1) 0.101(1) 0.1372(8) 0.0371 1.0000 Uani
C15 0.201(1) 0.158(1) 0.0562(8) 0.0392 1.0000 Uani
C16 -0.056(2) 0.273(2) 0.008(1) 0.0789 1.0000 Uani
C17 -0.096(2) 0.212(2) 0.215(2) 0.0692 1.0000 Uani
C18 0.205(3) 0.053(2) 0.301(1) 0.0795 1.0000 Uani
C19 0.420(2) 0.026(2) 0.147(1) 0.0696 1.0000 Uani
C20 0.261(3) 0.165(2) -0.034(1) 0.0711 1.0000 Uani
B1 0.746(2) 0.214(2) 0.458(1) 0.0648 1.0000 Uani
F1 0.646(1) 0.169(1) 0.3748(8) 0.0968 1.0000 Uani
F2 0.856(2) 0.336(2) 0.445(1) 0.1429 1.0000 Uani
F3 0.678(2) 0.262(2) 0.527(1) 0.1518 1.0000 Uani
F4 0.828(2) 0.103(1) 0.4818(9) 0.1108 1.0000 Uani
H21 0.65(1) 0.41(1) 0.288(8) 0.05(1) 1.0000 Uiso
H31 0.44(1) 0.39(1) 0.356(8) 0.05(1) 1.0000 Uiso
H41 0.28(1) 0.54(1) 0.324(9) 0.05(1) 1.0000 Uiso
H51 0.23(1) 0.62(1) 0.166(8) 0.05(1) 1.0000 Uiso
H61 0.41(1) 0.54(1) 0.076(9) 0.05(1) 1.0000 Uiso
H71 0.8256 0.6997 0.5080 0.17(2) 1.0000 Uiso
H72 0.6381 0.7192 0.4845 0.17(2) 1.0000 Uiso
H73 0.6838 0.5500 0.4817 0.17(2) 1.0000 Uiso
H81 0.7284 0.9093 0.3537 0.17(2) 1.0000 Uiso
H82 0.6874 0.8269 0.2443 0.17(2) 1.0000 Uiso
H83 0.5498 0.8114 0.3101 0.17(2) 1.0000 Uiso
H91 1.0035 0.6934 0.3963 0.17(2) 1.0000 Uiso
H92 0.9574 0.7245 0.2866 0.17(2) 1.0000 Uiso
H93 0.9442 0.5509 0.3117 0.17(2) 1.0000 Uiso
H161 -0.1428 0.3010 0.0393 0.17(2) 1.0000 Uiso
H162 0.0034 0.3651 -0.0134 0.17(2) 1.0000 Uiso
H163 -0.1007 0.1949 -0.0484 0.17(2) 1.0000 Uiso
H171 -0.0798 0.1784 0.2807 0.17(2) 1.0000 Uiso
H172 -0.1007 0.3185 0.2192 0.17(2) 1.0000 Uiso
H173 -0.1959 0.1473 0.1766 0.17(2) 1.0000 Uiso
H181 0.3031 0.0103 0.3092 0.17(2) 1.0000 Uiso
H182 0.2116 0.1396 0.3520 0.17(2) 1.0000 Uiso
H183 0.1094 -0.0267 0.3038 0.17(2) 1.0000 Uiso
H191 0.4698 0.0321 0.0896 0.17(2) 1.0000 Uiso
H192 0.5006 0.0787 0.2043 0.17(2) 1.0000 Uiso
H193 0.3890 -0.0833 0.1556 0.17(2) 1.0000 Uiso
H201 0.1878 0.2101 -0.0794 0.17(2) 1.0000 Uiso
H202 0.3714 0.2262 -0.0223 0.17(2) 1.0000 Uiso
H203 0.2647 0.0586 -0.0626 0.17(2) 1.0000 Uiso
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
'C   ' 0.0020 0.0020 2.3100 20.8439 1.0200 10.2075 1.5886 0.5687 0.8650 51.6512
0.2156 International_Tables_Vol_IV_Table_2.2B
'H   ' 0.0000 0.0000 0.4930 10.5109 0.3229 26.1257 0.1402 3.1424 0.0408 57.7997
0.0030 International_Tables_Vol_IV_Table_2.2B
'O   ' 0.0080 0.0060 3.0485 13.2771 2.2868 5.7011 1.5463 0.3239 0.8670 32.9089
0.2508 International_Tables_Vol_IV_Table_2.2B
'N   ' 0.0040 0.0030 12.2126 0.0057 3.1322 9.8933 2.0125 28.9975 1.1663 0.5826
-11.5290 International_Tables_Vol_IV_Table_2.2B
'P   ' 0.0900 0.0950 6.4345 1.9067 4.1791 27.1570 1.7800 0.5260 1.4908 68.1645
1.1149 International_Tables_Vol_IV_Table_2.2B
'B   ' 0.0000 0.0010 2.0545 23.2185 1.3326 1.0210 1.0979 60.3498 0.7068 0.1403
-0.1932 International_Tables_Vol_IV_Table_2.2B
'F   ' 0.0140 0.0100 3.5392 10.2825 2.6412 4.2944 1.5170 0.2615 1.0243 26.1476
0.2776 International_Tables_Vol_IV_Table_2.2B
'Ir  ' -2.0660 7.9900 27.3049 1.5928 16.7296 8.8655 15.6115 0.4179 5.8338
45.0011 11.4722 International_Tables_Vol_IV_Table_2.2B
loop_
_geom_angle_atom_site_label_1
_geom_angle_site_symmetry_1
_geom_angle_atom_site_label_2
_geom_angle_site_symmetry_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C3 . IR1 . C4 . 39.0(4) no
C3 . IR1 . C5 . 68.0(4) no
C4 . IR1 . C5 . 38.4(5) no
C3 . IR1 . C6 . 75.0(4) no
C4 . IR1 . C6 . 67.6(5) no
C5 . IR1 . C6 . 38.8(5) no
C3 . IR1 . C11 . 164.3(5) no
C4 . IR1 . C11 . 136.0(5) no
C5 . IR1 . C11 . 117.2(4) no
C6 . IR1 . C11 . 118.9(5) no
C3 . IR1 . C12 . 127.1(5) no
C4 . IR1 . C12 . 117.8(4) no
C5 . IR1 . C12 . 128.2(5) no
C6 . IR1 . C12 . 153.0(5) no
C11 . IR1 . C12 . 37.5(5) no
C3 . IR1 . C13 . 106.2(4) no
C4 . IR1 . C13 . 124.5(5) no
C5 . IR1 . C13 . 158.1(5) no
C6 . IR1 . C13 . 162.6(5) no
C11 . IR1 . C13 . 63.1(4) no
C3 . IR1 . C14 . 116.0(4) no
C4 . IR1 . C14 . 152.3(5) no
C5 . IR1 . C14 . 164.3(5) no
C6 . IR1 . C14 . 125.8(4) no
C11 . IR1 . C14 . 63.5(4) no
C3 . IR1 . C15 . 150.2(4) no
C4 . IR1 . C15 . 169.5(5) no
C5 . IR1 . C15 . 132.2(5) no
C6 . IR1 . C15 . 107.1(4) no
C11 . IR1 . C15 . 37.7(4) no
C12 . IR1 . C13 . 37.6(5) no
C12 . IR1 . C14 . 62.9(5) no
C13 . IR1 . C14 . 37.6(4) no
C12 . IR1 . C15 . 62.6(4) no
C13 . IR1 . C15 . 63.0(4) no
C14 . IR1 . C15 . 38.1(4) no
C2 . P1 . C7 . 110.8(6) no
C2 . P1 . C8 . 109.9(6) no
C7 . P1 . C8 . 108.5(8) no
C2 . P1 . C9 . 109.0(6) no
C7 . P1 . C9 . 109.5(8) no
C8 . P1 . C9 . 109.1(9) no
O1 . C1 . C2 . 123.5(10) no
O1 . C1 . C6 . 124.0(10) no
C2 . C1 . C6 . 112.5(9) no
P1 . C2 . C1 . 110.4(7) no
P1 . C2 . C3 . 116.3(7) no
C1 . C2 . C3 . 109.4(8) no
P1 . C2 . H21 . 107.4(79) no
C1 . C2 . H21 . 110.2(79) no
C3 . C2 . H21 . 102.9(79) no
IR1 . C3 . C2 . 108.5(7) no
IR1 . C3 . C4 . 70.6(6) no
C2 . C3 . C4 . 117.1(9) no
IR1 . C3 . H31 . 115.0(68) no
C2 . C3 . H31 . 114.0(68) no
C4 . C3 . H31 . 122.8(69) no
IR1 . C4 . C3 . 70.4(6) no
IR1 . C4 . C5 . 69.6(7) no
C3 . C4 . C5 . 114.4(11) no
IR1 . C4 . H41 . 122.2(90) no
C3 . C4 . H41 . 105.6(93) no
C5 . C4 . H41 . 139.6(93) no
IR1 . C5 . C4 . 72.1(7) no
IR1 . C5 . C6 . 71.9(6) no
C4 . C5 . C6 . 115.9(10) no
IR1 . C5 . H51 . 118.9(80) no
C4 . C5 . H51 . 119.8(81) no
C6 . C5 . H51 . 123.9(81) no
IR1 . C6 . C1 . 102.6(7) no
IR1 . C6 . C5 . 69.2(6) no
C1 . C6 . C5 . 124.5(11) no
IR1 . C6 . H61 . 122.1(79) no
C1 . C6 . H61 . 113.0(79) no
C5 . C6 . H61 . 117.2(79) no
P1 . C7 . H71 . 109.2(11) no
P1 . C7 . H72 . 109.2(12) no
H71 . C7 . H72 . 109.7(14) no
P1 . C7 . H73 . 109.2(11) no
H71 . C7 . H73 . 109.7(16) no
H72 . C7 . H73 . 109.8(14) no
P1 . C8 . H81 . 109.4(12) no
P1 . C8 . H82 . 109.6(12) no
H81 . C8 . H82 . 111.2(16) no
P1 . C8 . H83 . 108.2(11) no
H81 . C8 . H83 . 109.0(16) no
H82 . C8 . H83 . 109.3(16) no
P1 . C9 . H91 . 108.0(12) no
P1 . C9 . H92 . 109.0(13) no
H91 . C9 . H92 . 108.4(13) no
P1 . C9 . H93 . 110.0(10) no
H91 . C9 . H93 . 109.9(18) no
H92 . C9 . H93 . 111.4(16) no
IR1 . C11 . C12 . 70.7(7) no
IR1 . C11 . C15 . 70.6(6) no
C12 . C11 . C15 . 107.1(10) no
IR1 . C11 . C16 . 127.4(9) no
C12 . C11 . C16 . 127.5(15) no
C15 . C11 . C16 . 125.2(15) no
IR1 . C12 . C11 . 71.8(7) no
IR1 . C12 . C13 . 70.7(7) no
C11 . C12 . C13 . 108.8(11) no
IR1 . C12 . C17 . 125.7(9) no
C11 . C12 . C17 . 122.0(17) no
C13 . C12 . C17 . 129.2(16) no
IR1 . C13 . C12 . 71.7(7) no
IR1 . C13 . C14 . 70.0(6) no
C12 . C13 . C14 . 107.8(10) no
IR1 . C13 . C18 . 125.2(9) no
C12 . C13 . C18 . 126.5(14) no
C14 . C13 . C18 . 125.7(14) no
IR1 . C14 . C13 . 72.4(6) no
IR1 . C14 . C15 . 72.7(6) no
C13 . C14 . C15 . 108.7(10) no
IR1 . C14 . C19 . 125.3(8) no
C13 . C14 . C19 . 123.9(12) no
C15 . C14 . C19 . 127.2(12) no
IR1 . C15 . C11 . 71.7(6) no
IR1 . C15 . C14 . 69.2(6) no
C11 . C15 . C14 . 107.7(10) no
IR1 . C15 . C20 . 124.3(9) no
C11 . C15 . C20 . 125.6(13) no
C14 . C15 . C20 . 126.7(13) no
C11 . C16 . H161 . 109.9(19) no
C11 . C16 . H162 . 109.0(15) no
H161 . C16 . H162 . 110.1(16) no
C11 . C16 . H163 . 109.0(14) no
H161 . C16 . H163 . 110.1(17) no
H162 . C16 . H163 . 108.8(22) no
C12 . C17 . H171 . 107.2(19) no
C12 . C17 . H172 . 110.7(14) no
H171 . C17 . H172 . 110.9(17) no
C12 . C17 . H173 . 108.1(14) no
H171 . C17 . H173 . 107.5(17) no
H172 . C17 . H173 . 112.2(24) no
C13 . C18 . H181 . 110.4(16) no
C13 . C18 . H182 . 108.3(14) no
H181 . C18 . H182 . 111.0(17) no
C13 . C18 . H183 . 108.1(15) no
H181 . C18 . H183 . 110.9(17) no
H182 . C18 . H183 . 108.0(19) no
C14 . C19 . H191 . 109.8(14) no
C14 . C19 . H192 . 109.5(13) no
H191 . C19 . H192 . 109.3(15) no
C14 . C19 . H193 . 109.7(13) no
H191 . C19 . H193 . 109.4(15) no
H192 . C19 . H193 . 109.1(17) no
C15 . C20 . H201 . 110.3(17) no
C15 . C20 . H202 . 109.7(13) no
H201 . C20 . H202 . 110.4(15) no
C15 . C20 . H203 . 108.8(13) no
H201 . C20 . H203 . 109.2(15) no
H202 . C20 . H203 . 108.4(20) no
F1 . B1 . F2 . 106.7(16) no
F1 . B1 . F3 . 114.7(18) no
F2 . B1 . F3 . 106.1(16) no
F1 . B1 . F4 . 110.2(14) no
F2 . B1 . F4 . 107.4(17) no
F3 . B1 . F4 . 111.3(18) no
loop_
_geom_bond_atom_site_label_1
_geom_bond_site_symmetry_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
IR1 . C3 . 2.14(1) yes
IR1 . C4 . 2.14(1) yes
IR1 . C5 . 2.11(1) yes
IR1 . C6 . 2.14(1) yes
IR1 . C11 . 2.21(1) yes
IR1 . C12 . 2.19(1) yes
IR1 . C13 . 2.18(1) yes
IR1 . C14 . 2.15(1) yes
IR1 . C15 . 2.19(1) yes
P1 . C2 . 1.82(1) yes
P1 . C7 . 1.77(1) yes
P1 . C8 . 1.77(1) yes
P1 . C9 . 1.78(1) yes
O1 . C1 . 1.22(1) yes
C1 . C2 . 1.50(1) yes
C1 . C6 . 1.46(2) yes
C2 . C3 . 1.51(1) yes
C2 . H21 . 0.8(1) no
C3 . C4 . 1.43(2) yes
C3 . H31 . 1.0(1) no
C4 . C5 . 1.40(2) yes
C4 . H41 . 0.8(1) no
C5 . C6 . 1.41(2) yes
C5 . H51 . 0.8(1) no
C6 . H61 . 0.9(1) no
C7 . H71 . 1.00(1) no
C7 . H72 . 1.00(2) no
C7 . H73 . 1.00(2) no
C8 . H81 . 0.99(1) no
C8 . H82 . 0.99(2) no
C8 . H83 . 1.01(2) no
C9 . H91 . 1.02(2) no
C9 . H92 . 1.00(2) no
C9 . H93 . 0.98(2) no
C11 . C12 . 1.41(2) yes
C11 . C15 . 1.42(2) yes
C11 . C16 . 1.52(2) yes
C12 . C13 . 1.41(2) yes
C12 . C17 . 1.55(2) yes
C13 . C14 . 1.39(2) yes
C13 . C18 . 1.52(2) yes
C14 . C15 . 1.42(2) yes
C14 . C19 . 1.53(2) yes
C15 . C20 . 1.48(2) yes
C16 . H161 . 0.99(2) no
C16 . H162 . 1.00(2) no
C16 . H163 . 1.00(2) no
C17 . H171 . 1.02(3) no
C17 . H172 . 0.96(2) no
C17 . H173 . 1.00(2) no
C18 . H181 . 0.97(2) no
C18 . H182 . 1.01(2) no
C18 . H183 . 1.01(2) no
C19 . H191 . 1.00(2) no
C19 . H192 . 1.00(2) no
C19 . H193 . 1.00(2) no
C20 . H201 . 0.99(2) no
C20 . H202 . 1.00(2) no
C20 . H203 . 1.01(2) no
B1 . F1 . 1.34(2) yes
B1 . F2 . 1.38(2) yes
B1 . F3 . 1.31(2) yes
B1 . F4 . 1.35(2) yes
