#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:33:12 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179334 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/31/4323101.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4323101
loop_
_publ_author_name
'T. M. Rajendiran'
'Olivier Kahn'
'Stéphane Golhen'
'Lahcène Ouahab'
'Zentaro Honda'
'Koichi Katsumata'
_publ_section_title
;
 Dimerized Nickel2+ Chain Compounds with Nitro-Nitrito Bridges and
 Unprecedented [Ln(NO3)4(CH3OH)2]- Anions (Ln = Lanthanide). Crystal
 Structure and Magnetic Properties
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              5693
_journal_page_last               5696
_journal_paper_doi               10.1021/ic980458q
_journal_volume                  37
_journal_year                    1998
_chemical_formula_moiety         '[Eu(No3)4(CH3OH)2][NO3][Ni(en)2(NO2)]2CH3OH'
_chemical_formula_sum            'C11 H44 Eu N15 Ni2 O22'
_chemical_formula_weight         1007.99
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   15.791(7)
_cell_length_b                   10.465(5)
_cell_length_c                   21.716(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    233(2)
_cell_measurement_theta_max      11.021
_cell_measurement_theta_min      8.441
_cell_volume                     3589(2)
_computing_cell_refinement       'Nonius CAD4'
_computing_data_collection       'Nonius CAD4'
_computing_data_reduction        MolEN
_computing_molecular_graphics    ORTEP
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      233(2)
_diffrn_measurement_device       'Enraf-nonius 4-circle diffractometer'
_diffrn_measurement_method       θ-\2q
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0224
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            4534
_diffrn_reflns_theta_max         27.96
_diffrn_reflns_theta_min         1.59
_diffrn_standards_decay_%        0.1
_diffrn_standards_interval_count 250
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.865
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.866
_exptl_crystal_F_000             2040
_refine_diff_density_max         1.296
_refine_diff_density_min         -1.005
_refine_diff_density_rms         0.229
_refine_ls_extinction_coef       0.0030(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   1.188
_refine_ls_goodness_of_fit_obs   1.231
_refine_ls_matrix_type           full
_refine_ls_number_parameters     351
_refine_ls_number_reflns         4517
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.755
_refine_ls_restrained_S_obs      1.231
_refine_ls_R_factor_all          0.0617
_refine_ls_R_factor_obs          0.0439
_refine_ls_shift/esd_max         -0.013
_refine_ls_shift/esd_mean        0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0867P)²+1.6611P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.2000
_refine_ls_wR_factor_obs         0.1269
_reflns_number_observed          3713
_reflns_number_total             4534
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic980458q.cif
_cod_data_source_block           euni
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'None' changed to 'none'
according to the built-in table from CIF Core dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1673 2011-04-08 12:14:43Z adriana 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0867P)^2^+1.6611P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0867P)^2^+1.6611P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3588.5(23)
_cod_database_code               4323101
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x+1/2, -y+1/2, -z+1/2'
'-x, y+1/2, -z'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'-x-1/2, y-1/2, z-1/2'
'x, -y-1/2, z'
'x-1/2, y, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Eu1 Eu 0.30051(2) 0.7500 0.060433(14) 0.02670(14) Uani 1 d S .
O1 O 0.2886(3) 0.6491(5) -0.0446(2) 0.0601(13) Uani 1 d . .
O2 O 0.2729(5) 0.7500 -0.1304(3) 0.068(2) Uani 1 d S .
N1 N 0.2835(4) 0.7500 -0.0744(3) 0.0419(15) Uani 1 d S .
O3 O 0.2740(3) 0.6471(4) 0.1656(2) 0.0428(8) Uani 1 d . .
N2 N 0.2685(4) 0.7500 0.1956(3) 0.0316(11) Uani 1 d S .
O4 O 0.2593(4) 0.7500 0.2521(2) 0.0442(13) Uani 1 d S .
O6 O 0.0402(4) 0.7500 0.0440(3) 0.058(2) Uani 1 d S .
O5 O 0.1583(3) 0.6473(4) 0.0537(2) 0.0547(11) Uani 1 d . .
N3 N 0.1171(4) 0.7500 0.0500(3) 0.044(2) Uani 1 d S .
O7 O 0.4367(3) 0.7500 0.1188(2) 0.0369(11) Uani 1 d S .
O8 O 0.4481(3) 0.7500 0.0200(2) 0.0386(11) Uani 1 d S .
N4 N 0.4850(4) 0.7500 0.0724(3) 0.0351(13) Uani 1 d S .
O9 O 0.5615(4) 0.7500 0.0774(3) 0.058(2) Uani 1 d S .
O10 O 0.3374(2) 0.5247(3) 0.0663(2) 0.0358(8) Uani 1 d . .
C1 C 0.3773(4) 0.4413(6) 0.0229(3) 0.0462(13) Uani 1 d . .
H1A H 0.3195(48) 0.3989(79) -0.0078(35) 0.074(24) Uiso 1 d . .
H1B H 0.4176(67) 0.4599(110) 0.0353(53) 0.105(39) Uiso 1 d . .
H1C H 0.3934(40) 0.4975(61) -0.0098(29) 0.042(16) Uiso 1 d . .
Ni1 Ni 0.98902(4) 0.49946(6) 0.21140(3) 0.0320(2) Uani 1 d . .
N5 N 1.0051(5) 0.4841(7) 0.1167(3) 0.0505(14) Uani 1 d . .
H5A H 1.0350(46) 0.4428(70) 0.1159(35) 0.044(26) Uiso 1 d . .
H5B H 1.0208(40) 0.5377(62) 0.1037(29) 0.032(17) Uiso 1 d . .
C2 C 0.9229(5) 0.4675(7) 0.0871(3) 0.058(2) Uani 1 d . .
H2A H 0.9003(45) 0.3870(77) 0.0920(33) 0.063(20) Uiso 1 d . .
H2B H 0.9398(61) 0.4881(93) 0.0357(48) 0.101(31) Uiso 1 d . .
C3 C 0.8609(6) 0.5476(8) 0.1193(3) 0.059(2) Uani 1 d . .
H3A H 0.8743(51) 0.6182(76) 0.1144(36) 0.067(24) Uiso 1 d . .
H3B H 0.8154(40) 0.5271(62) 0.1070(29) 0.038(16) Uiso 1 d . .
N6 N 0.8618(4) 0.5187(6) 0.1868(3) 0.0488(12) Uani 1 d . .
H6A H 0.8230(41) 0.5904(66) 0.2055(28) 0.047(17) Uiso 1 d . .
H6B H 0.8369(60) 0.4634(92) 0.1858(42) 0.080(32) Uiso 1 d . .
N7 N 0.9695(3) 0.5022(5) 0.3053(2) 0.0387(9) Uani 1 d . .
H7A H 0.9593(42) 0.5873(72) 0.3211(30) 0.054(18) Uiso 1 d . .
H7B H 0.9259(53) 0.4650(84) 0.3020(37) 0.074(26) Uiso 1 d . .
C4 C 1.0464(4) 0.4637(6) 0.3366(3) 0.0475(14) Uani 1 d . .
H4A H 1.0462(26) 0.4885(41) 0.3690(22) 0.006(10) Uiso 1 d . .
H4B H 1.0331(79) 0.3808(120) 0.3253(53) 0.144(45) Uiso 1 d . .
C5 C 1.1210(4) 0.5181(8) 0.3032(3) 0.058(2) Uani 1 d . .
H5C H 1.1186(38) 0.6078(66) 0.2952(28) 0.044(17) Uiso 1 d . .
H5D H 1.1738(58) 0.5146(87) 0.3248(38) 0.081(25) Uiso 1 d . .
N8 N 1.1162(4) 0.4867(7) 0.2377(3) 0.0544(13) Uani 1 d . .
H8A H 1.1325(43) 0.4170(72) 0.2378(31) 0.047(20) Uiso 1 d . .
H8B H 1.1377(65) 0.5377(100) 0.2123(41) 0.101(34) Uiso 1 d . .
N9 N 1.0210(5) 0.7009(7) 0.2023(3) 0.0286(15) Uani 0.50 d P .
O11 O 1.0873(3) 0.7500 0.1812(3) 0.0498(14) Uani 1 d S .
O12 O 0.9668(5) 0.7890(6) 0.2204(4) 0.041(2) Uani 0.50 d P .
N10 N 0.9539(5) 0.2968(7) 0.2156(3) 0.0281(15) Uani 0.50 d P .
O13 O 0.8816(4) 0.2500 0.2197(3) 0.055(2) Uani 1 d S .
O14 O 1.0120(5) 0.2112(6) 0.2144(3) 0.038(2) Uani 0.50 d P .
N11 N 0.8095(4) 0.2500 0.3504(3) 0.0375(13) Uani 1 d S .
O15 O 0.7697(3) 0.1474(4) 0.3481(2) 0.0549(11) Uani 1 d . .
O16 O 0.8866(4) 0.2500 0.3571(3) 0.0542(15) Uani 1 d S .
O17 O 0.6149(4) 0.2500 0.4122(3) 0.060(2) Uani 1 d S .
C6 C 0.6517(7) 0.2500 0.4709(4) 0.082(4) Uani 1 d S .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O10 Eu1 O10 151.6(2) 7_575 . ?
O10 Eu1 O8 78.11(9) 7_575 . ?
O10 Eu1 O8 78.11(9) . . ?
O10 Eu1 O5 129.54(13) 7_575 . ?
O10 Eu1 O5 78.54(14) . . ?
O8 Eu1 O5 145.29(13) . . ?
O10 Eu1 O5 78.54(14) 7_575 7_575 ?
O10 Eu1 O5 129.54(13) . 7_575 ?
O8 Eu1 O5 145.29(13) . 7_575 ?
O5 Eu1 O5 51.0(2) . 7_575 ?
O10 Eu1 O7 76.53(9) 7_575 . ?
O10 Eu1 O7 76.53(9) . . ?
O8 Eu1 O7 51.1(2) . . ?
O5 Eu1 O7 143.67(13) . . ?
O5 Eu1 O7 143.67(13) 7_575 . ?
O10 Eu1 O1 70.04(14) 7_575 7_575 ?
O10 Eu1 O1 118.10(14) . 7_575 ?
O8 Eu1 O1 75.6(2) . 7_575 ?
O5 Eu1 O1 93.5(2) . 7_575 ?
O5 Eu1 O1 72.5(2) 7_575 7_575 ?
O7 Eu1 O1 121.6(2) . 7_575 ?
O10 Eu1 O1 118.10(14) 7_575 . ?
O10 Eu1 O1 70.04(14) . . ?
O8 Eu1 O1 75.6(2) . . ?
O5 Eu1 O1 72.5(2) . . ?
O5 Eu1 O1 93.5(2) 7_575 . ?
O7 Eu1 O1 121.6(2) . . ?
O1 Eu1 O1 49.5(2) 7_575 . ?
O10 Eu1 O3 113.62(12) 7_575 . ?
O10 Eu1 O3 65.49(11) . . ?
O8 Eu1 O3 117.89(14) . . ?
O5 Eu1 O3 73.96(14) . . ?
O5 Eu1 O3 94.94(14) 7_575 . ?
O7 Eu1 O3 71.83(14) . . ?
O1 Eu1 O3 166.3(2) 7_575 . ?
O1 Eu1 O3 128.26(15) . . ?
O10 Eu1 O3 65.49(11) 7_575 7_575 ?
O10 Eu1 O3 113.62(12) . 7_575 ?
O8 Eu1 O3 117.89(14) . 7_575 ?
O5 Eu1 O3 94.94(14) . 7_575 ?
O5 Eu1 O3 73.96(14) 7_575 7_575 ?
O7 Eu1 O3 71.83(14) . 7_575 ?
O1 Eu1 O3 128.26(15) 7_575 7_575 ?
O1 Eu1 O3 166.3(2) . 7_575 ?
O3 Eu1 O3 49.7(2) . 7_575 ?
O10 Eu1 N3 104.07(9) 7_575 . ?
O10 Eu1 N3 104.07(9) . . ?
O8 Eu1 N3 154.9(2) . . ?
O5 Eu1 N3 25.53(10) . . ?
O5 Eu1 N3 25.53(10) 7_575 . ?
O7 Eu1 N3 154.0(2) . . ?
O1 Eu1 N3 81.7(2) 7_575 . ?
O1 Eu1 N3 81.7(2) . . ?
O3 Eu1 N3 84.62(15) . . ?
O3 Eu1 N3 84.62(15) 7_575 . ?
O10 Eu1 N4 75.91(9) 7_575 . ?
O10 Eu1 N4 75.91(9) . . ?
O8 Eu1 N4 25.8(2) . . ?
O5 Eu1 N4 154.44(10) . . ?
O5 Eu1 N4 154.44(10) 7_575 . ?
O7 Eu1 N4 25.4(2) . . ?
O1 Eu1 N4 98.9(2) 7_575 . ?
O1 Eu1 N4 98.9(2) . . ?
O3 Eu1 N4 94.79(15) . . ?
O3 Eu1 N4 94.79(15) 7_575 . ?
N3 Eu1 N4 179.3(2) . . ?
O10 Eu1 N1 94.22(9) 7_575 . ?
O10 Eu1 N1 94.22(9) . . ?
O8 Eu1 N1 74.6(2) . . ?
O5 Eu1 N1 81.9(2) . . ?
O5 Eu1 N1 81.9(2) 7_575 . ?
O7 Eu1 N1 125.7(2) . . ?
O1 Eu1 N1 24.78(11) 7_575 . ?
O1 Eu1 N1 24.78(11) . . ?
O3 Eu1 N1 150.90(11) . . ?
O3 Eu1 N1 150.90(11) 7_575 . ?
N3 Eu1 N1 80.3(2) . . ?
N4 Eu1 N1 100.3(2) . . ?
O10 Eu1 N2 89.40(8) 7_575 . ?
O10 Eu1 N2 89.40(8) . . ?
O8 Eu1 N2 120.4(2) . . ?
O5 Eu1 N2 84.55(15) . . ?
O5 Eu1 N2 84.55(15) 7_575 . ?
O7 Eu1 N2 69.3(2) . . ?
O1 Eu1 N2 151.55(13) 7_575 . ?
O1 Eu1 N2 151.55(13) . . ?
O3 Eu1 N2 24.88(8) . . ?
O3 Eu1 N2 24.88(8) 7_575 . ?
N3 Eu1 N2 84.7(2) . . ?
N4 Eu1 N2 94.6(2) . . ?
N1 Eu1 N2 165.0(2) . . ?
N1 O1 Eu1 96.9(4) . . ?
O2 N1 O1 121.7(3) . . ?
O2 N1 O1 121.7(3) . 7_575 ?
O1 N1 O1 116.5(7) . 7_575 ?
O2 N1 Eu1 177.4(6) . . ?
O1 N1 Eu1 58.3(3) . . ?
O1 N1 Eu1 58.3(3) 7_575 . ?
N2 O3 Eu1 96.5(3) . . ?
O4 N2 O3 121.4(3) . 7_575 ?
O4 N2 O3 121.4(3) . . ?
O3 N2 O3 117.2(6) 7_575 . ?
O4 N2 Eu1 177.0(5) . . ?
O3 N2 Eu1 58.6(3) 7_575 . ?
O3 N2 Eu1 58.6(3) . . ?
N3 O5 Eu1 95.8(3) . . ?
O6 N3 O5 121.4(3) . 7_575 ?
O6 N3 O5 121.4(3) . . ?
O5 N3 O5 117.2(6) 7_575 . ?
O6 N3 Eu1 178.3(5) . . ?
O5 N3 Eu1 58.6(3) 7_575 . ?
O5 N3 Eu1 58.6(3) . . ?
N4 O7 Eu1 96.7(4) . . ?
N4 O8 Eu1 96.4(4) . . ?
O9 N4 O7 122.1(6) . . ?
O9 N4 O8 122.2(6) . . ?
O7 N4 O8 115.8(6) . . ?
O9 N4 Eu1 180.0(5) . . ?
O7 N4 Eu1 57.9(3) . . ?
O8 N4 Eu1 57.8(3) . . ?
C1 O10 Eu1 131.5(3) . . ?
N7 Ni1 N5 176.0(2) . . ?
N7 Ni1 N6 96.2(2) . . ?
N5 Ni1 N6 82.7(3) . . ?
N7 Ni1 N8 82.8(2) . . ?
N5 Ni1 N8 98.5(3) . . ?
N6 Ni1 N8 177.9(3) . . ?
N7 Ni1 N9 96.4(2) . . ?
N5 Ni1 N9 87.5(3) . . ?
N6 Ni1 N9 96.1(3) . . ?
N8 Ni1 N9 82.2(3) . . ?
N7 Ni1 N10 86.2(2) . . ?
N5 Ni1 N10 89.8(3) . . ?
N6 Ni1 N10 82.0(3) . . ?
N8 Ni1 N10 99.8(3) . . ?
N9 Ni1 N10 176.9(3) . . ?
N7 Ni1 O14 90.5(2) . 7_565 ?
N5 Ni1 O14 86.1(3) . 7_565 ?
N6 Ni1 O14 105.0(3) . 7_565 ?
N8 Ni1 O14 76.9(3) . 7_565 ?
N9 Ni1 O14 157.0(3) . 7_565 ?
N10 Ni1 O14 24.0(2) . 7_565 ?
N7 Ni1 O12 83.0(2) . 7_575 ?
N5 Ni1 O12 100.4(3) . 7_575 ?
N6 Ni1 O12 77.1(3) . 7_575 ?
N8 Ni1 O12 100.9(3) . 7_575 ?
N9 Ni1 O12 24.7(3) . 7_575 ?
N10 Ni1 O12 155.2(3) . 7_575 ?
O14 Ni1 O12 173.4(3) 7_565 7_575 ?
C2 N5 Ni1 109.6(5) . . ?
N5 C2 C3 108.5(6) . . ?
C2 C3 N6 110.2(6) . . ?
C3 N6 Ni1 106.2(5) . . ?
C4 N7 Ni1 109.6(4) . . ?
N7 C4 C5 109.1(5) . . ?
N8 C5 C4 110.2(6) . . ?
C5 N8 Ni1 107.5(4) . . ?
O12 N9 N9 83.6(6) 7_575 7_575 ?
O12 N9 O11 149.4(9) 7_575 . ?
N9 N9 O11 65.8(4) 7_575 . ?
O12 N9 O12 38.0(7) 7_575 . ?
N9 N9 O12 45.6(4) 7_575 . ?
O11 N9 O12 111.4(7) . . ?
O12 N9 Ni1 82.0(6) 7_575 . ?
N9 N9 Ni1 165.6(2) 7_575 . ?
O11 N9 Ni1 128.6(6) . . ?
O12 N9 Ni1 119.9(5) . . ?
N9 O11 N9 48.4(8) . 7_575 ?
O12 O12 N9 96.4(6) 7_575 7_575 ?
O12 O12 N9 45.6(4) 7_575 . ?
N9 O12 N9 50.7(8) 7_575 . ?
O12 O12 Ni1 169.7(2) 7_575 7_575 ?
N9 O12 Ni1 73.4(6) 7_575 7_575 ?
N9 O12 Ni1 124.1(6) . 7_575 ?
O14 N10 N10 84.8(6) 7_565 7_565 ?
O14 N10 O13 151.5(9) 7_565 . ?
N10 N10 O13 66.8(4) 7_565 . ?
O14 N10 O14 39.1(7) 7_565 . ?
N10 N10 O14 45.7(5) 7_565 . ?
O13 N10 O14 112.5(7) . . ?
O14 N10 Ni1 80.5(6) 7_565 . ?
N10 N10 Ni1 165.1(2) 7_565 . ?
O13 N10 Ni1 127.9(5) . . ?
O14 N10 Ni1 119.5(6) . . ?
N10 O13 N10 46.3(7) 7_565 . ?
O14 O14 N10 95.2(6) 7_565 7_565 ?
O14 O14 N10 45.7(5) 7_565 . ?
N10 O14 N10 49.5(8) 7_565 . ?
O14 O14 Ni1 170.5(2) 7_565 7_565 ?
N10 O14 Ni1 75.5(6) 7_565 7_565 ?
N10 O14 Ni1 125.0(6) . 7_565 ?
O16 N11 O15 120.4(3) . . ?
O16 N11 O15 120.4(3) . 7_565 ?
O15 N11 O15 119.2(7) . 7_565 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O10 2.432(4) 7_575 ?
Eu1 O10 2.432(4) . ?
Eu1 O8 2.491(5) . ?
Eu1 O5 2.494(4) . ?
Eu1 O5 2.494(4) 7_575 ?
Eu1 O7 2.495(5) . ?
Eu1 O1 2.521(4) 7_575 ?
Eu1 O1 2.521(4) . ?
Eu1 O3 2.559(4) . ?
Eu1 O3 2.559(4) 7_575 ?
Eu1 N3 2.906(7) . ?
Eu1 N4 2.924(6) . ?
Eu1 N1 2.941(7) . ?
Eu1 N2 2.978(6) . ?
O1 N1 1.242(6) . ?
O2 N1 1.227(8) . ?
N1 O1 1.242(6) 7_575 ?
O3 N2 1.261(5) . ?
N2 O4 1.235(7) . ?
N2 O3 1.261(5) 7_575 ?
O6 N3 1.221(9) . ?
O5 N3 1.259(5) . ?
N3 O5 1.259(5) 7_575 ?
O7 N4 1.262(7) . ?
O8 N4 1.279(8) . ?
N4 O9 1.213(8) . ?
O10 C1 1.430(6) . ?
Ni1 N7 2.063(5) . ?
Ni1 N5 2.079(6) . ?
Ni1 N6 2.088(6) . ?
Ni1 N8 2.093(6) . ?
Ni1 N9 2.177(8) . ?
Ni1 N10 2.194(8) . ?
Ni1 O14 2.235(7) 7_565 ?
Ni1 O12 2.250(7) 7_575 ?
N5 C2 1.459(10) . ?
C2 C3 1.465(11) . ?
C3 N6 1.498(9) . ?
N7 C4 1.447(8) . ?
C4 C5 1.497(9) . ?
C5 N8 1.461(9) . ?
N9 O12 0.948(10) 7_575 ?
N9 N9 1.03(2) 7_575 ?
N9 O11 1.252(9) . ?
N9 O12 1.318(10) . ?
O11 N9 1.252(9) 7_575 ?
O12 O12 0.816(13) 7_575 ?
O12 N9 0.948(10) 7_575 ?
O12 Ni1 2.250(7) 7_575 ?
N10 O14 0.922(10) 7_565 ?
N10 N10 0.98(2) 7_565 ?
N10 O13 1.244(10) . ?
N10 O14 1.282(9) . ?
O13 N10 1.244(10) 7_565 ?
O14 O14 0.811(13) 7_565 ?
O14 N10 0.922(10) 7_565 ?
O14 Ni1 2.235(7) 7_565 ?
N11 O16 1.227(9) . ?
N11 O15 1.245(5) . ?
N11 O15 1.245(5) 7_565 ?
O17 C6 1.402(11) . ?
