#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:34:46 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179336 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/33/4323309.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4323309
loop_
_publ_author_name
'Olga Crespo'
'M. Concepción Gimeno'
'Peter G. Jones'
'Birte Ahrens'
'Antonio Laguna'
_publ_contact_author
;
      For X-ray structures:
      Jones, Peter G.
      Institut für Analytische und Anorganische Chemie
      Technische Universität Braunschweig
      Postfach 3329
      38023 Braunschweig
      Germany
;
_publ_contact_author_email       jones@xray36.anchem.nat.tu-bs.de
_publ_contact_author_fax         '049 531 391-5387'
_publ_contact_author_phone       '049 531 391-5382'
_publ_section_title
;
 Synthesis and Characterization of Gold(I) Complexes with the Ligand
 1,2-Dithiolate-o-carborane. Crystal Structures of
 [Au₂(μ-S₂C₂B₁₀H₁₀)(PPh₃)₂],
 [Au₂(μ-S₂C₂B₁₀H₁₀)(μ-{(PPh₂)₂(CHCH)}], and
 [Au₂(μ-S₂C₂B₁₀H₁₀)(μ-{(PPh₂)₂)(C₆H₄)}]
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              495
_journal_page_last               500
_journal_paper_doi               10.1021/ic960822q
_journal_volume                  36
_journal_year                    1997
_chemical_formula_sum            'C28 H32 Au2 B10 P2 S2'
_chemical_formula_weight         996.63
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     Patterson
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 109.12(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.304(2)
_cell_length_b                   13.416(3)
_cell_length_c                   20.351(4)
_cell_measurement_reflns_used    56
_cell_measurement_temperature    143(2)
_cell_measurement_theta_max      11.5
_cell_measurement_theta_min      10
_cell_volume                     3432.0(12)
_computing_cell_refinement       'Stoe DIF4'
_computing_data_collection       'Stoe DIF4'
_computing_data_reduction        'Stoe REDU4'
_computing_molecular_graphics    'Siemens XP'
_computing_publication_material  SHELXL-93
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      143(2)
_diffrn_measurement_device       'Stoe STADI-4'
_diffrn_measurement_method       ω/θ-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0455
_diffrn_reflns_av_sigmaI/netI    0.0517
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            9312
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         3.04
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    8.775
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.347
_exptl_absorpt_correction_type   Psi-scans
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.929
_exptl_crystal_description       'hexagonal tablet'
_exptl_crystal_F_000             1880
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.45
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.336
_refine_diff_density_min         -1.655
_refine_diff_density_rms         0.161
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.066
_refine_ls_goodness_of_fit_obs   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         6020
_refine_ls_number_restraints     337
_refine_ls_restrained_S_all      1.074
_refine_ls_restrained_S_obs      1.037
_refine_ls_R_factor_all          0.0430
_refine_ls_R_factor_obs          0.0329
_refine_ls_shift/esd_max         0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0364P)²+1.1807P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0842
_refine_ls_wR_factor_obs         0.0749
_reflns_number_observed          5144
_reflns_number_total             6032
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic960822q_2.cif
_cod_data_source_block           ochre
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0364P)^2^+1.1807P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0364P)^2^+1.1807P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        3432.1(11)
_cod_database_code               4323309
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Au1 Au 0.17795(2) 0.10592(2) 0.225057(13) 0.02053(8) Uani 1 d . .
Au2 Au 0.29543(2) 0.25606(2) 0.166829(13) 0.02167(8) Uani 1 d . .
S1 S 0.11996(12) 0.08422(12) 0.10637(9) 0.0233(4) Uani 1 d U .
S2 S 0.34677(14) 0.19521(12) 0.07652(9) 0.0245(4) Uani 1 d U .
P1 P 0.22937(13) 0.12438(12) 0.34122(9) 0.0212(4) Uani 1 d U .
P2 P 0.25771(13) 0.34620(12) 0.24990(9) 0.0197(4) Uani 1 d U .
B1 B 0.3440(6) -0.0035(6) 0.1448(4) 0.0231(14) Uani 1 d U .
H1 H 0.3698(6) 0.0319(6) 0.1976(4) 0.028 Uiso 1 calc R .
B2 B 0.2555(6) -0.1044(6) 0.1253(4) 0.0272(15) Uani 1 d U .
H2 H 0.2241(6) -0.1384(6) 0.1650(4) 0.033 Uiso 1 calc R .
B3 B 0.1761(6) -0.0931(6) 0.0368(4) 0.026(2) Uani 1 d U .
H3 H 0.0918(6) -0.1199(6) 0.0169(4) 0.032 Uiso 1 calc R .
B4 B 0.2164(6) 0.0181(6) 0.0045(4) 0.0243(15) Uani 1 d U .
H4 H 0.1591(6) 0.0669(6) -0.0351(4) 0.029 Uiso 1 calc R .
B5 B 0.4315(6) -0.0133(5) 0.0950(4) 0.0223(14) Uani 1 d U .
H5 H 0.5162(6) 0.0127(5) 0.1143(4) 0.027 Uiso 1 calc R .
B6 B 0.3900(6) -0.1202(6) 0.1299(5) 0.028(2) Uani 1 d U .
H6 H 0.4473(6) -0.1646(6) 0.1725(5) 0.034 Uiso 1 calc R .
B7 B 0.2840(6) -0.1771(6) 0.0608(5) 0.030(2) Uani 1 d U .
H7 H 0.2718(6) -0.2597(6) 0.0573(5) 0.036 Uiso 1 calc R .
B8 B 0.2600(7) -0.1013(6) -0.0139(5) 0.032(2) Uani 1 d U .
H8 H 0.2309(7) -0.1338(6) -0.0676(5) 0.038 Uiso 1 calc R .
B9 B 0.3514(6) -0.0001(6) 0.0066(4) 0.0262(15) Uani 1 d U .
H9 H 0.3821(6) 0.0349(6) -0.0331(4) 0.031 Uiso 1 calc R .
B10 B 0.3926(6) -0.1196(6) 0.0420(5) 0.028(2) Uani 1 d U .
H10 H 0.4514(6) -0.1646(6) 0.0259(5) 0.033 Uiso 1 calc R .
C1 C 0.2166(5) 0.0084(5) 0.0886(3) 0.0223(13) Uani 1 d U .
C2 C 0.3250(5) 0.0642(5) 0.0711(3) 0.0216(13) Uani 1 d U .
C3 C 0.3160(5) 0.2307(5) 0.3744(4) 0.0246(14) Uani 1 d U .
H3A H 0.3578(5) 0.2282(5) 0.4222(4) 0.030 Uiso 1 calc R .
C4 C 0.3277(5) 0.3113(5) 0.3397(3) 0.0213(13) Uani 1 d U .
H4A H 0.3800(5) 0.3574(5) 0.3655(3) 0.026 Uiso 1 calc R .
C11 C 0.3118(5) 0.0205(5) 0.3856(4) 0.0282(15) Uani 1 d DU .
C12 C 0.3137(6) -0.0144(6) 0.4491(4) 0.045(2) Uani 1 d DU .
H12 H 0.2706(6) 0.0162(6) 0.4725(4) 0.054 Uiso 1 calc R .
C13 C 0.3774(7) -0.0933(7) 0.4792(5) 0.059(2) Uani 1 d DU .
H13 H 0.3770(7) -0.1176(7) 0.5230(5) 0.070 Uiso 1 calc R .
C14 C 0.4417(7) -0.1380(6) 0.4473(5) 0.049(2) Uani 1 d DU .
H14 H 0.4862(7) -0.1923(6) 0.4688(5) 0.058 Uiso 1 calc R .
C15 C 0.4409(6) -0.1035(6) 0.3845(5) 0.044(2) Uani 1 d DU .
H15 H 0.4852(6) -0.1342(6) 0.3620(5) 0.053 Uiso 1 calc R .
C16 C 0.3770(6) -0.0247(6) 0.3527(4) 0.040(2) Uani 1 d DU .
H16 H 0.3772(6) -0.0012(6) 0.3087(4) 0.048 Uiso 1 calc R .
C21 C 0.1213(5) 0.1374(5) 0.3762(3) 0.0227(13) Uani 1 d DU .
C22 C 0.0228(5) 0.0965(6) 0.3412(4) 0.036(2) Uani 1 d DU .
H22 H 0.0120(5) 0.0614(6) 0.2989(4) 0.043 Uiso 1 calc R .
C23 C -0.0597(6) 0.1068(6) 0.3679(5) 0.048(2) Uani 1 d DU .
H23 H -0.1273(6) 0.0786(6) 0.3438(5) 0.057 Uiso 1 calc R .
C24 C -0.0442(6) 0.1577(7) 0.4293(4) 0.050(2) Uani 1 d DU .
H24 H -0.1005(6) 0.1638(7) 0.4481(4) 0.060 Uiso 1 calc R .
C25 C 0.0518(6) 0.1989(6) 0.4625(4) 0.043(2) Uani 1 d DU .
H25 H 0.0613(6) 0.2360(6) 0.5039(4) 0.051 Uiso 1 calc R .
C26 C 0.1353(6) 0.1884(6) 0.4382(4) 0.035(2) Uani 1 d DU .
H26 H 0.2028(6) 0.2159(6) 0.4634(4) 0.042 Uiso 1 calc R .
C31 C 0.1177(5) 0.3480(5) 0.2414(3) 0.0241(13) Uani 1 d DU .
C32 C 0.0832(5) 0.3664(5) 0.2979(4) 0.0291(15) Uani 1 d DU .
H32 H 0.1339(5) 0.3784(5) 0.3424(4) 0.035 Uiso 1 calc R .
C33 C -0.0241(6) 0.3675(5) 0.2898(5) 0.038(2) Uani 1 d DU .
H33 H -0.0472(6) 0.3810(5) 0.3285(5) 0.046 Uiso 1 calc R .
C34 C -0.0978(6) 0.3486(6) 0.2249(5) 0.046(2) Uani 1 d DU .
H34 H -0.1717(6) 0.3494(6) 0.2190(5) 0.055 Uiso 1 calc R .
C35 C -0.0645(6) 0.3286(6) 0.1684(5) 0.047(2) Uani 1 d DU .
H35 H -0.1154(6) 0.3154(6) 0.1241(5) 0.056 Uiso 1 calc R .
C36 C 0.0434(5) 0.3281(5) 0.1766(4) 0.033(2) Uani 1 d DU .
H36 H 0.0663(5) 0.3141(5) 0.1380(4) 0.040 Uiso 1 calc R .
C41 C 0.2971(5) 0.4767(5) 0.2512(3) 0.0250(14) Uani 1 d DU .
C42 C 0.2750(5) 0.5445(5) 0.2964(4) 0.0302(15) Uani 1 d DU .
H42 H 0.2366(5) 0.5235(5) 0.3260(4) 0.036 Uiso 1 calc R .
C43 C 0.3084(6) 0.6410(5) 0.2984(4) 0.037(2) Uani 1 d DU .
H43 H 0.2941(6) 0.6867(5) 0.3299(4) 0.045 Uiso 1 calc R .
C44 C 0.3619(6) 0.6724(5) 0.2555(4) 0.036(2) Uani 1 d DU .
H44 H 0.3844(6) 0.7398(5) 0.2571(4) 0.043 Uiso 1 calc R .
C45 C 0.3833(6) 0.6071(5) 0.2102(4) 0.040(2) Uani 1 d DU .
H45 H 0.4196(6) 0.6296(5) 0.1799(4) 0.048 Uiso 1 calc R .
C46 C 0.3523(6) 0.5085(5) 0.2085(4) 0.033(2) Uani 1 d DU .
H46 H 0.3690(6) 0.4628(5) 0.1779(4) 0.039 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 S1 177.96(6) . . y
P1 Au1 Au2 108.70(5) . . y
S1 Au1 Au2 73.21(4) . . y
P2 Au2 S2 168.11(6) . . y
P2 Au2 Au1 78.08(4) . . y
S2 Au2 Au1 113.74(4) . . y
C1 S1 Au1 105.7(2) . . y
C2 S2 Au2 108.3(2) . . y
C21 P1 C3 105.5(3) . . y
C21 P1 C11 107.8(3) . . y
C3 P1 C11 102.2(3) . . y
C21 P1 Au1 114.6(2) . . y
C3 P1 Au1 114.5(2) . . y
C11 P1 Au1 111.3(2) . . y
C31 P2 C4 105.7(3) . . y
C31 P2 C41 105.7(3) . . y
C4 P2 C41 100.5(3) . . y
C31 P2 Au2 114.1(2) . . y
C4 P2 Au2 116.6(2) . . y
C41 P2 Au2 113.0(2) . . y
C2 B1 C1 62.1(4) . . y
C2 B1 B6 106.6(5) . . y
C1 B1 B6 107.1(6) . . y
C2 B1 B2 108.5(6) . . y
C1 B1 B2 58.4(4) . . y
B6 B1 B2 61.0(4) . . y
C2 B1 B5 58.2(4) . . y
C1 B1 B5 108.3(5) . . y
B6 B1 B5 60.2(4) . . y
B2 B1 B5 109.3(6) . . y
C1 B2 B1 59.6(4) . . y
C1 B2 B6 106.7(5) . . y
B1 B2 B6 59.3(4) . . y
C1 B2 B7 105.9(6) . . y
B1 B2 B7 107.6(5) . . y
B6 B2 B7 61.1(5) . . y
C1 B2 B3 58.7(4) . . y
B1 B2 B3 107.3(5) . . y
B6 B2 B3 108.6(6) . . y
B7 B2 B3 59.6(5) . . y
C1 B3 B8 106.4(5) . . y
C1 B3 B7 106.0(6) . . y
B8 B3 B7 60.4(5) . . y
C1 B3 B2 58.3(4) . . y
B8 B3 B2 108.1(6) . . y
B7 B3 B2 60.2(5) . . y
C1 B3 B4 59.0(4) . . y
B8 B3 B4 60.6(4) . . y
B7 B3 B4 108.8(5) . . y
B2 B3 B4 107.2(5) . . y
C1 B4 C2 61.3(4) . . y
C1 B4 B8 104.2(6) . . y
C2 B4 B8 103.8(5) . . y
C1 B4 B3 58.0(4) . . y
C2 B4 B3 106.5(5) . . y
B8 B4 B3 58.9(4) . . y
C1 B4 B9 106.8(6) . . y
C2 B4 B9 57.4(4) . . y
B8 B4 B9 59.5(4) . . y
B3 B4 B9 107.2(6) . . y
C2 B5 B10 105.7(5) . . y
C2 B5 B6 105.7(5) . . y
B10 B5 B6 61.3(5) . . y
C2 B5 B9 58.7(4) . . y
B10 B5 B9 60.1(4) . . y
B6 B5 B9 109.0(6) . . y
C2 B5 B1 58.5(4) . . y
B10 B5 B1 107.0(5) . . y
B6 B5 B1 58.8(4) . . y
B9 B5 B1 106.4(5) . . y
B1 B6 B2 59.8(4) . . y
B1 B6 B5 61.0(4) . . y
B2 B6 B5 109.0(6) . . y
B1 B6 B7 106.7(6) . . y
B2 B6 B7 59.5(4) . . y
B5 B6 B7 107.3(6) . . y
B1 B6 B10 106.9(6) . . y
B2 B6 B10 107.1(6) . . y
B5 B6 B10 59.1(4) . . y
B7 B6 B10 59.4(5) . . y
B3 B7 B8 59.5(5) . . y
B3 B7 B2 60.1(4) . . y
B8 B7 B2 107.4(5) . . y
B3 B7 B10 107.9(6) . . y
B8 B7 B10 59.9(5) . . y
B2 B7 B10 107.8(6) . . y
B3 B7 B6 107.7(5) . . y
B8 B7 B6 107.6(6) . . y
B2 B7 B6 59.5(4) . . y
B10 B7 B6 60.2(5) . . y
B3 B8 B7 60.1(4) . . y
B3 B8 B10 108.7(6) . . y
B7 B8 B10 60.5(5) . . y
B3 B8 B9 109.4(5) . . y
B7 B8 B9 108.6(6) . . y
B10 B8 B9 59.7(4) . . y
B3 B8 B4 60.5(4) . . y
B7 B8 B4 108.4(6) . . y
B10 B8 B4 108.2(6) . . y
B9 B8 B4 60.7(4) . . y
C2 B9 B10 105.1(5) . . y
C2 B9 B8 105.7(5) . . y
B10 B9 B8 60.1(5) . . y
C2 B9 B5 58.4(4) . . y
B10 B9 B5 59.6(4) . . y
B8 B9 B5 107.4(6) . . y
C2 B9 B4 59.5(4) . . y
B10 B9 B4 107.8(5) . . y
B8 B9 B4 59.9(4) . . y
B5 B9 B4 107.6(5) . . y
B5 B10 B9 60.4(4) . . y
B5 B10 B8 108.2(5) . . y
B9 B10 B8 60.2(4) . . y
B5 B10 B7 108.4(5) . . y
B9 B10 B7 108.3(5) . . y
B8 B10 B7 59.6(5) . . y
B5 B10 B6 59.6(4) . . y
B9 B10 B6 107.8(5) . . y
B8 B10 B6 107.4(5) . . y
B7 B10 B6 60.4(5) . . y
B2 C1 B3 63.0(5) . . y
B2 C1 B1 61.9(4) . . y
B3 C1 B1 112.5(5) . . y
B2 C1 B4 114.1(5) . . y
B3 C1 B4 62.9(4) . . y
B1 C1 B4 110.6(5) . . y
B2 C1 C2 108.5(5) . . y
B3 C1 C2 109.2(5) . . y
B1 C1 C2 58.6(4) . . y
B4 C1 C2 60.0(4) . . y
B2 C1 S1 124.2(4) . . y
B3 C1 S1 119.0(4) . . y
B1 C1 S1 123.0(5) . . y
B4 C1 S1 113.3(5) . . y
C2 C1 S1 119.6(4) . . y
B5 C2 B1 63.3(4) . . y
B5 C2 B9 62.9(4) . . y
B1 C2 B9 113.6(5) . . y
B5 C2 B4 114.1(5) . . y
B1 C2 B4 110.1(5) . . y
B9 C2 B4 63.1(4) . . y
B5 C2 C1 110.1(5) . . y
B1 C2 C1 59.3(4) . . y
B9 C2 C1 109.3(5) . . y
B4 C2 C1 58.7(4) . . y
B5 C2 S2 119.0(4) . . y
B1 C2 S2 119.9(5) . . y
B9 C2 S2 118.6(4) . . y
B4 C2 S2 118.5(5) . . y
C1 C2 S2 122.4(4) . . y
C4 C3 P1 127.8(5) . . y
C3 C4 P2 129.2(5) . . y
C12 C11 C16 118.9(7) . . y
C12 C11 P1 123.6(6) . . y
C16 C11 P1 117.5(5) . . y
C11 C12 C13 120.3(8) . . y
C12 C13 C14 121.1(8) . . y
C15 C14 C13 119.0(8) . . y
C14 C15 C16 121.1(8) . . y
C15 C16 C11 119.5(7) . . y
C22 C21 C26 118.9(6) . . y
C22 C21 P1 120.0(5) . . y
C26 C21 P1 121.1(5) . . y
C23 C22 C21 120.0(7) . . y
C22 C23 C24 120.2(7) . . y
C25 C24 C23 119.5(7) . . y
C24 C25 C26 121.6(7) . . y
C25 C26 C21 119.8(7) . . y
C32 C31 C36 119.5(7) . . y
C32 C31 P2 122.0(5) . . y
C36 C31 P2 118.5(5) . . y
C33 C32 C31 120.8(7) . . y
C32 C33 C34 119.4(7) . . y
C35 C34 C33 120.5(7) . . y
C36 C35 C34 119.9(8) . . y
C35 C36 C31 120.0(7) . . y
C46 C41 C42 119.2(6) . . y
C46 C41 P2 119.9(5) . . y
C42 C41 P2 120.9(5) . . y
C43 C42 C41 120.1(6) . . y
C44 C43 C42 120.5(7) . . y
C43 C44 C45 120.2(7) . . y
C44 C45 C46 120.2(7) . . y
C41 C46 C45 119.8(7) . . y
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.249(2) . y
Au1 S1 2.301(2) . y
Au1 Au2 3.0195(5) . y
Au2 P2 2.265(2) . y
Au2 S2 2.309(2) . y
S1 C1 1.768(7) . y
S2 C2 1.778(6) . y
P1 C21 1.809(6) . y
P1 C3 1.818(7) . y
P1 C11 1.821(7) . y
P2 C31 1.814(7) . y
P2 C4 1.820(7) . y
P2 C41 1.826(7) . y
B1 C2 1.701(9) . y
B1 C1 1.713(10) . y
B1 B6 1.743(11) . y
B1 B2 1.752(11) . y
B1 B5 1.783(10) . y
B2 C1 1.691(10) . y
B2 B6 1.773(11) . y
B2 B7 1.773(11) . y
B2 B3 1.771(12) . y
B3 C1 1.698(10) . y
B3 B8 1.754(11) . y
B3 B7 1.763(11) . y
B3 B4 1.783(11) . y
B4 C1 1.717(10) . y
B4 C2 1.739(10) . y
B4 B8 1.785(11) . y
B4 B9 1.799(11) . y
B5 C2 1.696(9) . y
B5 B10 1.759(11) . y
B5 B6 1.768(10) . y
B5 B9 1.774(11) . y
B6 B7 1.802(12) . y
B6 B10 1.799(12) . y
B7 B8 1.769(12) . y
B7 B10 1.785(11) . y
B8 B10 1.775(12) . y
B8 B9 1.779(11) . y
B9 C2 1.701(10) . y
B9 B10 1.769(11) . y
C1 C2 1.762(8) . y
C3 C4 1.328(9) . y
C11 C12 1.366(10) . y
C11 C16 1.396(9) . y
C12 C13 1.369(10) . y
C13 C14 1.371(11) . y
C14 C15 1.356(11) . y
C15 C16 1.379(10) . y
C21 C22 1.383(9) . y
C21 C26 1.393(9) . y
C22 C23 1.381(9) . y
C23 C24 1.380(11) . y
C24 C25 1.352(10) . y
C25 C26 1.364(9) . y
C31 C32 1.392(9) . y
C31 C36 1.391(9) . y
C32 C33 1.383(9) . y
C33 C34 1.387(11) . y
C34 C35 1.387(11) . y
C35 C36 1.389(9) . y
C41 C46 1.376(9) . y
C41 C42 1.392(9) . y
C42 C43 1.366(9) . y
C43 C44 1.360(10) . y
C44 C45 1.368(10) . y
C45 C46 1.382(9) . y
