#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:34:46 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179336 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/33/4323310.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4323310
loop_
_publ_author_name
'Olga Crespo'
'M. Concepción Gimeno'
'Peter G. Jones'
'Birte Ahrens'
'Antonio Laguna'
_publ_contact_author
;
      For X-ray structures:
      Jones, Peter G.
      Institut für Analytische und Anorganische Chemie
      Technische Universität Braunschweig
      Postfach 3329
      38023 Braunschweig
      Germany
;
_publ_contact_author_email       jones@xray36.anchem.nat.tu-bs.de
_publ_contact_author_fax         '049 531 391-5387'
_publ_contact_author_phone       '049 531 391-5382'
_publ_section_title
;
 Synthesis and Characterization of Gold(I) Complexes with the Ligand
 1,2-Dithiolate-o-carborane. Crystal Structures of
 [Au₂(μ-S₂C₂B₁₀H₁₀)(PPh₃)₂],
 [Au₂(μ-S₂C₂B₁₀H₁₀)(μ-{(PPh₂)₂(CHCH)}], and
 [Au₂(μ-S₂C₂B₁₀H₁₀)(μ-{(PPh₂)₂)(C₆H₄)}]
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              495
_journal_page_last               500
_journal_paper_doi               10.1021/ic960822q
_journal_volume                  36
_journal_year                    1997
_chemical_formula_sum            'C32 H34 Au2 B10 P2 S2'
_chemical_formula_weight         1046.69
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     Patterson
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                114.113(15)
_cell_angle_beta                 91.63(2)
_cell_angle_gamma                115.010(12)
_cell_formula_units_Z            2
_cell_length_a                   11.921(3)
_cell_length_b                   12.894(4)
_cell_length_c                   14.342(4)
_cell_measurement_reflns_used    50
_cell_measurement_temperature    143(2)
_cell_measurement_theta_max      11.5
_cell_measurement_theta_min      10
_cell_volume                     1768.7(10)
_computing_cell_refinement       'Stoe DIF4'
_computing_data_collection       'Stoe DIF4'
_computing_data_reduction        'Stoe REDU4'
_computing_molecular_graphics    'Siemens XP'
_computing_publication_material  SHELXL-93
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      143(2)
_diffrn_measurement_device       'Stoe STADI-4'
_diffrn_measurement_method       ω/θ-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0374
_diffrn_reflns_av_sigmaI/netI    0.0482
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            8775
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         3.06
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    8.519
_exptl_absorpt_correction_T_max  0.843
_exptl_absorpt_correction_T_min  0.642
_exptl_absorpt_correction_type   Psi-scans
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.965
_exptl_crystal_description       prism
_exptl_crystal_F_000             992
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.669
_refine_diff_density_min         -1.378
_refine_diff_density_rms         0.165
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.046
_refine_ls_goodness_of_fit_obs   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         6220
_refine_ls_number_restraints     400
_refine_ls_restrained_S_all      1.034
_refine_ls_restrained_S_obs      1.010
_refine_ls_R_factor_all          0.0462
_refine_ls_R_factor_obs          0.0357
_refine_ls_shift/esd_max         0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0364P)²+6.0613P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0883
_refine_ls_wR_factor_obs         0.0793
_reflns_number_observed          5274
_reflns_number_total             6230
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic960822q_3.cif
_cod_data_source_block           occam
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0364P)^2^+6.0613P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0364P)^2^+6.0613P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        1768.7(9)
_cod_database_code               4323310
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Au1 Au 0.21622(3) 0.12753(3) 0.22119(2) 0.02197(9) Uani 1 d . .
Au2 Au 0.37779(3) 0.20597(3) 0.42457(2) 0.02367(9) Uani 1 d . .
P1 P 0.0271(2) 0.1087(2) 0.25605(14) 0.0213(4) Uani 1 d U .
P2 P 0.2583(2) 0.3022(2) 0.49504(13) 0.0196(4) Uani 1 d U .
S1 S 0.3827(2) 0.1039(2) 0.1536(2) 0.0309(4) Uani 1 d U .
S2 S 0.5230(2) 0.1282(2) 0.3848(2) 0.0338(5) Uani 1 d U .
B1 B 0.2751(8) -0.0952(8) 0.2328(6) 0.0237(15) Uani 1 d U .
H1 H 0.2204(8) -0.0482(8) 0.2783(6) 0.028 Uiso 1 calc R .
B2 B 0.2303(9) -0.1833(8) 0.0929(7) 0.028(2) Uani 1 d U .
H2 H 0.1437(9) -0.1989(8) 0.0447(7) 0.034 Uiso 1 calc R .
B3 B 0.3735(8) -0.1565(8) 0.0507(7) 0.027(2) Uani 1 d U .
H3 H 0.3836(8) -0.1552(8) -0.0263(7) 0.033 Uiso 1 calc R .
B4 B 0.5003(8) -0.0514(8) 0.1658(7) 0.026(2) Uani 1 d U .
H4 H 0.5938(8) 0.0236(8) 0.1668(7) 0.032 Uiso 1 calc R .
B5 B 0.2164(9) -0.2648(8) 0.1696(7) 0.030(2) Uani 1 d U .
H5 H 0.1210(9) -0.3343(8) 0.1712(7) 0.035 Uiso 1 calc R .
B6 B 0.2807(9) -0.3016(9) 0.0581(7) 0.033(2) Uani 1 d U .
H6 H 0.2281(9) -0.3972(9) -0.0143(7) 0.039 Uiso 1 calc R .
B7 B 0.4505(9) -0.2183(8) 0.1021(6) 0.027(2) Uani 1 d U .
H7 H 0.5116(9) -0.2575(8) 0.0588(6) 0.033 Uiso 1 calc R .
B8 B 0.4902(9) -0.1337(8) 0.2412(7) 0.028(2) Uani 1 d U .
H8 H 0.5774(9) -0.1169(8) 0.2896(7) 0.033 Uiso 1 calc R .
B9 B 0.3457(9) -0.1621(9) 0.2837(7) 0.028(2) Uani 1 d U .
H9 H 0.3351(9) -0.1645(9) 0.3603(7) 0.034 Uiso 1 calc R .
B10 B 0.3525(9) -0.2889(9) 0.1743(7) 0.030(2) Uani 1 d U .
H10 H 0.3479(9) -0.3754(9) 0.1785(7) 0.036 Uiso 1 calc R .
C1 C 0.3631(7) -0.0394(7) 0.1541(5) 0.0227(13) Uani 1 d U .
C2 C 0.4367(7) -0.0249(7) 0.2751(5) 0.0237(14) Uani 1 d U .
C11 C -0.0865(7) -0.0553(7) 0.1602(5) 0.0246(15) Uani 1 d DU .
C12 C -0.1764(7) -0.0872(7) 0.0767(5) 0.029(2) Uani 1 d DU .
H12 H -0.1872(7) -0.0211(7) 0.0707(5) 0.035 Uiso 1 calc R .
C13 C -0.2512(8) -0.2149(7) 0.0015(6) 0.035(2) Uani 1 d DU .
H13 H -0.3140(8) -0.2359(7) -0.0549(6) 0.042 Uiso 1 calc R .
C14 C -0.2351(8) -0.3104(8) 0.0080(6) 0.033(2) Uani 1 d DU .
H14 H -0.2869(8) -0.3977(8) -0.0437(6) 0.039 Uiso 1 calc R .
C15 C -0.1444(8) -0.2811(8) 0.0890(6) 0.037(2) Uani 1 d DU .
H15 H -0.1313(8) -0.3474(8) 0.0921(6) 0.044 Uiso 1 calc R .
C16 C -0.0724(7) -0.1547(7) 0.1656(6) 0.030(2) Uani 1 d DU .
H16 H -0.0122(7) -0.1351(7) 0.2231(6) 0.036 Uiso 1 calc R .
C21 C -0.0214(7) 0.2162(7) 0.2379(5) 0.0274(15) Uani 1 d DU .
C22 C 0.0467(8) 0.2877(7) 0.1899(6) 0.032(2) Uani 1 d DU .
H22 H 0.1187(8) 0.2813(7) 0.1672(6) 0.038 Uiso 1 calc R .
C23 C 0.0092(9) 0.3694(8) 0.1748(6) 0.040(2) Uani 1 d DU .
H23 H 0.0563(9) 0.4191(8) 0.1422(6) 0.048 Uiso 1 calc R .
C24 C -0.0952(8) 0.3789(9) 0.2065(6) 0.045(2) Uani 1 d DU .
H24 H -0.1191(8) 0.4362(9) 0.1973(6) 0.054 Uiso 1 calc R .
C25 C -0.1641(8) 0.3054(8) 0.2514(7) 0.042(2) Uani 1 d DU .
H25 H -0.2377(8) 0.3101(8) 0.2714(7) 0.050 Uiso 1 calc R .
C26 C -0.1289(8) 0.2243(8) 0.2682(6) 0.035(2) Uani 1 d DU .
H26 H -0.1774(8) 0.1742(8) 0.3002(6) 0.042 Uiso 1 calc R .
C31 C 0.2592(7) 0.4201(7) 0.4575(5) 0.0225(14) Uani 1 d DU .
C32 C 0.1751(7) 0.4700(7) 0.4860(5) 0.029(2) Uani 1 d DU .
H32 H 0.1168(7) 0.4417(7) 0.5249(5) 0.034 Uiso 1 calc R .
C33 C 0.1764(8) 0.5608(7) 0.4575(6) 0.036(2) Uani 1 d DU .
H33 H 0.1199(8) 0.5957(7) 0.4778(6) 0.043 Uiso 1 calc R .
C34 C 0.2597(8) 0.6008(8) 0.3996(6) 0.038(2) Uani 1 d DU .
H34 H 0.2590(8) 0.6618(8) 0.3789(6) 0.045 Uiso 1 calc R .
C35 C 0.3438(8) 0.5528(8) 0.3718(6) 0.036(2) Uani 1 d DU .
H35 H 0.4019(8) 0.5811(8) 0.3327(6) 0.044 Uiso 1 calc R .
C36 C 0.3431(7) 0.4624(7) 0.4014(5) 0.028(2) Uani 1 d DU .
H36 H 0.4014(7) 0.4295(7) 0.3825(5) 0.034 Uiso 1 calc R .
C41 C 0.3252(6) 0.3880(6) 0.6367(5) 0.0192(14) Uani 1 d DU .
C42 C 0.3596(7) 0.5175(7) 0.6990(5) 0.0235(15) Uani 1 d DU .
H42 H 0.3508(7) 0.5674(7) 0.6683(5) 0.028 Uiso 1 calc R .
C43 C 0.4066(8) 0.5723(7) 0.8062(5) 0.031(2) Uani 1 d DU .
H43 H 0.4294(8) 0.6603(7) 0.8498(5) 0.038 Uiso 1 calc R .
C44 C 0.4209(8) 0.5012(7) 0.8504(6) 0.033(2) Uani 1 d DU .
H44 H 0.4542(8) 0.5413(7) 0.9243(6) 0.039 Uiso 1 calc R .
C45 C 0.3885(7) 0.3736(7) 0.7908(5) 0.026(2) Uani 1 d DU .
H45 H 0.3981(7) 0.3251(7) 0.8225(5) 0.032 Uiso 1 calc R .
C46 C 0.3412(7) 0.3171(7) 0.6828(5) 0.025(2) Uani 1 d DU .
H46 H 0.3194(7) 0.2292(7) 0.6400(5) 0.030 Uiso 1 calc R .
C51 C -0.0032(7) 0.1176(7) 0.3831(5) 0.0222(14) Uani 1 d DU .
C52 C 0.0890(7) 0.2013(6) 0.4807(5) 0.0219(14) Uani 1 d DU .
C53 C 0.0464(7) 0.2093(7) 0.5719(5) 0.030(2) Uani 1 d DU .
H53 H 0.1068(7) 0.2630(7) 0.6381(5) 0.037 Uiso 1 calc R .
C54 C -0.0817(7) 0.1410(8) 0.5687(6) 0.037(2) Uani 1 d DU .
H54 H -0.1083(7) 0.1522(8) 0.6324(6) 0.044 Uiso 1 calc R .
C55 C -0.1694(7) 0.0576(7) 0.4738(6) 0.034(2) Uani 1 d DU .
H55 H -0.2565(7) 0.0084(7) 0.4710(6) 0.040 Uiso 1 calc R .
C56 C -0.1295(7) 0.0459(7) 0.3817(5) 0.028(2) Uani 1 d DU .
H56 H -0.1904(7) -0.0128(7) 0.3159(5) 0.033 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 S1 167.50(7) . . y
P1 Au1 Au2 104.88(5) . . y
S1 Au1 Au2 83.86(6) . . y
P2 Au2 S2 169.18(7) . . y
P2 Au2 Au1 83.41(5) . . y
S2 Au2 Au1 107.27(5) . . y
C21 P1 C11 107.6(3) . . y
C21 P1 C51 105.0(3) . . y
C11 P1 C51 104.3(3) . . y
C21 P1 Au1 115.8(3) . . y
C11 P1 Au1 103.4(2) . . y
C51 P1 Au1 119.6(2) . . y
C31 P2 C41 106.4(3) . . y
C31 P2 C52 103.6(3) . . y
C41 P2 C52 103.7(3) . . y
C31 P2 Au2 117.1(2) . . y
C41 P2 Au2 105.6(2) . . y
C52 P2 Au2 119.1(2) . . y
C1 S1 Au1 102.4(2) . . y
C2 S2 Au2 105.1(2) . . y
C2 B1 C1 64.2(5) . . y
C2 B1 B9 58.8(5) . . y
C1 B1 B9 110.2(6) . . y
C2 B1 B5 107.2(6) . . y
C1 B1 B5 105.9(6) . . y
B9 B1 B5 60.6(5) . . y
C2 B1 B2 109.3(6) . . y
C1 B1 B2 57.3(4) . . y
B9 B1 B2 109.4(6) . . y
B5 B1 B2 59.9(5) . . y
C1 B2 B6 106.4(6) . . y
C1 B2 B3 58.3(5) . . y
B6 B2 B3 60.3(5) . . y
C1 B2 B5 107.9(6) . . y
B6 B2 B5 60.0(5) . . y
B3 B2 B5 108.5(7) . . y
C1 B2 B1 59.8(4) . . y
B6 B2 B1 106.7(6) . . y
B3 B2 B1 106.6(6) . . y
B5 B2 B1 59.9(5) . . y
C1 B3 B7 106.9(6) . . y
C1 B3 B2 58.2(4) . . y
B7 B3 B2 108.1(7) . . y
C1 B3 B4 59.5(4) . . y
B7 B3 B4 59.9(5) . . y
B2 B3 B4 106.6(6) . . y
C1 B3 B6 105.7(6) . . y
B7 B3 B6 60.7(5) . . y
B2 B3 B6 59.7(5) . . y
B4 B3 B6 107.6(6) . . y
C1 B4 C2 63.9(4) . . y
C1 B4 B7 105.2(6) . . y
C2 B4 B7 105.4(6) . . y
C1 B4 B3 57.7(4) . . y
C2 B4 B3 108.8(6) . . y
B7 B4 B3 59.5(5) . . y
C1 B4 B8 108.5(6) . . y
C2 B4 B8 57.3(5) . . y
B7 B4 B8 60.0(5) . . y
B3 B4 B8 108.3(6) . . y
B6 B5 B1 106.7(6) . . y
B6 B5 B2 59.7(5) . . y
B1 B5 B2 60.2(5) . . y
B6 B5 B9 107.9(7) . . y
B1 B5 B9 59.2(5) . . y
B2 B5 B9 108.4(6) . . y
B6 B5 B10 59.6(5) . . y
B1 B5 B10 106.2(6) . . y
B2 B5 B10 107.5(7) . . y
B9 B5 B10 60.0(5) . . y
B2 B6 B10 108.7(6) . . y
B2 B6 B5 60.3(5) . . y
B10 B6 B5 60.5(5) . . y
B2 B6 B3 60.0(5) . . y
B10 B6 B3 108.5(6) . . y
B5 B6 B3 108.6(6) . . y
B2 B6 B7 107.1(6) . . y
B10 B6 B7 60.6(5) . . y
B5 B6 B7 108.3(6) . . y
B3 B6 B7 59.1(5) . . y
B3 B7 B4 60.6(5) . . y
B3 B7 B8 109.4(6) . . y
B4 B7 B8 60.3(5) . . y
B3 B7 B6 60.2(5) . . y
B4 B7 B6 107.8(6) . . y
B8 B7 B6 107.8(6) . . y
B3 B7 B10 108.3(6) . . y
B4 B7 B10 108.0(6) . . y
B8 B7 B10 60.2(5) . . y
B6 B7 B10 59.2(5) . . y
C2 B8 B7 107.2(6) . . y
C2 B8 B4 60.1(5) . . y
B7 B8 B4 59.6(5) . . y
C2 B8 B9 58.6(5) . . y
B7 B8 B9 108.2(6) . . y
B4 B8 B9 107.4(6) . . y
C2 B8 B10 106.3(6) . . y
B7 B8 B10 60.5(5) . . y
B4 B8 B10 107.7(6) . . y
B9 B8 B10 59.8(5) . . y
C2 B9 B1 59.2(5) . . y
C2 B9 B10 105.8(6) . . y
B1 B9 B10 107.0(6) . . y
C2 B9 B5 107.1(6) . . y
B1 B9 B5 60.2(5) . . y
B10 B9 B5 60.1(5) . . y
C2 B9 B8 57.7(5) . . y
B1 B9 B8 105.6(6) . . y
B10 B9 B8 60.1(5) . . y
B5 B9 B8 107.8(6) . . y
B6 B10 B9 108.1(6) . . y
B6 B10 B5 59.8(5) . . y
B9 B10 B5 60.0(5) . . y
B6 B10 B8 107.8(6) . . y
B9 B10 B8 60.1(5) . . y
B5 B10 B8 107.7(6) . . y
B6 B10 B7 60.2(5) . . y
B9 B10 B7 107.4(6) . . y
B5 B10 B7 107.5(6) . . y
B8 B10 B7 59.3(5) . . y
B2 C1 B3 63.5(5) . . y
B2 C1 B4 113.5(6) . . y
B3 C1 B4 62.8(5) . . y
B2 C1 B1 62.9(5) . . y
B3 C1 B1 113.0(6) . . y
B4 C1 B1 107.9(6) . . y
B2 C1 S1 125.2(5) . . y
B3 C1 S1 122.0(5) . . y
B4 C1 S1 115.3(5) . . y
B1 C1 S1 120.7(5) . . y
B2 C1 C2 108.3(5) . . y
B3 C1 C2 108.6(5) . . y
B4 C1 C2 58.4(4) . . y
B1 C1 C2 57.3(4) . . y
S1 C1 C2 117.5(5) . . y
B8 C2 B9 63.7(5) . . y
B8 C2 B1 112.6(6) . . y
B9 C2 B1 62.0(5) . . y
B8 C2 B4 62.6(5) . . y
B9 C2 B4 113.4(6) . . y
B1 C2 B4 108.3(5) . . y
B8 C2 S2 121.0(5) . . y
B9 C2 S2 123.7(5) . . y
B1 C2 S2 121.1(5) . . y
B4 C2 S2 116.4(5) . . y
B8 C2 C1 107.8(5) . . y
B9 C2 C1 108.3(5) . . y
B1 C2 C1 58.5(4) . . y
B4 C2 C1 57.7(4) . . y
S2 C2 C1 119.6(5) . . y
C12 C11 C16 118.0(7) . . ?
C12 C11 P1 124.5(6) . . ?
C16 C11 P1 117.1(5) . . ?
C11 C12 C13 120.6(7) . . ?
C14 C13 C12 120.4(7) . . ?
C13 C14 C15 120.3(7) . . ?
C14 C15 C16 119.5(8) . . ?
C15 C16 C11 121.2(7) . . ?
C22 C21 C26 119.6(8) . . ?
C22 C21 P1 119.2(6) . . ?
C26 C21 P1 121.2(6) . . ?
C21 C22 C23 119.5(8) . . ?
C24 C23 C22 120.8(8) . . ?
C25 C24 C23 119.4(8) . . ?
C24 C25 C26 121.2(8) . . ?
C25 C26 C21 119.5(8) . . ?
C36 C31 C32 119.2(7) . . ?
C36 C31 P2 120.6(6) . . ?
C32 C31 P2 120.2(5) . . ?
C33 C32 C31 120.0(7) . . ?
C34 C33 C32 120.1(8) . . ?
C35 C34 C33 120.3(8) . . ?
C34 C35 C36 119.4(8) . . ?
C31 C36 C35 120.9(7) . . ?
C42 C41 C46 119.8(6) . . ?
C42 C41 P2 123.5(5) . . ?
C46 C41 P2 116.7(5) . . ?
C43 C42 C41 118.8(7) . . ?
C44 C43 C42 120.7(7) . . ?
C43 C44 C45 121.7(7) . . ?
C44 C45 C46 118.3(7) . . ?
C45 C46 C41 120.7(6) . . ?
C56 C51 C52 119.4(6) . . ?
C56 C51 P1 115.6(5) . . ?
C52 C51 P1 124.6(5) . . ?
C53 C52 C51 117.4(6) . . ?
C53 C52 P2 118.2(5) . . ?
C51 C52 P2 124.4(5) . . ?
C54 C53 C52 122.1(6) . . ?
C55 C54 C53 119.9(7) . . ?
C54 C55 C56 119.3(6) . . ?
C55 C56 C51 121.8(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.257(2) . y
Au1 S1 2.313(2) . y
Au1 Au2 2.9771(10) . y
Au2 P2 2.267(2) . y
Au2 S2 2.321(2) . y
P1 C21 1.813(8) . y
P1 C11 1.815(7) . y
P1 C51 1.835(7) . y
P2 C31 1.804(7) . y
P2 C41 1.820(6) . y
P2 C52 1.830(7) . y
S1 C1 1.765(7) . y
S2 C2 1.756(7) . y
B1 C2 1.705(11) . y
B1 C1 1.728(11) . y
B1 B9 1.754(12) . y
B1 B5 1.773(12) . y
B1 B2 1.779(11) . y
B2 C1 1.681(11) . y
B2 B6 1.764(13) . y
B2 B3 1.770(12) . y
B2 B5 1.775(13) . y
B3 C1 1.684(10) . y
B3 B7 1.754(12) . y
B3 B4 1.773(12) . y
B3 B6 1.776(13) . y
B4 C1 1.717(11) . y
B4 C2 1.731(11) . y
B4 B7 1.760(12) . y
B4 B8 1.773(13) . y
B5 B6 1.769(13) . y
B5 B9 1.780(12) . y
B5 B10 1.781(13) . y
B6 B10 1.766(13) . y
B6 B7 1.784(13) . y
B7 B8 1.767(11) . y
B7 B10 1.790(13) . y
B8 C2 1.681(11) . y
B8 B9 1.784(13) . y
B8 B10 1.784(13) . y
B9 C2 1.699(12) . y
B9 B10 1.780(12) . y
C1 C2 1.824(10) . y
C11 C12 1.380(9) . ?
C11 C16 1.392(10) . ?
C12 C13 1.386(9) . ?
C13 C14 1.362(10) . ?
C14 C15 1.373(10) . ?
C15 C16 1.379(10) . ?
C21 C22 1.380(10) . ?
C21 C26 1.396(10) . ?
C22 C23 1.390(10) . ?
C23 C24 1.373(11) . ?
C24 C25 1.363(12) . ?
C25 C26 1.379(11) . ?
C31 C36 1.375(9) . ?
C31 C32 1.393(9) . ?
C32 C33 1.384(10) . ?
C33 C34 1.379(11) . ?
C34 C35 1.377(11) . ?
C35 C36 1.390(10) . ?
C41 C42 1.392(9) . ?
C41 C46 1.395(9) . ?
C42 C43 1.381(9) . ?
C43 C44 1.368(10) . ?
C44 C45 1.372(10) . ?
C45 C46 1.388(9) . ?
C51 C56 1.389(10) . ?
C51 C52 1.416(9) . ?
C52 C53 1.397(9) . ?
C53 C54 1.391(10) . ?
C54 C55 1.369(11) . ?
C55 C56 1.388(10) . ?
