#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:35:57 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179337 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/34/4323431.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4323431
loop_
_publ_author_name
'G. Attilio Ardizzoia'
'Girolamo La Monica'
'Angelo Maspero'
'Massimo Moret'
'Norberto Masciocchi'
_publ_contact_author             'G.Attilio Ardizzoia'
_publ_contact_author_email       attilio@csmtbo.mi.cnr.it
_publ_section_title
;
 Silver(I) Pyrazolates. Synthesis and X-ray and 31P-NMR Characterization
 of Triphenylphosphine Complexes and Their Reactivity toward
 Heterocumulenes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2321
_journal_page_last               2328
_journal_paper_doi               10.1021/ic960908j
_journal_volume                  36
_journal_year                    1997
_chemical_formula_sum            'C60 H51 Ag2 N4 P3'
_chemical_formula_weight         1136.70
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                101.840(10)
_cell_angle_beta                 99.83(2)
_cell_angle_gamma                100.68(2)
_cell_formula_units_Z            2
_cell_length_a                   9.752(2)
_cell_length_b                   14.163(2)
_cell_length_c                   20.450(2)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      14
_cell_measurement_theta_min      10
_cell_volume                     2651.8(8)
_computing_molecular_graphics    'ORTEP (Johnson)'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       CAD-4
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.8317
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            9280
_diffrn_reflns_theta_max         24.96
_diffrn_reflns_theta_min         3.02
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  7200
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.871
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.81
_exptl_absorpt_correction_type   psi-scans
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.424
_exptl_crystal_description       prism
_exptl_crystal_F_000             1156
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.07
_refine_diff_density_max         0.298
_refine_diff_density_min         -0.442
_refine_diff_density_rms         0.057
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   0.957
_refine_ls_goodness_of_fit_obs   1.058
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         9280
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.957
_refine_ls_restrained_S_obs      1.058
_refine_ls_R_factor_all          0.0468
_refine_ls_R_factor_obs          0.0253
_refine_ls_shift/esd_max         0.548
_refine_ls_shift/esd_mean        0.135
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0359P)²+1.3495P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0674
_refine_ls_wR_factor_obs         0.0645
_reflns_number_observed          7075
_reflns_number_total             9280
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic960908j_2.cif
_cod_data_source_block           Complex2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0359P)^2^+1.3495P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0359P)^2^+1.3495P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2651.8(7)
_cod_database_code               4323431
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Ag1 Ag 0.16345(2) 0.116311(13) 0.293683(9) 0.04025(6) Uani 1 d . .
Ag2 Ag 0.21723(2) -0.112751(15) 0.186116(10) 0.05330(7) Uani 1 d . .
P1 P 0.27740(7) 0.28417(4) 0.36839(3) 0.03914(14) Uani 1 d . .
P2 P -0.08180(6) 0.03206(4) 0.29261(3) 0.03915(14) Uani 1 d . .
P3 P 0.14399(8) -0.27466(5) 0.11318(4) 0.0528(2) Uani 1 d . .
N1 N 0.1887(2) 0.1044(2) 0.18295(10) 0.0456(5) Uani 1 d . .
N2 N 0.1658(2) 0.0114(2) 0.14171(10) 0.0463(5) Uani 1 d . .
N3 N 0.3296(2) 0.03034(15) 0.33154(11) 0.0466(5) Uani 1 d . .
N4 N 0.3400(2) -0.0557(2) 0.29093(10) 0.0459(5) Uani 1 d . .
C1 C 0.1884(4) 0.1664(2) 0.1426(2) 0.0706(9) Uani 1 d . .
H1 H 0.2011(4) 0.2346(2) 0.1578(2) 0.085 Uiso 1 calc R .
C2 C 0.1666(5) 0.1162(3) 0.0753(2) 0.0930(12) Uani 1 d . .
H2 H 0.1624(5) 0.1424(3) 0.0371(2) 0.112 Uiso 1 calc R .
C3 C 0.1524(3) 0.0193(3) 0.07737(15) 0.0674(8) Uani 1 d . .
H3 H 0.1357(3) -0.0336(3) 0.03932(15) 0.081 Uiso 1 calc R .
C4 C 0.4016(3) 0.0366(2) 0.39442(15) 0.0630(8) Uani 1 d . .
H4 H 0.4108(3) 0.0886(2) 0.43217(15) 0.076 Uiso 1 calc R .
C5 C 0.4603(4) -0.0438(2) 0.3960(2) 0.0700(9) Uani 1 d . .
H5 H 0.5160(4) -0.0571(2) 0.4331(2) 0.084 Uiso 1 calc R .
C6 C 0.4178(3) -0.0998(2) 0.32996(15) 0.0576(7) Uani 1 d . .
H6 H 0.4401(3) -0.1603(2) 0.31444(15) 0.069 Uiso 1 calc R .
C7 C 0.3326(2) 0.27997(12) 0.45752(6) 0.0420(5) Uani 1 d G .
C8 C 0.47287(15) 0.31346(13) 0.49475(8) 0.0521(6) Uani 1 d G .
H8 H 0.5441(2) 0.3405(2) 0.47454(12) 0.062 Uiso 1 calc R .
C9 C 0.5067(2) 0.30649(15) 0.56217(8) 0.0656(8) Uani 1 d G .
H9 H 0.6005(2) 0.3289(2) 0.58708(11) 0.079 Uiso 1 calc R .
C10 C 0.4001(2) 0.2660(2) 0.59236(7) 0.0690(9) Uani 1 d G .
H10 H 0.4227(3) 0.2614(2) 0.63747(8) 0.083 Uiso 1 calc R .
C11 C 0.2598(2) 0.23255(14) 0.55514(9) 0.0680(8) Uani 1 d G .
H11 H 0.1886(3) 0.2055(2) 0.57534(12) 0.082 Uiso 1 calc R .
C12 C 0.22606(14) 0.23952(13) 0.48771(9) 0.0562(7) Uani 1 d G .
H12 H 0.13219(15) 0.2171(2) 0.46281(12) 0.067 Uiso 1 calc R .
C13 C 0.1881(2) 0.38834(12) 0.37569(9) 0.0462(6) Uani 1 d G .
C14 C 0.1324(2) 0.4108(2) 0.31500(8) 0.0734(9) Uani 1 d G .
H14 H 0.1390(3) 0.3727(2) 0.27331(8) 0.088 Uiso 1 calc R .
C15 C 0.0669(2) 0.4901(2) 0.31662(11) 0.0941(13) Uani 1 d G .
H15 H 0.0296(4) 0.5052(3) 0.27601(14) 0.113 Uiso 1 calc R .
C16 C 0.0570(2) 0.54710(14) 0.37892(15) 0.0890(12) Uani 1 d G .
H16 H 0.0132(3) 0.6002(2) 0.3800(2) 0.107 Uiso 1 calc R .
C17 C 0.1127(3) 0.52467(14) 0.43962(11) 0.0812(10) Uani 1 d G .
H17 H 0.1061(4) 0.5628(2) 0.48130(13) 0.097 Uiso 1 calc R .
C18 C 0.1783(2) 0.44529(14) 0.43800(8) 0.0657(8) Uani 1 d G .
H18 H 0.2156(3) 0.4303(2) 0.47861(9) 0.079 Uiso 1 calc R .
C19 C 0.4416(2) 0.33645(11) 0.34429(9) 0.0420(5) Uani 1 d G .
C20 C 0.5101(2) 0.43614(11) 0.36744(9) 0.0599(7) Uani 1 d G .
H20 H 0.4741(3) 0.47871(14) 0.39750(13) 0.072 Uiso 1 calc R .
C21 C 0.6325(2) 0.47218(10) 0.34567(12) 0.0796(10) Uani 1 d G .
H21 H 0.6784(3) 0.53888(11) 0.3612(2) 0.095 Uiso 1 calc R .
C22 C 0.6863(2) 0.40855(15) 0.30075(12) 0.0814(10) Uani 1 d G .
H22 H 0.7682(2) 0.4327(2) 0.2862(2) 0.098 Uiso 1 calc R .
C23 C 0.6178(2) 0.30887(13) 0.27759(10) 0.0689(8) Uani 1 d G .
H23 H 0.6538(3) 0.2663(2) 0.24753(14) 0.083 Uiso 1 calc R .
C24 C 0.4954(2) 0.27282(9) 0.29936(9) 0.0526(7) Uani 1 d G .
H24 H 0.4495(3) 0.20613(10) 0.28386(13) 0.063 Uiso 1 calc R .
C25 C -0.1119(2) -0.10155(9) 0.28720(9) 0.0429(6) Uani 1 d G .
C26 C 0.00534(14) -0.13866(12) 0.30936(10) 0.0562(7) Uani 1 d G .
H26 H 0.0943(2) -0.0958(2) 0.32835(14) 0.067 Uiso 1 calc R .
C27 C -0.0104(2) -0.23989(13) 0.30314(11) 0.0738(9) Uani 1 d G .
H27 H 0.0681(2) -0.2647(2) 0.3180(2) 0.089 Uiso 1 calc R .
C28 C -0.1433(2) -0.30399(9) 0.27476(11) 0.0742(10) Uani 1 d G .
H28 H -0.1538(3) -0.37172(9) 0.2706(2) 0.089 Uiso 1 calc R .
C29 C -0.2605(2) -0.26688(11) 0.25260(10) 0.0682(9) Uani 1 d G .
H29 H -0.3494(2) -0.3098(2) 0.23361(15) 0.082 Uiso 1 calc R .
C30 C -0.24480(15) -0.16566(12) 0.25882(10) 0.0569(7) Uani 1 d G .
H30 H -0.3232(2) -0.1408(2) 0.24399(14) 0.068 Uiso 1 calc R .
C31 C -0.22281(14) 0.03716(13) 0.22268(7) 0.0430(6) Uani 1 d G .
C32 C -0.3600(2) 0.04376(14) 0.23019(8) 0.0523(7) Uani 1 d G .
H32 H -0.3819(2) 0.0511(2) 0.27320(9) 0.063 Uiso 1 calc R .
C33 C -0.46439(13) 0.03940(15) 0.17343(10) 0.0626(8) Uani 1 d G .
H33 H -0.55616(15) 0.0438(2) 0.17846(13) 0.075 Uiso 1 calc R .
C34 C -0.4317(2) 0.0284(2) 0.10915(8) 0.0712(9) Uani 1 d G .
H34 H -0.5015(2) 0.0255(2) 0.07116(10) 0.085 Uiso 1 calc R .
C35 C -0.2945(2) 0.0218(2) 0.10163(7) 0.0782(10) Uani 1 d G .
H35 H -0.2726(3) 0.0145(3) 0.05862(8) 0.094 Uiso 1 calc R .
C36 C -0.19008(14) 0.0262(2) 0.15839(9) 0.0587(7) Uani 1 d G .
H36 H -0.0983(2) 0.0218(2) 0.15336(12) 0.070 Uiso 1 calc R .
C37 C -0.1366(2) 0.08300(13) 0.37088(8) 0.0486(6) Uani 1 d G .
C38 C -0.1654(2) 0.17676(13) 0.37936(11) 0.0753(10) Uani 1 d G .
H38 H -0.1627(4) 0.2095(2) 0.34442(14) 0.090 Uiso 1 calc R .
C39 C -0.1981(3) 0.22152(15) 0.44007(14) 0.105(2) Uani 1 d G .
H39 H -0.2173(4) 0.2843(2) 0.4458(2) 0.126 Uiso 1 calc R .
C40 C -0.2020(3) 0.1725(2) 0.49230(10) 0.109(2) Uani 1 d G .
H40 H -0.2239(4) 0.2025(3) 0.53292(13) 0.131 Uiso 1 calc R .
C41 C -0.1733(3) 0.0788(2) 0.48382(9) 0.0978(13) Uani 1 d G .
H41 H -0.1759(4) 0.0460(3) 0.51876(12) 0.117 Uiso 1 calc R .
C42 C -0.1406(2) 0.03400(13) 0.42311(10) 0.0692(8) Uani 1 d G .
H42 H -0.1214(4) -0.0287(2) 0.4174(2) 0.083 Uiso 1 calc R .
C43 C 0.2215(2) -0.37334(12) 0.13897(9) 0.0536(7) Uani 1 d G .
C44 C 0.2719(2) -0.36271(13) 0.20851(8) 0.0672(8) Uani 1 d G .
H44 H 0.2626(4) -0.3081(2) 0.24014(10) 0.081 Uiso 1 calc R .
C45 C 0.3361(3) -0.4337(2) 0.23076(8) 0.0817(10) Uani 1 d G .
H45 H 0.3697(4) -0.4265(2) 0.27728(8) 0.098 Uiso 1 calc R .
C46 C 0.3499(2) -0.51523(14) 0.18347(12) 0.0778(10) Uani 1 d G .
H46 H 0.3929(3) -0.5627(2) 0.1984(2) 0.093 Uiso 1 calc R .
C47 C 0.2996(3) -0.52586(13) 0.11394(10) 0.0808(10) Uani 1 d G .
H47 H 0.3088(4) -0.5804(2) 0.08230(13) 0.097 Uiso 1 calc R .
C48 C 0.2354(2) -0.45492(14) 0.09169(7) 0.0699(9) Uani 1 d G .
H48 H 0.2017(4) -0.4620(2) 0.04517(7) 0.084 Uiso 1 calc R .
C49 C 0.1808(2) -0.2793(2) 0.02855(8) 0.0571(7) Uani 1 d G .
C50 C 0.3216(2) -0.2428(2) 0.02577(12) 0.0863(11) Uani 1 d G .
H50 H 0.3916(3) -0.2186(3) 0.0660(2) 0.104 Uiso 1 calc R .
C51 C 0.3578(3) -0.2426(2) -0.0371(2) 0.117(2) Uani 1 d G .
H51 H 0.4520(3) -0.2182(3) -0.0389(2) 0.141 Uiso 1 calc R .
C52 C 0.2532(4) -0.2789(2) -0.09712(12) 0.123(2) Uani 1 d G .
H52 H 0.2774(5) -0.2788(3) -0.13917(15) 0.147 Uiso 1 calc R .
C53 C 0.1124(3) -0.3154(2) -0.09434(9) 0.112(2) Uani 1 d G .
H53 H 0.0424(4) -0.3397(3) -0.13452(10) 0.135 Uiso 1 calc R .
C54 C 0.0762(2) -0.3156(2) -0.03150(11) 0.0783(10) Uani 1 d G .
H54 H -0.0181(2) -0.3400(3) -0.0296(2) 0.094 Uiso 1 calc R .
C55 C -0.0496(2) -0.31861(14) 0.09789(10) 0.0577(7) Uani 1 d G .
C56 C -0.1169(2) -0.41539(13) 0.09497(11) 0.0714(9) Uani 1 d G .
H56 H -0.0627(3) -0.4617(2) 0.1012(2) 0.086 Uiso 1 calc R .
C57 C -0.2651(2) -0.44295(15) 0.08281(13) 0.0905(12) Uani 1 d G .
H57 H -0.3101(3) -0.5077(2) 0.0809(2) 0.109 Uiso 1 calc R .
C58 C -0.3461(2) -0.3737(2) 0.07357(13) 0.0963(13) Uani 1 d G .
H58 H -0.4452(2) -0.3922(3) 0.0654(2) 0.116 Uiso 1 calc R .
C59 C -0.2788(2) -0.2770(2) 0.07649(13) 0.0916(11) Uani 1 d G .
H59 H -0.3330(3) -0.2307(2) 0.0703(2) 0.110 Uiso 1 calc R .
C60 C -0.1306(2) -0.24940(13) 0.08865(12) 0.0724(9) Uani 1 d G .
H60 H -0.0856(3) -0.18465(13) 0.0906(2) 0.087 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N3 100.67(8) . . ?
N1 Ag1 P2 108.98(6) . . ?
N3 Ag1 P2 111.70(6) . . ?
N1 Ag1 P1 112.03(6) . . ?
N3 Ag1 P1 99.38(6) . . ?
P2 Ag1 P1 121.73(3) . . ?
N1 Ag1 Ag2 57.77(5) . . ?
N3 Ag1 Ag2 56.96(5) . . ?
P2 Ag1 Ag2 90.67(3) . . ?
P1 Ag1 Ag2 146.57(2) . . ?
N4 Ag2 N2 110.39(8) . . ?
N4 Ag2 P3 132.24(6) . . ?
N2 Ag2 P3 117.28(6) . . ?
N4 Ag2 Ag1 60.11(5) . . ?
N2 Ag2 Ag1 58.24(5) . . ?
P3 Ag2 Ag1 155.23(2) . . ?
C19 P1 C7 105.17(8) . . ?
C19 P1 C13 101.69(9) . . ?
C7 P1 C13 102.60(8) . . ?
C19 P1 Ag1 110.82(6) . . ?
C7 P1 Ag1 111.45(6) . . ?
C13 P1 Ag1 123.32(7) . . ?
C37 P2 C31 105.23(8) . . ?
C37 P2 C25 104.26(9) . . ?
C31 P2 C25 102.10(8) . . ?
C37 P2 Ag1 111.30(7) . . ?
C31 P2 Ag1 116.69(6) . . ?
C25 P2 Ag1 115.92(6) . . ?
C49 P3 C55 104.68(10) . . ?
C49 P3 C43 102.92(10) . . ?
C55 P3 C43 106.24(10) . . ?
C49 P3 Ag2 112.75(8) . . ?
C55 P3 Ag2 110.30(7) . . ?
C43 P3 Ag2 118.78(7) . . ?
C1 N1 N2 107.0(2) . . ?
C1 N1 Ag1 133.5(2) . . ?
N2 N1 Ag1 117.33(15) . . ?
C3 N2 N1 107.9(2) . . ?
C3 N2 Ag2 129.1(2) . . ?
N1 N2 Ag2 120.18(15) . . ?
C4 N3 N4 107.1(2) . . ?
C4 N3 Ag1 130.6(2) . . ?
N4 N3 Ag1 120.40(15) . . ?
C6 N4 N3 107.5(2) . . ?
C6 N4 Ag2 129.4(2) . . ?
N3 N4 Ag2 122.36(15) . . ?
N1 C1 C2 110.7(3) . . ?
C3 C2 C1 104.3(3) . . ?
N2 C3 C2 110.1(3) . . ?
N3 C4 C5 110.9(3) . . ?
C4 C5 C6 103.7(2) . . ?
N4 C6 C5 110.7(2) . . ?
C8 C7 C12 120.0 . . ?
C8 C7 P1 123.45(10) . . ?
C12 C7 P1 116.54(10) . . ?
C7 C8 C9 120.0 . . ?
C10 C9 C8 120.0 . . ?
C9 C10 C11 120.0 . . ?
C12 C11 C10 120.0 . . ?
C11 C12 C7 120.0 . . ?
C14 C13 C18 120.0 . . ?
C14 C13 P1 116.75(11) . . ?
C18 C13 P1 123.23(11) . . ?
C15 C14 C13 120.0 . . ?
C16 C15 C14 120.0 . . ?
C15 C16 C17 120.0 . . ?
C16 C17 C18 120.0 . . ?
C17 C18 C13 120.0 . . ?
C20 C19 C24 120.0 . . ?
C20 C19 P1 122.65(9) . . ?
C24 C19 P1 117.32(9) . . ?
C19 C20 C21 120.0 . . ?
C22 C21 C20 120.0 . . ?
C21 C22 C23 120.0 . . ?
C22 C23 C24 120.0 . . ?
C23 C24 C19 120.0 . . ?
C26 C25 C30 120.0 . . ?
C26 C25 P2 117.77(10) . . ?
C30 C25 P2 122.15(10) . . ?
C27 C26 C25 120.0 . . ?
C26 C27 C28 120.0 . . ?
C29 C28 C27 120.0 . . ?
C28 C29 C30 120.0 . . ?
C29 C30 C25 120.0 . . ?
C32 C31 C36 120.0 . . ?
C32 C31 P2 123.47(9) . . ?
C36 C31 P2 116.35(9) . . ?
C31 C32 C33 120.0 . . ?
C34 C33 C32 120.0 . . ?
C33 C34 C35 120.0 . . ?
C36 C35 C34 120.0 . . ?
C35 C36 C31 120.0 . . ?
C38 C37 C42 120.0 . . ?
C38 C37 P2 117.86(11) . . ?
C42 C37 P2 121.99(11) . . ?
C37 C38 C39 120.0 . . ?
C40 C39 C38 120.0 . . ?
C39 C40 C41 120.0 . . ?
C40 C41 C42 120.0 . . ?
C41 C42 C37 120.0 . . ?
C44 C43 C48 120.0 . . ?
C44 C43 P3 117.60(11) . . ?
C48 C43 P3 122.36(11) . . ?
C43 C44 C45 120.0 . . ?
C44 C45 C46 120.0 . . ?
C45 C46 C47 120.0 . . ?
C48 C47 C46 120.0 . . ?
C47 C48 C43 120.0 . . ?
C50 C49 C54 120.0 . . ?
C50 C49 P3 116.61(14) . . ?
C54 C49 P3 123.38(14) . . ?
C51 C50 C49 120.0 . . ?
C50 C51 C52 120.0 . . ?
C53 C52 C51 120.0 . . ?
C54 C53 C52 120.0 . . ?
C53 C54 C49 120.0 . . ?
C56 C55 C60 120.0 . . ?
C56 C55 P3 123.62(13) . . ?
C60 C55 P3 116.38(13) . . ?
C57 C56 C55 120.0 . . ?
C58 C57 C56 120.0 . . ?
C59 C58 C57 120.0 . . ?
C58 C59 C60 120.0 . . ?
C59 C60 C55 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.295(2) . ?
Ag1 N3 2.323(2) . ?
Ag1 P2 2.4613(9) . ?
Ag1 P1 2.4843(8) . ?
Ag1 Ag2 3.7060(6) . ?
Ag2 N4 2.176(2) . ?
Ag2 N2 2.235(2) . ?
Ag2 P3 2.3704(8) . ?
P1 C19 1.8260(14) . ?
P1 C7 1.8267(13) . ?
P1 C13 1.8402(15) . ?
P2 C37 1.825(2) . ?
P2 C31 1.8300(14) . ?
P2 C25 1.8375(13) . ?
P3 C49 1.817(2) . ?
P3 C55 1.825(2) . ?
P3 C43 1.833(2) . ?
N1 C1 1.322(4) . ?
N1 N2 1.366(3) . ?
N2 C3 1.329(3) . ?
N3 C4 1.333(3) . ?
N3 N4 1.358(3) . ?
N4 C6 1.333(3) . ?
C1 C2 1.374(5) . ?
C2 C3 1.364(5) . ?
C4 C5 1.369(4) . ?
C5 C6 1.368(4) . ?
C7 C8 1.39 . ?
C7 C12 1.39 . ?
C8 C9 1.39 . ?
C9 C10 1.39 . ?
C10 C11 1.39 . ?
C11 C12 1.39 . ?
C13 C14 1.39 . ?
C13 C18 1.39 . ?
C14 C15 1.39 . ?
C15 C16 1.39 . ?
C16 C17 1.39 . ?
C17 C18 1.39 . ?
C19 C20 1.39 . ?
C19 C24 1.39 . ?
C20 C21 1.39 . ?
C21 C22 1.39 . ?
C22 C23 1.39 . ?
C23 C24 1.39 . ?
C25 C26 1.39 . ?
C25 C30 1.39 . ?
C26 C27 1.39 . ?
C27 C28 1.39 . ?
C28 C29 1.39 . ?
C29 C30 1.39 . ?
C31 C32 1.39 . ?
C31 C36 1.39 . ?
C32 C33 1.39 . ?
C33 C34 1.39 . ?
C34 C35 1.39 . ?
C35 C36 1.39 . ?
C37 C38 1.39 . ?
C37 C42 1.39 . ?
C38 C39 1.39 . ?
C39 C40 1.39 . ?
C40 C41 1.39 . ?
C41 C42 1.39 . ?
C43 C44 1.39 . ?
C43 C48 1.39 . ?
C44 C45 1.39 . ?
C45 C46 1.39 . ?
C46 C47 1.39 . ?
C47 C48 1.39 . ?
C49 C50 1.39 . ?
C49 C54 1.39 . ?
C50 C51 1.39 . ?
C51 C52 1.39 . ?
C52 C53 1.39 . ?
C53 C54 1.39 . ?
C55 C56 1.39 . ?
C55 C60 1.39 . ?
C56 C57 1.39 . ?
C57 C58 1.39 . ?
C58 C59 1.39 . ?
C59 C60 1.39 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 N1 N2 Ag2 -31.6(2) . . . . ?
Ag1 N3 N4 Ag2 5.1(3) . . . . ?
