#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:39:19 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179340 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/37/4323775.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4323775
loop_
_publ_author_name
'F. Albert Cotton'
'John H. Matonic'
'Carlos A. Murillo'
_publ_section_title
;
 Synthesis and Structural Studies of Platinum Complexes Containing
 Monodentate, Bridging, and Chelating Formamidine Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              498
_journal_page_last               503
_journal_paper_doi               10.1021/ic950741e
_journal_volume                  35
_journal_year                    1996
_chemical_formula_analytical     none
_chemical_formula_moiety         'C52 H44 N8 Pt2'
_chemical_formula_structural
'(C13 H11 N2) Pt (C13 H11 N2)2 Pt (C13 H11 N2)'
_chemical_formula_sum            'C52 H44 N8 Pt2'
_chemical_formula_weight         1171.13
_chemical_name_systematic
;
 tetrakis-(diphenylformamidinate)-diplatinate(II)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.75(2)
_cell_angle_beta                 91.02(2)
_cell_angle_gamma                110.20(2)
_cell_formula_units_Z            2
_cell_length_a                   12.296(3)
_cell_length_b                   12.310(4)
_cell_length_c                   15.374(4)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      15
_cell_measurement_theta_min      12.5
_cell_volume                     2183.1(11)
_computing_cell_refinement       'CAD4 Software Version III'
_computing_data_collection       'CAD4 Software Version III'
_computing_data_reduction        'Structure Determination Package'
_computing_molecular_graphics    ORTEP
_computing_publication_material  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_refinement  'SHELXL-93 (Sheldrick, 1993)'
_computing_structure_solution    'SHELXS-86 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measurement_device       CAD4
_diffrn_measurement_method       Omega
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0456
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            5343
_diffrn_reflns_theta_max         22.55
_diffrn_reflns_theta_min         2.02
_diffrn_standards_decay_%        2.3
_diffrn_standards_interval_time  7200
_diffrn_standards_number         180
_exptl_absorpt_coefficient_mu    6.448
_exptl_absorpt_correction_T_max  0.9990
_exptl_absorpt_correction_T_min  0.7108
_exptl_absorpt_correction_type   psi-scans
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.782
_exptl_crystal_description       rod
_exptl_crystal_F_000             1136
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.875
_refine_diff_density_min         -1.301
_refine_diff_density_rms         0.380
_refine_ls_extinction_coef       none
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   1.061
_refine_ls_goodness_of_fit_obs   1.083
_refine_ls_hydrogen_treatment    'calculated, ride on carbon atoms'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     559
_refine_ls_number_reflns         5343
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.061
_refine_ls_restrained_S_obs      1.083
_refine_ls_R_factor_all          0.0287
_refine_ls_R_factor_obs          0.0214
_refine_ls_shift/esd_max         0.500
_refine_ls_shift/esd_mean        0.092
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0276P)²+2.1674P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0537
_refine_ls_wR_factor_obs         0.0527
_reflns_number_observed          4986
_reflns_number_total             5343
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            ic950741e_2.cif
_cod_data_source_block           C52H44N8Pt2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0276P)^2^+2.1674P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0276P)^2^+2.1674P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        2183(1)
_cod_database_code               4323775
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_group
Pt1 Pt 0.24116(2) 0.1467(2) 0.16900(1) 0.02890(7) Uani 1 d . .
Pt2 Pt 0.353265(15) 0.25887(2) 0.331030(12) 0.02896(7) Uani 1 d . .
N1 N 0.2509(3) 0.3117(3) 0.1461(3) 0.0313(9) Uani 1 d . .
N2 N 0.0933(3) 0.1342(3) 0.2331(3) 0.0308(9) Uani 1 d . .
N3 N 0.3833(4) 0.1309(4) 0.1110(3) 0.039(1) Uani 1 d . .
N4 N 0.2609(4) -0.0124(4) 0.1766(3) 0.039(1) Uani 1 d . .
N5 N 0.3662(3) 0.4067(3) 0.2673(3) 0.0315(9) Uani 1 d . .
N6 N 0.1895(3) 0.2495(3) 0.3534(3) 0.0296(9) Uani 1 d . .
N7 N 0.5114(3) 0.2405(4) 0.3237(3) 0.038(1) Uani 1 d . .
N8 N 0.3692(4) 0.1169(4) 0.3890(3) 0.038(1) Uani 1 d . .
C1 C 0.3050(4) 0.4037(4) 0.1951(3) 0.030(1) Uani 1 d . .
H1 H 0.2998(4) 0.4736(4) 0.1771(3) 0.036 Uiso 1 calc R .
C2 C 0.3589(5) 0.0224(5) 0.1357(4) 0.044(1) Uani 1 d . .
H2 H 0.4048(5) -0.0225(5) 0.1254(4) 0.054 Uiso 1 calc R .
C3 C 0.0965(4) 0.1953(4) 0.3051(3) 0.032(1) Uani 1 d . .
H3 H 0.0267(4) 0.2004(4) 0.3233(3) 0.038 Uiso 1 calc R .
C4 C 0.4774(4) 0.1413(5) 0.3643(3) 0.043(1) Uani 1 d . .
H4 H 0.5226(4) 0.0955(5) 0.3742(3) 0.052 Uiso 1 calc R .
C11 C 0.1751(4) 0.3237(4) 0.0777(3) 0.031(1) Uani 1 d . .
C12 C 0.0886(4) 0.3685(5) 0.0942(3) 0.0403(13) Uani 1 d . .
H12 H 0.0835(4) 0.3984(5) 0.1493(3) 0.048 Uiso 1 calc R .
C13 C 0.0106(5) 0.3689(5) 0.0300(4) 0.052(2) Uani 1 d . .
H13 H -0.0483(5) 0.3977(5) 0.0418(4) 0.062 Uiso 1 calc R .
C14 C 0.0187(5) 0.3273(6) -0.0516(4) 0.058(2) Uani 1 d . .
H14 H -0.0343(5) 0.3287(6) -0.0951(4) 0.069 Uiso 1 calc R .
C15 C 0.1047(5) 0.2832(5) -0.0699(4) 0.051(2) Uani 1 d . .
H15 H 0.1101(5) 0.2554(5) -0.1256(4) 0.061 Uiso 1 calc R .
C16 C 0.1829(5) 0.2806(5) -0.0050(3) 0.042(3) Uani 1 d . .
H16 H 0.2407(5) 0.2501(5) -0.0167(3) 0.050 Uiso 1 calc R .
C21 C -0.0193(4) 0.0725(4) 0.1968(4) 0.037(1) Uani 1 d . .
C22 C -0.0393(5) 0.0632(5) 0.1090(4) 0.045(1) Uani 1 d . .
H22 H 0.0218(5) 0.0951(5) 0.0717(4) 0.054 Uiso 1 calc R .
C23 C -0.1492(5) 0.0073(5) 0.0750(5) 0.059(2) Uani 1 d . .
H23 H -0.1613(5) 0.0015(5) 0.0149(5) 0.070 Uiso 1 calc R .
C24 C -0.2404(6) -0.0399(7) 0.1282(6) 0.080(2) Uani 1 d . .
H24 H -0.3148(6) -0.0764(7) 0.1050(6) 0.096 Uiso 1 calc R .
C25 C -0.2208(6) -0.0326(7) 0.2150(6) 0.100(3) Uani 1 d . .
H25 H -0.2825(6) -0.0657(7) 0.2515(6) 0.120 Uiso 1 calc R .
C26 C -0.1123(5) 0.0222(6) 0.2510(5) 0.065(2) Uani 1 d . .
H26 H -0.1010(5) 0.0257(6) 0.3110(5) 0.078 Uiso 1 calc R .
C31 C 0.4835(4) 0.1983(4) 0.0695(3) 0.035(1) Uani 1 d . .
C32 C 0.5760(5) 0.1605(6) 0.0518(4) 0.056(2) Uani 1 d . .
H32 H 0.5720(5) 0.0867(6) 0.0678(4) 0.068 Uiso 1 calc R .
C33 C 0.6729(5) 0.2311(7) 0.0109(5) 0.068(2) Uani 1 d . .
H33 H 0.7333(5) 0.2043(7) -0.0004(5) 0.082 Uiso 1 calc R .
C34 C 0.6813(5) 0.3401(6) -0.0130(4) 0.059(2) Uani 1 d . .
H34 H 0.7470(5) 0.3876(6) -0.0404(4) 0.070 Uiso 1 calc R .
C35 C 0.5916(5) 0.3785(6) 0.0037(4) 0.059(2) Uani 1 d . .
H35 H 0.5964(5) 0.4524(6) -0.0129(4) 0.071 Uiso 1 calc R .
C36 C 0.4935(5) 0.3083(5) 0.0452(4) 0.049(1) Uani 1 d . .
H36 H 0.4338(5) 0.3361(5) 0.0567(4) 0.060 Uiso 1 calc R .
C41 C 0.2084(5) -0.1204(4) 0.2146(3) 0.039(1) Uani 1 d . .
C42 C 0.0994(5) -0.1446(5) 0.2492(4) 0.047(1) Uani 1 d . .
H42 H 0.0639(5) -0.0890(5) 0.2477(4) 0.057 Uiso 1 calc R .
C43 C 0.0433(6) -0.2498(5) 0.2855(4) 0.060(2) Uani 1 d . .
H43 H -0.0297(6) -0.2647(5) 0.3084(4) 0.073 Uiso 1 calc R .
C44 C 0.0934(6) -0.3324(5) 0.2882(4) 0.058(2) Uani 1 d . .
H44 H 0.0544(6) -0.4041(5) 0.3121(4) 0.070 Uiso 1 calc R .
C45 C 0.2003(7) -0.3096(6) 0.2561(5) 0.070(2) Uani 1 d . .
H45 H 0.2348(7) -0.3659(6) 0.2587(5) 0.084 Uiso 1 calc R .
C46 C 0.2599(6) -0.2037(5) 0.2192(4) 0.060(2) Uani 1 d . .
H46 H 0.3338(6) -0.1891(5) 0.1978(4) 0.072 Uiso 1 calc R .
C51 C 0.4278(4) 0.5199(4) 0.3036(4) 0.037(1) Uani 1 d . .
C52 C 0.4786(6) 0.6119(5) 0.2492(5) 0.067(2) Uani 1 d . .
H52 H 0.4764(6) 0.5996(5) 0.1893(5) 0.080 Uiso 1 calc R .
C53 C 0.5317(7) 0.7206(6) 0.2838(6) 0.094(3) Uani 1 d . .
H53 H 0.5637(7) 0.7823(6) 0.2470(6) 0.113 Uiso 1 calc R .
C54 C 0.5387(6) 0.7402(6) 0.3726(6) 0.080(2) Uani 1 d . .
H54 H 0.5746(6) 0.8144(6) 0.3958(6) 0.096 Uiso 1 calc R .
C55 C 0.4923(5) 0.6493(5) 0.4258(5) 0.059(2) Uani 1 d . .
H55 H 0.4976(5) 0.6609(5) 0.4858(5) 0.071 Uiso 1 calc R .
C56 C 0.4374(4) 0.5400(5) 0.3908(4) 0.043(1) Uani 1 d . .
H56 H 0.4062(4) 0.4784(5) 0.4279(4) 0.052 Uiso 1 calc R .
C61 C 0.1765(4) 0.3251(4) 0.4224(3) 0.032(1) Uani 1 d . .
C62 C 0.1322(5) 0.4112(5) 0.4058(4) 0.042(1) Uani 1 d . .
H62 H 0.1032(5) 0.4174(5) 0.3505(4) 0.051 Uiso 1 calc R .
C63 C 0.1306(5) 0.4887(5) 0.4713(4) 0.050(2) Uani 1 d . .
H63 H 0.0996(5) 0.5462(5) 0.4599(4) 0.060 Uiso 1 calc R .
C64 C 0.1735(5) 0.4817(5) 0.5517(4) 0.056(2) Uani 1 d . .
H64 H 0.1736(5) 0.5351(5) 0.5951(4) 0.067 Uiso 1 calc R .
C65 C 0.2172(5) 0.3947(5) 0.5690(4) 0.052(2) Uani 1 d . .
H65 H 0.2455(5) 0.3887(5) 0.6245(4) 0.062 Uiso 1 calc R .
C66 C 0.2192(5) 0.3167(5) 0.5047(3) 0.039(1) Uani 1 d . .
H66 H 0.2492(5) 0.2586(5) 0.5166(3) 0.047 Uiso 1 calc R .
C71 C 0.6193(4) 0.2914(5) 0.2858(3) 0.039(1) Uani 1 d . .
C72 C 0.7036(5) 0.2400(6) 0.2799(4) 0.058(2) Uani 1 d . .
H72 H 0.6885(5) 0.1655(6) 0.3004(4) 0.070 Uiso 1 calc R .
C73 C 0.8098(5) 0.2987(7) 0.2439(5) 0.070(2) Uani 1 d . .
H73 H 0.8659(5) 0.2638(7) 0.2417(5) 0.084 Uiso 1 calc R .
C74 C 0.8333(5) 0.4071(6) 0.2116(4) 0.060(2) Uani 1 d . .
H74 H 0.9052(5) 0.4468(6) 0.1884(4) 0.071 Uiso 1 calc R .
C75 C 0.7497(5) 0.4561(6) 0.2139(4) 0.058(2) Uani 1 d . .
H75 H 0.7640(5) 0.5287(6) 0.1901(4) 0.069 Uiso 1 calc R .
C76 C 0.6440(5) 0.4002(5) 0.2510(4) 0.050(2) Uani 1 d . .
H76 H 0.5888(5) 0.4360(5) 0.2526(4) 0.060 Uiso 1 calc R .
C81 C 0.3017(4) 0.0164(4) 0.4306(3) 0.036(1) Uani 1 d . .
C82 C 0.1911(5) 0.0064(5) 0.4552(4) 0.049(1) Uani 1 d . .
H82 H 0.1632(5) 0.0663(5) 0.4442(4) 0.058 Uiso 1 calc R .
C83 C 0.1219(6) -0.0918(5) 0.4958(4) 0.058(2) Uani 1 d . .
H83 H 0.0475(6) -0.0972(5) 0.5115(4) 0.070 Uiso 1 calc R .
C84 C 0.1597(6) -0.1809(5) 0.5135(4) 0.060(2) Uani 1 d . .
H84 H 0.1125(6) -0.2462(5) 0.5415(4) 0.072 Uiso 1 calc R .
C85 C 0.2694(6) -0.1722(5) 0.4889(5) 0.066(2) Uani 1 d . .
H85 H 0.2964(6) -0.2326(5) 0.5000(5) 0.079 Uiso 1 calc R .
C86 C 0.3397(5) -0.0752(5) 0.4480(5) 0.059(2) Uani 1 d . .
H86 H 0.4136(5) -0.0709(5) 0.4318(5) 0.071 Uiso 1 calc R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 N2 85.0(2) . . y
N1 Pt1 N3 104.8(2) . . y
N2 Pt1 N3 170.3(2) . . y
N1 Pt1 N4 168.2(2) . . y
N2 Pt1 N4 106.8(2) . . y
N3 Pt1 N4 63.5(2) . . y
N1 Pt1 Pt2 80.1(1) . . y
N2 Pt1 Pt2 83.1(1) . . y
N3 Pt1 Pt2 98.2(1) . . y
N4 Pt1 Pt2 101.7(1) . . y
N6 Pt2 N5 85.0(2) . . y
N6 Pt2 N8 104.9(2) . . y
N5 Pt2 N8 170.2(2) . . y
N6 Pt2 N7 168.6(2) . . y
N5 Pt2 N7 106.3(2) . . y
N8 Pt2 N7 63.8(2) . . y
N6 Pt2 Pt1 80.3(1) . . y
N5 Pt2 Pt1 83.4(1) . . y
N8 Pt2 Pt1 98.0(1) . . y
N7 Pt2 Pt1 101.6(1) . . y
C1 N1 C11 117.6(4) . . ?
C1 N1 Pt1 126.5(3) . . ?
C11 N1 Pt1 115.0(3) . . ?
C3 N2 C21 116.1(4) . . ?
C3 N2 Pt1 121.3(3) . . ?
C21 N2 Pt1 122.0(3) . . ?
C2 N3 C31 126.2(4) . . ?
C2 N3 Pt1 93.2(3) . . ?
C31 N3 Pt1 140.2(3) . . ?
C2 N4 C41 126.9(5) . . ?
C2 N4 Pt1 93.1(3) . . ?
C41 N4 Pt1 139.8(4) . . ?
C1 N5 C51 115.8(4) . . ?
C1 N5 Pt2 121.1(3) . . ?
C51 N5 Pt2 122.5(3) . . ?
C3 N6 C61 116.7(4) . . ?
C3 N6 Pt2 127.1(3) . . ?
C61 N6 Pt2 115.5(3) . . ?
C4 N7 C71 125.4(5) . . ?
C4 N7 Pt2 93.4(3) . . ?
C71 N7 Pt2 140.8(4) . . ?
C4 N8 C81 126.2(4) . . ?
C4 N8 Pt2 93.2(3) . . ?
C81 N8 Pt2 140.2(3) . . ?
N1 C1 N5 126.5(4) . . y
N4 C2 N3 110.1(5) . . y
N6 C3 N2 125.9(4) . . y
N7 C4 N8 109.5(5) . . y
C12 C11 C16 119.5(5) . . ?
C12 C11 N1 121.2(4) . . ?
C16 C11 N1 119.1(4) . . ?
C13 C12 C11 120.2(5) . . ?
C12 C13 C14 120.4(5) . . ?
C13 C14 C15 120.5(5) . . ?
C14 C15 C16 119.6(6) . . ?
C15 C16 C11 119.8(5) . . ?
C22 C21 C26 118.3(5) . . ?
C22 C21 N2 121.3(5) . . ?
C26 C21 N2 120.3(5) . . ?
C21 C22 C23 120.7(6) . . ?
C24 C23 C22 120.9(7) . . ?
C25 C24 C23 118.7(6) . . ?
C24 C25 C26 121.9(7) . . ?
C25 C26 C21 119.5(7) . . ?
C36 C31 N3 118.9(5) . . ?
C36 C31 C32 117.5(5) . . ?
N3 C31 C32 123.5(5) . . ?
C33 C32 C31 120.9(6) . . ?
C34 C33 C32 120.8(6) . . ?
C33 C34 C35 119.1(6) . . ?
C34 C35 C36 120.6(6) . . ?
C31 C36 C35 121.0(5) . . ?
C46 C41 C42 118.5(5) . . ?
C46 C41 N4 123.2(5) . . ?
C42 C41 N4 118.3(5) . . ?
C43 C42 C41 120.6(5) . . ?
C44 C43 C42 120.7(6) . . ?
C45 C44 C43 119.4(6) . . ?
C44 C45 C46 121.4(6) . . ?
C41 C46 C45 119.4(6) . . ?
C56 C51 C52 118.5(5) . . ?
C56 C51 N5 121.4(5) . . ?
C52 C51 N5 120.1(5) . . ?
C53 C52 C51 119.9(7) . . ?
C52 C53 C54 120.9(7) . . ?
C55 C54 C53 119.0(6) . . ?
C54 C55 C56 120.1(7) . . ?
C51 C56 C55 121.6(6) . . ?
C62 C61 C66 119.5(5) . . ?
C62 C61 N6 121.4(4) . . ?
C66 C61 N6 118.9(4) . . ?
C61 C62 C63 120.0(5) . . ?
C64 C63 C62 120.7(5) . . ?
C63 C64 C65 119.5(5) . . ?
C66 C65 C64 120.5(6) . . ?
C65 C66 C61 119.7(5) . . ?
C76 C71 C72 117.5(5) . . ?
C76 C71 N7 117.9(5) . . ?
C72 C71 N7 124.6(5) . . ?
C73 C72 C71 120.6(6) . . ?
C74 C73 C72 120.9(6) . . ?
C75 C74 C73 118.9(6) . . ?
C74 C75 C76 121.2(6) . . ?
C75 C76 C71 120.8(5) . . ?
C82 C81 C86 117.8(5) . . ?
C82 C81 N8 118.8(5) . . ?
C86 C81 N8 123.3(5) . . ?
C83 C82 C81 120.4(5) . . ?
C84 C83 C82 121.6(6) . . ?
C83 C84 C85 118.4(6) . . ?
C86 C85 C84 120.9(6) . . ?
C85 C86 C81 120.8(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 Pt2 2.9128(9) . y
Pt1 N1 2.028(4) . y
Pt1 N2 2.043(4) . y
Pt1 N3 2.043(4) . y
Pt1 N4 2.060(4) . y
Pt2 N6 2.012(4) . y
Pt2 N5 2.037(4) . y
Pt2 N8 2.039(4) . y
Pt2 N7 2.038(4) . y
N1 C1 1.316(6) . ?
N1 C11 1.436(6) . ?
N2 C3 1.322(6) . ?
N2 C21 1.429(6) . ?
N3 C2 1.326(7) . ?
N3 C31 1.396(6) . ?
N4 C2 1.306(7) . ?
N4 C41 1.403(7) . ?
N5 C1 1.323(6) . ?
N5 C51 1.436(6) . ?
N6 C3 1.317(6) . ?
N6 C61 1.450(6) . ?
N7 C4 1.316(7) . ?
N7 C71 1.399(7) . ?
N8 C4 1.323(7) . ?
N8 C81 1.400(7) . ?
C11 C12 1.382(7) . ?
C11 C16 1.389(7) . ?
C12 C13 1.366(7) . ?
C13 C14 1.367(9) . ?
C14 C15 1.376(8) . ?
C15 C16 1.382(8) . ?
C21 C22 1.364(8) . ?
C21 C26 1.395(8) . ?
C22 C23 1.376(8) . ?
C23 C24 1.36(1) . ?
C24 C25 1.35(1) . ?
C25 C26 1.371(9) . ?
C31 C36 1.374(8) . ?
C31 C32 1.399(7) . ?
C32 C33 1.376(9) . ?
C33 C34 1.366(9) . ?
C34 C35 1.368(9) . ?
C35 C36 1.390(8) . ?
C41 C46 1.380(8) . ?
C41 C42 1.387(8) . ?
C42 C43 1.370(8) . ?
C43 C44 1.360(9) . ?
C44 C45 1.350(9) . ?
C45 C46 1.390(9) . ?
C51 C56 1.356(8) . ?
C51 C52 1.388(8) . ?
C52 C53 1.37(1) . ?
C53 C54 1.38(1) . ?
C54 C55 1.36(1) . ?
C55 C56 1.377(8) . ?
C61 C62 1.373(7) . ?
C61 C66 1.380(7) . ?
C62 C63 1.383(8) . ?
C63 C64 1.350(9) . ?
C64 C65 1.380(8) . ?
C65 C66 1.375(8) . ?
C71 C76 1.384(8) . ?
C71 C72 1.392(7) . ?
C72 C73 1.385(9) . ?
C73 C74 1.37(1) . ?
C74 C75 1.360(9) . ?
C75 C76 1.381(8) . ?
C81 C82 1.383(7) . ?
C81 C86 1.388(8) . ?
C82 C83 1.380(8) . ?
C83 C84 1.360(9) . ?
C84 C85 1.375(9) . ?
C85 C86 1.377(9) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Pt1 Pt2 N5 -9.3(2) . . . . ?
N2 Pt1 Pt2 N6 -9.4(2) . . . . ?
N3 Pt1 Pt2 N7 -11.1(2) . . . . ?
N4 Pt1 Pt2 N8 -11.4(2) . . . . ?
