#------------------------------------------------------------------------------
#$Date: 2016-03-23 15:42:34 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179343 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/40/4324073.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4324073
loop_
_publ_author_name
'David W. Shaffer'
'Scott A. Ryken'
'Ryan A. Zarkesh'
'Alan F. Heyduk'
_publ_section_title
;
 Redox Behavior of Rhodium 9,10-Phenanthrenediimine Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              13
_journal_page_last               21
_journal_paper_doi               10.1021/ic1007632
_journal_volume                  50
_journal_year                    2011
_chemical_formula_sum            'C31 H41 N2 O2 Rh'
_chemical_formula_weight         576.57
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 120.613(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   35.218(6)
_cell_length_b                   9.3465(16)
_cell_length_c                   20.861(4)
_cell_measurement_temperature    151(2)
_cell_volume                     5909.7(18)
_computing_cell_refinement       'Bruker SMART/SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      151(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0243
_diffrn_reflns_av_sigmaI/netI    0.0189
_diffrn_reflns_limit_h_max       46
_diffrn_reflns_limit_h_min       -46
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            31653
_diffrn_reflns_theta_full        28.29
_diffrn_reflns_theta_max         28.29
_diffrn_reflns_theta_min         1.34
_diffrn_standards_decay_%        '< 1.0'
_diffrn_standards_interval_count 'initial 50 frames recollected'
_diffrn_standards_number         '50 frames'
_exptl_absorpt_coefficient_mu    0.606
_exptl_absorpt_correction_T_max  0.9093
_exptl_absorpt_correction_T_min  0.8251
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SADABS'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.296
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2416
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.510
_refine_diff_density_min         -0.424
_refine_diff_density_rms         0.052
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     489
_refine_ls_number_reflns         7286
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0245
_refine_ls_R_factor_gt           0.0209
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0273P)²+4.4680P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0528
_refine_ls_wR_factor_ref         0.0554
_reflns_number_gt                6581
_reflns_number_total             7286
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic1007632_si_002_1.cif
_cod_data_source_block           sad115
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'n/a' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        5909.8(17)
_cod_database_code               4324073
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.120832(3) 0.690739(10) 0.124658(5) 0.01668(4) Uani 1 1 d . . .
C30 C 0.10445(5) 0.55372(15) 0.04969(8) 0.0289(3) Uani 1 1 d . . .
C31 C 0.12768(5) 0.53646(15) 0.18669(8) 0.0260(3) Uani 1 1 d . . .
C6 C 0.09788(4) 0.81123(13) -0.02244(7) 0.0175(2) Uani 1 1 d . . .
C7 C 0.13117(4) 0.78781(13) -0.03963(7) 0.0197(2) Uani 1 1 d . . .
C15 C 0.17904(4) 0.82664(15) 0.01532(7) 0.0231(3) Uani 1 1 d . . .
H2 H 0.1789(5) 0.8988(17) 0.0481(9) 0.023(4) Uiso 1 1 d . . .
C11 C 0.05326(4) 0.78277(15) -0.07421(7) 0.0217(3) Uani 1 1 d . . .
C9 C 0.07542(5) 0.69276(16) -0.15917(8) 0.0291(3) Uani 1 1 d . . .
H7 H 0.0676(6) 0.6513(19) -0.2041(10) 0.032(4) Uiso 1 1 d . . .
C24 C 0.07856(5) 0.80743(16) 0.25896(9) 0.0289(3) Uani 1 1 d . . .
H3 H 0.0756(5) 0.8678(19) 0.2172(9) 0.029(4) Uiso 1 1 d . . .
C19 C 0.20104(5) 0.73283(16) 0.32783(8) 0.0274(3) Uani 1 1 d . . .
C2 C 0.11586(4) 0.99412(13) 0.06806(7) 0.0168(2) Uani 1 1 d . . .
C5 C 0.16061(5) 1.06607(16) 0.27490(7) 0.0244(3) Uani 1 1 d . . .
H19 H 0.1611(6) 1.162(2) 0.2646(10) 0.032(5) Uiso 1 1 d . . .
H18 H 0.1901(6) 1.034(2) 0.3127(10) 0.036(5) Uiso 1 1 d . . .
H20 H 0.1426(6) 1.055(2) 0.2954(10) 0.039(5) Uiso 1 1 d . . .
C3 C 0.13099(4) 1.05083(14) 0.13913(7) 0.0179(2) Uani 1 1 d . . .
H5 H 0.1346(5) 1.1542(18) 0.1442(9) 0.021(4) Uiso 1 1 d . . .
C18 C 0.15677(5) 0.77541(14) 0.28311(7) 0.0211(3) Uani 1 1 d . . .
C12 C 0.01670(5) 0.81584(17) -0.05785(8) 0.0301(3) Uani 1 1 d . . .
H1 H 0.0295(6) 0.858(2) -0.0106(11) 0.036(5) Uiso 1 1 d . . .
C22 C 0.14023(6) 0.69153(17) 0.37510(9) 0.0365(4) Uani 1 1 d . . .
H11 H 0.1192(6) 0.6766(18) 0.3904(10) 0.033(5) Uiso 1 1 d . . .
C4 C 0.14393(4) 0.97675(14) 0.20527(7) 0.0177(2) Uani 1 1 d . . .
C23 C 0.12603(5) 0.75743(15) 0.30626(7) 0.0253(3) Uani 1 1 d . . .
C8 C 0.11921(5) 0.72579(16) -0.10823(8) 0.0250(3) Uani 1 1 d . . .
H6 H 0.1402(6) 0.7064(17) -0.1196(10) 0.030(5) Uiso 1 1 d . . .
C10 C 0.04299(5) 0.72289(17) -0.14266(8) 0.0279(3) Uani 1 1 d . . .
H8 H 0.0133(6) 0.6997(17) -0.1776(10) 0.030(5) Uiso 1 1 d . . .
C20 C 0.21374(6) 0.67099(18) 0.39691(9) 0.0379(4) Uani 1 1 d . . .
H9 H 0.2447(7) 0.643(2) 0.4300(11) 0.046(5) Uiso 1 1 d . . .
C27 C 0.23453(5) 0.74855(19) 0.30280(8) 0.0324(3) Uani 1 1 d . . .
H4 H 0.2226(6) 0.8083(17) 0.2598(10) 0.029(4) Uiso 1 1 d . . .
C28 C 0.27744(6) 0.8189(2) 0.36163(12) 0.0428(4) Uani 1 1 d . . .
H39 H 0.2917(7) 0.763(3) 0.4018(12) 0.054(6) Uiso 1 1 d . . .
C17 C 0.20184(5) 0.89427(19) -0.02315(9) 0.0315(3) Uani 1 1 d . . .
H31 H 0.2314(6) 0.922(2) 0.0126(10) 0.037(5) Uiso 1 1 d . . .
H30 H 0.2037(6) 0.8241(19) -0.0561(11) 0.039(5) Uiso 1 1 d . . .
H32 H 0.1878(6) 0.978(2) -0.0500(10) 0.037(5) Uiso 1 1 d . . .
C21 C 0.18376(7) 0.6501(2) 0.41993(9) 0.0431(4) Uani 1 1 d . . .
H10 H 0.1930(6) 0.611(2) 0.4650(11) 0.049(6) Uiso 1 1 d . . .
C14 C -0.00847(8) 0.6822(3) -0.05933(17) 0.0569(6) Uani 1 1 d . . .
H24 H -0.0306(8) 0.707(2) -0.0480(13) 0.062(7) Uiso 1 1 d . . .
C1 C 0.10537(5) 1.09992(15) 0.00653(8) 0.0236(3) Uani 1 1 d . . .
H17 H 0.1079(7) 1.194(2) 0.0225(11) 0.045(6) Uiso 1 1 d . . .
H16 H 0.0767(6) 1.090(2) -0.0341(11) 0.041(5) Uiso 1 1 d . . .
H15 H 0.1229(6) 1.084(2) -0.0163(10) 0.043(5) Uiso 1 1 d . . .
C16 C 0.20514(6) 0.6971(2) 0.06128(10) 0.0358(4) Uani 1 1 d . . .
H27 H 0.2356(7) 0.725(2) 0.1004(11) 0.046(5) Uiso 1 1 d . . .
H28 H 0.2049(7) 0.626(2) 0.0292(12) 0.047(6) Uiso 1 1 d . . .
H29 H 0.1912(7) 0.657(2) 0.0860(11) 0.048(6) Uiso 1 1 d . . .
C25 C 0.06492(6) 0.9008(2) 0.30421(10) 0.0372(4) Uani 1 1 d . . .
H33 H 0.0368(6) 0.944(2) 0.2705(10) 0.041(5) Uiso 1 1 d . . .
C13 C -0.01538(6) 0.9270(2) -0.11241(12) 0.0445(4) Uani 1 1 d . . .
H21 H -0.0363(7) 0.951(2) -0.0994(11) 0.053(6) Uiso 1 1 d . . .
H22 H -0.0308(8) 0.891(3) -0.1632(13) 0.063(7) Uiso 1 1 d . . .
C29 C 0.24483(6) 0.6030(2) 0.28141(13) 0.0489(5) Uani 1 1 d . . .
H42 H 0.2655(7) 0.613(2) 0.2652(12) 0.055(6) Uiso 1 1 d . . .
H43 H 0.2181(8) 0.557(3) 0.2411(13) 0.066(7) Uiso 1 1 d . . .
C26 C 0.04647(6) 0.6827(2) 0.22375(12) 0.0429(4) Uani 1 1 d . . .
H36 H 0.0521(7) 0.629(2) 0.1908(12) 0.055(6) Uiso 1 1 d . . .
H37 H 0.0163(7) 0.718(2) 0.1930(12) 0.049(6) Uiso 1 1 d . . .
H38 H 0.0486(7) 0.623(2) 0.2653(12) 0.056(6) Uiso 1 1 d . . .
N1 N 0.11061(3) 0.85499(11) 0.05236(5) 0.0163(2) Uani 1 1 d . . .
N2 N 0.14218(3) 0.83509(12) 0.21012(6) 0.0173(2) Uani 1 1 d . . .
O2 O 0.13078(4) 0.43783(12) 0.22090(6) 0.0404(3) Uani 1 1 d . . .
O1 O 0.09615(5) 0.46530(12) 0.00720(6) 0.0472(3) Uani 1 1 d . . .
H34 H 0.0612(7) 0.837(2) 0.3421(12) 0.055(6) Uiso 1 1 d . . .
H23 H 0.0008(7) 1.013(3) -0.1127(12) 0.065(7) Uiso 1 1 d . . .
H35 H 0.0853(7) 0.970(2) 0.3301(12) 0.057(6) Uiso 1 1 d . . .
H40 H 0.2974(8) 0.837(2) 0.3406(13) 0.063(7) Uiso 1 1 d . . .
H41 H 0.2719(7) 0.908(3) 0.3766(12) 0.061(7) Uiso 1 1 d . . .
H44 H 0.2570(7) 0.542(2) 0.3224(12) 0.052(6) Uiso 1 1 d . . .
H25 H -0.0236(8) 0.642(3) -0.1103(14) 0.057(7) Uiso 1 1 d . . .
H26 H 0.0108(9) 0.619(3) -0.0247(15) 0.077(8) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C31 Rh1 C30 85.80(6) . . ?
C31 Rh1 N2 92.57(5) . . ?
C30 Rh1 N2 176.74(6) . . ?
C31 Rh1 N1 177.13(5) . . ?
C30 Rh1 N1 91.93(5) . . ?
N2 Rh1 N1 89.79(4) . . ?
O1 C30 Rh1 176.08(14) . . ?
O2 C31 Rh1 176.10(12) . . ?
C11 C6 C7 121.68(11) . . ?
C11 C6 N1 119.55(11) . . ?
C7 C6 N1 118.59(11) . . ?
C8 C7 C6 118.07(12) . . ?
C8 C7 C15 120.74(12) . . ?
C6 C7 C15 121.18(11) . . ?
C7 C15 C16 111.42(12) . . ?
C7 C15 C17 112.26(12) . . ?
C16 C15 C17 110.35(13) . . ?
C10 C11 C6 117.81(12) . . ?
C10 C11 C12 120.10(13) . . ?
C6 C11 C12 122.10(12) . . ?
C10 C9 C8 120.06(13) . . ?
C23 C24 C26 112.20(14) . . ?
C23 C24 C25 111.21(13) . . ?
C26 C24 C25 110.13(13) . . ?
C20 C19 C18 117.73(14) . . ?
C20 C19 C27 119.80(14) . . ?
C18 C19 C27 122.45(12) . . ?
N1 C2 C3 124.14(11) . . ?
N1 C2 C1 119.18(11) . . ?
C3 C2 C1 116.68(11) . . ?
C4 C3 C2 127.99(12) . . ?
C23 C18 C19 121.81(12) . . ?
C23 C18 N2 119.05(12) . . ?
C19 C18 N2 119.10(12) . . ?
C11 C12 C14 112.27(15) . . ?
C11 C12 C13 111.07(13) . . ?
C14 C12 C13 109.89(16) . . ?
C21 C22 C23 120.69(16) . . ?
N2 C4 C3 124.30(11) . . ?
N2 C4 C5 119.12(11) . . ?
C3 C4 C5 116.57(12) . . ?
C22 C23 C18 118.09(14) . . ?
C22 C23 C24 120.12(13) . . ?
C18 C23 C24 121.79(12) . . ?
C9 C8 C7 120.93(13) . . ?
C9 C10 C11 121.32(13) . . ?
C21 C20 C19 121.21(16) . . ?
C19 C27 C28 112.88(14) . . ?
C19 C27 C29 110.75(15) . . ?
C28 C27 C29 109.40(14) . . ?
C20 C21 C22 120.42(14) . . ?
C2 N1 C6 118.03(10) . . ?
C2 N1 Rh1 126.86(8) . . ?
C6 N1 Rh1 115.07(8) . . ?
C4 N2 C18 117.23(10) . . ?
C4 N2 Rh1 126.81(8) . . ?
C18 N2 Rh1 115.96(8) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C31 1.8693(14) . ?
Rh1 C30 1.8708(14) . ?
Rh1 N2 2.0491(11) . ?
Rh1 N1 2.0514(11) . ?
C30 O1 1.1358(18) . ?
C31 O2 1.1365(17) . ?
C6 C11 1.4066(18) . ?
C6 C7 1.4067(18) . ?
C6 N1 1.4459(15) . ?
C7 C8 1.3954(18) . ?
C7 C15 1.5231(19) . ?
C15 C16 1.527(2) . ?
C15 C17 1.531(2) . ?
C11 C10 1.3989(19) . ?
C11 C12 1.522(2) . ?
C9 C10 1.380(2) . ?
C9 C8 1.391(2) . ?
C24 C23 1.519(2) . ?
C24 C26 1.527(2) . ?
C24 C25 1.531(2) . ?
C19 C20 1.398(2) . ?
C19 C18 1.4063(19) . ?
C19 C27 1.521(2) . ?
C2 N1 1.3308(16) . ?
C2 C3 1.3994(16) . ?
C2 C1 1.5097(17) . ?
C5 C4 1.5110(17) . ?
C3 C4 1.3965(17) . ?
C18 C23 1.4021(19) . ?
C18 N2 1.4481(15) . ?
C12 C14 1.523(3) . ?
C12 C13 1.530(2) . ?
C22 C21 1.384(3) . ?
C22 C23 1.4001(19) . ?
C4 N2 1.3316(17) . ?
C20 C21 1.378(3) . ?
C27 C28 1.528(2) . ?
C27 C29 1.532(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C31 Rh1 C30 O1 -33(2) . . . . ?
N2 Rh1 C30 O1 27(3) . . . . ?
N1 Rh1 C30 O1 148(2) . . . . ?
C30 Rh1 C31 O2 -8(2) . . . . ?
N2 Rh1 C31 O2 174(96) . . . . ?
N1 Rh1 C31 O2 29(3) . . . . ?
C11 C6 C7 C8 -4.32(19) . . . . ?
N1 C6 C7 C8 170.79(12) . . . . ?
C11 C6 C7 C15 176.63(12) . . . . ?
N1 C6 C7 C15 -8.26(18) . . . . ?
C8 C7 C15 C16 -82.72(16) . . . . ?
C6 C7 C15 C16 96.30(15) . . . . ?
C8 C7 C15 C17 41.62(18) . . . . ?
C6 C7 C15 C17 -139.35(13) . . . . ?
C7 C6 C11 C10 3.28(19) . . . . ?
N1 C6 C11 C10 -171.78(12) . . . . ?
C7 C6 C11 C12 -176.36(12) . . . . ?
N1 C6 C11 C12 8.58(19) . . . . ?
N1 C2 C3 C4 1.4(2) . . . . ?
C1 C2 C3 C4 -178.20(12) . . . . ?
C20 C19 C18 C23 0.1(2) . . . . ?
C27 C19 C18 C23 178.60(14) . . . . ?
C20 C19 C18 N2 -177.80(13) . . . . ?
C27 C19 C18 N2 0.7(2) . . . . ?
C10 C11 C12 C14 61.3(2) . . . . ?
C6 C11 C12 C14 -119.04(18) . . . . ?
C10 C11 C12 C13 -62.16(19) . . . . ?
C6 C11 C12 C13 117.47(16) . . . . ?
C2 C3 C4 N2 -2.7(2) . . . . ?
C2 C3 C4 C5 177.73(12) . . . . ?
C21 C22 C23 C18 2.2(2) . . . . ?
C21 C22 C23 C24 -177.69(15) . . . . ?
C19 C18 C23 C22 -1.7(2) . . . . ?
N2 C18 C23 C22 176.17(13) . . . . ?
C19 C18 C23 C24 178.16(13) . . . . ?
N2 C18 C23 C24 -3.9(2) . . . . ?
C26 C24 C23 C22 -72.43(18) . . . . ?
C25 C24 C23 C22 51.42(19) . . . . ?
C26 C24 C23 C18 107.68(16) . . . . ?
C25 C24 C23 C18 -128.47(15) . . . . ?
C10 C9 C8 C7 0.8(2) . . . . ?
C6 C7 C8 C9 2.2(2) . . . . ?
C15 C7 C8 C9 -178.72(13) . . . . ?
C8 C9 C10 C11 -1.9(2) . . . . ?
C6 C11 C10 C9 -0.1(2) . . . . ?
C12 C11 C10 C9 179.54(14) . . . . ?
C18 C19 C20 C21 1.1(2) . . . . ?
C27 C19 C20 C21 -177.42(16) . . . . ?
C20 C19 C27 C28 -50.4(2) . . . . ?
C18 C19 C27 C28 131.13(16) . . . . ?
C20 C19 C27 C29 72.66(19) . . . . ?
C18 C19 C27 C29 -105.81(17) . . . . ?
C19 C20 C21 C22 -0.7(3) . . . . ?
C23 C22 C21 C20 -1.1(3) . . . . ?
C3 C2 N1 C6 -175.41(11) . . . . ?
C1 C2 N1 C6 4.16(17) . . . . ?
C3 C2 N1 Rh1 2.21(18) . . . . ?
C1 C2 N1 Rh1 -178.22(9) . . . . ?
C11 C6 N1 C2 -97.70(14) . . . . ?
C7 C6 N1 C2 87.09(14) . . . . ?
C11 C6 N1 Rh1 84.40(12) . . . . ?
C7 C6 N1 Rh1 -90.81(12) . . . . ?
C31 Rh1 N1 C2 141.8(10) . . . . ?
C30 Rh1 N1 C2 179.52(11) . . . . ?
N2 Rh1 N1 C2 -3.26(10) . . . . ?
C31 Rh1 N1 C6 -40.5(11) . . . . ?
C30 Rh1 N1 C6 -2.80(10) . . . . ?
N2 Rh1 N1 C6 174.42(9) . . . . ?
C3 C4 N2 C18 -179.79(11) . . . . ?
C5 C4 N2 C18 -0.20(17) . . . . ?
C3 C4 N2 Rh1 0.17(18) . . . . ?
C5 C4 N2 Rh1 179.76(9) . . . . ?
C23 C18 N2 C4 89.77(15) . . . . ?
C19 C18 N2 C4 -92.26(15) . . . . ?
C23 C18 N2 Rh1 -90.19(13) . . . . ?
C19 C18 N2 Rh1 87.77(13) . . . . ?
C31 Rh1 N2 C4 -176.25(11) . . . . ?
C30 Rh1 N2 C4 123.8(9) . . . . ?
N1 Rh1 N2 C4 2.11(11) . . . . ?
C31 Rh1 N2 C18 3.71(10) . . . . ?
C30 Rh1 N2 C18 -56.2(10) . . . . ?
N1 Rh1 N2 C18 -177.93(9) . . . . ?
