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#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/49/4324933.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4324933
loop_
_publ_author_name
'Pradip Pachfule'
'Raja Das'
'Pankaj Poddar'
'Rahul Banerjee'
_publ_contact_author
;
Dr. Rahul Banerjee
Scientist
Physical/Materials Chemistry Division  
National Chemical Laboratory
Dr. Homi Bhaba Road
Pune 411008, India
;
_publ_contact_author_email       r.banerjee@ncl.res.in
_publ_contact_author_fax         '91 020 2590 2636'
_publ_contact_author_phone       '91 020 2590 2535'
_publ_section_title
;
 Structural, Magnetic, and Gas Adsorption Study of a Series of Partially
 Fluorinated Metal-Organic Frameworks (HF-MOFs)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3855
_journal_page_last               3865
_journal_paper_doi               10.1021/ic1017246
_journal_volume                  50
_journal_year                    2011
_chemical_formula_moiety         'C23 H17 Co F6 N O5'
_chemical_formula_sum            'C23 H17 Co F6 N O5'
_chemical_formula_weight         560.31
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           33
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2c -2n'
_symmetry_space_group_name_H-M   'P n a 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   26.194(13)
_cell_length_b                   10.524(5)
_cell_length_c                   8.243(4)
_cell_measurement_reflns_used    5254
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      28.170
_cell_measurement_theta_min      1.77
_cell_volume                     2272.3(19)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.966
_diffrn_measured_fraction_theta_max 0.966
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1031
_diffrn_reflns_av_sigmaI/netI    0.0683
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            24044
_diffrn_reflns_theta_full        28.17
_diffrn_reflns_theta_max         28.17
_diffrn_reflns_theta_min         1.55
_exptl_absorpt_coefficient_mu    0.841
_exptl_absorpt_correction_T_max  0.8787
_exptl_absorpt_correction_T_min  0.7076
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, Acta Cryst. (1995) A51 33-58'
_exptl_crystal_colour            Pink
_exptl_crystal_density_diffrn    1.638
_exptl_crystal_description       Prismic
_exptl_crystal_F_000             1132.0
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.860
_refine_diff_density_min         -0.998
_refine_diff_density_rms         0.088
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.01(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.095
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     332
_refine_ls_number_reflns         5254
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.095
_refine_ls_R_factor_all          0.0641
_refine_ls_R_factor_gt           0.0550
_refine_ls_shift/su_max          0.017
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0454P)²+1.2236P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1133
_refine_ls_wR_factor_ref         0.1168
_reflns_number_gt                4653
_reflns_number_total             5254
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic1017246_si_002_2.cif
_cod_data_source_block           Co-FMOF-W
_cod_original_cell_volume        2272.4(19)
_cod_original_formula_sum        'C23 H17 Co F6 N O5 '
_cod_database_code               4324933
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z+1/2'
'x+1/2, -y+1/2, z'
'-x+1/2, y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.92732(13) 0.4206(3) 0.2036(5) 0.0180(7) Uani 1 1 d .
C2 C 0.88036(13) 0.3665(3) 0.2861(4) 0.0182(7) Uani 1 1 d .
C3 C 0.85991(13) 0.2503(3) 0.2423(5) 0.0217(8) Uani 1 1 d .
H3 H 0.8740 0.2048 0.1566 0.026 Uiso 1 1 calc R
C4 C 0.81846(14) 0.2015(4) 0.3259(5) 0.0227(8) Uani 1 1 d .
H4 H 0.8044 0.1244 0.2934 0.027 Uiso 1 1 calc R
C5 C 0.79747(13) 0.2656(3) 0.4575(4) 0.0192(8) Uani 1 1 d .
C6 C 0.81682(14) 0.3842(4) 0.4951(5) 0.0233(8) Uani 1 1 d .
H6 H 0.8026 0.4300 0.5803 0.028 Uiso 1 1 calc R
C7 C 0.85692(13) 0.4359(3) 0.4081(5) 0.0210(8) Uani 1 1 d .
H7 H 0.8682 0.5177 0.4316 0.025 Uiso 1 1 calc R
C8 C 0.75641(14) 0.1980(4) 0.5588(5) 0.0235(8) Uani 1 1 d .
C9 C 0.72962(16) 0.2863(5) 0.6813(6) 0.0354(11) Uani 1 1 d .
C10 C 0.78538(18) 0.0947(5) 0.6578(6) 0.0389(12) Uani 1 1 d .
C11 C 0.71307(12) 0.1444(3) 0.4551(4) 0.0173(7) Uani 1 1 d .
C12 C 0.68861(13) 0.0298(4) 0.4899(5) 0.0201(8) Uani 1 1 d .
H12 H 0.7016 -0.0231 0.5703 0.024 Uiso 1 1 calc R
C13 C 0.64533(13) -0.0054(3) 0.4060(4) 0.0201(8) Uani 1 1 d .
H13 H 0.6295 -0.0823 0.4300 0.024 Uiso 1 1 calc R
C14 C 0.62503(13) 0.0721(3) 0.2866(4) 0.0180(7) Uani 1 1 d .
C15 C 0.65044(13) 0.1831(3) 0.2457(5) 0.0212(8) Uani 1 1 d .
H15 H 0.6379 0.2342 0.1627 0.025 Uiso 1 1 calc R
C16 C 0.69445(15) 0.2182(4) 0.3281(5) 0.0246(8) Uani 1 1 d .
H16 H 0.7117 0.2918 0.2981 0.029 Uiso 1 1 calc R
C17 C 0.97620(17) 0.1399(4) -0.1543(5) 0.0318(9) Uani 1 1 d .
H17 H 0.9432 0.1692 -0.1353 0.038 Uiso 1 1 calc R
C18 C 0.98269(19) 0.0124(4) -0.1901(7) 0.0412(12) Uani 1 1 d .
C19 C 1.0314(2) -0.0302(5) -0.2143(9) 0.0608(17) Uani 1 1 d .
H19 H 1.0377 -0.1151 -0.2381 0.073 Uiso 1 1 calc R
C20 C 1.0708(2) 0.0550(5) -0.2029(9) 0.0650(18) Uani 1 1 d .
H20 H 1.1042 0.0276 -0.2183 0.078 Uiso 1 1 calc R
C21 C 1.06128(18) 0.1800(4) -0.1689(7) 0.0429(12) Uani 1 1 d .
H21 H 1.0886 0.2363 -0.1619 0.051 Uiso 1 1 calc R
C23 C 0.9378(2) -0.0752(5) -0.1974(11) 0.075(2) Uani 1 1 d .
H23A H 0.9212 -0.0771 -0.0936 0.112 Uiso 1 1 calc R
H23B H 0.9492 -0.1591 -0.2253 0.112 Uiso 1 1 calc R
H23C H 0.9142 -0.0454 -0.2781 0.112 Uiso 1 1 calc R
C24 C 1.07586(13) 0.4652(3) 0.2026(4) 0.0172(7) Uani 1 1 d .
Co1 Co 1.002784(16) 0.41514(4) -0.07486(8) 0.01643(12) Uani 1 1 d .
F1 F 0.76106(11) 0.3231(3) 0.8016(3) 0.0560(9) Uani 1 1 d .
F2 F 0.69015(10) 0.2294(3) 0.7534(4) 0.0535(8) Uani 1 1 d .
F3 F 0.71199(11) 0.3906(3) 0.6107(4) 0.0465(7) Uani 1 1 d .
F4 F 0.82801(10) 0.1409(3) 0.7221(4) 0.0566(9) Uani 1 1 d .
F5 F 0.79903(9) -0.0023(3) 0.5628(4) 0.0449(7) Uani 1 1 d .
F6 F 0.75839(10) 0.0457(3) 0.7783(3) 0.0516(8) Uani 1 1 d .
N1 N 1.01436(12) 0.2232(3) -0.1456(4) 0.0204(7) Uani 1 1 d .
O1 O 0.94711(9) 0.3567(2) 0.0927(3) 0.0215(6) Uani 1 1 d .
O2 O 0.94568(10) 0.4337(2) -0.2506(3) 0.0206(6) Uani 1 1 d .
O3 O 1.05792(9) 0.4708(3) -0.2483(3) 0.0218(6) Uani 1 1 d .
O4 O 1.06070(10) 0.3930(2) 0.0938(3) 0.0210(6) Uani 1 1 d .
O5 O 0.99339(12) 0.6153(3) -0.0198(4) 0.0275(7) Uani 1 1 d .
H5A H 1.0166(15) 0.636(5) 0.013(7) 0.041 Uiso 1 1 d D
H5B H 0.9705(15) 0.635(5) 0.024(7) 0.041 Uiso 1 1 d D
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 O3 126.0(3) . 2_765
O1 C1 C2 117.6(3) . .
O3 C1 C2 116.4(3) 2_765 .
C3 C2 C7 118.9(3) . .
C3 C2 C1 122.0(3) . .
C7 C2 C1 119.1(3) . .
C2 C3 C4 120.1(4) . .
C2 C3 H3 119.9 . .
C4 C3 H3 119.9 . .
C3 C4 C5 121.2(3) . .
C3 C4 H4 119.4 . .
C5 C4 H4 119.4 . .
C6 C5 C4 117.9(3) . .
C6 C5 C8 123.6(3) . .
C4 C5 C8 118.4(3) . .
C5 C6 C7 121.2(4) . .
C5 C6 H6 119.4 . .
C7 C6 H6 119.4 . .
C6 C7 C2 120.3(3) . .
C6 C7 H7 119.9 . .
C2 C7 H7 119.9 . .
C11 C8 C5 112.8(3) . .
C11 C8 C9 104.5(3) . .
C5 C8 C9 113.3(3) . .
C11 C8 C10 113.4(3) . .
C5 C8 C10 105.5(3) . .
C9 C8 C10 107.4(4) . .
F3 C9 F2 107.3(4) . .
F3 C9 F1 107.4(4) . .
F2 C9 F1 105.9(4) . .
F3 C9 C8 111.8(4) . .
F2 C9 C8 111.9(4) . .
F1 C9 C8 112.2(4) . .
F6 C10 F4 107.0(4) . .
F6 C10 F5 106.6(4) . .
F4 C10 F5 106.8(4) . .
F6 C10 C8 113.9(4) . .
F4 C10 C8 111.3(4) . .
F5 C10 C8 110.9(3) . .
C16 C11 C12 118.4(3) . .
C16 C11 C8 118.3(3) . .
C12 C11 C8 123.0(3) . .
C13 C12 C11 120.5(3) . .
C13 C12 H12 119.8 . .
C11 C12 H12 119.8 . .
C12 C13 C14 120.9(3) . .
C12 C13 H13 119.5 . .
C14 C13 H13 119.5 . .
C13 C14 C15 119.0(3) . .
C13 C14 C24 120.0(3) . 3_455
C15 C14 C24 121.0(3) . 3_455
C14 C15 C16 120.3(3) . .
C14 C15 H15 119.9 . .
C16 C15 H15 119.9 . .
C15 C16 C11 120.7(4) . .
C15 C16 H16 119.7 . .
C11 C16 H16 119.7 . .
N1 C17 C18 123.9(4) . .
N1 C17 H17 118.1 . .
C18 C17 H17 118.1 . .
C19 C18 C17 117.6(5) . .
C19 C18 C23 121.8(5) . .
C17 C18 C23 120.6(5) . .
C18 C19 C20 118.6(5) . .
C18 C19 H19 120.7 . .
C20 C19 H19 120.7 . .
C21 C20 C19 120.4(5) . .
C21 C20 H20 119.8 . .
C19 C20 H20 119.8 . .
N1 C21 C20 122.0(4) . .
N1 C21 H21 119.0 . .
C20 C21 H21 119.0 . .
C18 C23 H23A 109.5 . .
C18 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C18 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
O4 C24 O2 126.4(3) . 2_765
O4 C24 C14 116.4(3) . 3
O2 C24 C14 117.3(3) 2_765 3
O4 Co1 O2 178.07(11) . .
O4 Co1 O1 91.95(12) . .
O2 Co1 O1 89.23(10) . .
O4 Co1 O3 89.14(11) . .
O2 Co1 O3 89.66(11) . .
O1 Co1 O3 178.45(10) . .
O4 Co1 N1 88.42(12) . .
O2 Co1 N1 90.05(11) . .
O1 Co1 N1 90.05(11) . .
O3 Co1 N1 88.88(11) . .
O4 Co1 O5 92.99(11) . .
O2 Co1 O5 88.46(11) . .
O1 Co1 O5 93.92(11) . .
O3 Co1 O5 87.13(11) . .
N1 Co1 O5 175.74(13) . .
C21 N1 C17 117.6(4) . .
C21 N1 Co1 119.9(3) . .
C17 N1 Co1 122.2(3) . .
C1 O1 Co1 127.7(2) . .
C24 O2 Co1 127.5(2) 2_764 .
C1 O3 Co1 131.9(2) 2_764 .
C24 O4 Co1 130.6(2) . .
Co1 O5 H5A 106(5) . .
Co1 O5 H5B 119(4) . .
H5A O5 H5B 116(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.248(4) .
C1 O3 1.270(4) 2_765
C1 C2 1.517(5) .
C2 C3 1.383(5) .
C2 C7 1.387(5) .
C3 C4 1.385(5) .
C3 H3 0.9300 .
C4 C5 1.391(5) .
C4 H4 0.9300 .
C5 C6 1.382(5) .
C5 C8 1.536(5) .
C6 C7 1.383(5) .
C6 H6 0.9300 .
C7 H7 0.9300 .
C8 C11 1.529(5) .
C8 C9 1.541(6) .
C8 C10 1.557(6) .
C9 F3 1.326(6) .
C9 F2 1.335(5) .
C9 F1 1.346(5) .
C10 F6 1.323(5) .
C10 F4 1.328(5) .
C10 F5 1.336(6) .
C11 C16 1.392(5) .
C11 C12 1.395(5) .
C12 C13 1.379(5) .
C12 H12 0.9300 .
C13 C14 1.385(5) .
C13 H13 0.9300 .
C14 C15 1.386(5) .
C14 C24 1.514(5) 3_455
C15 C16 1.388(5) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 N1 1.331(5) .
C17 C18 1.385(6) .
C17 H17 0.9300 .
C18 C19 1.368(7) .
C18 C23 1.494(7) .
C19 C20 1.370(7) .
C19 H19 0.9300 .
C20 C21 1.369(7) .
C20 H20 0.9300 .
C21 N1 1.324(6) .
C21 H21 0.9300 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 O4 1.241(5) .
C24 O2 1.265(4) 2_765
C24 C14 1.514(5) 3
Co1 O4 2.071(3) .
Co1 O2 2.092(3) .
Co1 O1 2.101(3) .
Co1 O3 2.115(3) .
Co1 N1 2.124(3) .
Co1 O5 2.169(3) .
O2 C24 1.265(4) 2_764
O3 C1 1.270(4) 2_764
O5 H5A 0.70(5) .
O5 H5B 0.73(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C3 0.4(5) . .
O3 C1 C2 C3 178.7(3) 2_765 .
O1 C1 C2 C7 -179.0(3) . .
O3 C1 C2 C7 -0.8(5) 2_765 .
C7 C2 C3 C4 -3.7(5) . .
C1 C2 C3 C4 176.9(3) . .
C2 C3 C4 C5 -1.8(6) . .
C3 C4 C5 C6 4.7(6) . .
C3 C4 C5 C8 -171.8(3) . .
C4 C5 C6 C7 -2.1(6) . .
C8 C5 C6 C7 174.2(3) . .
C5 C6 C7 C2 -3.4(6) . .
C3 C2 C7 C6 6.2(5) . .
C1 C2 C7 C6 -174.3(3) . .
C6 C5 C8 C11 132.3(4) . .
C4 C5 C8 C11 -51.4(5) . .
C6 C5 C8 C9 13.8(5) . .
C4 C5 C8 C9 -169.9(4) . .
C6 C5 C8 C10 -103.4(4) . .
C4 C5 C8 C10 72.9(4) . .
C11 C8 C9 F3 -71.1(4) . .
C5 C8 C9 F3 52.0(4) . .
C10 C8 C9 F3 168.1(3) . .
C11 C8 C9 F2 49.3(5) . .
C5 C8 C9 F2 172.4(3) . .
C10 C8 C9 F2 -71.5(5) . .
C11 C8 C9 F1 168.3(3) . .
C5 C8 C9 F1 -68.6(5) . .
C10 C8 C9 F1 47.5(5) . .
C11 C8 C10 F6 -70.4(5) . .
C5 C8 C10 F6 165.7(4) . .
C9 C8 C10 F6 44.6(5) . .
C11 C8 C10 F4 168.5(4) . .
C5 C8 C10 F4 44.7(5) . .
C9 C8 C10 F4 -76.5(5) . .
C11 C8 C10 F5 49.8(4) . .
C5 C8 C10 F5 -74.0(4) . .
C9 C8 C10 F5 164.8(3) . .
C5 C8 C11 C16 -41.7(5) . .
C9 C8 C11 C16 81.7(4) . .
C10 C8 C11 C16 -161.6(4) . .
C5 C8 C11 C12 143.6(3) . .
C9 C8 C11 C12 -92.9(4) . .
C10 C8 C11 C12 23.8(5) . .
C16 C11 C12 C13 -3.6(5) . .
C8 C11 C12 C13 171.0(3) . .
C11 C12 C13 C14 -0.4(6) . .
C12 C13 C14 C15 3.5(5) . .
C12 C13 C14 C24 -176.6(3) . 3_455
C13 C14 C15 C16 -2.5(5) . .
C24 C14 C15 C16 177.6(3) 3_455 .
C14 C15 C16 C11 -1.5(6) . .
C12 C11 C16 C15 4.5(6) . .
C8 C11 C16 C15 -170.3(3) . .
N1 C17 C18 C19 1.4(8) . .
N1 C17 C18 C23 179.9(5) . .
C17 C18 C19 C20 -0.3(9) . .
C23 C18 C19 C20 -178.8(7) . .
C18 C19 C20 C21 -0.4(10) . .
C19 C20 C21 N1 0.2(10) . .
C20 C21 N1 C17 0.8(8) . .
C20 C21 N1 Co1 175.2(5) . .
C18 C17 N1 C21 -1.7(7) . .
C18 C17 N1 Co1 -175.8(4) . .
O4 Co1 N1 C21 -45.5(4) . .
O2 Co1 N1 C21 133.3(4) . .
O1 Co1 N1 C21 -137.4(4) . .
O3 Co1 N1 C21 43.7(4) . .
O5 Co1 N1 C21 63.9(18) . .
O4 Co1 N1 C17 128.6(3) . .
O2 Co1 N1 C17 -52.6(3) . .
O1 Co1 N1 C17 36.6(3) . .
O3 Co1 N1 C17 -142.3(3) . .
O5 Co1 N1 C17 -122.1(16) . .
O3 C1 O1 Co1 -10.5(5) 2_765 .
C2 C1 O1 Co1 167.6(2) . .
O4 Co1 O1 C1 79.2(3) . .
O2 Co1 O1 C1 -102.3(3) . .
O3 Co1 O1 C1 -146(4) . .
N1 Co1 O1 C1 167.7(3) . .
O5 Co1 O1 C1 -13.9(3) . .
O4 Co1 O2 C24 -132(3) . 2_764
O1 Co1 O2 C24 100.6(3) . 2_764
O3 Co1 O2 C24 -80.5(3) . 2_764
N1 Co1 O2 C24 -169.4(3) . 2_764
O5 Co1 O2 C24 6.6(3) . 2_764
O4 Co1 O3 C1 -97.6(3) . 2_764
O2 Co1 O3 C1 83.9(3) . 2_764
O1 Co1 O3 C1 128(4) . 2_764
N1 Co1 O3 C1 174.0(3) . 2_764
O5 Co1 O3 C1 -4.5(3) . 2_764
O2 C24 O4 Co1 9.6(5) 2_765 .
C14 C24 O4 Co1 -170.2(2) 3 .
O2 Co1 O4 C24 150(3) . .
O1 Co1 O4 C24 -82.7(3) . .
O3 Co1 O4 C24 98.4(3) . .
N1 Co1 O4 C24 -172.7(3) . .
O5 Co1 O4 C24 11.3(3) . .
